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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Применить Всего найдено 11029. Отображено 100.
29-06-2021 дата публикации

Устройство усовершенствованной микроповерхностной реакции гидрирования с нисходящим потоком и фиксированным слоем для производства нефтепродуктов

Номер: RU0000205181U1

Полезная модель относится к устройству усовершенствованной микроповерхностной реакции гидрирования с нисходящим потоком и фиксированным слоем для производства нефтепродуктов. Устройство включает в себя реактор с фиксированным слоем и генератор микроповерхностей, при этом генератор микроповерхностей расположен над реактором с фиксированным слоем для преобразования энергии давления водорода и/или кинетической энергии нефтепродукта во время реакции в поверхностную энергию пузырька и передачи поверхностной энергии пузырьку водорода, так что пузырек водорода дробится на микропузырьки и микропузырьки смешиваются с нефтепродуктом в процессе реакции для образования газожидкостной эмульсии; реактор с фиксированным слоем используется в качестве места протекания реакции гидрирования для образования стабильной усовершенствованной газожидкостной системы для реакции с фиксированным слоем, когда газожидкостная эмульсия поступает в реактор с фиксированным слоем; резервуар для разделения газа и жидкости соединен с реактором с фиксированным слоем для отделения газа от жидкости в смеси, являющейся результатом реакции в реакторе с фиксированным слоем. Устройство микроповерхностной реакции гидрирования с фиксированным слоем имеет преимущества низкого потребления энергии, низкого рабочего давления, большой площади межфазной границы массопереноса газ-жидкость, высокой видимой скорости реакции и высокой эффективности использования газа. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 205 181 U1 (51) МПК B01J 8/02 (2006.01) C10G 45/08 (2006.01) C10G 45/22 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (52) СПК B01J 8/02 (2021.02); C10G 45/08 (2021.02); C10G 45/22 (2021.02) (21)(22) Заявка: 2020129865, 06.06.2019 (24) Дата начала отсчета срока действия патента: Дата регистрации: 29.06.2021 15.03.2019 CN 201910196596.X (45) Опубликовано: 29.06.2021 Бюл. № 19 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.09.2020 (73) ...

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12-01-2012 дата публикации

Method and System for Synthesizing Liquid Hydrocarbon Compounds

Номер: US20120010304A1
Автор: Kazuhiko Tasaka

Provided is a method for synthesizing liquid hydrocarbon compounds wherein synthesizing liquid hydrocarbon compounds from a synthesis gas by a Fisher-Tropsch synthesis reaction. The method includes a first absorption step of absorbing a carbon dioxide gas, which is contained in gaseous by-products generated in the Fisher-Tropsch synthesis reaction, with an absorbent, and a second absorption step of absorbing a carbon dioxide gas, which is contained in the synthesis gas, with the absorbent which is passed through the first absorption step.

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17-05-2012 дата публикации

Hydroconversion multi-metallic catalyst and method for making thereof

Номер: US20120122655A1
Принадлежит: Chevron USA Inc

In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals is recovered as a metal precursor feed, which can be recycled for use in the co-precipitation reaction. An effluent stream from the process to waste treatment contains less than 50 ppm metal ions.

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24-05-2012 дата публикации

Process for Cracking Heavy Hydrocarbon Feed

Номер: US20120125812A1
Принадлежит: EQUISTAR CHEMICALS LP

A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a hydroprocessing step, and a steam cracking step is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a counter-current steam produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream reacted with hydrogen in the presence of a catalyst to produce a hydroprocessed product. A liquid hydroprocessed product is fed to the vaporization unit.

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21-06-2012 дата публикации

Production of renewable fuels

Номер: US20120157742A1
Принадлежит: ConocoPhillips Co

The present disclosure relates to a process for the conversion of oxygen-containing hydrocarbons into long-chain hydrocarbons suitable for use as a fuel. These hydrocarbons may be derived from biomass, and may optionally be mixed with petroleum-derived hydrocarbons prior to conversion. The process utilizes a catalyst comprising Ni and Mo to convert a mixture comprising oxygenated hydrocarbons into product hydrocarbons containing from ten to thirty carbons. Hydro-conversion can be performed at a significantly lower temperature than is required for when utilizing a hydrotreating catalyst comprising Co and Mo (CoMo), while still effectively removing sulfur compounds (via hydrodesulfurization) to a level of 10 ppm (by weight) or less.

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19-07-2012 дата публикации

Method for upgrading heavy hydrocarbon oil

Номер: US20120181216A1
Принадлежит: Arisdyne Systems Inc

A process for upgrading hydrocarbon oil including mixing hydrocarbon oil with hydrogen gas and heating the hydrogen-enriched hydrocarbon oil before passing the oil through a cavitation apparatus to induce hydrotreating. Hydrotreating is achieved by hydrodynamically generating hydrogen-filled cavitation bubbles and collapsing the bubbles in the hydrocarbon oil under static pressure. The hydrotreating process can increase the API gravity of the hydrocarbon oil and reduce the viscosity of the hydrocarbon oil.

