Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polymer compositions and methods

The present disclosure describes polymer compositions comprising aliphatic polycarbonate chains containing epoxy functional groups. In certain embodiments, the aliphatic polycarbonate chains comprise epoxy functional groups capable of participating in epoxide ring-opening reactions. In certain embodiments, the invention encompasses composites formed by the reaction of nucleophilic reagents and epoxide functional groups, wherein the epoxide functional groups are located on aliphatic polycarbonate chains.

"Precise Control of Molecular Weight and Chain Shape Control in Carbon Dioxide/Epoxide Alternating Copolymerization and Preparation of Low Molecular Weight Poly(alkylene Carbonate) Thereby"

This invention relates to a method of preparing poly(alkylene carbonate) that has a molecular weight and polymer chain structure precisely controlled by adding a chain transfer agent composed of a compound having an alcohol or carboxylic acid functional group upon alternating copolymerization of an epoxide compound and carbon dioxide using a catalyst composed of a trivalent metal complex compound synthesized from a quaternary ammonium salt-containing Salen type ligand, and to a polymer compound prepared thereby. According to this invention, the polymer compound having a star-shaped chain as well as the polymer having a linear chain can be prepared. The low-molecular-weight poly(alkylene carbonate) has an —OH terminal group and can be used alone as a coating agent, etc., and also in mixtures with an isocyanate compound and thus can be easily utilized to prepare polyurethane.

DEGRADABLE POLYCARBONATE SPORT FISHING MATERIALS

Degradable polycarbonates network based bulk materials are provided. The bulk materials of the present disclosure may be produced having a wide range of tunable mechanical, physical, and thermal properties and are hydrolytically degradable. The bulk materials of the present disclosure may be suitable for the manufacture of a variety of sport fishing equipment or other equipment for water use or that may benefit from hydrolytic degradation in the environment. 1. A hydrolytically-degradable device comprising a hydrolytically-degradable polycarbonate network , wherein the hydrolytically-degradable polycarbonate network comprises:a polyhydroxyl monomer that is a natural product, such a polyhydroxyl monomer modified to consume at least one hydroxyl group with an allyl carbonate group, or any mixtures thereof,a crosslinking comonomer; anda functional additive2. The device of claim 1 , wherein the polyhydroxyl monomer is a molecule comprising two or more hydroxyl groups.3. The device of claim 1 , wherein the polyhydroxyl monomer modified to consume at least one hydroxyl group with an allyl carbonate group is an allyl glucopyranoside monomer.4. The device of claim 1 , wherein the polyhydroxyl monomer modified to consume at least one hydroxyl group with an allyl carbonate group is an allyl sucrose monomer.5. The device of claim 1 , wherein the crosslinking comonomer is a thiol comonomer.6. The device of claim 1 , wherein the polycarbonate network has a glass transition temperature in the range of from −25° C. to 175° C.7. The device of claim 1 , wherein the polycarbonate network has a storage modulus in the range of from 0.1 MPa to 4000 MPa.8. The device of claim 1 , wherein the functional additive is selected from the group consisting of glitters claim 1 , dyes claim 1 , fragrances claim 1 , flavorants claim 1 , insect repellents claim 1 , photoacid generators claim 1 , pH sensitive moieties claim 1 , plasticizers claim 1 , tougheners claim 1 , and any combination thereof.9 ...

Polycarbonate Containing Compounds and Methods Related Thereto

Disclosed herein are crosslinked polycarbonates, composition thereof and methods thereof. The crosslinked polycarbonates can be prepared from allyl or epoxy polycarbonates. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention. 122-. (canceled)24. The compound of claim 23 , wherein the targeting peptide is a cancer targeting peptide.25. The compound of claim 23 , wherein the targeting peptide is N-methylmorpholine.26. A nanoparticle claim 23 , comprising the compound of .27. The nanoparticle of claim 26 , further comprising a therapeutic agent claim 26 , prophylactic agent claim 26 , a diagnostic agent claim 26 , or a mixture thereof.28. The nanoparticle of claim 26 , further comprising a cancer therapeutic agent.30. The compound of claim 29 , wherein the targeting peptide is a cancer targeting peptide.31. The compound of claim 29 , wherein the targeting peptide is N-methylmorpholine.32. A nanoparticle claim 29 , comprising the compound of .33. The nanoparticle of claim 32 , further comprising a therapeutic agent claim 32 , prophylactic agent claim 32 , a diagnostic agent claim 32 , or a mixture thereof.34. The nanoparticle of claim 32 , further comprising a cancer therapeutic agent.36. The method of claim 35 , wherein the targeting peptide is a cancer targeting peptide.37. The method of claim 36 , wherein the targeting peptide is N-methylmorpholine.38. The method of claim 35 , wherein the crosslinking thereby forms a nanoparticle.42. The method of claim 41 , wherein the targeting peptide is a cancer targeting peptide.43. The method of claim 42 , wherein the targeting peptide is N-methylmorpholine.44. The method of claim 42 , wherein the crosslinking thereby forms a nanoparticle. This application is a continuation of U.S. application Ser. No. 15/443,456, filed Feb. 27, 2017, which is a continuation of U.S. application Ser. No. 14/399,920, filed Nov. 7, 2014, which is a ...

Polycarbonate Containing Compounds and Methods Related Thereto

Disclosed herein are crosslinked polycarbonates, composition thereof and methods thereof. The crosslinked polycarbonates can be prepared from allyl or epoxy polycarbonates. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention. 122-. (canceled)23. A method of crosslinking polycarbonates , comprising:(a) providing an epoxy functionalized polycarbonate;(b) providing an allyl functionalized polycarbonate; and(c) crosslinking the epoxy functionalized polycarbonate and the allyl functionalized polycarbonate via a crosslinker.24. The method of claim 23 , wherein the crosslinker comprises one or more ether bonds.25. The method of claim 23 , wherein the crosslinker comprises at least one amine moiety.26. The method of claim 23 , wherein the crosslinker comprises at least one thiol moiety.27. The method of claim 23 , wherein the crosslinker comprises at least one amine moiety and at least one thiol moiety.34. The method of claim 23 , wherein the crosslinking thereby forms a nanoparticle.35. A method of crosslinking polycarbonates claim 23 , comprising:(a) providing a first carbonate and a second carbonate; and(b) crosslinking the first carbonate and the second carbonate via a crosslinker having a thiol moiety and an amine moiety.36. The method of claim 35 , wherein the first carbonate is an epoxy functionalized carbonate.39. The method of claim 35 , wherein the first carbonate is an allyl functionalized carbonate.42. The method of claim 35 , wherein the crosslinking thereby forms a nanoparticle. This Application is a continuation of U.S. application Ser. No. 16/422,700, filed May 24, 2019, which is a continuation of U.S. application Ser. No. 15/443,456, filed Feb. 27, 2017, now U.S. Pat. No. 10,308,774, which is a continuation of U.S. application Ser. No. 14/399,920, filed Nov. 7, 2014, now U.S. Pat. No. 9,580,548, which is a National Stage of International Application No. PCT/ ...

POLYCARBONATE POLYOL COMPOSITIONS AND METHODS

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of COand epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO, wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent. 1. A polymerization system for the copolymerization of COand epoxides , the system comprising:a metal complex including a permanent ligand set and at least one ligand that is a polymerization initiator, and{'sub': '2', 'a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO, wherein the chain transfer agent contains one or more masked hydroxyl groups.'}2. The polymerization system of claim 1 , wherein the chain transfer agent has a structure Y-A-(Y) claim 1 , wherein:{'sub': '2', 'each —Y group is independently a functional group capable of initiating chain growth of epoxide COcopolymers or a protected hydroxyl group, wherein at least one Y group is a protected hydroxyl group and the number of Y protected hydroxyl groups is less than the total number of Y groups;'}-A- is a multivalent moiety; andn′ is an integer between 1 and 10, inclusive.4. The polymerization system of claim 3 , wherein each Y group is independently selected from the group consisting of —OR claim 3 , —OH claim 3 , and —C(O)OH.5. ...

Aliphatic polycarbonate compositions and methods

In one aspect, the present invention pertains to novel block materials comprising an aliphatic polycarbonate (APC) chain bound to a hydrocarbon. The invention also provides methods of making the block materials and using them as compatibilizers for polymer blends. In another aspect, the present invention encompasses methods of making blends of APCs with polyolefins. In certain embodiments, the methods comprise the step of blending one or more APCs with one or more polyolefins in the presence of a compatibilizer as described herein. In another aspect, the present invention encompasses novel blends of APCs with polyolefins. In certain embodiments, the blends comprise one or more APCs; at least one polyolefin and a compatibilizer as described herein.

