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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 22911. Отображено 100.
26-01-2012 дата публикации

Flame-retardant poly lactic acid-containing film or sheet, and method for manufacturing thereof

Номер: US20120021202A1
Принадлежит: Nitto Denko Corp

Provided is a film or sheet composed of a resin composition that includes a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic cyclic phosphazene-containing flame retardant (D) including a compound of General Formula (I) and in which the aromatic cyclic phosphazene-containing flame retardant (D) is included in an amount of 10 to 70 parts by weight based on 100 parts by weight of the poly lactic acid (A), and a method for manufacturing the film or sheet by melt film formation. Each sign in Formula is as described in the specification.

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26-01-2012 дата публикации

Olefin/acrylic polymer blends

Номер: US20120022218A1
Автор: Hailan Guo, Jian-Yang Cho
Принадлежит: Rohm and Haas Co

In one aspect of the present invention, there is provided a polymeric film comprising one or more polyolefin and one or more acrylic polymer, wherein the weight ratio of said acrylic polymer to said polyolefin is from 0.02:1 to 5:1, wherein said polyolefin comprises polymerized units of one or more functional monomer, wherein the amount of said polyolefin in said polymeric film is more than 30% by weight, based on the weight of said polymeric film, and wherein said acrylic polymer comprises polymerized units of one or more hydrogen-bondable monomer.

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02-02-2012 дата публикации

Aqueous dispersion, its production method, and its use

Номер: US20120029132A1
Принадлежит: Dow Global Technologies LLC

Aqueous dispersions including at least one thermoplastic resin; at least one dispersing agent; and water; wherein the dispersion has a pH of less than 12 are disclosed along with dispersions including at least one thermoplastic resin; at least one dispersing agent; and water wherein the dispersion has a volume average particle size of less than about 5 μm. Some dispersions include less than about 4 percent by weight of the dispersing agent based on the weight of the thermoplastic resin. Other dispersions include at least one propylene-rich alpha-olefin interpolymer; at least one dispersing agent; and water. Methods of making such dispersions are also described.

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23-02-2012 дата публикации

Phylon Processes of Making Foam Articles Comprising Ethylene/alpha-Olefins Block Interpolymers

Номер: US20120046373A1
Принадлежит: Individual

Methods of making a foam article comprise the steps of compressing a foam at an elevated temperature in a mold for shaping the foam; and cooling the mold to a temperature greater than room temperature, wherein the foam comprises at least one ethylene/α-olefin block interpolymer. The foam may further comprise an ethylene vinyl acetate copolymer and an additive such as a filler or a crosslinking agent. The ethylene/α-olefin block interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block.

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26-04-2012 дата публикации

Process for producing resin molded article

Номер: US20120098160A1
Принадлежит: Sumitomo Chemical Co Ltd

A process for producing a resin molded article, comprising steps of (1) plasticizing a resin composition containing an organic fiber and a thermoplastic resin with an injection-molding machine, (2) injecting the plasticized resin composition into a mold cavity of the injection-molding machine, and (3) pressure-holding against the resin composition in the mold cavity for a pressure-holding time of 0.5 to 60 seconds under holding-pressure of 70 to 300 MPa.

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03-05-2012 дата публикации

Thermoplastic Composition

Номер: US20120108722A1
Автор: Dean Thetford
Принадлежит: Lubrizol Advanced Materials Inc

The invention relates to a composition containing a particulate solid, a plastic material and a compound obtained/obtainable by a process comprising (i) reacting at a temperature of 120° C. or less, or 100° C. or less a hydroxycarboxylic acid and a lactone; and (ii) optionally reacting the product of (i) with a C 1-50 carboxylic acid. The invention further relates to novel compounds, and the use of the compound as a dispersant in a plastic material.

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03-05-2012 дата публикации

Polymer composition, method for producing non-stretched film, non-stretched film, heat seal material, and packing material

Номер: US20120108754A1
Принадлежит: Du Pont Mitsui Polychemicals Co Ltd

Provided is a polymer composition that contains an ionomer which includes an ethylene-α,β-unsaturated carboxylic acid copolymer and a ternary polymer of ethylene-α,β-unsaturated carboxylic acid-α,β-unsaturated carboxylic acid ester, and a propylene-based polymer, wherein a melt flow rate (MFR) value (under a load of 2160 g) of the ionomer at a process temperature in forming a film by T-die melting casting method is from 50% to 250% based on an MFR value of the propylene-based polymer under the same condition.

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10-05-2012 дата публикации

Thermoplastic resin composite bead production method, expandable thermoplastic resin composite bead, expanded thermoplastic resin composite bead, and foamed molded article formed from expanded thermoplastic resin composite beads

Номер: US20120115968A1
Принадлежит: JSP Corp

A seed beads dispersing disperse system is obtained by dispersing olefin resin seed beads 1 with a specific tubular shape in an aqueous medium. Then, the olefin resin seed beads 1 are impregnated with styrene monomers and the styrene monomers are polymerized in the presence of a polymerization initiator by heating at a temperature in a specified range, to thereby obtain tubular thermoplastic resin composite beads. Expandable thermoplastic resin composite beads obtained by impregnating the thermoplastic resin composite beads with a blowing agent, expanded thermoplastic resin composite beads obtained by foaming and expanding the expandable thermoplastic resin composite beads, and a foamed molded article formed from the expanded thermoplastic resin composite beads by molding are also obtained.

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09-08-2012 дата публикации

Microporous membranes, methods for making such membranes, and the use of such membranes as battery separator film

Номер: US20120202044A1
Принадлежит: Toray Tonen Speciality Separator GK

The invention relates to microporous membranes having one or more layers comprising polymer and inorganic molecules. The invention also relates to methods for producing these membranes, and the use of these membranes as battery separator film.

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30-08-2012 дата публикации

Methods of Improving the Physical Properties of Polyolefin Films

Номер: US20120217682A1
Принадлежит: Nova Chemicals Inc

Methods of improving the physical properties of a polyolefin film that include providing interpolymer resin particles, forming a blend composition by blending from about 0.1 to about 25% by weight based on the weight of the blend composition of interpolymer resin particles into a second polyolefin; and forming a film from the blend composition. The interpolymer resin particles are made up a styrenic polymer intercalated within a first polyolefin. The first polyolefin is present at from about 20% to about 80% by weight based on the weight of the particles and the styrenic polymer is present at from about 20% to about 80% by weight based on the weight of the particles.

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25-10-2012 дата публикации

Gas-barrier multilayer film

Номер: US20120270058A1
Принадлежит: Toyobo Co Ltd

Provided is a gas-barrier multilayer film which is superior in gas-barrier properties and interlayer adhesion property, and which exhibits less deterioration in gas-barrier properties and is resistant to interlayer delamination even in prolonged exposure to a high-temperature and high-humidity environment or after a retort treatment. A gas-barrier multilayer film, wherein (A) a first inorganic thin film layer, (C) a gas-barrier resin composition layer, and (D) a second inorganic thin film layer are stacked in this order with or without intervention of other layers on at least one surface of a plastic film, the gas-barrier resin composition layer (C) is formed from a gas-barrier resin composition comprising (a) a gas-barrier resin including an ethylene-vinyl alcohol-based copolymer, (b) an inorganic layered compound, and (c) at least one additive selected from coupling agents and crosslinking agents, and the content of the inorganic layered compound (b) in the gas-barrier resin composition is from 0.1% by mass to 20% by mass based on 100% by mass in total of the gas-barrier resin (a), the inorganic layered compound (b), and the additive (c).

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08-11-2012 дата публикации

High melt strength polyethylene compositions and methods for making the same

Номер: US20120283390A1
Принадлежит: Dow Brasil SA, Dow Global Technologies LLC

The present invention is a method for increasing the melt strength of a polyethylene resin comprising reacting the polyethylene resin with a free radical generator with a decomposition energy in between −50 kJoule/mole and −250 kJoules/mole and a peak decomposition temperature of less than 280 degree C. The resulting resin has increased melt strength with higher ratio of elongational viscosities at 0.1 to 100 rad/s when compared to substantially similar polyethylene resins which have not been reacted with a free radical generator such as an alkoxy amine derivative.

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31-01-2013 дата публикации

Deformable, rigid polystyrene foam board

Номер: US20130030069A1
Принадлежит: OWENS CORNING INTELLECTUAL CAPITAL LLC

Provided are methods for producing a high strength, but easily deformed, polystyrene foam board that can endure repeated deformations from its original configuration into more complex curved shapes without damaging the board integrity or substantially reducing its structural strength. Also provided are rigid polystyrene foam boards produced by this method that exhibit improved bending and impact resistance while substantially retaining or improving other properties, for example, the thermal dimensional stability and fire resistance, exhibited by corresponding conventional XPS foam boards. The foamable compositions may incorporate one or more of a variety of polymer processing aids for the purpose of altering the performance of the final foam products, thereby allowing the properties of the final foam product to be customized to some degree.

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28-02-2013 дата публикации

Separator film, its fabrication method, supercapacitor, battery and capacitor provided with said film

Номер: US20130052539A1
Принадлежит: Bollore SE

The invention relates to a separator film for a device used for storing electrical energy, the film being porous and oriented, and being obtained by stretching in a longitudinal direction and in a direction transverse to the longitudinal direction, the film containing a mixture comprising a polypropylene homopolymer, at least 10% of a copolymer obtained from monomers comprising at least propylene and ethylene, and at least one beta-nucleating agent. According to the invention, the ethylene content of the copolymer is ≧1% but <10% and a propylene content of the copolymer is ≧90% for a film thickness of ≧8 microns and ≦30 microns, corresponding to a specified space factor according to the IEC-60674-3-1 standard greater than or equal to 145% and a density of the biaxially stretched film greater than or equal to 0.18 g/cm 3 but less than or equal to 0.41 g/cm 3 .

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28-02-2013 дата публикации

Recycled thermoplastic with toughener

Номер: US20130053503A1
Принадлежит: EI Du Pont de Nemours and Co

Disclosed is a thermoplastic composition including a) a recycled thermoplastic including polyamide resin, polyolefin and mineral filler, wherein the recycled thermoplastic includes at least 60 weight percent content of recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, blends of polyamide 66 and polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and at least 1 weight percent content of polyolefin; b) polymer toughener, wherein the polymer toughener includes at least 50 to 85 weight percent non-functionalized rubber and 15 to 50 weight percent of a functionalized rubber; and c) 10 to 50 reinforcing agent having a minimum aspect ratio of 3; and molded articles manufactured therefrom.

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21-03-2013 дата публикации

Insulating member for covering a conduit in a clean room

Номер: US20130071593A1
Принадлежит: Individual

This disclosure provides an insulating member for covering a conduit in a clean room. The insulating member typically has a length and defines a cavity extending along the length. The cavity is sized and shaped to receive the conduit. The insulating member typically includes an innermost layer that may be a closed cell fluoropolymer foam and is disposed to contact the conduit. The insulating member also typically includes an outermost layer that is disposed on the innermost layer and that may be a second fluoropolymer.

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27-06-2013 дата публикации

Resin compositions for extrusion coating

Номер: US20130164552A1
Автор: Jian Wang
Принадлежит: Dow Global Technologies LLC

A composition of matter suitable for use in extrusion coating applications is disclosed. The composition comprises a blend of particular LLDPE with particular LDPE. The LLDPE has the following characteristics: a density in the range of from 0.89 g/cc to 0.97 g/cc; an MWD less than 2.8; a melt index (I 2 ) in the range of 4.0 to 25 g/10 min; a Comonomer Distribution Constant in the range of from greater than from 45 to 400; and a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition. The LDPE has a melt index (I 2 ) in the range of 0.1 to 15 g/10 min, and has a melt strength which satisfies the inequality: Log Melt strength (cN)> 1.14−0.6 ×Log I 2 (g/ 10 min, 190 ° C.)

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14-11-2013 дата публикации

Method of forming polymeric foam and related foam articles

Номер: US20130303645A1
Принадлежит: MuCell Extrusion LLC

Methods of forming polymeric foams are provided. The methods may involve co-extruding a foam layer along with one or more skin layers. In some embodiments, the skin layer(s) may be removed (e.g., in a peeling operation); while, in other embodiments, the skin layer(s) may form part of the final article. The methods are particularly well suited for producing polymeric foams from polymeric materials that are considered to be difficult to foam by those of skill in the art.

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09-01-2014 дата публикации

Process for Obtaining A Film that Comprises the Incorporation of Natural Antimicrobial Agents in a Polymeric Structure

Номер: US20140008836A1
Принадлежит: Universidad de Santiago de Chile

A process for obtaining a film that comprises the incorporation of natural antimicrobial agents in a polymeric structure for the development of packages designed to increase the shelf life of chilled or refrigerated meat, preferably fresh chilled salmon; said process comprises the following steps: a) mixing a first extrusion of the antimicrobial active agent with low density polyethylene powder to obtain a pellet; b) a second extrusion to obtain a film incorporating the pellet obtained in step (a) in a proportion of 10% polyethylene pellets; c) conduct a three-layer coextrusion to develop the film into which the antimicrobial agent is incorporated, wherein the antimicrobial active agent is incorporated into the film layer which is in direct contact with salmon, where the binder, the middle and the outer structure of the film, provide the requirements for the film structure, without the incorporation of the active agent.

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27-02-2014 дата публикации

Aqueous polymer dispersions and products from those dispersions

Номер: US20140058034A1
Принадлежит: Dow Global Technologies LLC

A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.

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20-03-2014 дата публикации

Flame-retardant polyamides with pale color

Номер: US20140080949A1
Принадлежит: BASF SE

Thermoplastic molding compositions comprising A) from 10 to 99.8% by weight of a thermoplastic polyamide, B) from 0.1 to 60% by weight of red phosphorus, C) from 0.01 to 4% by weight of a Cu(I) salt or Ag(I) oxide or Cu(I) complex or Ag(I) salt or Cu(I) oxide or Ag(I) complex, or a mixture of these, D) from 0 to 40% by weight of an impact modifier, and E) from 0 to 60% by weight of further additional substances, where the total of the percentages by weight of A) to E) is 100%.

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27-03-2014 дата публикации

Thermally foamable resin composition, thermally foamable resin sheet, foam, and production method thereof

Номер: US20140088211A1
Принадлежит: Nitto Denko Corp

A thermally foamable resin composition includes a base resin, foamable resin particles, and a cross-linking agent, wherein each of the foamable resin particles contains a solid resin and a thermally expandable substance contained in the solid resin.

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03-04-2014 дата публикации

Electret sheet

Номер: US20140091249A1
Принадлежит: KANSAI UNIVERSITY, Sekisui Chemical Co Ltd

Provided is an electret having high piezoelectric properties. An electret sheet of the invention is characterized in that it comprises a synthetic resin sheet is electrified by injecting electric charges thereinto, that the synthetic resin sheet comprises two types of synthetic resins incompatible with each other, and that these synthetic resins form a phase separated structure and are cross-linked through a polyfunctional monomer. Therefore, positive and negative charges in an apparently polarized state are present in the interfacial portions between the two types of synthetic resins incompatible with each other. By applying an external force to the electret sheet to deform it, the relative positions of these positive and negative charges are changed, and these changes cause a favorable electrical response. Therefore, the electret sheet has high piezoelectric properties.

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06-01-2022 дата публикации

POLYMER FOAM ARTICLES AND METHODS OF MAKING POLYMER FOAMS

Номер: US20220002511A1
Принадлежит:

Molded polymer foam articles are described as having a novel foam structure. The polymer foam articles include a continuous polymer matrix defining a plurality of pneumatoceles therein which is present throughout the entirety of the article. The surface region is further characterized as having compressed pneumatoceles. The novel foam structure is achieved even when molding polymer foam articles comprising a shape and volume wherein a sphere having a diameter between 2 cm and 1000 cm would fit within the article in at least one location without protruding from a surface of the article, and the article further has a total volume of more than 1000 cm. Methods of making a stabilized molten polymer foam, and of making a molded polymer foam article using the stabilized molten polymer foam are also described. 1. A method of forming a molten polymer foam , the method comprising:heating and mixing a thermoplastic polymer with a pneumatogen source to form a molten pneumatic mixture, wherein the temperature of the molten pneumatic mixture exceeds the temperature at which the pneumatogen source produces a pneumatogen at atmospheric pressure, and wherein a pressure applied to the molten pneumatic mixture is sufficient to substantially prevent formation of pneumatoceles;collecting a selected amount of the molten pneumatic mixture in a collection region;defining an expansion volume in the collection region proximal to the molten pneumatic mixture that results in a pressure drop at a rate of 0.01 GPa/s to 5 GPa/s, to form a molten polymer foam; anddispensing the molten polymer foam from the collection region.2. The method of wherein the method is carried out using an injection molding machine claim 1 , further wherein a backpressure is set to be 500 kPa to 25 MPa.3. The method of wherein the method further comprises allowing an expansion period of 0 seconds to 5 seconds to pass after the defining and before the dispensing claim 1 , wherein the molten polymer foam is allowed to ...