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26-07-2012 дата публикации

Molecular Sieve Of MFS Framework Type With Controllable Average Size, Its Method of Making And Use

Номер: US20120190896A1
Принадлежит: ExxonMobil Chemical Patents Inc

A method of making a crystalline molecular sieve of MFS framework type, preferably ZSM-57, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure-directing-agent (R) and water, said alkali metal (M) comprising potassium, and having the following mole composition (expressed in terms of oxide): YO 2 :( p )X 2 O 3 :( q )OH − :( r )R:( s )H 2 O, wherein (p) is in the range from 0.005 to 0.05, (q) is in the range from 0.01 to 3, (r) is in the range from 0.03 to 2 and (s) is in the range from 10 to 75 (based on total weight of said synthesis mixture); wherein the crystals of molecular sieve formed having an average diameter (D) of less than or equal to 1.5 micron and an average thickness (T) of less than or equal to 300 nanometers.

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16-08-2012 дата публикации

Hydroprocessing Catalyst Prepared with Waste Catalyst Fines and Its Use

Номер: US20120205290A1
Принадлежит: Shell Oil Co

A hydroprocessing catalyst composition that comprises a shaped support that is formed from a mixture of inorganic oxide powder and catalyst fines and wherein the shaped support has incorporated therein at least one metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition is prepared by incorporating into the shaped support a metal component, a chelating agent and a polar additive. The hydroprocessing catalyst composition has particular application in the catalytic hydroprocessing of petroleum derived feedstocks.

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23-08-2012 дата публикации

Process for hydrotreating naphtha fraction and process for producing hydrocarbon oil

Номер: US20120211401A1
Принадлежит: Individual

A process for hydrotreating a naphtha fraction that includes a step of estimating the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, based on the reaction temperature of the Fischer-Tropsch synthesis reaction and the ratio of the flow rate of the treated naphtha fraction returned to the naphtha fraction hydrotreating step relative to the flow rate of the treated naphtha fraction discharged from the naphtha fraction hydrotreating step, a step of measuring the difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature, and a step of adjusting the reaction temperature of the naphtha fraction hydrotreating step so that the measured difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature becomes substantially equal to the estimated difference between the naphtha fraction hydrotreating reactor outlet temperature and inlet temperature.

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04-10-2012 дата публикации

Apparatus for producing diesel

Номер: US20120251403A1
Принадлежит: UOP LLC

An apparatus is disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit shares the same recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.

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04-10-2012 дата публикации

Dispersed metal sulfide-based catalysts

Номер: US20120252660A1
Принадлежит: Intevep SA

The invention provides a catalyst composition, which includes an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase comprises an aqueous solution containing a group 6 metal and a group 8, 9 or 10 metal. The metals can be provided in two separate emulsions, and these emulsions are well suited for treating hydrocarbon feedstocks.

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22-11-2012 дата публикации

Oil and polar additive impregnated composition useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

Номер: US20120295786A1
Принадлежит: Shell Oil Co

A composition that comprises a support material having incorporated therein a metal component and impregnated with both hydrocarbon oil and a polar additive. The composition that is impregnated with both hydrocarbon oil and polar additive is useful in the hydrotreating of hydrocarbon feedstocks, and it is especially useful in applications involving delayed feed introduction whereby the composition is first treated with hot hydrogen, and, optionally, with a sulfur compound, prior to contacting it with a hydrocarbon feedstock under hydrodesulfurization process conditions.

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29-11-2012 дата публикации

Regenerated hydrotreatment catalyst

Номер: US20120298557A1

The present invention relates to a regenerated hydrotreatment catalyst regenerated from a hydrotreatment catalyst for treating a petroleum fraction, the hydrotreatment catalyst being prepared by supporting molybdenum and at least one species selected from metals of Groups 8 to 10 of the Periodic Table on an inorganic carrier containing an aluminum oxide, wherein a residual carbon content is in the range of 0.15 mass % to 3.0 mass %, a peak intensity of a molybdenum composite metal oxide with respect to an intensity of a base peak is in the range of 0.60 to 1.10 in an X-Ray diffraction spectrum, and a peak intensity of a Mo—S bond derived from a residual sulfur peak with respect to an intensity of a base peak is in the range of 0.10 to 0.60 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum of an X-ray absorption fine structure analysis.

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13-12-2012 дата публикации

Apparatus and method for hydroconversion

Номер: US20120315202A1
Принадлежит: Chevron Corp

An apparatus is disclosed for the hydroconversion of hydrocarbon feedstock with a hydrogen gas at elevated temperature and pressure with the use of a catalyst. The apparatus is a reactor vessel with a grid plate distributor for improved gas liquid distribution. The distributor comprises a grid plate and a bubble cap assembly with a plurality of tubular risers extending through the grid plate. Each tubular riser has an upper section above the grid plate and a lower section below the grid plate, the lower section terminated with an open bottom end for ingress of the hydrogen gas and hydrocarbon feedstock, the upper section having a closed top terminated with a housing cap. Each tubular riser has at least a vertical slot and a least a side hole sufficiently sized such that in operation, the liquid level in the zone below the grid plate is above the vertical slot and below the side hole opening.

