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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 2904. Отображено 100.
07-06-2012 дата публикации

Process for polymerizing lactam

Номер: US20120141791A1
Принадлежит: BASF SE

The present invention relates to a novel process for the anionic polymerization of lactam monomers.

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21-06-2012 дата публикации

Air drying resin and composition

Номер: US20120157617A1
Принадлежит: Individual

Air drying resins and methods for preparing and using the same are provided which are both water- and solvent-soluble and have a combination of properties desirable for different types of applications, for example as being suitable for coating compositions. The resins include a polyesteramide prepared from: A) at least one anhydride chosen from the list containing succinic, glutaric, citraconic, itaconic or maleic anhydride or a combination of any of them, and B) at least one alkanol-amine, and C) at least one fatty acid, wherein the fatty acid is incorporated in the resin in an amount equivalent to an oil-length between 15 and 40%.

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22-11-2012 дата публикации

Barrier and priming compositions

Номер: US20120296030A1
Автор: Chih-Chung Hsu
Принадлежит: 3M Innovative Properties Co

The present application is directed to a primer composition comprising a fluorinated polymer and a nitrogen containing polymer. In some embodiments, the fluorinated polymer is a copolymer. In some embodiments, the fluorinated polymer is chlorinated. In some embodiments, the nitrogen containing polymer is amino functional, and in some embodiments, the nitrogen containing polymer is amide functional.

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29-11-2012 дата публикации

Titanium/titanium alloy-and-resin composite and method for making the same

Номер: US20120301690A1

A titanium/titanium alloy-and-resin composite includes a titanium/titanium alloy substrate, a nano-porous oxide film formed on the substrate, and resin compositions coupled to the surface of the nano-porous oxide film. The nano-porous oxide film has nano pores and includes at least two layers of different three dimensional meshed structures. The resin compositions contain crystalline thermoplastic synthetic resins. A method for making the titanium/titanium alloy-and-resin composite is also described.

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28-03-2013 дата публикации

Process for producing polyamides via anionic polymerization

Номер: US20130079465A1
Принадлежит: BASF SE

The present invention relates to a process for producing polyamides, preferably crosslinked polyamides, via anionic polymerization of lactams in the presence of an anionic catalyst and of a caprolactam-capped polyisocyanate, where said isocyanate comprises more than 3.5 capped isocyanate groups.

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11-04-2013 дата публикации

Fibers of Polymer-Wax Compositions

Номер: US20130089747A1
Принадлежит: Procter and Gamble Co

Disposable article that include fibers formed from compositions comprising thermoplastic polymers and waxes are disclosed, where the wax is dispersed throughout the thermoplastic polymer.

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09-05-2013 дата публикации

PRODUCTION PROCESS OF POLYIMIDE FILM LAMINATE, AND POLYIMIDE FILM LAMINATE

Номер: US20130115473A1
Принадлежит: UBE INDUSTRIES, LTD.

A process for producing a polyimide film laminate includes a substrate and a polyimide film, which includes forming a coating film including a polyamic acid solution composition on the surface of a substrate to produce a laminate composed of the substrate and the polyamic acid solution composition, heating the laminate composed of the substrate and the polyamic acid solution composition at a temperature ranging from at least 150 to 200° C. for 10 minutes or longer, and then heating the heated laminate at a temperature up to 400 to 550° C. 2. The process as claimed in claim 1 , wherein logarithmic viscosity of the polyamic acid in the polyamic acid solution composition is 2.0 dL/g or less.3. The process as claimed in claim 1 , wherein thickness of the obtained polyimide film is 40 μm or less.4. The process as claimed in claim 1 , wherein another material is further stacked on the polyimide film surface at the polyimide film laminate to obtain a polyimide film laminate having the substrate claim 1 , the polyimide film and the another material.5. The process as claimed in claim 4 , wherein the substrate is separated from the polyimide film laminate having the substrate claim 4 , the polyimide film and the another material to obtain a polyimide film laminate having the polyimide and the another material.6. A polyimide film laminate having a substrate and a polyimide film obtained by the process as claimed in .7. A polyimide film laminate obtained by further stacking another material on the polyimide film surface of the polyimide film laminate as claimed in .8. A laminate of a polyamide film and another material obtained by separating the substrate from the polyimide film laminate as claimed in .9. The process as claimed in claim 2 , wherein thickness of the obtained polyimide film is 40 μm or less.10. The process as claimed in claim 2 , wherein another material is further stacked on the polyimide film surface of the polyimide film laminate to obtain a polyimide film ...

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09-05-2013 дата публикации

COMPOSITE POLYAMIDE ARTICLE

Номер: US20130115836A1
Принадлежит: Rhodia Operations

The use of a polyamide modified by hydroxyl aromatic compounds used to impregnate reinforcement materials assuming the form of industrial fabric cloth for manufacturing composite materials is described. Also described, is a composite material produced and a method by which the composite material is produced. Further, the method by which the composite material is produced can include: 1. A process for manufacturing a composite article , the process comprising:a) impregnating a reinforcing cloth with a polyamide composition in a molten state, wherein the polyamide comprises hydroxyaromatic units chemically bonded to a chain of the polyamide, the composition comprising a novolac resin; andb) cooling and subsequently recovering the composite article.2. The process as defined by claim 1 , wherein the polyamide composition exhibits a melt viscosity η of 1 Pa·s to 50 Pa·s.3. The process as defined by claim 1 , wherein the melt viscosity is measured using a plate/plate rheometer with a diameter of 50 mm under a stepwise shear sweep ranging from 1 sto 160 s claim 1 , by melting a film of polyamide with a thickness of 150 μm at a temperature of 25° C. to 30° C. above its melting point.4. The process as defined by claim 1 , wherein the polyamide is selected from the group consisting of a polyamide obtained by polycondensation of at least one linear aliphatic dicarboxylic acid with an aliphatic or cyclic diamine or between at least one aromatic dicarboxylic acid and one aliphatic or aromatic diamine claim 1 , a polyamide obtained by polycondensation of at least one amino acid or lactam with itself claim 1 , or a combination thereof and a (co)polyamide.5. The process as defined by claim 1 , wherein the polyamide is obtained by addition claim 1 , before or during the polymerization of a polyamide monomer claim 1 , a monomer of a diamine claim 1 , a monomer of a dicarboxylic acid claim 1 , a monomer of a monoamine or a monomer of a monocarboxylic acid type.6. The process as ...

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06-06-2013 дата публикации

LIQUID COMPOSITION, RECORDING METHOD, AND RECORDED MATTER

Номер: US20130143008A1
Принадлежит:

A liquid composition containing: a water-soluble cationic polymer obtained by polymerizing monomers containing epihalohydrin and at least one of amine and amide; and water, wherein the liquid composition is for agglutinating negatively charged particles which are dispersed in a dispersion liquid. 1. A liquid composition comprising:a water-soluble cationic polymer obtained by polymerizing a monomer comprising an epihalohydrin and at least one selected from the group consisting of an amine and an amide; andwater,wherein the liquid composition is suitable for agglutinating negatively charged particles dispersed in a dispersion liquid.2. The liquid composition according to claim 1 , further comprising an organic acid ammonium salt.3. The liquid composition according to claim 2 , wherein the organic acid ammonium salt is ammonium lactate.5. The liquid composition according to claim 1 , wherein the liquid composition has a surface tension of 30 mN/m or lower.6. The liquid composition according to claim 1 , further comprising:a fluorine-based surfactant; and {'br': None, 'sub': 1', '3', '2', 'n', '2', '4, 'HORRC—[CH]—CRROH\u2003\u2003Formula (6),'}, 'a compound of formula (6){'sub': 1', '2, 'wherein Rand Rare each independently an alkyl group comprising 3 to 6 carbon atoms;'}{'sub': 3', '4, 'Rand Rare each independently an alkyl group comprising 1 to 2 carbon atoms; and'}n denotes an integer of from 1 to 6.7. A recording method comprising:adhering a liquid composition onto a recording medium; andadhering a dispersion liquid comprising dispersed negatively charged particles comprising a colorant onto the recording medium,wherein the liquid composition comprises:a water-soluble cationic polymer obtained by polymerizing a monomer comprising an epihalohydrin and at least one selected from the group consisting of an amine and an amide; and 'wherein the liquid composition is suitable for aggultinating negatively charged particles dispersed in a dispersion liquid.', 'water,'}8. ...

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20-06-2013 дата публикации

Electrical Insulation Enamels Composed of Modified Polymers and Electrical Conductors Produced Therefrom and Having Improved Sliding Capacity

Номер: US20130153261A1
Принадлежит: Schwering & Hasse Elektrodraht GmbH

The present invention relates to electrical insulation enamels which contain a polymer comprising a base polymer and modifying units which are incompatible with the base polymer after the polymer has cured and lead to the formation of separate phases at the surface, and to processes for the production thereof. The electrical insulation enamels have a low coefficient of friction and frictional resistance and are preferably suitable for the coating of wires. 131.-. (canceled)32. An electrical insulation enamel comprising a polymer comprising a base polymer and modifying units which are incompatible with the base polymer after the polymer has cured , wherein the base polymer is selected from the group consisting of polyamide-imides , polyester-imides , polyamides , polyurethanes , polyimides , polyester-amide-imides , polyepoxides , and mixtures or combinations thereof , wherein the modifying units are polydialkylsiloxanes which comprise 40 to 500 Si units.33. The electrical insulation enamel of claim 32 , comprising separate regions on the surface of the cured enamel after the polymer has cured.34. The electrical insulation enamel of claim 32 , wherein the modifying units are polydimethylsiloxanes.35. The electrical insulation enamel of claim 32 , wherein the base polymer is a polyamide-imide and/or a polyester-imide.36. A cured electrical insulation enamel which can be obtained by thermally curing the electrical insulation enamel of claim 32 , comprising separate regions on the surface of the cured electrical insulation enamel.37. A process for producing the electrical insulation enamel of claim 32 , comprising:polymerizing a first modified block, for example a monomer or a prepolymer, which comprises at least one modifying unit, with at least one second monomer, so as to obtain a polymer comprising modifying units; and,formulating the polymer comprising modifying units with a solvent and optionally additives so as to form an electrical insulation enamel.38. A ...

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20-06-2013 дата публикации

COATING CONTAINING PEK AND/OR PEEK

Номер: US20130157024A1
Автор: Eigenbrod Volkmar
Принадлежит: Rhenotherm Kunststoffbeschichtungs GmbH

The invention concerns a non-stick coating for a substrate consisting of a metallic material, glass, ceramic, stone or enamel, which is characterised by at least one layer applied directly to the substrate and consisting of at least 33 wt. % polyetherketone and/or polyetheretherketone (PEEK), at least 33 wt. % of one or more fluoropolymers and no more than 16 wt. % additives. 1. A non-stick coating for a substrate consisting of a metallic material , glass , ceramic , stone or enamel , the non-stick coating comprising at least one first layer applied directly to the substrate and consisting of at least 33 wt. % polyetherketone and/or polyetheretherketone (PEEK) , at least 33 wt. % of one or more fluoropolymers and no more than 16 wt. % additives.2. The non-stick coating according to claim 1 , wherein the at least one first layer includes at least 50 wt. % PEK and/or PEEK.3. The non-stick coating according to claim 1 , wherein the at least one first layer includes more than 40 wt. % of one or more fluoropolymers.4. The non-stick coating according to claim 1 , wherein the proportion of additive does not exceed 10 wt. %.5. The non-stick coating according to claim 1 , the additives comprise one or more colour pigments.6. The non-stick coating according to claim 1 , wherein the additives comprise inorganic substances.7. The non-stick coating according to claim 1 , wherein the additives comprise organic substances.8. The non-stick coating according to claim 1 , wherein the at least one first layer includes electrically conductive inorganic fibres with a proportion of 5 to 9 wt. % in relation to the at least one first layer.9. The non-stick coating according to claim 1 , wherein the one or more fluoropolymers are selected from the group consisting of PTFE claim 1 , PFA claim 1 , MFA and FEP.10. The non-stick coating according to claim 1 , wherein the coating consists exclusively of the at least one first layer.11. The non-stick coating according to claim 1 , wherein the non ...

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20-06-2013 дата публикации

SPRAYABLE WASTE RUBBER-BASED COATING

Номер: US20130158144A1
Принадлежит:

Surface coating composition, method and apparatus for coating a surface. The surface coating composition comprises a recycled rubber product, one or more binding agent and optionally one or more additional agent. 1. A surface coating composition comprising:crumbs of size 10-20 mesh and buffings from a recycled rubber product, an epoxy-based binding agent and', 'a polyurethane-based binding agent, and, 'a binding agent consisting of a mixture ofup to 3% by weight of the composition of fibers selected from polyester, nylon, Kevlar and their mixture thereof.3. A surface coating composition comprising:crumbs of size 10-20 mesh and buffings obtained from a recycled rubber product; a polyurethane-based binding agent produced from a reaction between an aromatic or aliphatic type polyisocyanate and a polyol in the presence of catalysts, and', 'up to 3% by weight of fibers selected from polyester, nylon, Kevlar and their mixture thereof., 'a binding agent consisting of'}4. The composition as defined in claim 3 , wherein crumb and buffings are obtained from reclaimed tire processing.5. The composition as defined in claim 3 , further comprising an additional agent selected from viscosity modifier claim 3 , foaming agents claim 3 , fire retardants claim 3 , coloring agents claim 3 , fungicides and their mixture thereof.6. The surface coating composition according to claim 3 , wherein 80% of the total crumbs weight is crumb rubber particles in the 1-3 mm range.7. The surface coating composition according to claim 3 , wherein the size of said buffings is above 90 mesh.8. The surface coating composition as defined in claim 3 , wherein the buffings are between 20-90 mesh size.9. The surface coating composition as defined in claim 3 , wherein the polyisocyanate is diphenylmethane diisocynate (MDI) claim 3 , tolulene diisocynate (TDI) claim 3 , naphthalene diisocynate (NDI) m- and p-phenylene diisocyanate claim 3 , p claim 3 ,p′-diphenyl diisocyanate tetra- claim 3 , penta- claim 3 , ...

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04-07-2013 дата публикации

FILM SEALANT AND SEALING METHOD

Номер: US20130171440A1
Принадлежит: DAICEL-EVONIK LTD.

A film sealant useful for tightly sealing an electric device at a low temperature and a sealing method of using the sealant are provided. 1. A film sealant for covering and sealing a device , the sealant comprising a copolyamide-series resin.2. A film sealant according to claim 1 , wherein the copolyamide-series resin has a melting point or softening point of 75 to 160° C.3. A film sealant according to claim 1 , wherein the copolyamide-series resin is a crystalline resin.4. A film sealant according to claim 1 , wherein the copolyamide-series resin is a crystalline resin and has a melting point of 90 to 160° C.5. A film sealant according to claim 1 , wherein the copolyamide-series resin comprises at least one selected from the group consisting of a binary copolymer to a quaternary copolymer.6. A film sealant according to claim 1 , wherein the copolyamide-series resin contains a unit derived from a long-chain component having a Calkylene group.7. A film sealant according to claim 1 , wherein the copolyamide-series resin contains a unit derived from at least one component selected from the group consisting of a Clactam and an aminoCalkanecarboxylic acid.8. A film sealant according to claim 1 , wherein the copolyamide-series resin contains a unit derived from at least one component selected from the group consisting of laurolactam claim 1 , aminoundecanoic acid claim 1 , and aminododecanoic acid.9. A film sealant according to claim 1 , which is a sealant for covering one side of the device.10. A lamination film comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a film sealant recited in and'}a protective layer laminated to one side of the film sealant, the protective layer comprising a heat-resistant resin.11. A lamination film according to claim 10 , wherein the heat-resistant resin has a melting point or softening point of not lower than 170° C.12. A lamination film according to claim 10 , wherein the heat-resistant resin comprises at least one member ...

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18-07-2013 дата публикации

POWDER COMPRISING POLYMER-COATED POLYMERIC CORE PARTICLES

Номер: US20130183529A1
Принадлежит: EVONIK DEGUSSA GmbH

The invention relates to powder, comprising composite particles comprising core particles completely or partially coated with a precipitated first polymer, where the core particles comprise a second polymer which differs from the precipitated first polymer, and where the ratio of the dmedian diameter of the composite particles to the dmedian diameter of the core particles is 1.15 or greater. The invention further relates to processes of using the powders of the present invention to making mouldings. 1. A powder , comprising composite particles comprising core particles completely or partially coated with a precipitated first polymer , where the core particles comprise a second polymer which differs from the precipitated first polymer , and where the ratio of the dmedian diameter of the composite particles to the dmedian diameter of the core particles is 1.15 or greater.2. A powder according to claim 1 , wherein the core particles consist of the second polymer.3. A powder according to claim 1 , wherein the second polymer is selected from the group consisting of a polycarbonate claim 1 , a polymethyl methacrylate claim 1 , a polypropylene claim 1 , a polybutylene terephthalate claim 1 , a polyethylene terephthalate claim 1 , a polyether ether ketone and a polyphthalamide.4. A powder according to claim 1 , wherein the precipitated first polymer is selected from the group consisting of a polyolefin claim 1 , a polyethylene claim 1 , a polypropylene claim 1 , a polyvinyl chloride claim 1 , a polyacetal claim 1 , a polystyrene claim 1 , a polyimide claim 1 , a polysulphone claim 1 , a poly(N-methylmethacrylimide) claim 1 , a polymethyl methacrylate claim 1 , a polyvinylidene fluorides claim 1 , an ionomer claim 1 , a polyether ketone claim 1 , a polyaryl ether ketone claim 1 , a polyamide claim 1 , a copolyamide claim 1 , and a mixture thereof.5. A powder according to claim 1 , wherein the precipitated first polymer is a mixture of a homopolyamide and a copolyamide.6. A ...

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18-07-2013 дата публикации

RESIN COMPOSITION AND MANUFACTURING PROCESS THEREFOR

Номер: US20130184406A1
Принадлежит: Toray Industries, Inc.

A polyamic acid resin composition includes (a) a polyamic acid having structures represented by general formula (1) in an amount of at least 80% of all the repeating units and (b) a solvent. In formula (1), A is a polyamic acid block represented by general formula (2); B is a polyamic acid block represented by general formula (3); and k is a positive integer. In formula (2), Ws are divalent organic groups having two or more carbon atoms, mainly composed of divalent organic groups represented by general formula (4); Xs are tetravalent organic groups having two or more carbon atoms. In formula (3), Ys are divalent organic groups having two or more carbon atoms, exclusive of the groups represented by formula (4); Zs are tetravalent organic groups each having two or more carbon atoms, and are mainly composed of tetravalent organic groups represented by general formula (5) or (6). 4. The resin composition according to claim 1 , further comprising (c) inorganic particles. The present invention relates to polyamic acid resin compositions. Particularly, it relates to a polyamic resin composition to be used suitably for, e.g., flexible substrates of a flat-panel display, an electronic papers, and a solar battery, a surface protective coat of a semiconductor element, a dielectric film among layers, an insulation layer or spacer layer of an organic electro-luminescence device (organic EL element), a planarization layer of a thin film transistor substrate, an insulation layer of an organic transistor, a flexible printed circuit board, and a binder for electrodes of a lithium ion secondary battery.Organic films are advantageous in that they are more flexible and less prone to rupture in comparison to glass. Recently, there is an increasing move toward rendering displays more flexible by replacing the substrates of flat display panels from conventional glass to organic films.In the event that a display is produced on an organic film, a process is common in which the organic film ...

