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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 16930. Отображено 100.
26-01-2012 дата публикации

Olefin/acrylic polymer blends

Номер: US20120022218A1
Автор: Hailan Guo, Jian-Yang Cho
Принадлежит: Rohm and Haas Co

In one aspect of the present invention, there is provided a polymeric film comprising one or more polyolefin and one or more acrylic polymer, wherein the weight ratio of said acrylic polymer to said polyolefin is from 0.02:1 to 5:1, wherein said polyolefin comprises polymerized units of one or more functional monomer, wherein the amount of said polyolefin in said polymeric film is more than 30% by weight, based on the weight of said polymeric film, and wherein said acrylic polymer comprises polymerized units of one or more hydrogen-bondable monomer.

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02-02-2012 дата публикации

Aqueous dispersion, its production method, and its use

Номер: US20120029132A1
Принадлежит: Dow Global Technologies LLC

Aqueous dispersions including at least one thermoplastic resin; at least one dispersing agent; and water; wherein the dispersion has a pH of less than 12 are disclosed along with dispersions including at least one thermoplastic resin; at least one dispersing agent; and water wherein the dispersion has a volume average particle size of less than about 5 μm. Some dispersions include less than about 4 percent by weight of the dispersing agent based on the weight of the thermoplastic resin. Other dispersions include at least one propylene-rich alpha-olefin interpolymer; at least one dispersing agent; and water. Methods of making such dispersions are also described.

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23-02-2012 дата публикации

Phylon Processes of Making Foam Articles Comprising Ethylene/alpha-Olefins Block Interpolymers

Номер: US20120046373A1
Принадлежит: Individual

Methods of making a foam article comprise the steps of compressing a foam at an elevated temperature in a mold for shaping the foam; and cooling the mold to a temperature greater than room temperature, wherein the foam comprises at least one ethylene/α-olefin block interpolymer. The foam may further comprise an ethylene vinyl acetate copolymer and an additive such as a filler or a crosslinking agent. The ethylene/α-olefin block interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block.

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03-05-2012 дата публикации

Thermoplastic Composition

Номер: US20120108722A1
Автор: Dean Thetford
Принадлежит: Lubrizol Advanced Materials Inc

The invention relates to a composition containing a particulate solid, a plastic material and a compound obtained/obtainable by a process comprising (i) reacting at a temperature of 120° C. or less, or 100° C. or less a hydroxycarboxylic acid and a lactone; and (ii) optionally reacting the product of (i) with a C 1-50 carboxylic acid. The invention further relates to novel compounds, and the use of the compound as a dispersant in a plastic material.

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03-05-2012 дата публикации

Polymer composition, method for producing non-stretched film, non-stretched film, heat seal material, and packing material

Номер: US20120108754A1
Принадлежит: Du Pont Mitsui Polychemicals Co Ltd

Provided is a polymer composition that contains an ionomer which includes an ethylene-α,β-unsaturated carboxylic acid copolymer and a ternary polymer of ethylene-α,β-unsaturated carboxylic acid-α,β-unsaturated carboxylic acid ester, and a propylene-based polymer, wherein a melt flow rate (MFR) value (under a load of 2160 g) of the ionomer at a process temperature in forming a film by T-die melting casting method is from 50% to 250% based on an MFR value of the propylene-based polymer under the same condition.

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10-05-2012 дата публикации

Thermoplastic resin composite bead production method, expandable thermoplastic resin composite bead, expanded thermoplastic resin composite bead, and foamed molded article formed from expanded thermoplastic resin composite beads

Номер: US20120115968A1
Принадлежит: JSP Corp

A seed beads dispersing disperse system is obtained by dispersing olefin resin seed beads 1 with a specific tubular shape in an aqueous medium. Then, the olefin resin seed beads 1 are impregnated with styrene monomers and the styrene monomers are polymerized in the presence of a polymerization initiator by heating at a temperature in a specified range, to thereby obtain tubular thermoplastic resin composite beads. Expandable thermoplastic resin composite beads obtained by impregnating the thermoplastic resin composite beads with a blowing agent, expanded thermoplastic resin composite beads obtained by foaming and expanding the expandable thermoplastic resin composite beads, and a foamed molded article formed from the expanded thermoplastic resin composite beads by molding are also obtained.

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09-08-2012 дата публикации

Microporous membranes, methods for making such membranes, and the use of such membranes as battery separator film

Номер: US20120202044A1
Принадлежит: Toray Tonen Speciality Separator GK

The invention relates to microporous membranes having one or more layers comprising polymer and inorganic molecules. The invention also relates to methods for producing these membranes, and the use of these membranes as battery separator film.

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30-08-2012 дата публикации

Methods of Improving the Physical Properties of Polyolefin Films

Номер: US20120217682A1
Принадлежит: Nova Chemicals Inc

Methods of improving the physical properties of a polyolefin film that include providing interpolymer resin particles, forming a blend composition by blending from about 0.1 to about 25% by weight based on the weight of the blend composition of interpolymer resin particles into a second polyolefin; and forming a film from the blend composition. The interpolymer resin particles are made up a styrenic polymer intercalated within a first polyolefin. The first polyolefin is present at from about 20% to about 80% by weight based on the weight of the particles and the styrenic polymer is present at from about 20% to about 80% by weight based on the weight of the particles.

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25-10-2012 дата публикации

Gas-barrier multilayer film

Номер: US20120270058A1
Принадлежит: Toyobo Co Ltd

Provided is a gas-barrier multilayer film which is superior in gas-barrier properties and interlayer adhesion property, and which exhibits less deterioration in gas-barrier properties and is resistant to interlayer delamination even in prolonged exposure to a high-temperature and high-humidity environment or after a retort treatment. A gas-barrier multilayer film, wherein (A) a first inorganic thin film layer, (C) a gas-barrier resin composition layer, and (D) a second inorganic thin film layer are stacked in this order with or without intervention of other layers on at least one surface of a plastic film, the gas-barrier resin composition layer (C) is formed from a gas-barrier resin composition comprising (a) a gas-barrier resin including an ethylene-vinyl alcohol-based copolymer, (b) an inorganic layered compound, and (c) at least one additive selected from coupling agents and crosslinking agents, and the content of the inorganic layered compound (b) in the gas-barrier resin composition is from 0.1% by mass to 20% by mass based on 100% by mass in total of the gas-barrier resin (a), the inorganic layered compound (b), and the additive (c).

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31-01-2013 дата публикации

Deformable, rigid polystyrene foam board

Номер: US20130030069A1
Принадлежит: OWENS CORNING INTELLECTUAL CAPITAL LLC

Provided are methods for producing a high strength, but easily deformed, polystyrene foam board that can endure repeated deformations from its original configuration into more complex curved shapes without damaging the board integrity or substantially reducing its structural strength. Also provided are rigid polystyrene foam boards produced by this method that exhibit improved bending and impact resistance while substantially retaining or improving other properties, for example, the thermal dimensional stability and fire resistance, exhibited by corresponding conventional XPS foam boards. The foamable compositions may incorporate one or more of a variety of polymer processing aids for the purpose of altering the performance of the final foam products, thereby allowing the properties of the final foam product to be customized to some degree.

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28-02-2013 дата публикации

Recycled thermoplastic with toughener

Номер: US20130053503A1
Принадлежит: EI Du Pont de Nemours and Co

Disclosed is a thermoplastic composition including a) a recycled thermoplastic including polyamide resin, polyolefin and mineral filler, wherein the recycled thermoplastic includes at least 60 weight percent content of recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, blends of polyamide 66 and polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and at least 1 weight percent content of polyolefin; b) polymer toughener, wherein the polymer toughener includes at least 50 to 85 weight percent non-functionalized rubber and 15 to 50 weight percent of a functionalized rubber; and c) 10 to 50 reinforcing agent having a minimum aspect ratio of 3; and molded articles manufactured therefrom.

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21-03-2013 дата публикации

Insulating member for covering a conduit in a clean room

Номер: US20130071593A1
Принадлежит: Individual

This disclosure provides an insulating member for covering a conduit in a clean room. The insulating member typically has a length and defines a cavity extending along the length. The cavity is sized and shaped to receive the conduit. The insulating member typically includes an innermost layer that may be a closed cell fluoropolymer foam and is disposed to contact the conduit. The insulating member also typically includes an outermost layer that is disposed on the innermost layer and that may be a second fluoropolymer.

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27-06-2013 дата публикации

Resin compositions for extrusion coating

Номер: US20130164552A1
Автор: Jian Wang
Принадлежит: Dow Global Technologies LLC

A composition of matter suitable for use in extrusion coating applications is disclosed. The composition comprises a blend of particular LLDPE with particular LDPE. The LLDPE has the following characteristics: a density in the range of from 0.89 g/cc to 0.97 g/cc; an MWD less than 2.8; a melt index (I 2 ) in the range of 4.0 to 25 g/10 min; a Comonomer Distribution Constant in the range of from greater than from 45 to 400; and a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition. The LDPE has a melt index (I 2 ) in the range of 0.1 to 15 g/10 min, and has a melt strength which satisfies the inequality: Log Melt strength (cN)> 1.14−0.6 ×Log I 2 (g/ 10 min, 190 ° C.)

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14-11-2013 дата публикации

Method of forming polymeric foam and related foam articles

Номер: US20130303645A1
Принадлежит: MuCell Extrusion LLC

Methods of forming polymeric foams are provided. The methods may involve co-extruding a foam layer along with one or more skin layers. In some embodiments, the skin layer(s) may be removed (e.g., in a peeling operation); while, in other embodiments, the skin layer(s) may form part of the final article. The methods are particularly well suited for producing polymeric foams from polymeric materials that are considered to be difficult to foam by those of skill in the art.

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09-01-2014 дата публикации

Process for Obtaining A Film that Comprises the Incorporation of Natural Antimicrobial Agents in a Polymeric Structure

Номер: US20140008836A1
Принадлежит: Universidad de Santiago de Chile

A process for obtaining a film that comprises the incorporation of natural antimicrobial agents in a polymeric structure for the development of packages designed to increase the shelf life of chilled or refrigerated meat, preferably fresh chilled salmon; said process comprises the following steps: a) mixing a first extrusion of the antimicrobial active agent with low density polyethylene powder to obtain a pellet; b) a second extrusion to obtain a film incorporating the pellet obtained in step (a) in a proportion of 10% polyethylene pellets; c) conduct a three-layer coextrusion to develop the film into which the antimicrobial agent is incorporated, wherein the antimicrobial active agent is incorporated into the film layer which is in direct contact with salmon, where the binder, the middle and the outer structure of the film, provide the requirements for the film structure, without the incorporation of the active agent.

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27-02-2014 дата публикации

Aqueous polymer dispersions and products from those dispersions

Номер: US20140058034A1
Принадлежит: Dow Global Technologies LLC

A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.

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20-03-2014 дата публикации

Flame-retardant polyamides with pale color

Номер: US20140080949A1
Принадлежит: BASF SE

Thermoplastic molding compositions comprising A) from 10 to 99.8% by weight of a thermoplastic polyamide, B) from 0.1 to 60% by weight of red phosphorus, C) from 0.01 to 4% by weight of a Cu(I) salt or Ag(I) oxide or Cu(I) complex or Ag(I) salt or Cu(I) oxide or Ag(I) complex, or a mixture of these, D) from 0 to 40% by weight of an impact modifier, and E) from 0 to 60% by weight of further additional substances, where the total of the percentages by weight of A) to E) is 100%.

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03-04-2014 дата публикации

Electret sheet

Номер: US20140091249A1
Принадлежит: KANSAI UNIVERSITY, Sekisui Chemical Co Ltd

Provided is an electret having high piezoelectric properties. An electret sheet of the invention is characterized in that it comprises a synthetic resin sheet is electrified by injecting electric charges thereinto, that the synthetic resin sheet comprises two types of synthetic resins incompatible with each other, and that these synthetic resins form a phase separated structure and are cross-linked through a polyfunctional monomer. Therefore, positive and negative charges in an apparently polarized state are present in the interfacial portions between the two types of synthetic resins incompatible with each other. By applying an external force to the electret sheet to deform it, the relative positions of these positive and negative charges are changed, and these changes cause a favorable electrical response. Therefore, the electret sheet has high piezoelectric properties.

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06-01-2022 дата публикации

Polyamides with phosphorous and al-phosphonates

Номер: US20220002543A1
Принадлежит: BASF SE

Described herein are thermoplastic molding materials including components:A) 10 to 98.5 wt % of a thermoplastic polyamide,B) 1 to 20 wt % of red phosphorus,C) 0.5 to 15 wt % of an aluminum salt of phosphonic acid,D) 0 to 55 wt % of a fibrous or particulate filler or mixtures thereof,E) 0 to 30 wt % of further additives,wherein the weight percentages of the components A) to E) sum to 100%.

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01-01-2015 дата публикации

Polymeric material for an insulated container

Номер: US20150001435A1
Принадлежит: Berry Plastics Corp

A formulation includes a polymeric material, a nucleating agent, a blowing agent, and a surface active agent. The formulation can be used to form a container.

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05-01-2017 дата публикации

COMPOSITE RESIN PARTICLES, FOAMABLE PARTICLES, PRE-FOAMED PARTICLES, AND FOAM MOLDED BODY

Номер: US20170002163A1
Принадлежит: SEKISUI PLASTICS CO., LTD.

Composite resin particles including: a polyethylene-based resin and a polystyrene-based resin, wherein the polyethylene-based resin and the polystyrene-based resin are included in the ranges of 50 to 20% by mass and 50 to 80% by mass respectively, with respect to the total of these resins, the polyethylene-based resin is composed of: a first polyethylene-based resin having a medium density to a high density in the range of 925 to 965 kg/m; and a second polyethylene-based resin which is linear and which has a lower density than the first polyethylene-based resin, and the first polyethylene-based resin and the second polyethylene-based resin are included in the ranges of 90 to 30% by mass and 10 to 70% by mass respectively, with respect to the total of these resins. 1. Composite resin particles comprising: a polyethylene-based resin and a polystyrene-based resin , whereinsaid polyethylene-based resin and said polystyrene-based resin are included in ranges of 50 to 20% by mass and 50 to 80% by mass respectively, with respect to the total of these resins,{'sup': '3', 'said polyethylene-based resin is composed of: a first polyethylene-based resin having a medium density to a high density in a range of 925 to 965 kg/m; and a second polyethylene-based resin which is linear and which has a lower density than said first polyethylene-based resin, and'}said first polyethylene-based resin and said second polyethylene-based resin are included in ranges of 90 to 30% by mass and 10 to 70% by mass respectively, with respect to the total of these resins.2. The composite resin particles according to claim 1 , wherein said second polyethylene-based resin has a density of 15 kg/mor more lower than the density of said first polyethylene-based resin.3. The composite resin particles according to claim 1 , wherein said first polyethylene-based resin has a crystallization calorific value of 140mJ/mg or more and said second polyethylene-based resin has a crystallization calorific value of ...

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05-01-2017 дата публикации

THERMALLY EXPANDABLE COMPOSITIONS

Номер: US20170002164A1
Принадлежит:

The present application relates to a thermally expandable composition containing an endothermic chemical blowing agent, to shaped bodies containing said composition and to a method for sealing and filling cavities in components, for strengthening or reinforcing components, in particular hollow components, and for bonding movable components using shaped bodies of this type. 1. A thermally expandable composition containing at least one endothermic chemical blowing agent , at least one reactive binder and at least one of a curing agent and an accelerator.2. The thermally expandable composition according to claim 1 , wherein the at least one endothermic chemical blowing agent is selected from bicarbonates claim 1 , solid polycarboxylic acids claim 1 , solid polycarboxylic acid salts and mixtures thereof; and the at least one reactive binder is selected from the group consisting of epoxies claim 1 , rubbers claim 1 , peroxide-crosslinkable polymers and combinations thereof.3. The thermally expandable composition according to claim 2 , wherein the endothermic chemical blowing agent contains a bicarbonate of formula XHCO claim 2 , wherein X is a cation.4. The thermally expandable composition according to claim 3 , wherein X is selected from Na claim 3 , K claim 3 , NH claim 3 , ½ Zn claim 3 , ½ Mg claim 3 , ½ Ca and mixtures thereof.5. The thermally expandable composition according to claim 2 , wherein the endothermic chemical blowing agent contains a mixture of 2 or more bicarbonates.6. The thermally expandable composition according to claim 2 , wherein the solid polycarboxylic acids are selected from organic di- claim 2 , tri- claim 2 , tetra- acids and combinations thereof.7. The thermally expandable composition according to claim 2 , wherein the solid polycarboxylic acids comprise hydroxyl-functionalized and/or unsaturated di- claim 2 , tri- claim 2 , tetra- or polycarboxylic acids.8. The thermally expandable composition according to claim 2 , wherein the endothermic ...

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05-01-2017 дата публикации

BARRIER FILM FOR FOOD PACKAGING

Номер: US20170002186A1
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

Barrier films are prepared from a blend of two high density polyethylene blend components and a high performance organic nucleating agent. The two high density polyethylene blend components have substantially different melt indices. Large reductions in the moisture vapor transmission rate of the film are observed in the presence of the nucleating agent when the melt indices of the two blend components have a ratio of greater than 10/1. The resulting barrier films are suitable for the preparation of packaging for dry foods such as crackers and breakfast cereals. 115-. (canceled)16. A method for improving the barrier properties of a polyethylene film , said method comprising the steps of converting into a film a mixture comprising;{'sub': '2', 'I) from about 5 to about 60 weight percent, based on the total weight of said mixture, of a blend component a), comprising a first high density polyethylene having a melt index, I;'}{'sub': '2', 'II) from about 95 to about 40 weight percent, based on the total weight of said mixture, of a blend component b), comprising a second high density polyethylene having a melt index I′, and;'}III) from 100 to 3,000 ppm of a nucleating agent, comprising a calcium salt of 1,2 cyclohexanedicarboxylic acid;{'sub': 2', '2, 'wherein, a melt index ratio, defined by dividing said melt index, I, of said blend component a) by said melt index, I′′, of blend component b), is from about 12 to about 19;'}wherein each of said blend component a) and said blend component b) have a density from about 0.950 to about 0.975 g/cc;wherein said mixture has a melt index from about 0.5 to about 4 grams/10 minutes;wherein the water vapor transmission rate of said polyethylene film is improved, by being from about 19 percent lower to about 25 percent lower relative to a control polyethylene film of the same composition but not containing said nucleating agent, and;wherein melt index is measured according to ASTM D1238 (2.16 kg load and 190° C.), density is measured ...

