19-12-2013 дата публикации
Номер: US20130338265A1
To provide a curable epoxy resin composition that exhibits excellent fluidity during molding without having adverse effects on the physical properties of the cured material. A curable epoxy resin composition, containing (I) a curable epoxy resin, and (II) an epoxy functional group- and aromatic hydrocarbon group-containing organopolysiloxane having an epoxy equivalent weight of 3,000 or lower, a content of aromatic hydrocarbon groups of 45 to 80% by weight (mass), and a glass transition point of less than 0° C. 1. A curable epoxy resin composition comprising:(I) a curable epoxy resin; and(II) an epoxy functional group- and aromatic hydrocarbon group-containing organopolysiloxane having an epoxy equivalent weight of 3,000 or lower, a content of aromatic hydrocarbon groups of 45 to 80% by weight (mass), and a glass transition point of less than 0° C.2. The curable epoxy resin composition according to claim 1 , wherein a proportion of epoxy functional groups among organic groups bound to silicon atoms in a molecule of the organopolysiloxane is 0.1 to 40 mol %.3. The curable epoxy resin composition according to claim 1 , wherein a proportion of aromatic hydrocarbon groups among organic groups bound to silicon atoms in a molecule of the organopolysiloxane is 40 mol % or higher.4. The curable epoxy resin composition according to claim 1 , wherein the ingredient (II) is a branched organopolysiloxane expressed by the following average unit formula:{'br': None, 'sup': 1', '2', '3', '4', '5', '6, 'sub': 1/2', 'a', '2/2', 'b', '3/2', 'c, '(RRRSiO)(RRSiO)(RSiO)\u2003\u2003(1)'}wherein:{'sup': 1', '2', '3', '4', '5', '6', '1', '2', '3', '4', '5', '6', '1', '2', '3', '4', '5', '6, 'R, R, R, R, R, and Rrespectively and independently represent a monovalent hydrocarbon group or epoxy functional group, where at least one of R, R, R, R, R, and Ris an epoxy functional group, at least one of R, R, R, R, R, and Ris a monovalent aromatic hydrocarbon group; and'}“a” is 0 to 0.2, “b” is a ...
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