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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 7791. Отображено 100.
05-01-2012 дата публикации

Adhesive and adhesive sheet

Номер: US20120000599A1
Принадлежит: Denki Kagaku Kogyo KK

Provided is a adhesive and an adhesive sheet which exhibit excellent chip-holding properties during dicing and from which chips can be easily stripped during pick up, even when considering changes over time. It is a adhesive composition which contains both (A) a (meth)acrylic acid ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of less than 350,000 and (B) a (meth)acrylic ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of 350,000 to 2,000,000 at a weight ratio of 10:90 to 90:10, and further contains 0.5 to 20 parts by mass of a crosslinking agent per 100 parts by mass of components (A) and (B) in total, the crosslinking agent being a crosslinking agent that reacts with both the functional groups of the component (A) and the functional groups of the component (B).

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26-04-2012 дата публикации

Optical pressure-sensitive adhesive sheet, optical film and display device

Номер: US20120100359A1
Принадлежит: Nitto Denko Corp

The present invention provides an optical pressure-sensitive adhesive sheet in which white turbidity is not caused by humidification and durability is excellent as well. The present invention provides an optical pressure-sensitive adhesive sheet, comprising: a pressure-sensitive adhesive layer in which a moisture ratio after storage under an environment of 60° C. and 95% RH for 120 hours is 0.65 wt % or more, and a shear storage elastic modulus at 85° C. which is measured by a dynamic viscoelastic measurement is 5.0×10 4 to 5.0×10 5 Pa, wherein a peeling distance measured by the constant-load peel test is 30 mm or less when an adherend is a polyethylene terephthalate plate, and the peeling distance measured by the following constant-load peel test is 30 mm or less when the adherend is an acrylic plate.

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10-05-2012 дата публикации

Adhesive sheet for processing of semiconductor wafter

Номер: US20120114938A1
Принадлежит: Nitto Denko Corp

An adhesive sheet for processing of a semiconductor wafer has an adhesive layer disposed on at least one surface of a base substrate, the adhesive layer includes a base polymer, a plasticizer and a surfactant, an SP value of the plasticizer and the surfactant satisfies the relationship: 0.9≦(the plasticizer SP value)/(the surfactant SP value)≦1.0. The present invention has the object of providing an adhesive sheet for processing of a semiconductor wafer that exhibits superior storage stability under a range of environments, and that prevents contamination of the adherend after use.

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10-05-2012 дата публикации

Adhesive system and method of producting a wood based product

Номер: US20120115992A1
Принадлежит: AKZO NOBEL COATINGS INTERNATIONAL BV

The invention relates to an adhesive system comprising a protein; a polymer comprising at least one carboxylic group or at least one carboxylic anhydride group, or a combination thereof, with the proviso that said polymer does not contain 5 to 90 wt-% of vinyl pivalate units in combination with 0.2 to 15 wt-% of primary hydroxyl group-containing vinyl compound units, and a polyamine-epihalohydrin. The invention further relates to the use of the adhesive system, an adhesive composition, a method of producing a wood based product and a wood based product.

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14-06-2012 дата публикации

Dual cure adhesive formulations

Номер: US20120145312A1
Автор: Mark W. Pressley
Принадлежит: Lord Corp

An adhesive composition comprising as principal components, a polymerizable component, an ambient temperature radical polymerization catalyst system and a photoinitiator. The adhesive may optionally comprise an adhesion promoter, a toughener, an epoxy, and a filler material. Further, a two-part reactive adhesive comprising, a first part comprising, (i) at least one free radical-polymerizable monomer, (ii) at least one reducing agent, and (iii) a photoinitiator, and a second part comprising an oxidizing agent that is reactive at ambient temperature with the reducing agent to produce free radicals that are capable of initiating and propagating free radical polymerization.

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28-06-2012 дата публикации

Radiation-curable adhesive composition and adhesive sheet

Номер: US20120165489A1
Автор: Tomokazu Takahashi
Принадлежит: Nitto Denko Corp

A radiation-curable adhesive composition having a base polymer including structural units derived from a monomer A having a functional group a; a monomer B formed from a methacrylate monomer having an alkyl group that includes at least 10 and no more than 17 carbon atoms; and a monomer C that has both a functional group c that reacts with the functional group a and a polymerizable carbon-carbon double bond group, and a main chain of the base polymer is configured from the monomer B and the monomer A, the proportion of the monomer B being at least 50 wt % of the total monomers configuring the main chain; and the base polymer includes a polymerizable carbon-carbon double bond group in a side chain as a result of a portion of the functional group a in the monomer A reacting and bonding with the functional group c in the monomer C.

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16-08-2012 дата публикации

(meth)acrylic resin composition

Номер: US20120205043A1
Принадлежит: Denki Kagaku Kogyo KK

Provided is an adhesive (meth)acrylic resin composition being high in adhesiveness and capable of affording an adhered body which can be used at high temperatures of 250° C. or higher, and possessing low outgassing property and heat resistance. A (meth)acrylic resin composition including (A) a polyfunctional (meth)acrylate, and (B) a photopolymerization initiator that exhibits a mass loss on heating of 15% by mass or less when increasing temperature from 30° C. to 250° C. at a temperature increase rate of 10° C./min. under nitrogen flow, wherein the glass transition temperature of a cured body obtained from the composition is 250° C. or higher.

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18-10-2012 дата публикации

Pressure-sensitive adhesive dispersion comprising polymers with ureido groups or with ureido-analogous groups and prepared by stage polymerization

Номер: US20120261070A1
Принадлежит: BASF SE

A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH 2 , O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The polymer P1 is prepared by polymerization in at least 2 stages, the glass transition temperature of a polymer from monomers of the first stage being lower by at least 20° C. than the glass transition temperature of a polymer from monomers of a later, second stage.

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01-11-2012 дата публикации

Optically diffusive adhesive and method of making the same

Номер: US20120276317A1
Принадлежит: 3M Innovative Properties Co

A method of making an optically diffusive adhesive comprises: preparing a first adhesive composition comprising first particles dispersed in an optically clear adhesive matrix; determining a first haze and a first clarity of the first adhesive composition; and based upon the first haze and the first clarity, preparing a second adhesive composition that comprises the optically clear adhesive matrix, the first particles, and second particles dispersed in the optically clear adhesive matrix. An optically diffusive adhesive comprises first and second particles dispersed in an optically clear adhesive matrix is also disclosed. The first and second particles have a higher refractive index than the optically clear adhesive matrix. Articles comprising the optically diffusive adhesive are also disclosed.

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01-11-2012 дата публикации

Adhesive Compositions For Easy Application and Improved Durability

Номер: US20120277341A1
Принадлежит: Curwood Inc

The present invention is directed to an adhesive composition comprising a crosslinkable acrylic copolymer, a multi-functionalized crosslinkable oligomer and a photoinitiator wherein the partially cured composition exhibits excellent wet out characteristics as reflected in a tan delta value of at least 0.4, preferably greater than 0.5, more preferable greater than 0.6 as measured at 20° C. resulting from a first curing stage, and the fully cured composition exhibits an improved stiffness and temperature resistance as reflected in a storage elastic modulus of at least 175,000 Pa at 20° C. and a shear adhesion failure temperature of at least 425° F. (218.3° C.) at 1 Kg/in 2 (0.155 Kg/cm 2 ), respectively, which result from a second sequential curing stage.

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06-12-2012 дата публикации

Adhesive composition for glass bonding, glass assembly and display using the same

Номер: US20120308833A1
Принадлежит: Dongwoo Fine Chem Co Ltd

Disclosed are an adhesive composition for glass bonding, a glass assembly and a display using the adhesive composition. The adhesive composition includes a urethane-acryl copolymer, a monomer mixture of an acrylic monomer having no hydroxyl group and a monomer having a hydroxyl group, an isocyanate cross-linking agent, and a photo-polymerization initiator. The adhesive composition has advantages of: favorable scattering prevention of broken glass pieces, excellent heat-resistant durability enabling prevention of damage to an image display apparatus caused by temperature change, no adverse effect upon transmittance of the image display apparatus, hence ensuring desired visibility.

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20-12-2012 дата публикации

Organosilicon compounds, production processes thereof, pressure-sensitive adhesive compositions containing the organosilicon compounds, self-adhesive polarizers and liquid crystal displays

Номер: US20120322946A1
Автор: Kazuhiro Tsuchida
Принадлежит: Shin Etsu Chemical Co Ltd

Organosilicon compounds are represented by the following formula: wherein R is a hydrolyzable group, R′ is an alkyl having 1 to 4 carbon atoms, A is an alkylene having 1 to 6 carbon atoms, X is O or S, Y is —NH— or S, L 1 and L 2 are C or N, Z and M are —NH—, O or S, R 1 to R 11 are H, alkyl having 1 to 6 carbon atoms, alkoxy or fluoroalkyl, or amino, m is 1 to 3, and n is 0 to 3. R 1 and R 2 or R 2 and R 3 may bonded together. R 5 and R 6 or R 9 and R 10 may directly bond together. R 4 and R 7 or R 8 and R 11 may form a ring skeleton. Their production processes, pressure-sensitive adhesive compositions, self-adhesive polarizers and LCDs are also disclosed.

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03-01-2013 дата публикации

Acrylic pressure-sensitive adhesive composition for optical use and acrylic pressure-sensitive adhesive tape for optical use

Номер: US20130005910A1
Принадлежит: Nitto Denko Corp

An acrylic pressure-sensitive adhesive composition for optical use includes: an acrylic polymer (A) that contains, as a monomer unit, a vinyl monomer having a nitrogen atom in its backbone and that does not substantially contain a carboxyl group-containing monomer; and a (meth)acrylic polymer (B) having a weight average molecular weight of 1000 or more and less than 30000.

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07-02-2013 дата публикации

Display panel assembly and methods of making same

Номер: US20130034713A1
Принадлежит: 3M Innovative Properties Co

A display panel assembly is made by optically bonding a display panel and a substantially transparent substrate. Optical bonding is carried out by forming an optical bonding layer having regions of different physical properties.

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18-04-2013 дата публикации

Multilayer adhesive sheet and method for manufacturing electronic component

Номер: US20130092318A1
Принадлежит: Denki Kagaku Kogyo KK

Provided is a multilayer adhesive sheet which enables easy separation between an adhesive layer and a die attach film during the pick-up even in cases where an acrylate ester copolymer is used in the die attach film, thereby making the pick-up work of semiconductor chips after the dicing easy. The multilayer adhesive sheet comprises a base film, an adhesive layer that is disposed on one surface of the base film, and a die attach film that is disposed on an exposed surface of the adhesive layer. The adhesive that constitutes the adhesive layer contains: (A) a (meth)acrylate ester copolymer; (B) an ultraviolet polymerizable compound; (C) a multifunctional isocyanate curing agent; (D) a photopolymerization initiator; and (E) a silicone polymer.

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18-04-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE LAYER FOR OPTICAL FILM, PRESSURE-SENSITIVE ADHESIVE OPTICAL FILM, AND IMAGE DISPLAY

Номер: US20130094083A1
Принадлежит: NITTO DENKO CORPORATION

The pressure-sensitive adhesive layer for an optical film having good heat and moisture durability is formed by a process of applying an aqueous dispersion-type pressure-sensitive adhesive containing an emulsion of a (meth)acryl-based polymer obtained by subjecting a monomer mixture containing at least one of an alkyl (meth)acrylate (a1) with an alkyl group of 1 to 3 carbon atoms and an alkoxysilyl group-containing monomer (a2), and an alkyl (meth)acrylate (b) with an alkyl group of 4 to 14 carbon atoms to emulsion polymerization in water in the presence of a radical polymerization initiator and a reactive surfactant having a radically-polymerizable functional group; and then drying the emulsion, wherein a content of the reactive surfactant is 0.3 to 3 parts by weight based on 100 parts by weight of the monomer mixture, and has a saturated water absorption of 1.2 to 3.2% by weight at 50° C. and 90% R.H. 1. A pressure-sensitive adhesive layer for an optical film , which is formed by a process comprising:applying an aqueous dispersion-type pressure-sensitive adhesive containing an emulsion of a (meth)acryl-based polymer obtained by subjecting a monomer mixture containingat least one of an alkyl (meth)acrylate (a1) with an alkyl group of 1 to 3 carbon atoms and an alkoxysilyl group-containing monomer (a2), andan alkyl (meth)acrylate (b) with an alkyl group of 4 to 14 carbon atoms to emulsion polymerization in water in the presence of a radical polymerization initiator and a reactive surfactant having a radically-polymerizable functional group; and then drying the emulsion,wherein a content of the reactive surfactant is 0.3 to 3 parts by weight based on 100 parts by weight of the monomer mixture, andthe pressure-sensitive adhesive layer has a saturated water absorption of 1.2 to 3.2% by weight at 50° C. and 90% R.H.2. The pressure-sensitive adhesive layer for an optical film according to claim 1 , wherein the content of the reactive surfactant is 0.3 to less than 2 ...

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25-04-2013 дата публикации

Dual cure adhesives

Номер: US20130102698A1
Принадлежит: Henkel Corp

This invention is a dual cure adhesive that can be designed to have a proper balance of properties by choosing formulation materials to meet certain inequalities. The dual cure adhesive comprises ethylenically unsaturated compounds capable of UV-initiated free radical polymerization and epoxy compounds and their corresponding curing agents capable of thermal cure. In a particular embodiment, the dual cure adhesive comprises (A) one or more monofunctional acrylate compounds containing an oxygen-containing cyclic unit, (B) one or more monofunctional acrylate compounds in which the ester group contains a hydrocarbon group consisting of at least six carbon atoms, and (C) one or more thermoplastic, solid, amorphous epoxy compounds having a softening point or melting point between 60° C. and 100° C.

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25-04-2013 дата публикации

Polymeric adhesive for anchoring compliant materials to another surface

Номер: US20130103157A1
Принадлежит:

Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint. 1. A composition of matter comprising a urethane dimethacrylate-methyl methacrylate copolymer comprising a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate.2. The composition of wherein the first polymer regions based on urethane dimethacrylate comprise about 60%-99% (w/w) of the copolymer and the second polymer regions based on methyl methacrylate comprise about 1%-40% (w/w) of the copolymer.3. The composition of wherein the first polymer regions based on urethane dimethacrylate comprise about 60%-80% (w/w) of the copolymer and the second polymer regions based on methyl methacrylate comprise from about 20%-40% (w/w) of the copolymer.4. The composition of wherein the first polymer regions based on urethane dimethacrylate comprise soft segments based on poly(tetramethyl) glycol claim 1 , the soft segments having a molecular weight between about 100 Da and about 5000 Da.5. The composition of wherein the urethane dimethacrylate-methyl methacrylate copolymer defines a compressive modulus between about 30 MPa and about 2000 MPa.6. The composition of wherein ...

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16-05-2013 дата публикации

Pressure-sensitive adhesive sheet

Номер: US20130123451A1
Принадлежит: Nitto Denko Corp

The present invention provides a pressure-sensitive adhesive sheet excellent in anti-white turbidity and anti-foaming release property under a high-temperature and high-humidity environment and corrosion resistance. The invention provides a pressure-sensitive adhesive sheet including a pressure-sensitive adhesive layer which includes an acrylic polymer (A) and has a gel fraction of 70 to 100 wt %, wherein the acrylic polymer (A) is formed from a component including, as an essential monomer component, methyl methacrylate and a hydroxyl group-containing monomer in an amount of 10 to 40 wt % based on a total amount (100 wt %) of the monomer component, the component forming the acrylic polymer (A) substantially does not contain a carboxyl group-containing monomer.

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06-06-2013 дата публикации

LINERLESS LABEL

Номер: US20130143010A1

The invention relates to an aqueous adhesive composition containing at least one acrylate polymer with a glass transition temperature Tg>50° C. and at least one amorphous polyurethane or polyurethane-polyurea polymer with a glass transition temperature Tg<+10° C., the use of the adhesive compositions for the manufacture of heat-activated adhesive layers, and planar formations containing adhesive layers based on the adhesive composition. 121-. (canceled)22. An aqueous adhesive composition comprising at least one acrylate polymer with a glass transition temperature in the range from 50° C. to 90° C. and at least one amorphous polyurethane or polyurethane-polyurea polymer with a glass transition temperature in the range from -50° C. to 10° C. , the glass transition temperature being determined by a DSC measurement according to DIN 65467 at a heating rate of 20 K/min.23. The aqueous adhesive composition of claim 22 , wherein the acrylate polymer has a glass transition temperature in the range from 50° C. to 80° C.24. The aqueous adhesive composition of claim 22 , wherein the amorphous polyurethane or polyurethane-polyurea polymer has a glass transition temperature in the range from −50° C. to +5° C.25. The aqueous adhesive composition of claim 22 , wherein the polyurethane or polyurethane-polyurea polymer has a weight average molecular weight Mw in the range from 15 claim 22 ,000 to 150 claim 22 ,000 g/mol.26. The aqueous adhesive composition of claim 22 , wherein the polyurethane or polyurethane-polyurea polymer in the dispersion has an average particle diameter in the range from 30 to 400 nm.27. The aqueous adhesive composition of claim 22 , wherein the acrylate polymer has a weight average molecular weight Mw in the range from 10to 10g/mol.28. The aqueous adhesive composition of claim 22 , wherein the acrylate polymer has an average particle diameter in the range from 40 to 200 nm.29. A method of manufacture of a heat-activated adhesive layer on a substrate which ...

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06-06-2013 дата публикации

Liquid resin composition and semiconductor device

Номер: US20130143983A1
Принадлежит: Sumitomo Bakelite Co Ltd

According to the invention, a liquid resin composition which has favorable wet spreadability after mounting of a chip and exhibits excellent solder cracking resistance even in a high-temperature solder reflow process at about 260° C., i.e., even when being used in lead-free solder, and a semiconductor package using the liquid resin composition are provided. In the liquid resin composition of the invention, an acrylic copolymer having a radical polymerizable functional group contains alkyl(meth)acrylate as a constituent monomer having a linear or branched alkyl group having 6 to 9 carbon atoms in an amount of 10 wt % to 40 wt % of the entire constituent monomers.