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02-01-2020 дата публикации

Polymer foam and preparation method thereof

Номер: US20200002498A1
Автор: Fuqi Liu, Zhenhuan LUO

The present disclosure relates to a polymer foam and a preparation method thereof. The polymer foam is obtained by physically foaming a thermoplastic elastomer or a polyolefin material, and has an apparent density of 0.30 g/cm3 or less and a rebound degree of 50% or more as measured according to ASTM D2632.

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02-01-2020 дата публикации

METHOD FOR PHYSICALLY FOAMING A POLYMER MATERIAL AND FOAMED ARTICLE

Номер: US20200002499A1
Автор: Liu Fuqi, Luo Zhenhuan
Принадлежит:

The present disclosure relates to a method for physically foaming a polymer material and a foamed article. The method for physically foaming a polymer material comprises: (1) making a thermoplastic elastomer or a polyolefin material into a blank with an injector, an extruder, or a molding press; (2) subjecting the polyolefin blank to a crosslinking reaction to obtain a crosslinked polyolefin blank; (3) subjecting the thermoplastic elastomer blank or the crosslinked polyolefin blank to a high pressure impregnation with a supercritical fluid in an autoclave, then releasing the pressure to a normal pressure to obtain a supercritical fluid-impregnated blank; and (4) placing the supercritical fluid-impregnated blank into an end-product mold to perform an 1:1 in-mold foaming to obtain a finished foam article. 1. A method for physically foaming a polymer material , comprising:(1) making a thermoplastic elastomer or a polyolefin material into a thermoplastic elastomer blank or a polyolefin blank with an injector, an extruder, or a molding press;(2) subjecting the polyolefin blank to a crosslinking reaction to obtain a crosslinked polyolefin blank;(3) subjecting the thermoplastic elastomer blank or the crosslinked polyolefin blank to a high pressure impregnation with a supercritical fluid at a pressure of 10-50 MPa in an autoclave, then releasing the pressure to a normal pressure to obtain a supercritical fluid-impregnated blank; and(4) placing the supercritical fluid-impregnated blank into an end-product mold to perform an 1:1 in-mold foaming to obtain a finished foam article.2. The method according to claim 1 , wherein claim 1 , the thermoplastic elastomer comprises at least one of a thermoplastic polyurethane (TPU) claim 1 , a thermoplastic polyester elastomer (TPEE) claim 1 , and a polyether block amide elastomer (Pebax) claim 1 , or a mixture thereof.3. The method according to claim 1 , wherein claim 1 , the polyolefin material comprises at least one of poly(ethylene-co ...

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03-01-2019 дата публикации

ETHYLENE ALPHA-OLEFIN COPOLYMERS WITH MULTIMODAL COMONOMER DISTRIBUTIONS AND PROCESSES FOR OBTAINING THE SAME

Номер: US20190002676A1
Принадлежит: Braskem S.A.

A polymer composition may include a plurality of ethylene-based polymers forming a multimodal composition distribution, each having a distinct crystallization peak in a CEF curve. A process of making a polymer composition may include melt blending a plurality of polyethylenes with different microstructural characteristics in the molten state. Another process of making a polymer composition may include polymerizing ethylene and an optional alpha olefin in combination with a plurality of metallocene catalysts in a polymerization reactor to form a plurality of ethylene based polymers. Yet another process of making a polymer composition may include polymerizing ethylene and an optional alpha olefin in combination with a multimetal catalyst in a polymerization process to form a plurality of ethylene based polymers. 1. A polymer composition , comprising:a plurality of ethylene-based polymers forming a multimodal composition distribution, each having a distinct crystallization peak in a CEF curve.2. The polymer composition of claim 1 , wherein the distinct crystallization peaks comprise at least two peaks in a range of 40 to 120° C.3. The polymer composition of claim 2 , wherein the at least two peaks are in the range of 40 to 75° C. and 85 to 110° C.4. The polymer composition of claim 3 , further comprising a third peak in the range of 70 to 90° C.5. The polymer composition of claim 1 , wherein the plurality of ethylene-based polymer comprises two or more of:a first polyethylene having an alpha-olefin comonomer content ranging from 0 to 10 wt %;a second polyethylene having an alpha-olefin comonomer content ranging from 10 to 15 wt %; anda third polyethylene having an alpha-olefin comonomer content ranging from 15 to 40 wt %.6. The polymer composition of claim 5 , wherein the first polyethylene is present in an amount ranging from 0 to 30 wt % claim 5 , the second polyethylene is present in an amount ranging from 0 to 60 wt % claim 5 , and the third polyethylene is present ...

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03-01-2019 дата публикации

Product with absorbed gel

Номер: US20190002698A1
Автор: Rossi Enrico Maria
Принадлежит: NX GEL LLC

A product with absorbed gel leaving the exposed surface of such product free of stickiness and/or free of the release of oils in any appreciable amounts. 1. A product with gel , comprising:a porous substrate; anda gel substrate adjoined to the porous substrate, the gel substrate comprising a thermoplastic elastomer, a paraffinic aromatic oil, and a viscosity modifier compound;wherein the viscosity modifier compound comprises:a powder of low density ultrafine polyethylene;a slip agent; anda linear low density polyethylene resin.2. The product as claimed in claim 1 , wherein particles of the powder of low density ultrafine polyethylene are essentially spherical with an average size comprised between 10 micron and 50 micron.3. The product as claimed in claim 1 , wherein the powder of low density ultrafine polyethylene is comprised between 1% and 7% by weight.4. The product as claimed in claim 1 , wherein the slip agent comprises a refined vegetable oil mixed with erucamide.5. The product as claimed in claim 4 , wherein the slip agent is comprised between 0.2% and 1% by weight.6. The product as claimed in claim 1 , wherein the linear low density polyethylene resin comprises a hexane copolymer.7. The product as claimed in claim 6 , wherein the linear low density polyethylene resin is comprised between 0.5% and 2% by weight.8. The product claimed in claim 1 , wherein the gel substrate comprises an antioxidant.9. The product as claimed in claim 8 , wherein the antioxidant is a phenolic antioxidant.10. The product as claimed in claim 9 , wherein the antioxidant is comprised between 0.1% and 0.5% by weight.11. The product as claimed in claim 1 , wherein the gel substrate comprises a phase change material.12. The product as claimed in claim 11 , wherein the phase change material comprises particles containing paraffin with a melting point comprised between 24° C. and 32° C.13. The product as claimed in claim 12 , wherein the phase change material is comprised up to 25% by ...

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13-01-2022 дата публикации

PACKAGED VISCOELASTIC POLYMER SUBSTANCE

Номер: US20220010079A1
Принадлежит: TESA SE

Packaged viscoelastic polymer substances and methods for the production of the packaged viscoelastic polymer substances are provided. The packaged viscoelastic polymer substances are further processable under the influence of heat and shear. 1. A method for producing a packaged viscoelastic polymer substance , the method comprising:a) plastifying a viscoelastic polymer substance at elevated temperatures, the viscoelastic polymer substance being a polymer substance based on poly(meth)acrylates having a weight-average molecular weight of 500,000 g/mol or more;b) continuously dispensing the plastified viscoelastic polymer substance into a protective polymer film, that has no self-adhesive properties and which, before being filled with the plastified viscoelastic polymer substance, has been brought into a tubular form, to give a strandlike polymer assembly having a diameter of 55 to 70 mm, a core of the plastified viscoelastic polymer substance, and a shell of the protective polymer film, wherein a fraction of the protective polymer film, based on a total weight of the protective polymer film and the plastified viscoelastic polymer substance, is less than 1.0 wt %, and wherein the plastified viscoelastic polymer substance has a viscosity of more than 100 Pas at the instant of being dispensed into the tubular protective polymer film;c) converting the strandlike polymer assembly into a flattened strandlike polymer assembly with a smallest cross-section having a ratio of width to height of about 2:1 to 7:1;d) cooling the flattened strandlike polymer assembly to a temperature at which the strandlike polymer assembly is still plastically deformable; ande) subsequently winding the flattened strandlike polymer assembly onto a reel, wherein the strandlike polymer assembly wound onto the reel has a length of more than 30 meters.2. The method of claim 1 , wherein the converting of the strandlike polymer assembly into the flattened strandlike polymer assembly in c) is carried out ...

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01-01-2015 дата публикации

POLYOLEFIN MICROPOROUS FILM AND METHOD FOR PRODUCING SAME

Номер: US20150005405A1
Принадлежит:

A polyolefin microporous membrane is produced by forming a gel-like molding using a polyolefin resin containing polypropylene, and stretching the molding in at least one direction, followed by washing, the polyolefin microporous membrane having an injection of electrolyte of 20 seconds or less and a uniform polypropylene distribution in at least one plane perpendicular to the thickness direction. 16-. (canceled)7. A polyolefin microporous membrane produced by forming a gel-like molding using a polyolefin resin containing polypropylene , and stretching the molding in at least one direction , followed by washing , the polyolefin microporous membrane having an injection of electrolyte of 20 seconds or less and a uniform polypropylene distribution in at least one plane perpendicular to the thickness direction.8. The polyolefin microporous membrane according to claim 7 , wherein the polyolefin resin contains polypropylene having a weight average molecular weight of more than 50 claim 7 ,000 but less than 300 claim 7 ,000 in an amount of 0.5% by mass or more but less than 5% by mass.9. The polyolefin microporous membrane according to claim 7 , having a normalized PP/PE ratio whose average is 0.5 or more claim 7 , whose standard deviation is 0.2 or less claim 7 , and whose kurtosis is 1.0 or less claim 7 , as measured by Raman spectroscopy in at least one plane perpendicular to the thickness direction.10. The polyolefin microporous membrane according to claim 7 , wherein weight average molecular weight of polypropylene is more than 50 claim 7 ,000 but less than 150 claim 7 ,000.11. The polyolefin microporous membrane according to claim 7 , containing an ultra-high molecular weight polyethylene having a mass average molecular weight of 1×10or more in an amount of 1 to 50% by weight based on 100% by mass of a total amount of the polyolefin resin.12. A method of producing the polyolefin microporous membrane according to claim 7 , comprising:{'sup': '6', '(a) melt blending a ...

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14-01-2016 дата публикации

Rotomoulded articles

Номер: US20160009058A1
Автор: Eric Maziers
Принадлежит: Total Research and Technology Feluy SA

A rotomoulded article having one or more layers includes a layer A. The layer A includes from 50 to 99.4 wt % of a polyolefin; from 0.5 to 50 wt % of a polyester; from 0.1 to 20 wt % of a co- or ter-polymer; and from 0.1 to 20 wt % of an ionomer.

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12-01-2017 дата публикации

Shape Memory Products and Method For Making Them

Номер: US20170009040A1
Автор: Kurup Sreeni
Принадлежит: TYCO ELECTRONICS UK LTD.

A method for producing a heat-shrinkable product is provided. First, a polymer composition containing a polymer, a crosslinking agent and a micro-encapsulated foaming agent uniformly dispensed therein is melt mixed. The foaming agent has a peak activation temperature which is higher than a temperature of the melt mixing. Next, the polymer composition is injection molded into a molded product. This carried out at the peak activation temperature to activate the foaming agent. Then, the molded product is crosslinked within the mold. 1. A method for producing a shape memory product comprising the steps of:(i) melt mixing a polymer composition containing a polymer, a crosslinking agent and a micro-encapsulated foaming agent uniformly dispensed therein, the micro-encapsulated foaming agent having a peak activation temperature which is higher than a temperature of the melt mixing,(ii) injection molding the polymer composition into a molded product, the injection molding carried out at the peak activation temperature to activate the micro-encapsulated foaming agent; and(iii) crosslinking the molded product within a mold.2. The method according to claim 1 , wherein the micro-encapsulated foaming agent is a blowing agent.3. The method according to claim 2 , wherein the polymer composition includes a polyolefin.4. The method according to claim 3 , wherein the polymer composition further includes polyethylene.5. The method according to claim 4 , wherein the polymer composition further includes ethylene-vinyl acetate copolymer (EVA).6. The method according to claim 1 , wherein the polymer composition includes 40 to 60% by weight of polyethylene and 10 to 20% by weight of EVA.7. The method according to claim 1 , wherein injection molding is carried out at a temperature in a range of 120 to 160° C.8. The method according to claim 7 , wherein the mold is heated to a temperature in a range of 170 to 210° C.9. The method according to claim 8 , wherein the injection molding is carried ...

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10-01-2019 дата публикации

PLASTIC FILM AND PLASTIC FILM HAVING THE PLASTIC FILM LAYER

Номер: US20190009510A1
Автор: Ren Xuefen
Принадлежит:

A plastic film layer includes polyolefin elastomers. The polyolefin elastomers have better fluidity and can improve the dispersion effect of polypropylene base raw materials. The polypropylene base raw materials are mixed evenly, and enhance the bonding strength between plastic film layers. The plastic film layer also includes a polyaniline resin. A plastic film having the plastic film layer is also provided. The plastic film layer and the plastic film applying the plastic film layer have strong tensile force and are not easily damaged. 1. A plastic film layer comprising:a polypropylene base raw material;a polyolefin elastomer; anda polyphthalamide resin.2. The plastic film layer of claim 1 , wherein a weight percentage range of the polypropylene base material is substantially 86-98 percent claim 1 , a weight percentage range of the polyolefin elastomer is substantially 2-14 percent claim 1 , and a weight percentage range of the polyphthalamide resin is substantially 0.1-1.0 percent.3. The plastic film layer of claim 2 , wherein a weight percentage of the polypropylene base material is substantially 92 percent claim 2 , a weight percentage of the polyolefin elastomer is substantially 7.5 percent claim 2 , and a weight percentage of the polyphthalamide resin is substantially 0.5 percent.4. The plastic film layer of claim 2 , wherein the polypropylene base raw material comprises a first polypropylene raw material and a second polypropylene raw material.5. The plastic film layer of claim 4 , wherein the first polypropylene raw material is an injection molding grade homopolymer polypropylene claim 4 , and the second polypropylene raw material is a blown film grade homopolymer polypropylene.6. The plastic film layer of claim 4 , wherein a weight of the second polypropylene material is substantially 1-4 times that of the first polypropylene material.7. The plastic film layer of claim 6 , wherein the weight of the second polypropylene material is three times that of the ...

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11-01-2018 дата публикации

CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION

Номер: US20180009958A1
Принадлежит: Dow Global Technologies LLC

The instant invention provides procatalysts and catalyst systems for olefin polymerization, olefin based polymers polymerized therewith, and process for producing the same. In one embodiment, the instant invention provides a procatalyst comprising a metal-ligand complex of formula (I): 2. The procatalyst according to wherein Z is O.3. A catalyst system comprising the reaction product of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'one or more procatalysts of ; and'}one or more cocatalysts; wherein the ratio of total number of moles of the one or more metal-ligand complexes of formula (I) to total number of moles of the one or more cocatalysts is from 1:10,000 to 100:1.4. A polymerization process comprising the steps of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'polymerizing one or more α-olefins in the presence of one or more catalyst systems of under olefin polymerizing conditions; and thereby forming an olefin based polymer.'}5. An olefin based polymer comprising the polymerization reaction product of:{'claim-ref': {'@idref': 'CLM-00003', 'claim 3'}, 'one or more α-olefins in the presence of one or more catalyst systems of under olefin polymerizing conditions.'} The present application is a continuation of U.S. patent application Ser. No. 14/437,543, filed on Apr. 22, 2015, which is a national stage entry of PCT/US2013/073976, filed on Dec. 10, 2013, which claims the benefit of U.S. Provisional Application No. 61/746,151, filed on Dec. 27, 2012.The instant invention relates to procatalysts and catalyst systems for olefin polymerization, olefin based polymers polymerized therewith, articles made from such polymers, and process for producing the same.Olefin based polymers such as polyethylene and/or polypropylene are produced via various catalyst systems. Selection of such catalyst system used in the polymerisation process of the olefin based polymers is an important factor contributing to the characteristics and properties of such olefin based ...

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27-01-2022 дата публикации

FOAM FOR OPTICAL FIBER CABLE, COMPOSITION, AND METHOD OF MANUFACTURING

Номер: US20220026651A1
Принадлежит:

Embodiments of the disclosure relate to an optical fiber cable having at least one optical fiber, a cable jacket, and a foam layer. The cable jacket has an inner surface and an outer surface. The outer surface is an outermost surface of the optical fiber cable, and the inner surface is disposed around the at least one optical fiber. The foam layer is disposed between the at least one optical fiber and the cable jacket. The foam layer includes a polymer component having from 30% to 100% by weight of a polyolefin elastomer (POE) or thermoplastic elastomer (TPE) and from 0% to 70% by weight of low density polyethylene (LDPE). The foam layer has a closed-cell morphology having pores with an average effective circle diameter of 10 μm to 500 μm. Further, the expansion ratio of the foam layer is at least 50%. 1. An optical fiber cable comprising:at least one optical fiber;a cable jacket having an inner surface and an outer surface, wherein the outer surface is an outermost surface of the optical fiber cable and wherein the inner surface disposed around the at least one optical fiber;a foam layer disposed between the at least one optical fiber and the cable jacket;wherein the foam layer comprises a polymer component comprising from 30% to 100% by weight of a polyolefin elastomer (POE) or thermoplastic elastomer (TPE) and from 0% to 70% by weight of low density polyethylene (LDPE);wherein the foam layer comprises a closed-cell morphology having pores with an average effective circle diameter of 10 μm to 500 μm; andwherein the expansion ratio of the foam layer is at least 50%.2. The optical fiber cable of claim 1 , the optical fiber cable comprises no more than 432 optical fibers and wherein the modulus is no more than 1 MPa when measured at 50% strain under compression test.3. The optical fiber cable of claim 1 , wherein the optical fiber cable comprises more than 432 optical fibers and wherein the modulus is no more than 0.8 MPa when measured at 50% strain under compression ...