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12-09-2013 дата публикации

PARTIAL-DISCHARGE-RESISTANT INSULATING VARNISH, INSULATED WIRE AND METHOD OF MAKING THE SAME

Номер: US20130236638A1
Принадлежит: HITACHI MAGNET WIRE CORPORATION

A partial-discharge-resistant insulating varnish has a polyamide-imide enamel varnish and an organo-silica sol that are dispersed in a solvent. The solvent has 50 to 100% by weight of γ-butyrolactone. An insulated wire has a conductor, and a partial-discharge-resistant insulation coating film formed on the surface of the conductor. The partial-discharge-resistant insulation coating film is made of the partial-discharge-resistant insulating varnish. 1. A method of making a partial-discharge-resistant insulating varnish , comprising:mixing a polyamide-imide enamel varnish with an organo-silica sol,wherein the polyamide-imide enamel varnish comprises γ-butyrolactone as a main solvent,the organo-silica sol comprises γ-butyrolactone as a main dispersion solvent, andthe partial-discharge-resistant insulating varnish comprises 50 to 100% by weight of γ-butyrolactone to a total amount of a solvent thereof.2. The method according to claim 1 , wherein:the polyamide-imide enamel varnish comprises 60 to 100% by weight of γ-butyrolactone to a total amount of a solvent thereof.3. The method according to claim 1 , wherein:the organo-silica sol comprises 80 to 100% by weight of γ-butyrolactone to a total amount of a dispersion solvent thereof.4. A method of making an insulated wire claim 1 , comprising:preparing a partial-discharge-resistant insulating varnish by mixing a polyamide-imide enamel varnish with an organo-silica sol; andcoating the partial-discharge-resistant insulating varnish on the surface of a conductor and then baking the varnish to form a coating film on the conductor,wherein the polyamide-imide enamel varnish comprises γ-butyrolactone as a main solvent,the organo-silica sol comprises γ-butyrolactone as a main dispersion solvent, andthe partial-discharge-resistant insulating varnish comprises 50 to 100% by weight of γ-butyrolactone to a total amount of a solvent thereof.5. The method according to claim 4 , further comprising:forming an organic insulation coating ...

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03-10-2013 дата публикации

Titanium or titanium alloy-and-resin composite and method for making the same

Номер: US20130256141A1
Принадлежит: Individual

A method for making a titanium-and-resin composite or titanium alloy-and-resin composite includes: providing a titanium or titanium alloy substrate; electrochemically treating the substrate to form a titanium hydride layer; anodizing the substrate having the titanium hydride layer to form an nano-porous oxide film on the surface of the substrate, the nano-porous oxide film having nano pores and comprising at least two layers of different porosity or pore diameters; and inserting the substrate in a mold and melting resin on the surface of the nano-porous oxide film to form the composite.

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24-10-2013 дата публикации

Polyamide Resin Composition with Excellent Reflectivity, Heat Resistance, and Water Resistance

Номер: US20130281587A1
Принадлежит:

A polyamide resin composition includes (A) polyamide resin, (B) white pigment, and (C) sodium phosphate salt. 1. A polyamide resin composition comprising (A) polyamide resin , (B) white pigment , and (C) sodium phosphate salt.2. The polyamide resin composition of claim 1 , wherein the polyamide resin composition comprises about 0.1 to about 50 parts by weight of white pigment (B) and about 0.01 to about 20 parts by weight of sodium phosphate salt (C) claim 1 , based on about 100 parts by weight of polyamide resin (A).3. The polyamide resin composition of claim 1 , wherein the polyamide resin (A) includes aromatic dicarboxylic acid and optionally aliphatic diamine claim 1 , cycloaliphatic diamine claim 1 , or a combination thereof as repeating units.5. The polyamide resin composition of claim 1 , wherein the white pigment (B) comprises titanium oxide claim 1 , zinc oxide claim 1 , zinc sulfide claim 1 , lead white claim 1 , zinc sulfate claim 1 , barium sulfate claim 1 , calcium carbonate claim 1 , aluminum oxide claim 1 , or a combination thereof.6. The polyamide resin composition of claim 1 , wherein the sodium phosphate salt (C) comprises sodium phosphate monobasic claim 1 , sodium phosphate dibasic claim 1 , sodium phosphate claim 1 , sodium acid pyrophosphate claim 1 , or a combination thereof.7. The polyamide resin composition of claim 6 , wherein the sodium phosphate salt (C) is surface-treated with a silane coupling agent claim 6 , titanium coupling agent claim 6 , organic acid claim 6 , polyol claim 6 , or silicone.8. The polyamide resin composition of claim 1 , wherein the polyamide resin composition further comprises about 0.01 to about 80 parts by weight of filler (D).9. The polyamide resin composition of claim 8 , wherein the filler (D) includes glass fiber having an average length of about 0.1 to about 20 mm and an aspect ratio of about 10 to about 2 claim 8 ,000.10. The polyamide resin composition of claim 1 , wherein the polyamide resin composition ...

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31-10-2013 дата публикации

COATED METALLIC ARTICLE

Номер: US20130287981A1
Принадлежит:

A method for coating of a metallic article is provided. According to the method, the metal surface is coated with a composition which comprises a polymer or comprises a two-component system that reacts to form a polymer following application to the metal surface. The composition comprises 70-2700 meq/kg olefinic double bonds which leads to stronger adhesion and to increased corrosion resistance. 1. A method for coating a metallic article , comprising:applying a composition to the metal surface to obtain a coated surface;wherein a) a polymer; or', 'a two-component system which reacts to form a polymer following application to the metal surface; and,, 'the composition comprisesthe composition comprises 70-2700 meq/kg olefinic double bonds.2. The method according to claim 1 ,whereinthe polymer or the two component system which reacts to form a polymer comprises the 70-2700 meq/kg olefinic double bonds.3. The method according to claim 2 ,whereinthe polymer is a polyamide or a polyurethane which comprises polymerized ethylenically unsaturated dicarboxylic acids, orthe polymer formed by the two component system is a polyamide or a polyurethane which comprises polymerized ethylenically unsaturated dicarboxylic acids.4. The method according to claim 1 ,wherein the composition further comprises:b) an amount of an unsaturated compound which comprises olefinic double bonds such that the composition comprises 70-2700 meq/kg olefinic double bonds,{'sub': 'n', 'wherein a number average molecular weight (M) of the unsaturated compound is not more than 38,000 g/mol as determined by vapour pressure osmometry.'}5. The method according to claim 1 ,wherein the composition comprises the polymer and the polymer is selected from the group consisting of polyamides, polyolefins, thermoplastic polyurethanes, polyvinyl chloride and fluoropolymers.6. The method according to claim 1 , wherein the composition comprises the two component system and the two component system is a resin/curing agent ...

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31-10-2013 дата публикации

TRIAZINE RING-CONTAINING POLYMER AND FILM-FORMING COMPOSITION CONTAINING SAME

Номер: US20130289203A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

A polymer containing a repeating unit structure having a triazine ring such as, for example, that which is represented by formula (25): can exhibit alone high heat resistance, high transparency, high refractive index, high solubility and low volume shrinkage; and can be used as a component in a film-forming composition as appropriate. 2. The triazine ring-containing polymer according to claim 1 , wherein the combination of Arand Aris two selected from the group consisting of formulas (5) to (12) and formulas (14) to (18).3. The triazine ring-containing polymer according to claim 1 , wherein the combination of Arand Aris two selected from the group consisting of formulas (7) claim 1 , (11) claim 1 , (12) claim 1 , (14) and (15).8. The triazine ring-containing polymer according to claim 1 , wherein the polymer is capped on at least one end by an alkyl claim 1 , aralkyl claim 1 , aryl claim 1 , alkylamino claim 1 , alkoxysilyl-containing alkylamino claim 1 , aralkylamino claim 1 , arylamino claim 1 , alkoxy claim 1 , aralkyloxy claim 1 , aryloxy or ester group.9. The triazine ring-containing polymer according to claim 8 , wherein the polymer has at least one terminal triazine ring claim 8 , which terminal triazine ring is capped by an alkyl claim 8 , aralkyl claim 8 , aryl claim 8 , alkylamino claim 8 , alkoxysilyl-containing alkylamino claim 8 , aralkylamino claim 8 , arylamino claim 8 , alkoxy claim 8 , aralkyloxy claim 8 , aryloxy or ester group.10. A film-forming composition comprising the triazine ring-containing polymer of .11. A film obtained from the film-forming composition of .12. A film comprising the triazine ring-containing polymer according to .13. An electronic device comprising a base material and the film of or formed on the base material.14. An optical member comprising a base material and the film of or formed on the base material.15. A solid-state image sensor formed of a charge-coupled device or a complementary metal oxide semiconductor claim 1 , ...

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07-11-2013 дата публикации

Aqueous autoxidisable coating composition

Номер: US20130296486A1
Принадлежит: DSM IP ASSETS BV

An aqueous coating composition comprising an autoxidisable polyester resin having ≧30 wt % of fatty acid residues; a Tg in the range of from −60° C. to +35° C.; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; said composition having a co-solvent content less that 15 wt % by weight of total composition; a solids content >30 wt %; and when a film, a telegraphing value of less than 20 gloss units.

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26-12-2013 дата публикации

Composition for Use as an Assay

Номер: US20130345357A1
Принадлежит: SIEMENS HEALTHCARE DIAGNOSTICS INC.

A composition for use as an assay reagent comprises a solid support comprising a member of a signal producing system and a coating of a synthetic copolymer. The synthetic copolymer comprises a first polymerized monomer comprising a pendant moiety comprising a reactive functionality or a derivative of a reactive functionality and a second polymerized monomer comprising a pendant moiety comprising at least 1 carbon atoms and at least 2 heteroatoms. In some embodiments the copolymer comprises a polyethylenic backbone comprising the pendant moiety comprising a reactive functionality or a derivative of a reactive functionality and the pendant moiety comprising at least 1 carbon atom and at least 2 heteroatoms. 2. The copolymer according to wherein:{'sup': 1', '1, 'A is NRwherein Ris H or alkyl of from 1 to 6 carbon atoms;'}n is 1 to 10;{'sup': 8', '8, 'sub': '2', 'G′ is CHO; CH(OR)wherein Ris alkyl of from 1 to 6 carbon atoms; or a member of a specific binding pair;'}{'sub': 2', 'p', 'q', '2', 'r, 'claim-text': X is O;', {'sup': ⊕', '3', '4', '3', '4, 'Y is >N(RR) wherein Rand Rare independently H or alkyl of from 1 to 6 carbon atoms;'}, 'p is 1 to 10;', 'q is 1;', 'r is 1 to 10;', {'sub': '3', 'sup': '−', 'Z′ is SO;'}], 'D′ is —C(O)—X—(CH)—(Y)—(CH)—Z′ wherein{'sup': 5', '6', '7, 'R, Rand Rare independently H or alkyl of from 1 to 6 carbon atoms; and'}x and y are independently 1 to 1000.3. The copolymer according to wherein:A is NH;n is 1;{'sup': 8', '8, 'sub': '2', 'G′ is CHO; CH(OR)wherein Ris methyl; or a member of a specific binding pair;'}{'sub': 2', 'p', 'q', '2', 'r, 'claim-text': X is O;', {'sup': ⊕', '3', '4', '3', '4, 'Y is >N(RR) wherein Rand Rare both methyl;'}, 'p is 2;', 'q is 1;', 'r is 3;', {'sub': '3', 'sup': '−', 'Z′ is SO;'}], 'D′ is —C(O)—X—(CH)—(Y)—(CH)—Z′ wherein{'sup': 5', '6', '7, 'Rand Rare independently H or methyl and Ris H; and'}x and y are independently 1 to 1000.4. The copolymer according to wherein:{'sup': 1', '1, 'A is NRwherein Ris H or ...

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16-01-2014 дата публикации

Image Destruct Feature Used With Image Receiving Layers In Secure Documents

Номер: US20140017473A1
Принадлежит: L-1 SECURE CREDENTIALING, INC.

An image destruct material comprises a release layer positioned between an image receiving layer and a base layer. The adhesion between the release layer and the base layer is greater than adhesion between the release layer and the image receiving layer. The release layer material can be used in secure documents that have an image receiving layer. After information is printed on the image receiving layer, an overlaminate is applied over it. Removal of the overlaminate destroys the printed image on the receiving layer because of the relative adhesive properties of the image receiving layer, overlaminate and release layer. 1. An identification document comprising:a base layer;a release layer over the base layer, the release layer being applied in a pattern and the pattern covering less than an entire area of the base layer;an image receiving layer over the base layer and the release layer, wherein the image receiving layer is in direct contact with the base layer except where the image receiving layer contacts the pattern of the release layer; andan overlaminate layer over the image receiving layer,wherein the adhesion of the release layer to the base layer is greater than the adhesion of the release layer to the image receiving layer and wherein the adhesion of the overlaminate layer to the image receiving layer is greater than the adhesion of the image receiving layer to the release layer, such that removal of the overlaminate layer causes an image printed on the image receiving layer to remain adhered to the overlaminate layer in the area of the release layer while the image printed on the image receiving layer remains with the base layer outside the area of the release layer.2. The identification document of claim 1 , wherein the image receiving layer comprises a D2T2 image receiving layer.3. The identification document of claim 1 , wherein the release layer comprises a water soluble polymer and a solvent soluble polymer claim 1 , and wherein the release layer ...

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23-01-2014 дата публикации

Air drying resin and composition

Номер: US20140024770A1
Принадлежит: DSM IP ASSETS BV

The invention relates to an airdrying resin suitable for a coating composition characterized in that the resin is a polyesteramide prepared from: A) at least one anhydride chosen from the list containing succinic, glutaric, citraconic, itaconic or maleic anhydride or a combination of any of them, and B) at least one alkanol-amine, and C) at least one fatty acid, wherein the fatty acid is incorporated in the resin in an amount equivalent to an oil- length between 15 and 40%. This airdrying resin is both water- and solvent-soluble, having a combination of properties desirable for different types of applications. The invention relates also to a method for preparing such a polyesteramide resin, to a composition comprising at least one polyesteramide resin and a method for preparing such a composition, to a substrate fully or partially coated with this composition, a method for curing the coated substrate, the cured and coated substrate and the use of resin in various applications.

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13-02-2014 дата публикации

COMPOSITE REINFORCEMENT COATED WITH A SELF-ADHESIVE POLYMER LAYER WHICH ADHERES TO RUBBER

Номер: US20140044964A1
Принадлежит:

Composite reinforcer (R-2) capable of adhering directly to a diene rubber matrix, which can be used as a reinforcing element for a pneumatic tyre, comprising: 124-. (canceled)25. A composite reinforcer comprising:at least one reinforcing thread; and a thermoplastic polymer having a glass transition temperature that is positive,', 'an unsaturated thermoplastic styrene elastomer having a glass transition that is negative, and', 'a poly(p-phenylene ether)., 'a layer of a thermoplastic polymer composition covering each thread individually or plural threads collectively, of the at least one reinforcing thread, wherein the thermoplastic polymer composition includes26. The composite reinforcer according to claim 25 , wherein the glass transition temperature of the thermoplastic polymer is above +20° C.27. The composite reinforcer according to claim 25 , wherein the glass transition temperature of the unsaturated thermoplastic styrene elastomer is below −20° C.28. The composite reinforcer according to claim 26 , wherein the glass transition temperature of the unsaturated thermoplastic styrene elastomer is below −20° C.29. The composite reinforcer according to claim 25 , wherein a difference between the glass transition temperature of the thermoplastic polymer and the glass transition temperature of the unsaturated thermoplastic styrene elastomer is greater than 60° C.30. The composite reinforcer according to claim 25 , wherein the thermoplastic polymer is an aliphatic polyamide or a polyester.31. The composite reinforcer according to claim 25 , wherein the thermoplastic elastomer is a copolymer that includes styrene blocks and diene blocks.32. The composite reinforcer according to claim 25 , wherein the poly(p-phenylene ether) has a glass transition temperature above 150° C.33. The composite reinforcer according to claim 25 , wherein the poly(p-phenylene ether) is poly(2 claim 25 ,6-dimethyl-1 claim 25 ,4-phenylene ether).34. The composite reinforcer according to claim 25 , ...

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13-02-2014 дата публикации

Auto-Adhesive Composite Reinforcement

Номер: US20140045984A1
Принадлежит:

Composite reinforcer (R-) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer. 1. A composite reinforcer comprising:one or more reinforcing thread(s);covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups.2. The reinforcer according to claim 1 , wherein the glass transition temperature of the thermoplastic polymer is above +20° C.3. The reinforcer according to claim 1 , wherein the glass transition temperature of the unsaturated thermoplastic stirene elastomer is below −10° C.4. The reinforcer according to claim 1 , wherein the difference in glass transition temperature between the thermoplastic polymer and the unsaturated thermoplastic stirene elastomer is greater than 50° C.5. The reinforcer according to claim 1 , wherein the thermoplastic polymer is an ...

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05-01-2017 дата публикации

AQUEOUS-BASED COATING COMPOSITION CONTAINING A POLYANHYDRIDE

Номер: US20170002226A1
Принадлежит: PPG Industries Ohio, Inc.

An aqueous-based coating composition suitable as a package coating comprising: 2. The coating composition of in which the acid functional polymer is a (meth)acrylic polymer.3. The coating composition of in which the reactive functional groups are carboxylic acid and/or hydroxyl.4. The coating composition of in which the curing agent is a phenolplast and/or an aminoplast.5. The coating composition of in which X is a group of the structure O—R—O where Ris alkylene.6. The coating composition of in which Ris Cto Calkylene.7. The coating composition of in which (i) is present in the coating composition in amounts of 20 to 50 percent by weight based on weight of resin solids in the coating composition.8. The coating composition of in which (ii) is present in the coating composition in amounts of 20 to 50 percent by weight based on weight of resin solids in the coating composition.9. The coating composition of in which (iii) is present in the coating composition in amounts of 0.5 to 3 percent by weight based on weight of resin solids in the coating composition.10. The coating composition of which has a resin solids content of 25 to 30 percent by weight based on total weight of the composition.11. A coated package or portion thereof having a food or beverage-contacting surface comprising a coating composition of applied to at least a portion of the food or beverage-contacting surface of the package.12. The coated package of in which the package is an aluminum or steel container.13. The coated package of in which the container is a 2-piece or 3-piece can including a can end.14. A method comprising:(a) providing a substrate with a food or beverage-contacting surface,{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, '(b) applying a coating composition of to the food or beverage-contacting surface, and'}(c) forming the substrate into a package before or after application of the coating composition.15. The method of in which the substrate is a metal sheet or a coil metal strip ...

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04-01-2018 дата публикации

WATER DISPERSIBLE POLYAMIDE BUILDING BLOCKS

Номер: US20180002484A1
Принадлежит:

Water dispersible polyamides having carboxylic acid groups are disclosed. These are made by reacting polycarboxyl is acids or anhydrides thereof with amine containing monomer or an amide terminated polyamide under reaction conditions such that a few of the carboxylic acid groups are residual and can promote dispersion in water. These polyamides after dispersion can be chain extended to higher molecular weight polymers or can be terminally functionalized with reactive groups such as isocyanate, epoxy, vinyl, acetoacetonate, or silanol groups. Composites and hybrids of these polyamides with vinyl polymers are also disclosed and claimed. 1. A water dispersible polyamide comprising a polyamide condensation reaction product of at least one polycarboxylic acid and/or anhydride thereof with at least one amine monomer with a primary or secondary amine group or an amine terminated polyamide , wherein said polyamide reaction product has a titratable acid content derived from said at least one polycarboxylic acid of from about 1 to about 100 mg KOH/gram of polyamide.2. A water dispersible polyamide according to claim 1 , wherein said titratable acid content is from about 10 to about 60 mgKOH/gram.3. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide has a number average molecular weight from about 500 to about 50 claim 1 ,000 g/mole.4. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide has a number average molecular weight from about 500 to about 30 claim 1 ,000 g/mole.5. A water dispersible polyamide according to claim 1 , wherein said at least one amine monomer is reacted with said polycarboxylic acid or anhydride thereof and said amine monomer comprises a polyamine with two or more primary or secondary amine groups.6. A water dispersible polyamide according to claim 1 , wherein said water dispersible polyamide is neutralized to a pH above 7 prior to dispersion or during dispersion in a ...