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06-01-2022 дата публикации

Polyamides with phosphorous and al-phosphonates

Номер: US20220002543A1
Принадлежит: BASF SE

Described herein are thermoplastic molding materials including components:A) 10 to 98.5 wt % of a thermoplastic polyamide,B) 1 to 20 wt % of red phosphorus,C) 0.5 to 15 wt % of an aluminum salt of phosphonic acid,D) 0 to 55 wt % of a fibrous or particulate filler or mixtures thereof,E) 0 to 30 wt % of further additives,wherein the weight percentages of the components A) to E) sum to 100%.

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01-01-2015 дата публикации

Polymeric material for an insulated container

Номер: US20150001435A1
Принадлежит: Berry Plastics Corp

A formulation includes a polymeric material, a nucleating agent, a blowing agent, and a surface active agent. The formulation can be used to form a container.

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05-01-2017 дата публикации

COMPOSITE RESIN PARTICLES, FOAMABLE PARTICLES, PRE-FOAMED PARTICLES, AND FOAM MOLDED BODY

Номер: US20170002163A1
Принадлежит: SEKISUI PLASTICS CO., LTD.

Composite resin particles including: a polyethylene-based resin and a polystyrene-based resin, wherein the polyethylene-based resin and the polystyrene-based resin are included in the ranges of 50 to 20% by mass and 50 to 80% by mass respectively, with respect to the total of these resins, the polyethylene-based resin is composed of: a first polyethylene-based resin having a medium density to a high density in the range of 925 to 965 kg/m; and a second polyethylene-based resin which is linear and which has a lower density than the first polyethylene-based resin, and the first polyethylene-based resin and the second polyethylene-based resin are included in the ranges of 90 to 30% by mass and 10 to 70% by mass respectively, with respect to the total of these resins. 1. Composite resin particles comprising: a polyethylene-based resin and a polystyrene-based resin , whereinsaid polyethylene-based resin and said polystyrene-based resin are included in ranges of 50 to 20% by mass and 50 to 80% by mass respectively, with respect to the total of these resins,{'sup': '3', 'said polyethylene-based resin is composed of: a first polyethylene-based resin having a medium density to a high density in a range of 925 to 965 kg/m; and a second polyethylene-based resin which is linear and which has a lower density than said first polyethylene-based resin, and'}said first polyethylene-based resin and said second polyethylene-based resin are included in ranges of 90 to 30% by mass and 10 to 70% by mass respectively, with respect to the total of these resins.2. The composite resin particles according to claim 1 , wherein said second polyethylene-based resin has a density of 15 kg/mor more lower than the density of said first polyethylene-based resin.3. The composite resin particles according to claim 1 , wherein said first polyethylene-based resin has a crystallization calorific value of 140mJ/mg or more and said second polyethylene-based resin has a crystallization calorific value of ...

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05-01-2017 дата публикации

THERMALLY EXPANDABLE COMPOSITIONS

Номер: US20170002164A1
Принадлежит:

The present application relates to a thermally expandable composition containing an endothermic chemical blowing agent, to shaped bodies containing said composition and to a method for sealing and filling cavities in components, for strengthening or reinforcing components, in particular hollow components, and for bonding movable components using shaped bodies of this type. 1. A thermally expandable composition containing at least one endothermic chemical blowing agent , at least one reactive binder and at least one of a curing agent and an accelerator.2. The thermally expandable composition according to claim 1 , wherein the at least one endothermic chemical blowing agent is selected from bicarbonates claim 1 , solid polycarboxylic acids claim 1 , solid polycarboxylic acid salts and mixtures thereof; and the at least one reactive binder is selected from the group consisting of epoxies claim 1 , rubbers claim 1 , peroxide-crosslinkable polymers and combinations thereof.3. The thermally expandable composition according to claim 2 , wherein the endothermic chemical blowing agent contains a bicarbonate of formula XHCO claim 2 , wherein X is a cation.4. The thermally expandable composition according to claim 3 , wherein X is selected from Na claim 3 , K claim 3 , NH claim 3 , ½ Zn claim 3 , ½ Mg claim 3 , ½ Ca and mixtures thereof.5. The thermally expandable composition according to claim 2 , wherein the endothermic chemical blowing agent contains a mixture of 2 or more bicarbonates.6. The thermally expandable composition according to claim 2 , wherein the solid polycarboxylic acids are selected from organic di- claim 2 , tri- claim 2 , tetra- acids and combinations thereof.7. The thermally expandable composition according to claim 2 , wherein the solid polycarboxylic acids comprise hydroxyl-functionalized and/or unsaturated di- claim 2 , tri- claim 2 , tetra- or polycarboxylic acids.8. The thermally expandable composition according to claim 2 , wherein the endothermic ...

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05-01-2017 дата публикации

BARRIER FILM FOR FOOD PACKAGING

Номер: US20170002186A1
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

Barrier films are prepared from a blend of two high density polyethylene blend components and a high performance organic nucleating agent. The two high density polyethylene blend components have substantially different melt indices. Large reductions in the moisture vapor transmission rate of the film are observed in the presence of the nucleating agent when the melt indices of the two blend components have a ratio of greater than 10/1. The resulting barrier films are suitable for the preparation of packaging for dry foods such as crackers and breakfast cereals. 115-. (canceled)16. A method for improving the barrier properties of a polyethylene film , said method comprising the steps of converting into a film a mixture comprising;{'sub': '2', 'I) from about 5 to about 60 weight percent, based on the total weight of said mixture, of a blend component a), comprising a first high density polyethylene having a melt index, I;'}{'sub': '2', 'II) from about 95 to about 40 weight percent, based on the total weight of said mixture, of a blend component b), comprising a second high density polyethylene having a melt index I′, and;'}III) from 100 to 3,000 ppm of a nucleating agent, comprising a calcium salt of 1,2 cyclohexanedicarboxylic acid;{'sub': 2', '2, 'wherein, a melt index ratio, defined by dividing said melt index, I, of said blend component a) by said melt index, I′′, of blend component b), is from about 12 to about 19;'}wherein each of said blend component a) and said blend component b) have a density from about 0.950 to about 0.975 g/cc;wherein said mixture has a melt index from about 0.5 to about 4 grams/10 minutes;wherein the water vapor transmission rate of said polyethylene film is improved, by being from about 19 percent lower to about 25 percent lower relative to a control polyethylene film of the same composition but not containing said nucleating agent, and;wherein melt index is measured according to ASTM D1238 (2.16 kg load and 190° C.), density is measured ...

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02-01-2020 дата публикации

Polymer foam and preparation method thereof

Номер: US20200002498A1
Автор: Fuqi Liu, Zhenhuan LUO

The present disclosure relates to a polymer foam and a preparation method thereof. The polymer foam is obtained by physically foaming a thermoplastic elastomer or a polyolefin material, and has an apparent density of 0.30 g/cm3 or less and a rebound degree of 50% or more as measured according to ASTM D2632.

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02-01-2020 дата публикации

METHOD FOR PHYSICALLY FOAMING A POLYMER MATERIAL AND FOAMED ARTICLE

Номер: US20200002499A1
Автор: Liu Fuqi, Luo Zhenhuan
Принадлежит:

The present disclosure relates to a method for physically foaming a polymer material and a foamed article. The method for physically foaming a polymer material comprises: (1) making a thermoplastic elastomer or a polyolefin material into a blank with an injector, an extruder, or a molding press; (2) subjecting the polyolefin blank to a crosslinking reaction to obtain a crosslinked polyolefin blank; (3) subjecting the thermoplastic elastomer blank or the crosslinked polyolefin blank to a high pressure impregnation with a supercritical fluid in an autoclave, then releasing the pressure to a normal pressure to obtain a supercritical fluid-impregnated blank; and (4) placing the supercritical fluid-impregnated blank into an end-product mold to perform an 1:1 in-mold foaming to obtain a finished foam article. 1. A method for physically foaming a polymer material , comprising:(1) making a thermoplastic elastomer or a polyolefin material into a thermoplastic elastomer blank or a polyolefin blank with an injector, an extruder, or a molding press;(2) subjecting the polyolefin blank to a crosslinking reaction to obtain a crosslinked polyolefin blank;(3) subjecting the thermoplastic elastomer blank or the crosslinked polyolefin blank to a high pressure impregnation with a supercritical fluid at a pressure of 10-50 MPa in an autoclave, then releasing the pressure to a normal pressure to obtain a supercritical fluid-impregnated blank; and(4) placing the supercritical fluid-impregnated blank into an end-product mold to perform an 1:1 in-mold foaming to obtain a finished foam article.2. The method according to claim 1 , wherein claim 1 , the thermoplastic elastomer comprises at least one of a thermoplastic polyurethane (TPU) claim 1 , a thermoplastic polyester elastomer (TPEE) claim 1 , and a polyether block amide elastomer (Pebax) claim 1 , or a mixture thereof.3. The method according to claim 1 , wherein claim 1 , the polyolefin material comprises at least one of poly(ethylene-co ...

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03-01-2019 дата публикации

SEMIAROMATIC POLYAMIDE RESIN AND PREPARATION METHOD THEREOF AND POLYAMIDE MOLDING COMPOSITION CONSISTING OF THE SAME

Номер: US20190002638A1
Принадлежит:

The present invention discloses a semiaromatic polyamide resin, a preparation method thereof, and a polyamide molding composition consisting of the same, which consists of following components: 19-. (canceled)10. A semiaromatic polyamide resin consisting of following components in percentage by weight:(A) 20-95 wt % of a PA10T homopolymer derived from 1,10-decanediamine and terephthalic acid; and(B) 5-80 wt % of a PA6T homopolymer derived from 1,6-hexanediamine and terephthalic acid;wherein (A)+(B)=100 wt %.11. The semiaromatic polyamide resin according to claim 10 , wherein the semiaromatic polyamide resin consists of following components in percentage by weight:(A) 30-85 wt % of the PA10T homopolymer derived from 1,10-decanediamine and terephthalic acid; and(B) 15-70 wt % of the PA6T homopolymer derived from 1,6-hexanediamine and terephthalic acid;wherein (A)+(B)=100 wt %.12. The semiaromatic polyamide resin according to claim 11 , wherein the semiaromatic polyamide resin consists of following components in percentage by weight:(A) 40-70 wt % of the PA10T homopolymer derived from 1,10-decanediamine and terephthalic acid; and(B) 30-60 wt % of the PA6T homopolymer derived from 1,6-hexanediamine and terephthalic acid;wherein (A)+(B)=100 wt %.13. The semiaromatic polyamide resin according to claim 10 , wherein with reference to ASTM D3418-2003 claim 10 , a melting point of the semiaromatic polyamide resin is 280° C.-340° C. claim 10 , preferably 285° C.-320° C. claim 10 , more preferably 290° C.-310° C.14. The semiaromatic polyamide resin according to claim 11 , wherein with reference to ASTM D3418-2003 claim 11 , a melting point of the semiaromatic polyamide resin is 280° C.-340° C. claim 11 , preferably 285° C.-320° C. claim 11 , more preferably 290° C.-310° C.15. The semiaromatic polyamide resin according to claim 12 , wherein with reference to ASTM D3418-2003 claim 12 , a melting point of the semiaromatic polyamide resin is 280° C.-340° C. claim 12 , preferably ...

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03-01-2019 дата публикации

SEMIAROMATIC COPOLYAMIDE RESIN AND POLYAMIDE MOLDING COMPOSITION CONSISTING OF THE SAME

Номер: US20190002639A1
Принадлежит:

The present invention discloses a semiaromatic copolyamide resin and a polyamide molding composition consisting of the same, consisting of following repeat units: 112-. (canceled)13. A semiaromatic copolyamide resin consisting of following repeat units by molar percentage:(A) based on an amount of all monomeric units, 26-80 mol % of units derived from para-amino benzoic acid;(B) based on the amount of all monomeric units, 4-70 mol % of units derived from 11-aminoundecanoic acid or undecanolactam, and 0-70 mol % of units derived from another amino acids having 6-36 carbon atoms or units consisting of a lactam having 6-36 carbon atoms;(C) based on the amount of all monomeric units, 0-37 mol % of units derived from a diamine unit having 4-36 carbon atoms; and(D) based on the amount of all monomeric units, 0-37 mol % of units derived from a diacid unit having 6-36 carbon atoms;wherein, (A)+(B)+(C)+(D)=100 mol %; and molar contents of the units derived from para-amino benzoic acid and the units derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol % simultaneously.14. The semiaromatic copolyamide resin according to claim 13 , wherein the semiaromatic copolyamide resin consists of the following repeat units by molar percentage:(A) based on the amount of all monomeric units, 26-80 mol % of the units derived from para-amino benzoic acid; and(B) based on the amount of all monomeric units, 4-70 mol % of the units derived from 11-aminoundecanoic acid or undecanolactam, and 4-70mol % of the units derived from the amino acids having 6-36 carbon atoms or the units consisting of the lactam having 6-36 carbon atoms;wherein, (A)+(B)=100 mol %; and the molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol % simultaneously.15. The semiaromatic copolyamide resin according to claim 13 , wherein the semiaromatic copolyamide resin consists of the following repeat ...

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03-01-2019 дата публикации

ETHYLENE ALPHA-OLEFIN COPOLYMERS WITH MULTIMODAL COMONOMER DISTRIBUTIONS AND PROCESSES FOR OBTAINING THE SAME

Номер: US20190002676A1
Принадлежит: Braskem S.A.

A polymer composition may include a plurality of ethylene-based polymers forming a multimodal composition distribution, each having a distinct crystallization peak in a CEF curve. A process of making a polymer composition may include melt blending a plurality of polyethylenes with different microstructural characteristics in the molten state. Another process of making a polymer composition may include polymerizing ethylene and an optional alpha olefin in combination with a plurality of metallocene catalysts in a polymerization reactor to form a plurality of ethylene based polymers. Yet another process of making a polymer composition may include polymerizing ethylene and an optional alpha olefin in combination with a multimetal catalyst in a polymerization process to form a plurality of ethylene based polymers. 1. A polymer composition , comprising:a plurality of ethylene-based polymers forming a multimodal composition distribution, each having a distinct crystallization peak in a CEF curve.2. The polymer composition of claim 1 , wherein the distinct crystallization peaks comprise at least two peaks in a range of 40 to 120° C.3. The polymer composition of claim 2 , wherein the at least two peaks are in the range of 40 to 75° C. and 85 to 110° C.4. The polymer composition of claim 3 , further comprising a third peak in the range of 70 to 90° C.5. The polymer composition of claim 1 , wherein the plurality of ethylene-based polymer comprises two or more of:a first polyethylene having an alpha-olefin comonomer content ranging from 0 to 10 wt %;a second polyethylene having an alpha-olefin comonomer content ranging from 10 to 15 wt %; anda third polyethylene having an alpha-olefin comonomer content ranging from 15 to 40 wt %.6. The polymer composition of claim 5 , wherein the first polyethylene is present in an amount ranging from 0 to 30 wt % claim 5 , the second polyethylene is present in an amount ranging from 0 to 60 wt % claim 5 , and the third polyethylene is present ...

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03-01-2019 дата публикации

Product with absorbed gel

Номер: US20190002698A1
Автор: Rossi Enrico Maria
Принадлежит: NX GEL LLC

A product with absorbed gel leaving the exposed surface of such product free of stickiness and/or free of the release of oils in any appreciable amounts. 1. A product with gel , comprising:a porous substrate; anda gel substrate adjoined to the porous substrate, the gel substrate comprising a thermoplastic elastomer, a paraffinic aromatic oil, and a viscosity modifier compound;wherein the viscosity modifier compound comprises:a powder of low density ultrafine polyethylene;a slip agent; anda linear low density polyethylene resin.2. The product as claimed in claim 1 , wherein particles of the powder of low density ultrafine polyethylene are essentially spherical with an average size comprised between 10 micron and 50 micron.3. The product as claimed in claim 1 , wherein the powder of low density ultrafine polyethylene is comprised between 1% and 7% by weight.4. The product as claimed in claim 1 , wherein the slip agent comprises a refined vegetable oil mixed with erucamide.5. The product as claimed in claim 4 , wherein the slip agent is comprised between 0.2% and 1% by weight.6. The product as claimed in claim 1 , wherein the linear low density polyethylene resin comprises a hexane copolymer.7. The product as claimed in claim 6 , wherein the linear low density polyethylene resin is comprised between 0.5% and 2% by weight.8. The product claimed in claim 1 , wherein the gel substrate comprises an antioxidant.9. The product as claimed in claim 8 , wherein the antioxidant is a phenolic antioxidant.10. The product as claimed in claim 9 , wherein the antioxidant is comprised between 0.1% and 0.5% by weight.11. The product as claimed in claim 1 , wherein the gel substrate comprises a phase change material.12. The product as claimed in claim 11 , wherein the phase change material comprises particles containing paraffin with a melting point comprised between 24° C. and 32° C.13. The product as claimed in claim 12 , wherein the phase change material is comprised up to 25% by ...