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08-01-2015 дата публикации

SYSTEM AND METHODS FOR SLURRY HYDROCONVERSION PITCH DISPOSITION AS SOLID PELLETS AND COMPOSITION OF THE SAME

Номер: US20150011686A1

A system and method for producing solid pellets from a slurry HDC pitch is disclosed which utilizes a polymer additive that is mixed with the pitch to increase the softening point of the solid pellets. 1. A method of producing solid pellets from a hydroconversion pitch produced from a hydroconversion process , the method comprising:providing a stream hydroconversion pitch;providing a stream of polymer additive;mixing the stream of hydroconversion pitch with the stream of polymer additive to produce a mixture of hydroconversion pitch and polymer additive; andpelletizing the mixture of hydroconversion pitch and polymer additive to produce pellets having a softening point of at least 65° C. (150° F.).2. The method according to claim 1 , wherein the hydroconversion pitch is slurry hydroconversion pitch claim 1 , wherein the hydroconversion process is a slurry hydroconversion process.3. The method according to claim 1 , wherein the mixture of hydroconversion pitch and polymer additive contains less than 10 wt % of polymer additive.4. The method according to claim 1 , wherein the stream of polymer additive is a molten stream of polymer additive.5. The method according to claim 1 , wherein the polymer additive is one of polyethylenes claim 1 , polypropylenes and polycarbonates and mixtures thereof.6. The method according to claim 5 , wherein the polymer additive is a low density polyethylene (LDPE) claim 5 , a high density polyethylene (HDPE) claim 5 , or a combination thereof.7. The method according to claim 1 , further comprising:providing a stream of air; andpassing the stream of hydroconversion pitch through the stream of air prior to mixing with the stream of the polymer additive.8. The method according to claim 1 , wherein the pellets having a softening point of at least 93° C. (200° F.).9. A system for producing solid pellets from a hydroconversion pitch produced from a hydroconversion process claim 1 , the system comprising:a source of hydroconversion pitch;a ...

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08-01-2015 дата публикации

METHOD FOR PROCESSING POLYETHYLENE

Номер: US20150011696A1
Принадлежит:

A method can include consecutively batch processing at least two different polyethylene grades in pellet form in a pellet handling unit. A ratio of a melt flow index (MI) of a first polyethylene in pellet form (MI) to a MI of a later processed polyethylene in pellet form (MI) can be smaller than 0.30. The method can include processing an intermediate polyethylene grade in pellet form. An amount of intermediate polyethylene grade processed can be at most 1/100of a handling capacity of the pellet handling unit. The intermediate polyethylene grade can have the same MI as the later processed polyethylene in pellet form. 17-. (canceled)8. A method of processing different polyethylene grades comprising: a first polyethylene in pellet form in a pellet handling unit;', 'an intermediate polyethylene grade in pellet form in the pellet handling unit; and', 'a later processed polyethylene in pellet form in the pellet handling unit;, 'consecutively batch processing{'sub': f', 'l, 'wherein a ratio of a melt flow index (MI) of the first polyethylene in pellet form (MI) to a MI of the later processed polyethylene in pellet form (MI) is smaller than 0.30; and'}wherein the intermediate polyethylene grade has the same MI as the later processed polyethylene in pellet form.9. The method according to claim 8 , wherein the consecutively batch processed polyethylene pellets are obtained from polyethylene resins produced in the presence of a metallocene catalyst.10. The method according to claim 8 , wherein the pellet handling unit comprises one or more transfer lines claim 8 , one or more homogenization silos claim 8 , one or more storage silos claim 8 , or combinations thereof.11. The method according to claim 8 , wherein at least one of the first polyethylene and the later process polyethylene has a monomodal molecular weight distribution.12. The method according to claim 8 , wherein the first polyethylene and the later process polyethylene have monomodal molecular weight distributions. ...

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08-01-2015 дата публикации

Ethylene-Based Interpolymers and Processes to Make the Same

Номер: US20150011708A1
Принадлежит:

Ethylene-based interpolymers, e.g., ethylene-acrylic acid copolymers, are made by a process comprising the steps of: 115-. (canceled)16. An ethylene-based interpolymer comprising at least one comonomer that comprises at least one ethylenic unsaturation and at least one carbonyl group , and wherein the interpolymer comprises at least one the following properties:{'sup': '2', 'A. An average small gel count per 50,000 square inches (in) of less than or equal to 600; and'}{'sup': '2', 'B. An average micro gel count per 50,000 inof less than or equal to 3,500.'}17. The ethylene-based interpolymer of having a percent by weight of acid comonomer units in the polymer chain from 2 to 30.18. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 16 , Mw/Mn) from 3 to 20.19. The ethylene-based interpolymer of having a molecular weight distribution (MWD claim 17 , Mw/Mn) from 3 to 20.20. The ethylene-based interpolymer of wherein the ethylenic unsaturation of the comonomer is conjugated with the carbonyl group.21. The ethylene-based interpolymer of wherein the comonomer is at least one of an ethylenically unsaturated carboxylic acid claim 16 , anhydride claim 16 , or ester or its salt.22. The ethylene-based interpolymer of wherein the comonomer is acrylic acid or methacrylic acid.23. The ethylene-based interpolymer of wherein the average small gel count per 50 claim 16 ,000 square inches (in) of less than or equal to 300.24. The ethylene-based interpolymer of wherein the average micro gel count per 50 claim 16 ,000 inof less than or equal to 1 claim 16 ,500.25. The ethylene-based interpolymer of wherein the percent by weight of acid comonomer units in the interpolymer chain is from 4 to 15.26. The ethylene-based interpolymer of wherein the molecular weight distribution (MWD claim 16 , Mw/Mn) from 5 to 12.27. The ethylene-based interpolymer of comprising greater than claim 16 , or equal to claim 16 , 1 weight percent of the comonomer based on the ...

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10-01-2019 дата публикации

Low Noise Polymer Composition

Номер: US20190010299A1
Принадлежит:

A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer, reinforcing fibers, and at least one tribological modifier. The tribological modifier, in one embodiment, can comprise a graft copolymer. The use of a graft copolymer has been found to unexpectedly and dramatically improve noise generation when tested against various substrates, especially glass substrates. 1. A polymer composition comprising:a polyoxymethylene polymer;reinforcing fibers present in the polymer composition in an amount from about 5% to about 55% by weight; anda tribological modifier comprising a graft copolymer of a polyolefin or polycarbonate and a branch polymer, the tribological modifier being present in the composition in an amount of 2% by weight or greater.2. A polymer composition as defined in claim 1 , wherein the graft copolymer is a copolymer of a polyolefin claim 1 , the polyolefin comprising polyethylene or polypropylene.3. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a styrenic polymer.4. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises an acrylonitrile polymer.5. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a styrene acrylonitrile polymer.6. A polymer composition as defined in claim 1 , wherein the branch polymer of the graft copolymer comprises a vinyl polymer or an ether polymer.7. A polymer composition as defined in claim 1 , wherein the tribological modifier is present in the composition in an amount from about 3% to about 7% by weight.8. A polymer composition as defined in claim 1 , wherein the graft copolymer is the only tribological modifier present in the polymer composition.9. A polymer composition as defined in claim 1 , wherein the polymer composition further contains ultra-high molecular ...

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10-01-2019 дата публикации

INTEGRATED PROCESS FOR TREATING RECYCLED PET AND PTT MATERIALS

Номер: US20190010303A1
Принадлежит:

A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C-Cfatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof. 129.-. (canceled)30. A process comprising:(a) reacting a recycle stream comprising recycled carpet selected from PTT carpet, PET carpet or mixtures thereof, with a glycol in a reactor, thereby forming a completely digested product stream comprising polyols, and at least one undigested stream;(b) separating the completely digested product stream from the undigested stream, thereby forming a separated digested product stream and a separated undigested product stream; and{'sub': 6', '36', '6', '36', '9', '18', '6', '36, '(b) reacting the separated digested product stream in the reactor with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C-Cfatty acid units, saturated or unsaturated C-Cfatty acids, alkoxylated castor oil, saturated or unsaturated C-Cdicarboxylic acids, cardanol- ...

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09-01-2020 дата публикации

Oriented polyethylene films and a method for making the same

Номер: US20200010631A1
Принадлежит: Dow Global Technologies LLC

A first oriented film comprising a first polyethylene composition which comprises: from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an I 2 lower than 2 g/10 min; and from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than or equal to 0.925 g/cc and an I 2 greater than or equal to 2 g/10 min; wherein the first polyethylene composition has an 12 from 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc is provided.

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09-01-2020 дата публикации

A PROCESS FOR PRODUCING POLYOLEFIN FILM COMPOSITION AND FILMS PREPARED THEREOF

Номер: US20200010655A1
Принадлежит:

The present invention deals with a process for producing a multimodal ethylene polymer composition suitable for producing films by blow moulding. The process comprises (i) copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta polymerisation catalyst to produce a first ethylene homo- or copolymer (PE1) having a density of from 940 to 980 kg/mand a melt flow rate MFRof from 400 to 1000 g/10 min; (ii) copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene copolymer to produce a first ethylene polymer mixture (PEM1) comprising the first ethylene copolymer and a second ethylene copolymer, said first ethylene polymer mixture having a density of from 940 to 980 kg/mand a melt flow rate MFR2 of from 150 to 800 g/10 min, and wherein the MFRof the first ethylene copolymer (PEI) is higher than first ethylene polymer mixture (PEM1) and (iii) copolymerising ethylene and an alpha-olefin comonomer in a third polymerisation step in the presence of the first ethylene polymer mixture to produce a second ethylene polymer mixture (PEM2) comprising the first ethylene polymer mixture and a third ethylene copolymer, said second ethylene polymer mixture having a density of from 915 to 925 kg/mand a melt flow rate MFRof from 0.3 to 5 g/10 min. 1. A process for producing multimodal ethylene polymer film compositions comprising the steps of{'sup': '3', 'sub': '2', '(i) copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta polymerisation catalyst to produce a first ethylene copolymer (PE1) having a density of from 940 to 980 kg/mand a melt flow rate MFRof from 400 to 1000 g/10 min;'}{'sup': '3', 'sub': 2', '2, '(ii) copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene copolymer to produce a ...

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09-01-2020 дата публикации

Flame-Retardant, Moisture-Cured Wire and Cable Constructions with Improved Glancing Impact Performance

Номер: US20200010682A1
Принадлежит: Dow Global Technologies LLC

Articles made from a moisture-curable, polymeric composition comprising in weight percent based on the weight of the composition: (A) 2 to less than 80 weight percent (wt %) of an ethylenic polymer with (1) a crystallinity at room temperature of 34% to 55%, or 65% to 80%, and (2) a melt index (I 2 ) of 0.1 to 50 decigrams per minute (dg/min); (B) 3 to 30 wt % of a halogenated flame retardant; (C) 3 to 30 wt % an inorganic antimony flame retardant; and (D) 0 to 10 wt % of at least one of an inorganic flame retardant other than the inorganic antimony flame retardant, e.g., zinc oxide exhibit enhanced ACBD properties in comparison to articles alike in all respects except made from a composition comprising an ethylenic polymer without the requisite crystallinity at room temperature.

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09-01-2020 дата публикации

METHOD FOR FORMING MULTILAYER COATING FILM

Номер: US20200010698A1
Принадлежит:

A method for forming a multilayer coating film is provided. The method includes coating at least one object with an aqueous primer coating composition, an aqueous first colored coating composition, an aqueous second colored coating composition, and a clear coating composition, in that order. The aqueous primer coating composition contains a component (A) which contains a polyolefin resin, a component (B) which contains a polyurethane resin, a curing agent (C) and electrically conductive carbon (D). The aqueous first colored coating composition and aqueous second colored coating composition each contain a core/shell emulsion. The clear coating composition contains a hydroxyl group-containing acrylic resin, a polyisocyanate and a melamine resin. The method improves the appearance, chipping resistance, adhesive properties and low temperature impact properties of a coating film. 2. The method for forming a multilayer coating film as claimed in claim 1 , wherein the plastic base material contains at least one type of resin material selected from the group consisting of PP resins claim 1 , ABS resins claim 1 , PC resins and ABS/PC resins.3. The method for forming a multilayer coating film as claimed in claim 1 , which is characterized in that a proportion in terms of parts by mass of component (A) and component (B) in the aqueous primer coating composition is 20/80 to 80/20 in terms of resin solid content claim 1 , a proportion in terms of parts by mass of component (C) and {component (A)+component (B)} is 1/100 to 30/100 in terms of solid content claim 1 , and furthermore a proportion in terms of parts by mass of component (D) and {component (A)+component (B)+component (C)} is 2/98 to 20/80 in terms of solid content.4. The method for forming a multilayer coating film as claimed in claim 1 , which is characterized in that component (B) in the aqueous primer coating composition is a colloidal dispersion type or emulsion type aqueous polyurethane resin.5. The method for ...

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03-02-2022 дата публикации

EXPANDABLE, SHELF STABLE POLYMER BEAD

Номер: US20220033608A1
Принадлежит:

The invention relates to an expandable bead comprising a) a polyolefin selected from polyethylene (PE), polypropylene (PP) and mixtures thereof and b) thermoplastic microspheres encapsulating a blowing agent. 1. An expandable bead comprisinga) a polyolefin selected from polyethylene (PE), polypropylene (PP) and mixtures thereof andb) thermoplastic microspheres encapsulating a blowing agent,wherein an aspect ratio, defined as quotient of a largest diameter D1 of the bead to a smallest diameter D2 of the bead, is in the range from ≥1.0 to ≤1.40, wherein the smallest diameter D2 of the bead is in the range from ≥0.5 to ≤2.5 mm.2. The expandable bead of wherein the expandable bead comprises the polyolefin in the range from ≥70% by weight to ≤98% by weight claim 1 ,wherein the total amount of the polyolefin and the thermoplastic microspheres is 100% by weight.3. The expandable bead of comprising a polypropylene having a melt flow index (MFI) of from ≥5 to ≤60 g/10 min claim 1 , as measured according to ISO 1133 at 230° C. and a load of 2.16 kg.4. The expandable bead of wherein the polypropylene is selected from homopolymer PP and random PP copolymer.5. The expandable bead of wherein the polyethylene is linear low density polyethylene (LLDPE) claim 1 , having a MFI in the range from ≥5 to ≤70 g/10 min as measured according to ISO 1133 at 190° C. and 2.16 kg and/orhaving a density in the range from ≥910 to ≤940 kg/m3 as measured according to ISO 1183;and/orhigh density polyethylene (HDPE), having a MFI in the range from ≥5 to ≤70 g/10 min as measured according to ISO 1133 at 190° C. and a load of 2.16 kg and/orhaving a density in the range from ≥940 to ≤970 kg/m3 as measured according to ISO 1183.6. The expandable bead of wherein the diameter D2 is in the range from ≥0.8 to ≤2.0 mm claim 1 ,and/orhaving a bulk density in the range from ≥430 to ≤600 kg/m3 and/orhaving a shelf-stability of at least 6 month.7. The expandable bead of havinga bulk density after its expansion in ...

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03-02-2022 дата публикации

GREASE-RESISTANT FILM, GREASE-RESISTANT BASE MATERIAL, AND GREASE-RESISTANT PAPER

Номер: US20220033637A1
Принадлежит: KURARAY CO., LTD.

An oil-resistant film may be provided by an oil-resistant base material that is excellent in the oil resistance even in not only a plane part but also a bent part of a package can be obtained and also to the provision of an oil-resistant base material having the oil-resistant film and an oil-resistant paper having the oil-resistant film. An oil-resistant film may contain a polyvinyl alcohol-based polymer (A) and a polymer particle (B) containing a polymer having a glass transition temperature of 40° C. or lower, wherein the content of the polymer particle (B) is 1 part by mass or more and less than 150 parts by mass based on 100 parts by mass of the polyvinyl alcohol-based polymer (A); and an oil-resistant base material (oil-resistant paper) having the oil-resistant film on a base material (paper). 1. An oil-resistant film comprising a polyvinyl alcohol-based polymer (A) and a polymer particle (B) containing a polymer having a glass transition temperature of 40° C. or lower , wherein the content of the polymer particle (B) is 1 part by mass or more and less than 150 parts by mass based on 100 parts by mass of the polyvinyl alcohol-based polymer (A).2. The oil-resistant film according to claim 1 , wherein a number average molecular weight of the polymer particle (B) is 5 claim 1 ,000 or more.3. The oil-resistant film of claim 1 , wherein an average particle diameter of the polymer particle (B) is 10 to 500 nm.4. The oil-resistant film of claim 1 , wherein the polymer particle (B) is a (meth)acrylic acid ester-based polymer particle.5. The oil-resistant film of claim 1 , wherein the polymer particle (B) is a (meth)acrylic acid ester-based homopolymer particle.6. The oil-resistant film of claim 1 , wherein the polymer particle (B) contains a dispersant containing an ionic group.7. The oil-resistant oil film according to claim 6 , wherein the ionic group is at least one selected from the group consisting of an anionic group and a salt of an anionic group.8. The oil- ...

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19-01-2017 дата публикации

PROTECTIVE TUBE FOR COIL SPRING AND METHOD FOR MANUFACTURING THE SAME

Номер: US20170015028A1
Автор: LEE Won Sik
Принадлежит:

A protective tube for a coil spring and a method for manufacturing the same are disclosed herein. The protective tube for a coil spring is manufactured by: mixing 40-70 parts by weight of a thermoplastic elastomer, 20-40 parts by weight of a thermoplastic resin, 0.2-5 parts by weight of an antioxidant, and 0.2-5 parts by weight of a crosslinking agent to obtain a mixture; pelletizing the mixture to obtain pellets; extrusion-molding the pellets into a tube; crosslinking the tube by radiation; enlarging the diameter of the crosslinked tube while forming the tube into a spiral shape by heating; and setting the enlarged-diameter tube by cooling. 1. A protective tube for a coil spring , which is manufactured by: mixing 40-70 parts by weight of a thermoplastic elastomer , 20-40 parts by weight of a thermoplastic resin , 0.2-5 parts by weight of an antioxidant , and 0.2-5 parts by weight of a crosslinking agent to obtain a mixture; pelletizing the mixture to obtain pellets; extrusion-molding the pellets into a tube; crosslinking the tube by radiation; enlarging a diameter of the crosslinked tube while forming the tube into a spiral shape by heating; and setting the enlarged-diameter tube by cooling.2. The protective tube of claim 1 , wherein the thermoplastic elastomer is one or more selected from the group consisting of a polyolefin-based thermoplastic elastomer (TPO) claim 1 , a polystyrene-based thermoplastic elastomer (TPS) claim 1 , a polyimide-based thermoplastic elastomer (TPA) claim 1 , a polyurethane-based thermoplastic elastomer (TPU) claim 1 , a polyester-based thermoplastic elastomer (TPC) claim 1 , and a thermoplastic vulcanizate (TPV).3. The protective tube of claim 1 , wherein the thermoplastic resin is one or more selected from the group consisting of polyvinyl chloride-based resin claim 1 , polyamide-based resin claim 1 , polyethylene-based resin claim 1 , polyester-based resin claim 1 , polycarbonate-based resin claim 1 , polystyrene-based resin claim 1 , ...