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03-01-2019 дата публикации

FREE-STANDING NON-FOULING POLYMERS, THEIR COMPOSITIONS, AND RELATED MONOMERS

Номер: US20190002625A1
Принадлежит: UNIVERSITY OF WASHINGTON

Free-standing non-fouling polymers and polymeric compositions, monomers and macromonomers for making the polymers and polymeric compositions, objects made from the polymers and polymeric compositions, and methods for making and using the polymers and polymeric compositions. 119-. (canceled)2122-. (canceled)23. A polymer of having a fibrinogen binding level of less than 30 ng/cmin a fibrinogen binding assay (polymer surface is incubated at 37° C. for 90 minutes with a 1.0 mg/mL fibrinogen solution in 0.15 M phosphate buffered saline at pH 7.4).24. A polymer of having a tensile or compressive strength greater than 0.5 MPa.25. A polymer of having a fibrinogen binding level of less than 30 ng/cmin a fibrinogen binding assay (polymer surface is incubated at 37° C. for 90 minutes with a 1.0 mg/mL fibrinogen solution in 0.15 M phosphate buffered saline at pH 7.4) and a tensile or compressive strengths greater than 0.5 MPa.26. A polymer of claim 20 , wherein the polymer is crosslinked.27. A composite claim 20 , comprising a polymer of and a second polymer.28. The composite of claim 27 , wherein the second polymer is selected from the group consisting of polyesters claim 27 , polycarbonates claim 27 , polyurethanes claim 27 , polyureas claim 27 , polysulfides claim 27 , polysulfones claim 27 , polyimides claim 27 , polyepoxies claim 27 , aromatic polyesters claim 27 , cellulosics claim 27 , fluoropolymers claim 27 , polyacrylics claim 27 , polyamides claim 27 , polyanhydrides claim 27 , polyethers claim 27 , vinyl polymers claim 27 , phenolics claim 27 , elastomers claim 27 , and other addition polymers.29. The composite of further comprising a strength additive.30. The composite of further comprising a strength additive selected from the groups consisting of fiber claim 27 , clays claim 27 , nanotubes claim 27 , and other inorganic objects.31. A polymer of formed into an object by a method selected from the group consisting of injection molding claim 20 , blow molding claim ...

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02-01-2020 дата публикации

MAGNETICALLY INDUCTIVE FLOW METER

Номер: US20200003592A1
Принадлежит: Endress+Hauser Flowtec AG

A magnetically inductive flow meter having a measuring tube with a wall, which includes an electrically insulating surface of a first material, and an electrode having an electrode axis, wherein the electrode has at least one electrode end surface for tapping off a measuring signal, in particular a measuring voltage, in a measuring medium, and has an electrode shank extending through the measuring tube wall, wherein the electrode has a stop projecting from the electrode shank with a stop surface to limit the displaceability of the electrode relative to the wall along the electrode axis, wherein the electrode has an electrically insulating coating in a region of the electrode shank and in a region of the stop surface, wherein the material of the electrically insulating coating has a Shore hardness which is equal to or lower than that of the first material. 115-. (canceled)16. A magnetically inductive flow meter , the flow meter comprising:a measuring tube including a measuring tube wall, which includes an electrically insulating surface made of a first material; anda electrode including an electrode end surface configured for tapping off a measuring signal in a measuring medium and an electrode shank, which extends through the measuring tube wall, wherein the electrode has a stop that projects from the electrode shank, the stop including a stop surface structured to limit the displaceability of the electrode along the electrode axis and relative to the measuring tube wall,wherein the electrode includes an electrically insulating coating on at least a portion of the electrode shank and on at least a portion of the stop surface, and wherein the material of the coating has a Shore hardness that is equal to or lower than the Shore hardness of the first material.17. The flow meter of claim 16 , wherein the measuring signal is a measurement voltage.18. The flow meter of claim 16 , wherein the measuring tube has an impression for receiving the electrode.19. The flow meter ...

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12-01-2017 дата публикации

SPIRAL-TYPE SEPARATION MEMBRANE ELEMENT

Номер: US20170007969A1
Принадлежит: NITTO DENKO CORPORATION

The objective of the present invention is to provide a spiral-type separation membrane element having superior oxidant resistance relative to the prior art, and a salt-blocking rate that tends not to decrease. The spiral-type separation membrane element is characterized in including: a supply-side flow-path material; a composite semipermeable membrane in which a skin layer is formed on the surface of a porous support, the skin layer containing a polyamide resin obtained by interfacial polymerization of a polyfunctional amine component and a polyfunctional acid halogen component; and a permeation-side flow-path material, wherein the polyfunctional amine component contains N,N′-dimethyl-meta-phenylenediamine and the permeation-side flow-path material has a porosity of 40 to 75%. 1. A spiral-type separation membrane element including: a supply-side flow-path material; a composite semipermeable membrane in which a skin layer is formed on the surface of a porous support , the skin layer containing a polyamide resin obtained by interfacial polymerization of a polyfunctional amine component and a polyfunctional acid halogen component; and a permeation-side flow-path material , whereinthe polyfunctional amine component contains N,N′-dimethyl-meta-phenylenediamine andthe permeation-side flow-path material has a porosity of 40 to 75%.2. The spiral-type separation membrane element according to claim 1 , wherein the permeation-side flow-path material is a tricot knit fabric. The present invention relates to a spiral-type separation membrane element including a supply-side flow-path material, a composite semipermeable membrane and a permeation-side flow-path material. The spiral-type separation membrane element is suitably used for production of ultrapure water, desalination of brackish water or sea water, etc., and usable for removing or collecting pollution sources or effective substances from pollution, which causes environment pollution occurrence, such as dyeing drainage ...

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20-01-2022 дата публикации

Protective film forming agent for plasma dicing and method for manufacturing semiconductor chip

Номер: US20220020643A1
Принадлежит: Tokyo Ohka Kogyo Co Ltd

A protective film forming agent for plasma dicing which can favorably form an opening (processed groove) of a desired shape by irradiation of a laser beam, at a desired position of the protective film, upon producing semiconductor chips by cutting a semiconductor substrate by plasma dicing, and a method for producing a semiconductor chip using this protective film forming agent. The protective film forming agent comprises a water-soluble resin, a light absorber, and a solvent, and a weight loss rate when the temperature is raised to 500° C. in thermogravimetry of the water-soluble resin is at least 80 weight %.

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14-01-2016 дата публикации

WATER-BORNE POLYAMIDE-UREA DISPERSIONS

Номер: US20160009953A1
Принадлежит: LUBRIZOL ADVANCED MATERIALS, INC.

Polymers are disclosed that incorporate large portions of elastomeric polyamide oligomers connected with polyisocyanates. These polymers have enhanced properties over similar polyurethanes due to better hydrolysis resistance of polyamides over polyesters and better UV resistance of polyamides over polyethers. Polyurea linkages can also improve properties over polyurethane linkages. Composites and hybrids of these polymers and other polyamides with vinyl polymers are also disclosed and claimed. 1. A colloidally stabilized polymer dispersion in water comprising a polyamide oligomer with amine terminal groups reacted with a polyisocyanate to form a polymer with a urea link between said polyamide oligomer and said polyisocyanate , said polymer being then dispersed in water to form a polymer dispersion in water , wherein said dispersion has a number average particle size of less than 100 microns.2. (canceled)3. A polymer dispersion in water according to claim 1 , wherein said polyamide oligomer is characterized as comprising at least two amide linkages characterized as being derived from reacting an amine with a carboxyl group claim 1 , and said polyamide oligomer comprising repeat units derived from polymerizing one or more of monomers selected from lactams claim 1 , aminocarboxylic acids claim 1 , dicarboxylic acids claim 1 , and diamines.4. A polymer dispersion according to wherein said polyamide oligomer comprises repeat units linked together with chemical linkages comprising amide linkages and optionally linked with other chemical linkages; wherein desirably at least 10% of the total number of the heteroatom containing linkages connecting hydrocarbon type linkages (more desirably at least 45 claim 3 , 50 claim 3 , 55 claim 3 , 60 claim 3 , 75 claim 3 , 80 claim 3 , 90 claim 3 , or 95%) are characterized as being amide linkages and at least 25% of the amide linkages are characterized as being tertiary amide linkages.5. A polymer dispersion according to claim 1 , ...

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11-01-2018 дата публикации

THERMOSETTING RESIN COMPOSITION, CURED FILM, SUBSTRATE WITH CURED FILM, AND ELECTRONIC COMPONENT

Номер: US20180009983A1
Принадлежит:

Provided are a thermosetting resin composition containing polyester amide acid (A), epoxy compound (B) having a fluorene skeleton, epoxy curing agent (C) and colorant (D), and the thermosetting resin composition capable of forming a cured film having an excellent balance of satisfactory hardness and adhesion to glass under high-temperature conditions, and also an application of the thermosetting resin composition. 1. A thermosetting resin composition , comprising polyester amide acid (A) , epoxy compound (B) having a fluorene skeleton , epoxy curing agent (C) and colorant (D).2. The thermosetting resin composition according to claim 1 , wherein an epoxy equivalent in epoxy compound (B) having the fluorene skeleton is 200 to 550 g/eq.3. The thermosetting resin composition according to claim 1 , comprising epoxy curing agent (C) in an amount of 1 to 380 parts by weight based on 100 parts by weight of epoxy compound (B) having the fluorene skeleton.4. The thermosetting resin composition according to claim 1 , comprising epoxy compound (B) having the fluorene skeleton in an amount of 10 to 400 parts by weight based on 100 parts by weight of polyester amide acid (A).5. The thermosetting resin composition according to claim 1 , wherein epoxy curing agent (C) is an anhydride curing agent.6. The thermosetting resin composition according to claim 1 , wherein a weight average molecular weight of polyester amide acid (A) is 2 claim 1 ,000 to 30 claim 1 ,000.8. The thermosetting resin composition according claim 1 , wherein polyester amide acid (A) is a compound obtained by allowing tetracarboxylic dianhydride (a1) claim 1 , diamine (a2) and polyvalent hydroxy compound (a3) to react thereamong as essential components.9. The thermosetting resin composition according to claim 1 , wherein polyester amide acid (A) is a compound obtained by allowing tetracarboxylic dianhydride (a1) claim 1 , diamine (a2) claim 1 , polyvalent hydroxy compound (a3) and monohydric alcohol (a4) to react ...

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09-01-2020 дата публикации

POLYASPARTIC COATING COMPOSITION, COATING FILM, AND COATED ARTICLE

Номер: US20200010723A1
Автор: TAKENO Satoshi
Принадлежит: ASAHI KASEI KABUSHIKI KAISHA

The present invention provides a polyaspartic coating composition containing (A) an aspartic acid ester compound represented by the following formula (I) 2. The polyaspartic coating composition according to claim 1 , wherein the polyol further contains a polyoxyalkylene polyol.3. The polyaspartic coating composition according to claim 2 , wherein a ratio of the polyoxyalkylene polyol to a total amount of the polyoxyalkylene polyol and the polycaprolactone polyol is 80% by mass or less.4. The polyaspartic coating composition according to claim 1 , wherein an equivalent ratio between the amino group of (A) the aspartic acid ester compound and the isocyanate group of (B) the polyisocyanate component is amino group:isocyanate group=10:1 to 1:10.6. The polyaspartic coating composition according to claim 5 , wherein a number-average molecular weight of (B′) the polyisocyanate component is 700 to 3500.7. The polyaspartic coating composition according to claim 5 , wherein an equivalent ratio between the amino group of (A) the aspartic acid ester compound and the isocyanate group of (B′) the polyisocyanate component is amino group:isocyanate group=10:1 to 1:10.8. The polyaspartic coating composition according to claim 1 , wherein the diisocyanate monomer contains a hexamethylene diisocyanate.9. A coating film formed from the polyaspartic coating composition defined in .10. A coated article comprising the coating film defined in .11. Use of the polyaspartic coating composition defined in for heavy-duty anticorrosion coating.12. A method for preventing corrosion of a structure claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'coating a structure with the polyaspartic coating composition defined in .'} The present invention relates to a polyaspartic coating composition, a coating film and a coated article.Priority is claimed on Japanese Patent Application No. 2017-043141, filed Mar. 7, 2017 and Japanese Patent Application No. 2017-169741, filed Sep. 4, ...

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03-02-2022 дата публикации

BACKSHEET FOR PHOTOVOLTAIC MODULES COMPRISING AN ALIPHATIC POLYAMIDE

Номер: US20220033679A1
Принадлежит:

The present invention relates to a backsheet for photovoltaic modules comprising a polymeric layer comprising an aliphatic polyamide comprising 1,10-decanedioic acid. Examples of such aliphatic polyamides are polyamide 4,10, polyamide 5,10 or polyamide 6,10. Preferably polyamide 4,10 is present in the rear layer of the backsheet. A polyolefin layer is preferably present in the core layer of the backsheet. It is however also possible that the polyamide is present in the core layer and polyolefin is present in the rear layer of the backsheet. The polyolefin is preferably chosen from the group consisting of polyethylene, polypropylene or ethylene-propylene copolymers. More preferably the polyolefin is polypropylene. The backsheet preferably comprises at least a further polymeric layer comprising a polymer selected from the group consisting of an optionally functionalized polyolefin such as a maleic anhydride functionalized polypropylene homo or copolymer. The present invention further relates to a photovoltaic module containing essentially, in order of position from the front-sun facing side to the back non-sun-facing side, a transparent pane, a front encapsulant layer, a solar cell layer comprised of one or more electrically interconnected solar cells, a back encapsulant layer and the back-sheet according to the present invention. 1. Backsheet for photovoltaic modules comprising a core and/or rear layer comprising an aliphatic polyamide containing monomer units of an aliphatic linear dicarboxylic acid with at least 8 carbon atoms.2. Backsheet according to whereby the aliphatic linear dicarboxylic acid is chosen from the group of 1 claim 1 ,10-decanedioic acid claim 1 , 1 claim 1 ,11-undecandioic acid claim 1 , 1 claim 1 ,12-dodecanedioic acid claim 1 , 1 claim 1 ,13-tridecanedioic acid claim 1 , 1 claim 1 ,14-tetradecanedioic acid claim 1 , 1 claim 1 ,15-pentadecanedioic acid claim 1 , 1 claim 1 ,16-hexadecanedioic acid claim 1 , 1 claim 1 ,17-heptadecanedioic acid ...

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19-01-2017 дата публикации

INKJET INK

Номер: US20170015854A1
Принадлежит: RISO KAGAKU CORPORATION

An inkjet ink is provided which preferably having a small particle size and excellent intermittent dischargeability. Moreover, the inkjet ink is provided which preferably improving the storage stability of the inkjet ink, and printing a printed item having excellent rub fastness. Specifically, an inkjet ink comprising colored resin particles, a basic dispersant and a non-aqueous solvent, wherein the colored resin particles comprise a pigment, a solid resin and a pigmentary synergist is provided. 1. An inkjet ink comprising colored resin particles , a basic dispersant and a non-aqueous solvent , wherein the colored resin particles comprise a pigment , a solid resin and a pigmentary synergist.2. The inkjet ink according to Claim I , wherein the colored resin particles also comprise a liquid organic compound having an acidic group.3. The inkjet ink according to claim 2 , wherein the acidic group of the liquid organic compound having an acidic group includes a phosphoric acid group.4. The inkjet ink according to claim 1 , wherein the solid resin comprises one or more resins selected from among nitrogen-containing resins and aromatic ring-containing resins.5. The inkjet ink according to claim 4 , wherein the solid resin comprises nitrocelluloses.6. The inkjet ink according to claim 4 , wherein the solid resin comprises polyamide resins having an alkoxy group.7. The inkjet ink according to claim 4 , wherein the solid resin comprises styrene-(meth)acrylic-based resins.8. The inkjet ink according to claim 1 , wherein the non-aqueous solvent has an initial boiling point of 250° C. or higher.9. The inkjet ink according to claim 1 , wherein an amount of the pigmentary synergist relative to a total mass of the colored resin particles is within a range from 0.25 mass % to 10 mass %.10. The inkjet ink according to claim 1 , wherein an amount of the pigmentary synergist claim 1 , expressed as a mass ratio relative to a value of 1 for the pigment claim 1 , is within range from 0. ...

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21-01-2016 дата публикации

ACTIVE-ENERGY-RAY-CURABLE RESIN, AND GAS BARRIER LAMINATE COMPRISING CURED PRODUCT OF SAID RESIN

Номер: US20160017095A1
Автор: Honda Eiichi, KOUNO Kazuki
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

A resin according to the present invention is prepared by reacting a reaction product, which is obtained by Michael addition reaction between the following component (A) and the following component (B) and a subsequent amide group formation reaction, with the following component (C): 2. The resin according to claim 1 , wherein the component (A) is m-xylylenediamine or p-xylylenediamine.3. The resin according to or claim 1 , wherein the component (B) is acrylic acid claim 1 , methacrylic acid claim 1 , crotonic acid and/or a derivative thereof.4. The resin according to claim 1 , wherein the component (C) is glycidyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate.5. The resin according to claim 1 , wherein the derivative in the component (B) is at least one selected from the group consisting of an ester claim 1 , an amide claim 1 , an acid anhydride and an acid chloride.7. The resin according to claim 6 , wherein X is a hydrocarbon group having a Caromatic ring.8. The resin according to or claim 6 , wherein Ys each independently represent a hydrogen atom claim 6 , an alkyl group having 1 to 3 carbon atoms claim 6 , an aralkyl group having 1 to 8 carbon atoms or an aryl group.10. A resin composition containing the resin according to .11. A cured product obtained by curing the resin composition according to .1224-. (canceled)25. A resin composition containing the resin according to .26. A cured product obtained by curing the resin composition according to .27. A coating material containing the resin according to .28. An adhesive containing the resin according to .29. A gas barrier laminate comprising a base material layer and at least one gas barrier layer claim 1 , wherein the gas barrier layer comprises a cured product of the resin according to .30. The gas barrier laminate according to claim 29 , wherein the base material layer is at least one selected from the group consisting of a flexible polymer film layer claim 29 , a paper layer and a metal foil layer.31. ...

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16-01-2020 дата публикации

SILICONE HYDROGEL LENSES WITH WATER-RICH SURFACES

Номер: US20200017713A1
Принадлежит:

The invention is related to a hydrated silicone hydrogel contact lens having a layered structural configuration: a lower water content silicone hydrogel core (or bulk material) completely covered with a layer of a higher water content hydrogel totally or substantially free of silicone. A hydrated silicone hydrogel contact lens of the invention possesses high oxygen permeability for maintaining the corneal health and a soft, water-rich, lubricious surface for wearing comfort. 164-. (canceled)65. A silicone hydrogel contact lens , comprising:a silicone hydrogel bulk material covered with an outer surface hydrogel layer,{'sub': 'SiHy', 'wherein the silicone hydrogel bulk material comprises (i) repeating units derived from a silicone-containing vinylic monomer, a silicone-containing vinylic macromer, a silicone-containing prepolymer or combinations thereof and (ii) repeating units derived from a hydrophilic vinylic monomer, and has a first water content (designated as WC) of from about 10% to about 70% by weight,'}wherein the outer surface hydrogel layer comprises a crosslinked polymeric material which comprises poly(ethylene glycol) chains which are designated as PEG chains, andwherein the silicone hydrogel contact lens has a silicon atomic percentage of about 5% or less of total elemental percentage as measured by XPS analysis of the silicone hydrogel contact lens in dried state,wherein the silicone hydrogel contact lens, when being fully hydrated, has: an oxygen transmissibility of at least about 40 barrers/mm; an elastic modulus (or Young's Modulus) of from about 0.3 MPa to about 1.8 MPa; and an averaged water contact angle of about 80 degrees or less.66. The silicone hydrogel contact lens of claim 65 , wherein the PEG chains are derived from at least one member selected from the group consisting of: PEG-N H; HN-PEG-NH; HN-PEG-COOH; a multi-arm PEG with one or more amino groups; a PEG dendrimer with one or more amino groups; and combinations thereof.67. The silicone ...