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01-01-2015 дата публикации

POLYPROPYLENE-BASED RESIN COMPOSITION AND FOAM SHEET

Номер: US20150004394A1
Принадлежит: Japan Polypropylene Corporation

Provided is a polypropylene-based resin composition which gives uniform and fine cells and from which a foamed sheet and thermoform excellent in appearance, thermoformability, impact resistance, lightness, stiffness, heat resistance, heat insulating properties, oil resistance and the like can be produced. A polypropylene-based resin composition comprising (X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which block copolymer comprises (Y-1) a propylene (co)polymer and (Y-2) a propylene-ethylene copolymer, said resin (X) having properties (X-i) to (X-iv) and said block copolymer (Y) having properties (Y-i) to (Y-v), and the like. 1: A polypropylene-based resin composition comprising:(X) 5 to 99% by weight of a polypropylene resin comprising a structure with long chain branches, and (Y-1) a propylene (co)polymer, and', '(Y-2) a propylene-ethylene copolymer, and wherein said resin (X) has:, '(Y) 1 to 95% by weight of a sequentially polymerized propylene-based block copolymer wherein said resin (Y) comprises(X-i): a melt flow rate (MFR) of 0.1 to 30.0 g/10 minutes,(X-ii): a molecular weight distribution Mw/Mn of 3.0 to 10.0 measured by GPC and Mz/Mw of 2.5 to 10.0, [{'br': None, 'log(MT)≧−0.9×log(MFR)+0.7, or'}, {'br': None, 'MT≧15,'}], '(X-iii): a melt tension (MT) (unit: g) where'}(X-iv): a content of p-xylene soluble components (CXS) at 25° C. of less than 5% by weight based on the total amount of said resin (X), and whereinsaid block copolymer (Y) has:(Y-i): a weight ratio of 50 to 99% of (Y-1) and 1 to 50% of (Y-2) where said ratio is calculated based on the total weight of said block copolymer (Y) regarded as 100% by weight, and(Y-ii): an MFR of said block copolymer (Y) of 0.1 to 200.0 g/10 minutes,(Y-iii): a melting point of said block copolymer (Y) of more than 155° C.,(Y-iv): an ethylene content of said (Y-2) of 11.0 ...

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13-01-2022 дата публикации

PACKAGED VISCOELASTIC POLYMER SUBSTANCE

Номер: US20220010079A1
Принадлежит: TESA SE

Packaged viscoelastic polymer substances and methods for the production of the packaged viscoelastic polymer substances are provided. The packaged viscoelastic polymer substances are further processable under the influence of heat and shear. 1. A method for producing a packaged viscoelastic polymer substance , the method comprising:a) plastifying a viscoelastic polymer substance at elevated temperatures, the viscoelastic polymer substance being a polymer substance based on poly(meth)acrylates having a weight-average molecular weight of 500,000 g/mol or more;b) continuously dispensing the plastified viscoelastic polymer substance into a protective polymer film, that has no self-adhesive properties and which, before being filled with the plastified viscoelastic polymer substance, has been brought into a tubular form, to give a strandlike polymer assembly having a diameter of 55 to 70 mm, a core of the plastified viscoelastic polymer substance, and a shell of the protective polymer film, wherein a fraction of the protective polymer film, based on a total weight of the protective polymer film and the plastified viscoelastic polymer substance, is less than 1.0 wt %, and wherein the plastified viscoelastic polymer substance has a viscosity of more than 100 Pas at the instant of being dispensed into the tubular protective polymer film;c) converting the strandlike polymer assembly into a flattened strandlike polymer assembly with a smallest cross-section having a ratio of width to height of about 2:1 to 7:1;d) cooling the flattened strandlike polymer assembly to a temperature at which the strandlike polymer assembly is still plastically deformable; ande) subsequently winding the flattened strandlike polymer assembly onto a reel, wherein the strandlike polymer assembly wound onto the reel has a length of more than 30 meters.2. The method of claim 1 , wherein the converting of the strandlike polymer assembly into the flattened strandlike polymer assembly in c) is carried out ...

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01-01-2015 дата публикации

Method For Recycling Floor Coverings

Номер: US20150005401A1
Принадлежит: CLARIANT FINANCE (BVI) LIMITED

The invention relates to a solvent-based separation method for the total material recycling of materials used in nonwoven, woven, and tufted wares into the individual material components thereof sorted by type. At least one of the materials contains a polyolefin wax. As a solvent and/or swelling agent, halogen-free, aliphatic hydrocarbons or aromatic hydrocarbons or a mixture of one or several of said solvents are used. 1. A method of recovering individual varietally pure component materials used combined with each other in tufteds , wovens and nonwovens comprising the step of selective dissolution , selective swelling or both , wherein at least one of the component materials contains a polyolefin wax and the solvent and/or the swellant used comprises halogen-free aliphatic hydrocarbons aromatic hydrocarbons or both.2. The method as claimed in wherein the polyolefin wax comprises homo- or copolymers manufactured from ethylene claim 1 , propylene claim 1 , higher α-olefins of 4 to 20 carbon atoms or a combination thereof by polymerizing in the presence of metallocene catalysts and wherein the polyolefin wax has a dropping or softening point claim 1 , ring/ball claim 1 , between 70 and 160° C. and a melt viscosity claim 1 , as measured at a temperature of 170° C. claim 1 , of not more than 40 000 mPa·s.3. The method as claimed in claim 1 , wherein the polyolefin wax has a weight-average molar mass Mbetween 1000 and 40 000 g/mol and a number-average molar mass Mbetween 500 and 25 000 g/mol.4. The method as claimed in claim 1 , wherein the polyolefin wax is a homopolymer based on ethylene or propylene or a copolymer consisting of propylene and 0.1 to 30 wt % of ethylene 0.1 to 50 wt % of at least one branched or unbranched C-Cα-olefin or a mixture thereof and wherein the polysiefin wax has a melt viscosity claim 1 , as measured at 170° C. claim 1 , of not more than 30 000 mPa·s.5. The method as claimed in claim 1 , wherein the polyolefin wax and its recyclate have a ...

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01-01-2015 дата публикации

POLYOLEFIN MICROPOROUS FILM AND METHOD FOR PRODUCING SAME

Номер: US20150005405A1
Принадлежит:

A polyolefin microporous membrane is produced by forming a gel-like molding using a polyolefin resin containing polypropylene, and stretching the molding in at least one direction, followed by washing, the polyolefin microporous membrane having an injection of electrolyte of 20 seconds or less and a uniform polypropylene distribution in at least one plane perpendicular to the thickness direction. 16-. (canceled)7. A polyolefin microporous membrane produced by forming a gel-like molding using a polyolefin resin containing polypropylene , and stretching the molding in at least one direction , followed by washing , the polyolefin microporous membrane having an injection of electrolyte of 20 seconds or less and a uniform polypropylene distribution in at least one plane perpendicular to the thickness direction.8. The polyolefin microporous membrane according to claim 7 , wherein the polyolefin resin contains polypropylene having a weight average molecular weight of more than 50 claim 7 ,000 but less than 300 claim 7 ,000 in an amount of 0.5% by mass or more but less than 5% by mass.9. The polyolefin microporous membrane according to claim 7 , having a normalized PP/PE ratio whose average is 0.5 or more claim 7 , whose standard deviation is 0.2 or less claim 7 , and whose kurtosis is 1.0 or less claim 7 , as measured by Raman spectroscopy in at least one plane perpendicular to the thickness direction.10. The polyolefin microporous membrane according to claim 7 , wherein weight average molecular weight of polypropylene is more than 50 claim 7 ,000 but less than 150 claim 7 ,000.11. The polyolefin microporous membrane according to claim 7 , containing an ultra-high molecular weight polyethylene having a mass average molecular weight of 1×10or more in an amount of 1 to 50% by weight based on 100% by mass of a total amount of the polyolefin resin.12. A method of producing the polyolefin microporous membrane according to claim 7 , comprising:{'sup': '6', '(a) melt blending a ...

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12-01-2017 дата публикации

CLOSED-CELL FOAM WATERSTOP SHEET WITH ADHESION LAYER

Номер: US20170008259A1
Принадлежит: Sekisui Chemical Co., Ltd.

A closed-cell foam water-stop sheet with an adhesion layer, wherein the closed-cell foam water-stop sheet comprises: 1. A closed-cell foam water-stop sheet with an adhesion layer , wherein the closed-cell foam water-stop sheet comprises:the adhesion layer that comprises a rubber component (A) having a total content of 80% by mass or more of a butyl rubber (a1) and an ethylene-propylene-diene rubber (a2), and a petroleum resin-based tackifier (B), the adhesion layer having a thickness of 0.01 to 2.0 mm; anda closed-cell foam sheet having a closed cell ratio of 70% or more, the closed-cell foam sheet being integrally attached to the adhesion layer, andwherein a mass ratio of the ethylene-propylene-diene rubber (a2) to the butyl rubber (a1) [(a2)/(a1)] is 0/100 to 93/7,a content of the petroleum resin-based tackifier (B) is 0.5 to 20 parts by mass based on 100 parts by mass of the rubber component (A), andthe closed-cell foam water-stop sheet with an adhesion layer has a 25% compression stress of 10 to 800 kPa.2. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the closed-cell foam sheet is an olefin-based resin foam.3. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the closed-cell foam sheet has an apparent density of 15 to 700 kg/m.4. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the Mooney viscosity ML (1+8) of the butyl rubber (a1) at 125° C. is 20 to 60.5. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the closed-cell foam sheet has a thickness of 0.05 to 15 mm.6. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the adhesion layer has a thickness of 0.03 to 1.0 mm.7. The closed-cell foam water-stop sheet with an adhesion layer according to claim 1 , wherein the mass ratio [(a2)/(a1)] is 1/99 to 90/10.8. The closed-cell foam water-stop sheet with ...

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14-01-2016 дата публикации

Rotomoulded articles

Номер: US20160009058A1
Автор: Eric Maziers
Принадлежит: Total Research and Technology Feluy SA

A rotomoulded article having one or more layers includes a layer A. The layer A includes from 50 to 99.4 wt % of a polyolefin; from 0.5 to 50 wt % of a polyester; from 0.1 to 20 wt % of a co- or ter-polymer; and from 0.1 to 20 wt % of an ionomer.

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12-01-2017 дата публикации

POLYOLEFIN RESIN FOAM PARTICLES, FOAM-PARTICLE MOULDED BODY, AND COMPOSITE STACKED BODY INCLUDING SAID MOULDED BODY

Номер: US20170009038A1
Принадлежит: JSP CORPORATION

The present invention relates to polyolefin resin expanded beads containing multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer, the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin, and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10, and a composite laminated body using an expanded beads molded body thereof, and the expanded beads molded body is excellent in solvent resistance and also excellent in adhesiveness to a thermosetting resin on the surface of the molded body, and can provide a composite laminated body excellent in productivity with a thermosetting resin. 1. Polyolefin resin expanded beads comprising multi-layer expanded beads containing a core layer in a foamed state containing a polyolefin resin and a cover layer coated on the core layer , the cover layer containing a mixed resin of a polyolefin resin (A) and at least one resin (B) selected from a polystyrene resin and a polyester resin , and the mixed resin having a weight ratio (A/B) of the polyolefin resin (A) and the resin (B) of from 15/85 to 90/10.2. The polyolefin resin expanded beads according to claim 1 , wherein a melting point (Ts) of the polyolefin resin (A) contained in the cover layer is lower than a melting point (Tc) of the polyolefin resin contained in the core layer.3. The polyolefin resin expanded beads according to claim 1 , wherein the mixed resin contained in the cover layer further contains a compatibilizing agent of the polyolefin resin (A) and the resin (B) claim 1 , and a content of the compatibilizing agent is from 1 to 20 parts by weight per 100 parts by weight of the total amount of the polyolefin resin (A) and the resin (B).4. The polyolefin resin expanded beads according to claim 1 , wherein the polyolefin resin contained in ...

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12-01-2017 дата публикации

Shape Memory Products and Method For Making Them

Номер: US20170009040A1
Автор: Kurup Sreeni
Принадлежит: TYCO ELECTRONICS UK LTD.

A method for producing a heat-shrinkable product is provided. First, a polymer composition containing a polymer, a crosslinking agent and a micro-encapsulated foaming agent uniformly dispensed therein is melt mixed. The foaming agent has a peak activation temperature which is higher than a temperature of the melt mixing. Next, the polymer composition is injection molded into a molded product. This carried out at the peak activation temperature to activate the foaming agent. Then, the molded product is crosslinked within the mold. 1. A method for producing a shape memory product comprising the steps of:(i) melt mixing a polymer composition containing a polymer, a crosslinking agent and a micro-encapsulated foaming agent uniformly dispensed therein, the micro-encapsulated foaming agent having a peak activation temperature which is higher than a temperature of the melt mixing,(ii) injection molding the polymer composition into a molded product, the injection molding carried out at the peak activation temperature to activate the micro-encapsulated foaming agent; and(iii) crosslinking the molded product within a mold.2. The method according to claim 1 , wherein the micro-encapsulated foaming agent is a blowing agent.3. The method according to claim 2 , wherein the polymer composition includes a polyolefin.4. The method according to claim 3 , wherein the polymer composition further includes polyethylene.5. The method according to claim 4 , wherein the polymer composition further includes ethylene-vinyl acetate copolymer (EVA).6. The method according to claim 1 , wherein the polymer composition includes 40 to 60% by weight of polyethylene and 10 to 20% by weight of EVA.7. The method according to claim 1 , wherein injection molding is carried out at a temperature in a range of 120 to 160° C.8. The method according to claim 7 , wherein the mold is heated to a temperature in a range of 170 to 210° C.9. The method according to claim 8 , wherein the injection molding is carried ...

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08-01-2015 дата публикации

Heat Activated Shrink Films

Номер: US20150010741A1
Принадлежит: Avery Dennison Corp

Shrinkable film layers having a blend of (i) one or more polymers with a high glass transition temperature, and (ii) one or more polymers with a low glass transition temperature are disclosed. Methods for preparing such film layers are also disclosed.

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08-01-2015 дата публикации

POLYPROPYLENE-BASED RESIN COMPOSITION AND FOAM SHEET

Номер: US20150010747A1
Принадлежит: Japan Polypropylene Corporation

Provided is a polypropylene-based resin composition which gives uniform and fine cells and from which a foamed sheet and thermoform excellent in appearance, thermoformability, impact resistance, lightness, stiffness, heat resistance, heat insulating properties, oil resistance and the like can be produced. A polypropylene-based resin composition comprising (X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which block copolymer comprises (Y-1) a propylene (co)polymer and (Y-2) a propylene-ethylene copolymer, said resin (X) having properties (X-i) to (X-iv) and said block copolymer (Y) having properties (Y-i) to (Y-v), and the like. 1. A polypropylene-based resin composition comprising:(X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y-1) a propylene (co)polymer, and', '(Y-2) a propylene-ethylene copolymer,, '(Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which comprises (X-i): MFR of 0.1 to 30.0 g/10 minutes,', '(X-ii): a molecular weight distribution Mw/Mn of 3.0 to 10.0 measured by GPC and Mz/Mw of 2.5 to 10.0,', [{'br': None, 'log(MT)≧−0.9×log(MFR)+0.7, or'}, {'br': None, 'MT≧15,'}], '(X-iii): a melt tension (MT) (unit: g) satisfying the relationship, '(X-iv): a content of p-xylene soluble components (CXS) at 25° C. of less than 5% by weight based on a total amount of the resin (X), and, 'wherein the resin (X) has the following properties (X-i) to (X-iv) (Y-i): ratios of the amounts of the (Y-1) and (Y-2) of 50 to 99% by weight and 1 to 50% by weight, respectively, with the proviso that each ratio is calculated based on a total of 100% by weight of the block copolymer (Y),', '(Y-ii): MFR of the block copolymer (Y) of 0.1 to 200.0 g/10 minutes,', '(Y-iii): melting point of the block copolymer (Y) of more than 155° C.,', '(Y ...