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07-03-2013 дата публикации

Catalytical hydrodesulfurization of kerosene in two steps on cobalt-molybdenum catalyst and intermediate stripping

Номер: US20130056391A1
Принадлежит: Indian Oil Corp Ltd

A process for selective removal of mercaptan from aviation turbine fuel feed includes mixing aviation turbine fuel feed with hydrogen, at a pressure in a range from 3 bar to 20 bar to obtain a reaction mixture. The reaction mixture is heated at a temperature range of 150° C. to 350° C. to obtain a heated mixture. The heated mixture is reacted with a hydrotreating catalyst in a rector to obtain a reactor effluent, and H 2 S gas is stripped from the reactor effluent to obtain a stripper bottom product. Moisture is removed from the stripper bottom product to obtain aviation turbine fuel product having less than 10 ppm mercaptan. The aviation fuel product has improved properties such as color and acidity. Embodiments also relate to an aviation turbine fuel product having less than 10 ppm mercaptan prepared by the described process of the present invention.

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21-03-2013 дата публикации

HYDROCONVERSION MULTI-METALLIC CATALYST AND METHOD FOR MAKING THEREOF

Номер: US20130068662A1
Принадлежит:

A method for hydroprocessing a hydrocarbon feedstock is provided. The method comprises contacting the feedstock with a catalyst under hydroprocessing conditions, wherein the catalyst is formed by sulfiding an unsupported catalyst precursor of the general formula A[(M)(OH)(L)](MO), wherein Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof; L is one or more oxygen-containing ligands, and L has a neutral or negative charge n<=0, Mis at least a Group VIB metal having an oxidation state of +6; M: Mhas an atomic ratio between 100:1 and 1:100; v−2+P*z−x*z+n*y*z=0; and 0≦y≦−P/n; 0≦x≦P; 0≦v≦2; 0≦z. In one embodiment, the catalyst precursor further comprises a cellulose-containing material. In another embodiment, the catalyst precursor further comprises at least a diluent (binder). In one embodiment, the diluent is a magnesium aluminosilicate clay. 1. A process for hydroprocessing a hydrocarbon feedstock which comprises contacting the hydrocarbon feedstock with a catalyst under hydroprocessing conditions ,{'sub': v', 'x', 'y', 'Z', '4, 'sup': P', 'n', 'VIB, 'wherein the catalyst is formed by sulfiding an unsupported catalyst precursor composition having a formula A[(M) (OH)(L)](MO),'}whereinA is at least one of an alkali metal cation, an ammonium, an organic ammonium and a phosphonium cation,{'sup': P', 'P', 'P, 'Mis selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, P is oxidation state with Mhaving an oxidation state of either +2 or +4 depending on the selection of M,'}L is at least one organic oxygen-containing ligand,{'sup': 'VIB', 'Mis at least a Group VIB metal, having an oxidation state of +6,'}{'sup': P', 'VIB, 'M: Mhas an atomic ratio of 100:1 to 1:100,'}v−2+P*z−x*z+n*y*z=0; and0 Подробнее

28-03-2013 дата публикации

PROCESS FOR HYDROCONVERSION OF PETROLEUM FEEDSTOCKS VIA A SLURRY TECHNOLOGY ALLOWING THE RECOVERY OF METALS FROM THE CATALYST AND FROM THE FEEDSTOCK USING A COKING STEP

Номер: US20130075303A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for hydroconversion of heavy petroleum feedstocks comprising a hydroconversion step of the feedstock in at least one reactor containing a slurry catalyst and allowing the recovery of metals in the unconverted residual fraction, in particular those used as catalysts, The process comprises a hydroconversion step, a gas/liquid separation step, a coking step, a combustion step, a metals extraction step and a step of preparing catalytic solutions which are recycled to the hydroconversion step. 1. Process for hydroconversion of heavy petroleum feedstocks containing metals comprising:a) a step of hydroconversion of the feedstock in at least one reactor containing a slurry catalyst containing at least one metal, and optionally a solid additive,b) a step of separation of the hydroconversion effluent without decompression into a so-called light fraction containing the compounds boiling at a maximum temperature of 500° C. and a residual fraction,b′) optionally a fractionation step comprising a separation under vacuum of said residual fraction as obtained in step b), and a vacuum residue with a high concentration of metals is obtained,c) a step of coking of said residual fraction as obtained in step b) and/or of said vacuum residue as obtained in step b′) making it possible to obtain a solid effluent containing coke,d) a step of combustion of said solid effluent containing coke at a temperature comprised between 200 and 700° C. making it possible to obtain ashes with a high concentration of metals,e) a step of extraction of the metals from the ashes obtained in the combustion step,f) a step of preparation of metallic solution(s) containing at least the metal of the catalyst which is/are recycled(s) as catalyst in the hydroconversion step.2. Process according to in which said so-called light fraction originating from the separation step without decompression is subjected to at least one hydrotreatment and/or hydrocracking step.3. Process according to claim 1 , in which ...