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21-01-2021 дата публикации

WATER-BASED INKS WITH RENEWABLE MATERIALS

Номер: US20210017418A1
Автор: VanOudenhoven Guy
Принадлежит: SUN CHEMICAL CORPORATION

Described herein are water-based varnishes and inks that include a high renewable carbon content polyamide in an aqueous dispersion and a water-insoluble particulate material. The inks and varnishes exhibit stable viscosity, that is, they are varnishes and inks that exhibit little to no viscosity change over an extended period of time. Further, the inks and varnishes exhibit little to no settling of the insoluble particulate material over an extended period of time. The water-based varnishes include an aqueous polyamide resin dispersion and an additive selected from a water-insoluble particulate material, and the polyamide resin has a renewable carbon content of ≥50 wt %. 1. A water-based varnish comprising:an aqueous polyamide resin dispersion and an additive selected from a water-insoluble particulate material, wherein the polyamide resin has a renewable carbon content of ≥50% and the presence of the polyamide resin reduces settling of the water-insoluble particulate material.2. The water-based varnish of claim 1 , further comprising an acrylate polymer.3. The water-based varnish of claim 1 , wherein the polyamide resin is soluble in alcohol or a co-solvent blend of alcohol and a hydrocarbon.4. The water-based varnish of claim 3 , wherein the alcohol is a Cto Calcohol.5. The water-based varnish of claim 1 , wherein the aqueous polyamide resin dispersion has a solids content of 30 wt % to 60 wt % claim 1 , preferably 35 wt % to 55 wt % claim 1 , more preferably 40 wt % to 50 wt %.6. The water-based varnish of claim 1 , wherein the aqueous polyamide resin dispersion has a pH at 25° C. of 6.5 to 9.5 claim 1 , preferably 7.0 to 9.0 claim 1 , more preferably 7.5 to 8.5.7. The water-based varnish of claim 1 , wherein the aqueous polyamide resin dispersion has a viscosity of 300 cps to 20 claim 1 ,000 cps claim 1 , preferably 375 cps to 575 cps claim 1 , more preferably 425 cps to 525 cps.8. The water-based varnish of claim 1 , wherein the aqueous polyamide resin ...

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28-01-2016 дата публикации

FLEXIBLE TUBE FOR ENDOSCOPES AND METHOD FOR PRODUCING SAME

Номер: US20160024343A1
Принадлежит: FUJIFILM Corporation

The present invention provides a flexible tube having a cylindrical flexible tube base that has flexibility and a resin layer that coats the flexible tube base, in which the resin layer is configured by at least two layers of a first layer that contains a specific resin and a second layer that contains a specific resin, or in which the resin layer is a single layer or multiple layers of two or more layers, and a layer A that is any of the resin layers includes polyester elastomers, and, hindered phenol compounds or hindered amine compounds. 1. A flexible tube having a cylindrical flexible tube base that has flexibility and a resin layer that coats the flexible tube base ,wherein the resin layer is configured by at least two layers of a first layer and a second layer,the first layer includes one or more elastomers or chain-extended forms thereof selected from a group consisting of polyester elastomers, polyurethane elastomers, and polyamide elastomers, andthe second layer includes chain-extended forms of two or more elastomers selected from a group consisting of polyester elastomers, polyurethane elastomers, and polyamide elastomers.2. The flexible tube according to claim 1 ,wherein a chain extender for preparing the chain-extended forms of the elastomers is selected from polyfunctional epoxy compounds, polyfunctional isocyanate compounds, polyfunctional amino compounds, oxazoline compounds, carbodiimide compounds, and acid anhydrides.3. The flexible tube according to claim 2 ,wherein the chain-extended form of the elastomer is obtained by adding at least one catalyst selected from amine compounds and tin chelate to the elastomer in addition to the chain extender.4. The flexible tube according to claim 2 ,wherein the chain-extended form of the elastomer is obtained by adding 0.01 to 10 parts by mass of the chain extender with respect to 100 parts by mass of the elastomer.5. The flexible tube according to claim 3 ,wherein the chain-extended form of the elastomer is ...

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26-01-2017 дата публикации

Periodic structured organic films

Номер: US20170022338A1
Принадлежит: Xerox Corp

An ordered structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

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22-01-2015 дата публикации

Carbon Fiber Bundle and Manufacturing Method of the Same

Номер: US20150025191A1
Принадлежит: Teijin Ltd

The present invention relates to a carbon fiber bundle excellent in terms of adhesion to matrix resins and process handleability and less apt to suffer the shedding of the sizing agent in processing steps the carbon fiber bundle being a carbon fiber bundle having a sizing agent adherent to the surface thereof, characterized in that the carbon fiber bundle includes a plurality of carbon fibers and the sizing agent includes a copolyamide resin, the copolyamide resin having both a specific polyamide component and nylon-6 and/or nylon-66 as repeating units and having a melting point of 180° C. or lower, the copolyamide resin preferably having a melting point of 60 to 160° C., or a glass transition temperature of −20 to 50° C.

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10-02-2022 дата публикации

PEM LAYER-BY-LAYER SYSTEMS FOR COATING SUBSTRATES TO IMPROVE BIOACTIVITY AND BIOMOLECULE DELIVERY

Номер: US20220041890A1

The invention relates to polyelectrolyte multilayer coatings and, methods for their preparation and application to substrates to enhance the bioactivity and corrosion protection of the substrates' surface. The invention is particularly suitable for coating substrates employed for medical applications, such as but not limited to medical implant devices for drug and/or biologics delivery in a patient. The substrate has a positive or negative charge. The polyelectrolyte multilayer coatings include at least a first polymer layer and a second polymer layer. The first polymer and second polymer have opposite charges. Each of the polymer layers is individually applied using a layer-by-layer such that an alternating charge multilayer coating is formed. 1. A coated medical implant device , comprising:a charged substrate having a positive charge or a negative charge; and at least one polymer layer comprising a first polymer and having a positive charge; and', 'at least one polymer layer comprising a second polymer and having a negative charge;, 'a plurality of interfacing, individual polymer layers, comprising, 'a polyelectrolyte multilayer coating deposited on the charged substrate, comprisingwherein an initial polymer layer of the plurality of interfacing, individual polymer layers is deposited on the charged substrate and has a charge opposite the charged substrate, andwherein an outer polymer layer of the plurality of interfacing, individual polymer layers forms an exterior surface of the charged substrate; andan active substance deposited on the exterior surface of the charged substrate.2. The device of claim 1 , wherein the charged substrate is selected from the group comprising magnesium metal claim 1 , magnesium alloy claim 1 , iron metal claim 1 , iron alloy claim 1 , ferrous metal and ferrous alloy.3. The device of claim 1 , wherein the charged substrate is degradable.4. The device of claim 1 , wherein the charged substrate is formed by treating a neutral substrate ...

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24-01-2019 дата публикации

Cross-Linked Poly-E-Lysine Non-Particulate Support

Номер: US20190023844A1
Автор: Donald A. Wellings
Принадлежит: SPHERITECH LTD

The invention provides a non-particulate cross-linked poly-ε-lysine polymer. The poly-ε-lysine and cross linker are linked by amide bonds and may the cross linker has at least two functional groups capable of reacting with an alpha carbon amine of poly-ε-lysine. The polymer is suitably insoluble in water and other solvents and is provided in macro form for example a sheet, article or fibre. The macro form polymer is useful in a wide range of applications including wound treatment, as a medical diagnostic comprising a particulate support and a functional material bound or retained by the support and solid phase synthesis of peptides, oligonucleotides, oligosaccharides, immobilisation of species, cell culturing and in chromatographic separation.

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24-04-2014 дата публикации

Polyester Quaternary Salt and Compositions Thereof

Номер: US20140114019A1
Принадлежит: Lubrizol Corp

The invention relates to a composition containing a particulate solid; an organic medium; and a quaternised polyester salt which comprises a product obtained/obtainable by reaction of (i) a polyester containing a tertiary amino group; and (ii) a quaternising agent suitable for converting the tertiary amino group to a quaternary nitrogen, wherein the quaternising agent is a hydrocarbyl epoxide in combination with an acid, or mixtures thereof. The invention further relates to the use of the product as a dispersant. The invention further relates to the use of the dispersant in media, such as inks, mill bases, plastics and paints.

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29-01-2015 дата публикации

CLEAR COAT COMPONENT

Номер: US20150031807A1
Принадлежит:

A curable clear coat component for use in a two-component clear coat coating composition system is provided. The curable clear coat component comprises A) a polyaspartic acid ester or a hydroxyl functional binder or a combination of both, and B) an antioxidant component comprising B1) a sterically hindered phenol antioxidant, and B2) an organophosphite antioxidant. 1. A curable clear coat component for use in a two-component clear coat coating composition system , said curable clear coat component comprising:A) a polyaspartic acid ester or a hydroxyl functional binder or a combination of both, and B1) a sterically hindered phenol antioxidant and', 'B2) an organophosphite antioxidant., 'B) an antioxidant component comprising'}3. The curable clear coat component of claim 2 , wherein n is 2 or 3.4. The curable clear coat component of claim 1 , comprising the hydroxyl functional binder claim 1 , wherein the hydroxyl functional binder comprises a hydroxyl-functional (meth)acrylic copolymer or a polyester oligomer or a combination of both.5. The curable clear coat component of claim 1 , wherein the antioxidant component B) is present in an amount of about 0.5 to about 4.0% by weight relative to the total amount of the curable clear coat component.6. The curable clear coat component of claim 1 , wherein the antioxidant component B) comprises the sterically hindered phenol antioxidant B1) and the organophosphite antioxidant B2) in a ratio by weight of about 3.0:0.5 to about 0.5:3.0.7. The curable clear coat component of claim 1 , wherein the sterically hindered phenol antioxidant B1) comprises butylated hydroxy toluene (BHT).8. The curable clear coat component of claim 1 , wherein the organophosphite antioxidant B2) comprises an organophosphite antioxidant chosen from trisnonylphenylphosphite claim 1 , triphenylphosphite claim 1 , triisodecylphosphite claim 1 , diphenylisodecylphosphite claim 1 , diphenylisooctylphosphite claim 1 , trilaurylphosphite and tris(2 claim 1 ,4- ...

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04-02-2016 дата публикации

THIXOTROPY-INCREASING ADDITIVE AND COMPOSITION CONTAINING SAID ADDITIVE

Номер: US20160032077A1
Принадлежит:

The invention relates to a use of at least one condensation product (A) in the form of the free compound or in the form of a salt of at least one acid as a thixotropy- increasing additive, which condensation product can be obtained by reacting at least one polymerized fatty acid or at least one reaction product (U) of at least two polymerized fatty acids and at least one polyamine having at least two primary amino groups as component (a1) with at least one polyalkylene polyamine, which is capable of forming at least one imidazoline and/or tetrahydropyrimidine unit and which has at least two primary amino groups or at least one primary and at least one secondary amino group, a composition containing at least one such condensation product (A) and at least one thixotropic agent (B), and a use of said composition, which additionally comprises at least one binder (C), as an adhesive, sealant, paint, coating agent, adhesive resin, casting resin, artificial marble, floor covering, polymer concrete, or fiber composite material. 2. The process as claimed in claim 1 , characterized in that the condensation product (A) has a tertiary nitrogen content in the range from 0.5 to 20 wt % claim 1 , based on the total weight of the condensation product (A).3. The process as claimed in claim 1 , characterized in that the condensation product (A) has an amine number in the range from 200 to 1000.4. The process as claimed in claim 1 , characterized in that the condensation product (A) is prepared using at least 0.9 mol of polyalkylenepolyamine per carboxylic acid group of the polymerized fatty acid used as component (a1) or of the reaction product (U) used as component (a1).5. The process as claimed in claim 1 , characterized in that the polymerized fatty acid used as component (a1) or the reaction product (U) used as component (a1) is prepared using at least one at least monounsaturated aliphatic C-Cmonocarboxylic acid.6. The process as claimed in claim 1 , characterized in that the ...

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04-02-2016 дата публикации

Protective water reversible clear coating for substrates

Номер: US20160032143A1
Принадлежит: Conservation Technologies LLC

A protective water reversible clear coating composition for the protection of substrates comprised of water, a volatile base, a film-forming acrylic polymer in a water dispersion form, a second film-forming polymer, specifically poly (2-ethyl-2-oxazoline) that is miscible with the first dispersed acrylic polymer, a poly acidic material (pH specific in terms of its solubility properties), and an alkaline swellable thickener that also can be water soluble as a function of pH and wherein said coating is both water applied and water reversible or re-soluble under specific pH conditions.

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04-02-2016 дата публикации

CARBON NANOMATERIAL-CONTAINING RESIN COMPOSITION AND MOLDED PLASTIC PRODUCT

Номер: US20160032144A1
Принадлежит:

Disclosed are a resin composition and a molded product obtained using the same. By using the resin composition according to the present invention, a molded product having excellent tensile strength, tensile modulus, electromagnetic shielding effects, anti-static effects, and the like may be provided. 1. A resin composition comprising 80 to 99.9 parts by weight of a thermoplastic resin and 0.1 to 20 parts by weight of polycyclic aromatic hydro derivative-comprising nanomaterials.2. The resin composition according to claim 1 , wherein claim 1 , in the polycyclic aromatic hydro derivative-comprising carbon nanomaterials claim 1 , a weight ratio of the carbon nanomaterials to the polycyclic aromatic hydro derivative is 1:0.1 to 1:1.5.3. The resin composition according to claim 1 , wherein the carbon nanomaterials are at least one selected from nanotube claim 1 , graphene claim 1 , and nano fibers.4. The resin composition according to claim 1 , wherein the polycyclic aromatic hydro derivative comprises 2 to 5 fused benzene rings.5. The resin composition according to claim 1 , wherein the polycyclic aromatic hydro derivative comprises at least one functional group selected from trialkyl azanium groups claim 1 , carboxylic acid groups claim 1 , and acylchloride groups.6. The resin composition according to claim 1 , wherein the thermoplastic resin is at least one selected from amide-based polymers claim 1 , ester-based polymers claim 1 , acrylate-based polymers claim 1 , polyketone-based polymers claim 1 , vinyl-based polymers claim 1 , styrene-based polymers claim 1 , polyolefines claim 1 , and polyphenylene ethers.7. The resin composition according to claim 1 , wherein the composition comprises 0.1 to 50 parts by weight of a reinforcement material having a fiber shape.8. The resin composition according to claim 7 , wherein the fiber-shaped reinforcement material is at least one selected from fibers and glass fibers.9. The resin composition according to claim 1 , wherein ...

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17-02-2022 дата публикации

THREE-DIMENSIONAL PRINTING

Номер: US20220049120A1

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant includes an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O=S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S=O, P═O, or C═S. 2. The build material composition as defined in claim 1 , further comprising a second antioxidant selected from the group consisting of a hindered amine claim 1 , an aromatic amine claim 1 , a hindered phenol claim 1 , an inorganic phosphite claim 1 , an organic sulfide claim 1 , and a combination thereof.3. The build material composition as defined in wherein the antioxidant includes the hydrazide having formula (I).4. The build material as defined in wherein A is O=S=O or P═O.5. The build material as defined in wherein the hydrazide is selected from the group consisting of adipic acid dihydrazide claim 3 , oxalyl dihydrazide claim 3 , succinic dihydrazide claim 3 , azelaic dihydrazide claim 3 , sebacic dihydrazide claim 3 , dodecanedioic dihydrazide claim 3 , and a combination thereof.6. The build material as defined in wherein A is C═O claim 3 , and n is 2.7. The build material composition as defined in wherein the antioxidant includes the hydrazide having formula (II).8. The build material composition as defined in wherein the hydrazide is carbohydrazide.9. The build material composition as defined in wherein A is P═O or A is O=S=O.10. The build material composition as defined in wherein the antioxidant is present in the build material composition in an amount ranging from about 0.05 wt % to about 2 wt % claim 1 , based on a total weight of the build ...

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04-02-2021 дата публикации

COATED BIOLOGICAL COMPOSITION

Номер: US20210030688A1
Принадлежит:

A coated biological composition has a mixture of biologic material and a volume of a liquid protectant. The mixture of biologic material has non-whole cellular components or whole cells or combinations of the non-whole cellular components and whole cells, wherein the mixture is compatible with biologic function. The volume of a liquid protectant is intermixed with the mixture of biologic material, wherein the liquid protectant forms a coating externally enveloping each of the non-whole cellular components, if any, and each of the whole cells, if any, of the mixture of biologic material, to form the coated biological composition. The coated biological composition is frozen and thereafter thawed and then frozen a second time for storage or frozen at least once and thawed and stored under refrigeration above freezing, or frozen and thawed and then concentrated by drying, or while frozen without thawing lyophilized for ambient or room temperature storage. 1. A method of making a coated biological composition comprises the steps of:collecting, recovering and processing bone marrow from a cadaver donor;mechanically separating cellular and non-cellular components of bone marrow from cadaverous bone;concentrating by centrifugation and filtering;separation by density gradient centrifugation;collecting non-cellular fractions or non-cellular components or combinations thereof of predetermined density;washing the non-cellular fractions or non-cellular components or combinations thereof to create a mixture;quantifying non-whole cell fraction concentration exceeds zero;suspending the mixture to a predetermined concentration in a liquid protectant to coat the mixture and form the coated biological composition;freezing the suspended mixture at a predetermined controlled rate; andthereafter thawing and then freezing a second time for storage or frozen at least once thawed and stored under refrigeration above freezing, or frozen and thawed and then concentrated by drying, or while ...

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04-02-2021 дата публикации

LAMINATED MULTILAYER POLYMER CONTAINING FILM COMPRISING A COPOLYAMIDE OF A DIAMINE, A DIMER ACID AND A LACTAM

Номер: US20210032405A1
Принадлежит: BASF SE

A laminated multilayer polymer containing film (P) comprises at least one layer comprising at least one copolyamide wherein the copolyamide is prepared by polymerizing the following components: (A) 15% to 84% by weight of at least one lactam, (B) 16% to 85% by weight of a monomer mixture (M) comprising the following components: (B1) at least one C32-C40 dimer acid and (B2) at least one C4-C12 diamine, where the percentages by weight of components (A) and (B) are each based on the sum total of the percentages by weight of components (A) and (B) and wherein the laminated multilayer polymer containing film (P) comprises at least one further layer, where the at least one further layer is selected from the group consisting of (i) at least one further polymer (FP) selected from the group consisting of polyolefins, poly(ethylene-vinyl alcohols), poly(ethylene-vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides, maleic anhydride-grafted polyolefins, polyesters and ionomers and (ii) aluminum metal and/or tin metal. 1. A laminated multilayer polymer containing film (P) comprising at least one layer , the at least one layer comprising at least one copolyamide ,wherein the at least one copolyamide is prepared by polymerizing the following components:(A) 15% to 84% by weight of at least one lactam, and [{'sub': 32', '40, '(B1) at least one C-Cdimer acid, and'}, {'sub': 4', '12, '(B2) at least one C-Cdiamine,'}], '(B) 16% to 85% by weight of a monomer mixture (M) comprising the following componentswhere the percentages by weight of components (A) and (B) are each based on the sum total weight of components (A) and (B), and (i) at least one further polymer (FP) selected from the group consisting of polyolefins, poly(ethylene-vinyl alcohols), poly(ethylene-vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides, maleic anhydride-grafted polyolefins, polyesters, and ionomers, and', '(ii) aluminum metal and/or tin metal., 'wherein the laminated ...

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02-02-2017 дата публикации

PRINTED ELECTRONICS

Номер: US20170034912A1
Принадлежит:

Printed electronic device comprising a substrate onto at least one surface of which has been applied a layer of an electrically conductive ink comprising functionalized graphene sheets and at least one binder. A method of preparing printed electronic devices is further disclosed. 12-. (canceled)3. A printed electronic device , comprising:a substrate comprising at least one surface;an electrically conductive ink applied to a portion of the at least one surface;wherein the electrically conductive ink comprises functionalized graphene sheets and at least one binder;wherein the functionalized graphene sheets completely comprise fully exfoliated single sheets of graphene; andwherein the functionalized graphene sheets comprise an X-ray or electron diffraction pattern that displays little or no signature corresponding to graphite or graphite oxide.4. The printed electronic device of claim 3 , wherein the electrically conductive ink is a gel.5. The printed electronic device of claim 3 , wherein the printed electronic device is selected from the group consisting of: a complete device claim 3 , a sub-element of a device claim 3 , and an electronic component.6. The printed electronic device of claim 3 , further comprising a material applied between the substrate and the electrically conductive ink claim 3 , wherein the material is selected from the group consisting of: a semiconductor claim 3 , a metal foil claim 3 , and a dielectric material.7. The printed electronic device of claim 3 , wherein the single sheets of graphene have a carbon to oxygen ratio of at least about 100:1.8. The printed electronic device of claim 3 , wherein the electrically conductive ink further comprises a metal-coated material claim 3 , and wherein the metal-coated material comprises one or more of: a particle claim 3 , a powder claim 3 , flakes claim 3 , a foil claim 3 , and a needle.9. The printed electronic device of claim 3 , wherein the electrically conductive ink further comprises a metal- ...