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06-06-2013 дата публикации

WATER-SOLUBLE PRESSURE SENSITIVE ADHESIVES

Номер: US20130143991A1
Автор: II Steven S., KANTNER
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A water-soluble pressure sensitive adhesive comprises a homogeneous blend comprising (a) a polymer selected from the group consisting of N-vinyl caprolactam homopolymers, N-vinyl pyrrolidone copolymers, and mixtures thereof and (b) a non-volatile plasticizer comprising a monohydric or polyhydric alcohol having hydrophilic-lipophilic balance of about 2 to about 10. The N-vinyl pyrrolidone copolymers comprise about 60% or less by weight N-vinyl pyrrolidone. 1. An adhesive comprising a homogeneous blend comprising:(a) a polymer selected from the group consisting of N-vinyl caprolactam homopolymers, N-vinyl pyrrolidone copolymers, and mixtures thereof, the N-vinylpyrrolidone copolymers comprising about 60% or less by weight N-vinyl pyrrolidone; and(b) a non-volatile plasticizer comprising a monohydric alcohol having hydrophilic-lipophilic balance of about 2 to about 10;wherein the plasticizer comprises from about 33% to about 80% by weight of the adhesive and the adhesive is pressure sensitive and water-soluble.2. The pressure sensitive adhesive of wherein the polymer comprises from about 35% to about 75% by weight of the pressure sensitive adhesive.3. The pressure sensitive adhesive of wherein the polymer is an N-vinyl caprolactam homopolymers.4. The pressure sensitive adhesive of wherein the polymer is an N-vinyl pyrrolidone copolymer.5. The pressure sensitive adhesive of claim 4 , wherein the polymer is selected from the group consisting of N-vinyl caprolactam/N-vinyl pyrrolidone copolymers and vinyl acetate/N-vinyl pyrrolidone copolymers claim 4 , the vinyl acetate/N-vinyl pyrrolidone copolymers comprising from about 20% to about 60% by weight N-vinyl pyrrolidone.6. The pressure sensitive adhesive of claim 5 , wherein the polymer is a copolymer of N-vinyl pyrrolidone and vinyl acetate comprising from about 30% to about 50% by weight N-vinyl pyrrolidone.7. The pressure sensitive adhesive of wherein the N-vinylpyrrolidone copolymers comprise about 30% or less by ...

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06-06-2013 дата публикации

ADHESIVE COMPOSITION, ADHESIVE LAYER AND ADHESIVE SHEET

Номер: US20130143999A1
Принадлежит: NITTO DENKO CORPORATION

Provided are: an adhesive composition that is capable of providing an adhesive layer in which titanium-based nanoparticles are stably dispersed, said adhesive layer having more enhanced mechanical characteristics, excellent refractive index and excellent adhesive force; and an adhesive sheet or the like which uses the adhesive composition. An adhesive composition is prepared so as to contain: a (meth)acryl-based polymer that contains, as a monomer component, 50% by weight or more of a (meth)acrylate represented by the formula CH═C(R)COOR(wherein Rrepresents hydrogen or a methyl group, and Rrepresents a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms), has a weight average molecular weight of from 500,000 to 3,000,000 as determined by gel permeation chromatography, and does not substantially contain an acid component; an aromatic polymer that has a weight average molecular weight of from 200 to 900 as determined by gel permeation chromatography in an amount of 120-400 parts by weight per 100 parts by weight of the (meth)acrylic polymer; and titanium-based nanoparticles that has an average particle size of 5 to 100 nm in an amount of 150 to 600 parts by weight per 100 parts by weight of the (meth)acrylic polymer. 1. An adhesive composition , comprising:{'sub': 2', '1', '2', '1', '2, '100 parts by weight of a (meth)acryl-based polymer comprising, as a monomer component, 50% by weight or more of a (meth)acrylate represented by the formula CH═C(R)COOR, wherein Rrepresents hydrogen or a methyl group, and Rrepresents a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, having a weight average molecular weight of from 500,000 to 3,000,000 as determined by gel permeation chromatography, and being substantially free of an acid component;'}120 to 400 parts by weight of an aromatic polymer comprising an aromatic ring-containing monomer having an unsaturated double bond-containing polymerizable functional group and an aromatic ring, the aromatic ...

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13-06-2013 дата публикации

CROSSLINKABLE ACRYLATE ADHESIVE POLYMER COMPOSITION

Номер: US20130150478A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A pre-adhesive syrup copolymer composition comprising an acid functional acrylate solute copolymer, a monomer solvent mixture, and a polyaziridine crosslinking agent is disclosed. 1. A process for preparing an pre-adhesive copolymer composition comprising: 1) a first component solute acid functional (meth)acrylate copolymer,', '2) a second component comprising at least one free-radically polymerizable solvent monomer comprising an acid functional monomer, and', '3) a polyfunctional aziridine crosslinking agent;, 'a) providing a syrup polymer composition comprisingb) wherein the component of the syrup polymer composition are combined for a time, and a temperature sufficient to react, andc) adding additional acid functional monomers.2. The process of claim 1 , wherein acid functional monomer is added in amount up to a total of 15 parts by weight claim 1 , relative to 100 parts total (meth)acrylate ester.3. The process of claim 1 , wherein acid functional monomer is added in amounts of 1 to 10 parts by weight claim 1 , relative to 100 parts total (meth)acrylate ester.4. The process of wherein the first component solute copolymer comprises:a) 100 parts by weight of an (meth)acrylic acid ester monomer units;b) 0.01 to less than 10 parts by weight of an acid functional monomer units;c) 0 to 25 parts by weight of a second, non-acid functional, polar monomer units;d) 0 to 5 parts vinyl monomer units.5. The process of wherein the solute copolymer comprises 0.01 to less than 5 parts by weight acid functional monomer units claim 1 , based on 100 parts of an (meth)acrylic acid ester.6. The process of wherein the solute copolymer comprises 0.1 to less than 1 parts by weight acid functional monomer units claim 1 , based on 100 parts of an (meth)acrylic acid ester.7. The process of wherein the solvent monomer component comprises:1) 100 parts by weight of an (meth)acrylic acid ester monomers;2) 0.01 to less than 10 parts by weight of an acid functional monomers;3) 0 to 25 parts by ...

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20-06-2013 дата публикации

OPTICAL PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20130158221A1
Принадлежит: NITTO DENKO CORPORATION

The present invention provides an optical pressure-sensitive adhesive sheet which can control the change in capacitance, which cause malfunction, when the optical pressure-sensitive adhesive sheet is applied to an optical member. The present invention provides an optical pressure-sensitive adhesive sheet including a pressure-sensitive adhesive layer, wherein a relative dielectric constant at a frequency of 1 MHz is 2 to 8, and a dielectric tangent at a frequency of 1 MHz is more than 0 and 0.2 or less. 1. An optical pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer , wherein a relative dielectric constant at a frequency of 1 MHz is 2 to 8 , and a dielectric tangent at a frequency of 1 MHz is more than 0 and 0.2 or less.2. The optical pressure-sensitive adhesive sheet according to claim 1 , wherein the relative dielectric constant at a frequency of 1.0×10Hz is 60% or more of a relative dielectric constant at a frequency of 1.0×10Hz.3. The optical pressure-sensitive adhesive sheet according to claim 1 , wherein an absolute value of a difference between the dielectric tangent at a frequency of 1.0×10Hz and a dielectric tangent at a frequency of 1.0×10Hz is 0.15 or less.4. The optical pressure-sensitive adhesive sheet according to claim 1 , which has a thickness accuracy of 10% or less.5. The optical pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive layer is an acrylic pressure-sensitive adhesive layer.6. The optical pressure-sensitive adhesive sheet according to claim 5 , wherein the acrylic pressure-sensitive adhesive layer comprises claim 5 , as a base polymer claim 5 , an acrylic polymer formed from a component comprising claim 5 , as an essential monomer component claim 5 , alkyl (meth)acrylate having a straight-chain or branched alkyl group having 1 to 14 carbon atoms and/or alkoxyalkyl (meth)acrylate.7. The optical pressure-sensitive adhesive sheet according to claim 5 , wherein the ...

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27-06-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE SHEET FOR GLASS PLATES

Номер: US20130165610A1
Автор: MIKI Kaori, NIWA Masahito
Принадлежит: NITTO DENKO CORPORATION

The present invention provides a pressure-sensitive adhesive sheet large in adhesive force when used for a surface of a glass member and capable of reducing the adhesive force to a degree allowing the occurrence of the cracking or breakage of the glass member to be suppressed when the sheet is peeled from the surface of the glass member. The pressure-sensitive adhesive sheet for glass plates of the present invention includes a pressure-sensitive adhesive layer including an acrylic polymer, wherein the content of the acrylic polymer in the pressure-sensitive adhesive layer is 30% by weight or more in relation to the total amount (100% by weight) of the pressure-sensitive adhesive layer; the acrylic polymer substantially includes no acidic functional group; the solvent-insoluble fraction of the pressure-sensitive adhesive layer is 50% or more; and the adhesive force to glass as determined by a specific method is 12.0 N or less. 1. A pressure-sensitive adhesive sheet for glass plates comprising a pressure-sensitive adhesive layer including an acrylic polymer ,wherein the content of the acrylic polymer in the pressure-sensitive adhesive layer is 30% by weight or more in relation to the total amount (100% by weight) of the pressure-sensitive adhesive layer;the acrylic polymer substantially comprises no acidic functional group;the solvent-insoluble fraction of the pressure-sensitive adhesive layer is 50% or more; andthe adhesive force to glass as determined by the following method is 12.0 N or less[Measurement Method of Adhesive Force to Glass]By using a pressure-sensitive adhesive sheet (width: 26 mm, length: 40 mm), a glass plateA (width: 50 mm, length: 100 mm, thickness: 0.7 mm) and a glass plate B (width: 26 mm, length: 760 mm, thickness: 1.0 mm) are laminated on each other to yield a laminate in such a way that: the size of the adhesion portion is 26 mm in width and 40 mm in length; the lengthwise direction of the pressure-sensitive adhesive sheet, the lengthwise ...

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04-07-2013 дата публикации

Dielectric adhesive film for electronic paper display device

Номер: US20130171399A1
Принадлежит: Toray Advanced Materials Korea Inc

A dielectric adhesive film for an electronic paper display device. A lower electrode to which voltage is applied and an image upper electrode coated with charged particles whose colors are changed depending on the applied voltage are attached to the adhesive film. Thickness of the adhesive film is controlled to be uniform and constant, and a resistance value in the thickness direction of the adhesive film, i.e., a resistance value in the direction where an electric field is formed, is controlled without changing adhesive properties and reliability as the thickness of the adhesive film is controlled. Since loss of the applied voltage is minimized and the charged particles are freely driven, driving performance of the display device is excellent although a high voltage is not applied in driving a flexible display device, such as a flexible LED, an organic electro luminescence (EL) element including an electronic paper, and the like.

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11-07-2013 дата публикации

Acrylic pressure-sensitive adhesive composition, acrylic pressure-sensitive adhesive layer, and acrylic pressure-sensitive adhesive tape

Номер: US20130177758A1
Принадлежит: Nitto Denko Corp

An acrylic pressure-sensitive adhesive composition contains 100 parts by mass of an acrylic polymer (A), 1 to 70 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (Mw) of 1000≦Mw<30000, and 1 to 50 parts by mass of a hydrogenated tackifying resin (C). The (meth)acrylic polymer (B) is a polymer having a weight average molecular weight smaller than that of the acrylic polymer (A) as a pressure-sensitive adhesive composition, and functions as a tackifying resin along with the hydrogenated tackifying resin (C).

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11-07-2013 дата публикации

TWO-PART, CYANOACRYLATE /CATIONICALLY CURABLE ADHESIVE SYSTEMS

Номер: US20130178560A1
Принадлежит: Henkel Ireland Limited

Two part cyanoacrylate/cationically curable adhesive systems, are provided. 1. A two part curable composition comprising:(a) a first part comprising a cyanoacrylate component and a cationic catalyst; and(b) a second part comprising a cationic curable component, wherein when mixed together the cationic catalyst initiates cure of the cationic curable component.2. The composition of claim 1 , wherein the cyanoacrylate component comprises HC═C(CN)—COOR claim 1 , wherein R is selected from alkyl claim 1 , alkoxyalkyl claim 1 , cycloalkyl claim 1 , alkenyl claim 1 , aralkyl claim 1 , aryl claim 1 , allyl and haloalkyl groups.3. The composition of claim 1 , wherein the cationic catalyst comprises salts of lithium and metals from Group II of the Periodic Table claim 1 , and non-nucleophilic acids.4. The composition of claim 1 , wherein the cationic catalyst is a non-nucleophilic acid having a pH of less than 1.0 when measured as a 10% by weight solution in water.5. The composition of claim 1 , wherein the cationic catalyst is a member selected from the group consisting of fluoroboric claim 1 , fluoroarsenic claim 1 , fluoroantimonic and fluorophosphoric acids; lithium tetrafluoroborate claim 1 , calcium di-tetrafluoroborate claim 1 , magnesium di-tetrafluoroborate claim 1 , lithum hexafluorophosphate claim 1 , calcium di-hexafluorophosphate claim 1 , magnesium di-hexafluorophosphate claim 1 , lithium hexafluoroantimonate and lithium hexafluoroarsenate; lanthanide triflate salts claim 1 , aryl iodonium salts claim 1 , aryl sulfonium salts claim 1 , lanthanum triflate claim 1 , ytterbium triflate claim 1 , trimethoxyboroxine claim 1 , trimethoxyboroxine-aluminum acetyl acetonate claim 1 , amine-boron trihalide complexes claim 1 , quaternary ammonium salts claim 1 , quaternary phosphonium salts claim 1 , tri-aryl sulfonium salts claim 1 , di-aryl iodonium salts claim 1 , and diazonium salts; trialkoxyboroxine curing agents; and combinations thereof.6. The composition of claim ...

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18-07-2013 дата публикации

ADHESIVE LAYER FOR OPTICAL FILM, METHOD FOR PRODUCING SAME, OPTICAL FILM WITH ADHESIVE LAYER, AND IMAGE DISPLAY DEVICE

Номер: US20130182324A1
Принадлежит: NITTO DENKO CORPORATION

The pressure-sensitive adhesive layer for an optical film of the invention is formed by a process comprising applying a water-dispersible pressure-sensitive adhesive containing emulsion particles comprising polymer particles emulsified with a surfactant and then drying the applied water-dispersible pressure-sensitive adhesive, and is in such a state that the polymer particles have a number average particle size (a) of 10 nm to 100 nm and that the ratio (a/b) of the number average particle size (a) to the average distance (b) between adjacent polymer particles is from 80/20 to 99.9/0.1, when the pressure-sensitive adhesive layer being observed with a transmission electron microscope. The pressure-sensitive adhesive layer makes it possible to reduce depolarization even when it is used on a high-contrast polarizing plate or any other component having a high degree of polarization. 1. A pressure-sensitive adhesive layer for an optical film ,the pressure-sensitive adhesive layer being formed by a process comprising applying a water-dispersible pressure-sensitive adhesive containing emulsion particles comprising polymer particles emulsified with a surfactant and then drying the applied water-dispersible pressure-sensitive adhesive, andthe pressure-sensitive adhesive layer being in such a state that the polymer particles have a number average particle size (a) of 10 nm to 100 nm and that the ratio (a/b) of the number average particle size (a) to the average distance (b) between adjacent polymer particles is from 80/20 to 99.9/0.1, when the pressure-sensitive adhesive layer being observed with a transmission electron microscope.2. The pressure-sensitive adhesive layer for an optical film according to claim 1 , wherein the pressure-sensitive adhesive layer has a residual water content of 0.1% by weight to 1% by weight at 23° C. and 55% R.H.3. The pressure-sensitive adhesive layer for an optical film according to claim 1 , wherein a difference between a refractive index of ...

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25-07-2013 дата публикации

Polymer for pressure sensitive adhesive, pressure sensitive adhesive composition and heat-peelable pressure sensitive adhesive sheet

Номер: US20130186565A1
Принадлежит: Nitto Denko Corp

A pressure sensitive adhesive having tackiness sufficient for fixing an article even when heated and having adhesive strength that may be lowered when heated to a higher temperature is provided. The pressure sensitive adhesive polymer comprises a copolymer of a (meth)acrylic monomer represented by a general formula, CH 2 ═C(R1)COOR2 (wherein R1 is a hydrogen group or a methyl group and R2 is a hydrogen group or an alkyl group having of 1 to 20 carbon atoms) and a comonomer having a double bond copolymerizable with the (meth)acrylic monomer, in which the comonomer has a ring structure having two or more carbon atoms and one or more double bonds and containing one or more atoms other than carbon, and the polymer is obtained by copolymerizing 1 to 20 parts by weight of the monomer having a ring structure with 100 parts by weight of the (meth)acrylic monomer.

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25-07-2013 дата публикации

Adhesive complex coacervates and method of making and using thereof

Номер: US20130189313A1

Described herein is the synthesis of adhesive complex coacervates and their use thereof. The adhesive complex coacervates are composed of a mixture of one or more polycations and one or more polyanions. The polycations and polyanions in the adhesive complex coacervate are crosslinked with one another by covalent bonds upon curing. The adhesive complex coacervates have several desirable features when compared to conventional bioadhesives, which are effective in water-based applications. The adhesive complex coacervates described herein exhibit good interfacial tension in water when applied to a substrate (i.e., they spread over the interface rather than being beaded up). Additionally, the ability of the complex coacervate to crosslink intermolecularly increases the cohesive strength of the adhesive complex coacervate. They have numerous biological applications as bioadhesives and drug delivery devices and are particularly useful in underwater applications and situations where water is present such as, for example, physiological conditions.