ALIPHATIC POLYCARBONATE

An object of this invention is to find a method for introducing a functional group into an aliphatic polycarbonate without impairing the excellent thermal decomposition property of the aliphatic polycarbonate. 2. The aliphatic polycarbonate according to claim 1 , which has a mass average molecular weight of 60000 or more and 1000000 or less.3. The aliphatic polycarbonate according to claim 1 , wherein the divalent group containing one or more heteroatoms represented by X in formula (1) is a group containing at least one atom selected from the group consisting of an oxygen atom claim 1 , a nitrogen atom claim 1 , and a sulfur atom.5. The aliphatic polycarbonate according to claim 1 , which consists of the constituent unit represented by formula (1) and the constituent unit represented by formula (2).6. An aliphatic polycarbonate composition comprising the aliphatic polycarbonate according to and a crosslinking agent.7. An adhesive composition obtained by using the aliphatic polycarbonate according to .8. An ink composition comprising the aliphatic polycarbonate according to .9. A coating composition comprising the aliphatic polycarbonate according to .10. A binder for sintering claim 1 , comprising the aliphatic polycarbonate according to .11. A dispersant comprising the aliphatic polycarbonate according to .12. An adhesive composition obtained by using the aliphatic polycarbonate according to the aliphatic polycarbonate composition according to .13. An ink composition comprising the aliphatic polycarbonate according the aliphatic polycarbonate composition according to .14. A coating composition comprising the aliphatic polycarbonate according to the aliphatic polycarbonate composition according to .15. A binder for sintering claim 6 , comprising the aliphatic polycarbonate according to the aliphatic polycarbonate composition according to .16. A dispersant comprising the aliphatic polycarbonate according to the aliphatic polycarbonate composition according to . The ...

POLYCARBONATE DIOLS

A polycarbonate diol containing a repeating unit represented by the specific formula (A) and a terminal hydroxyl group, wherein more than 0 mol % and not more than 3.0 mol % of the terminals thereof is an oxolane terminal represented by the specific formula (B).

POLYMERIZABLE COMPOSITION BASED ON ALLYL CARBONATE MONOMERS, POLYMERIZED PRODUCT OBTAINABLE FROM SAID COMPOSITION AND USES THEREOF

The present invention relates to a polymerizable composition based on allyl carbonate monomers comprising: —from 40% to 90% of a first reactive component (component A) comprising at least 50% by weight of diethylene glycol bis(allyl carbonate); 2. Polymerisable composition according to claim 1 , wherein said component A is obtained by reacting diallylcarbonate (DAC) and diethylene glycol (DEG) in a molar ratio DAC/DEG from 2.5/1 to 5/1 claim 1 , preferably from 2.75/1 to 4.0/1 claim 1 , more preferably from 2.5/1 to 3.5/1.3. Polymerisable composition according to claim 1 , wherein said component B is obtained by reacting diallylcarbonate (DAC) and at least one aliphatic polyol having at least 4 alcoholic hydroxyl groups in a molar ratio DAC/polyol from 4/1 to 24/1.4. Polymerisable composition according to claim 3 , wherein said molar ratio DAC/polyol is from 4/1 to 16/1 claim 3 , preferably from 8/1 to 14/1 claim 3 , more preferably from 10/1 to 14/1.5. Polymerisable composition according to claim 3 , wherein said aliphatic polyol having at least 4 alcoholic hydroxyl groups is selected from: di(trimethylolpropane) claim 3 , pentaerythritol claim 3 , di(pentaerythritol) and tri(pentaerythritol).6. Polymerisable composition according to claim 1 , wherein said component B is obtained by reacting diallylcarbonate (DAC) and pentaerythritol in a molar ratio DAC/pentaerythritol from 5/1 to 16/1 claim 1 , preferably from 8/1 to 14/1 claim 1 , more preferably from 10/1 to 14/1.7. Polymerisable composition according to claim 1 , wherein said peroxide radical initiator is selected from: peroxymonocarbonate esters claim 1 , peroxydicarbonate esters claim 1 , diacylperoxides claim 1 , peroxyesters and mixtures thereof.9. Polymerisable composition according to claim 1 , wherein the concentration of said peroxide radical initiator is within the range 0.4-5.0 phm claim 1 , more preferably within the range 0.5-3.5 phm.10. Polymerised product claim 1 , in particular claim 1 , organic ...

POLYMER COMPOSITIONS AND METHODS

The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups. 23-. (canceled)4. The epoxide COcopolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via an ester linkage.5. The epoxide COcopolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via a urethane linkage.6. The epoxide COcopolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via an ether linkage.7. The epoxide COcopolymer composition of claim 1 , wherein the adhesion enhancing functional group comprises a silicon-containing functional group and a silicon atom is bonded directly to a terminal oxygen atom of the epoxide COcopolymer.9. (canceled)12. The epoxide COcopolymer composition of claim 1 , wherein the epoxide COpolymer chains comprise a copolymer of COand an epoxide selected from the group consisting of: ethylene oxide claim 1 , propylene oxide claim 1 , 1 claim 1 ,2 butene oxide claim 1 , cylcohexene oxide claim 1 , epichlorohydrin claim 1 , 3-vinyl cyclohexene oxide claim 1 , 3-ethyl cyclohexene oxide claim 1 , a glycidyl ester claim 1 , a glycidyl ether and any combination of two or more of these.13. The epoxide COcopolymer composition of claim 1 , wherein the epoxide COpolymer chains comprise a copolymer of COand propylene oxide.1416-. (canceled)17. The epoxide COcopolymer composition of claim 1 , wherein the number average molecular weight of the epoxide COcopolymer is between about 500 g/mol and 5 claim 1 ,000 g/mol.1825-. (canceled)2934-. (canceled ...

Polymeric binder and all-solid-state secondary battery

A polymeric binder includes an ion-conducting polymer containing a polymer and a metal ion. The polymer is preferably selected from the group consisting of polyester, polyether, anionic polymer, polycarbonate, and silicone. An all-solid-state secondary battery includes an inorganic solid electrolyte, and the inorganic solid electrolyte in at least an electrode mixture layer or an inorganic solid electrolyte layer is bound together by the polymeric binder.

Polycarbonate Containing Compounds and Methods Related Thereto

Disclosed herein are crosslinked polycarbonates, composition thereof and methods thereof. The crosslinked polycarbonates can be prepared from allyl or epoxy polycarbonates. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention. 1. A method of crosslinking polycarbonates comprising:(a) providing a first epoxy functionalized polycarbonate and a second epoxy functionalized polycarbonate; and(b) crosslinking the first epoxy functionalized polycarbonate and the second epoxy functionalized polycarbonate via a crosslinker.2. The method of claim 1 , wherein the epoxy functionalizations are present as groups pendent from the polycarbonate backbone3. The method of claim 1 , wherein crosslinking thereby forms a particle.4. The method of claim 3 , wherein the particle is a nanoparticle.9. The method of claim 1 , wherein the crosslinker comprises at least two moieties that can be reacted with the epoxy functionalities.10. The method of claim 9 , wherein the moieties are amine moieties.13. The method of claim 9 , wherein the moieties are thiol moieties.16. The method of claim 1 , wherein the first epoxy functionalized polycarbonate and the second epoxy functionalized polycarbonate have the same structure.17. The method of claim 1 , wherein the first epoxy functionalized polycarbonate and the second epoxy functionalized polycarbonate are copolymers.22. A composition comprising the compound of . This Application is a continuation of U.S. application Ser. No. 14/399,920, filed Nov. 7, 2014, which is a National Stage of International Application No. PCT/US2013/040192, filed May 8, 2013, which claims the benefit of U.S. Provisional Application No. 61/644,241, filed on May 8, 2012, which is incorporated herein by reference in its entirety.This invention was made with U.S. government support under grant number CHE-0645737, awarded by the National Science Foundation (NSF), and under grant ...

Isocyanate-free method for preparing poly(carbonate-urethane) or poly(ester-urethane)

The present invention discloses a method for preparing poly(carbonate-urethane) or poly(ester-urethane) without isocyanate.