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05-02-2015 дата публикации

INK COMPOSITION FOR DECORATING NON-POROUS SUBSTRATES

Номер: US20150038616A1
Принадлежит: TORRECID, S.A.

The present invention relates to an ink composition for decorating non-porous substrates for printing on non-porous surfaces that are subjected to heat treatment after printing, and comprising at least one organic solvent as a vehicle which is liquid at room temperature and is made up of linear or non-linear n-alkane hydrocarbons, at least one binder composition with submicrometric particles of a glass frit, and at least one ceramic pigment corresponding to the color of the ink and to the etching of the ink. 147-. (canceled)48. An ink composition for non-porous substrates , for printing on non-porous surfaces of the type that are subjected to heat treatment after printing , characterized in that the composition comprises:a. At least one organic solvent as a vehicle which is liquid at room temperature and comprises linear or non-linear alkane hydrocarbons,b. At least one binder composition with submicrometric particles of a glass frit with a size less than 0.40 micrometers, andc. At least one ceramic pigment corresponding to the color of the ink and to the etching of the ink.49. The ink composition according to claim 48 , characterized in that the percentage by weight of the glass frit is comprised between 20% and 35% of the total weight.50. The ink composition according to claim 49 , wherein the glass frit comprises primarily of Si claim 49 , B and Zn oxides and salts.51. The ink composition according to claim 49 , wherein the glass frit comprises primarily of Si claim 49 , B claim 49 , Bi and Zn oxides and salts.52. The ink composition according to claim 48 , characterized in that the size of the submicrometric particles of the ceramic pigments is less than 0.40 micrometers.53. The ink composition according to claim 48 , characterized in that the percentage by weight of the ceramic pigments is comprised between 5% and 25% of the total weight.54. The ink composition according to claim 48 , characterized in that the ceramic pigments are selected from simple oxides ...

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05-02-2015 дата публикации

NOVEL POLYMER DISPERSANTS

Номер: US20150038640A1
Принадлежит: BASF SE

The present invention relates to novel polymer dispersants and to a liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The polymer dispersants have at least one functional moiety of the formula I, which is bound to one of the termini or to the backbone of the polymer: (I) where # indicates the point of attachment to the terminus and/or to the polymer backbone; k is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9, A is a chemical bond or a divalent moiety selected from the group consisting of C-Calkylene, —O—(C-Calkylene), —C(═O—O—(C-Calkylene), —NR—(C-Calkylene) and C(═O)—NR—(C-Calkylene), where the C-Calkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of —O—, —NH— and —S—; Ris independently selected from the group consisting of —OH, —COOH, —COOCH, —NH, —NH(C-Calkyl), —N(C-Calkyl), —NO, —S(═O)R, C-Calkyl, C-Calkoxy, halogen, aryloxy, aryl, heteroaryl; Ris selected from the group consisting of hydrogen, —S(═O)R, C-Calkyl, C-Ccycloalkyl, aryl, heteroaryl, aryl-C-C-alkyl and heteroaryl-C-C-alkyl; Ris selected from the group consisting of hydrogen, —S(═O)R, C-Calkyl, C-Ccycloalkyl, aryl and heteroaryl; Ris selected from the group consisting of OH, —NH, —NH(C-Calkyl), —N(C-Calkyl), C-Calkyl, C-Calkoxy, aryl and heteroaryl. 2. The composition according to claim 1 , whereink is 0 or 1;m is 0 or 1;{'sub': 2', '4', '2', '4, 'A is a chemical bond or a divalent moiety selected from the group consisting of —C(═O)—O—(C-Calkylene) and C(═O)—NH—(C-Calkylene), where the alkylene part is attached to Q;'}Q is a divalent moiety selected from the group consisting of —O— and —NH—;{'sup': 1', '4, 'sub': 3', '2', '1', '6', '1', '6', '2', '2', '2', '1', '4', '1', '4, 'Ris independently selected from the group consisting of —OH, —COOH, —COOCH, —NH, —NH(C-Calkyl), —N(C-Calkyl), —NO, —S(═O)R, C-Calkyl, C-Calkoxy, halogen, phenyl and pyridyl;'}{'sup': '2', 'sub': 1', '4 ...

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09-02-2017 дата публикации

Membranes and method for the production thereof

Номер: US20170036173A1

The invention concerns the field of polymer chemistry and relates to membranes, such as those used as membranes for the preparation of aqueous solutions by means of reverse osmosis or microfiltration, ultrafiltration or nanofiltration, for example. The object of the present invention is the specification of membranes that exhibit a reduced fouling tendency with equally suitable or improved filtration properties, as well as the specification of a simple and cost-effective method for the production thereof. The object is attained with membranes comprising a substrate on which a porous supporting layer is arranged, on which supporting layer a separation-active layer is arranged, and on which separation-active layer a cover layer is also arranged, wherein the material of the separation-active layer comprises functional groups which primarily have carbon-carbon triple bonds and/or carbon-nitrogen triple bonds, and wherein the material of the cover layer has functional groups which are primarily at least azide groups, and the functional groups having at least carbon-carbon triple bonds and/or carbon-nitrogen triple bonds are chemically coupled covalently with the azide groups.

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09-02-2017 дата публикации

3D Print Bed Having Permanent Coating

Номер: US20170036403A1
Принадлежит:

A coated print bed for a 3D printer having a permanent print-surface coating permanently secured to a print bed substrate plate, having a smooth, planar surface that provides an adhesive interface layer between a first layer of an applied plastic print material and the coated print bed. The coating contains a matrix-forming compound, such as a solvent- or water-based epoxy resin, an adhesive material, and optionally a filler. The user can print a series of print object directly onto the permanent print surface coating of the coated print bed, without having to refresh or refurbish the print surface, such as by applying to the print bed surface a temporary coating such as painter's tape, or a liquid adhesive. 1. A coated print bed for a three-dimensional (3D) printer , comprising a permanent print-surface coating permanently secured to a print bed substrate plate that provides an adhesive interface layer between a first layer of an applied plastic print material and the coated print bed.2. The coated print bed according to wherein the permanent print-surface coating is applied to an upper surface of the print bed substrate plate claim 1 , and has a smooth claim 1 , planar interface surface.3. The coated print bed according to wherein the permanent print-surface coating comprises a composite material comprising a matrix-forming compound or composition claim 1 , and one or more of material selected from the group consisting of a filler material and an adhesive material.4. The coated print bed according to wherein the permanent print-surface coating comprises a mixture of a thermosetting polymer and a thermoplastic material that provides adhesion performance properties for the surface of the permanent print-surface coating.5. The coated print bed according to wherein the thickness of the permanent print-surface coating is at least about 0.5 mil claim 3 , and up to about 5 mil claim 3 , and preferably about 1 mil to 2 mil.6. The coated print bed according to wherein the ...

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11-02-2016 дата публикации

Process for manufacturing polyamide

Номер: US20160039974A1

In one or a plurality of embodiments, a process for manufacturing polyamide, with a reduced use of an amide-based solvent in synthesis, is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (1) to (3): (1) dissolving diamine in a non-amide-based organic solvent or a non-amide-based organic solvent containing 10 mass% or less of an amide-based organic solvent; (2) adding diacid dichloride to a solution obtained in the step (1) and reacting the diamine with the diacid dichloride so as to generate polyamide; and (3) adding a trapping reagent capable of trapping hydrochloric acid.

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09-02-2017 дата публикации

SILICONE HYDROGEL LENS WITH A CROSSLINKED HYDROPHILIC COATING

Номер: US20170037276A1
Принадлежит:

The invention is related to a cost-effective method for making a silicone hydrogel contact lens having a crosslinked hydrophilic coating thereon. A method of the invention involves heating a silicone hydrogel contact lens in an aqueous solution in the presence of a water-soluble, highly branched, thermally-crosslinkable hydrophilic polymeric material having positively-charged azetidinium groups, to and at a temperature from about 40° C. to about 140° C. for a period of time sufficient to covalently attach the thermally-crosslinkable hydrophilic polymeric material onto the surface of the silicone hydrogel contact lens through covalent linkages each formed between one azetidinium group and one of the reactive functional groups on and/or near the surface of the silicone hydrogel contact lens, thereby forming a crosslinked hydrophilic coating on the silicone hydrogel contact lens. Such method can be advantageously implemented directly in a sealed lens package during autoclave. 120-. (canceled)21. A contact lens packaging solution , which is an aqueous solution comprising at least one buffering agent in an amount sufficient to maintain a pH of from about 6.0 to about 8.5 and from about 0.01% to about 2% by weight of a water-soluble and thermally-crosslinkable hydrophilic polymeric material;wherein the water-soluble and thermally-crosslinkable hydrophilic polymeric material which comprises (i) from about 20% to about 95% by weight of first polymer chains derived from an epichlorohydrin-functionalized polyamine or polyamidoamine, (ii) from about 5% to about 80% by weight of hydrophilic moieties or second polymer chains derived from at least one hydrophilicity-enhancing agent having at least one reactive functional group selected from the group consisting of amino group, carboxyl group, thiol group, and combination thereof, and (iii) positively-charged azetidinium groups which are parts of the first polymer chains or pendant or terminal groups covalently attached to the ...

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11-02-2016 дата публикации

Fibers of Polymer-Wax Compositions

Номер: US20160040334A1
Принадлежит:

Disposable article that include fibers formed from compositions comprising thermoplastic polymers and waxes are disclosed, where the wax is dispersed throughout the thermoplastic polymer. 1. A nonwoven comprising:a. a first fiber layer comprising a plurality of fibers, each of which comprising an intimate admixture of a [polyolefin] thermoplastic polymer, and a wax and/or oil, wherein at least some of the wax and/or oil is exposed at an outer surface of the fibers; andb. a second fiber layer that is adjacent the first fiber layer and that comprises a plurality of cellulosic fibers.2. The nonwoven of claim 1 , wherein the plurality of fibers comprise an intimate admixture of the polyolefin thermoplastic polymer claim 1 , the wax claim 1 , and the oil.3. The nonwoven of claim 1 , wherein the plurality of fibers comprise bicomponent fibers comprising a first component and a second component claim 1 , and wherein the wax or oil is primarily included in just one of the first component and the second component.4. The nonwoven of claim 1 , wherein the nonwoven comprises fine fibers having a diameter of from 0.1 microns to about 5 microns.5. The nonwoven of claim 1 , wherein the wax and/or oil comprises a stearic acid.6. The nonwoven of claim 1 , wherein the wax and/or oil comprises a triglyceride.7. The nonwoven of claim 1 , wherein the cellulosic fibers comprise rayon fibers.8. The nonwoven of claim 1 , wherein the nonwoven comprises mechanical entanglement claim 1 , hydrodynamic entanglement claim 1 , or needle punching.9. The nonwoven of claim 1 , further comprising an additive associated with the wax and/or oil.10. The nonwoven of claim 9 , wherein the additive is a perfume.11. The nonwoven of claim 9 , wherein the additive is a colorant.12. The nonwoven of wherein the colorant comprises a pigment or dye.13. The nonwoven of claim 12 , wherein the pigment or dye is selected from the group comprising yellow pigment claim 12 , red pigment claim 12 , blue pigment claim 12 ...

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08-02-2018 дата публикации

THIN CORROSION PROTECTIVE COATINGS INCORPORATING POLYAMIDOAMINE POLYMERS

Номер: US20180037770A1
Принадлежит:

Anti-corrosion metal pretreatment compositions comprising a Group IVB metal, a Group IB metal and polyamidoamine polymers; replenisher compositions for the metal pretreatment compositions; methods of making the metal pretreatment compositions; methods of forming an anti-corrosion Group IVB oxide coating on at least one metal substrate surface by contacting the surface with the metal pretreatment composition; and coated metal substrates having anti-corrosion coatings deposited on the metal substrates from chrome VI free, anti-corrosion metal pretreatment compositions having enhanced corrosion resistance of the Group IVB metal oxide coatings and adhesion of the anti-corrosion and primer coating layers to metal substrates. 2. The anti-corrosion metal pretreatment composition of claim 1 , wherein the polymer c) has a viscosity at 25° C. of 1 to 400 poise.3. The anti-corrosion metal pretreatment composition of claim 1 , wherein the polymer c) comprises a plurality of amine functional groups in addition to the amide functional groups.4. The anti-corrosion metal pretreatment composition of claim 3 , wherein the polymer c) has an amine value in a range of 100 to 1000 mg KOH/gram of polymer.5. The anti-corrosion metal pretreatment composition of claim 1 , wherein c) remains stably dissolved and/or dispersed in the composition against spontaneous separation or segregation of bulk phases that is perceptible with normal unaided human vision during storage at 25° C. for at least 10 days after preparation of the pretreatment composition.6. The anti-corrosion metal pretreatment composition of claim 1 , wherein the Group IVB metal is zirconium and the polymer c) comprises at least one polyamidopolyamine polymer.7. The anti-corrosion metal pretreatment composition of claim 6 , wherein the at least one polyamidopolyamine polymer has a weight average molecular weight ranging from 200 to 10 claim 6 ,000 Daltons.8. The anti-corrosion metal pretreatment composition of claim 1 , wherein ...

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24-02-2022 дата публикации

THREE-DIMENSIONAL PRINTING

Номер: US20220056284A1

An example of a build material composition for three-dimensional (3D) printing includes a polyamide material and an antioxidant. The antioxidant consists of an aromatic multihydrazide; or an aromatic sulfonomonohydrazide; or a hydrazide having formula (I) disclosed herein, wherein: R is null, a C1 to C12 unbranched alkyl, a C3 to C8 branched alkyl, a C2 to C8 unbranched alkylene, a C4 to C8 branched alkylene, an alicyclic compound, a polyethylene glycol, or a combination thereof; A is C═O, O═S═O, P═O, or C═S; and n is an integer ranging from 1 to 4; or formula (II) disclosed herein wherein A is C═O, O═S═O, P═O, or C═S. 2. The build material composition as defined in wherein the antioxidant is the hydrazide having formula (I).3. The build material composition as defined in wherein A is O═S═O or P═O.4. The build material composition as defined in wherein the hydrazide is selected from the group consisting of adipic acid dihydrazide claim 2 , oxalyl dihydrazide claim 2 , succinic dihydrazide claim 2 , azelaic dihydrazide claim 2 , sebacic dihydrazide claim 2 , dodecanedioic dihydrazide claim 2 , and a combination thereof.5. The build material composition as defined in wherein A is C═O and n is 2.6. The build material composition as defined in wherein the antioxidant is the hydrazide having formula (II).7. The build material composition as defined in wherein A is O═S═O or P═O.8. The build material composition as defined in wherein the hydrazide is carbohydrazide.9. The build material composition as defined in wherein the antioxidant is present in the build material composition in an amount ranging from about 0.05 wt % to about 2 wt % claim 1 , based on a total weight of the build material composition.11. The kit as defined in wherein the antioxidant is the hydrazide having formula (I) claim 10 , and the antioxidant is present in the build material composition in an amount J ranging from about 0.05 wt % to about 2 wt % claim 10 , based on a total weight of the build ...

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18-02-2016 дата публикации

METAL-COATING MATERIAL

Номер: US20160046836A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

The present invention provides a metal coating material containing a polyether polyamide (A) in which a diamine constituent unit thereof includes constituent units derived from a polyether diamine compound (a-1) having a specified structure and a xylylenediamine (a-2), and a dicarboxylic acid constituent unit thereof includes a constituent unit derived from an α,ω-linear aliphatic dicarboxylic acid (a-3) having from 4 to 20 carbon atoms, the metal coating material having favorable abrasion resistance and oil resistance and excellent adhesive properties to metals. 2. The metal coating material according to claim 1 , wherein a metal base material to be coated with the metal coating material comprises at least one metal selected from the group consisting of aluminum claim 1 , iron claim 1 , copper claim 1 , zinc claim 1 , and silver.3. The metal coating material according to claim 1 , wherein a proportion of the constituent unit derived from the polyether diamine compound (a-1) in the diamine constituent unit of the polyether polyamide (A) is 5 to 50% by mole.4. The metal coating material according to claim 1 , wherein the xylylenediamine (a-2) is m-xylylenediamine claim 1 , p-xylylenediamine claim 1 , or a mixture thereof.5. The metal coating material according to claim 1 , wherein the α claim 1 ,ω-linear aliphatic dicarboxylic acid (a-3) is adipic acid claim 1 , sebacic acid claim 1 , or a mixture thereof. The present invention relates to a metal coating material which can be used for a metal coating application.Polyamides have not only excellent mechanical properties, such as abrasion resistance, impact resistance, etc., but also excellent chemical resistance to a large number of substances, such as hydrocarbons, bases, inorganic acids, etc., and therefore, they are widely used for a coating application to metal base materials.However, it is known that the polyamides are insufficient in terms of adhesive properties to metals.For the purpose of enhancing the adhesive ...

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16-02-2017 дата публикации

COLLOIDS CONTAINING POLYARAMIDE

Номер: US20170044398A1
Принадлежит:

Colloids include a polyaramide and conductive materials, wavelength-converting materials, and/or light diffusing material. The colloid can be coated and optionally aligned on a substrate to form a film, and the film can be removed from the substrate to form a standalone film. 2. (canceled)3. (canceled)4. (canceled)5. (canceled)6. (canceled)7. (canceled)8. (canceled)9. The colloid of claim 1 , wherein the wavelength-converting material comprises a phosphor and the weight/weight % of phosphor to the polyaramide is between 50 and 300.10. The colloid of claim 1 , wherein the wavelength-converting material comprises a phosphor and the volume % of phosphor to the polyaramide is between 10 and 50.11. The colloid of claim 1 , wherein the wavelength-converting material comprises quantum dots and further wherein the weight/weight % of quantum dots to the polyaramide is between 0.1 and 10.12. The colloid of claim 1 , wherein the wavelength-converting material comprises quantum dots and further wherein the volume % of quantum dots to the polyaramide is between 0.02 and 3.13. The colloid of claim 1 , wherein the dispersed phase further comprises light diffusing material and the light diffusing material comprises organic polymer claim 1 , glass claim 1 , quartz claim 1 , fumed silica claim 1 , silicon dioxide claim 1 , titanium dioxide claim 1 , aluminum oxide claim 1 , calcium carbonate claim 1 , zinc sulfide claim 1 , zinc oxide claim 1 , antimony oxide claim 1 , or barium sulfate.14. The colloid of claim 13 , wherein the volume % of light diffusing material to the polyaramide is between 10 and 50.15. The colloid of claim 13 , wherein the weight/weight % of light diffusing material to the polyaramide is between 3 and 90.16. The colloid of claim 13 , wherein the dispersion medium is aqueous.17. The colloid of claim 13 , further comprising polyester.18. The colloid of claim 17 , wherein the weight/weight % of polyester to the polyaramide is between 50 and 100.19. A film ...

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15-02-2018 дата публикации

SILICONE HYDROGEL LENSES WITH WATER-RICH SURFACES

Номер: US20180044549A1
Принадлежит:

The invention is related to a hydrated silicone hydrogel contact lens having a layered structural configuration: a lower water content silicone hydrogel core (or bulk material) completely covered with a layer of a higher water content hydrogel totally or substantially free of silicone. A hydrated silicone hydrogel contact lens of the invention possesses high oxygen permeability for maintaining the corneal health and a soft, water-rich, lubricious surface for wearing comfort. 164-. (canceled)66. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.67. The silicone hydrogel contact lens of claim 66 , wherein the outer surface hydrogel layer has a thickness of from about 0.25 μm to about 15 μm.68. The silicone hydrogel contact lens of claim 66 , wherein the outer surface hydrogel layer has a thickness of from about 0.25 μm to about 15 μm.69. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a thickness of from about 0.5 μm to about 12.5 μm.70. The silicone hydrogel contact lens of claim 69 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.71. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a thickness of from about 1 μm to about 10 μm.72. The silicone hydrogel contact lens of claim 71 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.73. The silicone hydrogel contact lens of claim 65 , wherein the PEG chains which are derived from at least one member selected from the group consisting of: PEG-NH; PEG-SH; PEG-COOH; HN-PEG-NH; HOOC-PEG-COOH; HS-PEG-SH; HN-PEG-COOH; HOOC-PEG-SH; HN-PEG-SH; a multi-arm PEG with one or more amino claim 65 , carboxyl or thiol groups; a PEG dendrimer with one or more amino claim 65 , carboxyl or thiol groups; and combinations thereof.74. The silicone hydrogel contact lens of wherein ...