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10-01-2019 дата публикации

PLASTIC FILM AND PLASTIC FILM HAVING THE PLASTIC FILM LAYER

Номер: US20190009510A1
Автор: Ren Xuefen
Принадлежит:

A plastic film layer includes polyolefin elastomers. The polyolefin elastomers have better fluidity and can improve the dispersion effect of polypropylene base raw materials. The polypropylene base raw materials are mixed evenly, and enhance the bonding strength between plastic film layers. The plastic film layer also includes a polyaniline resin. A plastic film having the plastic film layer is also provided. The plastic film layer and the plastic film applying the plastic film layer have strong tensile force and are not easily damaged. 1. A plastic film layer comprising:a polypropylene base raw material;a polyolefin elastomer; anda polyphthalamide resin.2. The plastic film layer of claim 1 , wherein a weight percentage range of the polypropylene base material is substantially 86-98 percent claim 1 , a weight percentage range of the polyolefin elastomer is substantially 2-14 percent claim 1 , and a weight percentage range of the polyphthalamide resin is substantially 0.1-1.0 percent.3. The plastic film layer of claim 2 , wherein a weight percentage of the polypropylene base material is substantially 92 percent claim 2 , a weight percentage of the polyolefin elastomer is substantially 7.5 percent claim 2 , and a weight percentage of the polyphthalamide resin is substantially 0.5 percent.4. The plastic film layer of claim 2 , wherein the polypropylene base raw material comprises a first polypropylene raw material and a second polypropylene raw material.5. The plastic film layer of claim 4 , wherein the first polypropylene raw material is an injection molding grade homopolymer polypropylene claim 4 , and the second polypropylene raw material is a blown film grade homopolymer polypropylene.6. The plastic film layer of claim 4 , wherein a weight of the second polypropylene material is substantially 1-4 times that of the first polypropylene material.7. The plastic film layer of claim 6 , wherein the weight of the second polypropylene material is three times that of the ...

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11-01-2018 дата публикации

PROCESSING AID AND BLEND EMPLOYING THE PROCESSING AID FOR ACHIEVING EFFECTIVE ORIENTATION OF AN EXTRUDED FILM LAYER AND A BIAXIALLY ORIENTED FILM INCLUDING SUCH FILM LAYER

Номер: US20180009917A1
Принадлежит:

Processing aid for aiding in orienting an extruded film layer including a preponderance, by weight, of a high crystal-line polypropylene is a crystalline polypropylene wax. An oriented film layer including a blend of crystalline polypropylene wax and high crystallinity polypropylene homopolymer is part of the invention. The invention includes a method of forming an oriented film layer including a preponderance by weight of a high crystallinity polypropylene and includes the steps of blending a high crystallinity polypropylene with a crystalline polypropylene wax, directing the blend through an extruder to form a film layer and then orienting the film layer. The invention includes a biaxially oriented, multi-layer film including a base layer and at least one skin layer. The base layer includes a blend of crystalline metallocene catalyzed polypropylene wax and a high crystallinity polypropylene. 1. A processing aid for aiding in orienting an extruded film layer including a preponderance , by weight , of high crystalline polypropylene , said processing aid being a crystalline polypropylene wax.2. The processing aid of claim 1 , said crystalline polypropylene wax being a crystalline claim 1 , metallocene catalyzed wax.3. A processing aid for aiding in orienting a multilayer film including a core layer claim 1 , optionally one or more intermediate layers claim 1 , and at least one skin layer claim 1 , said processing aid including a crystalline polypropylene wax in said core layer and/or one or more of the optional intermediate layers.4. The processing aid of claim 3 , wherein said multilayer film includes only said core layer and at least one skin layer claim 3 , said processing aid being a crystalline polypropylene wax located only is said core layer.5. The processing aid of claim 3 , said crystalline polypropylene wax being a crystalline claim 3 , metallocene catalyzed wax.6. An oriented film layer including a blend of a crystalline polypropylene wax and a high ...

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11-01-2018 дата публикации

CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION

Номер: US20180009958A1
Принадлежит: Dow Global Technologies LLC

The instant invention provides procatalysts and catalyst systems for olefin polymerization, olefin based polymers polymerized therewith, and process for producing the same. In one embodiment, the instant invention provides a procatalyst comprising a metal-ligand complex of formula (I): 2. The procatalyst according to wherein Z is O.3. A catalyst system comprising the reaction product of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'one or more procatalysts of ; and'}one or more cocatalysts; wherein the ratio of total number of moles of the one or more metal-ligand complexes of formula (I) to total number of moles of the one or more cocatalysts is from 1:10,000 to 100:1.4. A polymerization process comprising the steps of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'polymerizing one or more α-olefins in the presence of one or more catalyst systems of under olefin polymerizing conditions; and thereby forming an olefin based polymer.'}5. An olefin based polymer comprising the polymerization reaction product of:{'claim-ref': {'@idref': 'CLM-00003', 'claim 3'}, 'one or more α-olefins in the presence of one or more catalyst systems of under olefin polymerizing conditions.'} The present application is a continuation of U.S. patent application Ser. No. 14/437,543, filed on Apr. 22, 2015, which is a national stage entry of PCT/US2013/073976, filed on Dec. 10, 2013, which claims the benefit of U.S. Provisional Application No. 61/746,151, filed on Dec. 27, 2012.The instant invention relates to procatalysts and catalyst systems for olefin polymerization, olefin based polymers polymerized therewith, articles made from such polymers, and process for producing the same.Olefin based polymers such as polyethylene and/or polypropylene are produced via various catalyst systems. Selection of such catalyst system used in the polymerisation process of the olefin based polymers is an important factor contributing to the characteristics and properties of such olefin based ...

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27-01-2022 дата публикации

FOAM FOR OPTICAL FIBER CABLE, COMPOSITION, AND METHOD OF MANUFACTURING

Номер: US20220026651A1
Принадлежит:

Embodiments of the disclosure relate to an optical fiber cable having at least one optical fiber, a cable jacket, and a foam layer. The cable jacket has an inner surface and an outer surface. The outer surface is an outermost surface of the optical fiber cable, and the inner surface is disposed around the at least one optical fiber. The foam layer is disposed between the at least one optical fiber and the cable jacket. The foam layer includes a polymer component having from 30% to 100% by weight of a polyolefin elastomer (POE) or thermoplastic elastomer (TPE) and from 0% to 70% by weight of low density polyethylene (LDPE). The foam layer has a closed-cell morphology having pores with an average effective circle diameter of 10 μm to 500 μm. Further, the expansion ratio of the foam layer is at least 50%. 1. An optical fiber cable comprising:at least one optical fiber;a cable jacket having an inner surface and an outer surface, wherein the outer surface is an outermost surface of the optical fiber cable and wherein the inner surface disposed around the at least one optical fiber;a foam layer disposed between the at least one optical fiber and the cable jacket;wherein the foam layer comprises a polymer component comprising from 30% to 100% by weight of a polyolefin elastomer (POE) or thermoplastic elastomer (TPE) and from 0% to 70% by weight of low density polyethylene (LDPE);wherein the foam layer comprises a closed-cell morphology having pores with an average effective circle diameter of 10 μm to 500 μm; andwherein the expansion ratio of the foam layer is at least 50%.2. The optical fiber cable of claim 1 , the optical fiber cable comprises no more than 432 optical fibers and wherein the modulus is no more than 1 MPa when measured at 50% strain under compression test.3. The optical fiber cable of claim 1 , wherein the optical fiber cable comprises more than 432 optical fibers and wherein the modulus is no more than 0.8 MPa when measured at 50% strain under compression ...

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08-01-2015 дата публикации

SYSTEM AND METHODS FOR SLURRY HYDROCONVERSION PITCH DISPOSITION AS SOLID PELLETS AND COMPOSITION OF THE SAME

Номер: US20150011686A1

A system and method for producing solid pellets from a slurry HDC pitch is disclosed which utilizes a polymer additive that is mixed with the pitch to increase the softening point of the solid pellets. 1. A method of producing solid pellets from a hydroconversion pitch produced from a hydroconversion process , the method comprising:providing a stream hydroconversion pitch;providing a stream of polymer additive;mixing the stream of hydroconversion pitch with the stream of polymer additive to produce a mixture of hydroconversion pitch and polymer additive; andpelletizing the mixture of hydroconversion pitch and polymer additive to produce pellets having a softening point of at least 65° C. (150° F.).2. The method according to claim 1 , wherein the hydroconversion pitch is slurry hydroconversion pitch claim 1 , wherein the hydroconversion process is a slurry hydroconversion process.3. The method according to claim 1 , wherein the mixture of hydroconversion pitch and polymer additive contains less than 10 wt % of polymer additive.4. The method according to claim 1 , wherein the stream of polymer additive is a molten stream of polymer additive.5. The method according to claim 1 , wherein the polymer additive is one of polyethylenes claim 1 , polypropylenes and polycarbonates and mixtures thereof.6. The method according to claim 5 , wherein the polymer additive is a low density polyethylene (LDPE) claim 5 , a high density polyethylene (HDPE) claim 5 , or a combination thereof.7. The method according to claim 1 , further comprising:providing a stream of air; andpassing the stream of hydroconversion pitch through the stream of air prior to mixing with the stream of the polymer additive.8. The method according to claim 1 , wherein the pellets having a softening point of at least 93° C. (200° F.).9. A system for producing solid pellets from a hydroconversion pitch produced from a hydroconversion process claim 1 , the system comprising:a source of hydroconversion pitch;a ...

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08-01-2015 дата публикации

METHOD FOR PROCESSING POLYETHYLENE

Номер: US20150011696A1
Принадлежит:

A method can include consecutively batch processing at least two different polyethylene grades in pellet form in a pellet handling unit. A ratio of a melt flow index (MI) of a first polyethylene in pellet form (MI) to a MI of a later processed polyethylene in pellet form (MI) can be smaller than 0.30. The method can include processing an intermediate polyethylene grade in pellet form. An amount of intermediate polyethylene grade processed can be at most 1/100of a handling capacity of the pellet handling unit. The intermediate polyethylene grade can have the same MI as the later processed polyethylene in pellet form. 17-. (canceled)8. A method of processing different polyethylene grades comprising: a first polyethylene in pellet form in a pellet handling unit;', 'an intermediate polyethylene grade in pellet form in the pellet handling unit; and', 'a later processed polyethylene in pellet form in the pellet handling unit;, 'consecutively batch processing{'sub': f', 'l, 'wherein a ratio of a melt flow index (MI) of the first polyethylene in pellet form (MI) to a MI of the later processed polyethylene in pellet form (MI) is smaller than 0.30; and'}wherein the intermediate polyethylene grade has the same MI as the later processed polyethylene in pellet form.9. The method according to claim 8 , wherein the consecutively batch processed polyethylene pellets are obtained from polyethylene resins produced in the presence of a metallocene catalyst.10. The method according to claim 8 , wherein the pellet handling unit comprises one or more transfer lines claim 8 , one or more homogenization silos claim 8 , one or more storage silos claim 8 , or combinations thereof.11. The method according to claim 8 , wherein at least one of the first polyethylene and the later process polyethylene has a monomodal molecular weight distribution.12. The method according to claim 8 , wherein the first polyethylene and the later process polyethylene have monomodal molecular weight distributions. ...

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08-01-2015 дата публикации

Ethylene-Based Interpolymers and Processes to Make the Same

Номер: US20150011708A1
Принадлежит:

Ethylene-based interpolymers, e.g., ethylene-acrylic acid copolymers, are made by a process comprising the steps of: 115-. (canceled)16. An ethylene-based interpolymer comprising at least one comonomer that comprises at least one ethylenic unsaturation and at least one carbonyl group , and wherein the interpolymer comprises at least one the following properties:{'sup': '2', 'A. An average small gel count per 50,000 square inches (in) of less than or equal to 600; and'}{'sup': '2', 'B. An average micro gel count per 50,000 inof less than or equal to 3,500.'}17. The ethylene-based interpolymer of having a percent by weight of acid comonomer units in the polymer chain from 2 to 30.18. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 16 , Mw/Mn) from 3 to 20.19. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 17 , Mw/Mn) from 3 to 20.20. The ethylene-based interpolymer of wherein the ethylenic unsaturation of the comonomer is conjugated with the carbonyl group.21. The ethylene-based interpolymer of wherein the comonomer is at least one of an ethylenically unsaturated carboxylic acid claim 16 , anhydride claim 16 , or ester or its salt.22. The ethylene-based interpolymer of wherein the comonomer is acrylic acid or methacrylic acid.23. The ethylene-based interpolymer of wherein the average small gel count per 50 claim 16 ,000 square inches (in) of less than or equal to 300.24. The ethylene-based interpolymer of wherein the average micro gel count per 50 claim 16 ,000 inof less than or equal to 1 claim 16 ,500.25. The ethylene-based interpolymer of wherein the percent by weight of acid comonomer units in the interpolymer chain is from 4 to 15.26. The ethylene-based interpolymer of wherein the molecular weight distribution (MWD claim 16 , Mw/Mn) from 5 to 12.27. The ethylene-based interpolymer of comprising greater than claim 16 , or equal to claim 16 , 1 weight percent of the comonomer based on the ...

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14-01-2021 дата публикации

METHOD FOR MANUFACTURING MOLDED ARTICLE AND PREFORM OF MOLDED ARTICLE

Номер: US20210009783A1
Принадлежит: Toray Industries, Inc.

Provided is a method for producing a molded article having a thin film layer (B) formed on a surface of a porous body (A). The method includes a process (I) and a process (II) described below in this order: 1. A method for producing a molded article having a thin film layer (B) formed on a surface of a porous body (A) , the method comprising a process (I) and a process (II) described below in this order:process (I): forming the thin film layer (B) on a surface of a precursor (a) of the porous body (A) to obtain a preform, andprocess (II): expanding and molding the precursor (a) to the porous body (A).2. The method for producing a molded article according to claim 1 , wherein in the preform obtained at the process (I) claim 1 , an adhesion property of the thin film layer (B) to the precursor (a) belongs to classes 0 to 3 in accordance with ES K5600-5-6 (1999).3. The method for producing a molded article according to claim 1 , wherein the thin film layer (B) is at least one of a primer layer claim 1 , a coating film layer claim 1 , and a waterproof layer.4. The method for producing a molded article according to claim 1 , wherein at the process (I) claim 1 , the thin film layer (B) is formed on the surface of the precursor (a) by wet coating.512. The method for producing a molded article according to claim 1 , wherein the thin film layer (B) comprises an additive (B) and a thermosetting resin (B).613. The method for producing a molded article according to claim 1 , wherein the thin film layer (B) comprises an additive (B) and a thermoplastic resin (B).71. The method for producing a molded article according to claim 5 , wherein a maximum size of the additive (B) is 200 μm or less.8. The method for producing a molded article according to claim 1 , wherein a thickness of the thin film layer (B) is in a range of 10 to 500 μm.91. The method for producing a molded article according to claim 1 , wherein a surface roughness Ra of the thin film layer (B) formed at the process ( ...

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10-01-2019 дата публикации

Low Noise Polymer Composition

Номер: US20190010299A1
Принадлежит:

A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer, reinforcing fibers, and at least one tribological modifier. The tribological modifier, in one embodiment, can comprise a graft copolymer. The use of a graft copolymer has been found to unexpectedly and dramatically improve noise generation when tested against various substrates, especially glass substrates. 1. A polymer composition comprising:a polyoxymethylene polymer;reinforcing fibers present in the polymer composition in an amount from about 5% to about 55% by weight; anda tribological modifier comprising a graft copolymer of a polyolefin or polycarbonate and a branch polymer, the tribological modifier being present in the composition in an amount of 2% by weight or greater.2. A polymer composition as defined in claim 1 , wherein the graft copolymer is a copolymer of a polyolefin claim 1 , the polyolefin comprising polyethylene or polypropylene.3. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a styrenic polymer.4. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises an acrylonitrile polymer.5. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a styrene acrylonitrile polymer.6. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a vinyl polymer or an ether polymer.7. A polymer composition as defined in claim 1 , wherein the tribological modifier is present in the composition in an amount from about 3% to about 7% by weight.8. A polymer composition as defined in claim 1 , wherein the graft copolymer is the only tribological modifier present in the polymer composition.9. A polymer composition as defined in claim 1 , wherein the polymer composition further contains ultra-high molecular ...

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10-01-2019 дата публикации

INTEGRATED PROCESS FOR TREATING RECYCLED PET AND PTT MATERIALS

Номер: US20190010303A1
Принадлежит:

A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C-Cfatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof. 129.-. (canceled)30. A process comprising:(a) reacting a recycle stream comprising recycled carpet selected from PTT carpet, PET carpet or mixtures thereof, with a glycol in a reactor, thereby forming a completely digested product stream comprising polyols, and at least one undigested stream;(b) separating the completely digested product stream from the undigested stream, thereby forming a separated digested product stream and a separated undigested product stream; and{'sub': 6', '36', '6', '36', '9', '18', '6', '36, '(b) reacting the separated digested product stream in the reactor with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids, cardanol- ...

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09-01-2020 дата публикации

Oriented polyethylene films and a method for making the same

Номер: US20200010631A1
Принадлежит: Dow Global Technologies LLC

A first oriented film comprising a first polyethylene composition which comprises: from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an I 2 lower than 2 g/10 min; and from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than or equal to 0.925 g/cc and an I 2 greater than or equal to 2 g/10 min; wherein the first polyethylene composition has an 12 from 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc is provided.