Highly functional, highly branched or hyperbranched polycarbonates and the production and use hereof

본 발명은 디알킬 또는 디아릴 카르보네이트 또는 포스겐, 디포스겐 또는 트리포스겐 및 지방족 디올 또는 폴리올을 기초로 하는 고작용성의 고분지형 또는 과분지형 폴리카르보네이트에 관한 것이다. 본 발명은 또한 이들의 제조 방법, 및 인쇄용 잉크 제조를 위한 이들의 사용에 관한 것이다. The present invention relates to highly functional, highly branched or hyperbranched polycarbonates based on dialkyl or diaryl carbonates or phosgenes, diphosgenes or triphosgenes and aliphatic diols or polyols. The invention also relates to their production method and their use for the production of printing inks.

Polycarbonate polyol compositions and methods

한 양태에서, 본원 명세서는 1) 영구 리간드 세트를 갖는 금속 배위 화합물과 중합 개시제인 하나 이상의 리간드를 포함하는 촉매 및 2) 중합을 개시할 수 있는 둘 이상의 부위를 갖는 쇄 전이제를 포함하는, CO 2 및 에폭사이드를 공중합하기 위한 중합 시스템을 포함한다. 제2 양태에서, 본원 명세서는 본 발명의 중합 시스템을 사용하여 폴리카보네이트 폴리올을 합성하는 방법을 포함한다. 제3 양태에서, 본원 명세서는 중합체 쇄가 높은 %의 -OH 말단 그룹과 높은 %의 카보네이트 결합을 가짐을 특징으로 하는 폴리카보네이트 폴리올 조성물을 포함한다. 상기 조성물은, 다수의 개별 폴리카보네이트 쇄에 결합된 임베딩(embedding)된 다관능성 잔기를 갖는 중합체 쇄를 함유함을 추가의 특징으로 한다. In one aspect, the present disclosure provides a process for the preparation of a catalyst comprising: 1) a catalyst comprising a metal coordination compound having a permanent set of ligands and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites capable of initiating polymerization. 2 and an epoxide. In a second aspect, the present disclosure includes a method of synthesizing a polycarbonate polyol using the polymerization system of the present invention. In a third aspect, the present specification includes a polycarbonate polyol composition wherein the polymer chain has a high% -OH end group and a high percent carbonate bond. The composition is further characterized in that it comprises a polymer chain having embedded multifunctional moieties attached to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO 2 , wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

Polymer compositions and methods

The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.

Aliphatic polycarbonate polyol compositions

The present invention encompasses CO 2 -based polycarbonate polyols that do not degrade from the chain ends to form cyclic carbonate. Importantly, the inventive polyol compositions retain —OH end group functionality desirable for thermoset applications.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polymer compositions and methods

The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.

Thermoplastic molding compositions and uses thereof

Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of -OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Polymer compositions and methods

Polymerization system for the copolymerization of CO2 and epoxides and related method

Un sistema de polimerización para la copolimerización de CO2 y epóxidos, comprendiendo el sistema: un complejo metálico que incluye un conjunto de ligandos permanentes y por lo menos un ligando que es un iniciador de polimerización, y un agente de transferencia de cadena que tiene un sitio capaz de iniciar la copolimerización de epóxidos y CO2, en el que el agente de transferencia de cadena tiene una estructura HO-RPG, en la que: RPG es un grupo protector de hidroxilo; preferentemente: en el que el agente de transferencia de cadena se selecciona del grupo que consiste en metanol, t-butanol, alcohol alílico, y alcohol bencílico. A polymerization system for the copolymerization of CO2 and epoxides, the system comprising: a metal complex that includes a set of permanent ligands and at least one ligand that is a polymerization initiator, and a chain transfer agent having a site capable of initiating the copolymerization of epoxides and CO2, in which the chain transfer agent has an HO-RPG structure, in which: RPG is a hydroxyl protecting group; preferably: wherein the chain transfer agent is selected from the group consisting of methanol, t-butanol, allyl alcohol, and benzyl alcohol.

Aliphatic polycarbonate polyol compositions

본 발명은 환형 카보네이트를 형성하는, 쇄 말단으로부터 분해되지 않는 CO 2 계 폴리카보네이트 폴리올을 포괄한다. 중요하게, 본 발명의 폴리올 조성물은 열경화성 적용에 바람직한 -OH 말단 작용기을 보유한다. The present invention encompasses CO 2 based polycarbonate polyols that do not decompose from the chain ends to form cyclic carbonates. Importantly, the polyol compositions of the present invention possess desirable -OH terminal functionality for thermosetting applications.

Polymers based on glycerin carbonate and amine

FIELD: chemistry. SUBSTANCE: present invention relates to polymers based on glycerin carbonate. Polymer obtained by polymerizing is described: a) at least one alkylene oxide or cyclic carbonate of formula (I) , where n is a number from 1 to 10, m is a number from 0 to 3 and R 1 denotes alkyl with 1-10 carbon atoms, alkenyl with 2-10 carbon atoms, aryl or aralkyl, b) glycerine carbonate and c) at least one amine, where amine is a primary or secondary amine and ammonia. Also described is a method of producing said polymer, which is realised by polymerisation of components a), b) and c). EFFECT: technical result is obtaining polymers based on glycerine carbonate and comonomer which is alkylene oxide and/or cyclic carbonate. 12 cl, 2 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 600 987 C2 (51) МПК C08G 65/02 (2006.01) C08G 65/26 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013142808/04, 31.01.2012 (24) Дата начала отсчета срока действия патента: 31.01.2012 (72) Автор(ы): РЭТЕР Роман Бенедикт (DE), БРАНД Фабье Жан (FR) (73) Патентообладатель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: R U 22.02.2011 EP 11155406.9 (43) Дата публикации заявки: 27.03.2015 Бюл. № 9 (45) Опубликовано: 27.10.2016 Бюл. № 30 2 6 0 0 9 8 7 (56) Список документов, цитированных в отчете о поиске: WO 2008/142374 A1, 27.11.2008. G. Rokicki, P.Rakoczy, P. Parzuchowski, M. Sobiecki "Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate" Grenn Chem., 2005, 7 p.529539. RU 2151780 C1, 27.06.2000. (86) Заявка PCT: C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 23.09.2013 EP 2012/051607 (31.01.2012) (87) Публикация заявки PCT: R U 2 6 0 0 9 8 7 WO 2012/113617 (30.08.2012) Адрес для переписки: 105064, Москва, а/я 88, "Патентные поверенные Квашнин, Сапельников и партнеры" (54) ПОЛИМЕРЫ НА ОСНОВЕ ГЛИЦЕРИНКАРБОНАТА И АМИНА (57) Реферат: Настоящее ...

Impact-Modified Polyesters with Hyprebranched Polysters/Polycarbonates

Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of A x B y type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of an impact-modifying polymer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.

Polycarbonate polyol compositions

한 양태에서, 본원 명세서는 1) 영구 리간드 세트를 갖는 금속 배위 화합물과 중합 개시제인 하나 이상의 리간드를 포함하는 촉매 및 2) 중합을 개시할 수 있는 둘 이상의 부위를 갖는 쇄 전이제를 포함하는, CO 2 및 에폭사이드를 공중합하기 위한 중합 시스템을 포함한다. 제2 양태에서, 본원 명세서는 본 발명의 중합 시스템을 사용하여 폴리카보네이트 폴리올을 합성하는 방법을 포함한다. 제3 양태에서, 본원 명세서는 중합체 쇄가 높은 %의 -OH 말단 그룹과 높은 %의 카보네이트 결합을 가짐을 특징으로 하는 폴리카보네이트 폴리올 조성물을 포함한다. 상기 조성물은, 다수의 개별 폴리카보네이트 쇄에 결합된 임베딩(embedding)된 다관능성 잔기를 갖는 중합체 쇄를 함유함을 추가의 특징으로 한다. In one aspect, the present specification comprises: 1) a metal coordination compound having a permanent ligand set and a catalyst comprising at least one ligand that is a polymerization initiator and 2) a chain transfer agent having two or more sites capable of initiating polymerization, CO 2 and a polymerization system for copolymerizing epoxides. In a second aspect, the present specification includes a method for synthesizing a polycarbonate polyol using the polymerization system of the present invention. In a third aspect, the present specification includes a polycarbonate polyol composition characterized in that the polymer chain has a high% -OH end group and a high% carbonate bond. The composition is further characterized by containing a polymer chain having embedded polyfunctional moieties bound to a number of individual polycarbonate chains.