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25-02-2016 дата публикации

PEM LAYER-BY-LAYER SYSTEMS FOR COATING SUBSTRATES TO IMPROVE BIOACTIVITY AND BIOMOLECULE DELIVERY

Номер: US20160053134A1

The invention relates to polyelectrolyte multilayer coatings and, methods for their preparation and application to substrates to enhance the bioactivity and corrosion protection of the substrates' surface. The invention is particularly suitable for coating substrates employed for medical applications, such as but not limited to medical implant devices for drug and/or biologics delivery in a patient. The substrate has a positive or negative charge. The polyelectrolyte multilayer coatings include at least a first polymer layer and a second polymer layer. The first polymer and second polymer have opposite charges. Each of the polymer layers is individually applied using a layer-by-layer such that an alternating charge multilayer coating is formed. 1. A coated medical implant device , comprising:a charged substrate having a positive charge or a negative charge; anda polyelectrolyte multilayer coating, comprising:a first layer comprising a first polymer deposited on the charged substrate; anda second layer comprising a second polymer deposited on the first layer,wherein, the first polymer has a charge opposite the charge of the charged substrate and the second polymer has a charge opposite the charge of the first polymer.2. The device of claim 1 , wherein the charged substrate is selected from the group comprising magnesium metal claim 1 , magnesium alloy claim 1 , iron metal claim 1 , iron alloy claim 1 , ferrous metal and ferrous alloy.3. The device of claim 1 , wherein the charged substrate is degradable.4. The device of claim 1 , wherein the charged substrate is formed by treating a neutral substrate with a pretreatment agent.5. The device of claim 4 , wherein the pretreatment agent is selected from the group consisting of alkali metal hydroxide claim 4 , hydrogen fluoride claim 4 , alkali metal carbonates claim 4 , phosphating bath comprising phosphoric acid and other metal phosphate salts claim 4 , and mixtures thereof.6. The device of claim 1 , wherein the first ...

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25-02-2021 дата публикации

FAST PREPARATION OF LOW PRIMARY AMINE CONTAINING POLYASPARTIC ESTERS AND USE OF THESE POLYASPARTIC ESTERS IN SLOW REACTIVITY POLYUREA SYSTEMS

Номер: US20210054146A1
Принадлежит:

Low primary amine (LPA) polyaspartic esters are provided which comprise a reaction product of an aliphatic diamine and an excess of a Michael addition receptor optionally, in the presence of a C-Calcohol, wherein the low primary amine (LPA) polyaspartic ester has a monoaspartate content of less than 10%. The low primary amine (LPA) polyaspartic esters of the invention may find use in slow reactivity polyurea systems and react with polyisocyanates to produce polyurea coatings, adhesives, sealants, films, composites, castings, and paints. 1. A low primary amine (LPA) polyaspartic ester comprising a reaction product of an aliphatic diamine and an excess of a Michael addition receptor , optionally , in the presence of a C-Calcohol ,wherein the low primary amine (LPA) polyaspartic ester has a monoaspartate content of less than 10%.2. The low primary amine (LPA) polyaspartic ester according to claim 1 , wherein the C-Calcohol is ethanol.3. The low primary amine (LPA) polyaspartic ester according to claim 1 , wherein the aliphatic diamine is a cycloaliphatic diamine.4. The low primary amine (LPA) polyaspartic ester according to claim 3 , wherein the cycloaliphatic diamine is selected from the group consisting of isophoronediamine (5-amino-(1-aminomethyl)-1 claim 3 ,3 claim 3 ,3-trimethylcyclohexane) claim 3 , 1 claim 3 ,3-cyclohexanebis(methylamine) claim 3 , 1 claim 3 ,4-cyclohexanebis(methylamine) claim 3 , 4 claim 3 ,4′-diaminodicyclohexylmethane (PACM 20) claim 3 , bis(4-amino-3-methylcyclohexyl)methane claim 3 , 3 claim 3 , 3′-dimethyl-4 claim 3 , 4′-diaminodicyclohexyl-methane (DMDC) claim 3 , isomers thereof claim 3 , salts thereof claim 3 , complexes thereof claim 3 , adducts thereof claim 3 , and any mixtures thereof.5. The low primary amine (LPA) polyaspartic ester according to claim 1 , wherein the Michael addition receptor is selected from the group consisting of dimethyl maleate claim 1 , diethyl maleate claim 1 , dibutyl maleate claim 1 , dimethyl fumarate ...

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25-02-2021 дата публикации

POROSITY REDUCTION BY ENCAPSULATED POLYMERIZING AGENTS

Номер: US20210054215A1
Принадлежит:

A method, composition, and article of manufacture. The method can include depositing a layer, which includes a set of particles and a set of microcapsules encapsulating polymerizing agents. The method can also include fusing particles in selected areas of the layer with a laser, and rupturing at least a portion of microcapsules using at least one energy source selected from the laser, an ultraviolet (UV) radiation source, and a heat source. The composition can include a set of particles and a set of microcapsules, each containing a polymerizing agent encapsulated by a degradable shell. The article of manufacture can include fused layers that include fused particles and pores sealed in reactions with polymerizing agents released from degradable microcapsules. 1. A method , comprising:depositing a layer, the layer comprising a set of particles and a set of microcapsules encapsulating polymerizing agents;fusing, by a laser, particles from the set of particles, wherein the fused particles are in selected areas of the layer; andrupturing, by an energy source, at least one portion of microcapsules from the set of microcapsules, wherein the energy source is at least one energy source selected from the group consisting of the laser, an ultraviolet (UV) radiation source, and a heat source.2. The method of claim 1 , wherein the UV radiation source exposes the at least one portion of microcapsules to electromagnetic radiation having a wavelength below approximately 260 nm.3. The method of claim 1 , wherein the heat source heats the at least one portion of microcapsules to a temperature of approximately 140° C.-180° C.4. The method of claim 1 , wherein the rupturing the at least one portion of microcapsules releases the polymerizing agents into pores in the selected areas of the layer.5. The method of claim 4 , further comprising curing the released polymerizing agents.6. The method of claim 1 , wherein each particle in the set of particles has a diameter between approximately ...

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25-02-2021 дата публикации

POWDER COATING RESINS FROM C12-C23 DIACIDS

Номер: US20210054230A1
Принадлежит:

Powder coating resins and coatings made using the powder coating resins are described. The powder coating resins are based on the use of Cto Cdiacids. The Cto Cdiacids are reacted with a reactant having an alcohol functionality and an amine functionality to form a carboxylic acid terminated polymer having ester and amide functionality. Alternatively, the Cto Cdiacids are reacted with a reactant having an alcohol functionality and an amine functionality to form an intermediate polyol, which is then reacted with acetoacetic acid or an ester thereof to form an acetoacetate-terminated polymer. 1. A powder coating resin comprising:a first carboxylic acid terminated polymer having ester and amide functionality comprising the reaction product of a first C12 to C23 diacid with a first reactant comprising an amine alcohol, or a mixture of a polyamine and a polyol, or a mixture of an amine alcohol and a polyamine, or a mixture of an amine alcohol and a polyol, or combinations thereof; ora first acetoacetate terminated polyol comprising the reaction product of a first intermediate polyol with acetoacetic acid or an ester thereof, and wherein the first intermediate polyol comprises the reaction product of a second C12 to C23 diacid with a second reactant comprising an amine alcohol or a mixture of a polyamine and a polyol, or a mixture of an amine alcohol and a polyamine, or a mixture of an amine alcohol and a polyol, or combinations thereof.2. The resin of further comprising one or more of:a second carboxylic acid terminated polymer having ester and amide functionality comprising the reaction product of a third C12 to C23 diacid with a third reactant comprising an amine alcohol or a mixture of a polyamine and a polyol, or a mixture of an amine alcohol and a polyamine, or a mixture of an amine alcohol and a polyol, or combinations thereof, and wherein the third C12 to C23 diacid used in the second carboxylic acid terminated polymer is different from the first C12 to C23 diacid ...

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23-02-2017 дата публикации

BIODEGRADABLE POLYESTERAMIDE COPOLYMERS FOR DRUG DELIVERY

Номер: US20170051110A1
Автор: Draaisma Guy, Mihov George
Принадлежит:

The present invention relates to a poly (ester amide) (PEA) having a chemical formula described by structural formula (IV), 120.-. (canceled)22. The article or device according to claim 21 , wherein a is at least 0.015 and a:b is from 0.15:0.85 to 0.95:0.05.23. The article or device according to claim 21 , wherein a is at least 0.05 and a:b is from 0.5:0.5 to 0.95:0.05.24. The article or device according to claim 21 , wherein a is at least 0.08 and a:b is from 0.8:0.2 to 0.95:0.05.25. The article or device according to claim 21 , whereinp=0 and m+a+b=1, m=0.75, a=0.125, and b=0.125;wherein the m, a, and b units are randomly distributed;{'sub': 1', '2', '8', '3', '3', '2', '2', '5', '7', '8', '2', '4, 'Ris (CH), Ris (CH)—CH—CH—, Ris hexyl, Ris benzyl, and Ris —(CH)—.'}26. The article or device according to claim 21 , whereinm+p+a+b=1, p=0.45, m=0.3, a=0.125, and b=0.125;wherein the m, p, a, and b units are randomly distributed;{'sub': 1', '2', '8', '3', '4', '3', '2', '2', '5', '2', '20', '7', '8', '2', '4, 'Ris —(CH); Rand Rrespectively, are (CH)—CH—CH—; Ris (C-C)alkylene; Ris benzyl; Ris —(CH)—; and'}{'sub': '6', 'Ris selected from bicyclic-fragments of 1,4:3,6-dianhydrohexitols of structural formula (III).'}27. The article or device according to claim 21 , whereinm+p+a+b=1, p=0.45, m=0.3, a=0.1875, and b=0.0625;wherein the m, p, a, and b units are randomly distributed;{'sub': 1', '2', '8', '4', '3', '2', '2', '7', '8', '2', '4, 'Ris —(CH); Ris (CH)—CH—CH—; Ris benzyl; Ris —(CH)—; and'}{'sub': '6', 'Ris selected from bicyclic-fragments of 1,4:3,6-dianhydrohexitols of structural formula (III).'}28. The article or device according to claim 21 , whereinm+p+a+b=1, p=0.30, m=0.6, a=0.05, and b=0.05;wherein the m, p, a, and b units are randomly distributed;{'sub': 1', '2', '4', '3', '4', '3', '2', '2', '7', '8', '2', '4', '5', '2', '20, 'R—(CH); Rand Rrespectively, are (CH)—CH—CH—; Rbenzyl; Ris —(CH)—; Ris (C-C)alkylene; and'}{'sub': '6', 'Ris selected from bicyclic- ...

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23-02-2017 дата публикации

FUNCTIONAL SELF-HEALING COATINGS AND COMPOSITIONS AND METHODS FOR FORMING SUCH COATINGS

Номер: US20170051157A1
Принадлежит:

Disclosed are coating compositions, methods for preparing the coatings and coatings made therefrom. The coatings have durable functional and damage healing properties. In some embodiments, compositions include a liquid media, surface modified diatomaceous earth (SMDE) particles chemically modified to impart a desired fluid wettability suspended in the liquid media, and microcapsules suspended in the liquid media. The SMDE particles are chemically modified through the use of various silanes imparting hydrophobicity, hydrophilicity, oleophobicity, or oleophilicity. In certain embodiments, the SMDE particles and the microcapsules are in different coating layers. In certain embodiments, compositions are in the form of powder coatings including mixtures of powder epoxy particles, SMDE particles chemically modified to impart a desired fluid wettability, and microcapsules. Disclosed further are methods for coating articles with the coatings and the coated articles. 1. A coating composition capable of forming a coating haying a desired fluid wettability and damage healing ability , comprising:a. a liquid media comprising a liquid;b. a plurality of surface modified diatomaceous earth particles chemically modified to impart the desired fluid wettability suspended in the liquid media; andc. a first plurality of microcapsules containing a resin suspended in the liquid media.2. The coating composition of claim 1 , wherein the plurality of surface modified diatomaceous earth particles is chemically modified with hydrophobic silane.3. The coating composition of claim 1 , wherein the plurality of surface modified diatomaceous earth particles is chemically modified with hydrophilic silane.4. The coating composition of claim 1 , wherein the plurality of surface modified diatomaceous earth particles is chemically modified with oleophobic silane.5. The coating composition of claim 1 , wherein the plurality of surface modified diatomaceous earth particles is chemically modified with ...

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21-02-2019 дата публикации

SILICONE HYDROGEL LENSES WITH WATER-RICH SURFACES

Номер: US20190055427A1
Принадлежит:

The invention is related to a hydrated silicone hydrogel contact lens having a layered structural configuration: a lower water content silicone hydrogel core (or bulk material) completely covered with a layer of a higher water content hydrogel totally or substantially free of silicone. A hydrated silicone hydrogel contact lens of the invention possesses high oxygen permeability for maintaining the corneal health and a soft, water-rich, lubricious surface for wearing comfort. 164-. (canceled)66. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.67. The silicone hydrogel contact lens of claim 66 , wherein the outer surface hydrogel layer has a thickness of from about 0.25 μm to about 15 μm.68. The silicone hydrogel contact lens of claim 66 , wherein the outer surface hydrogel layer has a thickness of from about 0.25 μm to about 15 μm.69. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a thickness of from about 0.5 μm to about 12.5 μm.70. The silicone hydrogel contact lens of claim 69 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.71. The silicone hydrogel contact lens of claim 65 , wherein the outer surface hydrogel layer has a thickness of from about 1 μm to about 10 μm.72. The silicone hydrogel contact lens of claim 71 , wherein the outer surface hydrogel layer has a water-swelling ratio of at least about 200%.73. The silicone hydrogel contact lens of claim 65 , wherein the reactive vinylic monomer is selected from the group consisting of amino-C-Calkyl (meth)acrylate claim 65 , C-Calkylamino-C-Calkyl (meth)acrylate claim 65 , allylamine claim 65 , vinylamine claim 65 , amino-C-Calkyl (meth)acrylamide claim 65 , C-Calkylamino-C-Calkyl (meth)acrylamide claim 65 , acrylic acid claim 65 , C-Calkylacrylic acid claim 65 , N claim 65 ,N-2-acrylamidoglycolic acid claim 65 , and combinations ...

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02-03-2017 дата публикации

METHOD OF MAKING EYEWEAR BY 3D PRINTING

Номер: US20170057159A1
Автор: LAM Yin Sang, Zhang Yan
Принадлежит: OKIA OPTICAL CO., LTD.

Provided herein are methods of preparing eyewear products made of a cellulose ester, a nylon or a polyester by simple and inexpensive single-nozzle or multi-nozzle 3D printers, wherein the eyewear products have a continuous range of colors or a gradual color change. Also provided herein are eyewear products made of a cellulose ester, a nylon or a polyester prepared by the methods disclosed herein. 2. The method of claim 1 , wherein the one or more dye compositions are one or more hydrophilic dye compositions claim 1 , each of which independently comprises a hydrophilic dye and water.3. The method of claim 1 , wherein the thermoplastic resin is cellulose acetate claim 1 , cellulose acetate propionate or a combination thereof.4. The method of claim 1 , wherein the thermoplastic resin is nylon 6 or nylon 12.5. The method of claim 1 , wherein the thermoplastic resin is PETG claim 1 , PCTG or PET-CHDM.6. The method of claim 2 , wherein the volume or weight ratio of the hydrophilic dye to water is from about 1:10 to about 1:20 claim 2 , the dyeing temperature is from about 50° C. to about 80° C. claim 2 , and the dyeing time is from about 30 minutes to about 5 hours.7. The method of claim 2 , wherein the hydrophilic dye comprises a pigment claim 2 , a polymeric surfactant claim 2 , and one or more polar solvents.8. The method of claim 7 , wherein the polymeric surfactant is poly(ethylene glycol) and the one or more polar solvents comprise benzyl alcohol claim 7 , acetone and ethylene glycol.9. The method of claim 1 , wherein the eyewear product is an eyeglass frame comprises a frame front and/or a pair of temples; or the eyewear product is a semi-finished eyewear product or one or more parts of an eyewear product; or the eyewear product includes one or more eyewear sheets suitable for making the eyewear product claim 1 , the semi-finished eyewear product and the one or more parts of an eyewear product.10. The method of claim 1 , wherein the eyewear product is an eyeglass ...

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03-03-2016 дата публикации

High Content Polyamide Hot-Applied Thermoplastic Composition

Номер: US20160060829A1
Принадлежит:

A hot applied thermoplastic pavement composition and method of using is described wherein the composition comprises; a modified polyamide resin in the range of between 3 and 10 percent by weight, wherein the composition contains rosin-modified esters, a copolymer, 30-70 percent by weight of a glass bead intermix, a range of between 1 and 15 percent by weight of either white or yellow pigment, the balance of the composition being selected from the group consisting of; one or more plasticizers, inorganic fillers, waxes, antioxidants and light stabilizers. 1. A hot applied thermoplastic pavement marking composition comprising:{'sup': '2', 'modified polyamide resin in the range of between 3 and 10 percent by weight, wherein said composition contains rosin-modified esters, a copolymer, between 30 and 70 percent by weight of a glass bead intermix, a range of between 1 and 15 percent by weight of either white or yellow pigment, the balance of said composition being selected from the group consisting of; one or more plasticizers, inorganic fillers, waxes, antioxidants, and light stabilizers and wherein said esters are selected from the group consisting of a pentaerythritol modified ester and a maleic modified glycerol rosin ester and wherein said glass beads impart retro-reflectivity in the range of 200-2000 mcd/m/lx.'}2. (canceled)3. The hot applied thermoplastic composition according to claim 1 , wherein said glass beads are 25% AASHTO Type 1 and 25% AASHTO Type 3 glass beads.4. The hot applied thermoplastic composition according to claim 1 , wherein said glass beads are 25% AASHTO Type 1 and 25% AASHTO Type 4 glass beads.5. (canceled)6. The hot applied thermoplastic composition according to claim 1 , wherein said copolymer is ethylene vinyl acetate.7. The hot applied thermoplastic composition according to claim 1 , wherein said one or more plasticizers are castor oil claim 1 , di-isononyl phthalate or both.8. The hot applied thermoplastic composition according to claim 1 ...

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05-03-2015 дата публикации

IMAGE FORMATION METHOD, DECORATIVE SHEET, DECORATIVE SHEET MOLDING, PROCESS FOR PRODUCING IN-MOLD MOLDED PRODUCT, IN-MOLD MOLDED PRODUCT, AND INK SET

Номер: US20150064398A1
Автор: UMEBAYASHI Tsutomu
Принадлежит: FUJIFILM Corporation

The object of the present invention is to provide an image formation method that can give an image that is excellent in terms of adhesion to a substrate, blocking resistance of a resulting printed material, and molding suitability, in particular vacuum forming properties, and that can suppress post-molding cracking of a molding. Disclosed is an image formation method comprising, in order, Step a: a step of applying Liquid A to a substrate, Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90%, Step c: a step of applying Liquid B to a cured layer of the completely cured or semi-cured Liquid A, and Step d: a step of completely curing Liquid A and Liquid B. 1. An image formation method comprising , in order ,Step a: a step of applying Liquid A to a substrate,Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90%,Step c: a step of applying Liquid B to a cured layer of the completely cured or semi-cured Liquid A, andStep d: a step of completely curing Liquid A and Liquid B,Liquid A comprising N-vinylcaprolactam as Component A, an aromatic ring-containing monofunctional acrylate as Component B, an aliphatic hydrocarbon ring-containing monofunctional acrylate as Component C, a polysiloxane compound as Component D, an acrylic resin having a glass transition temperature of 40° C. to 90° C. as Component E, a photopolymerization initiator as Component F, and a pigment as Component G, the content of Component E in Liquid A being at least 0.5 mass % but no greater than 5 mass %, andLiquid B comprising N-vinylcaprolactam as Component A, an aromatic ring-containing monofunctional acrylate as Component B, a polysiloxane compound as Component D, a thermoplastic resin having a glass transition temperature of 70° C. to 110° C. as Component H, and a photopolymerization ...

