13-04-2017 дата публикации
Номер: US20170101494A1
Автор:
Philip P. Fontaine,
Jerzy Klosin,
Endre Szuromi,
Carl N. Iverson,
Zach T. Rickaway,
Andrew J. Young,
Susan G. Brown,
Ruth Figueroa,
Mehmet Demirors,
Mridula Babli Kapur,
FONTAINE PHILIP P,
KLOSIN JERZY,
SZUROMI ENDRE,
IVERSON CARL N,
RICKAWAY ZACH T,
YOUNG ANDREW J,
BROWN SUSAN G,
FIGUEROA RUTH,
DEMIRORS MEHMET,
KAPUR MRIDULA BABLI,
Fontaine Philip P.,
Klosin Jerzy,
Szuromi Endre,
Iverson Carl N.,
Rickaway Zach T.,
Young Andrew J.,
Brown Susan G.,
Figueroa Ruth,
Demirors Mehmet,
Kapur Mridula Babli
The invention provides a process to form an olefin-based polymer, said process comprising polymerizing at least one olefin in the presence of at least one catalyst system comprising the reaction product of the following: A) at least one cocatalyst; and B) a procatalyst comprising a metal-ligand complex of Formula (I), as described herein: (Formula I). 2. The process of claim 1 , wherein for Formula I claim 1 , wherein when Ris a hydrogen atom claim 1 , then Ris a substituted or unsubstituted (C-C)hydrocarbyl claim 1 , a substituted or unsubstituted (C-C)heterohydrocarbyl claim 1 , —Si(R) claim 1 , —Ge(R) claim 1 , —P(R) claim 1 , —N(R) claim 1 , —OR claim 1 , —SR claim 1 , —NO claim 1 , —CN claim 1 , —CF claim 1 , —S(O)R claim 1 , —S(O)R claim 1 , —N═C(R) claim 1 , —OC(O)R claim 1 , —C(O)OR claim 1 , —N(R)C(O)R claim 1 , —C(O)N(R) claim 1 , or a halogen atom; and wherein each Ris independently a substituted or unsubstituted (C-C)hydrocarbyl claim 1 , or a substituted or unsubstituted (C-C) heterohydrocarbyl; or{'sup': 18', '17', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C, 'sub': 1', '40', '1', '40', '3', '3', '2', '2', '2', '3', '2', '2', '2', '1', '30', '1', '30, 'wherein, when Ris a hydrogen atom, then Ris a substituted or unsubstituted (C-C)hydrocarbyl, a substituted or unsubstituted (C-C)heterohydrocarbyl, —Si(R), —Ge(R), —P(R), —N(R), —ORS, —SRS, —NO, —CN, —CF, —S(O)R, —S(O)R, —N═C(R), —OC(O)R, —C(O)OR, —N(R)C(O)R, —C(O)N(R), or a halogen atom; and wherein each Ris independently a substituted or unsubstituted (C-C)hydrocarbyl, or a substituted or unsubstituted (C-C) heterohydrocarbyl; and/or'}{'sup': 19', '20', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C', 'C, 'sub': 1', '40', '1', '40', '3', '3', '2', '2', '2', '3', '2', '2', '2', '1', '30', '1', '30, 'wherein, when Ris a hydrogen atom, then Ris a substituted or unsubstituted (C-C)hydrocarbyl, a substituted or unsubstituted (C-C)heterohydrocarbyl, —Si(R), —Ge(R), —P(R), —N(R), —ORS, — ...
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