Resin composition for disposal resin molded product, and disposal resin molded product

Disclosed is a resin composition for disposable resin molded product, and a disposable resin molded product that enables preparation of a disposable resin molded product not only maintaining excellent mechanical properties but also having biodegradability entailing an environment-friendly feature. The resin composition for disposable resin molded product comprises a polyalkylene carbonate resin.

Resin composition for a disposable resin molded product, and disposable resin molded product

本发明公开了一种用于一次性树脂模制产品的树脂组合物和一次性树脂模制产品，该树脂组合物能够制备不仅保持优异的机械性能而且具有带来有利于环境特性的生物可降解性的一次性树脂模制产品。所述用于一次性树脂模制产品的树脂组合物包含聚碳酸亚烷基酯树脂。

Polycarbonate polyol compositions and methods

一方面，本发明涵盖用于共聚合CO 2 与环氧化物的聚合系统，其包含1)包括金属配位化合物的催化剂，所述化合物具有永久性配体组和至少一个为聚合引发剂的配体，以及2)链转移剂，具有两个或两个以上可起始聚合的位点。第二方面，本发明涵盖使用本发明聚合系统合成聚碳酸酯多元醇的方法。第三方面，本发明涵盖聚碳酸酯多元醇组合物，其特征在于所述聚合物的链具有高比例的‑OH端基和高比例的碳酸酯键联。所述组合物的特征另外在于其含有包埋的多官能部分键联至多个个别聚碳酸酯链的聚合物链。

Polyester molding material with flowability

Hydrolytically Degradable Polymers and Hydrogels Made Therefrom

Conjugates between a protein and a water soluble polymer comprising multiple degradable carbonate linkages are provided.

Highly branched or hyperbranched highly functional polycarbonate, method for producing and using the same

Polycarbonate polyol compositions

한 양태에서, 본원 명세서는 1) 영구 리간드 세트를 갖는 금속 배위 화합물과 중합 개시제인 하나 이상의 리간드를 포함하는 촉매 및 2) 중합을 개시할 수 있는 둘 이상의 부위를 갖는 쇄 전이제를 포함하는, CO 2 및 에폭사이드를 공중합하기 위한 중합 시스템을 포함한다. 제2 양태에서, 본원 명세서는 본 발명의 중합 시스템을 사용하여 폴리카보네이트 폴리올을 합성하는 방법을 포함한다. 제3 양태에서, 본원 명세서는 중합체 쇄가 높은 %의 -OH 말단 그룹과 높은 %의 카보네이트 결합을 가짐을 특징으로 하는 폴리카보네이트 폴리올 조성물을 포함한다. 상기 조성물은, 다수의 개별 폴리카보네이트 쇄에 결합된 임베딩(embedding)된 다관능성 잔기를 갖는 중합체 쇄를 함유함을 추가의 특징으로 한다. In one aspect, the present disclosure provides a process for the preparation of a catalyst comprising: 1) a catalyst comprising a metal coordination compound having a permanent set of ligands and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites capable of initiating polymerization. 2 and an epoxide. In a second aspect, the present disclosure includes a method of synthesizing a polycarbonate polyol using the polymerization system of the present invention. In a third aspect, the present specification includes a polycarbonate polyol composition wherein the polymer chain has a high% -OH end group and a high percent carbonate bond. The composition is further characterized in that it comprises a polymer chain having embedded multifunctional moieties attached to a plurality of individual polycarbonate chains.

Polycarbonate polyols and polyurethanes made therefrom

本发明的实施方案提供的聚碳酸酯多元醇包括至少一种多元醇组分和碳酸酯的反应产物。该聚碳酸酯在室温下是无定形液体和无定形固体中的一种。多元醇组分包括1,3-环己烷二甲醇和1,4-环己烷二甲醇（按照从约60:40到约5:95的重量比）以及源自天然油脂肪酸或天然油脂肪酸甲基酯的多元醇的混合物中的至少一种。

Modified polycarbonates, polyester carbonates and polyesters with improved extensibility and flame retardancy

Die vorliegende Erfindung betrifft Polycarbonat, Polyestercarbonat und Polyester mit Alkylsiloxan-substituierten Phenolen abgeleiteten Endgruppen sowie die Verwendung von phenolischen Verbindungen mit Alkylsiloxan-Substituenten als Kettenabbrecher zur Herstellung von Polycarbonaten, Polyestercarbonaten und Polyestern sowie Formteile und Extrudate aus diesen Polymeren, Verfahren zur Herstellung der Polymere sowie neue phenolische Verbindungen der Formel (2). The present invention relates to polycarbonate, polyester carbonate and polyester with alkylsiloxane-substituted phenols derived end groups and the use of phenolic compounds having alkylsiloxane substituents as chain terminators for the production of polycarbonates, polyester and polyesters, and molded parts and extrudates of these polymers, processes for preparing the polymers and new phenolic compounds of formula (2).

Modified polycarbonates, polyester carbonates and polyesters having improved elongation behavior and flame resistance

The present invention relates to polycarbonate, polyester carbonate and polyester having end groups derived from alkylsiloxane-substituted phenols, as well as to the use of phenolic compounds having alkylsiloxane substituents as chain terminators in the preparation of polycarbonate, polyester carbonate and polyester, as well as to mouldings and extrudates produced from these polymers, to processes for the preparation of the polymers, and to novel phenolic compounds of formula (2).

Polycarbonate polyols and polyurethanes made therefrom

Embodiments of the present invention provide a polycarbonate polyol comprising the reaction product of at least one polyol composition and a carbonate. Polycarbonate polyols are one of amorphous liquids and amorphous solids at room temperature. The polyol composition comprises at least one of a mixture of 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol in a weight ratio of about 60:40 to about 5:95 and a polyol derived from natural oil fatty acid or natural oil fatty acid methyl ester .

Hyper-branched polyesters and polycarbonates as de-emulsifiers for destruction of crude oil emulsions

Изобретение относится к применению гиперразветвленных сложных полиэфиров и поликарбонатов в качестве деэмульгаторов для разрушения эмульсий сырой нефти. Предложено применение недендримерных, высокофункциональных, гиперразветвленных сложных полиэфиров и поликарбонатов, которые могут быть получены взаимодействием (i) по меньшей мере одной алифатической, циклоалифатической, арилалифатической или ароматической дикарбоновой кислоты (A 2 ) или ее производных или органических карбонатов (A 2 '), (ii) по меньшей мере одного x-атомного алифатического, циклоалифатического, арилалифатического или ароматического спирта (C x ), содержащего более двух гидроксильных групп, причем x означает число больше 2, предпочтительно число от 3 до 8, особенно предпочтительно от 3 до 6, еще более предпочтительно 3 или 4, в частности 3, и (iii) по меньшей мере одного алкоксилированного амида жирной кислоты (D), выбранного из группы, включающей алкоксилированные амиды насыщенных или ненасыщенных жирных кислот с 2-30 атомами углерода, содержащие в среднем от 1 до 40 структурных единиц алкиленоксида, в качестве деэмульгаторов для разрушения эмульсий сырой нефти. Технический результат - деэмульгатор позволяет разрушать эмульсию сырой нефти очень быстро, уже на пути к подготовительной установке, при температуре свежедобытой эмульсии. 6 з.п. ф-лы, 1 табл., 3 пр. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08G 63/20 C08G 64/02 C10G 33/04 B01D 17/04 C08G 64/14 (13) 2 516 469 C2 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2011131653/04, 21.12.2009 (24) Дата начала отсчета срока действия патента: 21.12.2009 Приоритет(ы): (30) Конвенционный приоритет: (72) Автор(ы): БРУХМАНН Бернд (DE), АЙХХОРН Андреас (DE), ГУЦМАНН Маркус (DE) 29.12.2008 EP 08172997.2 (43) Дата публикации заявки: 10.02.2013 Бюл. № 4 R U (73) Патентообладатель(и): БАСФ СЕ (DE) (45) Опубликовано: 20.05.2014 Бюл. № 14 C 2 C 2 ...

