26-07-2018 дата публикации
Номер: US20180212074A1
The present invention discloses a polymer containing 1,2,5-benzoselenadiazole-N—R-5,6-dicarboxylic acid imide, and a preparation method and use thereof. The conjugated polymer prepared by the present invention has fluorescence, and a relatively wide absorption of sunlight, and thus it can be used for manufacture of an active layer for a polymer light-emitting diode device, a polymer field-effect transistor and a polymer solar cell. 3. The polymer containing 1 claim 2 ,2 claim 2 ,5-benzoselenadiazole-N—R-5 claim 2 ,6-dicarboxylic acid imide according to claim 2 , wherein said R claim 2 , said Rand said Rare linear alkyl chains claim 2 , branched alkyl chains or cyclic alkyl chains having 1 to 30 carbon atoms.4. A method of preparing the polymer containing 1 claim 1 ,2 claim 1 ,5-benzoselenadiazole-N—R-5 claim 1 ,6-dicarboxylic acid imide according to claim 1 , comprising the following steps:{'sub': 1', '1', '1', '1', '1', '1', '1, '(1) using 2,5-dithieno-3,4-thiazole as a parent for reacting with dimethyl acetylenedicarboxylate to obtain 4,7-bis(thien-2-yl)benzo[c][1,2,5]thiadiazole-5,6-dimethyl isophthalate, obtaining 4,7-bis(thien-2-yl)benzo[c][1,2,5]thiadiazole-5,6-dicarboxylic acid by performing a hydrolyzation to said 4,7-bis(thien-2-yl)benzo[c][1,2,5]thiadiazole-5,6-dimethyl isophthalate, reacting said 4,7-bis(thien-2-yl)benzo[c][1,2,5]thiadiazole-5,6-dicarboxylic acid with acetic anhydride to obtain 4,8-bis(thien-2-yl)isobenzofuran[5,6-C][1,2,5]thiadiazole-5,7-diketone, reacting said 4,8-bis(thien-2-yl)isobenzofuran[5,6-C][1,2,5]thiadiazole-5,7-diketone with alkylamine to obtain 6-R-4,8-bis(thien-2-yl)-5H-[1,2,5]thiadiazolo[3,4-f]isoindole-5,7(6H)-diketone, obtaining 5,6-diamino-4,7-bis(thien-2-yl)-N—R-isoindole-1,3-diketone by performing a reduction to said 6-R-4,8-bis(thien-2-yl)-5H-[1,2,5]thiadiazolo[3,4-f]isoindole-5,7(6H)-diketone with an iron powder, reacting said 5,6-diamino-4,7-bis(thien-2-yl)-N—R-isoindole-1,3-diketone with selenium dioxide to obtain ...
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