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01-08-2013 дата публикации

HIGH REFRACTIVE INDEX PRESSURE-SENSITIVE ADHESIVES

Номер: US20130196149A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

The present invention provides pressure-sensitive adhesives having a refractive index of at least 1.50. The pressure-sensitive adhesives comprise at least one monomer containing a substituted or an unsubstituted biphenyl group. 2. The adhesive article of claim 1 , wherein the substrate comprises a flexible substrate comprising a plastic film.3. The adhesive article of claim 2 , wherein the plastic film comprises a polypropylene film claim 2 , a polyethylene film claim 2 , a polyvinyl chloride film claim 2 , a polyester film claim 2 , a polycarbonate film claim 2 , a polymethyl(meth)acrylate film claim 2 , a cellulose acetate film claim 2 , a cellulose triacetate film claim 2 , or an ethyl cellulose film.4. The adhesive article of claim 1 , wherein the substrate comprises an inflexible substrate comprising metal claim 1 , metallized polymeric film claim 1 , tin oxide coated glass claim 1 , tin oxide coated polyester claim 1 , polymethyl(meth)acrylate plate claim 1 , polycarbonate plate claim 1 , glass claim 1 , or a ceramic sheet.5. The adhesive article of claim 1 , wherein the coated pressure sensitive adhesive has a thickness of from 2-500 micrometers dry thickness.6. The adhesive article of claim 1 , wherein the coated pressure sensitive adhesive has a thickness of from 25-250 micrometers dry thickness.7. The adhesive article of claim 1 , wherein the pressure sensitive adhesive further comprises at least one additive.8. The adhesive article of claim 7 , wherein the additive comprises a UV absorber claim 7 , a hindered amine light stabilizer claim 7 , or a combination thereof.9. The adhesive article of claim 7 , wherein the additive comprises a UV absorber claim 7 , wherein the UV absorber is present in an amount of 1 to 5 weight % based on the total weight of the pressure sensitive adhesive composition.11. The pressure sensitive adhesive of claim 10 , wherein the additive comprises a UV absorber claim 10 , a hindered amine light stabilizer claim 10 , or a ...

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01-08-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVES WITH ACID-EPOXY CROSSLINKING SYSTEMS

Номер: US20130196152A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A pre-adhesive composition is described comprising an acid-functional (meth)acryloyl copolymer and epoxy resin, which when crosslinked with or without using an ionic photoacid generator (PAG) provides a (e.g. pressure-sensitive) adhesive. 1. A crosslinkable syrup polymer composition comprising: i) an alkyl(meth)acrylate monomer;', 'ii) optionally an epoxy-functional (meth)acryloyl monomer;', 'iii) an acid-functional ethylenically unsaturated monomer;', 'iv) an optional non-acid functional polar monomer;', 'v) an optional vinyl monomer, and', 'vi) an optional multifunctional (meth)acrylate crosslinker;, 'a) a (meth)acrylic solute copolymer comprising interpolymerized monomers comprisingb) an epoxy resin; andc) optionally an ionic photoacid generatord) a solvent monomer mixture comprising an alkyl(meth)acrylate monomer.2. The crosslinkable syrup polymer composition of wherein the acid-functional ethylenically unsaturated monomer of said solute copolymer is used in amounts of 1 to 15 parts by weight of the 100 parts of the total monomer of the solute copolymer.3. The crosslinkable syrup polymer composition of wherein the epoxy resin comprises on average greater than 1 polymerizable epoxy group per molecule.4. The crosslinkable syrup polymer composition of wherein the epoxy resin contains cyclohexene oxide groups.5. The crosslinkable syrup polymer composition of wherein the epoxy-functional (meth)acryloyl monomer of the solute copolymer is used in an amount of 1 to 20 parts by weight relative to 100 parts by weight of the total monomer of the epoxy-functional copolymer.10. The crosslinkable syrup polymer composition of wherein the solvent monomer mixture comprisesi) an optional epoxy-functional (meth)acryloyl monomeri) an acid-functional ethylenically unsaturated monomer;iii) an optional non-acid functional polar monomer;iv) an optional vinyl monomer, andv) an optional multifunctional (meth)acrylate crosslinker.11. The crosslinkable syrup polymer composition of wherein ...

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01-08-2013 дата публикации

Pressure-sensitive adhesives with onium-epoxy crosslinking system

Номер: US20130196153A1
Принадлежит: 3M Innovative Properties Co

A pre-adhesive composition is described comprising an acid- and epoxy-functional (meth)acryloyl copolymer, which when crosslinked with or without using an ionic photoacid generator (PAG) provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles having desirable properties.

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08-08-2013 дата публикации

AQUEOUS POLYMER DISPERSION SUITABLE FOR APPLICATION AS TACKIFIER FOR ADHESIVES AND PREPARABLE BY EMULSION POLYMERIZATION BASED ON C1 TO C20 ALKYL (METH)ACRYLATES

Номер: US20130202886A1
Принадлежит:

Described is an aqueous dispersion comprising at least one polymer dispersed in water and having a weight-average molecular weight of less than 50 000 and a glass transition temperature of −40° C. to 0° C., preparable by emulsion polymerization in the presence of at least one chain transfer agent of a monomer mixture comprising at least 40% by weight of C1 to C20 alkyl (meth)acrylates, 0% to 30% by weight of vinylaromatics, at least 0.1% by weight of acid monomers, and 0% to 50% by weight of further monomers. The dispersion can be used in particular as a tackifier for adhesives. 1. An aqueous dispersion comprising at least one polymer dispersed in water and having a weight-average molecular weight of less than 50 000 and a glass transition temperature of greater than or equal to −40° C. to less than or equal to 0° C. , preferably greater than or equal to −35° C. to less than or equal to 0° C. , preparable by emulsion polymerization in the presence of at least one chain transfer agent and preparable from a monomer mixture comprising(a) at least 40% by weight of at least one C1 to C20 alkyl (meth)acrylate,(b) 0% to 30% by weight of at least one vinylaromatic,(c) at least 0.1% by weight of at least one acid monomer,(d) 0% to 50% by weight of further monomers,the figures for the monomer amounts being based in each case on the sum of all the monomers.2. The dispersion according to claim 1 , wherein the weight-average molecular weight of the polymer is from 1500 to 45 000 claim 1 , preferably from 2000 to 20 000.3. The dispersion according to either of the preceding claims claim 1 , wherein the theoretical glass transition temperature of the polymer claim 1 , calculated for a polymerization without chain transfer agent claim 1 , is greater than −25° C.4. The dispersion according to any of the preceding claims claim 1 , wherein the monomers (a) are used in an amount of 60% to 99.9% by weight and are selected from one or more C1 to C10 alkyl (meth)acrylates.5. The ...

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08-08-2013 дата публикации

ACRYLIC PRESSURE-SENSITIVE ADHESIVE TAPE

Номер: US20130203941A1
Принадлежит: NITTO DENKO CORPORATION

An acrylic pressure-sensitive adhesive tape including an acrylic pressure-sensitive adhesive layer, wherein a 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to a glass plate is 10 N/20 mm or more and a 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to an acrylic plate is 10 N/20 mm or more. The acrylic pressure-sensitive adhesive layer contains an acrylic polymer (A), has a gel fraction of 65% or more, and has a 300% tensile residual stress of from 7 to 16 N/cm. 1. An acrylic pressure-sensitive adhesive tape comprising an acrylic pressure-sensitive adhesive layer , whereina 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to a glass plate is 10 N/20 mm or more,a 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to an acrylic plate is 10 N/20 mm or more,the acrylic pressure-sensitive adhesive layer contains an acrylic polymer (A),the acrylic pressure-sensitive adhesive layer has a gel fraction of 65% or more, and{'sup': '2', 'the acrylic pressure-sensitive adhesive layer has a 300% tensile residual stress of from 7 to 16 N/cm.'}2. The acrylic pressure-sensitive adhesive tape according to claim 1 , wherein the acrylic polymer (A) contains claim 1 , as a monomer unit claim 1 , a monomer having a hydroxyl group in a molecule thereof.3. The acrylic pressure-sensitive adhesive tape according to claim 1 , wherein the acrylic pressure-sensitive adhesive layer further contains an acrylic polymer (B) having a weight average molecular weight of from 1 claim 1 ,000 to 30 claim 1 ,000.4. The acrylic pressure-sensitive adhesive tape according to claim 2 , wherein the acrylic pressure-sensitive adhesive layer further contains an acrylic polymer (B) having a weight average molecular weight of from 1 claim 2 ,000 to 30 claim 2 ,000.5. The acrylic pressure-sensitive adhesive tape according to claim 1 , which is an optical pressure-sensitive adhesive tape.6. The acrylic pressure- ...

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15-08-2013 дата публикации

DOUBLE-SIDED PRESSURE-SENSITIVE ADHESIVE TAPE

Номер: US20130209798A1
Принадлежит: NITTO DENKO CORPORATION

A double-sided pressure-sensitive adhesive tape includes: a substrate; a first pressure-sensitive adhesive layer provided on one surface of the substrate; and a second pressure-sensitive adhesive layer provided on the other surface of the substrate. At least one of the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer contains both an acrylic polymer and an acrylic oligomer whose weight average molecular weight is 20000 or less and whose monomer is different from that of the acrylic polymer. The content of a tackifier for providing tackiness is less than 5% by mass. By containing the acrylic oligomer whose monomer is different from that of the acrylic polymer in at least one of the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer, the drop impact resistance in a low-temperature atmosphere is improved. 1. A double-sided pressure-sensitive adhesive tape to be used for fixing members of electronic devices , comprising:a substrate;a first pressure-sensitive adhesive layer provided on one surface of the substrate; anda second pressure-sensitive adhesive layer provided on the other surface of the substrate, whereinat least one of the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer contains both an acrylic polymer and an acrylic oligomer whose weight average molecular weight is 20000 or less and whose monomer is different from that of the acrylic polymer.2. The double-sided pressure-sensitive adhesive tape according to claim 1 , whereinthe content of a tackifier in at least one of the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer is less than 5% by mass.3. The double-sided pressure-sensitive adhesive tape according to claim 1 , whereinthe thickness of the substrate is 5 to 20% relative to that of the double-sided pressure-sensitive adhesive tape.4. The double-sided pressure-sensitive adhesive tape according to ...

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15-08-2013 дата публикации

AQUEOUS DISPERSION TYPE OIL-RESISTANT PRESSURE-SENSITIVE ADHESIVE COMPOSITION, OIL-RESISTANT PRESSURE-SENSITIVE ADHESIVE SHEET, ADHESION METHOD, AND OIL-RESISTANT ADHESIVE STRUCTURE

Номер: US20130210993A1
Принадлежит: NITTO DENKO CORPORATION

An aqueous dispersion type oil-resistant pressure-sensitive adhesive composition contains an aqueous dispersion polymer and inorganic particles. The content ratio of the inorganic particles with respect to 100 parts by mass of the aqueous dispersion polymer is 3 to 90 parts by mass. 1. An aqueous dispersion type oil-resistant pressure-sensitive adhesive composition comprising:an aqueous dispersion polymer and inorganic particles, whereinthe content ratio of the inorganic particles with respect to 100 parts by mass of the aqueous dispersion polymer is 3 to 90 parts by mass.2. The aqueous dispersion type oil-resistant pressure-sensitive adhesive composition according to claim 1 , whereinan external cross-linking agent is further blended therein.3. The aqueous dispersion type oil-resistant pressure-sensitive adhesive composition according to claim 1 , whereinthe average particle size of each of the inorganic particles is 1 to 1000 nm.4. The aqueous dispersion type oil-resistant pressure-sensitive adhesive composition according to claim 1 , whereinthe inorganic particles are silica particles.5. The aqueous dispersion type oil-resistant pressure-sensitive adhesive composition according to claim 1 , whereinthe aqueous dispersion polymer is an acrylic polymer obtained by polymerizing a monomer component which contains, as the primary component, an alkyl (meth)acrylate.6. The aqueous dispersion type oil-resistant pressure-sensitive adhesive composition according to claim 1 , whereinthe standard deviation of the average particle size of the aqueous dispersion polymer based on volume is 0.001 μm or more and 0.2 μm or less.7. An oil-resistant pressure-sensitive adhesive sheet comprising:a pressure-sensitive adhesive layer prepared from an aqueous dispersion type oil-resistant pressure-sensitive adhesive composition, whereinthe aqueous dispersion type oil-resistant pressure-sensitive adhesive composition containsan aqueous dispersion polymer and inorganic particles, andthe ...

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29-08-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE COMPOUND, PRESSURE-SENSITIVE ADHESIVE TAPE, AND WAFER TREATMENT METHOD

Номер: US20130220533A1
Принадлежит:

The present invention aims to provide an adhesive composition which has high initial adhesion and can strongly fix an adherend, while can be peeled off easily by light irradiation even after undergoing a high-temperature process at 200° C. or higher. The present invention also aims to provide an adhesive tape produced from the adhesive composition, and wafer treatment method using the adhesive composition. The present invention provides an adhesive composition including an adhesive component, a photoinitiator, and a silicone compound containing a functional group that is crosslinkable with the adhesive component. 1. An adhesive composition , comprising:an adhesive component;a photoinitiator; anda silicone compound containing a functional group that is crosslinkable with the adhesive component.2. The adhesive composition according to claim 1 ,wherein the adhesive component is a photocurable adhesive component.3. The adhesive composition according to claim 2 ,wherein the photocurable adhesive component contains an alkyl (meth)acrylate polymerizable polymer having a radically-polymerizable unsaturated bond in a molecule.5. An adhesive tape claim 1 , comprising an adhesive layer of the adhesive composition according to on at least one surface of a substrate.6. A wafer treatment method claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a step of fixing a support plate in which a wafer is fixed to a support plate with the adhesive composition according to ;'}a step of treating the wafer in which the surface of the wafer fixed to the support plate is subjected to a treatment including heating at 200° C. or higher; anda step of peeling the support plate in which the wafer after the treatment is irradiated with light to cure the adhesive composition to peel off the support plate from the wafer.9. An adhesive tape claim 2 , comprising an adhesive layer of the adhesive composition according to on at least one surface of a substrate.10. An adhesive tape ...

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29-08-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE COMPOSITION

Номер: US20130224436A1
Принадлежит: LG Chem, LTD

Provided is a pressure-sensitive adhesive composition. The pressure-sensitive adhesive composition may be applied as a light diffusing or scattering material to various display devices or lighting apparatuses. 2. The composition according to claim 1 , wherein the monomer component further comprises (meth)acrylic acid.4. The composition according to claim 1 , wherein the monomer component or polymer component is a partially polymerized product of a mixture comprising a (meth)acrylic acid ester monomer; and the compound represented by any one of the Formulas 1 to 3.5. The composition according to claim 4 , wherein the mixture comprises 50 to 99.9 parts by weight of a (meth)acrylic acid ester monomer and 0.1 to 50 parts by weight of the compound represented by any one of the Formulas 1 to 3.6. The composition according to claim 4 , wherein the mixture further comprises a (meth)acrylic acid.7. The composition according to claim 6 , wherein the mixture comprises 50 to 99.9 parts by weight of a (meth)acrylic acid ester monomer claim 6 , 0.1 to 20 parts by weight of (meth)acrylic acid and 0.1 to 40 parts by weight of the compound represented by any one of the Formulas 1 to 3.9. The composition according to claim 8 , wherein the mixture comprises 50 to 99.9 parts by weight of a (meth)acrylic acid ester monomer claim 8 , 0.1 to 50 parts by weight of the compound represented by Formula 4 and 0.1 to 40 parts by weight of the compound represented by any one of the Formulas 1 to 3.10. The composition according to claim 1 , wherein “b*” value on the CIE coordinate system is from −2 to 3 claim 1 , and YI value is from −8.0 to 7.5 after being cured.11. The composition according to claim 10 , wherein the “b*” value on the CIE coordinate system is from −1 to 3 after being cured.12. The composition according to claim 10 , wherein the YI value is from 0 to 7.5 after being cured.13. The composition according to claim 1 , wherein the monomer or polymer component has a viscosity at 25° C. ...

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29-08-2013 дата публикации

MOISTURE-CURABLE REACTIVE HOT-MELT ADHESIVE AGENT COMPOSITION

Номер: US20130225745A1
Принадлежит: KANEKA CORPORATION

The present invention aims to provide a moisture-curable reactive hot-melt adhesive composition which contains no vinyl chloride resin, which is excellent in adhesion to oily steel sheets and electroplated steel sheets, which has high strength immediately after application to effectively improve the production cycle, and which can be suitably used in vehicle applications. This challenge is solved by a moisture-curable reactive hot-melt adhesive that includes an oxyalkylene polymer containing a reactive silyl group, an alkyl (meth)acrylate (co)polymer, a tackifying resin, and a specific inorganic filler in combination. 2. The moisture-curable reactive hot-melt adhesive composition according to claim 1 ,wherein the calcium carbonate (D) is calcium carbonate treated with a fatty acid or its salt, or with a resin acid or its salt.3. The moisture-curable reactive hot-melt adhesive composition according to claim 1 ,wherein the calcium carbonate (D) is heavy calcium carbonate treated with a fatty acid or its salt, or with a resin acid or its salt.4. The moisture-curable reactive hot-melt adhesive composition according to claim 1 ,wherein the silica (D) is hydrophobic silica.6. The moisture-curable reactive hot-melt adhesive composition according to claim 1 , for use as a hot-melt adhesive composition for oily steel sheets.7. The moisture-curable reactive hot-melt adhesive composition for oily steel sheets according to claim 6 ,wherein the inorganic filler (D) is hydrophobic silica.8. The moisture-curable reactive hot-melt adhesive composition according to claim 2 ,wherein the calcium carbonate (D) is heavy calcium carbonate treated with a fatty acid or its salt, or with a resin acid or its salt. The present invention relates to a moisture-curable reactive hot-melt adhesive composition which contains no vinyl chloride resin, which is excellent in adhesion to oily steel sheets and electroplated steel sheets, which effectively improves the production cycle, and which can be ...

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05-09-2013 дата публикации

CURABLE ADHESIVE COMPOSITIONS

Номер: US20130230706A1
Принадлежит: PixelOptics, Inc.

Curable adhesive compositions are provided that exhibit a high refractive index.