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10-03-2022 дата публикации

DISPLAY PANEL AND MANUFACTURING METHOD THEREOF

Номер: US20220077422A1
Автор: XIANG Changming
Принадлежит:

A display panel and a manufacturing method thereof are provided. The manufacturing method of the display panel include following blocks: providing a light-emitting element; coating a polymer solution on a light-emitting element and performing a first annealing process to the light-emitting element after it is coated with the polymer solution to form a first protecting layer; and coating an organic compound solution on the first protecting layer so that the organic compound solution is self-assembled on the first protecting layer to form a second protecting layer, wherein the second protecting layer has a crosslinking three-dimensional network structure. 1. A manufacturing method of a display panel , comprising following blocks:providing a light-emitting element;coating a polymer solution on the light-emitting element followed by subjecting the light-emitting element to a first annealing process to form a first protecting layer; andcoating an organic compound solution on the first protecting layer and making the organic compound solution self-assemble on the first protecting layer to form a second protecting layer, wherein the second protecting layer has a crosslinking three-dimensional network structure.2. The manufacturing method of the display panel as claimed in claim 1 , wherein the block of coating the organic compound solution on the first protecting layer and making the organic compound solution self-assemble on the first protecting layer to form the second protecting layer comprises:dispersing an organic compound in a solvent and adjusting hydrogen ion concentration (pH) of the solvent to acidity to form the organic compound solution;coating the organic compound solution on the first protecting layer and making the organic compound solution self-assemble on a surface of the first protecting layer to form a one-dimensional structure; andsubjecting the one-dimensional structure to a second annealing process at an annealing temperature ranging from 25 degrees ...

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05-03-2015 дата публикации

POLY(BUTYLENE-CO-ADIPATE TEREPHTHALATE), METHOD OF MANUFACTURE, AND USES THEREOF

Номер: US20150065610A1
Принадлежит:

A method for preparing poly(butylene terephthalate-co-adipate) copolymer includes reacting (i) poly(butylene terephthalate-co-adipate) oligomers, wherein the oligomers comprise at least one polymer residue derived from a polyethylene terephthalate component and a quencher, with (ii) a chain extender under conditions sufficient to form the poly(butylene terephthalate-co-adipate) copolymer. 115-. (canceled)16. A poly(butylene terephthalate-co-adipate) copolymer having a melt temperature from 100 to 120° C. , whereinthe copolymer comprises a residue derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate, polyethylene terephthalate copolymers, and combinations thereof;a residue of a quencher selected from the group consisting of a phosphorus-containing compound, a nitrogen-containing compound, a boron-containing compound, and combinations thereof; and wherein the poly(butylene terephthalate-co-adipate) copolymer has', 'a melting temperature of 100 to 120° C.;', 'a number average molecular weight of at least 30,000 g/mole;', 'an intrinsic viscosity of at least 1.0 deciliter per minute; and', {'sub': 'g', 'a Tof −30 to −10° C.'}], 'from 0.05 to 1 weight % of a residue of a chain extender selected from the group consisting of isocyanurate, polyisocyanate, isocyanate and combinations thereof, wherein oligomers of poly(butylene terephthalate-co-adipate have been reacted with the chain extender;'}17. The copolymer of claim 16 , comprising from 0.05 to 1 mol % of the quencher residue claim 16 , based on the copolymer.18. The copolymer of claim 16 , wherein residue derived from the polyethylene terephthalate component is selected from ethylene glycol groups claim 16 , diethylene glycol groups claim 16 , isophthalic acid groups claim 16 , and combinations thereof.19. The copolymer of claim 16 , wherein the copolymer comprises less than 10 mole % of ethylene glycol groups claim 16 , based on poly(butylene terephthalate ...

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22-05-2014 дата публикации

Additive Manufacturing with Polyamide Consumable Materials

Номер: US20140141168A1
Автор: Rodgers Luke M.B.
Принадлежит: STRATASYS, INC.

A consumable material for use in an additive manufacturing system, the consumable filament comprising a polyamide blend of at least one semi-crystalline polyamide, and at least one amorphous polyamide that is substantially miscible with the at least one semi-crystalline polyamide, and a physical geometry configured to be received by the additive manufacturing system for printing a three-dimensional part from the consumable material in a layer-by-layer manner using an additive manufacturing technique. The consumable material is preferably capable of printing three-dimensional parts having good part strengths and ductilities, and low curl. 1. A method for printing a three-dimensional part with an additive manufacturing system , the method comprising:providing a consumable material comprising a polyamide blend having at least one semi-crystalline polyamide and at least one amorphous polyamide that is substantially miscible with the at least one semi-crystalline polyamide, wherein the consumable material has a solidification temperature and a glass transition temperature, and wherein the consumable material is capable of printing a three-dimensional part having a curl less than about 0.01 inches pursuant to a Curl Bar Test, and has a relative strength in a conditioned state of at least about 1,600 psi;heating a chamber of the additive manufacturing system or locally heating a deposition region of the additive manufacturing system to a temperature between the solidification temperature and the glass transition temperature of the consumable material;feeding the consumable material to a liquefier assembly retained by the additive manufacturing system;melting the consumable material in the liquefier assembly; andextruding the molten consumable material from the liquefier assembly as a series of roads in the heated chamber or the locally-heated deposition region to print the three-dimensional part in a layer-by-layer manner.2. The method of claim 1 , wherein the at least one ...

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28-02-2019 дата публикации

(Co)POLYAMIDES OBTAINABLE FROM 1,4-CYCLOHEXANEDICARBOXYLIC ACID AND A DIAMINE OF FORMULA H2N-(CH2)2-O-(CH2)2-O-(CH2)2-NH2

Номер: US20190062499A1
Принадлежит:

The present invention relates to (co)polyamides comprising at least 60 mol. % of recurring units of formula (I): (I). The present invention also relates to polymer compositions comprising such (co)polyamides, as well as articles comprising the same and methods of using said articles in high temperature applications requiring sufficient swelling or deformation upon exposure to moisture, such as for example oil and gas extraction processes (e.g. fracturing balls), or as support materials used to print three-dimensional (3D) parts. 115-. (canceled)18. The (co)polyamide of claim 17 , wherein the (co)polyamide is the condensation product of the mixture further comprising one diacid (DA) selected from the group consisting of adipic acid claim 17 , sebacic acid claim 17 , isophthalic acid claim 17 , terephthalic acid claim 17 , 5-hydroxyisophthalic acid claim 17 , and 5-sulfophthalic acid.19. The polyamide of claim 17 , wherein the (co)polyamide is the condensation product of the mixture further comprising one diamine (NN) selected from the group consisting of 1 claim 17 ,4-diaminobutane claim 17 , 1 claim 17 ,5-diamonopentane claim 17 , 1 claim 17 ,6-diaminohexane claim 17 , 1 claim 17 ,10-diaminedecane claim 17 , HN—(CH)—O—(CH)—O(CH)—NH claim 17 , and m-xylylene diamine.20. The (co)polyamide of claim 19 , wherein the diamine (NN) is of formula (IV):{'br': None, 'sub': 2', '2', '3', '2', '2', '2', '3', '2, 'HN—(—CH)—O—(—CH)—O—(CH)—NH\u2003\u2003(IV).'}21. The (co)polyamide of comprising a molar ratio n/nranging from 0.8 to 1.2.22. The (co)polyamide of claim 16 , wherein the (co)polyamide has a melting point of at least 260° C. claim 16 , as determined according to ASTM D3418.23. The (co)polyamide of claim 16 , wherein the (co)polyamide has a water uptake at saturation claim 16 , by immersion in water at 23° C. of at least 2 wt. %.24. The (co)polyamide of claim 16 , wherein the (co)polyamide has a solubility in water of at least 50 wt. % at a concentration of 5 g/L claim ...

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08-03-2018 дата публикации

COATING COMPOSITION AND PAINT PRODUCED FROM SAME

Номер: US20180066141A1
Автор: ROLAND Jean-Francois
Принадлежит: BOLLIG & KEMPER GMBH & CO. KG

The invention relates to a coating composition based on organic or water-based solvent, containing at least one binder (A), optionally at least one cross-linking agent (B), and at least one matting agent (M) based on silicon dioxide (SiO), wherein the coating composition contains a combination of a) a matting agent based on silicon dioxide (SiO) that is surface-modified with one or more waxes, b) an organic matting agent, and c) polyamide particles, and a clear lacquer comprising a coating composition of this type. In this way, automobile series paints can be produced having targeted, adjustable low gloss. 1. A coating composition based on an organic solvent or water-based , comprising at least one binder (A) , optionally at least one cros slinking agent (B) , and at least one matting agent (M) based on silicon dioxide (SiO) , wherein the coating composition comprises a combination of{'sub': '2', 'a) a matting agent based on silica (SiO) surface-modified with one or more waxes, and'}b) an organic matting agent, andc) polyamide particles.2. The coating composition according to claim 1 , wherein the matting agent cased on (SiO) is a matting agent based on silicic acid.3. The coating composition according to claim 1 , wherein the coating composition contains the matting agent based on (SiO) in a range between ≧1 weight-% and ≦5 weight-% claim 1 , based on the total weight of the coating composition.4. The coating composition according to claim 1 , wherein the organic matting agent is a matting agent of urea-oxomethane polymer basis.5. The coating composition according to claim 1 , wherein the coating composition contains the organic matting agent on urea-oxomethane-polymer basis in a range of between ≧1 weight-% and ≦7 weight-% claim 1 , based on the total weight of the coating composition.6. The coating composition according to claim 1 , wherein the coating composition contains the polyamide particles in a range of between ≧3 weight-% and ≦12 weight-% claim 1 , based ...

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11-03-2021 дата публикации

Primer composition, primer coating film and formation method therefor, and formation method for coating film

Номер: US20210071028A1
Автор: Jyunsuke HOKKA
Принадлежит: Nippon Paint Industrial Coatings Co Ltd

Provided is a primer composition capable of forming, in a short time, a primer coating film excellent in adhesion to a metal substrate, adhesion to a polyamide resin-containing finish coating film, and corrosion resistance. A primer composition comprises: a phenol resin (A); a polyamide resin (B); and a solvent (C), wherein the phenol resin (A) is a resol-type phenol resin, the polyamide resin (B) is soluble in the solvent (C), and a solid content mass ratio (A/B) between the phenol resin (A) and the polyamide resin (B) is 80/20 to 99/1.

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28-02-2019 дата публикации

INSULATED WIRE

Номер: US20190066868A1
Принадлежит: TOYOTA JIDOSHA KABUSHIKI KAISHA

An insulated wire has a conductor, and an insulating film including a first insulating layer covering the conductor and a second insulating layer covering the first insulating layer. The second insulating layer contains a polyimide or a polyamideimide as a main component. The first insulating layer contains a reaction product of a carboxylic acid dianhydride and a diamine as an adhesive component and a component that is the same as the main component in the second insulating layer. At least one of the carboxylic acid dianhydride and the diamine has a carbonyl group. 1. An insulated wire comprising:a conductor; andan insulating film including a first insulating layer that covers the conductor; and a second insulating layer that covers the first insulating layer,wherein the second insulating layer contains a polyimide or a polyamideimide as a main component;the first insulating layer contains a reaction product of a carboxylic acid dianhydride and a diamine as an adhesive component and a predetermined component that is the same as the main component in the second insulating layer; andat least one of the carboxylic acid dianhydride and the diamine has a carbonyl group.2. The insulated wire according to claim 1 , wherein a proportion of the polyimide or polyamideimide in the second insulating layer is 50% by weight or more.3. The insulated wire according to claim 2 , wherein the proportion of the polyimide in the second insulating layer is 50% by weight or more.5. The insulated wire according to claim 1 , wherein the first insulating layer contains the adhesive component at a proportion of 0.5 mol % to 5 mol % when a content of the predetermined component is designated as 100 mol %. The disclosure of Japanese Patent Application No. 2017-163111 filed on Aug. 28, 2017 including the specification, drawings and abstract is incorporated herein by reference in its entirety.The disclosure relates to an insulated wire.A coil that is used in a motor, a transformer, and the like ...

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29-05-2014 дата публикации

Fluorine-Containing Polymerizable Monomer And Polymer Compound Using Same

Номер: US20140148548A1
Принадлежит:

The present invention provides a fluorine-containing fluorenediamine of the formula (2): The present invention relates to a novel fluorene-containing polymer compound useful as materials for protective films of electronic circuit boards, protective films of semiconductor devices, gas separation membranes and the like. The present invention also relates to a fluorene-containing polymerizable monomer for the production of the fluorene-containing polymer compound.Aromatic diamine compounds are useful as raw materials for heat-resistant polymers such as polyamide, polyimide and polybenzoxazole. These polymers are used in the fields of automotive vehicles, aerospace applications, fireproof suits etc. because of their high heat resistance. However, many of these polymers are low in solubility in organic solvents and low in moldability. It is thus common practice to, obtain a final molded product of e.g. polyimide or polybenzoxazole by molding an organic solvent-soluble polymer precursor (such as polyamic acid or polyamide-phenol) into a desired shape and converting the polymer precursor to polyimide or polybenzoxazole through dehydration cyclization reaction under high-temperature conditions of 300 to 350° C.The above molding process is however not suitable for the production of relatively low heat-resistant display parts using organic dyes, semiconductor lamination parts having different thermal expansion coefficients and susceptible to residual thermal stresses and the like because the molding temperature is too high. For this reason, attention is being given to organic solvent-soluble polyimide and polybenzoxazole materials that are moldable at temperature levels where organic solvents can be vaporized and volatilizedAs techniques for making the polymers soluble in organic solvents, it is known to: introduce a bent structure e.g. ether bond or methylene bond into the main chain skeletons of the polymers; introduce a bulky structure e.g. tert-butyl group or ...

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17-03-2016 дата публикации

ANTIBIOFOULING MEMBRANES AND METHODS FOR PRODUCTION

Номер: US20160074816A1
Принадлежит: FLINDES UNIVERSITY OF SOUTH AUSTRALIA

Disclosed herein is a composite filtration membrane comprising a porous support membrane and an antibiofouling polyamide layer on the porous support membrane. Also disclosed herein is a method for manufacturing the composite filtration membrane and a cross-linked copolymer. 164-. (canceled)65. A cross-linked copolymer formed by co-polymerisation of an aromatic diamine monomer , an amino zwitterionic monomer and a cross-linking monomer comprising a plurality of amine-reactive functional groups.66. The cross-linked copolymer according to claim 65 , wherein the aromatic diamine monomer is m-phenylenediamine.67. The cross-linked copolymer according to claim 65 , wherein the amino zwitterionic monomer is selected from the group consisting of sulfobetaine claim 65 , phosphobetaine claim 65 , and carboxybetaine monomers.68. The cross-linked copolymer according to claim 65 , wherein the amino zwitterionic monomer is selected from the group consisting of mono-amino and di-amino monomers.70. The cross-linked copolymer according to claim 69 , wherein a is 2.71. The cross-linked copolymer according to claim 69 , wherein b is 1.72. The cross-linked copolymer according to claim 69 , wherein c is 3.73. The cross-linked copolymer according to claim 69 , wherein d is 3.74. The cross-linked copolymer according to claim 69 , wherein Ris methyl.75. The cross-linked copolymer according to claim 69 , wherein Ris H.76. The cross-linked copolymer according to claim 69 , wherein Rand Rare both methyl.77. The cross-linked copolymer according to claim 65 , wherein the cross-linking monomer is an aromatic monomer.79. The cross-linked copolymer according to claim 78 , wherein X is Cl.811. A composite filtration membrane comprising a porous support membrane and an antibiofouling polyamide layer on the porous support membrane claim 78 , said antibiofouling polyamide layer comprising the cross-linked copolymer according to claim .82. A method for producing a composite filtration membrane claim 78 ...

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17-03-2016 дата публикации

SOLUTION OF AROMATIC POLYAMIDE FOR PRODUCING DISPLAY ELEMENT, OPTICAL ELEMENT, ILLUMINATION ELEMENT OR SENSOR ELEMENT

Номер: US20160075913A1
Принадлежит:

The present disclosure, in one aspect, relates to a polyamide solution which can suppress the yellowness. The present disclosure, in one or a plurality of embodiments, relates to a polyamide solution comprising an aromatic polyamide and a solvent, the aromatic polyamide comprising a constitutional unit having one or more free carboxyl groups and having an aromatic ring structure and an alicyclic structure in the main chain. Further, the present disclosure, in one aspect, relates to a laminated composite material, comprising a glass plate and a polyamide resin layer; the polyamide resin layer laminated onto one surface of the glass plate, the polyamide resin layer having yellowness (JIS K7373) of 2.4 or less; and the polyamide resin layer obtained by applying the solution onto the glass plate. 1. A polyamide solution comprising an aromatic polyamide and a solvent ,wherein the aromatic polyamide comprises a constitutional unit having one or more free carboxyl groups and has an aromatic ring structure and an alicyclic structure in the main chain.2. The polyamide solution according to claim 1 , wherein a cast film with a thickness of 9 to 12 μm formed by applying the solution onto a glass plate has yellowness (JIS K7373) of 2.4 or less.3. The solution according to claim 1 , wherein monomer components capable of introducing an alicyclic structure into the main chain account for 4 mole % or more and 50 mole % or less of the total amount of monomer components used for synthesis of the polyamide.4. The solution according to claim 1 , wherein monomer components having a free carboxyl group account for 0.01 mole % or more and 30 mole % or less of the total amount of monomer components used for synthesis of the polyamide.6. The solution according to claim 5 , wherein the polyamide contains multiple constitutional units of the general formulas (I) and (II) claim 5 , and wherein Ar claim 5 , Arand Arare the same or different.7. The solution according to claim 1 , wherein the ...

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15-03-2018 дата публикации

Bpa-free coatings

Номер: US20180072840A1
Принадлежит: Battelle Memorial Institute Inc

Provided are poly(AAG)-compositions, and corresponding coatings, foams, and coated articles. Also provided are methods for preparing the poly(AAG)-compositions and corresponding reagents including. e.g., polyol-AAG compositions. Coatings using the poly(AAG)-compositions may be useful for, e.g., replacing bisphenol-A cross-linked coatings used in food and beverage containers, coating metal articles, and the like.

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07-03-2019 дата публикации

POLYMERS FORMED FROM 2,3,3,3-TETRAFLUOROPROPENE AND ARTICLES AND USES THEREOF

Номер: US20190071585A1
Принадлежит:

The present invention generally relates to a novel polymeric material formed, at least in part, from monomeric material comprising 2,3,3,3-tetrafluoropropene (CFCF═CH, 1234yf), to polymeric compositions, to coating compositions, and to uses thereof. 1. A coating protecting a surface of a marine vessel from biofouling comprising: (a) a coating or impregnating composition comprising: a polymer composition comprising a fluoropolymer consisting essentially of suspension polymerized monomers of HFO-1234yf and vinylidene fluoride , where HFO-1234yf is provided in an amount from greater than 70 wt % to about 90 wt. % of the fluoropolymer and vinylidene fluoride is provided in an amount from about 10 wt. % to less than 30 wt. % of the fluoropolymer , wherein the fluoropolymer is solubilized in at least one of ethyl acetate , acetone , or tetrahydrofuran , wherein the composition comprises from about 1 to about 50 wt. % of the fluoropolymer , such that the surface of the marine vessel is protected from biofouling by said coating.2. The coating composition of claim 1 , wherein the surface tension is between about 15 mN/m and about 30 mN/m.3. The coating composition of claim 3 , wherein said composition further comprises comprising one or more additives selected from the group consisting of silica claim 3 , carbon- or silica-based nano-particules claim 3 , therapeutic agents or compounds claim 3 , high- or low-temperature additives claim 3 , fillers claim 3 , pigments claim 3 , saturants claim 3 , lubricants claim 3 , tackifiers claim 3 , adhesion promoters claim 3 , film-formers claim 3 , thickeners claim 3 , processing aids claim 3 , electrically conductive materials claim 3 , electrically insulative materials claim 3 , stabilizers claim 3 , impact modifiers claim 3 , viscosity modifiers claim 3 , and combinations thereof.4. A film-forming coating composition comprising:a film-forming protecting a surface of a marine vessel from biofouling substrate; and (i) said ...