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21-01-2016 дата публикации

MULTILAYERED ARTICLE COMPRISING POLYPROPYLENE IMPACT COPOLYMERS, AND METHOD OF MAKING SAME

Номер: US20160016389A1
Принадлежит:

A polymer sheet includes a core layer containing a propylene impact copolymer (ICP), and a first additional layer comprising a first polymer composition. The propylene impact copolymer (ICP) in the core layer includes a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which includes greater than 50 wt. % of units derived from propylene monomer. The dispersed phase includes a copolymer of ethylene and a C-Cα-olefin. The ICP has a first melting point being greater than 100° C. (e.g., in the range of from 100° C. to 130° C.) and a second melting point. The polymer sheet can also include a second additional layer containing a second polymer composition. 1. A polymer sheet , comprising: (a) a matrix comprising a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which comprises greater than 50 wt. % of units derived from propylene monomer, and', {'sub': 3', '8, '(b) a dispersed copolymer which comprises ethylene and a C-Cα-olefin,'}, 'wherein the ICP has a first melting point between 100° C. and 130° C. and, 'a core layer comprising a propylene impact copolymer (ICP), the propylene ICP comprisinga second melting point; anda first additional layer comprising a first polymer composition.2. The polymer sheet of claim 1 , whereinthe first polymer composition in the first additional layer comprises at least one of a polypropylene homopolymer, a random copolymer of propylene comprising from 0.01 molar percent (mol. %) to 5 mol. % of ethylene, the propylene ICP and blends thereof.3. The polymer sheet of claim 1 , further comprising:a second additional layer comprising a second polymer composition,wherein the first additional layer and the second additional layer are in direct contact with the core layer.4. The polymer sheet of claim 3 , whereinthe second polymer composition in the second additional layer comprises at least one of a polypropylene homopolymer, a random copolymer of ...

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18-01-2018 дата публикации

METHOD FOR TRENCHLESS RENOVATION OF A SEWER PIPE

Номер: US20180016434A1
Принадлежит:

A single or multilayered film is presented having at least one layer that contains at least one thermoplastic olefin homo or copolymer, modified if need be. The layer contains additionally, at least one polyester. Such film is used as a sliding film or preliner in trenchless pipe renovation using the tube lining technique in which the film is layed on the inner wall of an underground sewer pipe laid that will be renovated. An insertion pipe with a curable carrier material can be pulled in sliding fashion over the sliding film laid on the pipe. 1. Method for a trenchless renovation of a sewer pipe with a tube liner system , wherein said method comprises the step of:inserting a sliding or preliner film into a pipe laid underground, such that said sliding or preliner film is abutted to the inner wall of said pipe, wherein a first layer of the film comprises at least one modified or unmodified thermoplastic olefin homo- or co-polymer and at least one polyester, the thermoplastic olefin homo- or copolymer selected from a group consisting of (1) polyethylene, (2) polypropylene, (3) polybutylene, (4) polyisobutylene, and (5) a mixture of at least two of the polymers (1) through (4).2. The method according to claim 1 , wherein the first layer contains more than 50% by weight of thermoplastic olefin homo- or copolymer and 0.1 to 50% by weight of polyester.3. The method according to claim 1 , wherein the first layer contains more than 50% by weight of polyester and between 10% and 35% by weight of thermoplastic olefin homo- or copolymer.4. The method according to claim 1 , wherein the polyester is amorphous polyethylene terephthalate (A-PET).5. The method according to claim 4 , wherein the A-PET is contained in the first layer in more than 25% by weight claim 4 , or more than 40% by weight claim 4 , or more than 50% by weight claim 4 , or more than 65% by weight.6. The method according to claim 1 , wherein the first layer is an intermediate layer claim 1 , and wherein the ...

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15-01-2015 дата публикации

Ethylene polymer composition and shaped article of the same

Номер: US20150018491A1
Принадлежит: Mitsui Chemicals Inc, Prime Polymer Co Ltd

The present invention provides an ethylene polymer composition having a particularly high formability and having an excellent mechanical strength, a shaped article formed of such an ethylene polymer, and a film and multilayer film having a particularly excellent blocking resistance. An ethylene polymer composition (γ) according to the present invention includes a specific ethylene polymer (α) that is a copolymer of ethylene and an α-olefin having 4 to 10 carbon atoms and an ethylene polymer (β) that is a copolymer of ethylene and an α-olefin having 4 to 10 carbon atoms but different from the ethylene polymer (α), and weight fraction [Wα] of the ethylene polymer (α) is in the range of not less than 0.1 and not more than 0.9, and weight fraction [Wβ] of the ethylene polymer (β) is in the range of not less than 0.1 and not more than 0.9 (the sum of the Wα and the Wβ is 1.0).

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17-01-2019 дата публикации

METHOD AND SYSTEMS FOR TRANSPORTING BITUMEN IN SOLIDIFIED FORM

Номер: US20190016963A1
Принадлежит:

A solid bitumen pellet, including a mixture of bitumen and an additive, where the additive operates to increase the viscosity of the mixture. Optionally, the pellet includes a protective shell. 1. A solid pellet comprising a shell enclosing a core ,the core including crude oil refinery feedstock which is suitable for use as a feedstock to an oil refinery to separate into constituents that can be used as fuels, lubricants and feedstocks in petrochemical processes,wherein the shell constitutes a leak proof barrier configured to prevent one or more of the constituents of the crude oil from which a fuel can be derived by a refining process at the oil refinery from oozing out of the pellet, and wherein the pellet when subjected to a crush-resistance test, manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 1 meter.2. The solid pellet according to claim 1 , wherein the shell includes a material that is separable from the core such that the crude oil refinery feedstock maintains compatibility with the oil refinery to allow separation of the crude oil refinery feedstock into said constituents.3. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 5 meters.4. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 10 meters.5. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 , manifests a probability of failure per pellet that does not exceed 0.25 when the height of the load of pellets is of 20 meters.6. The solid pellet according to claim 2 , wherein the pellet when subjected to a crush-resistance test claim 2 ...

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16-01-2020 дата публикации

Polyethylene composition and film

Номер: US20200017668A1
Принадлежит: Nova Chemicals International SA

In some embodiments disclosed herein are polyethylene composition including a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of less than 75,000 and a molecular weight distribution Mw/Mn of <2.3, and a fourth polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 100,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition may have a soluble fraction in a CEF analysis of at least 7.5 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil) and an oxygen transmission rate (OTR) of ≥550 cm3 per 100 inch2 (at a film thickness of about 1 mil). Film made from the polyethylene composition retains much of its dart impact performance on downgauging from a thickness of 1 mil to a thickness of 0.75 mil.

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16-01-2020 дата публикации

Polyethylene composition and film having high stiffness, outstanding sealability and high permeability

Номер: US20200017669A1
Принадлежит: Nova Chemicals International SA

A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000, a molecular weight distribution Mw/Mn of >2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥200 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤90° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥160 Newtons·C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥600 cm3 per 100 inch2 (at a film thickness of about 1 mil).

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16-01-2020 дата публикации

POLYETHYLENE COMPOSITION AND FILM HAVING A GOOD PERMEABILITY, STIFFNESS AND SEALABILITY

Номер: US20200017670A1
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

A polyethylene composition includes a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution M/Mof <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M/Mof >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a soluble fraction in a CEF analysis of at least 10 weight percent. Film made from the polyethylene composition may have a machine direction 1% secant modulus of ≥190 MPa (at a film thickness of about 1 mil), a seal initiation temperature (SIT) of ≤100° C. (at a film thickness of about 2 mil), an area of hot tack window (AHTW) of ≥160 Newtons·C° (at a film thickness of about 2 mil) and an oxygen transmission rate (OTR) of ≥650 cmper 100 inch(at a film thickness of about 1 mil). 1. A polyethylene composition comprising:{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a first polyethylene which is an ethylene copolymer, the first polyethylene having a weight average molecular weight Mof from 70,000 to 250,000, a molecular weight distribution M/Mof <2.3 and from 5 to 100 short chain branches per thousand carbon atoms;'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a second polyethylene which is an ethylene copolymer or an ethylene homopolymer, the second polyethylene having a weight average molecular weight Mof from 15,000 to 100,000, a molecular weight distribution M/Mof <2.3 and from 0 to 20 short chain branches per thousand carbon atoms; and'}{'sub': w', 'w', 'n, 'from 5 to 80 wt % of a third polyethylene which is an ethylene copolymer or an ethylene homopolymer, the ...

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21-01-2021 дата публикации

Cross-Linked Polyolefin Separator and Manufacturing Method Thereof

Номер: US20210017351A1
Принадлежит: LG CHEM, LTD.

A method for manufacturing a crosslinked polyolefin separator and the crosslinked polyolefin separator obtained therefrom are provided. The method includes non-grafted polyolefin having a weight average molecular weight of 300,000 or more and silane-grafted polyolefin having a weight average molecular weight of 300,000 or more. The method minimizes gel formation, a side reaction occurring in an extruder during the manufacture of a-the separator, and provides a-the separator having a uniform surface. 1. A method for manufacturing a crosslinked polyolefin separator , comprising:{'b': '1', '(S) mixing non-grafted polyolefin having a weight average molecular weight of 300,000 or more, silane-grafted polyolefin having a weight average molecular weight of 300,000 or more, a diluting agent, an initiator, an alkoxysilane compound containing a carbon-carbon double bonded group and a crosslinking catalyst to an extruder and then carrying out reactive extrusion at 200° C. or higher to obtain a silane-grafted polyolefin composition;'}{'b': '2', '(S) molding and orienting the reactive extruded silane-grafted polyolefin composition in the form of a sheet;'}{'b': '3', '(S) extracting the diluting agent from the oriented sheet to obtain a porous membrane;'}{'b': '4', '(S) thermally fixing the porous membrane; and'}{'b': '5', '(S) crosslinking the porous membrane in the presence of water,'}wherein a content of the alkoxysilane compound containing the carbon-carbon double bonded group is 0.01-2 parts by weight based on 100 parts by weight of a total weight of the non-grafted polyolefin, silane-grafted polyolefin and the diluting agent.2. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein a weight ratio of the non-grafted polyolefin to the silane-grafted polyolefin is 90:10-20:80.3. The method for manufacturing the crosslinked polyolefin separator according to claim 1 , wherein the non-grafted polyolefin has a weight average molecular ...

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21-01-2021 дата публикации

METHOD AND SYSTEMS FOR TRANSPORTING BITUMEN IN SOLIDIFIED FORM

Номер: US20210017452A1
Принадлежит:

Historically, bitumen from oil sands has been carried over land using trucks, pipelines, or by rail, and over water using tankers. Each mode of transportation faces economic or technical challenges of its own. Here there is provided a method for transporting bitumen, comprising: receiving in a dry bulk shipping container a load of discrete pellets with bitumen entrapped into the pellets, wherein the pellets have non-stick outer surfaces configured to prevent the bitumen from sticking to walls of the container when the pellets are carried in the container; and transporting the dry bulk shipping container containing the pellets over a distance. Alternatively or additionally, the pellets may have non-stick outer surfaces configured to prevent the load from caking when the pellets are carried in the container such that the load of bitumen pellets is substantially free-flowing when the transporting is completed. 119.-. (canceled)20. A method for dry bulk shipping bituminous material , comprising: 'wherein the pellets have non-stick outer surfaces configured to prevent the bituminous material from sticking to walls of the container when the pellets are carried in the container, whereby the load remains pourable while it is being transported in the container; and', 'a) receiving in a dry bulk shipping container a pourable load of discrete pellets including bituminous material,'}b) transporting the dry bulk shipping container containing the pellets over a distance.21. The method of claim 20 , wherein the bituminous material is derived from bitumen which is suitable as a feedstock for a refinery to separate the feedstock into constituents that can be used as fuels and lubricants.22. The method of claim 21 , wherein the bituminous material is suitable for use as an oil refinery feedstock to separate the feedstock into constituents that can be used as fuels and lubricants.23. The method of claim 20 , wherein the dry bulk shipping container is a railcar.24. The method of claim ...

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24-01-2019 дата публикации

POLYOLEFIN ELASTOMER COMPOSITIONS AND METHODS OF MAKING THE SAME

Номер: US20190021441A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

An elastomeric article is provided that includes a composition having a silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm. The elastomeric article can exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.). The silane-crosslinked polyolefin elastomer can include a first polyolefin having a density less than 0.86 g/cm, a second polyolefin having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, and a condensation catalyst. 1. A silane-crosslinked polyolefin elastomer blend comprising:{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm;'}a second polyolefin having a percent crystallinity less than 40%;a silane crosslinker,{'sup': '3', 'wherein the silane-crosslinked polyolefin elastomer blend exhibits a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.) and wherein the silane-crosslinked polyolefin elastomer blend has a density less than 0.90 g/cm.'}2. The silane-crosslinked polyolefin elastomer blend of further comprising a microencapsulated foaming agent.3. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.70 g/cm.4. The silane-crosslinked polyolefin elastomer blend of further comprising a foaming agent.5. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the density is less than 0.60 g/cm.6. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the compression set is from about 15.0% to about 35.0% claim 1 , as measured according to ASTM D 395 (22 hrs @ 70° C.).7. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the first polyolefin comprises an ethylene-octene copolymer from about 60 wt % to about 97 wt %.8. The silane-crosslinked polyolefin elastomer blend of claim 1 , wherein the second polyolefin comprises a polypropylene homopolymer from about 10 wt % to about 35 wt % and/or ...

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28-01-2016 дата публикации

SINTERED POLYMERIC PARTICLES FOR POROUS STRUCTURES

Номер: US20160024269A1
Принадлежит:

Disclosed are porous elements that include sintered polymeric particles. The polymeric particles can be formed of a thermoplastic composition that includes a polyarylene sulfide. The polymeric particles sintered to form the porous elements have a very narrow size distribution. The porous elements can maintain their functionality and morphology even when utilized in high temperature applications. 1. A porous element comprising sintered polymeric particles , the polymeric particles comprising a thermoplastic composition that includes a polyarylene sulfide , the polymeric particles having a median particle size and a particle size distribution , the particle size distribution being such that 50% of the particles have a size between about 60% of the median particle size and about 140% of the median particle size.2. The porous element of claim 1 , the polymeric particles having a median particle size and a particle size distribution claim 1 , the particle size distribution being such that 50% of the particles have a size between about 80% of the median particle size and about 120% of the median particle size.3. The porous element of claim 1 , wherein the particle size distribution is such that 80% of the particles have a size between about 35% of the median particle size and about 175% of the median polymeric particle size.4. The porous element of claim 1 , the particle size distribution being such that 80% of the particles have a size between about 60% of the median particle size and about 135% of the median particle size.5. The porous element of claim 1 , wherein the median polymeric particle is about 1000 micrometers or less as determined via laser diffraction.6. The porous element of claim 1 , wherein the element has a porosity of about 30% or greater as determined according to DIN 66 133 testing protocol.7. The porous element of claim 1 , wherein the median pore size is from about 10 micrometers to about 150 micrometers as determined according to DIN 66 133 testing ...

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28-01-2016 дата публикации

MINERAL-FILLED POLYPROPYLENE COMPOSITION

Номер: US20160024287A1
Принадлежит:

The present invention relates to low density polypropylene compositions for the production of molded articles, such as finished parts for the automotive industry. 1. A composition having density lower than 1 g/cmcomprising:(A) from 15 to 60% by weight of one or more propylene-based components being selected from propylene homopolymers, propylene copolymers or combinations thereof, such first propylene-based component having a flexural modulus determined in accordance with ISO 178 higher than 1500 MPa, and a PI higher than 10; (B1) from 50 to 90% by weight of a crystalline polypropylene having a solubility in Xylene at room temperature lower than 5% by weight of the component (B1) and a melt flow rate higher than 50 g/10 min;', {'sub': 3', '10, '(B2) from 10 to 50% by weight of a copolymer of ethylene with at least one C-Calpha-olefin as comonomer such copolymer containing from 40 to 60% by weight, of ethylene and having a solubility in Xylene at room temperature higher than 70% by weight;'}], '(B) from 20 to 50% by weight of a heterophasic propylene polymer having a melt flow rate ranging from 10 to 20 g/10 min comprising{'sup': '3', '(D) from 5 to 25% by weight of an ethylene-based plastomer or elastomer, having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points, and a density lower than 0.890 g/cm;'}(E) from 0 to 20% by weight of talc;(C) from 0 to 10% by weight of high-density polyethylene (HDPE); andthe sum of the percentage amounts of the components of the composition is equal to 100 percent.2. The composition of claim 1 , wherein the flexural modulus determined in accordance with ISO 178 of the component (A) is higher than 2000 MPa and the PI of the component (A) is higher than 13.3. The composition of claim 1 , wherein the component (A) has a MFR (230° C. claim 1 , 2.16 kg) value of from 10 to 150 g/10 min.4. The composition of claim 1 , wherein the melt flow rate MFR (230° C. claim 1 , 2.16 kg) value of component (B1) is higher than 70 ...