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19-09-2013 дата публикации

ADHESIVE FOR POLARIZING PLATE, AND POLARIZING PLATE COMPRISING SAME

Номер: US20130244041A1
Принадлежит: LG CHEM. LTD.

Provided are an adhesive for a polarizing plate and a polarizing plate comprising the same, and more particularly, an adhesive composition for a polarizing plate comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator, as well as a polarizing plate comprising a polarizer, a polymer film adhered to one side or both sides of the polarizer, and an adhesive layer for bonding the polarizer and the polymer film, in which the adhesive layer is formed of an adhesive composition comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator. 1. An adhesive composition for a polarizing plate comprising:one or more acrylic monomers having a hydrophilic group;a radical polymerization initiator;an epoxy resin; anda cationic photopolymerization initiator.2. The adhesive composition for a polarizing plate of claim 1 , wherein the adhesive composition for a polarizing plate comprises 20 to 80 parts by weight of the one or more acrylic monomers having a hydrophilic group claim 1 , 0.5 to 10 parts by weight of the radical polymerization initiator claim 1 , 30 to 80 parts by weight of the epoxy resin and 1 to 10 parts by weight of the cationic photopolymerization initiator.3. The adhesive composition for a polarizing plate of claim 1 , wherein the adhesive composition for a polarizing plate comprises 20 to 50 parts by weight of the one or more acrylic monomers having a hydrophilic group claim 1 , 0.5 to 5 parts by weight of the radical polymerization initiator claim 1 , 20 to 60 parts by weight of the epoxy resin and 1 to 7 parts by weight of the cationic photopolymerization initiator.4. The adhesive composition for a polarizing plate of claim 1 , wherein the adhesive composition for a polarizing plate comprises 30 parts by weight of the one or more acrylic monomers having a ...

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26-09-2013 дата публикации

PROCESS FOR THE PREPARATION OF RADIATION CURABLE COMPOSITIONS

Номер: US20130251912A1
Принадлежит:

The present invention relates to a process for the preparation of a radiation curable composition comprising at least (meth)acrylic copolymer A and at least one radiation curable epoxy based compound B, said process comprising a first copolymerization step, and a subsequent esterification step. 2. Process according to wherein the (meth)acrylic monomer (a1) is selected from alkyl (meth)acrylates having a Tg claim 1 , when homopolymerized claim 1 , of less than −30° C. and wherein the copolymerizable monomer (a2) is selected from monomers having a Tg claim 1 , when homopolymerized claim 1 , of more than −30° C.3. Process according to wherein the (meth)acrylic monomer (a1) is selected from 2-ethylhexyl acrylate claim 1 , butylacrylate and mixtures thereof.4. Process according to wherein the copolymerizable monomer (a2) is selected from methyl (meth)acrylate claim 1 , ethylacrylate claim 1 , tert-butyl (meth)acrylate claim 1 , vinyl acetate claim 1 , styrene and mixtures thereof.5. Process according to wherein the copolymerizable monomer (a3) is selected from (meth)acrylic acid.6. Process according to wherein the radiation curable monomer (a4) is selected from (meth)acrylic acid.7. Process according to wherein the non-copolymerizable epoxy compound (b1) is selected from glycidyl esters of saturated or unsaturated carboxylic acids claim 1 , glycidyl ethers of aliphatic or aromatic polyols claim 1 , and mixtures thereof.8. Process according to wherein the non-copolymerizable epoxy compound (b1) is selected from the monoglycidyl esters of long chain alkyl carboxylic acids wherein the alkyl chain comprises from 6 to 24 carbon atoms.9. Process according to wherein:(i) from 5 to 60% by weight of non-copolymerizable epoxy compound (b1), and(ii) from 40 to 95% by weight of monomers comprising the monomers (a1), (a2) and (a3) based on the total weight of non-copolymerizable epoxy compound (b1) and monomers comprising the monomers (a1), (a2) and (a3) are used in the ...

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26-09-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE, PRESSURE-SENSITIVE ADHESIVE LAYER, AND PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20130251990A1
Принадлежит: NITTO DENKO CORPORATION

A pressure-sensitive adhesive of the invention includes a (meth)acryl-based polymer obtained by polymerization of a monomer component including: an alkyl(meth)acrylate (a1) having a branched alkyl group of 8 to 24 carbon atoms at an ester end; and an alkyl(meth)acrylate (a2) having a linear alkyl group of 8 to 24 carbon atoms at an ester end. The pressure-sensitive adhesive can has a satisfactory level of adhesive performance and can form a pressure-sensitive adhesive layer with a lower dielectric constant. 1. A pressure-sensitive adhesive , comprising a (meth)acryl-based polymer obtained by polymerization of a monomer component including: an alkyl(meth)acrylate (a1) having a branched alkyl group of 8 to 24 carbon atoms at an ester end; and an alkyl(meth)acrylate (a2) having a linear alkyl group of 8 to 24 carbon atoms at an ester end.2. The pressure-sensitive adhesive according to claim 1 , wherein the total content of the alkyl(meth)acrylate (a1) having a branched alkyl group of 8 to 24 carbon atoms at an ester end and the alkyl(meth)acrylate (a2) having a linear alkyl group of 8 to 24 carbon atoms at an ester end in the monomer component is from 35 to 99.5% by weight.3. The pressure-sensitive adhesive according to claim 1 , wherein the alkyl(meth)acrylate (a2) having a linear alkyl group at an ester end is capable of forming a homopolymer with a Tg of −20° C. or lower.4. The pressure-sensitive adhesive according to claim 1 , wherein the monomer component further include at least one functional group-containing monomer selected from a carboxyl group-containing monomer claim 1 , a hydroxyl group-containing monomer claim 1 , and a cyclic ether group-containing monomer.5. The pressure-sensitive adhesive according to claim 1 , wherein the alkyl(meth)acrylate (a2) having a linear alkyl group at an ester end is an alkyl methacrylate having a linear alkyl group at an ester end.6. The pressure-sensitive adhesive according to claim 1 , wherein the monomer component further ...

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26-09-2013 дата публикации

Pressure Sensitive Adhesive and Adhesive Tape

Номер: US20130251991A1
Принадлежит: 3M Innovative Properties Co

There is provided a pressure sensitive adhesive displaying sufficient adhesive force to the surface of PMMA under a wide range of temperatures including ambient, low, and high temperatures, and also an adhesive tape having an adhesive layer including the pressure sensitive adhesive. There is provided a pressure sensitive adhesive comprising a polymer obtained by polymerizing 100 mass parts of a monomer mixture comprising: a monomer component 1 comprising an acrylate mixture selected from an aliphatic alkyl(meth)acrylate having a carbon number of 4-6 and an aliphatic alkyl(meth)acrylate having a carbon number of 7-12; a monomer component 2 comprising an amide group-containing vinyl monomer; a monomer component 3 comprising an ester of a non-tertial aromatic alcohol and (meth)acrylic acid, or an ester of a non-tertial alicyclic alcohol and (meth)acrylic acid; and a monomer component 4 comprising (meth)acrylic acid.

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03-10-2013 дата публикации

POLYMERS DERIVED FROM SECONDARY ALKYL (METH)ACRYLATES

Номер: US20130260149A1
Принадлежит:

Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl(meth)acrylate monomer. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics and exceptional adhesion to low surface energy substrates. 2. The pressure-sensitive adhesive of wherein the at least three structural isomers of a secondary alkyl(meth)acrylate of Formula (I) are prepared by the reaction of (meth)acrylic acid with an olefin having a single unsaturation in the presence of a fluorinated sulfonic acid.3. The pressure-sensitive adhesive of wherein the at least three structural isomers of a secondary alkyl(meth)acrylate of Formula (I) are prepared by the reaction of (meth)acrylic acid with an olefin having a single unsaturation in a continuous process.4. The pressure-sensitive adhesive of wherein the continuous process uses a packed-bed reactor with a solid acid catalyst.6. (canceled)7. The pressure-sensitive adhesive of which has a Tc of ≦0° C.8. A pressure-sensitive adhesive article comprising a coating of the pressure-sensitive adhesive of on a backing.10. The (meth)acrylate polymer of wherein the interpolymerized monomers comprise at least one monomer selected from a (meth)acrylic acid ester of a C-Calkanol claim 9 , an acid-functional claim 9 , ethylenically unsaturated monomer claim 9 , a non-acid-functional claim 9 , ethylenically unsaturated polar monomer claim 9 , and a mixture thereof.11. The (meth)acrylate polymer of wherein the interpolymerized monomers comprise an acid-functional claim 10 , ethylenically unsaturated monomer.12. The (meth)acrylate polymer of wherein the interpolymerized monomers comprise:a) 20 to 99.5 parts by weight of the at least three structural isomers of a secondary alkyl(meth)acrylate of Formula (I); and{'sub': 1', '32, 'b) 0 to 80 parts by weight of a (meth)acrylic acid ester of a C-Calkanol;'}c) 0.5 to 20 parts by weight of an acid- ...

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10-10-2013 дата публикации

COMPOSITIONS FOR PRODUCTION OF ABHESIVE COATINGS

Номер: US20130266811A1
Принадлежит: HINTERWALDNER CONSULTING & PARTNER

The present invention relates to compositions which comprise an olefinic component and a compound reactive or curable with the olefinic component, and which are suitable for production of release layers 2. A composition as claimed in claim 1 , wherein A and B together contain at least 12 carbon atoms.3. A composition as claimed in claim 1 , wherein A and B independently of one another stand for an alkyl group having 6 to 24 carbon atoms.4. A composition as claimed in claim 1 , wherein A and B are different.5. A composition as claimed in claim 3 , wherein A is an unbranched alkyl group having 10 carbon atoms and B is an unbranched alkyl group having 8 carbon atoms.6. A composition as claimed in claim 1 , wherein component b) is selected from organosilicon compounds claim 1 , unsaturated polyester resins claim 1 , acrylate- or methacrylate-functionalized or allyl-functionalized polyalkylenediols claim 1 , and acrylic or methacrylic esters.7. A composition as claimed in claim 6 , wherein the organosilicon compound is radiation-curable.8. A composition as claimed in claim 7 , wherein the radiation-curable organosilicon compound is an organopolysiloxane containing epoxy groups claim 7 , an SiH-functional organosilicon compound or an organopolysiloxane containing acryloyloxy or methacryloyloxy groups.9. A composition as claimed in claim 8 , wherein the silicone containing epoxy groups are obtained by reacting a silane or siloxane having SiH groups with an olefinic epoxide claim 8 , in the presence of a tertiary amine and of a hydrosilylation catalyst.12. A composition as claimed in claim 1 , wherein the weight ratio of component (a) to component (b) is in the range from 1:5 to 2:1 claim 1 , more particularly in the range from 1:3 to 1:1.13. A composition as claimed in claim 1 , further comprising a photoinitiator claim 1 , a radical initiator or an initiator of cationic curing.14. (canceled)15. A method for producing an abhesive release layer claim 1 , wherein a ...

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10-10-2013 дата публикации

ADHESIVE COMPOSITION FOR BONDING LOW SURFACE ENERGY POLYOLEFIN SUBSTRATES

Номер: US20130267670A1
Автор: Xie Xiaoyi
Принадлежит: IPS CORPORATION

A two-part acrylic adhesive composition comprising at least one organoborane-amine complex initiator and at least one multifunctional maleimide crosslinker. 1. A two-part acrylic adhesive composition comprising:at least one organoborane-amine complex initiator, andat least one multifunctional maleimide crosslinker.2. The two-part acrylic adhesive composition of wherein the organoborane-amine complex initiator is a trialkylborane-amine complex.3. The two-part acrylic adhesive composition of wherein the trialkylborane-amine complex is triethylborane-1 claim 2 ,3-diaminopropane.4. The two-part acrylic adhesive composition of wherein the multifunctional maleimide crosslinker comprises at least two maleimide end groups per molecule.5. The two-part acrylic adhesive composition of wherein the multifunctional maleimide crosslinker is a bismaleimide crosslinker.7. The two-part acrylic adhesive composition of wherein a first part that is an initiator part comprises at least one organoborane-amine complex initiator claim 1 , and optionally at least one non-polymerizable plasticizer.8. The two-part acrylic adhesive composition of wherein a second part that is an activator part further comprises at least one activator which is an amine acceptor for decomplexing the organoborane-amine complex.9. The two-part acrylic adhesive composition of wherein the at least one activator comprises at least one organic acid.10. The two-part acrylic adhesive composition of wherein the at least one organic acid is a carboxylic acid.11. The two-part acrylic adhesive composition of wherein the carboxylic acid comprises at least one member selected from the group consisting of (meth)acrylic acid claim 10 , acetic acid claim 10 , benzoic acid claim 10 , p-methoxybenzoic acid claim 10 , maleic acid claim 10 , succinic acid and mixtures thereof.12. The two-part acrylic adhesive composition of further comprising at least one polymerizable ethylenically unsaturated monomer claim 1 , oligomer or a ...

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31-10-2013 дата публикации

ACTINICALLY CURABLE ADHESIVE COMPOSITION

Номер: US20130284360A1
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

A photocurable adhesive composition is disclosed herein that has high adhesive strength and optical clarity and which in the cured state is reworkable and exhibits low propensities for exhibiting glow mark and pooling effects. The composition contains a chain transfer agent, an urethane (meth)acrylate having a plurality of ethylenically unsaturated groups, a (meth)acrylate monomer and a photoinitiator. The composition may optionally contain a light stabilizer. 1. An actinically curable adhesive composition comprising:a) an aliphatic urethane acrylate having a plurality of ethylenically unsaturated groups;b) a (meth)acrylate monomer;c) a photoinitiator;d) a plasticizer; ande) pentaerythritol tetrakis(3-mercaptopropionate)wherein the level of the (meth)acrylate monomer plus the level of the plasticizer together range from 30 weight percent to 50 weight percent of the total weight of the composition.2. The actinically curable adhesive composition of wherein the composition in its actinically cured state in use in a display device is reworkable.3. The actinically curable adhesive composition of wherein the composition in its actinically cured state and in use for bonding a glass plate to a front polarizer of an LCD exhibits a glow mark test rating of 2 or less in a glow mark test.4. The actinically curable adhesive composition of wherein the composition in its actinically cured state and in use for bonding a glass plate to a front polarizer of an LCD exhibits a pooling test rating of 1 or less in a pooling test.5. The actinically curable adhesive composition of wherein level of the plasticizer ranges from 3 weight percent to 40 weight percent of the total weight of the composition.6. The actinically curable adhesive composition of wherein the composition upon curing exhibits a modulus of less than or equal to 0.27 megapascals.7. The actinically curable adhesive composition of wherein the composition upon curing exhibits a modulus that ranges from 0.01 megapascals to 0.1 ...

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31-10-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVES WITH TRIAZINE-EPOXY CROSSLINKING SYSTEM

Номер: US20130289219A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

A crosslinkable composition is described comprising an acid- and epoxy-functional copolymer, which when cross-linked with a triazine crosslinking agent provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles. 1. A crosslinkable composition comprising: an epoxy-functional (meth)acryloyl monomer;', 'an acid-functional ethylenically unsaturated monomer; and', 'an optional multifunctional (meth)acrylate crosslinker; and, 'an acid- and epoxy-functional (meth)acrylic copolymer comprising interpolymerized monomers comprisinga chlorinated triazine crosslinking agent;wherein the epoxy-functional (meth)acryloyl monomer is used in an amount of no greater than 5 parts by weight, and the chlorinated triazine crosslinking agent is used in an amount of no greater than 0.01 part by weight, relative to 100 parts by weight of the total monomer content that would form an unmodified acid-functional (meth)acrylic copolymer.2. The crosslinkable composition of wherein the epoxy-functional (meth)acryloyl monomer is used in an amount of no greater than 1 part by weight.3. The crosslinkable composition of wherein the acid- and epoxy-functional (meth)acrylic copolymer comprises interpolymerized monomers comprising a (meth)acrylic acid ester of a non-tertiary alcohol claim 1 , an acid-functional ethylenically unsaturated monomer claim 1 , and an epoxy-functional (meth)acryloyl monomer.4. The crosslinkable composition of wherein the acid-functional ethylenically unsaturated monomer is used in an amount of at least 1 part by weight of the 100 parts of the total monomer content that would form an unmodified acid-functional (meth)acrylic copolymer.5. The crosslinkable composition of wherein the acid- and epoxy-functional (meth)acrylic copolymer comprises interpolymerized monomers comprising:85 to 99 parts by weight of a (meth)acrylic acid ester of a non-tertiary alcohol; and1 to 15 parts by weight of an acid-functional ethylenically unsaturated monomer;based on 100 parts of ...

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05-12-2013 дата публикации

PRESSURE-SENSITIVE ADHESIVE SHEET FOR OPTICAL USE

Номер: US20130323437A1
Принадлежит: NITTO DENKO CORPORATION

Provided is a pressure-sensitive adhesive sheet for optical use which less suffers from a misoperation-causing change in capacitance upon application to an optical member. 1. A pressure-sensitive adhesive sheet for optical use comprising a pressure-sensitive adhesive layer , the pressure-sensitive adhesive sheet having a dielectric constant (relative) of from 2 to 8 at a frequency of 1 MHz and a dielectric loss tangent of more than 0 and 0.2 or less at a frequency of 1 MHz ,wherein the pressure-sensitive adhesive layer is an acrylic pressure-sensitive adhesive layer;wherein the acrylic pressure-sensitive adhesive layer comprises, as a base polymer, an acrylic polymer derived from an acrylic monomer as an essential monomer component and a polar-group-containing monomer as a copolymerizable monomer component;wherein the essential monomer component is an alkyl (meth)acrylate alone or in combination with an alkoxyalkyl (meth)acrylate, the alkyl (meth)acrylate having a linear or branched chain alkyl group containing 1 to 4 carbon atoms;wherein the polar-group-containing monomer is at least one monomer selected from the group consisting of carboxyl-containing monomers or acid anhydrides of them, hydroxyl-containing monomers, amino-containing monomers, amido-containing monomers, and heterocycle-containing vinyl monomers.2. The pressure-sensitive adhesive sheet for optical use according to claim 1 , wherein the pressure-sensitive adhesive sheet has a dielectric constant (relative) at a frequency of 1.0×10Hz being 60% or more of a dielectric constant (relative) at a frequency of 1.0×10Hz.3. The pressure-sensitive adhesive sheet for optical use according to claim 1 , wherein the pressure-sensitive adhesive sheet has an absolute value of difference between a dielectric loss tangent at a frequency of 1.0×10Hz and a dielectric loss tangent at a frequency of 1.0×10Hz of 0.15 or less.4. The pressure-sensitive adhesive sheet for optical use according to claim 1 ,wherein the ...