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09-01-2020 дата публикации

A PROCESS FOR PRODUCING POLYOLEFIN FILM COMPOSITION AND FILMS PREPARED THEREOF

Номер: US20200010655A1
Принадлежит:

The present invention deals with a process for producing a multimodal ethylene polymer composition suitable for producing films by blow moulding. The process comprises (i) copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta polymerisation catalyst to produce a first ethylene homo- or copolymer (PE1) having a density of from 940 to 980 kg/mand a melt flow rate MFRof from 400 to 1000 g/10 min; (ii) copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene copolymer to produce a first ethylene polymer mixture (PEM1) comprising the first ethylene copolymer and a second ethylene copolymer, said first ethylene polymer mixture having a density of from 940 to 980 kg/mand a melt flow rate MFR2 of from 150 to 800 g/10 min, and wherein the MFRof the first ethylene copolymer (PEI) is higher than first ethylene polymer mixture (PEM1) and (iii) copolymerising ethylene and an alpha-olefin comonomer in a third polymerisation step in the presence of the first ethylene polymer mixture to produce a second ethylene polymer mixture (PEM2) comprising the first ethylene polymer mixture and a third ethylene copolymer, said second ethylene polymer mixture having a density of from 915 to 925 kg/mand a melt flow rate MFRof from 0.3 to 5 g/10 min. 1. A process for producing multimodal ethylene polymer film compositions comprising the steps of{'sup': '3', 'sub': '2', '(i) copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta polymerisation catalyst to produce a first ethylene copolymer (PE1) having a density of from 940 to 980 kg/mand a melt flow rate MFRof from 400 to 1000 g/10 min;'}{'sup': '3', 'sub': 2', '2, '(ii) copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene copolymer to produce a ...

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09-01-2020 дата публикации

Flame-Retardant, Moisture-Cured Wire and Cable Constructions with Improved Glancing Impact Performance

Номер: US20200010682A1
Принадлежит: Dow Global Technologies LLC

Articles made from a moisture-curable, polymeric composition comprising in weight percent based on the weight of the composition: (A) 2 to less than 80 weight percent (wt %) of an ethylenic polymer with (1) a crystallinity at room temperature of 34% to 55%, or 65% to 80%, and (2) a melt index (I 2 ) of 0.1 to 50 decigrams per minute (dg/min); (B) 3 to 30 wt % of a halogenated flame retardant; (C) 3 to 30 wt % an inorganic antimony flame retardant; and (D) 0 to 10 wt % of at least one of an inorganic flame retardant other than the inorganic antimony flame retardant, e.g., zinc oxide exhibit enhanced ACBD properties in comparison to articles alike in all respects except made from a composition comprising an ethylenic polymer without the requisite crystallinity at room temperature.

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09-01-2020 дата публикации

METHOD FOR FORMING MULTILAYER COATING FILM

Номер: US20200010698A1
Принадлежит:

A method for forming a multilayer coating film is provided. The method includes coating at least one object with an aqueous primer coating composition, an aqueous first colored coating composition, an aqueous second colored coating composition, and a clear coating composition, in that order. The aqueous primer coating composition contains a component (A) which contains a polyolefin resin, a component (B) which contains a polyurethane resin, a curing agent (C) and electrically conductive carbon (D). The aqueous first colored coating composition and aqueous second colored coating composition each contain a core/shell emulsion. The clear coating composition contains a hydroxyl group-containing acrylic resin, a polyisocyanate and a melamine resin. The method improves the appearance, chipping resistance, adhesive properties and low temperature impact properties of a coating film. 2. The method for forming a multilayer coating film as claimed in claim 1 , wherein the plastic base material contains at least one type of resin material selected from the group consisting of PP resins claim 1 , ABS resins claim 1 , PC resins and ABS/PC resins.3. The method for forming a multilayer coating film as claimed in claim 1 , which is characterized in that a proportion in terms of parts by mass of component (A) and component (B) in the aqueous primer coating composition is 20/80 to 80/20 in terms of resin solid content claim 1 , a proportion in terms of parts by mass of component (C) and {component (A)+component (B)} is 1/100 to 30/100 in terms of solid content claim 1 , and furthermore a proportion in terms of parts by mass of component (D) and {component (A)+component (B)+component (C)} is 2/98 to 20/80 in terms of solid content.4. The method for forming a multilayer coating film as claimed in claim 1 , which is characterized in that component (B) in the aqueous primer coating composition is a colloidal dispersion type or emulsion type aqueous polyurethane resin.5. The method for ...

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03-02-2022 дата публикации

PROPYLENE TERPOLYMER

Номер: US20220033596A1
Принадлежит: BASELL POLIOLEFINE ITALIA S.R.L.

A terpolymer compositions made from or containing: 1. A terpolymer composition comprising: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %, based upon the total weight of the first terpolymer;', 'ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt % based upon the total weight of the first terpolymer;', 'iii) the xylene soluble fraction at 25° C. ranging from 7.2 wt % to 13.4 wt %, based upon the total weight of the first terpolymer;', 'iv) the melting point determined by differential scanning calorimetry (DSC), according to ISO 11357-3, with a heating rate of 20° C./minute ranging from 123° C. to 138° C.;', {'sup': '13', 'v) the CNMR sequences EEE ranging from 0.16 mol % to 0.40 mol %; and'}, 'vi) the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 1.0 g/10 min to 20.0 g/10 min; and, 'A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %, based upon the total weight of the second terpolymer;', 'ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt % based upon the total weight of the second terpolymer; and', 'iii) the xylene soluble fraction at 25° C. ranging from 38.2 wt % to 60.2 wt % based upon the total weight of the second terpolymer;, 'B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer havingwherein the content of 1-butene derived units of component A) is lower than the amount of the content of 1-butene derived units of component B); andthe terpolymer composition having -the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min;the sum of the amounts of A) and B) being 100 wt %.2. The terpolymer composition according to comprising from 83 wt % to 95 wt % of component A) and from 17 wt % to 5 wt % of component B).3. The ...

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03-02-2022 дата публикации

PUMPABLE, THERMALLY CURABLE AND EXPANDABLE PREPARATIONS

Номер: US20220033604A1
Принадлежит:

A thermally expandable preparation pumpable at application temperatures in the range of 50 to 120° C., is provided containing: at least one polymer selected from binary copolymers containing at least one monomer unit selected from vinyl acetate, (meth)acrylic acids, styrene and derivatives thereof, and terpolymers based on at least one first monomer selected from the monounsaturated or polyunsaturated hydrocarbons, and at least one second monomer selected from (meth)acrylic acids and derivatives thereof, and at least one third monomer selected from epoxy-functionalized (meth)acrylates, as well as combinations of the first two; at least one liquid polymer selected from liquid hydrocarbon resins, liquid polyolefins and liquid polymers based on one or more diene monomers; at least one peroxide; at least one thermally activatable blowing agent; and at least one adhesion promoter; as well as methods to stiffen/reinforce or seal structural components by application of the preparation. 1. A thermally expandable preparation which can be pumped at application temperatures in a range of 50° C. to 120° C. , and contains , in each case based on a total weight of the preparation: (a1) binary copolymers containing at least one monomer unit selected from vinyl acetate, (meth)acrylic acids, styrene and derivatives thereof, and', '(a2) terpolymers based on at least one first monomer selected from monounsaturated or polyunsaturated hydrocarbons, and at least one second monomer selected from (meth)acrylic acids and derivatives thereof, and at least one third monomer selected from epoxy-functionalized meth(acrylates); and combinations of (a1) and (a2);, '(a) 3 to 40 wt. % of at least one polymer, optionally comprising a peroxidically crosslinkable polymer, the at least one polymer being selected from (b1) liquid hydrocarbon resins;', '(b2) liquid polyolefins; and', '(b3) liquid polymers based on one or more diene monomers;, '(b) 1 to 40 wt. % of at least one liquid polymer selected ...

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03-02-2022 дата публикации

EXPANDABLE, SHELF STABLE POLYMER BEAD

Номер: US20220033608A1
Принадлежит:

The invention relates to an expandable bead comprising a) a polyolefin selected from polyethylene (PE), polypropylene (PP) and mixtures thereof and b) thermoplastic microspheres encapsulating a blowing agent. 1. An expandable bead comprisinga) a polyolefin selected from polyethylene (PE), polypropylene (PP) and mixtures thereof andb) thermoplastic microspheres encapsulating a blowing agent,wherein an aspect ratio, defined as quotient of a largest diameter D1 of the bead to a smallest diameter D2 of the bead, is in the range from ≥1.0 to ≤1.40, wherein the smallest diameter D2 of the bead is in the range from ≥0.5 to ≤2.5 mm.2. The expandable bead of wherein the expandable bead comprises the polyolefin in the range from ≥70% by weight to ≤98% by weight claim 1 ,wherein the total amount of the polyolefin and the thermoplastic microspheres is 100% by weight.3. The expandable bead of comprising a polypropylene having a melt flow index (MFI) of from ≥5 to ≤60 g/10 min claim 1 , as measured according to ISO 1133 at 230° C. and a load of 2.16 kg.4. The expandable bead of wherein the polypropylene is selected from homopolymer PP and random PP copolymer.5. The expandable bead of wherein the polyethylene is linear low density polyethylene (LLDPE) claim 1 , having a MFI in the range from ≥5 to ≤70 g/10 min as measured according to ISO 1133 at 190° C. and 2.16 kg and/orhaving a density in the range from ≥910 to ≤940 kg/m3 as measured according to ISO 1183;and/orhigh density polyethylene (HDPE), having a MFI in the range from ≥5 to ≤70 g/10 min as measured according to ISO 1133 at 190° C. and a load of 2.16 kg and/orhaving a density in the range from ≥940 to ≤970 kg/m3 as measured according to ISO 1183.6. The expandable bead of wherein the diameter D2 is in the range from ≥0.8 to ≤2.0 mm claim 1 ,and/orhaving a bulk density in the range from ≥430 to ≤600 kg/m3 and/orhaving a shelf-stability of at least 6 month.7. The expandable bead of havinga bulk density after its expansion in ...

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03-02-2022 дата публикации

GREASE-RESISTANT FILM, GREASE-RESISTANT BASE MATERIAL, AND GREASE-RESISTANT PAPER

Номер: US20220033637A1
Принадлежит: KURARAY CO., LTD.

An oil-resistant film may be provided by an oil-resistant base material that is excellent in the oil resistance even in not only a plane part but also a bent part of a package can be obtained and also to the provision of an oil-resistant base material having the oil-resistant film and an oil-resistant paper having the oil-resistant film. An oil-resistant film may contain a polyvinyl alcohol-based polymer (A) and a polymer particle (B) containing a polymer having a glass transition temperature of 40° C. or lower, wherein the content of the polymer particle (B) is 1 part by mass or more and less than 150 parts by mass based on 100 parts by mass of the polyvinyl alcohol-based polymer (A); and an oil-resistant base material (oil-resistant paper) having the oil-resistant film on a base material (paper). 1. An oil-resistant film comprising a polyvinyl alcohol-based polymer (A) and a polymer particle (B) containing a polymer having a glass transition temperature of 40° C. or lower , wherein the content of the polymer particle (B) is 1 part by mass or more and less than 150 parts by mass based on 100 parts by mass of the polyvinyl alcohol-based polymer (A).2. The oil-resistant film according to claim 1 , wherein a number average molecular weight of the polymer particle (B) is 5 claim 1 ,000 or more.3. The oil-resistant film of claim 1 , wherein an average particle diameter of the polymer particle (B) is 10 to 500 nm.4. The oil-resistant film of claim 1 , wherein the polymer particle (B) is a (meth)acrylic acid ester-based polymer particle.5. The oil-resistant film of claim 1 , wherein the polymer particle (B) is a (meth)acrylic acid ester-based homopolymer particle.6. The oil-resistant film of claim 1 , wherein the polymer particle (B) contains a dispersant containing an ionic group.7. The oil-resistant oil film according to claim 6 , wherein the ionic group is at least one selected from the group consisting of an anionic group and a salt of an anionic group.8. The oil- ...

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19-01-2017 дата публикации

PROTECTIVE TUBE FOR COIL SPRING AND METHOD FOR MANUFACTURING THE SAME

Номер: US20170015028A1
Автор: LEE Won Sik
Принадлежит:

A protective tube for a coil spring and a method for manufacturing the same are disclosed herein. The protective tube for a coil spring is manufactured by: mixing 40-70 parts by weight of a thermoplastic elastomer, 20-40 parts by weight of a thermoplastic resin, 0.2-5 parts by weight of an antioxidant, and 0.2-5 parts by weight of a crosslinking agent to obtain a mixture; pelletizing the mixture to obtain pellets; extrusion-molding the pellets into a tube; crosslinking the tube by radiation; enlarging the diameter of the crosslinked tube while forming the tube into a spiral shape by heating; and setting the enlarged-diameter tube by cooling. 1. A protective tube for a coil spring , which is manufactured by: mixing 40-70 parts by weight of a thermoplastic elastomer , 20-40 parts by weight of a thermoplastic resin , 0.2-5 parts by weight of an antioxidant , and 0.2-5 parts by weight of a crosslinking agent to obtain a mixture; pelletizing the mixture to obtain pellets; extrusion-molding the pellets into a tube; crosslinking the tube by radiation; enlarging a diameter of the crosslinked tube while forming the tube into a spiral shape by heating; and setting the enlarged-diameter tube by cooling.2. The protective tube of claim 1 , wherein the thermoplastic elastomer is one or more selected from the group consisting of a polyolefin-based thermoplastic elastomer (TPO) claim 1 , a polystyrene-based thermoplastic elastomer (TPS) claim 1 , a polyimide-based thermoplastic elastomer (TPA) claim 1 , a polyurethane-based thermoplastic elastomer (TPU) claim 1 , a polyester-based thermoplastic elastomer (TPC) claim 1 , and a thermoplastic vulcanizate (TPV).3. The protective tube of claim 1 , wherein the thermoplastic resin is one or more selected from the group consisting of polyvinyl chloride-based resin claim 1 , polyamide-based resin claim 1 , polyethylene-based resin claim 1 , polyester-based resin claim 1 , polycarbonate-based resin claim 1 , polystyrene-based resin claim 1 , ...

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18-01-2018 дата публикации

METHOD FOR ENCAPSULATING GLAZING IN POLYCARBONATE PROVIDED WITH AN ANTI-SCRATCH COATING

Номер: US20180015503A1
Автор: THIMONIER Sylvain
Принадлежит: SAINT-GOBAIN GLASS FRANCE

The present invention relates to a process for encapsulating a polycarbonate glazing comprising, on at least one of its faces, a silicone-based abrasion-resistant hardcoat, said process comprising the following successive steps: 1. A process for encapsulating a polycarbonate glazing comprising , on at least one of its faces , a silicone-based abrasion-resistant hardcoat , said process comprising:(a) treating a region of the face of the glazing bearing the silicone-based hardcoat by atmospheric plasma with a plasma nozzle having a power of between 100 voltamperes and 1000 voltamperes, wherein a distance between the end of the plasma nozzle and the surface of the glazing is at most equal to 7 mm, thereby obtaining a region treated by atmospheric plasma,(b) applying, to the region treated by atmospheric plasma, a primer composition comprising at least one adhesion promoter selected from the group consisting of diisocyanates, polyisocyanates, and chlorinated polyolefins, in solution or suspension in an organic or aqueous solvent,(c) evaporating the solvent, thereby forming a dry primer layer, and(d) overmolding a thermoplastic polymer over the region covered by the dry primer layer.2. The process as claimed in claim 1 , wherein the rate of relative movement of the plasma nozzle with respect to the glazing is between 2 and 4 m/minute.3. The process as claimed in claim 1 , wherein the distance between the end of the plasma nozzle and the surface of the glazing is less than 6 mm.4. The process as claimed in claim 1 , wherein the plasma nozzle operates with a carrier gas.5. The process as claimed in claim 1 , wherein the adhesion promoter is at least one selected from the group consisting of isophorone diisocyanate (IPDI) claim 1 , 4 claim 1 ,4′-diphenylmethane diisocyanate (MDI) and maleic anhydride-grafted chlorinated polyolefin.6. The process as claimed in claim 5 , wherein the primer composition essentially consists of the at least one adhesion promoter selected from ...

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19-01-2017 дата публикации

COMPRESSIBLE FIRE RETARDANT FOAM

Номер: US20170015803A1
Принадлежит: Armacell Enterprise GmbH & Co. KG

The present invention relates to a material for thermal and/or acoustic insulation which consists of at least 300 phr, preferably at least 400 phr, but less than 1200 phr, preferably less than 1000 phr, especially preferred less than 800 phr ingredients in total, comprising 100 phr of at least one polymer, of which at least 60 phr, preferably at least 70 phr, especially preferred at least 80 phr is chlorinated polyethylene (CPE), the process of manufacturing such material, wherein the polymeric material is expanded by decomposition of a chemical blowing agent. 1. An expanded polymeric material consisting of at least 300 phr , but less than 1200 phr ingredients in total , the material comprising:100 phr of at least one polymer, of which at least 60 phr is chlorinated polyethylene (CPE);wherein the chlorinated polyethylene (CPE) shows a chlorine content of at least 35 wt % according to ISO 1158; andat least 20 phr of at least one further chlorinated organic polymer.2. (canceled)3. (canceled)4. The material according to claim 1 , which is crosslinked by a crosslinking system.5. The material according to claim 4 , wherein the crosslinking system comprises thiadiazole and/or peroxides and/or sulphur crosslinking systems.6. The material according to claim 1 , further comprising at least one plasticiser that is present in the formulation in at least 50 phr.7. The material according to claim 6 , wherein at least one plasticizer is a chlorinated plasticizer selected from chlorinated paraffin and/or chlorinated fatty acid substituted glycerin and/or chlorinated alpha-olefin claim 6 , wherein the chlorinated plasticizer has a chlorine content of at least 20 wt % according to DIN 53474.8. The material according to claim 6 , wherein at least one plasticiser is a phosphate plasticizer.9. The material according to claim 1 , further comprising at least 100 phr of at least one inorganic filler.10. The material according to claim 9 , wherein the inorganic filler contains a metal.11. ...