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25-01-2018 дата публикации

PROPYLENE RESIN FOAM PARTICLES AND FOAM PARTICLE MOLDED ARTICLE

Номер: US20180022886A1
Принадлежит:

Provided is an expanded propylene resin bead including a core layer in a foamed state, which includes a propylene-based resin composition (a) satisfying the following (i) and (ii); and a cover layer which includes an olefin-based resin (b) satisfying the following (iii) or (iv): 1. An expanded propylene resin bead comprising a core layer being in a foamed state and constituted of a propylene-based resin composition (a) and a cover layer covering the core layer and constituted of an olefin-based resin (b) ,the propylene-based resin composition (a) satisfying the following (i) and (ii), and the olefin-based resin (b) satisfying the following (iii) or (iv):(i) the propylene-based resin composition (a) is a mixture of 65% by weight to 98% by weight of a propylene-based resin (a1) having a melting point of 145° C. to 165° C. and a flexural modulus of 1,200 MPa or more and 35% by weight to 2% by weight of a propylene-based resin (a2) having a melting point of 100° C. to 145° C. and a flexural modulus of 800 MPa to 1,200 MPa, provided that a sum total weight of the propylene-based resin (a1) and the propylene-based resin (a2) is 100% by weight;(ii) a difference between the melting point of the propylene-based resin (a1) and the melting point of the propylene-based resin (a2) [(melting point of a1)-(melting point of a2)] is 5° C. to 25° C.;(iii) the olefin-based resin (b) is a crystalline olefin-based resin having a melting point (TmB) that is lower than a melting point (TmA) of the propylene-based resin composition (a), with a difference between the melting point (TmA) and the melting point (TmB) [TmA-TmB] being more than 0° C. and 80° C. or less; and(iv) the olefin-based resin (b) is a non-crystalline olefin-based resin having a softening point (TsB) that is lower than the melting point (TmA) of the propylene-based resin composition (a), with a difference between the melting point (TmA) and the softening point (TsB) [TmA-TsB] being more than 0° C. and 100° C. or less.2. ...

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24-01-2019 дата публикации

RUBBER-FIBER COMPOSITE, RUBBER-RESIN COMPOSITE AND PNEUMATIC TIRE IN WHICH SAME IS USED

Номер: US20190023075A1
Автор: NAKAMURA Masaaki
Принадлежит: BRIDGESTONE CORPORATION

An object of the present invention is to provide: a rubber-fiber composite obtained by coating a core-sheath fiber with a rubber, in which adhesion between the rubber and the fiber is improved and which is thereby allowed to exhibit an improved durability as compared to conventional rubber-fiber composites when used as a reinforcing material; a rubber-resin composite; and a pneumatic tire using the same. The rubber-fiber composite is obtained by coating a reinforcing material with a rubber, which reinforcing material is composed of a core-sheath type composite fiber whose core portion is constituted by a high-melting-point resin having a melting point of 150° C. or higher and sheath portion is constituted by an olefin-based polymer having a melting point lower than that of the high-melting point resin. 1. A rubber-fiber composite obtained by coating a reinforcing material with a rubber , said reinforcing material being composed of a core-sheath type composite fiber whose core portion is constituted by a high-melting-point resin having a melting point of 150° C. or higher and sheath portion is constituted by an olefin-based polymer having a melting point lower than that of said high-melting point resin.2. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is an olefin-based random copolymer obtained by addition polymerization of a monomer comprising ethylene or propylene.3. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is an ethylene-propylene random copolymer.4. The rubber-fiber composite according to claim 3 , wherein the propylene content and the ethylene content in said ethylene-propylene random copolymer are 99.7% by mole to 20% by mole and 0.3% by mole to 80% by mole claim 3 , respectively.5. The rubber-fiber composite according to claim 1 , wherein said olefin-based polymer is a polyethylene-based polymer.6. The rubber-fiber composite according to claim 5 , wherein said polyethylene-based ...

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10-02-2022 дата публикации

Polyester film

Номер: US20220041835A1
Принадлежит: Nan Ya Plastics Corp

A polyester film is provided. The polyester film includes 10 wt % to 100 wt % of a regenerated polyester resin. The regenerated polyester resin includes a physically regenerated polyester resin and a chemically regenerated polyester resin. Based on a total weight of the regenerated polyester resin being 100 wt %, an amount of the chemically regenerated polyester resin is larger than or equal to 5 wt %.

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24-01-2019 дата публикации

THERMOPLASTIC RESIN COMPOSITION, METHOD OF PRODUCING THERMOPLASTIC RESIN COMPOSITION, MOLDED ARTICLE OF CELLULOSE-REINFORCED RESIN, AND METHOD OF PRODUCING MOLDED ARTICLE OF CELLULOSE-REINFORCED RESIN

Номер: US20190023877A1
Принадлежит: FURUKAWA ELECTRIC CO., LTD.

A method of producing a thermoplastic resin composition containing a thermoplastic synthetic resin and a cellulose, in which at least one type of the thermoplastic synthetic resin is a resin having a group containing a partial structure of an acid anhydride in the polymer molecule; 2. The thermoplastic resin composition according to claim 1 , comprising an ionic compound;wherein a content of the ionic compound is 0.001 times or more and less than 1.000 time of the mass content of the cellulose.5. The thermoplastic resin composition according to claim 3 , wherein the X is a halogen ion claim 3 , a carboxylic acid anion claim 3 , a sulfonic acid anion claim 3 , a phosphate anion claim 3 , a phosphonic acid anion claim 3 , a dicyanamide ion claim 3 , or a bis(trifluoromethanesulfonyl)imide ion.6. The thermoplastic resin composition according to claim 1 , wherein the cellulose is plant fiber-derived cellulose.7. The thermoplastic resin composition according to claim 1 , wherein a content of the cellulose is from 1 to 100 parts by mass claim 1 , with respect to 100 parts by mass of the thermoplastic synthetic resin.8. The thermoplastic resin composition according to claim 1 , wherein a content of the resin having a group containing a partial structure of an acid anhydride in the polymer molecule is from 1 to 50% by mass in the thermoplastic synthetic resin.9. The thermoplastic resin composition according to claim 1 , wherein an apparent elastic modulus (Ef) of the cellulose contained in the thermoplastic resin composition at the time when a uniform dispersion element is formed by applying a shear force to the thermoplastic resin composition claim 1 , is 1.1 times or more with respect to an apparent elastic modulus (Ef) of the cellulose contained in a thermoplastic resin composition at the time when a uniform dispersion element is formed by applying a shear force to the thermoplastic resin composition that does not contain the ionic compound or the resin having a group ...

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24-01-2019 дата публикации

COMPOSITION FOR PREPARING A FOAM, FOAM, AND SHOE EMPLOYING THE SAME

Номер: US20190023884A1
Принадлежит: TSRC CORPORATION

A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight. 1. A composition for preparing a foam , comprising:3-30 parts by weight of a first polymer, wherein the first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof; andat least one of a second polymer and a third polymer, wherein the total weight of the second polymer and the third polymer is 70-97 parts by weight, the second polymer is polyolefin, olefin copolymer, or a combination thereof, the third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof, and the total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.2. The composition for preparing a foam as claimed in claim 1 , wherein the cyclic olefin copolymer is a copolymer of a norbornene-based monomer and an olefin-based monomer.3. The composition for preparing a foam as claimed in claim 2 , wherein the norbornene-based monomer ...

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23-01-2020 дата публикации

Method for producing sheet

Номер: US20200024417A1
Принадлежит: TBM Co Ltd

Provided is a method for producing a foamable sheet with a convenient process. The method for producing a sheet includes the steps of: molding a resin composition including a thermoplastic resin and inorganic substance particles in a ratio of 80:20 to 20:80 and further including a foaming agent into a sheet-like product and stretching the sheet after being molded. The foaming agent preferably includes a polyethylene resin as a carrier resin and a hydrogencarbonate as an active component that acts as a thermally decomposable foaming agent serving as a foam nucleating agent.

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24-01-2019 дата публикации

Method for Making Crosslinked Fluoropolymer Compositions Containing Low Level of Extractable Fluorides

Номер: US20190027270A1
Принадлежит:

A composition for manufacturing a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance is provided, the composition including ETFE, about 0.1-10% w/w of a metal oxide that effectively scavenges high levels of fluoride ions; and a crosslinking agent. Methods of using and making the composition are also provided. 1. A method of making a crosslinked ethylene tetrafluoroethylene (ETFE) copolymer with enhanced abrasion resistance and heat resistance , the method comprising: (i) a fluoropolymer fraction consisting essentially of ETFE;', '(ii) a metal oxide selected from the group consisting of ZnO and MgO; and', '(iii) at least 1% w/w triallyl isocyanurate (TAIC) as a crosslinking agent; and, '(a) providing a composition comprising(b) exposing the composition to at least about 5 Mrad (50 kGy) ionizing radiation; wherein the level of extractable fluoride ions in the crosslinked ETFE copolymer is less than about 150 ppm w/w.2. The method of claim 1 , in which the TAIC is present at a concentration of up to about 10% w/w.3. The method of claim 1 , in which the TAIC is present at a concentration of about 3-7% w/w.4. The method of claim 1 , in which the TAIC is present at a concentration of about 5% w/w.5. The method of claim 1 , in which the metal oxide is present at a concentration of about 0.1-8% w/w.6. The method of claim 1 , in which the metal oxide is present at a concentration of at least about 2.5% w/w.7. The method of claim 1 , in which the metal oxide is present at a concentration of about 2.5-5.0% w/w.8. The method of claim 1 , in which the metal oxide is MgO present at a concentration of about 2.5-5.0% w/w.9. The method of claim 1 , in which the metal oxide is ZnO present at a concentration of about 2.5-5.0% w/w.10. The method of claim 1 , in which the ionizing radiation is electron radiation.11. The method of claim 1 , in which the ionizing radiation is high-energy electron radiation.12. The method of ...

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24-04-2014 дата публикации

Polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom

Номер: US20140113090A1
Принадлежит: Dow Global Technologies LLC

The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm 3 , and a melt index (I 2 ) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (M w /M n ) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm 3 , and a melt index (I 2 ) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants. When the polyethylene blend-composition is formed into a film via blown film process, the output rate is improved at least 6 percent relative to a similar linear low density polyethylene.

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29-01-2015 дата публикации

Polymer Compositions, Methods of Making the Same, and Articles Made Therefrom

Номер: US20150030867A1
Автор: German Paul M.
Принадлежит:

The present disclosure is directed to compositions and methods for improving the cling performance in stretch-cling films. Compositions include: (a) 80.0 to 99.5 wt. % of a propylene-based elastomer, the propylene-based elastomer comprising at least about 60.0 wt. % propylene-derived units and about 5.0 to about 25.0 wt. % ethylene-derived units, based on total weight of the propylene-based elastomer, wherein the propylene-based elastomer has a heat of fusion of less than about 80.0 J/g; and (b) 0.5 to 20.0 wt. % of a polyalphaolefin, wherein the amounts of the propylene-based elastomer, and the polyalphaolefin are based on the weight of the composition. Methods of making such compositions as well as compositions including an ethylene-based polymer and films and methods of making films are also disclosed. 2. The composition of claim 1 , wherein about 8.0 to about 22.5 wt. % of the polymer units in the propylene-based elastomer are ethylene-derived units and the polypropylene-based elastomer has an MFR of about 2.0 to about 30.0 g/10 min.3. The composition of claim 1 , wherein the propylene-based elastomer has a weight average molecular weight (M) of about 5.0×10to about 5.0×10g/mol.4. The composition of claim 1 , wherein the polyalphaolefin is present in an amount of about 2.0 to 12.0 wt. %.5. The composition of claim 1 , wherein the polyalphaolefin has a weight average molecular weight (M) of about 5.0×10to about 1.0×10g/mol.6. The composition of claim 1 , wherein the polyalphaolefin has a kinematic viscosity at 25° C. of about 5.0 to about 1.5×10cSt.7. The composition of claim 1 , wherein the polyalphaolefin has a pour point of −100.0 to 0° C.8. The composition of claim 1 , further comprising a polyolefin and having cling force of about 0.50×10to 2.0×10g/in at 2.0×10% stretch.10. The composition of claim 9 , wherein the propylene-based elastomer is present in an amount of about 5.0 to 20.0 wt. %.11. The composition of claim 9 , wherein about 8.0 to about 22.5 wt. ...

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29-01-2015 дата публикации

PLASTIC STRAPPING BAND FOR WRAPPING AN OBJECT AND OF METHOD OF MAKING THE BAND

Номер: US20150031803A1
Автор: Lenzen Peter Wilhelm
Принадлежит:

The present invention relates to a plastics-material strapping band () for wrapping around one or more articles. The plastics-material strapping band has the following constituent parts: a) up to approximately 90% by weight polyester, b) approximately 1% by weight to 5% by weight polyolefin and c) approximately 5% by weight to 10% by weight fibre material. The invention also relates to a method for producing a plastics-material strapping band. 1. Plastic strapping for wrapping around one or several objects , the strapping consisting essentially of the following components:a) up to about 90% polyester by weight,b) about 1 to 5% polyolefin by weight andc) about 5 to 10% fibrous material by weight.2. The plastic strapping according to claim 1 , wherein the fibrous material of component c) has a higher melting temperature than the components a) and b).3. The plastic strapping according to claim 1 , wherein the proportion of polyester of component a) is about 85% to 90% weight.4. The plastic strapping according to claim 1 , wherein the polyolefin is polyethylene claim 1 , polypropylene or combinations thereof.5. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is comprised of fibers of a maximal length of up to 20 mm.6. The plastic strapping according to claim 1 , wherein natural plant and/or other mineral fibers are used as the fibrous material of component c).7. The plastic strapping according to claim 1 , wherein cellulose fibers or rubber fibers from natural polymers are used as the fibrous material of component c).8. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is composed of inorganic glass fibers claim 1 , basalt fibers claim 1 , carbon fibers claim 1 , or ceramic fibers.9. The plastic strapping according to claim 1 , wherein the fibrous material of component c) is composed in combination of fibers according to to .10. A method of making of plastic strapping as defined in claim 1 ...

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02-02-2017 дата публикации

ORIENTED POLYETHYLENE FILMS AND A METHOD FOR MAKING THE SAME

Номер: US20170029583A1
Принадлежит:

A first oriented film comprising a first polyethylene composition which comprises: from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an Ilower than 2 g/10 min; and from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than or equal to 0.925 g/cc and an Igreater than or equal to 2 g/10 min; wherein the first polyethylene composition has an 12 from 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc is provided. 1. A first oriented film comprising a first polyethylene composition which comprises:{'sub': '2', 'from 20 to 50 wt % of a first linear low density polyethylene polymer having a density greater than 0.925 g/cc and an Ilower than 2 g/10 min; and'}{'sub': '2', 'from 80 to 50 wt % of a second linear low density polyethylene polymer having a density lower than 0.925 g/cc and an Igreater than 2 g/10 min;'}{'sub': '2', 'wherein the first polyethylene composition has an Ifrom 0.5 to 10 g/10 min and a density from 0.910 to 0.940 g/cc.'}2. The first oriented film according to claim 1 , wherein the first and/or second linear low density polyethylene polymer is produced using a Ziegler-Natta catalyst.3. The first oriented film according to claim 1 , wherein the first linear low density polyethylene polymer has a density greater than 0.930 g/cc and an Ilower than 1 g/10 min.4. The first oriented film according to claim 1 , wherein the second linear low density polyethylene polymer has a density lower than 0.920 g/cc and an Igreater than 4 g/10 min.5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. The first oriented film according to claim 1 , wherein the first polyethylene composition has an MWgreater than 135 kg/mol and Igreater than 42 kg/mol.12. (canceled)13. (canceled)14. The first oriented film according to claim 1 , wherein the first oriented film is oriented below the melting point of the first polyethylenecomposition.15. ( ...

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02-02-2017 дата публикации

EXPANDED POLYLACTIC ACID RESIN BEADS AND MOLDED ARTICLE OF EXPANDED POLYLACTIC ACID RESIN BEADS

Номер: US20170029591A1
Принадлежит:

The present invention provides expanded polylactic acid resin beads, in which each bead is composed of a core layer that is in an expanded state and contains a crystalline polylactic acid resin, and a coating layer that coats the core layer and contains a mixed resin of an amorphous polylactic acid resin and a crystalline polyolefin resin, wherein the content of the crystalline polyolefin resin in the coating layer is 3% by weight or more and less than 50% by weight. The expanded polylactic acid resin beads can stably produce a molded article of expanded polylactic acid resin beads excellent in fusibility of the expanded polylactic acid resin beads therein and also excellent in solvent resistance. 1. Expanded polylactic acid resin beads , wherein:the expanded bead is composed of a core layer that is in an expanded state and contains a crystalline polylactic acid resin, and a coating layer that coats the core layer and contains a mixed resin of an amorphous polylactic acid resin and a crystalline polyolefin resin, andthe content of the crystalline polyolefin resin in the coating layer is 3% by weight or more and less than 50% by weight.2. The expanded polylactic acid resin beads according to claim 1 , wherein the melting point of the crystalline polyolefin resin is lower than the melting point of the crystalline polylactic acid resin by 20° C. or more.3. A molded article of expanded polylactic acid resin beads claim 1 , which is produced by molding the expanded polylactic acid resin beads according to in a mold cavity.4. The molded article of expanded polylactic acid resin beads according to claim 3 , wherein the bulk density of the molded article of expanded polylactic acid resin beads is 15 to 300 kg/m claim 3 , and the ratio of a bending strength (kPa) of the molded article of expanded polylactic acid resin beads to the bulk density (kg/m) thereof (bending strength/bulk density) is 13 or more (kPa·m/kg).5. The molded article of expanded polylactic acid resin beads ...

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04-02-2016 дата публикации

ENCAPSULANT SHEET FOR SOLAR CELL

Номер: US20160032064A1
Автор: Yoda Hiroaki
Принадлежит:

An encapsulant sheet for a solar cell contains not less than 91% but less than 99% by mass of an ethylene-unsaturated ester copolymer (A), more than 1% but not more than 9% by mass of an olefin resins (B), 0.001 parts to 5 parts by mass of silicon dioxide and 0.001 to 0.5 parts by mass of a silane coupling agent, where the sum total of the content of the ethylene-unsaturated ester copolymer (A) and the content of the olefin resin (B) is taken as 100% by mass. The content of the silicon dioxide and the content of the silane coupling agent are relative to the total content of the ethylene-unsaturated ester copolymer (A) and the content of the olefin resin (B) being taken as 100% by mass. The encapsulant sheet is excellent in insulating property, storage stability, transparency, and durability of adhesion to glass. 1. An encapsulant sheet for a solar cell comprising:not less than 91% by mass but less than 99% by mass of an ethylene-unsaturated ester copolymer (A) that comprises monomer units derived from ethylene and monomer units derived from at least one unsaturated ester selected from the group consisting of vinyl acetate, vinyl propionate, methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, and ethyl methacrylate, and that fails to comprise monomer units derived from acrylic acid, methacrylic acid, or any unsaturated carboxylic glycidyl ester, wherein the content of the monomer units derived from ethylene is 60% by mass to 80% by mass and the content of the monomer units derived from the at least one unsaturated ester is 20% by mass to 40% by mass where the content of the monomer units derived from ethylene and the content of the monomer units derived from the at least one unsaturated ester are each relative to the sum total of the two contents being taken as 100% by mass,more than 1% by mass but not more than 9% by mass of at least one olefin resin (B) selected from the group consisting of an ethylene-(meth) acrylic acid copolymer comprising ...