APPLICATION OF HIGHLY BRANCHED POLYCARBONATES IN COSMETIC AND DERMATOLOGICAL COMPOSITIONS

1. Высокоразветвленные поликарбонаты,отличающиеся тем, что они полностью или частично замещены линейными или разветвленными алкильными или алкенильными остатками с 4-40 атомами углерода,- получены путем превращения высокоразветвленных поликарбонатов во время и/или после реакции полимеризации с соединениями А,- содержат линейный или разветвленный алкильный и/или алкенильный остаток с 4-40 атомами углерода и реакционноспособную по отношению к высокоразветвленному поликарбонату группу,- причем молярное отношение реакционноспособных групп замещающего соединения к реакционноспособным группам высокоразветвленного полимера составляет от 1:10 до 1:1, предпочтительно от 1:5 до 1:1,1, особенно предпочтительно от 1:2 до 1:1,2.2. Замещенные высокоразветвленные поликарбонаты по п.1, отличающиеся тем, что замещение осуществляют посредством производного формул R-CO-Y и/или R-NCO,в которыхR означает линейный или разветвленный алкил с 4-40 атомами углерода,Y означает OR, OC(O)R, NR , галоген,Rозначает водород, линейный или разветвленный алкил с 1-6 атомами углерода,Rозначает линейный или разветвленный алкил с 4-40 атомами углерода, причем остатки R и Rмогут быть одинаковыми или разными,Rозначает водород, линейный или разветвленный алкил с 1-4 атомами углерода, причем остатки Rмогут быть одинаковыми или отличаться друг от друга.3. Косметическая композиция, содержащая по меньшей мере один высокоразветвленный поликарбонат по п.1 или 2.4. Косметическая композиция по п.3, содержащая по меньшей мере одну косметически пригодную основу.5. Применение высокоразветвленного поликарбоната по одному из пп.1-4 в косметических и/или дерматологических композициях.6. Пр� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК A61K 8/84 (13) 2012 126 264 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2012126264/15, 23.11.2010 (71) Заявитель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: 26.11.2009 EP 09177203.8 (85) Дата начала ...

Based on the polymkeric substance of carbonic acid glyceride and amine

本发明涉及一种聚合物和相关聚合方法，以及本发明聚合物例如用作泡沫调节剂，用于分散固体或用作用于洗涤或清洁目的的表面活性剂的用途。该聚合物通过如下组分的聚合而制备：a)至少一种氧化烯或式(I)的环状碳酸酯，其中n为1-10，m为0-3，和R 1 为C 1 -C 10 烷基、C 2 -C 10 链烯基、芳基或芳烷基，b)碳酸甘油酯，和c)至少一种胺。

Polycarbonate polyol compositions and methods

일 측면에서, 본 개시내용은 하기를 포함하는, CO 2 와 에폭사이드의 공중합을 위한 중합 시스템을 포함한다: 1) 영구적 리간드 세트 및 중합 개시제인 적어도 하나의 리간드를 갖는 금속 배위 화합물을 포함하는 촉매, 및 2) 에폭사이드와 CO 2 의 공중합을 개시할 수 있는 1개 이상의 부위를 갖는 사슬 이동제로서, 1개 이상의 차폐된 하이드록실 그룹을 함유하는 사슬 이동제. 제 2 측면에서, 본 개시내용은 본 발명의 중합 시스템을 사용하여 폴리카보네이트 폴리올을 합성하는 방법을 포함한다. 제3 측면에서, 본 개시내용은 폴리카보네이트 폴리올 조성물을 포함하고, 폴리머 사슬은 높은 백분율의 -OH 말단 그룹들, 높은 백분율의 카보네이트 연결들을 가지며, 하이드록실 말단 그룹들을 갖는 실질적으로 모든 폴리카보네이트 사슬들은 포매된 사슬 이동제를 갖지 않는 것을 특징으로 한다. In one aspect, the present disclosure includes a polymerization system for the copolymerization of CO 2 with an epoxide comprising: 1) a catalyst comprising a set of permanent ligands and a metal coordination compound having at least one ligand that is a polymerization initiator , And 2) a chain transfer agent having at least one site capable of initiating copolymerization of an epoxide and CO 2 , wherein the chain transfer agent contains at least one blocked hydroxyl group. In a second aspect, the present disclosure includes a method of synthesizing a polycarbonate polyol using the polymerization system of the present invention. In a third aspect, the present disclosure comprises a polycarbonate polyol composition, wherein the polymer chain has a high percentage of -OH end groups, a high percentage of carbonate linkages, and substantially all of the polycarbonate chains having hydroxyl end groups are It is characterized in that it does not have an embedded chain transfer agent.

Highly functional, hyperbranched polycarbonates and production and use thereof

Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X 3 -(A 1 ) m -X 4 , where the variables are defined as follows: X 1 , X 2 are identical or different and are selected from among halogen, C 1 -C 10 -alkoxy, C 6 -C 10 -aryloxy and O—C(═O)-halogen, X 3 is a functional group selected from among OH, SH, NH 2 , NH—C 1 -C 4 -alkyl, iso-cyanate, epoxy, COOH, COOR 12 , C(═O)—O—C(═O), C(═O)—Cl, R 12 is C 1 -C 4 -alkyl or C 6 -C 10 -aryl, A 1 is a spacer or a single bond, m is zero or one. X 4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.

Polycarbonate resin composition

Disclosed is a polycarbonate resin composition having high biogenic matter content, which is excellent in heat resistance, thermal stability, moldability, hue and transparency. Specifically disclosed is a resin composition containing 0.0005-0.5 part by weight of at least one thermal stabilizer (component S) selected from the group consisting of phosphorus stabilizers (PS) and hindered phenol stabilizers (HS) per 100 parts by weight of a polycarbonate resin (component A) mainly containing a repeating unit represented by the formula (1) below. Also specifically disclosed is a molded article of such a resin composition.

Polycarbonate resins, polycarbonate resin compositions, optical film, and polycarbonate resin molded articles

Polycarbonate resin, production method therefor, and film

Provided are a polycarbonate resin having excellent hue and high thermal stability, a method for producing the polycarbonate resin, and a film. The polycarbonate resin has a polycarbonate structural unit represented by formula (A), contains a terminal group represented by formula (1) or formula (2), and contains 0.1-500 ppm of an aromatic monohydroxy compound. (A) (1) (In formula (1), R 1 represents an optionally substituted alkyl group having 6-15 carbon atoms, etc.) (2) (In formula (2), R 2 and R 3 each independently represent an optionally substituted alkylene group having 1-12 carbon atoms, etc., R 4 represents a hydrogen atom, an optionally substituted alkyl group having 1-12 carbon atoms, etc., and n represents an integer of 1-20.)

Polycarbonate polyol compositions and methods

一方面，本发明涵盖用于共聚合CO 2 与环氧化物的聚合系统，其包含1)包括金属配位化合物的催化剂，所述化合物具有永久性配体组和至少一个为聚合引发剂的配体，以及2)链转移剂，具有两个或两个以上可起始聚合的位点。第二方面，本发明涵盖使用本发明聚合系统合成聚碳酸酯多元醇的方法。第三方面，本发明涵盖聚碳酸酯多元醇组合物，其特征在于所述聚合物的链具有高比例的-OH端基和高比例的碳酸酯键联。所述组合物的特征另外在于其含有包埋的多官能部分键联至多个个别聚碳酸酯链的聚合物链。

Isocyanate-free method for preparing poly(carbonate-urethane) or poly(ester-urethane)

本发明公开了聚(碳酸酯-氨基甲酸酯)或聚(酯-氨基甲酸酯)的不使用异氰酸酯的制备方法。

GLYCERINE CARBONATE AND AMINE POLYMERS

1. Полимер, получаемый путем полимеризации:а) по меньшей мере одного алкиленоксида или циклического карбоната формулы (I):,в которойn означает число от 1 до 10,m означает число от 0 до 3 иRозначает алкил с 1-10 атомами углерода, алкенил с 2-10 атомами углерода, арил или аралкил,b) глицеринкарбоната иc) по меньшей мере одного амина.2. Полимер по п.1, отличающийся тем, что используемым в качестве компонента а) мономером является алкиленоксид, выбранный из группы, включающей этиленоксид, пропиленоксид, 1-бутеноксид, 2-бутеноксид, 1-пентеноксид, оксид стирола, эпихлоргидрин, глицидол, эпоксипропионовую кислоту и ее соли, сложные алкиловые эфиры эпоксипропионовой кислоты, 1-гексеноксид, 1-гептеноксид, 1-октеноксид, 1-ноненоксид, 1-деценоксид, 1-ундеценоксид и 1-додеценоксид, и/или циклический карбонат формулы (I), выбранный из группы, включающей этиленкарбонат и пропиленкарбонат.3. Полимер по п.1, отличающийся тем, что компонентом c) является амин, выбранный из группы, включающей гексиламин, 2-этилгексиламин, 2-пропилгептиламин, дециламин, додециламин, тридециламин и полиэтиленимины.4. Полимер по п.1, отличающийся тем, что компонентом a) является по меньшей мере один алкиленоксид, предпочтительно этиленоксид и/или пропиленоксид.5. Полимер по п.1, отличающийся тем, что полимеризацию осуществляют в виде инициируемого основанием полиприсоединения и/или при полимеризации используют основание, выбранное из группы, включающей KOH, КОСН, KO(трет-бутил), KH, NaOH, NaO(трет-бутил), NaOCH, NaH, натрий, калий, триметиламин, N,N-диметилэтаноламин, N,N-диметилциклогексиламин и более высокомолекулярные N,N-ди-метилалкиламины, N,N-диметиланилин, N,N-диметилбензиламин, N,N,N'N'-тетраме� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08G 65/00 (13) 2013 142 808 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2013142808/04, 31.01.2012 (71) Заявитель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: 22.02.2011 EP ...