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05-12-2013 дата публикации

OPTICALLY CLEAR ADHESIVE, METHOD OF USE AND ARTICLES THEREFROM

Номер: US20130323521A1
Принадлежит:

An adhesive composition includes an alkyl (meth)acrylate ester, wherein the alkyl group has 4 to 18 carbon atoms, a hydrophilic copolymerizable monomer and a free-radical generating initiator. The adhesive composition has a tan delta value of between about 0.5 and about 1.0 at a temperature of between about 25 C and about 100 C. 1. An adhesive composition comprising:an alkyl (meth)acrylate ester, wherein the alkyl group has 4 to 18 carbon atoms;a hydrophilic copolymerizable monomer; anda free-radical generating initiator;wherein the adhesive composition maintains a tan delta value of between about 0.5 and about 1.0 at a temperature of between about 25° C. and about 100° C.2. The adhesive composition of claim 1 , wherein the adhesive composition maintains a tan delta value of between about 0.6 and about 0.8 at a temperature of between about 25° C. and about 100° C.3. The adhesive composition of claim 1 , wherein the alkyl(meth)acrylate ester is selected from the group consisting of: 2-ethylhexyl acrylate (2-EHA) claim 1 , isobornyl acrylate (IBA) claim 1 , iso-octylacrylate (IOA) and butyl acrylate (BA).4. The adhesive composition of claim 1 , wherein the hydrophilic copolymerizable monomer is selected from the group consisting of: acrylic acid (AA) claim 1 , 2-hydroxyethyl acrylate (HEA) claim 1 , and hydroxypropyl acrylate (HPA) claim 1 , ethoxyethoxyethyl acrylate (V-190) claim 1 , acrylic amide (Acm) claim 1 , diacetone acrylamide claim 1 , N claim 1 ,N-dimethylacrylamide claim 1 , and N-morpholino acrylate (MoA).5. The adhesive composition of claim 1 , wherein the alkyl (meth)acrylate ester comprises a low Tg yielding alkyl (meth)acrylate ester claim 1 , wherein the low Tg alkyl (meth)acrylate ester as a homopolymer has a Tg of between about −70° C. and about 20° C.6. (canceled)7. The adhesive composition of claim 5 , wherein the alkyl (meth)acrylate ester further comprises a high Tg yielding alkyl (meth)acrylate ester claim 5 , wherein the high Tg alkyl (meth) ...

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26-12-2013 дата публикации

ADHESIVE FILM, ADHESIVE COMPOSITION FOR THE SAME, AND OPTICAL MEMBER INCLUDING THE SAME

Номер: US20130345333A1
Принадлежит:

An adhesive film, an adhesive composition for the same, and an optical member including the same, the adhesive film having an index of refraction of about 1.48 or more and a dielectric constant variation of about 30% or less, as expressed by Equation 1: 2. The adhesive film as claimed in claim 1 , wherein the adhesive film includes a (meth)acrylate copolymer having carbonate groups and aromatic groups claim 1 , a photocurable monomer claim 1 , an initiator claim 1 , and a crosslinking agent.3. The adhesive film as claimed in claim 2 , wherein the adhesive film is formed of a composition including about 1 wt % to about 65 wt % of the (meth)acrylate copolymer claim 2 , about 15 wt % to about 90 wt % of the photocurable monomer claim 2 , about 0.1 wt % to about 10 wt % of the initiator claim 2 , and about 0.01 wt % to about 10 wt % of the crosslinking agent.6. The adhesive film as claimed in claim 5 , wherein the adhesive film includes a (meth)acrylate copolymer having carbonate groups and aromatic groups claim 5 , a photocurable monomer claim 5 , an initiator claim 5 , and a crosslinking agent.7. The adhesive film as claimed in claim 6 , wherein the adhesive film is formed of a composition including about 1 wt % to about 65 wt % of the (meth)acrylate copolymer claim 6 , about 15 wt % to about 90 wt % of the photocurable monomer claim 6 , about 0.1 wt % to about 10 wt % of the initiator claim 6 , and about 0.01 wt % to about 10 wt % of the crosslinking agent.9. An adhesive composition comprising a (meth)acrylate copolymer having carbonate groups and aromatic groups.10. The adhesive composition as claimed in claim 9 , wherein the (meth)acrylate copolymer has a dielectric constant of about 3.0 or less at a frequency of 10Hz to 10Hz and an index of refraction of about 1.50 to about 1.60.11. The adhesive composition as claimed in claim 9 , wherein the (meth)acrylate copolymer has a weight average molecular weight of about 5 claim 9 ,000 g/mol to about 100 claim 9 ,000 g/ ...

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26-12-2013 дата публикации

Use of branched addition copolymers in curing systems

Номер: US20130345358A1
Принадлежит: UNILEVER PLC

The present invention relates to the use of branched addition copolymers in systems which can be cured post synthesis to form for example polymer coatings, sealants, inks, adhesives or composites and also relates to methods of preparing the cured systems, compositions comprising such copolymers and the use of the compositions in for example but not limited to coatings, inks, sealants, adhesives or composites.

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16-01-2014 дата публикации

PRESSURE-SENSITIVE ADHESIVE COMPOSITION (As Amended)

Номер: US20140016069A1
Принадлежит: LG CHEM, LTD.

A pressure-sensitive adhesive composition is provided. The pressure-sensitive adhesive composition can show stable antistatic performance, and in particular can stably maintain its antistatic performance even when the pressure-sensitive adhesive composition is kept for an extended time under extreme conditions or conditions in which environmental changes are severe, and also has excellent general physical properties such as pressure-sensitive adhesive properties, durability and workability. 1. A pressure-sensitive adhesive composition comprising;an acrylic polymer, comprising, as polymerized units, 60 to 89.9 parts by weight of (meth)acrylic acid ester monomer and 10 to 30 parts by weight of (meth)acrylic acid alkylene oxide monomer;an ionic compound that is in a liquid phase at room temperature; anda metal salt that is in a solid phase at room temperature, [{'br': None, 'i': 'B+C≦', '15\u2003\u2003General Relation 1'}, {'br': None, 'i': ≦B; and', ' Подробнее

16-01-2014 дата публикации

PRESSURE-SENSITIVE ADHESIVE COMPOSITION

Номер: US20140017420A1
Принадлежит: LG CHEM, LTD.

A pressure-sensitive adhesive composition, a pressure-sensitive adhesive polarizing plate and a liquid crystal display device are provided. The pressure-sensitive adhesive composition has excellent durability reliability under extreme conditions such as high temperature and/or humidity conditions, and shows superior workability such as cuttability or re-workability. Also, when the pressure-sensitive adhesive composition is applied to a polarizing plate or a liquid crystal display device, the composition can effectively prevent light leakage. Such a pressure-sensitive adhesive exhibits excellent characteristics, for example, even when the pressure-sensitive adhesive is applied to a 20-inch or more large display device. 2. The pressure-sensitive adhesive composition of claim 1 , wherein the cross-linkable acrylic polymer has a weight average molecular weight of 1 claim 1 ,000 claim 1 ,000 or more.3. The pressure-sensitive adhesive composition of claim 1 , wherein the cross-linkable acrylic polymer comprises claim 1 , as polymerized units claim 1 , 80 parts by weight to 99.9 parts by weight of (meth)acrylic acid ester monomer and 0.01 parts by weight to 20 parts by weight of cross-linkable monomer.4. The pressure-sensitive adhesive composition of claim 1 , wherein the cross-linking agent is an isocyanate cross-linking agent claim 1 , an epoxy cross-linking agent claim 1 , an aziridine cross-linking agent or a metal chelate cross-linking agent.5. The pressure-sensitive adhesive composition of claim 1 , wherein the multifunctional acrylate comprises a ring structure or a urethane bond.6. The pressure-sensitive adhesive composition of claim 1 , further comprising a radical initiator.7. The pressure-sensitive adhesive composition of claim 6 , wherein the radical initiator is a photoinitiator.8. The pressure-sensitive adhesive composition of claim 6 , wherein the radical initiator is comprised in an amount of 0.01 to 10 parts by weight claim 6 , relative to 100 parts by ...

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23-01-2014 дата публикации

MOISTURE-CURABLE HOT MELT ADHESIVE

Номер: US20140024781A1
Принадлежит: Henkel Corporation

Disclosed is a moisture-curable hot melt adhesive which has a high initial adhesive strength and is also excellent in adhesion to a slightly adhesive material. This adhesive comprises an urethane prepolymer having an isocyanate group at its end, and (A) an acrylic polymer, wherein the acrylic polymer has a polymer (A1) containing a moiety derived from a (meth)acrylic acid derivative (a1) having an alkyl group with 6 or more carbon atoms. In some embodiments the acrylic polymer (A) has an alicyclic structure. 1. A moisture-curable hot melt adhesive , comprising:an urethane prepolymer having an isocyanate group at its end, and(A) an acrylic polymer, wherein the acrylic polymer (A) includes a polymer (A1) containing a moiety derived from a (meth)acrylic acid derivative (a1) having an alkyl group with 6 or more carbon atoms.2. The moisture-curable hot melt adhesive according to claim wherein the acrylic polymer (A) has an alicyclic structure.3. The moisture-curable hot melt adhesive according to wherein the (meth)acrylic acid derivative is selected from at least one of meth)acrylic acid esters; (meth)acrylic acid amides and 2-(meth)acryloyloxyethylhexahydrophthalic acid.4. The moisture-curable hot melt adhesive according to wherein the (meth)acrylic acid derivative is selected from at least one of meth)acrylic acid esters and (meth)acrylic acid amides claim 1 , and the (meth)acrylic acid esters are alkyl esters of (meth)acrylic acid and the (meth)acrylic acid amides are meth)acrylic acid alkylamides.5. The moisture-curable hot melt adhesive according to wherein the (meth)acrylic acid derivative is selected from at least one of meth)acrylic acid ester and (meth)acrylic acid amide claim 1 , and the (meth)acrylic acid ester is selected from n-hexyl(meth)acrylate claim 1 , cyclohexyl(meth)acrylate claim 1 , n-octyl(meth)acrylate claim 1 , 2-ethylhexyl(meth)acrylate claim 1 , decyl(meth)acrylate claim 1 , isobornyl(meth)acrylate claim 1 , dodecyl (or lauryl) (meth)acrylate ...

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06-02-2014 дата публикации

PRESSURE-SENSITIVE ADHESIVES WITH MIXED PHOTOCROSSLINKING SYSTEM

Номер: US20140039083A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

The present disclosure provides a method of providing an adhesive composition comprising the steps of combining crosslinkable composition including: a) a (meth)acryloyl monomer mixture with the b) photocrosslinking agent mixture, and irradiating with UVC radiation to polymerize and crosslink the composition. 1. A method of preparing a (meth)acrylate adhesive composition comprising:a) providing a (meth)acryloyl monomer mixture and a photoinitiator,b) irradiating the mixture with UVA to partially polymerize the monomer mixture to a syrup copolymer;c) adding additional photoinitiator and optionally a multifunctional (meth)acrylate, followed by; i) a benzophenone photocrosslinker, and', 'ii) an anthraquinone photocrosslinker and/or a thioxanthone photocrosslinker;, 'd) combining the syrup polymer of steps b) or c) with a photocrosslinking mixture comprisinge) irradiating the mixture with UVA radiation andf) irradiating the mixture with UVC radiation to further crosslink the copolymer.2. The method of claim 1 , wherein the step of irradiating with UVA and UVC is concurrent.3. The method of claim 1 , wherein the step of irradiating with UVA and UVC is consecutive.4. The method of wherein the step of irradiating comprises irradiating first with a UVA source at 315 to 400 nanometers claim 1 , then with a UVC source at 100 to 280 nanometers.5. The method of wherein the photocrosslinking mixture comprises1) 5 to 50 wt. % benzophenone photocrosslinker, and2) 50 to 95 wt. % of either an anthraquinone photocrosslinker or a thioxanthone photocrosslinkers.6. The method of wherein the photocrosslinking mixture comprises1) 20 to 50 wt. % benzophenone photocrosslinker, and2) 50 to 80 wt. % of either an anthraquinone photocrosslinker or a thioxanthone photocrosslinkers.7. The method of where the photocrosslinking mixture comprises 0.01 to 10 wt. % relative to the (meth)acryloyl monomer mixture.8. The method of where the photocrosslinking mixture comprises 0.1 to 5 wt. % relative to ...

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06-02-2014 дата публикации

RADIATION-CURABLE PRESSURE-SENSITIVE ADHESIVE LAYER, AND RADIATION-CURABLE PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20140039128A1
Принадлежит: NITTO DENKO CORPORATION

An object of the present invention is to provide a radiation-curable pressure-sensitive adhesive layer that satisfies both reworkability and adhesion reliance. Further, another object of the present invention is to provide a pressure-sensitive adhesive sheet containing the radiation-curable pressure-sensitive adhesive layer. The invention relates to a radiation-curable pressure-sensitive adhesive layer, which has an adhesive strength of 1.0 N/20 mm or less before radiation curing and an adhesive strength of 3.0 N/20 mm or more after radiation curing, and a peeling adhesive strength of 40.0 N/(20 mm×20 mm) or less before radiation curing, to an acrylic plate. 1. A radiation-curable pressure-sensitive adhesive layer , which has an adhesive strength of 1.0 N/20 mm or less before radiation curing and an adhesive strength of 3.0 N/20 mm or more after radiation curing , and a peeling adhesive strength of 40.0 N/(20 mm×20 mm) or less before radiation curing , with respect to an acrylic plate.2. The radiation-curable pressure-sensitive adhesive layer according to claim 1 , which is formed from a radiation-curable pressure-sensitive adhesive comprising a base polymer and a polyfunctional monomer.3. The radiation-curable pressure-sensitive adhesive layer according to claim 2 , wherein the base polymer is a (meth)acryl-based polymer and the polyfunctional monomer is a polyfunctional monomer having an ether bond and at least two radically polymerizable functional groups with a carbon-carbon double bond in the molecule.4. The radiation-curable pressure-sensitive adhesive layer according to claim 2 , wherein the content of the polyfunctional monomer is 0.1 to 50 parts by weight based on 100 parts by weight of the base polymer.5. A radiation-curable pressure-sensitive adhesive sheet having a support and the radiation-curable pressure-sensitive adhesive layer according to formed on at least one side of the support.6. The radiation-curable pressure-sensitive adhesive sheet according ...

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27-02-2014 дата публикации

Touch panel

Номер: US20140057102A1
Принадлежит: LG Chem Ltd

[Summary] The present invention relates to a touch panel. The present touch panel has a shape that comprises a plastic substrate film and a pressure sensitive adhesive layer attached to said substrate film. Here, a phenomenon of penetrating oxygen, moisture or other foreign materials into an interface between said substrate film and said pressure sensitive adhesive layer is prevented, and decrease of optical properties by bubble generation due to the out-gassing phenomenon in the plastic substrate film is prevented. In addition, even if the pressure sensitive adhesive layer is directly attached to the conductive thin film, and it is exposed to a severe condition such as high temperature or high temperature and high humidity condition as such a state, change of resistance in the conductive thin film is effectively inhibited. Therefore, the present touch panel may be stably driven for a long time.

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27-03-2014 дата публикации

PRESSURE SENSITIVE ADHESIVE COPOLYMER COMPOSITIONS

Номер: US20140088220A1
Принадлежит: Momentive Specialty Chemicals Inc.

This invention relates to a copolymer composition comprising vinyl ester of 2-ethyl hexanoic acid (VEHA), and particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth)acrylate monomers. The present adhesive compositions provide a film with high cohesion and adhesion values, and more particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth)acrylate monomers and VeoVa 10. The present adhesive compositions provide a film with high cohesion and adhesion values with Peel on Teflon of at least 2 N/inch. 1. A pressure-sensitive adhesive copolymer composition comprising a reaction product of a vinyl ester of 2-ethyl hexanoic acid and an (meth)acrylate or a vinyl acetate and optionally a (meth)acrylic acid and optionally a vinyl ester of an alkyl group containing acid wherein the alkyl group comprises from 2 to 17 carbon atoms.2. The copolymer compositions of wherein the copolymer comprises 20-85 weight % of the vinyl ester of 2-ethyl hexanoic acid and 15-80 wt % of the (meth)acrylate.3. The copolymer compositions of wherein the copolymer comprises 60-85 weight % of the vinyl ester of 2-ethyl hexanoic acid and 15-40 wt % of the vinyl acetate.4. The copolymer compositions of wherein the copolymer comprises 0-5 wt % of the (meth)acrylic acid and 0-40 wt % of the vinyl ester of the alkyl group containing acid wherein the alkyl group comprises from 2 to 17 carbon atoms in 2 to 17 carbon atoms acids.5. The copolymer compositions of made by an emulsion polymerization route.6. The copolymer compositions of having a residual level of each monomer of below 100 ppm.7. A pressure-sensitive adhesive composition comprising the copolymer composition of claim 1 , one or more of silane derivatives claim 1 , a takifier claim 1 , an antifoam claim 1 , a plasticizer claim 1 , a surfactant claim 1 , a wetting agent claim 1 , a protective colloid claim 1 , filler claim 1 , a thickening agent claim 1 , an antiseptic claim 1 , a ...