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04-04-2013 дата публикации

HYDROPROCESSING OF HEAVY HYDROCARBON FEEDS USING SMALL PORE CATALYSTS

Номер: US20130081977A1

Heavy oil feeds are hydroprocessed in the presence of a solvent and in the presence of a catalyst with a median pore size of about 85 Å to about 120 Å under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst. 1. A process for producing a hydroprocessed product , comprising:{'sup': '−1', 'exposing a combined feedstock comprising a heavy oil feed component and a solvent component to a hydroprocessing catalyst comprising a Group VIII non-noble metal and a Group VI metal and having a median pore size of about 85 Å to about 120 Å, under effective hydroprocessing conditions to form a hydroprocessed effluent, the effective hydroprocessing conditions including a total pressure of about 1500 psig (10.3 MPag) or less, a temperature of at least about 360° C., and a liquid hourly space velocity of the fraction of the combined feedstock boiling above 1050° F. (566° C.) of at least about 0.10 hr;'}separating the hydroprocessing effluent to form at least a liquid effluent; andfractionating a first portion of the liquid effluent to form at least a distillate product and a bottoms product, the bottoms product having an ASTM D86 distillation point of at least about 600° F. (316° C.)2. The process of claim 1 , wherein the hydroprocessing catalyst is a bulk catalyst claim 1 , the hydroprocessing catalyst having a median pore size of about 85 Å to about 100 Å.3. The process of claim 1 , wherein the solvent component comprises a recycle component claim 1 , the process further comprising recycling a second portion of the liquid effluent to form the recycle component.4. The process of claim 3 , wherein the ratio of the recycle component to the heavy oil feed component on a weight basis is ...

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11-04-2013 дата публикации

PROCESS FOR THE HYDROCONVERSION OF PETROLEUM FEEDSTOCKS VIA SLURRY TECHNOLOGY ALLOWING THE RECOVERY OF METALS FROM THE CATALYST AND FEEDSTOCK USING A LEACHING STEP

Номер: US20130087481A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the hydroconversion of heavy oil feedstocks comprises a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in slurry mode used to recover metals from the residual unconverted fraction, especially those used as catalysts. The process comprises a hydroconversion step, a gas/liquid separation step, a liquid/liquid extraction step, a grinding step, a leaching step, a combustion step, a metals extraction step and a step for the preparation of catalytic solutions which are recycled to the hydroconversion step. 1. A process for the hydroconversion of heavy oil feedstocks containing metals , comprising:a. a step for hydroconversion of the feedstock in at least one reactor containing a catalyst in the form of a slurry containing at least one metal, and optionally a solid additive;b. a step for separation of the hydroconversion effluent without decompression into a fraction termed the light fraction containing compounds boiling at 500° C. at most and into a residual fraction;b′. an optional step for fractionation, comprising vacuum separation of said residual fraction as obtained in step b) to obtain a vacuum residue which is concentrated in metals;c. a step for liquid/liquid extraction of said residual fraction as obtained in step b) and/or said vacuum residue as obtained in step b′) using a solvent with a saturated nature in order to obtain a solid extract which is concentrated in metals and a raffinate;d. a step for grinding the solid extract which is concentrated in metals obtained from the liquid/liquid extraction step;e. a step for leaching the ground extract in the presence of water, a solvent with a saturated nature and a surfactant in order to obtain a solid extract and a leachate;f. a step for combustion of said solid extract obtained from the leaching step in the presence of oxygen in order to obtain ash which is concentrated in metals;g. a step for extraction of metals from the ash obtained in the combustion step; ...

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02-05-2013 дата публикации

Self-activating hydroprocessing catalyst and process for treating heavy hydrocarbon feedstocks

Номер: US20130105357A1
Автор: Opinder K. BHAN
Принадлежит: Shell Oil Co

A self activating catalyst for treating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound and then forming the co-mulled mixture into a particle that is calcined to thereby provide the calcined particle. The self activating catalyst may be activated when it is contacted under suitable process conditions with a heavy residue feedstock having high nickel, vanadium and sulfur concentrations.

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20-06-2013 дата публикации

Hydrodesulfurization catalyst for hydrocarbon oil, process of producing same and method for hydrorefining

Номер: US20130153467A1

A hydrodesulfurization catalyst is produced by pre-sulfurizing a hydrodesulfurization catalyst Y including a support containing silica, alumina and titania and at least one metal component supported thereon and selected from VIA and VIII groups of the periodic table (comprising at least Mo), in which the total area of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes in the support, measured by X-ray diffraction analysis being ¼ or less of the alumina diffraction peak area assigned to γ-alumina (400) planes. The molybdenum is formed into molybdenum disulfide crystal disposed in layers on the support by the pre-sulfurization, and having an average length of longer than 3.5 nm and 7 nm or shorter in the plane direction and an average number of laminated layers of more than 1.0 and 1.9 or fewer.

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04-07-2013 дата публикации

PROCESS FOR THE HYDRODESULPHURIZATION OF A GASOLINE CUT IN THE PRESENCE OF A SUPPORTED SULPHIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE

Номер: US20130168292A1
Принадлежит: IFP ENERGIES NOUVELLES

Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: 1. A process for the hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less , said process consisting of bringing said gasoline cut into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII and at least one metal from group VIB deposited on a support formed from at least one oxide , said catalyst being prepared using a process comprising at least:i) at least one step for bringing at least said support into contact with at least one solution containing at least one precursor of at least said metal from group VIII and at least one precursor of at least said metal from group VIB;ii) at least one step for bringing at least said support into contact with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits;iii) at least one drying step to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then 'the steps i) and ii) possibly being carried out separately, in any order, or simultaneously.', 'iv) at least one sulphurization step such that said active phase is in the sulphide form;'}2. A hydrodesulphurization process according to claim 1 , in which said gasoline cut originates from a fluid catalytic cracking unit.3. A hydrodesulphurization process according to claim 1 , in which said gasoline cut has a sulphur content in the range 200 to 5000 ppm by weight.4. A hydrodesulphurization process according to claim 1 , ...