Flame retardant polycarbonate resin composition

本発明の目的は、イソソルビドなどのエーテルジオール由来のポリカーボネート樹脂を含有し、難燃性、耐熱性、熱安定性、剛性、透明性および成形加工性に優れた樹脂組成物を提供することにある。本発明は、主として下記式（１）で表される繰り返し単位を含有するポリカーボネート樹脂（Ａ成分）１００重量部に対して、熱分解温度が３４０℃以下のリン化合物（Ｂ成分）１〜６０重量部を含有する難燃性樹脂組成物である。

ORGANIC OLIGOMERS OF GLYCEROL ACYLES

ORGANIC OLIGOMERS OF GLYCEROL ACYLES

L'invention concerne des oligomères organiques de glycérol acylés de formule (I) générale suivante : (I), dans laquelle : - M1 et Q1 sont des groupements organiques ; - G11 est un groupement propyle hydroxylé : - G12 et G13 sont des glycérol α/α'-acylés ; - n est un nombre entier naturel de l'intervalle [0 ; 8] ; - m est un nombre entier naturel de l'intervalle [0 ; 4], et ; - p est un nombre entier naturel de l'intervalle [0 ; 3]. The invention relates to acylated organic glycerol oligomers of the following general formula (I): (I), in which: M1 and Q1 are organic groups; - G11 is a hydroxylated propyl group: - G12 and G13 are α / α'-acylated glycerol; n is a natural integer of the interval [0; 8]; m is a natural integer of the interval [0; 4], and; p is a natural integer of the interval [0; 3].

OLIGOCARBONATES DIMETHACRYLES OR DIACRYLES OBTAINED FROM DIANHYDROHEXITOL DIALKYLCARBONATE OR DIANHYDROHEXITOL CARBONATE DIMER, PROCESS FOR THEIR MANUFACTURE AND USES THEREOF

Procédé de fabrication d'un oligocarbonate diméthacrylé ou diacrylé dénué de groupements aromatiques et de fonctions phénoliques comprenant la stynthÚse d'un oligocarbonate polyol et une étape consistant à faire réagir l'oligocarbonate polyol avec un agent (méth)acrylant choisi parmi le chlorure de methacryloyle, l'anhydride méthacrylique, l'acide méthacrylique ou l'acide acrylique, afin d'obtenir un oligocarbonate diméthacrylé ou diacrylé. A process for producing a dimethylcrystalline or diacrylated oligocarbonate of aromatic groups and phenolic functions, including oligolysis polyol stynthesis and a step of reacting the oligocarbonate polyol with a (meth) acrylant agent selected from methacryloyl chloride, methacrylic anhydride, methacrylic acid or acrylic acid, in order to obtain a dimethylcrystalline or diacrylated oligocarbonate ©.

Highly functional, highly branched or hyperbranched polycarbonates and the production and use hereof

본 발명은 디알킬 또는 디아릴 카르보네이트 또는 포스겐, 디포스겐 또는 트리포스겐 및 지방족 디올 또는 폴리올을 기초로 하는 고작용성의 고분지형 또는 과분지형 폴리카르보네이트에 관한 것이다. 본 발명은 또한 이들의 제조 방법, 및 인쇄용 잉크 제조를 위한 이들의 사용에 관한 것이다.

Branched aliphatic polycarbonates from tri-and tetra

Branched aliphatic polycarbonates are prepared by re-esterification of diaryl carbonates with tri- and tetra-functional hydroxy compounds of the general formula R-C(CH2OH)3, where R is H, C1-5 alkyl or CH2OH. The re-esterification is carried out without a catalyst at 100-200 deg.C., and the reactants are not used in equivalent amounts. The polycarbonates are new compounds. They have a molecular weight below 5000, preferably below 2000. They vary from viscous oils to resinous or glassy materials. They can be used as thickeners for organic solutions or printing pastes or as a basis for ointments; they are intermediates for cross-linking agents for acrylic resin lacquers.

Polycarbonate resin composition

Polymers on the basis of glycerin carbonate and an amine

본 발명은 중합체 및 관련 중합 방법 및 예를 들어 고체 분산을 위한 발포 억제제로서 또는 세정 또는 클리닝 목적을 위한 계면활성제로서의 본 발명에 따른 중합체의 용도에 관한 것이다. a) 하나 이상의 알킬렌 산화물 또는 하기 식 (I) 의 시클릭 카르보네이트: [식 중, n 은 1 내지 10 이고, m 은 0 내지 3 이고, R 1 은 C 1 -C 10 -알킬, C 2 -C 10 -알케닐, 아릴 또는 아르알킬임], b) 글리세린 카르보네이트 및 c) 하나 이상의 아민을 중합시켜 중합체를 제조한다. The present invention relates to polymers and related polymerization methods and to the use of the polymers according to the invention, for example as foam inhibitors for solid dispersion or as surfactants for cleaning or cleaning purposes. a) at least one alkylene oxide or cyclic carbonate of formula (I) Wherein n is 1 to 10, m is 0 to 3 and R 1 is C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, aryl or aralkyl, b) glycerin carbonate and c) at least one amine to produce a polymer.

Preparation of copolymer from carboxy-functionalized polycarbonate and nucleophilic polymer

Carboxy-functionalized polycarbonates are prepared by incorporating a carboxylic acid-substituted phenol, preferably t-butyl p-hydroxybenzoate, as a chainstopper in a polycarbonate-forming reaction. The products are capable of forming copolymers with other polymers such as polyamides and functionalized olefin polymers, by generation of a carboxy group which reacts therewith.

Polycarbonate resin and method for producing same

本发明的目的是提供生物起源物质的含有率高、耐吸湿性、耐热性、热稳定性以及成型加工性优异、表面能量高的聚碳酸酯树脂。本发明是聚碳酸酯树脂及其制造方法，所述聚碳酸酯树脂在整个主链中含有30～100摩尔%的下述式（1）表示的单元，（ⅰ）按照ASTM D6866 05测定的生物起源物质含有率为25%～100%，（ⅱ）将0.7g的树脂溶解于100ml的二氯甲烷中得到的溶液在20℃的比粘度为0.2～0.6，（ⅲ）OH值为2.5×10 3 以下。

PROCEDURE FOR THE OBTAINING OF CYCLIC DERIVATIVES OF CARBONIC ACID.

Flame-retardant polycarbonate resin composition

There is provided a resin composition that comprises a polycarbonate resin derived from an ether diol such as isosorbide and that is excellent in flame retardancy, heat resistance, thermal stability, rigidity, transparency and moldability. The resin composition is a flame-retardant resin composition comprising 1 to 60 parts by weight of phosphorus compound (component B) having a thermal decomposition temperature of not higher than 340° C. based on 100 parts by weight of polycarbonate resin (component A) that mainly comprises a recurring unit represented by the following formula (1).

Polymer compositions and methods

The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron- containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.

Flame-retardant polycarbonate resin composition

High-functionality highly branched or hyperbranched polycarbonates and their preparation and use

본 발명은 디알킬 또는 디아릴 카르보네이트 또는 포스겐, 디포스겐 또는 트리포스겐과 지방족, 지방족/방향족 및 방향족 디올 또는 폴리올을 기초로 하는 고작용성 고분지형 또는 과분지형 폴리카르보네이트 및 페인트 시스템 제조를 위한 이들의 사용에 관한 것이다. The present invention provides the preparation of highly functional, hyperbranched or hyperbranched polycarbonates and paint systems based on dialkyl or diaryl carbonates or phosgene, diphosgene or triphosgene with aliphatic, aliphatic / aromatic and aromatic diols or polyols. For their use. 고작용성, 고분지형, 과분지형, 폴리카르보네이트, 페인트 Highly functional, highly branched, hyperbranched, polycarbonate, paint

Hyperbranched polycarbonates for solubilization of low-solubility active substances

The invention relates to a composition containing an amphiphile and an active substance, which is soluble in water at at 10 g/1. The invention further relates to an amphiphile containing a hyperbranched polycarbonate, which is linked to at least one linear or comb-shaped polymer, to a method for producing the amphiphile, and to the use of the amphiphile in compositions containing an active substance which is soluble in water at at 10 g/1.