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31-01-2019 дата публикации

SHOE SOLES, COMPOSITIONS, AND METHODS OF MAKING THE SAME

Номер: US20190029361A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

A shoe sole composition and method for making a shoe sole are provided. The shoe sole includes a composition comprising a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm. The shoe sole exhibits a compression set of from about 5.0% to about 20.0%, as measured according to ASTM D 395 (6 hrs @ 50° C.). The foamed silane-crosslinked polyolefin elastomer can be produced from a blend including a first polyolefin having a density less than 0.86 g/cm, a second polyolefin, having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, a condensation catalyst, and a foaming agent. 1. A shoe midsole comprising:{'sup': '3', 'claim-text': [{'sup': '3', 'a first polyolefin having a density less than 0.86 g/cm,'}, 'a second polyolefin having a crystallinity less than 40%,', 'a silane crosslinker,', 'a grafting initiator,', 'a condensation catalyst, and', 'a foaming agent,, 'a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm, the foamed silane-crosslinked polyolefin elastomer comprisingwherein the shoe midsole exhibits a compression set of from about 1.0% to about 50.0%, as measured according to ASTM D 395 (48 hrs @ 50° C.).2. The shoe midsole of claim 1 , wherein the first polyolefin is an ethylene/α-olefin copolymer from about 60 wt % to about 97 wt %.3. The shoe midsole of claim 1 , wherein the second polyolefin is a polypropylene homopolymer and/or a poly(ethylene-co-propylene) claim 1 , the second polyolefin from about 10 wt % to about 35 wt %.4. The shoe midsole of claim 1 , wherein the silane crosslinker comprises a vinyltrialkoxy silane from about 1 wt % to about 4 wt %.5. The shoe midsole of claim 1 , wherein the grafting initiator comprises one or more halogen molecules claim 1 , azo compounds claim 1 , carboxylic peroxyacids claim 1 , peroxyesters claim 1 , peroxyketals claim 1 , and peroxides claim 1 , the grafting initiator from greater than 0.15 wt % to about 2 wt %.6. The shoe ...

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17-02-2022 дата публикации

PHOSPHATE ANION-QUATERNARY AMMONIUM ION PAIR COORDINATED POLYMER MEMBRANES

Номер: US20220052357A1
Автор: BAE Chulsung, Tian Ding
Принадлежит:

Ion exchange membranes materials according to the present disclosure exhibit improved conductivity at low and intermediate relative humidity without sacrificing mechanical strength. Polymers are provided that include a backbone with one or more aryl groups, a halocarbyl group, and a halocarbyl side chain attached to the backbone, wherein the halocarbyl side chain includes a halide separated from the backbone by a hydrocarbyl chain, a hydrocarbyl ring, or combinations thereof. The halide is substituted with a tertiary amine and halide anions are then exchanged with hydroxide anions. The polymers are then contacted with phosphoric acid, which is deprotonated by the hydroxide ions, forming anions which enhance interactions with adjacent quaternary ammonium groups and induce excess phosphoric acid molecules to cluster around those quaternary ammonium groups. The membranes exhibit negligible dopant leaching even at high relative humidity. 3. The ion exchange membrane material according to claim 1 , wherein R1 includes a hydrocarbyl chain claim 1 , a hydrocarbyl ring claim 1 , or combinations thereof.4. The ion exchange membrane material according to claim 1 , wherein A includes trimethylamine claim 1 , 1-methylpiperidine claim 1 , pyridine claim 1 , 1 claim 1 ,2-dimethylimidazole claim 1 , quinuclidine claim 1 , pentamethylguanidine claim 1 , or combinations thereof.5. The ion exchange membrane material according to claim 1 , wherein the ionic dopant includes dihydrogen phosphate anions and phosphoric acid molecules.6. The ion exchange membrane material according to claim 5 , wherein the number of phosphoric acid molecules per A group is above about 9.7. The ion exchange membrane material according to claim 6 , wherein the number of phosphoric acid molecules per A group is above about 14.8. The ion exchange membrane material according to claim 1 , wherein the halocarbyl group includes CF.9. A method of making an ion exchange membrane material claim 1 , comprising:{'claim ...

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05-02-2015 дата публикации

Biodegradable nanocomposites containing nanoclay and titanium dioxide nanoparticles

Номер: US20150038611A1
Принадлежит:

In the present invention, biodegradable nanocomposites are introduced which include nanoclay particles, titanium dioxide nanoparticles, polyethylene, polypropylene, starch as a biopolymer, maleic anhydride and glycerol. The obtained nanocomposites have very high physical, mechanical and antimicrobial properties. Proper dispersion and distribution of nanoparticles in composite substrate would help in improving the quality of the product to a great extent. The presence of polypropylene next to polyethylene would eliminate the weak points of polyethylene/biopolymer composite as polypropylene helps to modify the physical and engineering properties of nanocomposites in the presence of nanoclay. Titanium dioxide nanoparticles have antimicrobial properties and would result in products which are useful for food and pharmaceutical industries. Another important aspect of this invention is the production of samples in one step by reaction extrusion method. 1. A method for preparation of Biodegradable nanocomposites comprising the following steps of:a) Mixing nanoclay particles of at least 3% by weight with a plasticizer of choice;b) Mixing the product of step (a) with a biopolymer; wherein a ratio of said biopolymer with said plasticizer of choice is ⅓; wherein step (a) must be performed before step (b) creating a more effective intercalation;c) A batch of synthetic materials comprising compatibilizers, polyethylene and polypropylene, with anti-microbial nanoparticles were transferred into an extruder at the same time as step (b) wherein said batch and mixture of steps (a) and (b) were all added into said extruder by reactive extrusion methods; creating a final product.2. The method of ; wherein said plasticizer of choice comprises glycerol.3. The method of ; wherein said biopolymer comprises polysaccharides; such as carboxymethyl cellulose claim 1 , chitosan claim 1 , keratin and/or starch; wherein said starch comprises various types extracted from peas claim 1 , soya claim 1 ...

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05-02-2015 дата публикации

COMPOSITION FOR PRODUCING SHEET FOR FORMING LAMINATE, PROCESS FOR PRODUCING THE SAME, AND SHEET FOR FORMING LAMINATE

Номер: US20150038646A1
Принадлежит: BRIDGESTONE CORPORATION

To provide a composition for producing a sheet for forming a laminate, which contains an ethylene-vinyl acetate copolymer and a polyethylene resin, by which the above-described problems in the width of the temperature range in which a processable viscosity range is obtained and the like are improved and which excels in processing properties such as a film-forming property when producing a sheet, and a sheet for forming a laminate using this. A composition for producing a sheet for forming a laminate, which contains an ethylene-vinyl acetate copolymer and polyethylene, wherein the composition has a sea-island structure in which the ethylene-vinyl acetate copolymer is a sea phase and the polyethylene is an island phase, and a sheet for forming a laminate using this. 1. A composition for producing a sheet for forming a laminate , comprising an ethylene-vinyl acetate copolymer and polyethylene ,wherein the composition has a sea-island structure in which the ethylene-vinyl acetate copolymer is a sea phase and the polyethylene is an island phase.2. The composition according to claim 1 , wherein a volume ratio (EVA:PE) of the ethylene-vinyl acetate copolymer (EVA) to the polyethylene (PE) is in a range of 90:10 to 30:70.3. The composition according to claim 1 , wherein the sea-island structure is obtained by kneading the ethylene-vinyl acetate copolymer (EVA) and the polyethylene (PE) under a condition where a viscosity of the PE (V[Pa·s]) is 0.1 to 20 times with respect to a viscosity of the EVA (V[Pa·s]).4. The composition according to claim 1 , wherein the sea-island structure is obtained by kneading the ethylene-vinyl acetate copolymer and the polyethylene under a condition of a shear rate of 10 to 1500 s.5. The composition according to claim 1 , wherein an average diameter ((average long diameter (1)+average short diameter (d))/2) of the polyethylene island phase is 40 μm or less.6. The composition according to claim 1 , wherein an average aspect ratio (average long ...

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09-02-2017 дата публикации

Gloves Comprising Propylene-Based Elastomer and Methods of Making Same

Номер: US20170036425A1
Принадлежит:

Disclosed are gloves including a propylene-based elastomer that may provide desired use comfort and fitting characteristic. 1. A glove , comprising a film comprising a core layer , wherein the core layer comprises:a propylene-based elastomer comprising at least about 60 wt % propylene-derived units and about 3 to about 25 wt % ethylene-derived units, based on the total weight of the propylene-based elastomer, wherein the propylene-based elastomer has a heat of fusion of less than about 80 J/g.2. The glove of claim 1 , wherein the film has at least one of the following properties: (i) a hysteresis (EMC method) of up to 10% lower than that of a comparative PVC glove film; (ii) a tear strength in the Machine Direction (MD) of at least about 70% higher than that of a comparative PVC glove film and in the Transverse Direction (TD) of at least about 220% higher than that of a comparative PVC glove film: (iii) a puncture resistance of up to about 75% higher than that of a comparative PVC glove film; and (iv) a tensile strength of at least about 15% higher than that of a comparative PVC glove film.3. The glove of claim 1 , wherein the propylene-based elastomer is present in an amount of at least about 30 wt % claim 1 , based on total weight of polymer in the core layer.4. The glove of claim 1 , wherein the propylene-based elastomer is present in an amount of about 100 wt % claim 1 , based on total weight of polymer in the core layer.5. The glove of claim 1 , wherein the core layer further comprises a polyethylene.6. The glove of claim 1 , wherein the core layer further comprises at least one of a slip agent claim 1 , an anti block claim 1 , a filler claim 1 , an antioxidant claim 1 , an ultraviolet light stabilizer claim 1 , a thermal stabilizer claim 1 , a pigment claim 1 , a processing aid claim 1 , a crosslinking catalyst claim 1 , a flame retardant claim 1 , and a foaming agent.7. The glove of claim 1 , wherein the film further comprises an outer layer at each side of ...

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08-02-2018 дата публикации

EASY TO DISPERSE CALCIUM CARBONATE TO IMPROVE HOT TACK STRENGTH

Номер: US20180036764A1
Принадлежит:

The present invention relates to a process for producing an extrusion-coated material, an extrusion-coated material produced by the process, an article comprising the extrusion-coated material as well as the use of the extrusion-coated material in a lamination process. 1. A process for producing an extrusion-coated material comprising the following steps:a) providing at least one filler material in powder form,b) providing at least one polymer binder,c) providing at least one thermoplastic polymer,d) simultaneously or subsequently feeding the at least one filler material of step a) andthe at least one polymer binder of step b) into a high speed mixer unit,e) mixing the at least one filler material of step a) and the at least one polymer binder of step b) in the high speed mixer unit to obtain a compacted material,f) reducing the temperature of the compacted material obtained in step d) below the melting point or glass transition temperature of the at least one polymer binder,g) combining the compacted material obtained in step f) and the at least one thermoplastic polymer of step c) to obtain a filled thermoplastic polymer,h) extrusion coating the filled thermoplastic polymer obtained in step g) on at least a portion of the surface of a substrate.2. The process of claim 1 , wherein the at least one filler material of step a) comprises a calcium carbonate-comprising filler material.3. The process of claim 1 , wherein the at least one filler material of step a) is a calcium carbonate-comprising filler material being selected from the group consisting of natural ground calcium carbonate claim 1 , precipitated calcium carbonate claim 1 , surface-modified calcium carbonate claim 1 , and mixtures thereof claim 1 , and preferably natural ground calcium carbonate.4. The process of claim 1 , wherein the at least one filler material of step a) has a weight median particle size dfrom 0.05 to 10 μm claim 1 , preferably from 0.1 to 7 μm claim 1 , more preferably from 0.25 to 5 μ ...

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11-02-2016 дата публикации

A METHOD FOR THE PREPARATION OF PLA BEAD FOAMS

Номер: US20160039990A1
Принадлежит:

The present invention relates to a method for the preparation of PLA beads, more particularly expanded PLA bead foams. In addition, the present invention relates to a method for the preparation of moldings by sintering PLA beads. The method comprises the following steps: A) providing unfoamed PLA pellets, B) heating said unfoamed PLA pellets to an annealing temperature and saturating with a blowing agent, C) maintaining said PLA pellets on the annealing temperature and saturating with said blowing agent, D) depressurizing and cooling the saturated PLA pellets of step C) to room temperature to form expanded PLA bead foams. 1. A method for preparation of expanded polylactide bead foams comprising the following steps:A) providing unfoamed polylactide pellets,B) heating said unfoamed polylactide pellets to an annealing temperature and saturating with a blowing agent,C) maintaining said polylactide pellets on the annealing temperature and saturating with said blowing agent,D) depressurizing and cooling the saturated polylactide pellets of step C) to room temperature to form expanded polylactide bead foams.2. The method according to claim 1 , in which the annealing temperature is in the range of 60° C.-180° C.3. The method according to claim 1 , in which the annealing time during step C) is in the range of 10 min-300 min.4. The method according to claim 1 , in which the polylactide pellets in step A) are chosen from the group of linear polylactide claim 1 , branched polylactide and polylactide copolymers with D-lactide contents claim 1 , or combinations thereof.5. method according to claim 4 , in which step B) takes place in a suspension medium.6. A method according to claim 4 , in which the polylactide pellets in step A) are mixed with polyolefins and/or polyesters.7. An expanded polylactide bead foam having a double crystal melting peak claim 4 , in which the distance between the two peaks is in the range of 5° C.-25° C.8. (canceled)9. The polylactide bead according to ...

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09-02-2017 дата публикации

FOAMABLE MASTERBATCH AND POLYOLEFIN RESIN COMPOSITION WITH EXCELLENT EXPANDABILITY AND DIRECT METALLIZING PROPERTY

Номер: US20170037214A1
Принадлежит:

The present disclosure provides a masterbatch prepared by melting and extruding a mixture including a polyolefin resin, wherein the mixture includes 10 to 89% by weight of a polyolefin resin, 5 to 30% by weight of a chemical blowing agent, 5 to 30% by weight of thermally expandable microcapsule, and 1 to 30% by weight of an inorganic filler. In addition, the present disclosure provides a polyolefin resin composition with excellent expandability and direct metallizing property, which includes the foamable masterbatch. A molded article obtained by foam injection molding of the polyolefin resin composition according to one form of the present disclosure can be useful in satisfying uniform distribution and mechanical properties of foamed cells so that the molded article can be widely applied to parts for automobile interior/exterior materials, and also improving fuel efficiency of automobiles by achieving lightweight parts. 1. A foamable masterbatch prepared by melting and extruding a mixture comprising a polyolefin resin ,wherein the mixture comprises:(A) 10 to 89% by weight of a polyolefin resin;(B) 5 to 30% by weight of a chemical blowing agent;(C) 5 to 30% by weight of thermally expandable microcapsule; and(D) 1 to 30% by weight of an inorganic filler.2. The foamable masterbatch of claim 1 , wherein the polyolefin resin (A) comprises at least one selected from the group consisting of a random copolymer formed by polymerization of a comonomer selected from the group consisting of homo-polypropylene (Homo-PP) claim 1 , propylene claim 1 , ethylene claim 1 , butylene claim 1 , and octene claim 1 , a block copolymer formed by blending an ethylene-propylene rubber with polypropylene claim 1 , and a copolymer of polyethylene claim 1 , ethylene vinyl acetate claim 1 , and α-olefin.3. The foamable masterbatch of claim 1 , wherein the chemical blowing agent (B) comprises at least one selected from the group consisting of azodicarbon amide claim 1 , p claim 1 ,p′-oxybis( ...

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30-01-2020 дата публикации

POROUS FILM, SEPARATOR COMPRISING SAME, AND ELECTROCHEMICAL CELL

Номер: US20200035972A1
Принадлежит:

The present invention relates to a porous film including polyethylene and pore-forming particles, wherein the porous film has a structure including lamella and fibril, and the average size of pores located inside the porous film is larger than the average size of pores located on the surface of the porous film; a separator including the same; and an electrochemical cell. 1. A porous film comprisingpolyethylene and pore-forming particles, wherein the porous film has a structure comprising lamella and fibril and the average size of pores located inside the porous film is larger than the average size of pores located on the surface of the porous film.2. The porous film of claim 1 , wherein the polyethylene has density of greater than 0.95 g/cm.3. The porous film of claim 1 , wherein a ratio of the average size of pores located inside the porous film relative to the average size of pores located on the surface of the porous film (average size of inner pores/average size of surface pores) is 1.1 to 20.4. The porous film of claim 1 , wherein an average length of a minor axis of the pores located inside the porous film is 10 nm to 400 nm and an average length of a minor axis of the pores located on the surface of the porous film is 5 nm to 300 nm.5. The porous film of claim 1 , wherein an average thickness of a lamellar located inside the porous film is larger than an average thickness of the lamellar located on the surface of the porous film.6. The porous film of claim 5 , wherein a thickness of the lamellar located inside the porous film is 20 nm to 500 nm and a thickness of the lamellar located on the surface of the porous film is 10 nm to 200 nm.7. The porous film of claim 1 , wherein the porous film comprises the first pores formed by the pore-forming particles and the second pores formed between the lamellar of the polyethylene on the surface of the porous film claim 1 , and an average size of the first pores is larger than an average size of the second pores.8. The ...