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24-03-2022 дата публикации

Metal Surface Treatment Agent, and Metal Material Having Film and Manufacturing Method Therefor

Номер: US20220089882A1
Принадлежит:

The present invention addresses the problem of providing, for example, a novel metal surface treatment agent which can form a film capable of maintaining antimicrobial performance on or over a surface of a metal material. The problem can be solved by a metal surface treatment agent containing: a prescribed copolymer (A) obtained by polymerizing a compound (a) represented by the following Formula (1) [in Formula (1), Rand Reach independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, Rand Reach independently represent an alkyl group having 1 to 5 carbon atoms, and X— represents an ion of a halogen atom, or an acid anion] with a compound (b) represented by the following Formula (2) or (3) [in Formula (2), Rrepresents a hydrogen atom or a methyl group, Rand Reach independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, a benzyl group, or a hydroxyalkyl group having 2 or 3 carbon atoms; and, in Formula (3), Rrepresents a hydrogen atom or a methyl group]; and a water-soluble or water-dispersible resin (B). 2. The metal surface treatment agent according to claim 1 , wherein the resin (B) is one or more selected from urethane resins claim 1 , polyvinyl alcohol resins claim 1 , polyamide resins claim 1 , epoxy resins claim 1 , phenolic resins claim 1 , and polyvinylpyrrolidone resins.3. The metal surface treatment agent according to claim 1 , wherein a ratio [A/B] between the mass (A) of the copolymer (A) and the mass (B) of the resin (B) is in a range of 0.05 to 1.0.4. The metal surface treatment agent according to claim 1 , further comprising a crosslinking component (C).5. The metal surface treatment agent according to claim 4 , wherein the crosslinking component (C) is a carboxyl group-containing compound (excluding the copolymer (A)) and/or a water-soluble metal compound.6. The metal surface treatment agent according to claim 4 , wherein a ratio [C/(A+B)] between the mass (C) of the crosslinking component (C) and ...

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07-03-2019 дата публикации

Fibers of Polymer-Wax Compositions

Номер: US20190071801A1
Принадлежит:

A material web is disclosed. The material web includes a fiber layer having a first side and an opposing second side. The fiber layer has a plurality of fibers, each of which having an intimate admixture of a thermoplastic polymer, and a wax and/or oil, wherein at least some of the wax and/or oil is exposed at an outer surface of the fibers. A surface energy treatment is disposed on the first side and/or the second side of the fiber layer. 1. A material web comprising:a. a fiber layer having a first side and an opposing second side, the fiber layer comprising a plurality of fibers, each of which comprising an intimate admixture of a thermoplastic polymer, and a wax and/or oil, wherein at least some of the wax and/or oil is exposed at an outer surface of the fibers; andb. a surface energy treatment disposed on the first side and/or the second side of the fiber layer.2. The material web of claim 1 , wherein the plurality of fibers comprises bicomponent fibers comprising a first component and a second component.3. The material web of claim 2 , wherein the bicomponent fibers are arranged in a side-by-side configuration.4. The material web of claim 3 , wherein the wax and/or oil concentration in the first component and the second component are equal.5. The material web of claim 3 , wherein the wax and/or oil concentration in the first component and the second component are different.6. The material web of claim 2 , wherein the bicomponent fibers are arranged in a core-sheath configuration.7. The material web of claim 6 , wherein the wax and/or oil concentration in the first component and the second component are equal.8. The material web of claim 6 , wherein the wax and/or oil concentration in the first component and the second component are different.9530. The material web of claim 1 , wherein the material web comprises spunbond fibers having a diameter of from micrometers to micrometers.10. The material web of claim 1 , wherein the wax and/or oil comprises a stearic ...

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16-03-2017 дата публикации

Semi-aromatic copolyamide and process for preparing same

Номер: US20170073470A1
Принадлежит: Arkema France SA

The invention relates to a copolyamide comprising at least two units corresponding to the following general formula: A/10,T in which: A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb (cyclo)aliphatic diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36; 10,T denotes a unit obtained from the polycondensation of 1,10-decanediamine and terephthalic acid, characterized in that it has a polydispersity index, denoted by Ip, of less than or equal to 3.5, measured by gel permeation chromatography. The invention also relates to the process for preparing said copolyamide, a composition comprising this polyamide and also the use of this polyamide and of such a composition.

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16-03-2017 дата публикации

DISH SUPPORT RACK FOR DISHWASHER

Номер: US20170073544A1
Автор: SEIGNOBOS Elodie
Принадлежит:

The invention pertains to a dish support rack having outstanding resistance to chemically harsh environments, and possessing improved mechanical properties, said dish support rack comprising a metal wire frame coated with a polyamide composition [composition (C)] comprising: —more than 50% wt of a polyamide [polyamide (A), herein after], more than 50% moles of recurring units of said polyamide complying with formula: —HN—(CH)—NH—C(O)—(CH)—C(O)— [recurring units (R)], and, optionally: —up to 10% wt of conventional filler(s) and/or additive(s), and to a method for its manufacture. 1. A dish support rack , comprising a metal wire frame coated with a polyamide composition , said composition comprising:{'sub': 2', '6', '2', '8, 'more than 50 weight % of a polyamide, that comprises recurring units, wherein more than 50 mole % of the recurring unit are first recurring units according to the formula: —HN—(CH)—NH—C(O)—(CH)—C(O)—, and said polyamide exhibits a relative viscosity of at least 2, when measured in formic acid, according to ISO 307 standard.'}3. The dish support rack of claim 2 , wherein the polyamide is an aliphatic polyamide.4. The dish support rack of claim 2 , wherein the second recurring units are selected from the group consisting of:{'sub': 2', '5, '(j) —NH—(CH)—CO,'}{'sub': 2', '8, '(jj) —NH—(CH)—CO,'}{'sub': 2', '9, '(jjj) —NH—(CH)—CO,'}{'sub': 2', '10, '(jv) —NH—(CH)—CO,'}{'sub': 2', '11, '(v) —NH—(CH)—CO,'}{'sub': 2', '6', '2', '4, '(vj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '8', '2', '10, '(vjj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '6', '2', '12, '(vjjj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '10', '2', '10, '(jx) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '6', '2', '7, '(x) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '12', '2', '10, '(xj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '10', '2', '8, '(xjj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '4', '2', '4, '(xjjj) —NH—(CH)—NH—CO—(CH)—CO,'}{'sub': 2', '4', '2', '8, '(xjv) —NH—(CH)—NH—CO—(CH)—CO.'}5. The dish support rack of ...

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05-06-2014 дата публикации

CROSS-LINKED POLY-E-LYSINE PARTICLES

Номер: US20140154737A1
Автор: Wellings Donald
Принадлежит: SPHERITECH LTD

The invention provides a cross-linked poly-ε-lysine polymer. The poly-ε-lysine and cross linker are linked by amide bonds and may the cross linker has at least two functional groups capable of reacting with an alpha carbon amine of poly-ε-lysine. The polymer is suitably insoluble in water and other solvents and is provided in particulate form. The invention provides a particulate support comprising the cross-linked poly-ε-lysine polymer and the polymer may provide the particle itself or be coated on a particle for example silica. The polymer is useful in a wide range of applications including wound treatment, as a medical diagnostic comprising a particulate support and a functional material bound or retained by the support and solid phase synthesis of peptides, oligonucleotides, oligosaccharides, immobilisation of species, cell culturing and in chromatographic separation. 1. A cross-linked poly-ε-lysine polymer comprising poly-ε-lysine and a cross linker linked by amide bonds , wherein the cross linker comprises at least two functional groups capable of reacting with an alpha carbon amine of poly-ε-lysine.23-. (canceled)4. A polymer according to claim 1 , wherein the cross-linker comprises a moiety derived from a compound of formula X[COH]where n is 2 or more and X is a hydrophobic or hydrophilic linking group having a molecular weight of 14 to 250 excluding any functional substituents on the linking group.5. A polymer according to which is insoluble in water and other solvents.6. A polymer according to in particulate form.7. A particulate support comprising a cross-linked poly-ε-lysine polymer according to .8. A particulate support according to wherein the cross-linked poly-ε-lysine support is a spherical claim 7 , ellipsoidal or irregular particle.9. A particulate support according to wherein the cross-linked poly-ε-lysine support is used to coat a particle directly or indirectly.10. A particulate support according to claim 7 , wherein the cross-linked poly-ε- ...

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05-06-2014 дата публикации

WATER-BASED COATING FOR COLOR SAMPLING

Номер: US20140154938A1
Принадлежит: Valspar Sourcing, Inc.

A color sampling display product is provided that includes a radiation-curable water-based coating composition applied to a substrate, and shows mechanical integrity and aesthetic appeal. 2. The method of claim 1 , wherein the device is a color card.3. The method of claim 1 , wherein the device is not wrinkled claim 1 , buckled or curled by the application of the coating composition.5. The method of claim 4 , wherein the water-based polymer composition further comprises a water-dispersible polymer selected from the group consisting of polyurethanes claim 4 , epoxies claim 4 , polyamides claim 4 , chlorinated polyolefins claim 4 , acrylics claim 4 , oil-modified polymers claim 4 , polyesters and mixtures thereof.6. The method of claim 5 , wherein the water-dispersible polymer is an ethylenically unsaturated polyurethane.7. The method of claim 6 , wherein the ethylenic unsaturated polyurethane comprises (meth)acrylate functionality.8. The method of claim 6 , wherein the ethylenic unsaturation comprises auto-oxidative carbon-carbon double bonds.9. The method of claim 4 , wherein the support polymer comprises a latex emulsion.10. The method of claim 9 , wherein the latex emulsion comprises at least a first stage comprising a styrene-acrylic emulsion.11. The method of claim 9 , wherein the latex emulsion comprises a multi-stage polymer latex claim 9 , comprising:at least a first stage wherein the monomers forming the first stage polymer would form a polymer having a theoretical glass transition temperature in the range of 60° C. and 110° C.; andat least a second stage wherein the monomers forming the second stage polymer would form a polymer having a theoretical glass transition temperature in the range of 10° C. to 50° C.12. The method of claim 9 , wherein the latex emulsion is alkali soluble.13. The method of claim 4 , further comprising an efficacious amount of a performance-enhancing additive.14. The method of claim 13 , wherein the performance-enhancing additive is ...

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05-06-2014 дата публикации

Drier for alkyd resin compositions

Номер: US20140155514A1
Принадлежит: DSM IP ASSETS BV

The invention relates to an alkyd resin composition comprising components: (A) at least an auto-oxidisable alkyd resin component comprising unsaturated fatty acid or its derivative, selected from: (i) alpha, beta-unsaturated ester-functional alkyd resin; (ii) combination of a alpha, beta-unsaturated ester functional material and an alkyd resin; and (iii) mixture of components (i) and (ii); Wherein the alkyd has an oil length of at least 20% unsaturated fatty acids; (B) a daylight photoinitiator; (C) a metal drier; and (D) optionally a liquid medium selected from the group consisting of an organic solvent, water, non-volatile diluent and mixtures thereof; wherein if the liquid medium is present and is: a) substantially based on organic solvent and/or diluent then the VOC is <300 g/l, or b) substantially based on water then the VOC is <100 g/l.

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22-03-2018 дата публикации

COLORED HYDROGEL CONTACT LENSES WITH LUBRICIOUS COATING THEREON

Номер: US20180079157A1
Принадлежит:

The invention is generally related to colored contact lenses which comprise a hydrogel lens body having an opaque color image therein and/or thereon and a durable lubricious coating thereon. The coating comprises an anchoring layer of a polyanionic polymer having carboxyl groups and a hydrogel layer which is derived from a hydrophilic polymeric material having azetidinium groups and is covalently attached onto the anchoring layer of the polyanionic polymer through linkages each formed between one carboxyl group and one azetidinium groups. The colored contact lens has a surface lubricity better than the lubricity of the non-silicone hydrogel lens body and a friction rating of about 2 or lower after 7 cycles of manual rubbing. 1. A method for producing soft contact lenses , comprising the steps of:(1) obtaining a preformed hydrogel contact lens having a hydrogel lens body and a color image printed with an ink on and/or in one of the anterior and posterior surface of the hydrogel lens body, wherein the ink comprises pigment particles;(2) contacting the preformed hydrogel contact lens with a first aqueous coating solution of a polyanionic polymer at a pH of about 4.0 or less and at a coating temperature of from about 25° C. to about 80° C. to obtain a colored contact lens precursor which is the preformed hydrogel contact lens having a layer of the polyanionic polymer thereon, wherein the polyanionic polymer is one or more homo- or copolymers of acrylic acid, methacrylic acid, ethylacrylic acid, 2-acrylamidoglycolic acid, or 2-methacrylamidoglycolic acid, wherein the layer of the polyanionic polymer encloses the preformed hydrogel contact lens having the color image; and(3) heating the colored contact lens precursor obtained in step (2), in a second aqueous coating solution which comprises a water-soluble and thermally-crosslinkable hydrophilic polymeric material having azetidinium groups, at a temperature of from about 60° C. to about 140° C. for at least 30 minutes to ...

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24-03-2016 дата публикации

Solvent Resistant, Transparent Aromatic Polyamide Films with High Refractive Indices

Номер: US20160083538A1
Принадлежит: Akron Polymer Systems Inc

A solvent resistant, transparent aromatic polyamide film with a high refractive index may be made by reacting at least one aromatic diacid chloride, a first aromatic diamine, and at least one crosslinking agent or a second aromatic diamine in an organic solvent to form an aromatic polyamide polymer in solution. In one embodiment, the at least one aromatic diacid chloride is selected from the group consisting of isophthaloyl dichloride, terephthaloyl dichloride, 2,6 -naphthalene-dicarboxylic chloride, or combinations thereof and the first aromatic diamine is selected from the group consisting of 9,9-Bis(4-hydroxyphenyl)fluorine, 2,2′,5,5′-Tetrachlorobenzidine, or combinations thereof. The organic solvent is then evaporated from the aromatic polyamide polymer in solution to form a transparent aromatic polyamide precursor film. The precursor film is then heated at a temperature close to the glass transition temperature of the transparent aromatic polyamide precursor film to form the solvent resistant, transparent aromatic polyamide film.

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26-03-2015 дата публикации

ORGANIC POLYMER COMPOUNDS SUITABLE FOR FORMING POSITIVE A-TYPE RETARDERS AND METHODS OF PRODUCTION THEREOF

Номер: US20150086799A1
Принадлежит: LIGHT POLYMERS HOLDING

An organic polymer solution may include about 0.1%-30% by weight of a specific polymer having rigid rod-like molecules. These molecules may include various cores, spacers, and sides groups to ensure their solubility, viscosity, and cross-linking ability. The rigid rod-like molecules are selected in such a way that they form self-assembling structures in the polymer solution, which makes it a lyotropic liquid crystal. The organic polymer solution, when properly deposited on a substrate and dried to remove solvents, forms a solid optical retardation layer of positive A-type substantially transparent to electromagnetic radiation in the visible spectral range. 1. A polymer compound comprising n organic units having the following structural formula:{'br': None, 'sub': m', 'k', '1', 'n, '[-(Core(L))-G-],'}{'sub': 3', '4', '2, 'wherein the organic units comprise rigid conjugated organic component Core capable of forming rod-like macromolecules, wherein G is a spacer selected from the group consisting of —C(O)—NR1-, —O—NR1-, linear and branched (C1-C4)alkylenes, —CR1R2-O—C(O)—CR1R2-, —C(O)—O—, —O—, and —NR1-, wherein R1 and R2 are independently selected from the group consisting of H, alkyl, alkenyl, alkynyl, and aryl; wherein L are lyophilic side-groups providing solubility to the polymer in a solvent and which are the same or different and independently selected from the group consisting of —COOX, —SOX, wherein X is selected from the group consisting of H, alkyl, alkenyl, alkynyl, aryl, alkali metal, and NW, wherein W is H or alkyl or any combination thereof, —SONP1P2 and —CONP1P2, wherein P1 and P2 are independently selected from the list comprising group consisting of H, alkyl, alkenyl, alkynyl, and aryl; and wherein m is 0, 1, 2, or 3, and wherein k is 1, 2, or 3; and'}wherein the number n provides a molecule anisotropy that promotes self-assembling of macromolecules in a solution of the polymer, thereby forming a lyotropic liquid crystal.2. (canceled)3. The polymer ...

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22-03-2018 дата публикации

PROCESS FOR PRODUCING CONTACT LENSES WITH DURABLE LUBRICIOUS COATINGS THEREON

Номер: US20180081197A1
Принадлежит:

The invention is related to a method for producing soft contact lenses comprises a silicone hydrogel lens body and a composite coating thereon. The composite coating comprises: a plasma base coating which is chemically-attached directly onto the surface of the silicone hydrogel contact lens and functions as a fail-proof measure for ensuring the hydrophobic silicone hydrogel lens material to be shielded from any exposure to ocular environments even after at least 30 days of daily uses including daily waring and daily cleaning/disinfecting; and a relatively-durable lubricious hydrogel top coating for ensuring wearing comfort. A method of the invention comprises forming a plasma-reactive hydrophilic polymer hybrid base coating having reactive functional groups on a silicone hydrogel contact lens and heating the silicone hydrogel contact lens with the hybrid base coating in an aqueous solution of a water-soluble and thermally crosslinkable hydrophilic polymeric material to form a stable lubricious hydrogel coating thereon. This method has a minimized adverse impact on the mechanical properties of silicone hydrogel lens body. 2. The method of claim 1 , wherein the plasma-treated silicone hydrogel contact lens is obtained by treating a silicone hydrogel contact lens in dried state with a plasma generated in a plasma gas compose of a mixture of a C-Chydrocarbon and a secondary gas selected from the group consisting of air claim 1 , N claim 1 , O claim 1 , CO claim 1 , and combinations thereof.3. The method of claim 2 , wherein the poly(alkylacrylic acid) has a weight average molecular weight of at least 100 claim 2 ,000 Daltons.4. The method of claim 3 , wherein the plasma-treated silicone hydrogel contact lens is in dried state immediately before being in contact with the first aqueous coating solution.5. The method of claim 3 , wherein the plasma-treated silicone hydrogel contact lens is in fully hydrated state immediately before being in contact with the first aqueous ...

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29-03-2018 дата публикации

Composite Article and Method of Forming a Composite Article

Номер: US20180086924A1
Принадлежит:

A method of forming a composite article, wherein the method includes providing a composite formulation, the composite formulation including a polymer matrix and at least one additive distributed in the polymer matrix at a concentration of between 10% and 50%, by volume, the at least one additive having a molar percentage of carbon that is equal to or less than 90%, feeding the composite formulation to a printing head of an additive manufacturing device, heating the composite formulation to form a heated composite formulation, extruding the heated composite formulation through a nozzle in the printing head, and depositing the heated composite formulation onto a platform to form the composite article. Also provided is a composite article produced from a composite formulation having at least one additive distributed in a polymer matrix. 1. A method of forming a composite article , the method comprising:providing a composite formulation, the composite formulation including a polymer matrix and at least one additive distributed in the polymer matrix at a concentration of between 10% and 50%, by volume;feeding the composite formulation to a printing head of an additive manufacturing device;heating the composite formulation to form a heated composite formulation;extruding the heated composite formulation through a nozzle in the printing head; anddepositing the heated composite formulation onto a platform to form the composite article;wherein the depositing of the heated composite formulation to form the composite article includes forming an additive manufacturing structure within the composite article; andwherein the at least one additive has a molar percentage of carbon that is equal to or less than 90%.2. The method of claim 1 , wherein the at least one additive comprises a filler selected from the group consisting of a metal claim 1 , a metalloid claim 1 , a semimetal claim 1 , a ceramic claim 1 , and combinations thereof.3. The method of claim 2 , wherein the filler ...

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