Process for the preparation of high molecular weight (cyclo) aliphatic polyesters of carbonic acid with (cyclo) aliphatic diols

High functionality, multi-branched or hyper-branched polycarbonates and their production and use

Terminal modified polycarbonate and manufacturing process thereof

A terminal modified polycarbonate having a high content of biogenic matter, excellent heat resistance, heat stability, moldability and moist absorption resistance and high surface energy and a manufacturing process thereof are provided. The terminal modified polycarbonate has a main chain essentially composed of a recurring unit represented by the following formula (1): has a specific viscosity at 20° C. of a solution obtained by dissolving 0.7 g of the polycarbonate in 100 ml of methylene chloride of 0.2 to 0.5, and contains a terminal group represented by the following formula (2) or (3) in an amount of 0.3 to 9 wt % based on the main chain:

Aliphatic polycarbonate

本发明发现了在不损害脂肪族聚碳酸酯的优良的热分解性的情况下向脂肪族聚碳酸酯中导入官能团的方法。一种脂肪族聚碳酸酯，其包含式(1)(式中，R 1 、R 2 和R 3 相同或不同，表示氢原子、可被1个或2个以上取代基取代的碳原子数1～10的烷基、或者可被1个或2个以上取代基取代的碳原子数6～20的芳基，R 1 ～R 3 中的2个可相互键合并与它们所键合的碳原子一起形成取代或未取代的饱和或不饱和的环元数为3～10的脂肪族环，X表示包含1个或2个以上杂原子的二价基团或碳原子数3以上的亚烷基)所示的结构单元和式(2)(式中，R 4 、R 5 、R 6 和R 7 相同或不同，表示氢原子、可被1个或2个以上取代基取代的碳原子数1～10的烷基、或者可被1个或2个以上取代基取代的碳原子数6～20的芳基，R 4 ～R 7 中的2个可相互键合并与它们所键合的碳原子一起形成取代或未取代的饱和或不饱和的环元数为3～10的脂肪族环)所示的结构单元，式(1)所示的结构单元的含量相对于式(1)与式(2)的结构单元的合计量为0.1摩尔％以上且1.5摩尔％以下。

Copolycarbonates

Toner resins for electronic copying purposes

본 발명은 수평균 분자량이 500 내지 10000이고 유리 전이 온도가 30 내지 80℃이며 히드록실 기 값이 30 mg KOH/g 이하인 폴리카르보네이트, 및 전자 복사용 토너 또는 현상제를 제조하기 위한 성분으로서 사용되는 우레탄 개질 수지에서의 상기 폴리카르보네이트의 용도에 관한 것이다. 또한, 본 발명은, 특허청구범위 제1항 내지 제5항 중 어느 한 항에 따른 폴리카르보네이트 및 유리 전이 온도가 10 내지 60℃이고 히드록실 기 값이 20 내지 100 mg KOH/g인 중축합 수지를 포함하는 중합체 혼합물과 다관능성 이소시아네이트 혼합물의 반응에 의해서 얻을 수 있으며 여기서 폴리카르보네이트 및 중축합 수지의 중량비는 20:80 내지 80:20이고 폴리이소시아네이트 화합물 중의 이소시아네이트 기 대 중합체 혼합물 중의 히드록실 기의 몰비는 0.4 내지 1.2:1인 우레탄 개질 수지뿐 아니라 상기 우레탄 개질 폴리카르보네이트 기재 수지를 포함하는 전자 복사용 토너, 및 상기 토너 및 임의로 담체를 포함하는 현상제에 관한 것이다. The present invention relates to a polycarbonate having a number average molecular weight of 500 to 10000, a glass transition temperature of 30 to 80 DEG C and a hydroxyl group value of 30 mg KOH / g or less, and a component for producing a toner or developer for electron radiation To the use of said polycarbonate in the urethane modifying resins used. The polycarbonate according to any one of claims 1 to 5 and a polycondensate having a glass transition temperature of 10 to 60 占 폚 and a hydroxyl group value of 20 to 100 mg KOH / g Wherein the weight ratio of polycarbonate and polycondensate resin is from 20:80 to 80:20 and the ratio of isocyanate groups in the polyisocyanate compound to hydroisocyanate groups in the polymer mixture And a hydroxyl group-containing urethane-modified polycarbonate base resin as well as a urethane-modified resin having a molar ratio of 0.4 to 1.2: 1, and a developer comprising the toner and optionally a carrier.

Polycarbonate diol

本発明は、塗料の材料として、又は、ポリウレタンの原料として適したポリカーボネートジオールを提供することを目的とする。本発明は、塗料の構成材料として用いる場合、耐薬品性と、基材への密着性と、の少なくとも一つを確保できる塗膜を得ることができるポリカーボネートジオールを提供することを目的とする。また、本発明は、ポリウレタンの原料として用いる場合、機械的強度と、耐熱性と、柔軟性と、の少なくとも一つを確保できるポリウレタンを得ることが可能であるポリカーボネートジオールを提供することを目的とする。 特定の式（Ａ）で表される繰り返し単位と末端ヒドロキシル基とを含み、末端の０モル％より大きく３．０モル％以下が特定の式（Ｂ）で表されるオキソラン末端であるポリカーボネートジオール。 An object of the present invention is to provide a polycarbonate diol suitable as a material for paints or as a raw material for polyurethane. An object of the present invention is to provide a polycarbonate diol capable of obtaining a coating film capable of ensuring at least one of chemical resistance and adhesion to a substrate when used as a constituent material of a coating material. Another object of the present invention is to provide a polycarbonate diol capable of obtaining a polyurethane capable of ensuring at least one of mechanical strength, heat resistance, and flexibility when used as a raw material for polyurethane. do. Polycarbonate diol containing a repeating unit represented by the specific formula (A) and a terminal hydroxyl group, and more than 0 mol% at the end and 3.0 mol% or less being the oxolane terminal represented by the specific formula (B). ..

Impact-resistant modified polyester comprising hyperbranched polyesters/polycarbonates

A) 1종 이상의 열가소성 폴리에스테르 10 내지 99.99 중량％, B) B1) (DIN 53240, 파트 2에 따라) 폴리카르보네이트 1 g당 1 내지 600 mg KOH의 OH가를 갖는 1종 이상의 고분지형 또는 초분지형 폴리카르보네이트, 또는 B2) A x B y (x는 1.1 이상이고 y는 2.1 이상임) 유형의 1종 이상의 고분지형 또는 초분지형 폴리에스테르 또는 이들의 혼합물로 구성되는 혼합물 0.01 내지 50 중량％, 및 C) 충격성-개질 중합체 1 내지 40 중량％, D) 기타 첨가제 0 내지 60 중량％를 포함하며, 성분 A) 내지 D)의 중량％의 총합이 100％인 열가소성 성형 조성물. 열가소성 폴리에스테르, 성형 조성물, 사출 성형, 충격성 개질 중합체, 초분지형 폴리에스테르/폴리카르보네이트

Thermoplastic polyester-based moulding materials containing a mixture of hyper-branched polycarbonate and hyper-branched polyester, used for production of fibres, film and moulded parts, e.g. vehicle components and fittings

Thermoplastic polyester moulding materials (I) also contain 0.01-50 wt% of a mixture of highly-branched or hyper-branched polycarbonate(s) with an OH number of 1-600 mg KOH/g and highly-branched or hyper-branched polyester(s) of the A xB ytype. Thermoplastic moulding materials (I) containing (A) 10-99.99 wt% thermoplastic polyester, (B) 0.01-50 wt% of a mixture of (B1) highly-branched or hyper-branched polycarbonate with an OH number of 1-600 mg KOH/g and (B2) highly-branched or hyper-branched polyester(s) of the A xB ytype in which x : at least 1.1; y : at least 2.1 , and (C) 0-60 wt% other additives. An independent claim is also included for fibres, film and moulded products of all kinds made from (I).