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25-07-2013 дата публикации

Process for hydrotreating a hydrocarbon cut with a boiling point of more than 250°c in the presence of a sulphide catalyst prepared using a cyclic oligosaccharide

Номер: US20130186806A1
Принадлежит: IFP Energies Nouvelles IFPEN

Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.

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29-08-2013 дата публикации

Low viscosity oligomer oil product, process and composition

Номер: US20130225459A1
Принадлежит: INEOS USA LLC

The present invention relates to a low viscosity lubricant process, product, and composition characterized by low Noack volatility, low pour point, useful low temperature viscometrics, and high viscosity index and more particularly concerns a PAO composition having a kinetic viscosity at 100° C. in the range of about 4 cSt.

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05-09-2013 дата публикации

Method for efficiently operating an ebbulated bed reactor and an efficient ebbulated bed reactor

Номер: US20130228494A1
Принадлежит: Headwaters Heavy Oil LLC

A hydroprocessing method and system involves introducing heavy oil and well-dispersed metal sulfide catalyst particles, or a catalyst precursor capable of forming the well-dispersed metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The well-dispersed or in situ metal sulfide catalyst particles are formed by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the well-dispersed or in situ metal sulfide catalyst particles. The well-dispersed or in situ metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

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05-09-2013 дата публикации

Integrated hydrotreating and steam pyrolysis process including hydrogen redistribution for direct processing of a crude oil

Номер: US20130228495A1
Принадлежит: Saudi Arabian Oil Co

Steam pyrolysis and hydroprocessing are integrated including hydrogen redistribution to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. A feed is initially split into a light portion and a heavy portion, and the heavy portion is hydroprocessed. A hydroprocessed effluent is charged, along with steam, to a convection section of a steam pyrolysis zone. The mixture is heated and passed to a vapor-liquid separation section. A residual portion is removed and light components are charged to a pyrolysis section of the steam pyrolysis zone. A mixed product stream is recovered from the steam pyrolysis zone and it is separated into product including olefins and aromatics.

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31-10-2013 дата публикации

Conversion of Natural Gas

Номер: US20130289144A1
Автор: Rian Steyn
Принадлежит: Asa Energy Conversions Ltd

A process and apparatus for converting a mixture of hydrogen and carbon monoxide to hydrocarbons comprising reacting the hydrogen and carbon monoxide at elevated temperature and pressure in contact with a suitable catalyst in a reactive distillation column is disclosed.

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07-11-2013 дата публикации

Titania-Supported Hydrotreating Catalysts

Номер: US20130294985A1
Принадлежит: SACHTLEBEN CHEMIE GMBH

TiO-supported catalysts include at least molybdenum or tungsten as active components for hydrotreating processes, in particular for the removal of sulfur and nitrogen compounds as well as metals out of crude oil fractions and for the hydrogenation of sulfur oxides. 1. Supported catalyst composition for hydrotreating , comprising shaped titania support bodies having at least one oxide of molybdenum and/or tungsten on the surface thereof and having a surface area of at least 80 mper gram , a pore volume measured by mercury porosimetry of at least 0.25 cm/g , a side-crush strength greater than 7 N/mm , and a tapped bulk density in the range of 600-1200 kg/m.2. Catalyst composition according to claim 1 , having a titanium dioxide content of the support bodies in the range of 80 to 100 wt. % as calculated on the total weight of the supported catalyst composition.3. Catalyst composition according to claim 1 , having a content of molybdenum and/or tungsten in the range of 9.0 to 16.0 wt. % claim 1 , expressed as trioxides claim 1 , calculated on the total weight of the supported catalyst composition.4. Catalyst composition according to claim 1 , further comprising a total content of at least one of cobalt and nickel in the range of 0 to 6.5 wt. % claim 1 , expressed as CoOor NiO claim 1 , calculated on the total weight of the supported catalyst composition.5. Catalyst composition according to claim 1 , wherein at least 20 weight percent of the supported precursor particles of the catalytically active oxides being present after calcination are smaller than 50 nm.6. Catalyst composition for hydrotreating according to claim 1 , obtainable by applying an aqueous solution of at least one salt of molybdenum and/or tungsten on shaped titania support bodies followed by drying and calcining the obtained bodies.7. Process for the preparation of a catalyst composition as claimed in claim 1 , wherein a solution of at least one salt of molybdenum and/or tungsten is applied on titania ...