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18-01-2018 дата публикации

PREPREGS, CORES AND COMPOSITE ARTICLES INCLUDING POWDER COATED LAYERS

Номер: US20180015688A1
Принадлежит:

Composite articles comprising a porous prepreg or core layer and a powder coated layer thereon are described. In some instances, a thermoplastic composite article comprises a porous core layer comprising a web of reinforcing fibers held together by a thermoplastic material, and a powder coated layer disposed on the porous core layer, in which a particle size of the powder coated layer is selected to provide an interface between the powder coated layer and the porous core layer, wherein at least 50% by weight of the disposed powder coated layer is present above the interface. 1. A thermoplastic composite article comprising:a porous core layer comprising a web of reinforcing fibers held together by a thermoplastic material; anda powder coated layer comprising a polymeric powder disposed on the porous core layer, in which an average particle size of the powder is selected to provide an interface between the powder coated layer and the porous core layer and where substantially all of the disposed powder of the powder coated layer is present above the interface.2. The thermoplastic composite article of claim 1 , in which the porosity of the core layer is greater than 10 by volume of the core layer.3. The thermoplastic composite article of claim 1 , in which the powder coated layer comprises a thermoplastic material claim 1 , in which the thermoplastic material of the porous core layer is the same or different than the thermoplastic material of the powder coated layer.4. The thermoplastic composite article of claim 3 , in which the thermoplastic material of the porous core layer is a polyolefin and the thermoplastic material of the powder coated layer is a non-polyolefin or a polyolefin.5. The thermoplastic composite article of claim 3 , in which the thermoplastic material of the porous core layer is selected from the group consisting of a polyethylene claim 3 , a polypropylene claim 3 , a polystyrene claim 3 , a polyimide claim 3 , a polyetherimide claim 3 , a polyamide ...

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21-01-2016 дата публикации

MULTILAYERED ARTICLE COMPRISING POLYPROPYLENE IMPACT COPOLYMERS, AND METHOD OF MAKING SAME

Номер: US20160016389A1
Принадлежит:

A polymer sheet includes a core layer containing a propylene impact copolymer (ICP), and a first additional layer comprising a first polymer composition. The propylene impact copolymer (ICP) in the core layer includes a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which includes greater than 50 wt. % of units derived from propylene monomer. The dispersed phase includes a copolymer of ethylene and a C-Cα-olefin. The ICP has a first melting point being greater than 100° C. (e.g., in the range of from 100° C. to 130° C.) and a second melting point. The polymer sheet can also include a second additional layer containing a second polymer composition. 1. A polymer sheet , comprising: (a) a matrix comprising a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which comprises greater than 50 wt. % of units derived from propylene monomer, and', {'sub': 3', '8, '(b) a dispersed copolymer which comprises ethylene and a C-Cα-olefin,'}, 'wherein the ICP has a first melting point between 100° C. and 130° C. and, 'a core layer comprising a propylene impact copolymer (ICP), the propylene ICP comprisinga second melting point; anda first additional layer comprising a first polymer composition.2. The polymer sheet of claim 1 , whereinthe first polymer composition in the first additional layer comprises at least one of a polypropylene homopolymer, a random copolymer of propylene comprising from 0.01 molar percent (mol. %) to 5 mol. % of ethylene, the propylene ICP and blends thereof.3. The polymer sheet of claim 1 , further comprising:a second additional layer comprising a second polymer composition,wherein the first additional layer and the second additional layer are in direct contact with the core layer.4. The polymer sheet of claim 3 , whereinthe second polymer composition in the second additional layer comprises at least one of a polypropylene homopolymer, a random copolymer of ...

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18-01-2018 дата публикации

HARD COAT FILM

Номер: US20180016405A1
Принадлежит: NIPPON PAPER INDUSTRIES CO. ,LTD.

The present invention provides a hard coat film that is provided with a hard coat layer via an easy-bonding layer on at least one surface of a cycloolefin film, has excellent temporal adhesiveness under normal condition and under moisture and heat resistant condition, and has no crack occurrence under the heat resistant condition. 1. A hard coat film provided with a hard coat layer via an easy-bonding layer on at least one surface of a cycloolefin film , whereinthe easy-bonding layer includes a mixture of a polyolefin based resin and a styrene-acryl based resin; and,the hard coat layer includes an ionizing radiation curable resin having an weight-average molecular weight of 700 or larger and 3600 or smaller.2. The hard coat film according to claim 1 , wherein a blending ratio (parts by weight) of the polyolefin based resin and the styrene-acryl based resin in the easy-bonding layer is in the range of from 95/5 to 40/60.3. The hard coat film according to claim 1 , wherein the ionizing radiation curable resin contains a polyfunctional acrylate having 3 or more (meth)acryloyloxy groups in one molecule.4. The hard coat film according to claim 1 , wherein the hard coat layer satisfies the following conditions:{'sup': '2', '(1) on a polyethylene terephthalate film, a film on which a hard coat layer made of the ionizing radiation curable resin cured by a UV-ray amount of from 50 to 1000 mJ/cmis formed such that a coated film has a thickness of 2 μm is formed, and'}(2) when a test piece having width 15 mm×length 150 mm is prepared from said film and said test piece is subjected to a tensile test at a tensile speed of 50 mm/minute under an environment of temperature of 23° C. and humidity of 50% RH, an elongation rate until a crack is generated on the coated film is 8% or larger and 45% or smaller.5. The hard coat film according to claim 1 , wherein a thickness of the easy-bonding layer is in the range of from 0.1 μm to 1.0 μm. The present invention relates to a hard coat ...

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18-01-2018 дата публикации

METHOD FOR TRENCHLESS RENOVATION OF A SEWER PIPE

Номер: US20180016434A1
Принадлежит:

A single or multilayered film is presented having at least one layer that contains at least one thermoplastic olefin homo or copolymer, modified if need be. The layer contains additionally, at least one polyester. Such film is used as a sliding film or preliner in trenchless pipe renovation using the tube lining technique in which the film is layed on the inner wall of an underground sewer pipe laid that will be renovated. An insertion pipe with a curable carrier material can be pulled in sliding fashion over the sliding film laid on the pipe. 1. Method for a trenchless renovation of a sewer pipe with a tube liner system , wherein said method comprises the step of:inserting a sliding or preliner film into a pipe laid underground, such that said sliding or preliner film is abutted to the inner wall of said pipe, wherein a first layer of the film comprises at least one modified or unmodified thermoplastic olefin homo- or co-polymer and at least one polyester, the thermoplastic olefin homo- or copolymer selected from a group consisting of (1) polyethylene, (2) polypropylene, (3) polybutylene, (4) polyisobutylene, and (5) a mixture of at least two of the polymers (1) through (4).2. The method according to claim 1 , wherein the first layer contains more than 50% by weight of thermoplastic olefin homo- or copolymer and 0.1 to 50% by weight of polyester.3. The method according to claim 1 , wherein the first layer contains more than 50% by weight of polyester and between 10% and 35% by weight of thermoplastic olefin homo- or copolymer.4. The method according to claim 1 , wherein the polyester is amorphous polyethylene terephthalate (A-PET).5. The method according to claim 4 , wherein the A-PET is contained in the first layer in more than 25% by weight claim 4 , or more than 40% by weight claim 4 , or more than 50% by weight claim 4 , or more than 65% by weight.6. The method according to claim 1 , wherein the first layer is an intermediate layer claim 1 , and wherein the ...

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15-01-2015 дата публикации

Ethylene polymer composition and shaped article of the same

Номер: US20150018491A1
Принадлежит: Mitsui Chemicals Inc, Prime Polymer Co Ltd

The present invention provides an ethylene polymer composition having a particularly high formability and having an excellent mechanical strength, a shaped article formed of such an ethylene polymer, and a film and multilayer film having a particularly excellent blocking resistance. An ethylene polymer composition (γ) according to the present invention includes a specific ethylene polymer (α) that is a copolymer of ethylene and an α-olefin having 4 to 10 carbon atoms and an ethylene polymer (β) that is a copolymer of ethylene and an α-olefin having 4 to 10 carbon atoms but different from the ethylene polymer (α), and weight fraction [Wα] of the ethylene polymer (α) is in the range of not less than 0.1 and not more than 0.9, and weight fraction [Wβ] of the ethylene polymer (β) is in the range of not less than 0.1 and not more than 0.9 (the sum of the Wα and the Wβ is 1.0).

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15-01-2015 дата публикации

Polypropylene composition with improved sealing and thermal properties

Номер: US20150018492A1
Принадлежит: Borealis AG

The present invention relates to a polypropylene composition comprising comonomer units derived from ethylene in an amount of from 0.5 wt % to 25 wt %, and from at least one C 5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of at least 20 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4 wt % to 50 wt %.

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17-01-2019 дата публикации

METHOD AND SYSTEMS FOR TRANSPORTING BITUMEN IN SOLIDIFIED FORM

Номер: US20190016963A1
Принадлежит:

A solid bitumen pellet, including a mixture of bitumen and an additive, where the additive operates to increase the viscosity of the mixture. Optionally, the pellet includes a protective shell. 1. A solid pellet comprising a shell enclosing a core ,the core including crude oil refinery feedstock which is suitable for use as a feedstock to an oil refinery to separate into constituents that can be used as fuels, lubricants and feedstocks in petrochemical processes,wherein the shell constitutes a leak proof barrier configured to prevent one or more of the constituents of the crude oil from which a fuel can be derived by a refining process at the oil refinery from oozing out of the pellet, and wherein the pellet when subjected to a crush-resistance test, manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 1 meter.2. The solid pellet according to claim 1 , wherein the shell includes a material that is separable from the core such that the crude oil refinery feedstock maintains compatibility with the oil refinery to allow separation of the crude oil refinery feedstock into said constituents.3. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 5 meters.4. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 10 meters.5. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 20 meters.6. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 ...

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16-01-2020 дата публикации

HEAT-RESISTANT CHLORINE-CONTAINING CROSSLINKED RESIN FORMED BODY AND ITS PRODUCTION METHOD, SILANE MASTERBATCH AND MASTERBATCH MIXTURE, AND HEAT-RESISTANT PRODUCT

Номер: US20200017642A1
Принадлежит: FURUKAWA ELECTRIC CO., LTD.

A method of producing a heat-resistant chlorine-containing crosslinked resin formed body, formed from: Step (a) of melt-mixing, to a base resin containing a chlorinated polyethylene and a polyvinyl chloride and a plasticizer, an organic peroxide, an inorganic filler, and a silane coupling agent, at a specific ratio, at a temperature equal to or higher than a decomposition temperature of the organic peroxide; Step (b) of mixing a silane masterbatch obtained in Step (a) and a silanol condensation catalyst; and Step (c) of crosslinking by bringing a formed body obtained by Step (b) into contact with water; wherein, in Step (a), from 5 to 55 mass % of the plasticizer is contained in 100 mass % of the base resin to be used in the reaction with the silane coupling agent; the formed body produced therefrom; a silane masterbatch and a mixture thereof; and a heat resistant product. 1. A method of producing a heat-resistant chlorine-containing crosslinked resin formed body , formed from:(a) a step of melt-mixing, with respect to 100 parts by mass of abase resin containing a chlorinated polyethylene and a polyvinyl chloride and a plasticizer, from 0.003 to 0.3 parts by mass of an organic peroxide, from 0.5 to 400 parts by mass of an inorganic filler, and from more than 2 parts by mass to 15.0 parts by mass or less of a silane coupling agent having a grafting reaction site that is capable of causing a grafting reaction to the base resin, at a temperature equal to or higher than a decomposition temperature of the organic peroxide, thereby for subjecting the resultant mixture to the grafting reaction;(b) a step of mixing a silane masterbatch obtained in the step (a) and a silanol condensation catalyst, and then forming the mixture; and(c) a step of silane-crosslinking by bringing the resultant formed body obtained by the step (b) into contact with water;wherein, in the step (a), all or part of the base resin is used in the reaction of the base resin with the silane coupling agent ...

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16-01-2020 дата публикации

Polyethylene composition and film

Номер: US20200017668A1
Принадлежит: Nova Chemicals International SA

In some embodiments disclosed herein are polyethylene composition including a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, and a fourth polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 100,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition may have a soluble fraction in a CEF analysis of at least 7.5 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil) and an oxygen transmission rate (OTR) of ≥550 cm3 per 100 inch2 (at a film thickness of about 1 mil). Film made from the polyethylene composition retains much of its dart impact performance on downgauging from a thickness of 1 mil to a thickness of 0.75 mil.

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16-01-2020 дата публикации

Polyethylene composition and film having high stiffness, outstanding sealability and high permeability

Номер: US20200017669A1
Принадлежит: Nova Chemicals International SA

A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000, a molecular weight distribution Mw/Mn of >2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤90° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥160 Newtons·C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥600 cm3 per 100 inch2 (at a film thickness of about 1 mil).

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16-01-2020 дата публикации

POLYETHYLENE COMPOSITION AND FILM HAVING A GOOD PERMEABILITY, STIFFNESS AND SEALABILITY

Номер: US20200017670A1
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution M/Mof <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥190 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤100° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥160 Newtons·C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥650 cmper 100 inch(at a film thickness of about 1 mil). 1. A polyethylene composition comprising:{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a first polyethylene which is an ethylene copolymer, the first polyethylene having a weight average molecular weight Mof from 70,000 to 250,000, a molecular weight distribution M/Mof <2.3 and from 5 to 100 short chain branches per thousand carbon atoms;'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a second polyethylene which is an ethylene copolymer or an ethylene homopolymer, the second polyethylene having a weight average molecular weight Mof from 15,000 to 100,000, a molecular weight distribution M/Mof <2.3 and from 0 to 20 short chain branches per thousand carbon atoms; and'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a third polyethylene which is an ethylene copolymer or an ethylene homopolymer, the ...

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21-01-2021 дата публикации

LASER TRANSPARENT COMPOSITIONS AND METHODS OF LASER WELDING

Номер: US20210017344A1
Автор: Shi Ying, SMITH DENNIS C.
Принадлежит: LYONDELLBASELL ADVANCED POLYMERS INC.

Laser transparent compositions that may be black in color. The laser transparent compositions may include a matrix material that includes a polypropylene, a dye system that includes one, and optionally two or more, polar organic compounds, a plurality of glass fibers, and a UV stabilizer. Methods of laser welding, which may include irradiating a laser absorbing composition that contacts a laser transparent composition at an interface. 1. A laser transparent composition having a black color , the laser transparent composition comprising:a matrix material comprising a polypropylene;a dye system, wherein the dye system is (i) dispersed in the matrix material, and (ii) present at an amount of about 0.05% to about 0.5%, by weight, based on the weight of the laser transparent composition;a compatibilizer, wherein the compatibilizer is (i) dispersed in the matrix material, and (ii) present at an amount of about 0.1% to about 10%, by weight, based on the weight of the laser transparent composition;a plurality of glass fibers, wherein the plurality of glass fibers is (i) dispersed in the matrix material, and (ii) present at an amount of about 1% to about 40%, by weight, based on the weight of the laser transparent composition; anda UV stabilizer, wherein the UV stabilizer is (i) dispersed in the matrix material, and (ii) present at an amount of about 0.1% to about 2%, by weight, based on the weight of the laser transparent composition;wherein the laser transparent composition has a laser transparency of at least 50%.2. The laser transparent composition of claim 1 , wherein the laser transparent composition has a laser transparency of at least 65%.3. The laser transparent composition of claim 1 , wherein the dye system comprises two or more polar organic compounds.4. The laser transparent composition of claim 3 , wherein the two or more polar organic compounds of the dye system comprise a red dye and a green dye claim 3 , and wherein the red dye and the green dye are present ...

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21-01-2021 дата публикации

Cross-Linked Polyolefin Separator and Manufacturing Method Thereof

Номер: US20210017351A1
Принадлежит: LG CHEM, LTD.