Branched polyether carbonate polyols and process for preparation thereof

يتعلق الاختراع الحالي بعملية لتحضير بوليولات بولي إثير كربونات (polyether carbonate polyols) متفرعة، تشمل خطوة تفاعل أكسيد ألكيلين (alkylene oxide) وثاني أكسيد الكربون (carbon dioxide) مع مركب باديء وظيفي H (H-functional starter compound) في وجود حفاز، حيث يجرى التفاعل إضافيا في وجود مركب تفريع (branching compound) يشمل مجموعة وظيفية قابلة للبلمرة بواسطة فتحة حلقة (ring opening) ومجموعة وظيفية H. يضاف مركب التفريع أثناء التفاعل بحيث يكون مقدار مركب التفريع ≤ 7.5٪ بالوزن في أي وقت أثناء الإضافة، اعتمادا على كمية المركب الباديء الوظيفي H، أكسيد ألكيلين ومركب التفريع المضاف في هذا الوقت. يتعلق الاختراع إضافيا مع جليكول بولي إثير كربونات قابل للتحضير بواسطة عملية الاختراع ومع بوليمرات بولي إثير كربونات (polyether carbonate polymers) متصلة تقاطعيا معتمدة عليه.

Hyperbranched polycarbonates for solubilizing poorly soluble active substances

Terminal-modified polycarbonate and process for producing the same

本发明的目的在于，提供一种具有高生物起源物质含有率、耐热性、热稳定性、成型加工性以及耐吸湿性出色、表面能高的聚碳酸酯。本发明涉及末端改性聚碳酸酯及其制造方法，关于末端改性聚碳酸酯，其主链基本上由右述式(1)所示的重复单元构成，将其0.7g溶于二氯甲烷100ml中得到的溶液在20℃的比粘度为0.2～0.5，相对于主链含有右述式(2)或者(3)所示的末端基团0.3～9重量％，(在右述式(2)、(3)中，R 1 是碳原子数4～30的烷基等、碳原子数7～30的芳烷基、碳原子数4～30的全氟代烷基、或所述式(4)所示的基团，X表示从单键、醚键、硫醚键、酯键、氨基键以及酰胺键中选择的至少一种键，a是1～5的整数)。

Branched polyether carbonate polyols and method for their preparation

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung verzweigter Polyethercarbonatpolyole, umfassend den Schritt der Umsetzung eines Alkylenoxids und Kohlendioxid mit einer H-funktionellen Starterverbindung in Gegenwart eines Katalysators, wobei die Umsetzung weiterhin in Gegenwart einer Verzweigerverbindung durchgeführt wird, welche eine durch Ringöffnung polymerisierbare funktionelle Gruppe sowie eine H-funktionelle Gruppe umfasst. Die Verzweigerverbindung wird während der Umsetzung derart hinzugefügt, dass der Anteil der Verzweigerverbindung im erhaltenen Reaktionsgemisch zu jedem Zeitpunkt während des Hinzufügens ‰¤ 7,5 Gewichts-%, bezogen auf die Menge an zu diesem Zeitpunkt zugegebener H-funktioneller Starterverbindung, Alkylenoxid und Verzweigerverbindung, beträgt. Die Erfindung betrifft weiterhin ein nach dem erfindungsgemäßen Verfahren herstellbares Polyethercarbonatpolyol sowie hierauf basierende vernetzte Polyethercarbonat-Polymere. The present invention relates to a process for preparing branched polyethercarbonate polyols, comprising the step of reacting an alkylene oxide and carbon dioxide with an H-functional starter compound in the presence of a catalyst, the reaction also being carried out in the presence of a branching compound which has a functional group polymerizable by ring opening and comprises an H-functional group. The branching compound is added during the reaction such that the proportion of the branching compound in the resulting reaction mixture at any point during the addition is ‰¤7.5% by weight, based on the amount of H-functional starter compound, alkylene oxide and branching compound added at that point. amounts to. The invention further relates to a polyether carbonate polyol which can be prepared by the process according to the invention and to crosslinked polyether carbonate polymers based thereon.

Photoactive additive with functionalized benzophenone

Photoactive additives are disclosed. The additive includes a benzophenone having at least one substituent that comprises a divalent linker and a linking group, wherein the linking group is a carboxyl group, ester group, or acid halide group. The additive can be a polymer, an oligomer, or a compound. When added to a base polymeric resin, the photoactive additive permits crosslinking upon exposure to ultraviolet light.

Aliphatic polycarbonate compositions and methods

Polycarbonate polyol compositions and methods

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of -OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

Composition comprising amphiphile and active substance, which is soluble in h2o at 20 ° C, maximum 10 g / l in which amphiphilic contains hyperbranched polycarbonate, which is bound with at least one linear or comb-shaped polymer and / or a functional unit c1-c24; amphiphilic; process for preparing amphiphilic; and its use.

Composición que comprende anfifilo y sustancia activa, que está soluble en h20 a 20 grados Celsius, como máximo, 10 g/l en que anfifilo contiene policarbonato hiperramificado, que está ligado con al menos un polímero lineal o en forma de peine y/o una unidad funcional c1-c24; anfifilo; proceso para preparar anfifilo; uso; y material propagación. Composition comprising amphiphile and active substance, which is soluble in h20 at 20 degrees Celsius, maximum 10 g / l in which amphiphile contains hyperbranched polycarbonate, which is bound with at least one linear or comb-shaped polymer and / or a functional unit c1-c24; amphiphilic; process for preparing amphiphilic; use; and propagation material.

Polymer compositions and methods

The present disclosure describes polymer compositions comprising aliphatic polycarbonate chains containing epoxy functional groups. In certain embodiments, the aliphatic polycarbonate chains comprise epoxy functional groups capable of participating in epoxide ring-opening reactions. In certain embodiments, the invention encompasses composites formed by the reaction of nucleophilic reagents and epoxide functional groups, wherein the epoxide functional groups are located on aliphatic polycarbonate chains.

Isocyanate-free production method of poly (carbonate-urethane) or poly (ester-urethane)

Organic oligomers of acylglycerol

Organic oligomers of acylglycerol having general formula (I): Formula (I), in which M1 and Q1 are organic groups; G11 is a hydroxylpropyl group; G12 and G13 are α/α′-acylglycerols; n is a natural integer from the range [0; 8]; m is a natural integer from the range [0; 4]; and p is a natural integer from the range [0; 3].

Polymer composition and method

本公开描述包含含有环氧官能团的脂肪族聚碳酸酯链的聚合物组合物。在某些实施方案中，所述脂肪族聚碳酸酯链包含能够参与环氧化物开环反应的环氧官能团。在某些实施方案中，本发明包括通过亲核试剂和环氧官能团的反应形成的复合物，其中所述环氧官能团位于脂肪族聚碳酸酯链上。

Polycarbonate resin and method for producing same

本发明提供一种耐热性、机械强度优异，在聚合时、成型时不易着色，透明性、色调优异的新型的聚碳酸酯树脂。一种聚碳酸酯树脂，其特征在于，含有来自下述式(1)所示的二羟基化合物的结构单元，所述式(1)所示的二羟基化合物的硼酸含量为100重量ppm以下且/或叔胺含量为1000重量ppm以下，进一步具有来自下述式(2)所示的碳酸二酯的末端苯基，该末端苯基浓度为30μeq/g以上。(式(1)中，R 1 、R 2 、R 3 、R 4 各自独立地表示氢原子、碳原子数1～10的烷基、碳原子数1～10的烷氧基、碳原子数3～20的环烷基、碳原子数6～20的环烷氧基、碳原子数6～10的芳基、碳原子数7～20的芳烷基、碳原子数6～10的芳氧基或碳原子数7～20的芳烷氧基、或者卤素原子。环丁烷环表示顺式·反式异构体混合物、顺式异构体单独、反式异构体单独中的任一种)(式(2)中，R 5 、R 6 各自独立地为取代或无取代的芳香族基团)

Polymeric binder and all-solid-state secondary battery

Fluid polyester moulding masses

The invention relates to thermoplastic moulding masses, containing A) 10 to 99.99 wt. % of at least one thermoplastic polyester, B) 0.01 to 50 wt. % of a hyperbranched polycarbonate, having a hydroxyl number of 1 to 600 mg KOH/g polycarbonate (according to DIN 53240, part 2) and C) 0 to 60 wt. % of other additives, the sum of the weight percentages of the constituents A) to C) being equal to 100 %.