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07-11-2013 дата публикации

A CATALYST AND PROCESS FOR THE MANUFACTURE OF ULTRA-LOW SULFUR DISTILLATE PRODUCT

Номер: US20130296163A1
Автор: BHAN Opinder Kishan
Принадлежит:

Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor. 1. A composition for use as a distillate hydrodesulfurization catalyst in the manufacture of an ultra-low sulfur distillate product , wherein said composition comprises:a calcined mixture made by calcining a co-mulled mixture comprising an inorganic oxide material, molybdenum trioxide in the form of finely divided particles having a maximum dimension of less than 150 μm, and a Group VIII metal compound selected from the group consisting of a nickel compound, a cobalt compound and a combination thereof, wherein said calcined mixture has a molybdenum content in the range of from 10 weight percent to 22 weight percent with the weight percent being based upon the molybdenum as metal and the total weight of said calcined mixture, and a Group VIII metal content in the range of from 3 weight percent to 12 weight percent with the weight percent being based upon the Group VIII metal in its elemental form and the total weight of said calcined mixture, wherein said calcined mixture has a mean pore diameter in the range of from 50 angstroms to 100 angstroms, and wherein said calcined mixture has less than 1 percent of the total pore volume in macropores having a diameter greater than 1000 angstroms.2. A composition as recited in claim 1 , wherein said pore structure is ...

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14-11-2013 дата публикации

Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation

Номер: US20130303812A1
Принадлежит: Shell Oil Co

The present invention relates to a catalyst for the hydrogenation of unsaturated hydrocarbons, in particular aromatics with a broad molecular weight range, a process for the production thereof and a process for hydrogenating unsaturated hydrocarbons.

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21-11-2013 дата публикации

Coprocessing of biofeeds with group vi metal catalysts

Номер: US20130310618A1
Принадлежит: ExxonMobil Research and Engineering Co

Feedstocks containing biocomponent materials are coprocessed with mineral feeds using a Group VI metal catalyst prior to hydrodesulfurization of the feedstocks. The Group VI metal catalyst is optionally a physically promoted Group VI metal catalyst.

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21-11-2013 дата публикации

Catalytically Active Material for the Hydrogenation Treatment of Hydrocarbons

Номер: US20130310622A1
Принадлежит: Euro Support Catalyst Group Bv

A catalytically active material having adsorption properties is used for the hydrogenation treatment of hydrocarbons severely contaminated with inorganic constituents.

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28-11-2013 дата публикации

Process for direct hydrogen injection in liquid full hydroprocessing reactors

Номер: US20130313161A1
Автор: Hasan Dindi
Принадлежит: EI Du Pont de Nemours and Co

A process of hydroprocessing a hydrocarbon in a down flow reactor comprising one or more hydroprocessing-catalyst beds. The hydrocarbon feed is mixed with hydrogen and optionally diluent to form a liquid feed mixture wherein hydrogen is dissolved in the mixture, and the liquid feed mixture is introduced into the down flow reactor under hydroprocessing conditions. The hydroprocessing-catalyst bed(s) are liquid-full and the feed reacts by contact with the catalyst. Hydrogen gas is injected into at least one of the hydroprocessing-catalyst beds such that at least part of the hydrogen consumed in that bed is replenished and the liquid-full condition is maintained. In a multi-bed reactor, hydrogen gas may be injected into more than one or all of the hydroprocessing-catalyst beds.

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28-11-2013 дата публикации

Method of Simultaneously Removing Sulfur and Mercury from Hydrocarbon Material Using Catalyst by Means of Hydrotreating Reaction

Номер: US20130313165A1
Принадлежит: SK Innovation Co Ltd

Disclosed herein is a method of simultaneously removing sulfur and mercury from a hydrocarbon material, including: hydrotreating the hydrocarbon material containing sulfur and mercury in the presence of a catalyst including a metal supported with a carrier to convert sulfur into hydrogen sulfide, and adsorb mercury on a metal active site or a carrier of the catalyst in the form of mercury sulfide.

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28-11-2013 дата публикации

Distillate oil hydrogenation deacidification catalyst containing molecular sieve, preparation and use thereof

Номер: US20130316894A1
Принадлежит: Petrochina Co Ltd

Provided are a distillate oil hydrogenation deacidification catalyst containing a molecular sieve, preparation and use thereof. In this catalyst, the weight of the catalyst, on the basis of 100%, is 1-5% magnesium calculated as an oxide, 1-20% alumino-phosphate molecular sieve and/or aluminosilicate molecular sieve; 1-10% Co and/or Ni; 5-30% Mo and/or W, and the balance is aluminium oxide. The catalyst is prepared through forming, dipping and baking. The catalyst is very active in hydrogenation deacidification, and also in hydrodesulfurization and hydrodenitrogenation.

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26-12-2013 дата публикации

Novel fuel compositions and methods for making same

Номер: US20130340323A1
Принадлежит: ExxonMobil Research and Engineering Co

This invention relates to low sulfur marine/bunker fuel compositions and methods of making same. Contrary to conventional marine/bunker fuel compositions/methods, the inventive lower sulfur compositions/methods focus on use of mostly uncracked components, such as (cat feed) hydrotreated gasoils, and/or can also have reduced contents of residual components.