A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained therefrom are provided. The method includes non-grafted polyolefin having a weight average molecular weight of 300,000 or more and silane-grafted polyolefin having a weight average molecular weight of 300,000 or more. The method minimizes gel formation, a side reaction occurring in an extruder during the manufacture of a-the separator, and provides a-the separator having a uniform surface. 1. A method for manufacturing a crosslinked polyolefin separator , comprising:{'b': '1', '(S) mixing non-grafted polyolefin having a weight average molecular weight of 300,000 or more, silane-grafted polyolefin having a weight average molecular weight of 300,000 or more, a diluting agent, an initiator, an alkoxysilane compound containing a carbon-carbon double bonded group and a crosslinking catalyst to an extruder and then carrying out reactive extrusion at 200° C. or higher to obtain a silane-grafted polyolefin composition;'}{'b': '2', '(S) molding and orienting the reactive extruded silane-grafted polyolefin composition in the form of a sheet;'}{'b': '3', '(S) extracting the diluting agent from the oriented sheet to obtain a porous membrane;'}{'b': '4', '(S) thermally fixing the porous membrane; and'}{'b': '5', '(S) crosslinking the porous membrane in the presence of water,'}wherein a content of the alkoxysilane compound containing the carbon-carbon double bonded group is 0.01-2 parts by weight based on 100 parts by weight of a total weight of the non-grafted polyolefin, silane-grafted polyolefin and the diluting agent.2. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein a weight ratio of the non-grafted polyolefin to the silane-grafted polyolefin is 90:10-20:80.3. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein the non-grafted polyolefin has a weight average molecular ...

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21-01-2021 дата публикации

METHOD AND SYSTEMS FOR TRANSPORTING BITUMEN IN SOLIDIFIED FORM

Номер: US20210017452A1
Принадлежит:

Historically, bitumen from oil sands has been carried over land using trucks, pipelines, or by rail, and over water using tankers. Each mode of transportation faces economic or technical challenges of its own. Here there is provided a method for transporting bitumen, comprising: receiving in a dry bulk shipping container a load of discrete pellets with bitumen entrapped into the pellets, wherein the pellets have non-stick outer surfaces configured to prevent the bitumen from sticking to walls of the container when the pellets are carried in the container; and transporting the dry bulk shipping container containing the pellets over a distance. Alternatively or additionally, the pellets may have non-stick outer surfaces configured to prevent the load from caking when the pellets are carried in the container such that the load of bitumen pellets is substantially free-flowing when the transporting is completed. 119.-. (canceled)20. A method for dry bulk shipping bituminous material , comprising: 'wherein the pellets have non-stick outer surfaces configured to prevent the bituminous material from sticking to walls of the container when the pellets are carried in the container, whereby the load remains pourable while it is being transported in the container; and', 'a) receiving in a dry bulk shipping container a pourable load of discrete pellets including bituminous material,'}b) transporting the dry bulk shipping container containing the pellets over a distance.21. The method of claim 20 , wherein the bituminous material is derived from bitumen which is suitable as a feedstock for a refinery to separate the feedstock into constituents that can be used as fuels and lubricants.22. The method of claim 21 , wherein the bituminous material is suitable for use as an oil refinery feedstock to separate the feedstock into constituents that can be used as fuels and lubricants.23. The method of claim 20 , wherein the dry bulk shipping container is a railcar.24. The method of claim ...

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24-01-2019 дата публикации

POLYOLEFIN ELASTOMER COMPOSITIONS AND METHODS OF MAKING THE SAME

Номер: US20190021441A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst. 1. A silane-crosslinked polyolefin elastomer blend comprising:{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm;'}a second polyolefin having a percent crystallinity less than 40%;a silane crosslinker,{'sup': '3', 'wherein the silane-crosslinked polyolefin elastomer blend exhibits a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.) and wherein the silane-crosslinked polyolefin elastomer blend has a density less than 0.90 g/cm.'}2. The silane-crosslinked polyolefin elastomer blend of further comprising a microencapsulated foaming agent.3. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.70 g/cm.4. The silane-crosslinked polyolefin elastomer blend of further comprising a foaming agent.5. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.60 g/cm.6. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the compression set is from about 15.0% to about 35.0% claim 1 , as measured according to ASTM D 395 (22 hrs @ 70° C.).7. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the first polyolefin comprises an ethylene-octene copolymer from about 60 wt % to about 97 wt %.8. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the second polyolefin comprises a polypropylene homopolymer from about 10 wt % to about 35 wt % and/or ...

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28-01-2016 дата публикации

ANTI-REFLECTIVE FILM FOR PHOTOVOLTAIC ARRAYS

Номер: US20160024263A1
Принадлежит:

A film containing polymeric particles which have an average particle diameter from 0.75 to 15 μm and a refractive index which changes continuously from the center of the particles to the surface. The particles are embedded in a continuous polymeric phase comprising a polyolefin. The average refractive index difference measured from 400 nm to 800 nm between the polymeric particles and the continuous polymeric phase is no greater than 0.02. 1. A film comprising polymeric particles having: (a) an average particle diameter from 0.75 to 15 μm; and (b) a refractive index which changes continuously from the center of the particles to the surface; and a continuous polymeric phase comprising a polyolefin; wherein an average refractive index difference measured from 400 nm to 800 nm between the polymeric particles and the continuous polymeric phase is no greater than 0.02.2. The film of in which the average particle diameter is from 1.5 to 10 μm.3. The film of in which the polymeric particles have a refractive index from 1.45 to 1.53.4. The film of in which the polyolefin comprises polymers or copolymers of alkenes having from two to eight carbon atoms.5. The film of in which the refractive index refractive index at the center of the polymeric particles is from 1.52 to 1.60 and the refractive index at the surface is from 1.46 to 1.52.6. The film of in which the continuous polymeric phase comprises from 1 to 12 wt % of the polymeric particles.7. The film of in which the average particle diameter is from 2 to 8 μm.8. The film of in which the polymeric particles comprise at least 60% polymerized residues of acrylic and styrenic monomers. This invention relates to an anti-reflective film which is particularly useful for construction of photovoltaic modules.There are a number of approaches to minimizing wasteful reflection of visible light from photovoltaic arrays, including application of a low dielectric constant layer onto the surface of the array. For example, U.S. Pat. No. 7, ...

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28-01-2016 дата публикации

SINTERED POLYMERIC PARTICLES FOR POROUS STRUCTURES

Номер: US20160024269A1
Принадлежит:

Disclosed are porous elements that include sintered polymeric particles. The polymeric particles can be formed of a thermoplastic composition that includes a polyarylene sulfide. The polymeric particles sintered to form the porous elements have a very narrow size distribution. The porous elements can maintain their functionality and morphology even when utilized in high temperature applications. 1. A porous element comprising sintered polymeric particles , the polymeric particles comprising a thermoplastic composition that includes a polyarylene sulfide , the polymeric particles having a median particle size and a particle size distribution , the particle size distribution being such that 50% of the particles have a size between about 60% of the median particle size and about 140% of the median particle size.2. The porous element of claim 1 , the polymeric particles having a median particle size and a particle size distribution claim 1 , the particle size distribution being such that 50% of the particles have a size between about 80% of the median particle size and about 120% of the median particle size.3. The porous element of claim 1 , wherein the particle size distribution is such that 80% of the particles have a size between about 35% of the median particle size and about 175% of the median polymeric particle size.4. The porous element of claim 1 , the particle size distribution being such that 80% of the particles have a size between about 60% of the median particle size and about 135% of the median particle size.5. The porous element of claim 1 , wherein the median polymeric particle is about 1000 micrometers or less as determined via laser diffraction.6. The porous element of claim 1 , wherein the element has a porosity of about 30% or greater as determined according to DIN 66 133 testing protocol.7. The porous element of claim 1 , wherein the median pore size is from about 10 micrometers to about 150 micrometers as determined according to DIN 66 133 testing ...

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28-01-2016 дата публикации

MINERAL-FILLED POLYPROPYLENE COMPOSITION

Номер: US20160024287A1
Принадлежит:

The present invention relates to low density polypropylene compositions for the production of molded articles, such as finished parts for the automotive industry. 1. A composition having density lower than 1 g/cmcomprising:(A) from 15 to 60% by weight of one or more propylene-based components being selected from propylene homopolymers, propylene copolymers or combinations thereof, such first propylene-based component having a flexural modulus determined in accordance with ISO 178 higher than 1500 MPa, and a PI higher than 10; (B1) from 50 to 90% by weight of a crystalline polypropylene having a solubility in Xylene at room temperature lower than 5% by weight of the component (B1) and a melt flow rate higher than 50 g/10 min;', {'sub': 3', '10, '(B2) from 10 to 50% by weight of a copolymer of ethylene with at least one C-Calpha-olefin as comonomer such copolymer containing from 40 to 60% by weight, of ethylene and having a solubility in Xylene at room temperature higher than 70% by weight;'}], '(B) from 20 to 50% by weight of a heterophasic propylene polymer having a melt flow rate ranging from 10 to 20 g/10 min comprising{'sup': '3', '(D) from 5 to 25% by weight of an ethylene-based plastomer or elastomer, having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points, and a density lower than 0.890 g/cm;'}(E) from 0 to 20% by weight of talc;(C) from 0 to 10% by weight of high-density polyethylene (HDPE); andthe sum of the percentage amounts of the components of the composition is equal to 100 percent.2. The composition of claim 1 , wherein the flexural modulus determined in accordance with ISO 178 of the component (A) is higher than 2000 MPa and the PI of the component (A) is higher than 13.3. The composition of claim 1 , wherein the component (A) has a MFR (230° C. claim 1 , 2.16 kg) value of from 10 to 150 g/10 min.4. The composition of claim 1 , wherein the melt flow rate MFR (230° C. claim 1 , 2.16 kg) value of component (B1) is higher than 70 ...

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26-01-2017 дата публикации

SEGMENTED FILM AND METHOD OF MAKING THE SAME

Номер: US20170022339A1
Принадлежит:

A film having first and second segments arranged along the film's width direction. The second segments are more elastic than the first segments. The first segments can include a polymer and a diluent that is miscible with the polymer at a temperature above a melting temperature of the polymer but that phase separates from the polymer at a temperature below a crystallization temperature of the polymer, or the first segments can include at least one of a beta-nucleating agent or thermally induced phase separation caused by a diluent. Laminates and absorbent articles including such films are also disclosed. A method of making the film is also described. 1. A film comprising first and second segments arranged along the film's width direction , wherein the second segments are more elastic than the first segments , and wherein the first segments comprise a first polymeric composition comprising a polymer and a diluent that is miscible with the polymer at a temperature above a melting temperature of the polymer but that phase separates from the polymer at a temperature below a crystallization temperature of the polymer.2. A film comprising first and second segments arranged along the film's width direction , wherein the second segments are more elastic than the first segments , and wherein the first segments comprise a first polymeric composition comprising at least one of a beta-nucleating agent or thermally induced phase separation caused by a diluent , and wherein when the first polymeric composition includes the beta-nucleating agent , the first segments do not include upstanding posts.3. The film of claim 2 , wherein the first segments comprise thermally induced phase separation caused by a diluent.4. The film of claim 1 , wherein the first segments are microporous.5. The film of claim 1 , wherein the first and second segments are alternating side-by-side stripes comprising the first polymeric composition and an elastic polymeric composition claim 1 , respectively ...

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26-01-2017 дата публикации

NEW FOAM MATERIALS

Номер: US20170022344A1
Принадлежит:

A foamable composition comprising from 60 to 99.88% by weight (% wt.) of at least one poly(aryl ether sulfone), from 0.10 to 10.00% by weight (% wt.) of at least one olefinic polymer, from 0.01 to 5.00% by weight (% wt.) of at least one tetrazole compound and from 0.01 to 2.50% by weight (% wt.) of at least one additive selected from the group of titanium dioxide (Ti02), clays, talc, silicates, silica, aluminates, barites, titanates, borates, nitrides, carbon-based materials or combinations thereof, all % wt. are relative to the total weight of the composition (C). Foam materials made from said foamable compositions and articles made from said foam materials. 114-. (canceled)17. The foamable composition (C) according to claim 15 , wherein the olefinic polymer is selected from the group consisting of a very low density polyethylene claim 15 , a linear low density polyethylene claim 15 , a low density polyethylene claim 15 , a propylene homopolymer claim 15 , or a propylene copolymer.19. The foamable composition (C) according to claim 15 , wherein the additive is selected from the group of TiO claim 15 , silicates claim 15 , and talc.20. The composition (C) according to comprising from 0.01 to 1.00 wt. % of the additive.21. The composition (C) according to further comprising one or more additional ingredient (I) other than the poly(aryl ether sulfone) PAES polymer claim 15 , the olefinic polymer claim 15 , the tetrazole compound claim 15 , and the additive claim 15 , selected from the group consisting of (i) colorants claim 15 , (ii) pigments claim 15 , (iii) light stabilizers claim 15 , (iv) heat stabilizers claim 15 , (v) antioxidants claim 15 , (vi) acid scavengers claim 15 , (vii) processing aids claim 15 , (viii) internal lubricants and/or external lubricants claim 15 , (ix) flame retardants claim 15 , (x) smoke-suppressing agents claim 15 , (xi) anti-static agents claim 15 , (xii) anti-blocking agents claim 15 , (xiii) conductivity additives claim 15 , (xiv) ...

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25-01-2018 дата публикации

PROPYLENE RESIN FOAM PARTICLES AND FOAM PARTICLE MOLDED ARTICLE

Номер: US20180022886A1
Принадлежит:

Provided is an expanded propylene resin bead including a core layer in a foamed state, which includes a propylene-based resin composition (a) satisfying the following (i) and (ii); and a cover layer which includes an olefin-based resin (b) satisfying the following (iii) or (iv): 1. An expanded propylene resin bead comprising a core layer being in a foamed state and constituted of a propylene-based resin composition (a) and a cover layer covering the core layer and constituted of an olefin-based resin (b) ,the propylene-based resin composition (a) satisfying the following (i) and (ii), and the olefin-based resin (b) satisfying the following (iii) or (iv):(i) the propylene-based resin composition (a) is a mixture of 65% by weight to 98% by weight of a propylene-based resin (a1) having a melting point of 145° C. to 165° C. and a flexural modulus of 1,200 MPa or more and 35% by weight to 2% by weight of a propylene-based resin (a2) having a melting point of 100° C. to 145° C. and a flexural modulus of 800 MPa to 1,200 MPa, provided that a sum total weight of the propylene-based resin (a1) and the propylene-based resin (a2) is 100% by weight;(ii) a difference between the melting point of the propylene-based resin (a1) and the melting point of the propylene-based resin (a2) [(melting point of a1)-(melting point of a2)] is 5° C. to 25° C.;(iii) the olefin-based resin (b) is a crystalline olefin-based resin having a melting point (TmB) that is lower than a melting point (TmA) of the propylene-based resin composition (a), with a difference between the melting point (TmA) and the melting point (TmB) [TmA-TmB] being more than 0° C. and 80° C. or less; and(iv) the olefin-based resin (b) is a non-crystalline olefin-based resin having a softening point (TsB) that is lower than the melting point (TmA) of the propylene-based resin composition (a), with a difference between the melting point (TmA) and the softening point (TsB) [TmA-TsB] being more than 0° C. and 100° C. or less.2. ...

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24-01-2019 дата публикации

RUBBER-FIBER COMPOSITE, RUBBER-RESIN COMPOSITE AND PNEUMATIC TIRE IN WHICH SAME IS USED

Номер: US20190023075A1
Автор: NAKAMURA Masaaki
Принадлежит: BRIDGESTONE CORPORATION

An object of the present invention is to provide: a rubber-fiber composite obtained by coating a core-sheath fiber with a rubber, in which adhesion between the rubber and the fiber is improved and which is thereby allowed to exhibit an improved durability as compared to conventional rubber-fiber composites when used as a reinforcing material; a rubber-resin composite; and a pneumatic tire using the same. The rubber-fiber composite is obtained by coating a reinforcing material with a rubber, which reinforcing material is composed of a core-sheath type composite fiber whose core portion is constituted by a high-melting-point resin having a melting point of 150° C. or higher and sheath portion is constituted by an olefin-based polymer having a melting point lower than that of the high-melting point resin. 1. A rubber-fiber composite obtained by coating a reinforcing material with a rubber , said reinforcing material being composed of a core-sheath type composite fiber whose core portion is constituted by a high-melting-point resin having a melting point of 150° C. or higher and sheath portion is constituted by an olefin-based polymer having a melting point lower than that of said high-melting point resin.2. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is an olefin-based random copolymer obtained by addition polymerization of a monomer comprising ethylene or propylene.3. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is an ethylene-propylene random copolymer.4. The rubber-fiber composite according to claim 3 , wherein the propylene content and the ethylene content in said ethylene-propylene random copolymer are 99.7% by mole to 20% by mole and 0.3% by mole to 80% by mole claim 3 , respectively.5. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is a polyethylene-based polymer.6. The rubber-fiber composite according to claim 5 , wherein said polyethylene-based ...