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03-04-2014 дата публикации

ADHESIVE COMPOSITION, ADHESIVE LAYER, AND ADHESIVE SHEET

Номер: US20140093726A1
Принадлежит: NITTO DENKO CORPORATION

Provided is a pressure-sensitive adhesive composition capable of realizing a pressure-sensitive adhesive layer having satisfactory adhesion performance and a low dielectric constant. This pressure-sensitive adhesive composition is characterized by containing a methacrylic polymer with a glass transition temperature (Tg) of 0° C. or less obtained by polymerization of monomer components including 40-99.5 weight % of alkyl methacrylate having a C10-C18 alkyl group in a side chain. A pressure-sensitive adhesive layer and an adhesive sheet are also prepared from the said pressure-sensitive adhesive composition. 1. A pressure-sensitive adhesive composition , which contains a methacryl-based polymer obtained by polymerizing monomer components containing 40 to 99.5% by weight of an alkyl methacrylate having a C10-C18 alkyl group at its side chain , and having a glass transition temperature (Tg) of 0° C. or lower.2. The pressure-sensitive adhesive composition according to claim 1 , wherein the methacryl-based polymer has a weight-average molecular weight of 400 claim 1 ,000 to 2 claim 1 ,500 claim 1 ,000.3. The pressure-sensitive adhesive composition according to claim 1 , wherein the monomer components further contain 0.5% or more by weight of at least any one functional-group-containing monomer selected from carboxyl-group-containing monomers claim 1 , hydroxyl-group-containing monomers claim 1 , and cyclic-ether-group-containing monomers.4. The pressure-sensitive adhesive composition according to claim 1 , wherein the monomer components further contain a (meth)acryl-based monomer having a C1-C10 alkyl group at its side chain.5. The pressure-sensitive adhesive composition according to claim 1 , wherein the monomer components further contain a (meth)acryl-based monomer having a C3-C10 branched alkyl chain at its side chain.6. A pressure-sensitive adhesive layer claim 1 , which is obtained from the pressure-sensitive adhesive composition recited in .7. The pressure-sensitive ...

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03-04-2014 дата публикации

Scanned, pulsed electron-beam polymerization

Номер: US20140093727A1
Принадлежит: 3M Innovative Properties Co

A method including: a. coating at least a portion of at least one major surface of a substrate with a polymerizable composition to obtain a coated surface; b. initiating polymerization of the polymerizable composition by scanning a first electron-beam focused on the coated surface across at least a portion of the coated surface, thereby irradiating the coated surface at a frequency selected to achieve an exposure duration of greater than 0 and no greater than 10 microseconds, and a dark time between each exposure duration of at least one millisecond, thereby producing an at least partially polymerized composition. A pressure sensitive adhesive article and a cross-linked silicone release liner made according to the method are also disclosed.

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10-04-2014 дата публикации

Polymer composition, adhesive composition, temperature-responsive sheet produced using said polymer composition, and cold-release adhesive sheet produced using said adhesive composition

Номер: US20140100335A1
Принадлежит: Nitto Denko Corp

The purpose of the present invention is to provide a polymer composition which enables the steady and easy production of a temperature-responsive sheet. Provided is a polymer composition comprising a water-dispersible side-chain crystalline polymer and a water-dispersible amorphous polymer.

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06-01-2022 дата публикации

Bioadhesive for Soft Tissue Repair

Номер: US20220001074A1

The present invention provides compositions and methods for repair and reconstruction of defects and injuries to soft tissues. Some aspects of the invention provide tissue adhesives comprising a hybrid hydrogel by using a naturally derived polymer, gelatin and a synthetic polymer, polyethylene glycol, wherein the hydrogel is biocompatible, biodegradable, transparent, strongly adhesive to corneal tissue, and have a smooth surface and biomechanical properties similar to the cornea.

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07-01-2016 дата публикации

PRESSURE SENSITIVE ADHESIVE AND IMAGE DISPLAY DEVICE USING THE SAME

Номер: US20160002505A1
Принадлежит: NITTO DENKO CORPORATION

The pressure sensitive adhesive of the present invention includes an acryl-based base polymer and a hydrogenated terpene phenolic resin having a softening point of 70° C. to 150° C. The hydrogenated terpene phenolic resin preferably has a terpene molar ratio of 0.1 to 0.7. The content of acryl-based base polymer is preferably 45 to 95 parts by weight based on total 100 parts by weight of the pressure sensitive adhesive composition. In addition, total content of the acryl-based base polymer and the hydrogenated terpene phenolic resin is preferably 70 parts by weight or more. The pressure sensitive adhesive of the present invention is hardly clouded even under a high-temperature and high-humidity environment, and has level difference followability, thus can be used by disposing between a front transparent plate and a touch panel, between a front transparent plate and an image display panel or between a touch panel and an image display panel. 1. A pressure sensitive adhesive configured to be disposed between a front transparent plate and a touch panel , between a front transparent plate and an image display panel or between a touch panel and an image display panel , whereinthe pressure sensitive adhesive contains an acryl-based base polymer, and a hydrogenated terpene phenolic resin having a softening point of 70° C. to 150° C.,the hydrogenated terpene phenolic resin has a terpene molar ratio of 0.1 to 0.7, andbased on total 100 parts by weight of a pressure sensitive adhesive composition, a content of the acryl-based base polymer is 45 to 95 parts by weight, and a total content of the acryl-based base polymer and the hydrogenated terpene phenolic resin is 70 parts by weight or more.2. The pressure sensitive adhesive according to claim 1 , whereinthe acryl-based base polymer has a polar monomer unit content of 3 to 50% by weight based on a total amount of constituent monomer components.3. An image display device comprising: an image display panel; at least one of a ...

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07-01-2016 дата публикации

ADHESIVE SHEET, LAMINATE FOR TOUCH PANEL, AND CAPACITANCE-TYPE TOUCH PANEL

Номер: US20160002506A1
Принадлежит: FUJIFILM Corporation

In an adhesive sheet, temperature dependence of a relative dielectric constant that is determined by a test for evaluating temperature dependence is equal to or less than 30%, and a 180° peel strength determined by a test for evaluating adhesiveness is equal to or greater than 0.20 N/mm. The adhesive sheet can inhibit the occurrence of malfunctioning of a capacitance-type touch panel in an environment of a wide temperature range from a low temperature to a high temperature, and can be included in a laminate for a touch panel and a capacitance-type touch panel. 1. An adhesive sheet ,wherein temperature dependence of a relative dielectric constant that is determined by a test for evaluating temperature dependence is equal to or less than 30%,a 180° peel strength determined by a test for evaluating adhesiveness is equal to or greater than 0.20 N/mm,in the test for evaluating temperature dependence, the adhesive sheet is sandwiched between aluminum electrodes, a temperature of the adhesive sheet is increased by 20° C. from −40° C. to 80° C., a relative dielectric constant of the adhesive sheet at each temperature is calculated by measuring impedance at 1 MHz, a minimum value and a maximum value are selected from calculated relative dielectric constants, and a value (%) calculated by an equation of [(maximum value−minimum value)/minimum value×100] is determined to be the temperature dependence, andin the test for evaluating adhesiveness, the adhesive sheet is bonded to a glass substrate, and the 180° peel strength of the adhesive sheet is determined based on JIS 0237.2. The adhesive sheet according to claim 1 ,wherein the maximum value of the relative dielectric constants calculated at temperatures increased by 20° C. from −40° C. to 80° C. is equal to or less than 3.8.3. The adhesive sheet according to claim 1 , comprising:an adhesive in which a ratio of a value of inorganicity to a value of organicity is 0.05 to 0.3,wherein the ratio represents the value of ...

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07-01-2016 дата публикации

Curable Acrylate or Methacrylate Compositions

Номер: US20160002507A1
Принадлежит:

A curable composition based on a curable acrylate or methacrylate component; an organoborane initiator component; a vinyl ether component; and an activator for the organoborane component. The composition exhibits good storage stability and good bonding properties when used to bond low surface energy substrates. 1. A curable composition comprising:a curable acrylate or methacrylate component;an organoborane initiator component;a vinyl ether component; andan activator for the organoborane component.2. A curable composition according to wherein the vinyl ether component comprises a vinyl ether molecule which has at least two vinyl ether groups.3. A composition according to wherein the vinyl ether component comprises at least one of 1 claim 1 ,4-butanediol divinyl ether claim 1 , diethyleneglycol divinyl ether claim 1 , and triethyleneglycol divinyl ether.4. A curable composition according to in the form of a two-part composition comprising:a curable acrylate or methacrylate component in at least one of the first part or the second part;a first part comprising an organoborane initiator component and a vinyl ether component; anda second part comprising an activator for the organoborane component.5. A composition according to wherein the organoborane initiator component comprises a trialkyl borane.6. A composition according to wherein the organoborane initiator component comprises a borane:amine complex.7. A composition according to wherein the organoborane initiator component comprises a trialkylborane:amine complex.8. A composition according to wherein the organoborane initiator component is present in an amount from about 0.1 to about 10% weight percentage based on the total weight of the composition.9. A composition according to wherein the activator for the organoborane compound is selected from the group consisting of Lewis acids claim 1 , carboxylic acids claim 1 , phosphoric acids claim 1 , anhydrides and isocyanates and combinations thereof.10. A composition ...

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04-01-2018 дата публикации

BATTERY AND METHOD OF CONSTRUCTING A BATTERY

Номер: US20180002581A1
Принадлежит:

A battery and a method of constructing a battery are disclosed in which a first conductive substrate portion has a first face and a second conductive substrate portion has a second face opposed to the first face. A first electrode material is disposed in electrical contact with the first face, an electrolyte material is disposed in contact with the first electrode material, a second electrode material is disposed in contact with the electrolyte material, and a conductive tab disposed in contact with the second electrode material. The first conductive substrate portion, the first electrode material, and the conductive tab extend outward beyond a particular edge of the second conductive substrate portion. 1. A battery , comprising:a first conductive substrate portion having a first face and a second conductive substrate portion having a second face opposed to the first face;a first electrode material disposed in electrical contact with the first face;an electrolyte material disposed in contact with the first electrode material;a second electrode material disposed in contact with the electrolyte material; anda conductive tab disposed in contact with the second electrode material;wherein the first conductive substrate portion, the first electrode material, and the conductive tab extend outward beyond a particular edge of the second conductive substrate portion.2. The battery of claim 1 , wherein the first and second conductive substrate portions are integral with one another and a fold portion is disposed therebetween.3. The battery of claim 2 , wherein the electrolyte material is disposed between layers of the first electrode material.4. The battery of claim 1 , wherein the first and second conductive substrate portions are discrete elements.5. The battery of claim 1 , further including an adhesive disposed between the first and second faces for securing the first face to the second face and wherein the first electrode material is disposed in electrical contact with ...

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07-01-2021 дата публикации

CYANOACRYLATE COMPOSITIONS

Номер: US20210002455A1
Принадлежит:

This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, a polybutylmethacrylate-polymethylmethacrylate copolymer. The inventive cyanoacrylate compositions load up to nearly a threefold increase of polybutylmethacrylate-polymethylmethacrylate copolymer over conventional polymethylmethacrylate and cured products of the inventive cyanoacrylate compositions demonstrate improved flexibility in terms of modulus (at comparable loading levels as well as increased loading levels compared to conventional polymethylmethacrylate) without compromising stability, fixture time or tensile shear strength. 1. A cyanoacrylate composition , comprising:(a) a cyanoacrylate component, and(b) a polybutylmethacrylate-polymethylmethacrylate copolymer having a molecular weight below 80,000 Mn.2. The composition according to claim 1 , wherein the polybutylmethacrylate-polymethylmethacrylate copolymer has a molecular weight in the range of about 10 claim 1 ,000 Mn up to about 80 claim 1 ,000 Mn.3. The composition according to claim 1 , wherein the polybutylmethacrylate-polymethylmethacrylate copolymer has a molecular weight of about 60 claim 1 ,000 Mn.4. The composition according to claim 1 , wherein the polybutylmethacrylate-polymethylmethacrylate copolymer is present in an amount up to about 50 percent by weight of the total composition.5. The composition according to claim 1 , wherein the polybutylmethacrylate-polymethylmethacrylate copolymer is present in an amount in the range of about 2 percent by weight to about 45 percent by weight of the total composition.6. The composition according to claim 1 , wherein the polybutylmethacrylate-polymethylmethacrylate copolymer is present in an amount of about 20 percent by weight of the total composition.7. Cured products of the composition according to claim 1 , wherein the cured products demonstrate improved flexibility measured using a three point bending test without compromising ...

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02-01-2020 дата публикации

ELECTRICALLY DEBONDABLE ADHESIVE COMPOSITION, ADHESIVE SHEET, AND ADHERED BODY

Номер: US20200002581A1
Принадлежит:

An object of the present invention is to provide an electrically debondable composition for forming an electrically debondable adhesive layer suitable for suppressing corrosion of a metal adherend surface. The present invention further provides an adhesive sheet having the electrically debondable adhesive layer, and an adhered body including the adhesive sheet. An electrically debondable composition of the present invention includes a polymer, an ionic liquid, and at least one additive selected from the group consisting of a carbodiimide compound, an adsorptive inhibitor and a chelate-forming metal deactivator. 1. An electrically debondable adhesive composition comprisinga polymer,an ionic liquid, andat least one additive selected from the group consisting of a carbodiimide compound, an adsorptive inhibitor and a chelate-forming metal deactivator.2. The electrically debondable adhesive composition according to claim 1 , wherein the carbodiimide compound is contained in an amount of 0.01 parts by mass or more and 10 parts by mass or less claim 1 , per 100 parts by mass of the polymer.3. The electrically debondable adhesive composition according to claim 1 , wherein the adsorptive inhibitor contains an alkylamine claim 1 , and the content of the alkylamine is 0.01 parts by mass or more and 20 parts by mass or less claim 1 , per 100 parts by mass of the polymer.4. The electrically debondable adhesive composition according to claim 1 , wherein the adsorptive inhibitor contains a carboxylic acid salt or a carboxylic acid derivative claim 1 , and the total content of the carboxylic acid salt and the carboxylic acid derivative is 0.01 parts by mass or more and 10 parts by mass or less claim 1 , per 100 parts by mass of the polymer.5. The electrically debondable adhesive composition according to claim 1 , wherein the adsorptive inhibitor contains an alkyl phosphoric acid salt claim 1 , and the content of the alkyl phosphoric acid salt is 0.01 parts by mass or more and 10 ...

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07-01-2021 дата публикации

Substrate-Free Adhesive Tape

Номер: US20210002524A1
Принадлежит: LG Chem Ltd

A substrate-free adhesive tape that is excellent in adhesive physical properties and is suitable for a continuous process is provided. The substrate-free adhesive tape includes a release film, and an adhesive layer provided on one surface of the release film and the adhesive layer containing a cured product of an adhesive composition, wherein when the release film is fixed on the outer surface of a semicircular tip part of a jig, the semicircular tip part having a radius of 22.5 mm, a breaking distance of the adhesive layer is 110 mm or less when the adhesive layer is stretched at a rate of 20 m/min from a semicircular center of the semicircular tip part toward an outermost direction of the semicircular tip part.

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03-01-2019 дата публикации

PERMANENT ADHESIVE COMPOSITION FOR IMAGE SENSORS, AND BONDING METHOD AND LAMINATE USING SAME

Номер: US20190002744A1
Принадлежит:

A permanent adhesive composition for image sensors which provides an adhesive layer having excellent heat resistance and thermal shock resistance, and a bonding method and laminate using the permanent adhesive composition. The permanent adhesive composition for image sensors contains a thermosetting or photocurable resin containing a specific bifunctional (meth)acrylic acid ester-derived structural unit, a polymerizable monomer, and an antioxidant, and used to bond together a substrate and a support for the substrate. The bonding method includes bonding together a substrate and a support for the substrate using the permanent adhesive composition. The laminate is provided with a substrate, a support for the substrate, and an adhesive layer for bonding the substrate and the support together, and the adhesive layer is formed of the permanent adhesive composition. 2. The permanent adhesive composition according to claim 1 ,wherein the antioxidant (C) includes a phenol-based antioxidant.4. The permanent adhesive composition according to claim 1 , wherein the substrate includes a silicon substrate or a sapphire substrate.5. The permanent adhesive composition according to claim 1 , wherein the support body includes a glass substrate.6. A bonding method comprising bonding a substrate and a support body for the substrate to each other claim 1 , using the permanent adhesive composition according to .7. A laminate comprising a substrate claim 1 , a support body for the substrate claim 1 , and an adhesion layer that bonds the substrate and the support body claim 1 , wherein the adhesion layer is formed from the permanent adhesive composition according to . The present invention relates to a permanent adhesive composition for image sensors, and a bonding method and a laminate using the permanent adhesive composition.Patent Document 1 describes an adhesive composition including a hydrocarbon resin and a predetermined solvent, as an adhesive composition having excellent product ...

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01-01-2015 дата публикации

Pressure-sensitive adhesive, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet

Номер: US20150004407A1
Принадлежит: Nitto Denko Corp

The pressure-sensitive adhesive of the invention contains a (meth)acryl-based polymer obtained by polymerization of a monomer component containing 40 to 99.5% by weight of an alkyl (meth)acrylate having a branched alkyl group of 6 to 9 carbon atoms at an ester end and more than 0 to 40% by weight of a cyclic nitrogen-containing monomer having a six or more-membered cyclic nitrogen-containing structure. The pressure-sensitive adhesive of the invention can form a pressure-sensitive adhesive layer having a satisfactory level of adhesion performance and optical properties, a low dielectric constant, and moisture resistance reliability.