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24-02-2022 дата публикации

ETHYLENE HOMOPOLYMER HAVING GOOD BARRIER PROPERTIES

Номер: US20220056248A1
Автор: Wang XiaoChuan
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

A polyethylene homopolymer composition comprises: a first ethylene homopolymer having a density, dof from 0.930 to 0.975 g/cm, a melt index, Iof from 0.01 to 10 g/10 min, and a molecular weight distribution, Mw/Mn of less than 2.5; and a second ethylene homopolymer having a density, dof from 0.945 to 0.980 g/cm, a melt index, Iof at least 1.0 g/10 min, and a molecular weight distribution, M/Mof less than 2.5; wherein melt index, Iof the second ethylene homopolymer is greater than the melt index, Iof the first ethylene homopolymer. The polyethylene homopolymer compositions which may be nucleated have a weight average molecular weight, Mof 75,000, a molecular weight distribution, M/Mof less than 4.0 and may be usefully employed in molding applications, such as, for example, in compression molded closures. 1. A polyethylene homopolymer composition , the polyethylene homopolymer composition comprising:{'sup': 1', '3', '1, 'sub': '2', '(1) 10 to 90 weight % of a first ethylene homopolymer having a density, dof from 0.930 to 0.975 g/cm, a melt index, Iof from 0.01 to 10 g/10 min, and a molecular weight distribution, Mw/Mn of less than 2.5; and'}{'sup': 2', '3', '2, 'sub': 2', 'w', 'n, '(2) 90 to 10 weight % of a second ethylene homopolymer having a density, dof from 0.945 to 0.980 g/cm, a melt index, Iof at least 1.0 g/10 min, and a molecular weight distribution, M/Mof less than 2.5;'}{'sub': 2', '2', 'w', 'w', 'n, 'sup': 2', '1, 'wherein melt index, Iof the second ethylene homopolymer is greater than the melt index, Iof the first ethylene homopolymer, and wherein the polyethylene homopolymer composition has a weight average molecular weight, Mof ≤75,000 and a molecular weight distribution, M/Mof less than 4.0.'}2. The polyethylene homopolymer composition of wherein the first ethylene homopolymer has a melt index claim 1 , Iof from 0.1 to 10 g/10 min.3. The polyethylene homopolymer composition of wherein the second ethylene homopolymer has a melt index claim 1 , Iof from ...

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24-02-2022 дата публикации

NEW FOAM WITH IMPROVED EXPANSION BEHAVIOUR WHEN USED IN THIN LAYERS

Номер: US20220056255A1
Принадлежит: SIKA TECHNOLOGY AG

A thermally expandable composition, including (a) at least one polymer P, cross-linkable by a free-radical initiator, and (b) at least one solid butyl rubber BRu, and (c) at least one free-radical initiator, and (d) at least one blowing agent, and (e) at least one tackifier TA, whereby the cured expanded composition has a volume increase compared to the uncured composition of less than 1300%. The thermally expandable composition is able to provide good expansion behaviour and good adhesion on metal surfaces and is especially suitable for baffle and/or reinforcement elements, e.g. in automotive manufacturing. 1. A thermally expandable composition , comprising(a) at least one polymer P, cross-linkable by a free-radical initiator, and(b) at least one solid butyl rubber BRu, whereby the composition comprises the solid butyl rubber with an amount of between 5 wt.-% and 16 wt.-%, based on the total weight of the composition, and(c) at least one free-radical initiator, and(d) at least one blowing agent, and(e) at least one tackifier TA,whereby the cured expanded composition has a volume increase compared to the uncured composition of less than 1300%, whereby the volume increase is determined using the DIN EN ISO 1183 method of density measurement (Archimedes principle).2. The thermally expandable composition of claim 1 , wherein the composition comprises the tackifier with an amount of between 12 wt.-% and 30 wt.-% claim 1 , based on the total weight of the composition.3. The thermally expandable composition of claim 1 , wherein the tackifier is a hydrocarbon resin.4. The thermally expandable composition of claim 1 , wherein the composition further comprises at least one process oil PO selected from the group consisting of aromatic oil claim 1 , naphthenic oil and poly(iso)butylene.5. The thermally expandable composition according to claim 4 , wherein the composition comprises the process oil PO with an amount of between 18 wt.-% and 35 wt.-% claim 4 , based on the total ...

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24-02-2022 дата публикации

COMPOSITIONS AND METHODS OF MAKING THERMOSET FOAMS FOR SHOE SOLES

Номер: US20220056257A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

A footwear article is provided. The footwear article includes a shoe sole. The shoe sole includes a crosslinked foam polyolefin elastomer having a density less than 0.88 g/cm, the crosslinked foam polyolefin elastomer including: a silane-grafted polyolefin elastomer, a silane-grafted olefin block copolymer, a polyolefin elastomer (POE), an olefin block copolymer (OBC), or a combination thereof; an ethylene vinyl acetate (EVA) copolymer; a crosslinker; a condensation catalyst; and a foaming agent. The shoe sole exhibits a compression set of from about 1.0% to about 50.0%, as measured according to ASTM D 395 (48 hrs @ 50° C.). 1. A crosslinked foam polyolefin elastomer composition prepared by the process comprising:mixing or dry blending a silane-grafted polyolefin elastomer, a crosslinker, an ethylene vinyl acetate copolymer, and a blowing agent, to form a crosslinkable polyolefin blend, andmolding the crosslinkable polyolefin blend to form the crosslinked foam polyolefin elastomer composition.2. The crosslinked foam polyolefin elastomer composition of wherein the silane-grafted polyolefin elastomer was prepared using a silane crosslinker selected from vinyltrimethoxy silane (VTMO) claim 1 , vinyltriethoxy silane (VTEO) and a combination thereof.3. The crosslinked foam polyolefin elastomer composition of wherein the ethylene vinyl acetate copolymer also has silicone oil.4. The crosslinked foam polyolefin elastomer composition of wherein the molding is compression molding or injection molding.5. The crosslinked foam polyolefin elastomer composition of claim 1 , wherein the crosslinker comprises one or more halogen molecules claim 1 , azo compounds claim 1 , carboxylic peroxyacids claim 1 , peroxyesters claim 1 , peroxyketals claim 1 , and peroxides.6. The crosslinked foam polyolefin elastomer composition of claim 1 , wherein the expansion ratio of the composition is from about 136% to about 178% claim 1 , and wherein the specific gravity of the composition is from ...

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12-02-2015 дата публикации

Method for manufacturing foam-molded article, and foam-molded article

Номер: US20150045468A1
Автор: Masaaki Onodera
Принадлежит: Kyoraku Co Ltd

A foam-molded article has high weldability to a polypropylene-based resin molded article, a high expansion ratio, and a predetermined level of impact resistance despite using inexpensive polyethylene-based resin. The foam-molded article includes a foamed and molded base material resin in which a first polyethylene-based resin, a second polyethylene-based resin, and a polypropylene-based resin are mixed. The first polyethylene-based resin has a long-chain branched structure and a density of 0.920 g/cm 3 or more. The second polyethylene-based resin is manufactured by a low pressure slurry method, and has a long-chain branched structure and a density of 0.920 g/cm 3 or less. The second polyethylene-based resin has a melt tensile force of 70 mN or more at 160° C. The polypropylene-based resin has a compounding ratio of 20% or more by weight of the base material resin.

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18-02-2016 дата публикации

Thermoplastic Rubber Composition and Molded Product Using Same

Номер: US20160046802A1
Принадлежит:

Disclosed is a thermoplastic rubber composition comprising, based on 100 parts by weight of a block terpolymer (A) of an aromatic vinyl compound and an alkene compound, 50 to 100 parts by weight of a paraffin oil (B), 30 to 70 parts by weight of an inorganic additive (C), 5 to 30 parts by weight of a polyolefin-based resin (D), and 30 to 70 parts by weight of an acryl-based resin (E). The hardness of the thermoplastic rubber composition may be freely adjusted and the thermoplastic rubber composition has a bonding strength of 2 to 4 N/mm as measured using a UTM according to a KS M 6518 peeling test method. Accordingly, bonding strength thereof to a thermoplastic resin is increased even without addition of an adhesive. 1. A thermoplastic rubber composition comprising , based on 100 parts by weight of a block terpolymer (A) of an aromatic vinyl compound and an alkene compound ,50 to 100 parts by weight of a paraffin oil (B);30 to 70 parts by weight of an inorganic additive (C);5 to 30 parts by weight of a polyolefin-based resin (D); and30 to 70 parts by weight of an acryl-based resin (E).2. The thermoplastic rubber composition according to claim 1 , wherein the terpolymer (A) is an A-B-A′ type claim 1 , wherein A and A′ blocks are hard segments and B block is a soft segment claim 1 , wherein the terpolymer (A) comprises the hard segments in an amount of 20 to 35% by weight and the soft segment in an amount of 65 to 80% by weight.3. The thermoplastic rubber composition according to claim 2 , wherein A and A′ blocks are aromatic vinyl-based polymers and B block is a conjugated diene-based polymer.4. The thermoplastic rubber composition according to claim 1 , wherein the terpolymer (A) is selected from the group consisting of a styrene-ethylene-butadiene-styrene (SEBS) block copolymer claim 1 , a styrene-ethylene-propylene-styrene (SEPS) block copolymer claim 1 , a styrene-isoprene-styrene (SIS) block copolymer claim 1 , a styrene-ethylene-isoprene-styrene (SEIS) block ...

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16-02-2017 дата публикации

METHOD OF PRODUCING SLIDING MATERIAL FOR WEATHER STRIPS

Номер: US20170044331A1
Принадлежит:

PP, an EPDM prior to crosslinking, and PE particles are fed into a twin screw extruder and melt-kneaded so that the EPDM is dynamically crosslinked, whereby a sliding material for weather strips formed of an olefin-based TPV in which the PE particles are dispersed is produced. The amount of the PE particles blended is 10 parts by mass to 90 parts by mass with respect to 100 parts by mass of the total amount of the PP and the EPDM. It is preferable that the PE particles have an average particle diameter of 30 μm to 200 μm before the feeding, and are micronized by the melt kneading to have an average particle diameter of 10 μm to 50 μm in the produced sliding material for weather strips. 1. A method of producing a sliding material for weather strips , the sliding material formed of an olefin-based TPV in which PE particles are dispersed , the method comprising feeding PP , an EPDM prior to crosslinking , and PE particles into a twin screw extruder and melt-kneading the PP , the EPDM , and the PE particles to dynamically crosslink the EPDM.2. The method of producing a sliding material for weather strips according to claim 1 , wherein the PE particles are blended in an amount of 10 parts by mass to 90 parts by mass with respect to 100 parts by mass of the total amount of the PP and the EPDM.3. The method of producing a sliding material for weather strips according to claim 1 , wherein the PE particles have an average particle diameter of 30 μm to 200 μm before the feeding claim 1 , and are micronized by the melt-kneading to have an average particle diameter of 10 μm to 50 μm in a produced sliding material for weather strips.4. The method of producing a sliding material for weather strips according to claim 1 , wherein a material for the PE particles is an ultra-high molecular weight PE.5. The method of producing a sliding material for weather strips according to claim 1 , wherein claim 1 , in the sliding material for weather strips claim 1 , 30 parts by mass or less of ...

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16-02-2017 дата публикации

ROTOMOLDED ARTICLES

Номер: US20170044357A1
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

This disclosure relates to rotomolded articles, having a wall structure, where the wall structure contains at least one layer containing an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Y) greater than 0; total catalytic metal ≧3.0 ppm; ≧0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (X) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm, a polydispersity (M/M) from about 2 to about 25 and a CDBIfrom about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation. 1105-. (canceled)106. A rotomolded article comprising a wall structure; (I) a first ethylene interpolymer;', '(II) a second ethylene interpolymer, and;', '(III) optionally a third ethylene interpolymer;, 'wherein said wall structure comprises at least one layer comprising an ethylene interpolymer product comprising [{'br': None, 'sup': 'A', 'sub': a', 'b', 'n, 'i': 'l', '(L)M(P)(Q)'}, {'sup': 'A', 'wherein Lis selected from the group consisting of unsubstituted cyclopentadienyl, substituted cyclopentadienyl, unsubstituted indenyl, substituted indenyl, unsubstituted fluorenyl and substituted fluorenyl;'}, 'M is a metal selected from the group consisting of titanium, hafnium and zirconium;', 'Pl is a phosphinimine ligand;', {'sub': 1-10', '1-10', '5-10', '1-18', '1-8', '6-10', '1-8', '1-8, 'Q is independently selected from the group consisting of a hydrogen atom, a halogen atom, a Chydrocarbyl radical, a Calkoxy radical and a Caryl oxide radical; wherein each of said hydrocarbyl, alkoxy, and aryl oxide radicals may be ...

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15-02-2018 дата публикации

Masterbatches for preparing a composite material based on semi-crystalline polymer with enhanced conductivity properties, process and composite materials produced therefrom

Номер: US20180044485A1
Принадлежит:

The present invention relates to a masterbatch for use in a process of preparing a composite material comprising a blend of a first semi-crystalline polymer with at least 5 wt % carbon nanotubes. Good dispersion of the carbon nanotube is obtained within the masterbatch and evidenced by the blending of the masterbatch with a second semi-crystalline polymer miscible with the first one in respective proportions to obtain a composite material containing about 1 wt % of carbon nanotubes wherein said composite material yields an agglomerate area fraction U % lower than 2 and a surface resistivity lower than 10ohm/sq. 114.-. (canceled)15. A masterbatch for use in a process of preparing a composite material , the masterbatch comprising a blend of a first semi-crystalline polymer having a melting temperature Tm1 as measured according to ISO11357-3 , with carbon nanotubes , wherein the carbon nanotubes content being of at least 5 wt % of carbon nanotubes based on the total weight of the masterbatch as determined according to ISO11358 , the masterbatch having a high load melt index HLMI ranging from 100 g/10 min to 1000 g/10 min as determined according to ISO1133 under a load of 21.6 kg;characterised in that the first semi-crystalline polymer is selected from syndiotactic polypropylene and isotactic polypropylene; an agglomerate area fraction U % lower than 2%, as determined in accordance with ASTM D-2663-14,', {'sup': '5', 'a surface resistivity lower than 10ohm/sq, as determined according to CEI60167.'}], 'and in that the masterbatch presents a dispersion of the carbonanotubes as determined by the following characterization test: the masterbatch is blended with a second semi-crystalline polymer in respective proportions to obtain a composite material containing from 0.9 wt % to 1.1 wt, with respect to the total weight of the composite material as determined according to ISO11358, wherein the second semi-crystalline polymer is selected to be miscible with the first ...

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03-03-2022 дата публикации

MULTILAYER FILM

Номер: US20220063253A1
Принадлежит:

Multilayer film which comprises a core layer (C) and two outer layers (0-1, 0-2) sandwiching the core layer, wherein (i) the core layer (C) comprises 90 to 100% by weight of a first bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer having a density between >925 kg/mand 970 kg/mwith respect to the total weight of the layer, (ii) two outer layers (0-1) and (0-2) comprise (ii-1) the bimodal terpolymer as defined for the core layer (C) and (ii-2) a second bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer having a density between >910 kg/mand <925 kg/m. 1. Multilayer film , preferably for heavy duty shipping sacks , which comprises a core layer (C) and two outer layers (O-1 , O-2) sandwiching the core layer , wherein{'sub': 6', '12, 'sup': 3', '3, '(i) the core layer (C) comprises 90 to 100% by weight of a first bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer having a density between >925 kg/mand 970 kg/mwith respect to the total weight of the layer,'}(ii) two outer layers (O-1) and (O-2) comprise(ii-1) the bimodal terpolymer as defined for the core layer (C) and{'sub': 6', '12, '(ii-2) a second bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer having a density between >910 kg/m3 and <925 kg/m3.'}2. Multilayer film according to wherein the core layer (C) comprises a first bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer claim 1 , which can comprise(A-1) a low molecular weight homopolymer of ethylene and(A-2) a high molecular weight terpolymer of ethylene, 1-butene and a C6-C12-alpha-olefin3. Multilayer film according to or claim 1 , wherein the C6-C12-alpha-olefins is selected from the group of 1-hexene claim 1 , 4-methyl-1-pentene claim 1 , 1-octene and 1-decene.4. Multilayer film according to or wherein the first bimodal ethylene/1-butene/C-C-alpha-olefin terpolymer comprises a low molecular weight fraction of a homopolymer of ethylene and a high molecular weight fraction of a terpolymer of ethylene claim 1 , 1-butene and a C-C-alpha-olefin claim ...

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14-02-2019 дата публикации

ROOFING MEMBRANES, COMPOSITIONS, AND METHODS OF MAKING THE SAME

Номер: US20190045881A1
Принадлежит: COOPER-STANDARD AUTOMOTIVE INC.

A roofing membrane and a method of making the same is provided. The roofing membrane includes a top layer having a flame retardant and a first silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm; a scrim layer; and a bottom layer having a flame retardant and a second silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm. The top and bottom layers of the roofing membrane both exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.). 1. A roofing membrane comprising:{'sup': '3', 'a top layer comprising a flame retardant and a first silane-crosslinked polyolefin elastomer having a density less than 1.45 g/cm;'}an optional scrim layer; and{'sup': '3', 'a bottom layer comprising a flame retardant and a second silane-crosslinked polyolefin elastomer having a density less than 1.45 g/cm.'}2. The roofing membrane of claim 1 , wherein the flame retardant comprises a magnesium hydroxide and/or an aluminum hydroxide from about 20 wt % to about 70 wt %.3. The roofing membrane of claim 1 , wherein the first and second silane-crosslinked polyolefin elastomers both exhibit a crystallinity of from about 5% to about 25%.4. The roofing membrane of claim 1 , wherein the first and second silane-crosslinked polyolefin elastomers have a glass transition temperature of from about −75° C. to about −25° C.5. The roofing membrane of claim 1 , wherein the first and second silane-crosslinked polyolefin elastomers each comprise a first polyolefin having a density less than 0.86 g/cm claim 1 , a second polyolefin claim 1 , a silane crosslinker claim 1 , a grafting initiator claim 1 , and a condensation catalyst.6. The roofing membrane of claim 5 , wherein the silane crosslinker comprises a vinyltrialkoxy silane from about 1 wt % to about 4 wt %.7. The roofing membrane of claim 5 , wherein the condensation catalyst comprises a sulfonic ester catalyst and/or a tin catalyst from about 1 wt % to ...

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03-03-2022 дата публикации

POLYETHYLENE HOMOPOLYMER COMPOSITIONS HAVING GOOD BARRIER PROPERTIES

Номер: US20220064417A1
Автор: Wang XiaoChuan
Принадлежит: NOVA CHEMICALS (INTERNATIONAL) S.A.

A polyethylene homopolymer composition comprises: a first ethylene homopolymer having a density, dof from 0.943 to 0.975 g/cm, a melt index, Iof from 0.01 to 10 g/10 min, and a molecular weight distribution, Mw/Mn of less than 3.0; and a second ethylene homopolymer having a density, dof from 0.950 to 0.985 g/cm, a melt index, Iof at least 500 g/10 min, and a molecular weight distribution, M/Mof less than 3.0; wherein the ratio of the melt index, Iof the second ethylene homopolymer to the melt index, Iof the first ethylene homopolymer is at least 50. The polyethylene homopolymer compositions which may be nucleated have a weight average molecular weight, Mof ≤75,000, a high load melt index, Iof at least 200 g/10 min, a molecular weight distribution, M/Mof from 4.0 to 12.0 and may be usefully employed in molding applications, such as, for example, in compression molded closures.