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26-12-2013 дата публикации

MICROWAVE-PROMOTED DESULFURIZATION OF CRUDE OIL

Номер: US20130341247A1
Принадлежит: Saudi Arabian Oil Company

Heavy crude oils having high sulfur content and viscosities are upgraded by a hydrodesulfurization (HDS) process that includes microwave irradiation of a mixture of the sour heavy crude oil with at least one catalyst and optionally, one or more sensitizers, and irradiation in the presence of hydrogen. The process is also adapted to microwave treatment of hard to break emulsions, either above ground or below ground where water-in-oil emulsions are initially formed, followed by the catalytic hydrodesulfurization promoted by application of further microwave energy to the demulsified crude oil stream. 1. A process for upgrading a sulfur-containing crude oil feedstream to improve the API gravity and reduce the sulfur content , the process comprising:a. mixing the crude oil with one or more hydrotreating catalysts having a reaction surface to provide a catalyst-crude oil reaction mixture;b. irradiating the mixture of the crude oil and one or more hydrotreating catalysts with microwave energy in the presence of hydrogen at a pressure level of from one atmosphere to 400 psig to raise the temperature of the reaction mixture to a temperature in the range from 70° C. to about 400° C.;c. maintaining the temperature of the reaction mixture by varying the microwave energy, for a period of time that is sufficient to form soluble sulfur compounds and thereby reduce the sulfur content of the crude oil;d. separating the irradiated mixture into a catalyst-containing solid phase and an upgraded oil phase; ande. recovering the upgraded oil phase.2. The process of claim 1 , wherein the one or more catalysts comprise powdered iron claim 1 , palladium oxide claim 1 , calcium oxide claim 1 , an alkali metal oxide catalyst claim 1 , traditional hydrotreating catalysts claim 1 , and combinations thereof.3. The process of claim 1 , wherein the hydrotreating catalyst comprises at least one metal selected from Group VIB or VIIIB of the Periodic Table.4. The process of in which the at least one ...

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26-12-2013 дата публикации

Methods and apparatuses for deoxygenating biomass-derived pyrolysis oil

Номер: US20130345487A1
Принадлежит: UOP LLC

Embodiments of methods and apparatuses for deoxygenating a biomass-derived pyrolysis oil are provided. In one example, a method comprises the steps of separating a low-oxygen biomass-derived pyrolysis oil effluent into a low-oxygen-pyoil organic phase stream and an aqueous phase stream. Phenolic compounds are removed from the aqueous phase stream to form a phenolic-rich diluent recycle stream. A biomass-derived pyrolysis oil stream is diluted and heated with the phenolic-rich diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream is contacted with a deoxygenating catalyst in the presence of hydrogen to deoxygenate the heated diluted pyoil feed stream.

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02-01-2014 дата публикации

Metal nanoparticle deposited inorganic nanostructure hybrids, uses thereof and processes for their preparation

Номер: US20140005040A1

This invention relates to a hybrid component comprising at least one nanoparticle of inorganic layered compound (in the form of fullerene-like structure or nanotube), and at least one metal nanoparticle, uses thereof as a catalyst, (e.g. photocatalysis) and processes for its preparation.

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30-01-2014 дата публикации

Dual stripper column apparatus and methods of operation

Номер: US20140027347A1
Принадлежит: UOP LLC

Dual stripper column arrangements are described in which hot flash drum liquid is sent to one column and cold flash drum liquid is sent to a second column. Methods of operating the dual stripper column apparatus are also described.

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30-01-2014 дата публикации

PROCESS FOR HYDROTREATING HEAVY HYDROCARBON FEEDS WITH SWITCHABLE REACTORS INCLUDING AT LEAST ONE STEP OF PROGRESSIVE SWITCHING

Номер: US20140027351A1
Принадлежит: IFP ENERGIES NOUVELLES

Process for hydrotreating a heavy hydrocarbon fraction using a system of switchable fixed bed guard zones each containing at least one catalyst bed including at least one step during which the flow of feed supplied to the first guard zone brought into contact with the feed is partly displaced to the next guard zone downstream, preferably progressively. 1. Process for hydrotreating a heavy hydrocarbon fraction containing asphaltenes , sediments , sulphur-containing , nitrogen-containing and metallic impurities , in which the feed of hydrocarbons and hydrogen is passed , under hydrotreating conditions , over a hydrotreating catalyst , in at least two fixed bed hydrotreating guard zones each containing at least one catalyst bed , the guard zones being arranged in series to be used cyclically , consisting of successive repetition of steps b) , c) and c′) defined below:a step a) during which the feed passes through all the guard zones during a fraction of the deactivation time and/or clogging time of the first guard zone brought into contact with the feed,a step a′) during which a portion of the feed continues to pass through the first guard zone brought into contact with the feed and another portion of the feed is introduced into the next guard zone downstream for a period at most equal to the deactivation time and/or clogging time of the first guard zone brought into contact with the feed,a step b) during which the deactivated and/or clogged guard zone is by-passed and the catalyst that it contains is regenerated and/or replaced with fresh catalyst and during which the other guard zone(s) are used,a step c) during which the feed passes through all the guard zones, the guard zone of which the catalyst was regenerated during the preceding step being reconnected so as to be downstream of all the other guard zones and said step being continued for a fraction of the deactivation time and/or clogging time of the first guard zone brought into contact with the feed,a step c′) ...