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13-01-2022 дата публикации

PACKAGED VISCOELASTIC POLYMER SUBSTANCE

Номер: US20220010079A1
Принадлежит: TESA SE

Packaged viscoelastic polymer substances and methods for the production of the packaged viscoelastic polymer substances are provided. The packaged viscoelastic polymer substances are further processable under the influence of heat and shear. 1. A method for producing a packaged viscoelastic polymer substance , the method comprising:a) plastifying a viscoelastic polymer substance at elevated temperatures, the viscoelastic polymer substance being a polymer substance based on poly(meth)acrylates having a weight-average molecular weight of 500,000 g/mol or more;b) continuously dispensing the plastified viscoelastic polymer substance into a protective polymer film, that has no self-adhesive properties and which, before being filled with the plastified viscoelastic polymer substance, has been brought into a tubular form, to give a strandlike polymer assembly having a diameter of 55 to 70 mm, a core of the plastified viscoelastic polymer substance, and a shell of the protective polymer film, wherein a fraction of the protective polymer film, based on a total weight of the protective polymer film and the plastified viscoelastic polymer substance, is less than 1.0 wt %, and wherein the plastified viscoelastic polymer substance has a viscosity of more than 100 Pas at the instant of being dispensed into the tubular protective polymer film;c) converting the strandlike polymer assembly into a flattened strandlike polymer assembly with a smallest cross-section having a ratio of width to height of about 2:1 to 7:1;d) cooling the flattened strandlike polymer assembly to a temperature at which the strandlike polymer assembly is still plastically deformable; ande) subsequently winding the flattened strandlike polymer assembly onto a reel, wherein the strandlike polymer assembly wound onto the reel has a length of more than 30 meters.2. The method of claim 1 , wherein the converting of the strandlike polymer assembly into the flattened strandlike polymer assembly in c) is carried out ...

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13-01-2022 дата публикации

Electrically conductive adhesive

Номер: US20220010180A1
Принадлежит: Heraeus Deutschland GmbH and Co KG

One aspect refers to an electrically conductive adhesive including a) a (meth)acrylate monomer, b) a polymer being soluble in the (meth)acrylate monomer, c) a biocompatible metal having a median particle size d50 of below 50 μm, and d) a polymerization initiator. One aspect also refers to a kit for preparing an electrically conductive adhesive, to an implantable medical device including such an electrically conductive adhesive, or a cured form thereof, and to the use of such an electrically conductive adhesive.

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05-01-2017 дата публикации

PROTECTIVE FILM-FORMING FILM, SHEET FOR FORMING PROTECTIVE FILM, COMPLEX SHEET FOR FORMING PROTECTIVE FILM, AND METHOD OF PRODUCING MANUFACTURED PRODUCT

Номер: US20170004991A1
Принадлежит:

Provided is protective film-forming sheet () including: a protective film-forming film () having a light transmittance at a wavelength of 1064 nm of 55% or greater and a light transmittance at a wavelength of 550 nm of 20% or less; and a release sheet () which is laminated on one or both faces of the protective film-forming film (). According to this protective film-forming sheet (), it is possible to form a protective film which allows a workpiece such as a semiconductor wafer to have a modified layer disposed in advance therein by a laser so that the workpiece can be split through the application of force thereon, while preventing grinding marks on the workpiece or a product formed therefrom from being visible to the naked eye. 1. A protective film-forming film in which the light transmittance at a wavelength of 1064 nm is 55% or greater , and the light transmittance at a wavelength of 550 nm is 20% or less.2. The protective film-forming film according to claim 1 , which comprises an organic colorant.3. The protective film-forming film according to claim 2 , wherein the organic colorant comprises a pigment.4. The protective film-forming film according to claim 1 , which is a single layer formed of an uncured curable adhesive5. The protective film-forming film according to claim 4 , wherein the curable adhesive comprises a filler having an average particle diameter of 0.01 to 3 μm.6. The protective film-forming film according to claim 1 , which has a thickness of 3 to 15 μm.7. A sheet for forming a protective film claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the protective film-forming film of ; and'}a release sheet which is laminated on one or both surfaces of the protective film-forming film.8. A composite sheet for forming a protective film claim 1 , comprising:an adhesive sheet which is formed by laminating a pressure sensitive adhesive layer on one surface side of a base material; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, ...

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05-01-2017 дата публикации

PROTECTIVE FILM-FORMING FILM, SHEET FOR FORMING PROTECTIVE FILM, COMPLEX SHEET FOR FORMING PROTECTIVE FILM, AND INSPECTION METHOD

Номер: US20170005016A1
Принадлежит:

Provided is a sheet () for forming protective film, including: a protective film-forming film () characterized in that the light transmittance thereof at a wavelength of 1600 nm of 72% or more, and the light transmittance thereof at a wavelength of 550 nm of 20% or less; and a release sheet () laminated upon one or both faces of the protective film-forming film (). According to this sheet () for forming a protective film, it is possible to form a protective film that allows for the inspection of cracks, etc., on a workpiece or a product obtained by processing the workpiece, while preventing grinding marks on the workpiece or the product from being visible to the naked eye. 1. A protective film-forming film in which the light transmittance at a wavelength of 1600 nm is 72% or greater , and the light transmittance at a wavelength of 550 nm is 20% or less.2. The protective film-forming film according to claim 1 , which is a single layer formed of an uncured curable adhesive.3. The protective film-forming film according to claim 2 , wherein the curable adhesive comprises a colorant and a filler having an average particle diameter of 0.01 to 3 μm.4. The protective film-forming film according to claim 1 , which has a thickness of 3 to 15 μm.5. A sheet for forming a protective film claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the protective film-forming film ; and'}a release sheet which is laminated on one or both surfaces of the protective film-forming film.6. A composite sheet for forming a protective film claim 1 , comprising:an adhesive sheet which is formed by laminating a pressure sensitive adhesive layer on one surface side of a base material; anda protective film-forming film which is laminated on the a pressure sensitive adhesive layer side of the adhesive sheet, whereinthe light transmittance at a wavelength of 1600 nm of the protective film-forming film is 72% or greater, andthe light transmittance at a wavelength of 550 nm of the ...

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05-01-2017 дата публикации

DIE-BONDING LAYER FORMATION FILM, PROCESSED PRODUCT HAVING DIE-BONDING LAYER FORMATION FILM ATTACHED THERETO, AND SEMICONDUCTOR DEVICE

Номер: US20170005062A1
Принадлежит:

A die-bonding layer formation film to be used for fixing a processed product to an adherend, includes an adhesive layer, wherein, the storage elastic modulus has a local minimum value at a temperature within a range of 80° C. to 150° C., wherein the adhesive layer has a shear strength to a peeling strength test substrate of 20 N/2 mm or more and 50 N/2 mm or less, wherein the shear strength is measured after the processed product is placed above the peeling strength test substrate via the die-bonding layer formation film and the die-bonding layer formation film on the peeling strength test substrate is heated at 175° C. for 1 hour and then further maintained under an environment of 250° C. for 30 seconds. Bubbles (voids) are unlikely to grow at the boundary between the adhesive layer and an adherend even when subjected to thermal history. 1. A die-bonding layer formation film to be used for fixing a processed product to an adherend , the processed product being obtained by processing a workpiece , the die-bonding layer formation film comprising an adhesive layer ,wherein, when a temperature dependency of a storage elastic modulus of the adhesive layer is measured, the storage elastic modulus has a local minimum value at a temperature within a range of 80° C. to 150° C.,{'sup': □', '□, 'wherein the adhesive layer has a shear strength to a peeling strength test substrate of 20 N/2 mm or more and 50 N/2 mm or less, wherein the shear strength is measured after the processed product is placed above the peeling strength test substrate via the die-bonding layer formation film and the die-bonding layer formation film on the peeling strength test substrate is heated at 175° C. for 1 hour and then further maintained under an environment of 250° C. for 30 seconds.'}2. The die-bonding layer formation film as recited in claim 1 , wherein the adhesive layer comprises a binder component that contains a polymer component claim 1 , a curable component claim 1 , and a curing ...

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07-01-2021 дата публикации

SEMICONDUCTOR PACKAGE

Номер: US20210005532A1
Принадлежит:

A semiconductor package includes a semiconductor chip having an active surface on which a connection pad is disposed and an inactive surface opposing the active surface; a heat dissipation member disposed on the inactive surface of the semiconductor chip and including a graphite material; an adhesive member disposed between the semiconductor chip and the heat dissipation member; an encapsulant covering at least a portion of each of the semiconductor chip and the heat dissipation member; and an interconnect structure disposed on the active surface of the semiconductor chip and including a redistribution layer electrically connected to the connection pad. The encapsulant covers at least a portion of aside surface of the adhesive member. 1. A semiconductor package , comprising:a semiconductor chip having an active surface on which a connection pad is disposed and an inactive surface opposing the active surface;a heat dissipation member disposed on the inactive surface of the semiconductor chip and including a graphite material;an adhesive member disposed between the semiconductor chip and the heat dissipation member;an encapsulant covering at least a portion of each of the semiconductor chip and the heat dissipation member; andan interconnect structure disposed on the active surface of the semiconductor chip and including a redistribution layer electrically connected to the connection pad,wherein the encapsulant covers at least a portion of a side surface of the adhesive member.2. The semiconductor package of claim 1 , wherein the heat dissipation member includes a pyrolytic graphite sheet.3. The semiconductor package of claim 1 , wherein the adhesive member includes an epoxy resin and an (meth)acrylate-based resin.4. The semiconductor package of claim 3 , wherein the adhesive member includes one or more selected from the group consisting of cross-linking between the epoxy resin and the (meth)acrylate-based resin claim 3 , cross-linking between the epoxy resins claim 3 ...

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12-01-2017 дата публикации

ANTIMICROBIAL PRESSURE-SENSITIVE ADHESIVE SYSTEM

Номер: US20170007464A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

An antimicrobial pressure-sensitive adhesive (PSA). The PSA system can include an antimicrobial polymer having a plurality of pendant groups. The plurality of pendant groups can include (i) a first pendant group comprising a nonpolar compound, (ii) a second pendant group comprising a quaternary ammonium compound, and (iii) a third pendant group different from the first pendant group or the second pendent group, wherein the third pendant group provides inter-reactivity, such that the antimicrobial polymer can include one or more intermolecular interactions. The antimicrobial polymer can be free of non-ionic hydrophilic moieties. The PSA system can have a glass transition temperature Tranging from 0 to 50 degrees C. 1. A pressure-sensitive adhesive (PSA) system comprising: a first pendant group comprising a nonpolar compound,', 'a second pendant group comprising a quaternary ammonium compound, and', 'a third pendant group different from the first pendant group or the second pendent group, wherein the third pendant group provides inter-reactivity, such that the antimicrobial polymer can include one or more intermolecular interactions, and wherein the antimicrobial polymer is free of non-ionic hydrophilic moieties; and, 'an antimicrobial polymer having a plurality of pendant groups comprising'}{'sub': 'g', 'wherein the PSA system has a glass transition temperature Tranging from 0 to 50 degrees C.'}2. The PSA system of claim 1 , wherein the PSA system has a glass transition temperature ranging from 10 to 40 degrees C.3. The PSA system of claim 1 , further comprising at least one of a tackifier and a plasticizer.4. The PSA system of claim 1 , further comprising an antimicrobial agent dispersed within the PSA system.5. The PSA system of claim 4 , wherein the antimicrobial agent includes at least one of chlorhexidine gluconate claim 4 , chlorhexidine digluconate claim 4 , polyhexymethyl biguanide claim 4 , a quaternary ammonium compound claim 4 , silver claim 4 , and a ...

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12-01-2017 дата публикации

CURABLE COMPOSITION

Номер: US20170009113A1
Автор: ITANO Yu, Smits Wendy
Принадлежит: KANEKA CORPORATION

A curable composition includes an organic polymer containing a reactive silicon group (A), and a bound substance of kaolinite and quartz (B) at a proportion of 30-200 parts by weight relative to 100 parts by weight of the organic polymer containing a reactive silicon group (A). 1. A curable composition comprisingan organic polymer containing a reactive silicon group (A), anda bound substance of kaolinite and quartz (B) at a proportion of 30-200 parts by weight relative to 100 parts by weight of the organic polymer containing a reactive silicon group (A).2. The curable composition according to claim 1 , wherein the organic polymer containing a reactive silicon group (A) comprises a reactive silicon group-containing polyoxyalkylene-based polymer (A1) and/or a reactive silicon group-containing (meth)acrylate-based polymer (A2).3. The curable composition according to claim 1 , wherein the organic polymer containing a reactive silicon group (A) comprises a polyoxyalkylene-based polymer (a1) and/or a (meth)acrylate-based polymer (a2) as a main chain.4. (canceled)5. The curable composition according to claim 1 , wherein the bound substance of kaolinite and quartz (B) has a kaolinite content of not more than 15 wt %.6. The curable composition according to claim 1 , wherein the bound substance of kaolinite and quartz (B) has a Dparticle size of 1-3 μm.7. The curable composition according to claim 1 , wherein the bound substance of kaolinite and quartz (B) is calcined.8. The curable composition according to claim 1 , wherein the bound substance of kaolinite and quartz (B) is surface-treated.9. The curable composition according to claim 1 , further comprising an epoxy group-containing silane coupling agent (C) and an amidine compound (D).10. The curable composition according to of claim claim 1 , further comprising an organotin-based compound.11. An adhesive comprising the curable composition according to .12. A cured product obtained by curing the curable composition ...

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08-01-2015 дата публикации

PRESSURE SENSITIVE ADHESIVE COMPOSITION FOR PROTECTIVE FILM HAVING ANTI-STATIC PROPERTY AND MANUFACTURING PROCESS THEREOF

Номер: US20150010753A1
Принадлежит: LG CHEM, LTD. .

Provided is an adhesive composition for a protective film including an acrylic emulsion resin capable of providing contamination resistance on the film and low peel strength and minimizing generation of static electricity during peeling of the protective film. The acrylic emulsion resin includes a mixture including 80 to 99.9% by weight of a polymer of a (meth)acrylic acid ester monomer including a C-Calkyl group and a (meth)acrylic acid ester monomer including an alkylene oxide unit, and 0.1 to 20% by weight of a monomer including a carboxyl group and/or a hydroxyl group or a combination thereof, and 5 to 30 parts by weight of a reactive emulsifier having a double bond structure radical-polymerizable with the polymer and including an alkylene oxide unit based on 100 parts by weight of the mixture. 1. An adhesive composition for a protective film comprising acrylic emulsion resin particles and 0.5 to 5 parts by weight of an external cross-linking agent based on 100 parts by weight of the acrylic emulsion resin particles ,wherein the acrylic emulsion resin particles comprise:{'sub': 1', '14, 'a mixture comprising 80 to 99.9% by weight of a polymer of a (meth)acrylic acid ester monomer comprising a C-Calkyl group and a (meth)acrylic acid ester monomer comprising an alkylene oxide unit, and 0.1 to 20% by weight of a monomer comprising a carboxyl group and/or a hydroxyl group or a combination thereof; and'}5 to 30 parts by weight of a reactive emulsifier having a double bond structure radical-polymerizable with the polymer and comprising an alkylene oxide unit based on 100 parts by weight of the mixture.2. The adhesive composition according to claim 1 , wherein the (meth)acrylic acid ester monomer comprising a C-Calkyl group comprises at least one compound selected from the group consisting of methyl (meth)acrylate claim 1 , ethyl (meth)acrylate claim 1 , propyl (meth)acrylate claim 1 , isopropyl (meth)acrylate claim 1 , butyl (meth)acrylate claim 1 , t-butyl (meth) ...

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08-01-2015 дата публикации

PRESSURE-SENSITIVE ADHESIVE, PRESSURE-SENSITIVE ADHESIVE LAYER, AND PRESSURE-SENSITIVE ADHESIVE SHEET

Номер: US20150010754A1
Принадлежит: NITTO DENKO CORPORATION

A pressure-sensitive adhesive of the present invention comprises a (meth)acryl-based polymer obtained by polymerization of a monomer component containing 40 to 99.5% by weight of an alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end and more than 0 to 50% by weight or less of an alicyclic structure-containing monomer. The pressure-sensitive adhesive is capable of forming a pressure-sensitive adhesive layer that has a sufficiently low level of dielectric constant and a satisfactory level of adhesion performance. 1. A pressure-sensitive adhesive , comprising a (meth)acryl-based polymer obtained by polymerization of a monomer component containing 40 to 99.5% by weight of an alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end and more than 0 to 50% by weight or less of an alicyclic structure-containing monomer.2. The pressure-sensitive adhesive according to claim 1 , wherein the alicyclic structure-containing monomer has an alicyclic structure of 5 or more carbon atoms.3. The pressure-sensitive adhesive according to claim 1 , wherein the monomer component further contain at least one functional group-containing monomer selected from a carboxyl group-containing monomer claim 1 , a hydroxyl group-containing monomer claim 1 , and a cyclic ether group-containing monomer.4. The pressure-sensitive adhesive according to claim 1 , further comprising 0.01 to 5 parts by weight of a crosslinking agent based on 100 parts by weight of the (meth)acryl-based polymer.5. The pressure-sensitive adhesive according to claim 1 , wherein the alkyl group of the alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end is a branched alkyl group.6. The pressure-sensitive adhesive according to claim 1 , wherein the alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end is an alkyl methacrylate having an alkyl group of 10 to 18 carbon atoms at an ester end.7. The pressure- ...

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08-01-2015 дата публикации

ADHESIVE FILM AND METHOD OF MANUFACTURING THE SAME AND DISPLAY DEVICE INCLUDING THE ADHESIVE FILM

Номер: US20150010766A1
Принадлежит: Samsung Display Co., Ltd.

Disclosed is a method of manufacturing an adhesive film including: preparing a transparent adhesion layer, disposing a film mask including a light-transmitting region and a light-shielding region on the transparent adhesion layer, applying ultraviolet (UV) light to the transparent adhesion layer through the film mask to precure an area of the transparent adhesion layer corresponding to the light-transmitting region of the film mask, and cutting the precured area of the transparent adhesion layer. 1. A method of manufacturing an adhesive film comprising:preparing a transparent adhesion layer;disposing a film mask including a light-transmitting region and a light-shielding region on the transparent adhesion layer;applying ultraviolet (UV) light to the transparent adhesion layer through the film mask to precure an area of the transparent adhesion layer corresponding to the light-transmitting region of the film mask; andcutting the precured area of the transparent adhesion layer.2. The method of claim 1 , wherein the film mask comprises a light-blocking printed layer and a release layer formed on the transparent adhesion layer claim 1 , andwherein the light-blocking printed layer is formed on all areas of the transparent adhesion layer except for a place corresponding to the area where the transparent adhesion layer is to be cured.3. The method of claim 2 , wherein the place corresponding to the area where the transparent adhesion layer is to be cured is formed with a closed curved line.4. The method of claim 1 , wherein the preparing of the transparent adhesion layer comprises: laminating the optically clear adhesive in a semisolid state at room temperature.5. The method of claim 4 , wherein the optically clear adhesive comprises: an acrylic copolymer obtained from a composition including a solution-polymerizable acryl compound and a reaction initiator claim 4 , andan ultraviolet (UV) curable compound.6. The method of claim 5 , wherein the solution-polymerizable acryl ...