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10-02-2022 дата публикации

Polyester film

Номер: US20220041835A1
Принадлежит: Nan Ya Plastics Corp

A polyester film is provided. The polyester film includes 10 wt % to 100 wt % of a regenerated polyester resin. The regenerated polyester resin includes a physically regenerated polyester resin and a chemically regenerated polyester resin. Based on a total weight of the regenerated polyester resin being 100 wt %, an amount of the chemically regenerated polyester resin is larger than or equal to 5 wt %.

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24-01-2019 дата публикации

THERMOPLASTIC RESIN COMPOSITION, METHOD OF PRODUCING THERMOPLASTIC RESIN COMPOSITION, MOLDED ARTICLE OF CELLULOSE-REINFORCED RESIN, AND METHOD OF PRODUCING MOLDED ARTICLE OF CELLULOSE-REINFORCED RESIN

Номер: US20190023877A1
Принадлежит: FURUKAWA ELECTRIC CO., LTD.

A method of producing a thermoplastic resin composition containing a thermoplastic synthetic resin and a cellulose, in which at least one type of the thermoplastic synthetic resin is a resin having a group containing a partial structure of an acid anhydride in the polymer molecule; 2. The thermoplastic resin composition according to claim 1 , comprising an ionic compound;wherein a content of the ionic compound is 0.001 times or more and less than 1.000 time of the mass content of the cellulose.5. The thermoplastic resin composition according to claim 3 , wherein the X is a halogen ion claim 3 , a carboxylic acid anion claim 3 , a sulfonic acid anion claim 3 , a phosphate anion claim 3 , a phosphonic acid anion claim 3 , a dicyanamide ion claim 3 , or a bis(trifluoromethanesulfonyl)imide ion.6. The thermoplastic resin composition according to claim 1 , wherein the cellulose is plant fiber-derived cellulose.7. The thermoplastic resin composition according to claim 1 , wherein a content of the cellulose is from 1 to 100 parts by mass claim 1 , with respect to 100 parts by mass of the thermoplastic synthetic resin.8. The thermoplastic resin composition according to claim 1 , wherein a content of the resin having a group containing a partial structure of an acid anhydride in the polymer molecule is from 1 to 50% by mass in the thermoplastic synthetic resin.9. The thermoplastic resin composition according to claim 1 , wherein an apparent elastic modulus (Ef) of the cellulose contained in the thermoplastic resin composition at the time when a uniform dispersion element is formed by applying a shear force to the thermoplastic resin composition claim 1 , is 1.1 times or more with respect to an apparent elastic modulus (Ef) of the cellulose contained in a thermoplastic resin composition at the time when a uniform dispersion element is formed by applying a shear force to the thermoplastic resin composition that does not contain the ionic compound or the resin having a group ...

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24-01-2019 дата публикации

COMPOSITION FOR PREPARING A FOAM, FOAM, AND SHOE EMPLOYING THE SAME

Номер: US20190023884A1
Принадлежит: TSRC CORPORATION

A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight. 1. A composition for preparing a foam , comprising:3-30 parts by weight of a first polymer, wherein the first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof; andat least one of a second polymer and a third polymer, wherein the total weight of the second polymer and the third polymer is 70-97 parts by weight, the second polymer is polyolefin, olefin copolymer, or a combination thereof, the third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof, and the total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.2. The composition for preparing a foam as claimed in claim 1 , wherein the cyclic olefin copolymer is a copolymer of a norbornene-based monomer and an olefin-based monomer.3. The composition for preparing a foam as claimed in claim 2 , wherein the norbornene-based monomer ...

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26-01-2017 дата публикации

ELECTRICALLY CONDUCTIVE RUBBER COMPOSITION, TRANSFER ROLLER, AND IMAGE FORMING APPARATUS

Номер: US20170025197A1
Принадлежит: SUMITOMO RUBBER INDUSTRIES, LTD.

An electrically conductive rubber composition is provided, which comprises a rubber component including an SBR, an EPDM and an epichlorohydrin rubber, a crosslinking component and an azodicarbonamide foaming agent having an average particle diameter of 3 to 11 μm. The azodicarbonamide foaming agent is blended in a proportion of 0.5 to 8 parts by mass based on 100 parts by mass of the overall rubber component. A transfer roller () is produced by extruding the electrically conductive rubber composition into an elongated tubular body, and continuously feeding out the tubular body in the elongated state without cutting the tubular body to continuously pass the tubular body through a microwave crosslinking device and a hot air crosslinking device to continuously foam and crosslink the tubular body. 1. An electrically conductive rubber composition which can be foamed and crosslinked by means of a continuous crosslinking apparatus including a microwave crosslinking device and a hot air crosslinking device , the electrically conductive rubber composition comprising:a rubber component including at least a styrene butadiene rubber, an ethylene propylene diene rubber and an epichlorohydrin rubber;a crosslinking component for crosslinking the rubber component; anda foaming component for foaming the rubber component;wherein the foaming component comprises an azodicarbonamide foaming agent having an average particle diameter of not less than 3 μm and not greater than 11 μm in a proportion of not less than 0.5 parts by mass and not greater than 8 parts by mass based on 100 parts by mass of the overall rubber component.2. The electrically conductive rubber composition according to claim 1 , wherein the rubber component comprises at least one polar rubber selected from the group consisting of an acrylonitrile butadiene rubber claim 1 , a chloroprene rubber claim 1 , a butadiene rubber and an acryl rubber. The present application is a 37 C.F.R. §1.53(b) divisional of U.S. application ...

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23-01-2020 дата публикации

Method for producing sheet

Номер: US20200024417A1
Принадлежит: TBM Co Ltd

Provided is a method for producing a foamable sheet with a convenient process. The method for producing a sheet includes the steps of: molding a resin composition including a thermoplastic resin and inorganic substance particles in a ratio of 80:20 to 20:80 and further including a foaming agent into a sheet-like product and stretching the sheet after being molded. The foaming agent preferably includes a polyethylene resin as a carrier resin and a hydrogencarbonate as an active component that acts as a thermally decomposable foaming agent serving as a foam nucleating agent.

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24-01-2019 дата публикации

Method for Making Crosslinked Fluoropolymer Compositions Containing Low Level of Extractable Fluorides

Номер: US20190027270A1
Принадлежит:

A composition for manufacturing a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance is provided, the composition including ETFE, about 0.1-10% w/w of a metal oxide that effectively scavenges high levels of fluoride ions; and a crosslinking agent. Methods of using and making the composition are also provided. 1. A method of making a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance , the method comprising: (i) a fluoropolymer fraction consisting essentially of ETFE;', '(ii) a metal oxide selected from the group consisting of ZnO and MgO; and', '(iii) at least 1% w/w triallyl isocyanurate (TAIC) as a crosslinking agent; and, '(a) providing a composition comprising(b) exposing the composition to at least about 5 Mrad (50 kGy) ionizing radiation; wherein the level of extractable fluoride ions in the crosslinked ETFE copolymer is less than about 150 ppm w/w.2. The method of claim 1 , in which the TAIC is present at a concentration of up to about 10% w/w.3. The method of claim 1 , in which the TAIC is present at a concentration of about 3-7% w/w.4. The method of claim 1 , in which the TAIC is present at a concentration of about 5% w/w.5. The method of claim 1 , in which the metal oxide is present at a concentration of about 0.1-8% w/w.6. The method of claim 1 , in which the metal oxide is present at a concentration of at least about 2.5% w/w.7. The method of claim 1 , in which the metal oxide is present at a concentration of about 2.5-5.0% w/w.8. The method of claim 1 , in which the metal oxide is MgO present at a concentration of about 2.5-5.0% w/w.9. The method of claim 1 , in which the metal oxide is ZnO present at a concentration of about 2.5-5.0% w/w.10. The method of claim 1 , in which the ionizing radiation is electron radiation.11. The method of claim 1 , in which the ionizing radiation is high-energy electron radiation.12. The method of ...

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24-04-2014 дата публикации

Polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom

Номер: US20140113090A1
Принадлежит: Dow Global Technologies LLC

The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm 3 , and a melt index (I 2 ) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (M w /M n ) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm 3 , and a melt index (I 2 ) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants. When the polyethylene blend-composition is formed into a film via blown film process, the output rate is improved at least 6 percent relative to a similar linear low density polyethylene.

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29-01-2015 дата публикации

Polymer Compositions, Methods of Making the Same, and Articles Made Therefrom

Номер: US20150030867A1
Автор: German Paul M.
Принадлежит:

The present disclosure is directed to compositions and methods for improving the cling performance in stretch-cling films. Compositions include: (a) 80.0 to 99.5 wt. % of a propylene-based elastomer, the propylene-based elastomer comprising at least about 60.0 wt. % propylene-derived units and about 5.0 to about 25.0 wt. % ethylene-derived units, based on total weight of the propylene-based elastomer, wherein the propylene-based elastomer has a heat of fusion of less than about 80.0 J/g; and (b) 0.5 to 20.0 wt. % of a polyalphaolefin, wherein the amounts of the propylene-based elastomer, and the polyalphaolefin are based on the weight of the composition. Methods of making such compositions as well as compositions including an ethylene-based polymer and films and methods of making films are also disclosed. 2. The composition of claim 1 , wherein about 8.0 to about 22.5 wt. % of the polymer units in the propylene-based elastomer are ethylene-derived units and the polypropylene-based elastomer has an MFR of about 2.0 to about 30.0 g/10 min.3. The composition of claim 1 , wherein the propylene-based elastomer has a weight average molecular weight (M) of about 5.0×10to about 5.0×10g/mol.4. The composition of claim 1 , wherein the polyalphaolefin is present in an amount of about 2.0 to 12.0 wt. %.5. The composition of claim 1 , wherein the polyalphaolefin has a weight average molecular weight (M) of about 5.0×10to about 1.0×10g/mol.6. The composition of claim 1 , wherein the polyalphaolefin has a kinematic viscosity at 25° C. of about 5.0 to about 1.5×10cSt.7. The composition of claim 1 , wherein the polyalphaolefin has a pour point of −100.0 to 0° C.8. The composition of claim 1 , further comprising a polyolefin and having cling force of about 0.50×10to 2.0×10g/in at 2.0×10% stretch.10. The composition of claim 9 , wherein the propylene-based elastomer is present in an amount of about 5.0 to 20.0 wt. %.11. The composition of claim 9 , wherein about 8.0 to about 22.5 wt. ...

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02-02-2017 дата публикации

METHOD FOR THERMALLY INSULATING AND SOUND-PROOFING COMPONENTS

Номер: US20170028691A1
Принадлежит:

Disclosed is a method for sound-proofing and/or sound-insulating metal and/or plastic components, wherein an insulating layer made of an expanded first thermoplastic polymer material is applied to the components in a first step of the method, and a mass damping layer made of a second thermoplastic polymer material having a density of from 1.5 to 5 g/cmthen is applied to the insulating layer. 1. A method for sound-proofing and/or sound-insulating components , comprising steps of:i) applying an insulating layer made of an expanded first thermoplastic polymer material to at least one surface of a component;{'sup': '3', 'ii) applying a mass damping layer made of a second thermoplastic polymer material having a density of from 1.5 to 5 g/cmto the insulating layer as a defined profile by means of direct extrusion at melting temperatures of between 120 and 300° C.'}2. The method according to claim 1 , wherein the component is used for domestic appliances or domestic machines or is a component part of a domestic appliance or domestic machine.3. The method according to claim 1 , wherein the component is a sink claim 1 , bath tub claim 1 , shower base or shower tray.4. The method according to claim 1 , wherein the component comprises substrates to be coated made of at least one of stainless steel claim 1 , PVC polymers claim 1 , polycarbonate polymers claim 1 , polypropylene polymers claim 1 , acrylonitrile butadiene styrene polymers (ABS polymers) or glass-fiber-reinforced plastics materials (FRP).5. The method according to wherein the first thermoplastic polymer material is an expanded film.6. The method according to wherein the expanded film is an expanded polypropylene film.7. The method according to wherein the first thermoplastic polymer material is applied to the component by means of blow molding and is bonded.8. The method according to wherein the second thermoplastic polymer material is a polypropylene (PP) claim 1 , ethylene vinyl acetate (EVA) or polyamide ...

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29-01-2015 дата публикации

PLASTIC STRAPPING BAND FOR WRAPPING AN OBJECT AND OF METHOD OF MAKING THE BAND

Номер: US20150031803A1
Автор: Lenzen Peter Wilhelm
Принадлежит:

The present invention relates to a plastics-material strapping band () for wrapping around one or more articles. The plastics-material strapping band has the following constituent parts: a) up to approximately 90% by weight polyester, b) approximately 1% by weight to 5% by weight polyolefin and c) approximately 5% by weight to 10% by weight fibre material. The invention also relates to a method for producing a plastics-material strapping band. 1. Plastic strapping for wrapping around one or several objects , the strapping consisting essentially of the following components:a) up to about 90% polyester by weight,b) about 1 to 5% polyolefin by weight andc) about 5 to 10% fibrous material by weight.2. The plastic strapping according to claim 1 , wherein the fibrous material of component c) has a higher melting temperature than the components a) and b).3. The plastic strapping according to claim 1 , wherein the proportion of polyester of component a) is about 85% to 90% weight.4. The plastic strapping according to claim 1 , wherein the polyolefin is polyethylene claim 1 , polypropylene or combinations thereof.5. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is comprised of fibers of a maximal length of up to 20 mm.6. The plastic strapping according to claim 1 , wherein natural plant and/or other mineral fibers are used as the fibrous material of component c).7. The plastic strapping according to claim 1 , wherein cellulose fibers or rubber fibers from natural polymers are used as the fibrous material of component c).8. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is composed of inorganic glass fibers claim 1 , basalt fibers claim 1 , carbon fibers claim 1 , or ceramic fibers.9. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is composed in combination of fibers according to to .10. A method of making of plastic strapping as defined in claim 1 ...

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29-01-2015 дата публикации

POLYMERIC MATERIAL AND PROCESS FOR RECYCLING PLASTIC BLENDS

Номер: US20150031837A1
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There is provided a polymeric material comprising: a co-continuous or highly-continuous blend of polyethylene and polypropylene, the blend comprising a polyethylene phase and a polypropylene phase separated by a polyethylene/polypropylene interface; and one or more thermoplastics other than polyethylene and polypropylene, the one or more thermoplastics each having an interfacial tension with polypropylene higher than the interfacial tension of the polyethylene/polypropylene interface, wherein the one or more thermoplastics form discrete phases that are encapsulating each other, and wherein said discrete phases are comprised within the polypropylene phase of the co-continuous or highly-continuous blend or are located at the polyethylene/polypropylene interface. There is also provided a process for recycling a blend of thermoplastics comprising polyethylene, polypropylene and one or more other thermoplastics, the process comprising the step of melting and mixing the polyethylene, the polypropylene and the one or more other thermoplastics, thereby producing a polymeric material. 1. A polymeric material comprising:a co-continuous or highly-continuous blend of polyethylene and polypropylene, the blend comprising a polyethylene phase and a polypropylene phase separated by a polyethylene/polypropylene interface; andone or more thermoplastics other than polyethylene and polypropylene, the one or more thermoplastics each having an interfacial tension with polypropylene higher than the interfacial tension of the polyethylene/polypropylene interface,wherein the one or more thermoplastics form discrete phases that are encapsulating each other, andwherein said discrete phases are comprised within the polypropylene phase of the co-continuous or highly-continuous blend or are located at the polyethylene/polypropylene interface.2. The polymeric material of claim 1 , wherein the polyethylene/polypropylene interface is compatibilized by an interfacial agent and said discrete phases ...

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02-02-2017 дата публикации

ORIENTED POLYETHYLENE FILMS AND A METHOD FOR MAKING THE SAME

Номер: US20170029583A1
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A first oriented film comprising a first polyethylene composition which comprises: from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an Ilower than 2 g/10 min; and from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than or equal to 0.925 g/cc and an Igreater than or equal to 2 g/10 min; wherein the first polyethylene composition has an 12 from 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc is provided. 1. A first oriented film comprising a first polyethylene composition which comprises:{'sub': '2', 'from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an Ilower than 2 g/10 min; and'}{'sub': '2', 'from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than 0.925 g/cc and an Igreater than 2 g/10 min;'}{'sub': '2', 'wherein the first polyethylene composition has an Ifrom 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc.'}2. The first oriented film according to claim 1 , wherein the first and/or second linear low density polyethylene polymer is produced using a Ziegler-Natta catalyst.3. The first oriented film according to claim 1 , wherein the first linear low density polyethylene polymer has a density greater than 0.930 g/cc and an Ilower than 1 g/10 min.4. The first oriented film according to claim 1 , wherein the second linear low density polyethylene polymer has a density lower than 0.920 g/cc and an Igreater than 4 g/10 min.5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. The first oriented film according to claim 1 , wherein the first polyethylene composition has an MWgreater than 135 kg/mol and Igreater than 42 kg/mol.12. (canceled)13. (canceled)14. The first oriented film according to claim 1 , wherein the first oriented film is oriented below the melting point of the first polyethylenecomposition.15. ( ...

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