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25-02-2016 дата публикации

LUMPS AND COMPOSITION

Номер: US20160053080A1
Принадлежит: MITSU CHEMICALS, INC.

[Objective] 1. A lump comprising 100 parts by mass of ethylene copolymer (X) which comprises a structural unit derived from ethylene [A] , a structural unit derived from α-olefin [B] having 3 to 20 carbon atoms , and a structural unit derived from at least one component [C] selected from the group consisting of (c-1) polyene and (c-2) cyclic olefin , and which satisfies (1) to (3) below , and 750 to 2 ,000 parts by mass of plasticizer (Y); wherein(1) the structural unit derived from ethylene [A] represents 50 to 90 mol % in 100 mol % of a total of the structural unit derived from component [A], the structural unit derived from component [B], and the structural unit derived from component [C] in copolymer (X),(2) the structural unit derived from component [C] represents 1.0 to 5.0 mol % in 100 mol % of a total of the structural unit derived from component [A], the structural unit derived from component [B], and the structural unit derived from component [C] in copolymer (X), and(3) an intrinsic viscosity [η] of ethylene copolymer (X) measured in a decalin solution of 135° C. is 7.8 to 13.0 dl/g.2. The lump according to claim 1 , wherein an intrinsic viscosity [q] of plasticizer (Y) measured in a decalin solution of 135° C. is not more than 0.2 dl/g.3. The lump according to claim 1 , which has a mass of 1 kg to 100 kg.4. The lump according to claim 1 , wherein the lump is bale.5. A production method of a rubber composition comprising melt kneading the lump described in claim 1 , a rubber claim 1 , and compounding agents as needed.6. The production method of a rubber composition according to claim 5 , wherein the rubber comprises at least one type of ethylene α-olefin non-conjugated polyene copolymer.7. A composition (Z) comprising 100 parts by mass of ethylene copolymer (X) which comprises a structural unit derived from ethylene [A] claim 5 , a structural unit derived from a-olefin [B] having 3 to 20 carbon atoms claim 5 , and a structural unit derived from at least ...

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25-02-2021 дата публикации

Films And Methods Of Making The Same

Номер: US20210054179A1
Принадлежит:

Disclosed are films, and methods of making such films, the films comprising a first polyethylene and a hydrocarbon resin, which can provide improved friction performance. The hydrocarbon resin may be incorporated in neat form or as a blend, for instance with a second polyethylene that may be the same as or different from the first polyethylene. 1. A film , comprising a layer comprising:{'sup': '3', 'sub': 2.16', '21.6', '2.16', 'w', 'z', 'w', 'z', 'w, '(a) a first polyethylene, the first polyethylene having (i) a density of about 0.900 to about 0.925 g/cm, (ii) a melt index (MI), I, of from about 0.1 to about 10.0 g/10 min, (iii) a melt index ratio (MIR), I/I, of from about 15 to about 50, (iv) a weight average molecular weight (M) of from about 20,000 to about 200,000; (v) a molecular weight distribution (MWD) of from about 2.0 to about 5.0; and (vi) a z-average molecular weight (M) to weight average molecular weight (M) (M/M) ratio of from about 1.7 to about 3.5; and'}(b) from about 5 to about 20 wt % of a hydrocarbon resin, based on total weight of polymer in the layer, the hydrocarbon resin comprising an aliphatic hydrocarbon resin, a hydrogenated aliphatic hydrocarbon resin, an aromatic hydrocarbon resin, a hydrogenated aromatic hydrocarbon resin, a cycloaliphatic hydrocarbon resin, a hydrogenated cycloaliphatic hydrocarbon resin, a polyterpene resin, a terpene-phenol resin, a rosin ester resin, a rosin acid resin, or a combination thereof;wherein the film has at least one of the following properties: (i) an Elmendorf tear of at least about 15% higher in the Machine Direction (MD); (ii) an Elmendorf tear of at least about 25% higher in the Transverse Direction (TD); (iii) a dart impact of at least about 4% higher; (iv) a static coefficient of friction (COF) of at least about 3% lower; and (v) a dynamic COF of at least about 40% lower, compared to that of a film free of the hydrocarbon resin but otherwise identical in terms of film formulation, thickness, and ...

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23-02-2017 дата публикации

SCENT EXTENDED ANIMAL-REPELLING SYNTHETIC RESIN COMPOSITION

Номер: US20170051137A1
Принадлежит:

An article that repels animals includes a synthetic resin composition. The synthetic resin composition includes a first thermoplastic polymer. A master blend is combined with the first thermoplastic polymer. The master blend includes a second thermoplastic polymer. At least one odorant compound is selected from the group consisting of a salicylic acid ester, menthol, corn mint oil, eucalyptus oil, camphor oil, and combinations thereof. At least one scent extender compound includes at least one cyclodextrin compound, wherein a ratio by weight of the second thermoplastic polymer to a combination of the odorant compound and the scent extender compound is about 2:1. A method for forming a master blend, a method for forming a synthetic resin composition, and an article that repels animals including a synthetic resin composition are also described. 1. An article that repels animals , comprising a synthetic resin composition including:a first thermoplastic polymer; anda master blend combined with said first thermoplastic polymer, said master blend including a second thermoplastic polymer, at least one odorant compound selected from the group consisting of a salicylic acid ester, menthol, corn mint oil, eucalyptus oil, camphor oil, and combinations thereof, and at least one scent extender compound comprising at least one cyclodextrin compound,wherein a ratio by weight of said second thermoplastic polymer to a combination of said odorant compound and said scent extender compound is about 2:1.2. The article of claim 1 , wherein said scent extender compound comprises at least one of: alpha-cyclodextrin claim 1 , beta-cyclodextrin claim 1 , hydroxypropyl-beta-cyclodextrin claim 1 , and methyl-beta-cyclodextrin.3. The article of claim 1 , comprising a synthetic resin composition at between about 10 parts per million and about 15 claim 1 ,000 parts per million by weight based on a total weight of said synthetic resin composition.4. The article of claim 1 , wherein said ...

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10-03-2022 дата публикации

CURABLE COMPOSITIONS COMPRISING UNSATURATED POLYOLEFINS

Номер: US20220073540A1
Принадлежит:

The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking. 1. A curable composition comprising (A) a polyolefin component comprising an unsaturated polyolefin of the formula ALthat has a viscosity less than 100 ,000 cP and (B) a curing component comprising a cross-linking agent , wherein:{'sup': '1', 'Lis a polyolefin;'}{'sup': 1', '1', '1', '1', '1', '1', '1', '1', '1, 'sub': 2', '2', '2', '2, 'Ais selected from the group consisting of a vinyl group, a vinylidene group of the formula CH═C(Y)—, a vinylene group of the formula YCH═CH—, a mixture of a vinyl group and a vinylene group of the formula YCH═CH—, a mixture of a vinyl group and a vinylidene group of the formula CH═C(Y)—, a mixture of a vinylidene group of the formula CH═C(Y)— and a vinylene group of the formula YCH═CH—, and a mixture of a vinyl group, a vinylidene group of the formula CH═C(Y)—, and a vinylene group of the formula YCH═CH—; and'}{'sup': '1', 'sub': 1', '30, 'Yat each occurrence independently is a Cto Chydrocarbyl group.'}2. A curable composition comprising (A) a polyolefin component comprising a telechelic polyolefin of the formula ALLAthat has a viscosity less than 100 ,000 cP and (B) a curing component comprising a cross-linking agent , wherein:{'sup': '1', 'Lis a polyolefin;'}{'sup': 1', '1', '1', '1', '1', '1', '1', '1', '1, 'sub': 2', '2', '2', '2, 'Ais selected from the group consisting of a vinyl group, a vinylidene group of the formula CH═C(Y)—, a vinylene group of the formula YCH═CH—, a mixture of a vinyl group and a vinylene group of the formula YCH═CH—, a mixture of a vinyl group and a vinylidene group of the formula CH═C(Y)—, a mixture of a vinylidene group of the formula CH═C(Y)— and a vinylene group of the formula YCH═CH—, and a mixture of a vinyl group, a vinylidene group of the formula CH═C(Y)—, and a ...

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03-03-2016 дата публикации

MOLDED BODY OF COMPOSITE RESIN FOAM

Номер: US20160060413A1
Принадлежит: SEKISUI PLASTICS CO., LTD.

A composite resin expanded molded article comprising: 100 parts by mass of an ethylene-vinyl acetate copolymer; and 100 to 400 parts by mass of a polystyrene-based resin, wherein the composite resin expanded molded article has an average cell diameter D of 100 to 500 μm and an average cell membrane thickness T of 1 to 5 μm. 1. A composite resin expanded molded article comprising: 100 parts by mass of an ethylene-vinyl acetate copolymer; and 100 to 400 parts by mass of a polystyrene-based resin , wherein said composite resin expanded molded article has an average cell diameter D of 100 to 500 μm and an average cell membrane thickness T of 1 to 5 μm.2. The composite resin expanded molded article according to claim 1 , wherein said composite resin expanded molded article does not include a flame retardant.3. The composite resin expanded molded article according to claim 1 , wherein said average cell diameter D and said average cell membrane thickness T satisfy a relationship of 200≦D×T≦1 claim 1 ,100.4. The composite resin expanded molded article according to claim 1 , wherein a content of aliphatic hydrocarbons having 3 to 6 carbons in said composite resin expanded molded article is 0.5% by mass or less. The present invention relates to a molded body of composite resin foam (composite resin expanded molded article). More specifically, the present invention relates to a composite resin expanded molded article having superior slow-burning properties and thermal resistance.In general, although expanded molded articles of a polyethylene-based resin have high elasticity, and superior oil resistance and impact resistance, they have the disadvantages of low rigidity and weak compression strength. On the other hand, expanded molded articles of a polystyrene-based resin, although having superior rigidity, have the disadvantage of being brittle.Thus, in order to complement these disadvantages, expanded molded articles of a composite resin of a polyethylene-based resin and a ...

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03-03-2016 дата публикации

ALIPHATICALLY MODIFIED ROSIN RESIN AND TACKIFIED ADHESIVE

Номер: US20160060495A1
Принадлежит:

Aliphatically modified rosin resins are prepared by reacting rosin esters with aliphatic monomers. These aliphatically modified rosin resins are compatible with metallocene catalyzed polyolefins and other aliphatic base polymers and are used as tackifiers in combination with metallocene catalyzed polyolefins and other aliphatic base polymers to form adhesive compositions for hot melt and pressure sensitive applications. 1. A method of producing an aliphatically modified rosin resin comprising the steps of:esterifying a rosin by reaction with a polyol to produce a rosin polyol ester andreacting said rosin polyol ester with a monomer material to produce said aliphatically modified rosin resin,{'sub': 6', '22', '6', '22', '4', '22, 'wherein said monomer material is selected from: Cto Calpha-olefins; vinyl-terminated monomers; Cto Calpha-beta unsaturated esters and acids; fumaric, maleic, or acrylic esters or diesters of Cto Caliphatic chains or rings; and combinations thereof.'}2. The method of wherein said rosin is reacted with said polyol in step (a) in the presence of a catalyst effective for 4+2 additions and other electrophilic substitutions.3. The method of wherein said catalyst is: Bentonite Clay (F-100).4. The method of wherein said monomer material is a Cto Calpha-olefin.5. The method of wherein said monomer material is 1-decene.6. The method of wherein said monomer material is a branched claim 1 , cyclic claim 1 , or straight chained Cto Cvinyl ether.7. The method of wherein said monomer material is ethyl vinyl ether claim 1 , isobutyl vinyl ether claim 1 , n-butyl vinyl ether claim 1 , tert-butyl vinyl ether claim 1 , cyclohexyl vinyl ether claim 1 , dodecyl vinyl ether claim 1 , octadecyl vinyl ether claim 1 , or 2-ethyl hexyl vinyl ether.8. An aliphatically modified rosin resin produced by the method of .9. An aliphatically modified rosin resin produced by the method of .10. An aliphatically modified rosin resin produced by the method of .11. An ...

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01-03-2018 дата публикации

MASTERBATCH COMPRISING COLORANT PARTICLES AND A POLYOL POLY(HYDROXY FATTY ACID) ESTER AS DISPERSING AGENT

Номер: US20180057643A1
Автор: Norn Viggo Creemers
Принадлежит: EINAR A/S

The present invention relates to a masterbatch comprising colorant particles, a polyol poly(hydroxy fatty acid) ester dispersing agent and a carrier resin. The masterbatch is used for coloring thermoplastic polymer compositions. The present invention also relates to a method for producing said masterbatch, a colored thermoplastic polymer composition comprising said masterbatch and colored thermoplastic products formed of said colored thermoplastic composition. 1. A masterbatch for coloring of thermoplastic polymer compositions , said masterbatch comprising a colorant in a total amount of 10-50% (w/w) relative to the total weight of the masterbatch , a dispersing agent in a total amount of 0.5-20% (w/w) relative to the total weight of the masterbatch and a carrier resin in a total amount of 30-80% (w/w) relative to the total weight of the masterbatch , wherein the dispersing agent is a polyol poly(hydroxy fatty acid) ester (pphe dispersing agent) wherein the pphe dispersing agent is poly(glycerol) poly(ricinoleate) ester (PGPR) in which the esterified poly(ricinoleate) has an average degree of polymerization of at least 5 and in which the esterified polyglycerol of the PGPR has an average degree of polymerization of 2-5.2. (canceled)3. (canceled)4. The masterbatch according to claim 1 , wherein the total amount of pphe dispersing agent in the masterbatch is 3-10% (w/w) relative to the total weight of the masterbatch.5. (canceled)6. The masterbatch according to claim 1 , wherein the colorant is a pigment composition comprising organic claim 1 , metalorganic and/or inorganic particles claim 1 , where said particles are insoluble in polymers.7. (canceled)8. The masterbatch according to claim 1 , wherein the total amount of colorant in the masterbatch is 20-50% (w/w) relative to the total weight of the masterbatch.9. The masterbatch according to claim 1 , wherein the carrier resin is selected from the group consisting of polyolefins claim 1 , acrylic resins claim 1 , ...

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02-03-2017 дата публикации

RECONSTITUTED COMPOSITE MATERIALS DERIVED FROM WASTE MADE BY SOLID STATE PULVERIZATION

Номер: US20170058094A1
Автор: Frenkel Stuart D.
Принадлежит:

A method of making polymeric composite particles from polymeric scrap material, virgin polymeric material, or mixtures thereof and glass particles by subjecting a mixture of the polymeric particles and glass particles to a solid state shear pulverization and in-situ polymer compatibilization. 1. A method for preparing reconstituted composite particles , comprising the steps of:a) providing a mixture of polymer material and glass material;b) effecting a chemical change to said mixture by application of mechanical energy thereto through solid state shear pulverization in the presence of cooling sufficient to maintain said mixture in the solid state during said pulverization to form reconstituted composite particles; andc) discharging said composite particles.2. A method for manufacturing of a powder of reconstituted composite material from a supply of polymeric material and glass material , comprising the steps of:a) providing a mixture of polymeric material and glass material to form a composite mixture;b) introducing said composite mixture into a pulverization device having an inlet for said composite mixture, means for pulverizing said composite mixture to effect chemical change by means of solid state shear pulverization in the presence of cooling sufficient to maintain solely in the solid state during the pulverization, an outlet for said pulverized composite material, and means for cooling the temperature of said composite material between said inlet and outlet;c) cooling said composite material to maintain said composite material in the solid state without melting within the pulverization device;d) pulverizing said solid state composite material within the pulverization device to chemically alter said composite material; ande) discharging said resulting composite pulverized powder from said outlet.3. A product produced by the method of .4. The method of claim 1 , wherein the solid state shear pulverization is effected by a co-rotating screw pulverizer.5. The ...

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02-03-2017 дата публикации

GLASS FIBER-REINFORCED POLYAMIDE 66 RESIN COMPOSITION WITH HIGH TENSILE STRENGTH AND METHOD OF MANUFACTURING THE SAME

Номер: US20170058104A1
Принадлежит:

A glass fiber-reinforced polyamide 66 resin composition with a high tensile strength of 260 MPa or more and a method of manufacturing the same are provided. The method of manufacturing the composition includes that 27.2 to 49% by weight of a polyamide 66 resin, 0.2 to 2% by weight of a dye mixture, 0.2 to 2% by weight of a compatibilizer, 0.1 to 3% by weight of an antioxidant, 0.1 to 3% by weight of a lubricant and 50 to 70% by weight of a glass fiber chopped strand are mixed in a twin screw extruder, the materials are extruded in the form of a strand by an extrusion die, and cooled to obtain a pellet-type glass fiber-reinforced polyamide 66 resin composition. The glass fiber-reinforced polyamide 66 resin composition is suitable for vehicular engine mounts due to excellent mechanical strength, and for parts requiring physical properties. 1. A glass fiber-reinforced polyamide 66 resin composition with a high tensile strength of 260 MPa or more comprising:27.2 to 49% by weight of a polyamide 66 resin:0.2 to 2% by weight of a dye mixture for coloring;0.2 to 2% by weight of a compatibilizer for improving physical properties;0.1 to 3% by weight of an antioxidant comprising 1,3,5-tris(2,6-dimethyl-3-hydroxy-4-tert-butylbenzyl)isocyanurate,0.1 to 3% by weight of a lubricant comprising an ethylene bis stearamide wax; and50 to 70% by weight of a glass fiber chopped strand,wherein the compatibilizer is a zinc-based complex, and the zinc-based complex comprises at least one of zinc soap, fatty acid zinc, zinc oxide, zinc stearate, zinc borate, zinc laurate, zinc tartrate, zinc oleate, zinc sulfate, and a mixture of at least a part thereof,the polyamide 66 resin has a relative viscosity of 1.5 to 3.5 in a sulfuric acid solution,the glass fiber has a mean particle diameter of 6 μm to 15 μm and a mean length of 2 mm to 12 mm,the dye mixture is a mixture of 10 to 70% by weight of a dye and 30 to 90% by weight of polyethylene, andthe dye comprises carbon black or nigrosine.2. A ...

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