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11-01-2018 дата публикации

OPTICAL ADHESIVE SHEET

Номер: US20180010016A1
Принадлежит: LG CHEM, LTD.

The present invention relates to an optical adhesive sheet having an excellent repulsion resistance and an excellent swelling rate, and a method for manufacturing the same. 1. An optical adhesive sheet , comprising:a substrate; andan adhesive agent layer formed on at least one surface of the substrate,{'sup': '2', 'wherein the adhesive agent layer is formed by curing an adhesive agent composition, which comprises an acrylic copolymer formed by polymerizing a monomer mixture comprising ethylhexyl acrylate and isobornyl acrylate, at an ambient temperature of 20 to 30° C. by irradiation with UV light having a UV intensity of 6 to 8 mW/cm, and'} {'br': None, 'i': W', '/W, 'sub': 1', '2, 'Swelling rate (%)=()×100 \u2003\u2003[Equation 1]'}, 'a swelling rate of the adhesive agent layer, which is calculated by the following Equation 1, is 60% or morehere,{'sub': '1', 'W=an initial weight which is a weight of a sample before immersing the sample, which is obtained by cutting a cured adhesive agent layer into a predetermined size, into a solvent, and'}{'sub': '2=', 'Wa post weight which is a weight of a sample obtained by immersing the sample into a solvent, leaving the sample to stand for a predetermined time, filtering the sample using a filtration device, and then drying the sample.'}2. The adhesive sheet of claim 1 , wherein a total UV dose irradiated onto the adhesive agent composition at the ambient temperature is 1 claim 1 ,500 mJ/cmor more.3. The adhesive sheet of claim 1 , wherein the adhesive agent composition further comprises a photoinitiator selected from the group consisting of a benzoin-based initiator claim 1 , a hydroxy ketone-based initiator claim 1 , an amino ketone-based initiator claim 1 , caprolactam claim 1 , and a combination thereof.4. The adhesive sheet of claim 1 , wherein the substrate is thermoplastic foam or thermosetting foam.5. A method for manufacturing an optical adhesive sheet claim 1 , the method comprising:forming an adhesive agent ...

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08-01-2015 дата публикации

Methods for making biocompatible polymerizable acrylate products

Номер: US20150011747A1
Принадлежит: EMPIRE TECHNOLOGY DEVELOPMENT LLC

Sugar-acrylic monomers are synthesized to have a carbohydrate moiety linked to an acrylate group. The sugar-acrylic monomers may be polymerized to form polymers, adhesives, hydrogels, and the like. The sugar-acrylic monomers and polymers may be used in tissue engineering, adhesives and sealers, wound healing, and the like.

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14-01-2021 дата публикации

Acrylic resin powder, resin composition, hot melt adhesive composition containing acrylic resin powder and method for producing same

Номер: US20210009868A1
Автор: Shogo MIYAI, Toru Kondo
Принадлежит: Mitsubishi Chemical Corp

An acrylic resin powder soluble in acetone, including a multi-stage polymer (M) that includes a polymer (B) obtained by polymerizing a monomer mixture (b) containing methyl methacrylate and an alkyl (meth)acrylate ester (mb) in the presence of a polymer dispersion that contains a polymer (A) obtained by polymerizing a monomer mixture (a) containing an alkyl (meth)acrylate ester (ma), in which an alkyl group in the alkyl (meth)acrylate ester (ma) has 4 to 8 carbon atoms, an alkyl group in the alkyl (meth)acrylate ester (mb) has 4 to 8 carbon atoms, a glass transition temperature of the polymer (A) is 20° C. or lower, a glass transition temperature of the polymer (B) obtained by polymerizing the monomer mixture (b) is 55° C. or higher, and a mass average molecular weight of the multi-stage polymer (M) is 10,000 or more and 300,000 or less.

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10-01-2019 дата публикации

Pressure-sensitive adhesive tape, pressure-sensitive adhesive tape for affixing component for electronic appliance, and transparent pressure-sensitive adhesive tape for optical use

Номер: US20190010366A1
Принадлежит: Sekisui Chemical Co Ltd

The present invention aims to provide an adhesive tape excellent in resistance against sebum to be able to maintain its adhesive force even when applied to a part frequently touched with human hands, and an adhesive tape for fixing electronic device component and a transparent adhesive tape for optical use each provided with the adhesive tape. The present invention relates to an adhesive tape including an adhesive layer containing an acrylic adhesive, the adhesive layer having a swelling ratio of 100% or more and 130% or less after immersion in oleic acid under the conditions of a temperature of 60° C. and a humidity of 90% for 24 hours.

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11-01-2018 дата публикации

ADHESIVE FOR PELLICLE, PELLICLE, AND METHOD OF SELECTING ADHESIVE FOR PELLICLE

Номер: US20180011397A1
Автор: HORIKOSHI Jun, YANASE Yu
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

Provided are an adhesive comprising substantially no surface modifier and leaving a less residue behind after a pellicle is separated; a pellicle; and a method of selecting an adhesive leaving a less residue behind. More specifically, provided are an adhesive for a pellicle having a ratio of a peel strength to a tensile strength of from 0.10 to 0.33; a pellicle comprising a pellicle frame, a pellicle film provided over an upper end face of the pellicle frame, and the adhesive adhered to a lower end face of the pellicle frame; and a method of selecting an adhesive, comprising the steps of: measuring a peel strength and a tensile strength of an adhesive, and selecting an adhesive having a ratio of the former to the latter of from 0.10 to 0.33 as the adhesive for a pellicle. 1. An adhesive for a pellicle , the adhesive having a ratio of a peel strength to a tensile strength of from 0.10 to 0.33.2. The adhesive for a pellicle according to claim 1 , wherein the adhesive has a stroke of 660% or less claim 1 , wherein the stroke is an elongation percentage at the time of breaking in measurement of the tensile strength.3. The adhesive for a pellicle according to claim 1 , wherein the peel strength is 1.20 N/cmor more.4. The adhesive for a pellicle according to claim 1 , wherein the adhesive is an acrylic adhesive.5. The adhesive for a pellicle according to claim 1 , wherein the adhesive is a cured one from a composition comprising:an alkyl acrylate or methacrylate copolymer comprising 90 to 99% by weight of alkyl acrylate or methacrylate monomer units, and 1 to 10% of monomer units having reactivity with an epoxy group or an isocyanate group, anda curing agent which is an epoxy compound or an isocyanate compound, wherein the composition comprises substantially no surface modifier.6. A pellicle comprising:a pellicle frame;a pellicle film provided over an upper end face of the pellicle frame; and{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the adhesive according to , ...

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12-01-2017 дата публикации

PROTECTIVE FILM FORMING FILM, PROTECTIVE FILM FORMING SHEET AND WORK PRODUCT MANUFACTURING METHOD

Номер: US20170011949A1
Принадлежит:

A protective film forming film is provided in which the product of the breaking stress (MPa) measured at a measurement temperature of 0° C. and the breaking strain (unit: %) measured at a measurement temperature of 0° C. in at least one of the protective film forming film and a protective film formed from the protective film forming film is in a range of 1 MPa·% to 250 MPa·%. According to such a protective film forming film , the protective film forming film or the protective film formed from the protective film forming film can be suitably divided in an expanding process performed on a workpiece when the workpiece is divided to obtain a work product. 1. A protective film forming film ,wherein the product of the breaking stress (MPa) measured at a measurement temperature of 0° C. and the breaking strain (unit: %) measured at a measurement temperature of 0° C. in at least one of the protective film forming film and a protective film formed from the protective film forming film is in a range of 1 MPa·% to 250 MPa·%.2. The protective film forming film according to claim 1 , wherein the light transmittance at a wavelength of 1064 nm is 30% or greater.3. A protective film forming sheet claim 1 , comprising:a dicing sheet which includes a base material and an adhesive layer laminated on one surface side of the base material; and{'claim-ref': [{'@idref': 'CLM-00001', 'claim 1'}, {'@idref': 'CLM-00002', '2'}], 'the protective film forming film according to or which is laminated on the adhesive layer side of the dicing sheet.'}4. The protective film forming sheet according to claim 3 , wherein the light transmittance at a wavelength of 1064 nm is 30% or greater.5. A method of manufacturing a work product claim 3 , comprising:a first modified layer forming process of forming a modified layer in the inside of a workpiece by irradiating the workpiece with laser beams in the infrared region such that the laser beams are focused on a focal point set in the inside of the workpiece ...

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14-01-2016 дата публикации

Circuit board

Номер: US20160014894A1
Принадлежит: Fujifilm Corp

This wiring board is provided with: a plurality of metal wires disposed upon an insulating substrate; and a transparent adhesive agent layer which is disposed upon the metal wires, and which is in direct contact with the metal wires. The metal wires include: a first metal wire which has a pulse signal supplied thereto; and a second metal wire which has a fixed electric potential applied thereto. The pulse signal has a reference level identical to the fixed electric potential, and has a pulse train in which a plurality of pulses having a pulse width of not more than 3 msec are arranged, the integral time of the pulses in a period of 600 seconds being less than 60 seconds.

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03-02-2022 дата публикации

CONTACT ADHESIVES

Номер: US20220033692A1
Принадлежит:

The present invention relates to a polymer latex composition, a method to prepare polymer latex compositions and an article comprising said polymer latex compositions. In particular but not exclusively, the invention relates also to a one-part aqueous contact adhesive comprising said polymer latex compositions. Furthermore, the present invention refers to a method to coagulate said polymer latex compositions. 1. A polymer latex composition comprising: (a) at least one alkyl (meth)acrylate,', '(b) at least one ethylenically unsaturated compound comprising at least one additional functional group, the at least one additional functional group being different than the ethylenically unsaturated group; and', '(c) optionally at least one polyethylenically unsaturated compound;', 'wherein the monomer mixture does not comprise any ethylenically unsaturated acids; and', 'in the presence of', '(d) a surfactant system comprising anionic surfactants comprising an alkyl carboxylic acid salt,, '(I) the reaction product obtained by free-radical emulsion polymerization in aqueous medium conducted at a pH of 7.5 or higher of a monomer mixture comprising(II) a compound which is not polymerizable by free-radical polymerization and which comprises at least 2 functional groups capable of reacting with the at least one additional functional group of (b).2. The polymer latex composition of claim 1 , wherein the monomer mixture comprises:(a) 80 to 99.5 wt.-% of alkyl (meth)acrylates;(b) 0.5 to 10 wt.-% of ethylenically unsaturated compounds comprising at least one additional functional group, wherein the at least one additional functional group is different than the ethylenically unsaturated group; and(c) 0 to 10 wt.-% of polyethylenically unsaturated compounds;the weight percentages being based on the total amount of monomers.3. The polymer latex composition of claim 1 , wherein '0.3 to 5 wt.-% of anionic surfactants comprising a carboxylic acid salt, the weight percentages being based on ...

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15-01-2015 дата публикации

ADHESIVE COMPOSITION FOR POLARIZING PLATE, ADHESIVE FILM FOR POLARIZING PLATE COMPRISING THE SAME, POLARIZING PLATE COMPRISING THE SAME AND DISPLAY DEVICE COMPRISING THE SAME

Номер: US20150017448A1
Принадлежит:

An adhesive composition for a polarizing plate has good initial curing and an adhesive property. The adhesive composition includes (A) a polymerizable functional group-containing monomer capable of providing an anchor effect; (B) an epoxy group-containing compound; (D) a photoacid generator; and (E) at least one of a photopolymerization initiator and a photosensitizer. 1. An adhesive composition for a polarizing plate , comprising:(A) a polymerizable functional group-containing monomer capable of providing an anchor effect;(B) an epoxy group-containing compound;(D) a photoacid generator; and(E) at least one of a photopolymerization initiator and a photosensitizer.2. The adhesive composition of claim 1 , wherein (A) the polymerizable functional group-containing monomer capable of providing an anchor effect comprises (A1) a polymerizable functional group-containing macromonomer or (A2) an allyl-group-and-hydroxyl-group-containing (meth)acrylate monomer.3. The adhesive composition of claim 2 , wherein the adhesive composition comprises (A1) the polymerizable functional group-containing macromonomer in an amount of about 0.5 parts by weight to about 30 parts by weight claim 2 , (B) the epoxy group-containing compound in an amount of about 40 parts by weight to about 99.5 parts by weight claim 2 , (C) the (meth)acrylic-based monomer in an amount of about 0 parts by weight to about 59.5 parts by weight claim 2 , (D) the photoacid generator in an amount of about 1 part by weight to about 7 parts by weight claim 2 , and (E) the at least one of the photopolymerization initiator and the photosensitizer in an amount of about 0.1 parts by weight to about 7 parts by weight claim 2 , with respect to 100 parts by weight of (A)+(B)+(C).4. The adhesive composition of claim 2 , wherein the adhesive composition comprises (A2) the allyl-group-and-hydroxyl-group-containing (meth)acrylate monomer in an amount of about 20 parts by weight to about 70 parts by weight claim 2 , (B) the epoxy ...

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16-01-2020 дата публикации

BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, AND METHOD FOR MANUFACTURING A BIO-ELECTRODE

Номер: US20200015699A1
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

The present invention provides a bio-electrode composition including a silsesquioxane bonded to an N-carbonyl sulfonamide salt, wherein the N-carbonyl sulfonamide salt is shown by the following general formula (1): 3. The bio-electrode composition according to claim 1 , further comprising an adhesive resin as a component (B) in addition to the silsesquioxane bonded to an N-carbonyl sulfonamide salt as a component (A).4. The bio-electrode composition according to claim 2 , further comprising an adhesive resin as a component (B) in addition to the silsesquioxane bonded to an N-carbonyl sulfonamide salt as a component (A).5. The bio-electrode composition according to claim 3 , wherein the component (B) is one or more resins selected from a silicone resin claim 3 , a (meth)acrylate resin claim 3 , and a urethane resin.6. The bio-electrode composition according to claim 4 , wherein the component (B) is one or more resins selected from a silicone resin claim 4 , a (meth)acrylate resin claim 4 , and a urethane resin.7. The bio-electrode composition according to claim 3 , wherein the component (B) contains diorganosiloxane having an alkenyl group claim 3 , and organohydrogenpolysiloxane having an SiH group.8. The bio-electrode composition according to claim 5 , wherein the component (B) contains diorganosiloxane having an alkenyl group claim 5 , and organohydrogenpolysiloxane having an SiH group.9. The bio-electrode composition according to claim 7 , wherein the component (B) further contains a silicone resin having an RSiOunit (wherein claim 7 , R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms claim 7 , and “x” is a number in a range of 2.5 to 3.5) and an SiOunit.10. The bio-electrode composition according to claim 8 , wherein the component (B) further contains a silicone resin having an RSiOunit (wherein claim 8 , R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms claim 8 ...

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21-01-2016 дата публикации

PHOTOBASE GENERATORS AS LATENT IONIC CROSSLINKERS FOR ACRYLIC PRESSURE-SENSITIVE ADHESIVES

Номер: US20160017073A1
Принадлежит:

The present disclosure provides an ionically crosslinkable composition comprising a (meth)acrylate copolymer component having pendant acid functional groups and pendant photobase functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that ionically crosslinks the copolymer.

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21-01-2016 дата публикации

CYANOACRYLATE COMPOSITIONS

Номер: US20160017189A1
Принадлежит:

This invention relates to flexible cyanoacrylate-containing compositions, having improved torsion stress resistance particularly when bonded to plastic substrates.

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18-01-2018 дата публикации

PHOTOINITIATORS THAT ARE POLYMERIC OR POLYMERIZABLE FOR USE IN UV CURABLE PRESSURE SENSITIVE ADHESIVES

Номер: US20180016363A1
Принадлежит:

Disclosed are photoinitiators that are ultra violet (UV) reactive. The photoinitiators can be polymerized into polymeric backbones for use in UV curable hot melt pressure sensitive adhesives. The preferred polymeric backbones are acrylic-based polymers. The photoinitiators are very UVC sensitive and have excellent hot melt viscosity stability that is many fold higher than existing photoinitiators. The subject photoinitiators feature aryl ketones linked through an ether linkage to a variety of connector sequences that allow for polymerization of the photoinitiators. 5. (canceled)6. (canceled)8. (canceled)10. An ultra violet light curable polymer comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'an acrylic polymer that is a reaction product of a plurality of one or more acrylic monomers and one or more photoinitiators according to , wherein said acrylic polymer is crosslinkable through said photoinitiator groups upon exposure to ultra violet light.'}11. The ultra violet light curable polymer according to wherein the photoinitiator is present in an amount of from 0.1 to 10 mole percent based on the total number of moles of acrylate monomers used for polymerization to obtain the acrylic polymer.14. The ultra violet light curable polymer according to wherein the acrylic monomers are selected from the group consisting of: acrylic acid claim 10 , methacrylates claim 10 , methyl methacrylates claim 10 , ethyl acrylates claim 10 , 2-chloroethyl vinyl ethers claim 10 , 2 ethylhexyl acrylate claim 10 , acetoacetoxyethyl methacrylate (AAEM) claim 10 , hydroxyethyl methacrylate claim 10 , butyl acrylate claim 10 , butyl methacrylate claim 10 , trimethylolpropane triacrylate (TMPTA) claim 10 , and mixtures thereof.15. An ultra violet light curable polymer comprising:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, 'an acrylic polymer that is a reaction product of a plurality of one or more acrylic monomers and one or more photoinitiators according to , wherein said ...

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