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06-02-2014 дата публикации

Extracted conjunct polymer naphtha

Номер: US20140039230A1
Принадлежит: Chevron USA Inc

We provide an extracted conjunct polymer naphtha ( 45 ), comprising a hydrogenated conjunct polymer naphtha, from a used ionic liquid catalyst, having a final boiling point less than 246° C. (475° F.), a Bromine Number of 5 or less, and at least 30 wt % naphthenes. We also provide a blended alkylate gasoline ( 97 ) comprising the extracted conjunct polymer naphtha ( 45 ), and integrated alkylation processes to make the extracted conjunct polymer naphtha ( 45 ) and the blended alkylate gasoline ( 97 ). We also provide a method to analyze alkylate products, by determining an amount of methylcyclohexane in the alkylate products ( 80 ).

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06-03-2014 дата публикации

Hydroconversion Multi-Metallic Catalyst and Method For Making Thereof

Номер: US20140066293A1
Принадлежит: Chevron USA Inc

The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst contains Ni:W in a mole ratio of 1:3 to 4:1, on a transition metal basis. The self supported MMS catalyst is characterized as having an HYD reaction rate constant of at least 15% higher than that of a catalyst comprising nickel sulfide alone or a catalyst comprising tungsten sulfide alone, when compared on same metal molar basis in hydrotreating of benzene as a feedstock at identical process conditions.

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20-03-2014 дата публикации

Regeneration or remanufacturing catalyst for hydrogenation processing heavy oil, and method for manufacturing same

Номер: US20140076781A1
Автор: Hea Kyung Park

Provided are a regenerated or remanufactured catalyst for hydrogenating heavy oil or residual oil obtained by effectively removing a sulfur component, a carbonaceous component and a vanadium component, which are present in a spent catalyst for hydrogenating the heavy oil or residual oil and thus degrade an activity thereof, a method of manufacturing the same, and a method of hydrogenating heavy oil or residual oil using the same.

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20-03-2014 дата публикации

HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, A METHOD OF MAKING A HIGH ACTIVITY HYDRODESULFURIZATION CATALYST, AND A PROCESS FOR MANUFACTURING AN ULTRA-LOW SULFUR DISTILLATE PRODUCT

Номер: US20140076783A1
Автор: BHAN Opinder Kishan
Принадлежит: SHELL OIL COMPANY

A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration. 2. A method as recited in claim 1 , wherein said calcined shaped particle has a material absence of both boehmite and a crystalline transitional phase of alumina other than gamma-alumina.3. A method as recited in claim 2 , wherein said calcined shaped particle contains less than 5 weight percent boehmite with the weight percent being based on the total weight of said calcined shaped particle.4. A method as recited in claim 3 , wherein less than 5 weight percent of said alumina of said calcined shaped particle is said transitional crystalline phase of alumina other than gamma alumina.5. A method as recited in claim 4 , wherein the median pore diameter of said calcined shaped particle is in the range of from about 80 angstroms to about 110 angstroms claim 4 , wherein the total pore volume of said calcined shaped particle is in the range of from about 0.6 cc/gram to about 1.1 cc/gram claim 4 , and wherein more than 70 percent of the total pore volume of said calcined shaped particle is contained in the pores having a pore diameter of from 80 angstroms to 350 angstroms.6. A method as recited in claim 5 , wherein said ...

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03-04-2014 дата публикации

Transition-metal free reductive cleavage of aromatic c-o, c-n, and c-s bonds by activated silanes

Номер: US20140091256A1

The present invention describes chemical systems and methods for reducing C—O, C—N, and C—S bonds, said system comprising a mixture of (a) at least one organosilane and (b) at least one strong base, said system being substantially free of a transition-metal compound, and said system optionally comprising at least one molecular hydrogen donor compound, molecular hydrogen, or both.

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01-01-2015 дата публикации

Generating cellulosic-renewable identification numbers in a refinery

Номер: US20150000186A1
Принадлежит: Ensyn Renewables Inc

The present application generally relates to methods of generating cellulosic-renewable identification numbers by thermally processing a cellulosic biomass to form a renewable fuel oil, and then co-processing the renewable fuel oil with a petroleum fraction in a refinery to form a cellulosic-renewable identification number-compliant fuel.

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07-01-2016 дата публикации

HYDROTREATMENT CATALYST WITH A HIGH DENSITY OF MOLYBDENUM, AND PROCESS FOR ITS PREPARATION

Номер: US20160001272A1
Автор: Daudin Antoine
Принадлежит: IFP ENERGIES NOUVELLES

The present invention concerns a hydrotreatment catalyst comprising an alumina-based support, at least one metal from group VIB, at least one metal from group VIII and phosphorus, in which: 2. The catalyst according to claim 1 , in which:the content of the metal from group VIB is in the range 3% to 35% by weight of oxide of said metal from group VIB with respect to the total catalyst weight;the content of the metal from group VIII is in the range 0.1% to 10% by weight of oxide of said metal from group VIII with respect to the total catalyst weight;{'sub': 2', '5, 'the phosphorus content is in the range 0.3% to 10% by weight of POwith respect to the total catalyst weight.'}3. The catalyst according to claim 1 , in which the (metal from group VIII)/(metal from group VIB) molar ratio is in the range 0.1 to 0.8 and the phosphorus/(metal from group VIB) molar ratio is in the range 0.1 to 0.7.4. The catalyst according to claim 1 , in which the specific surface area of the catalyst is in the range 30 to 150 m/g claim 1 , preferably in the range 40 to 95 m/g and highly preferably in the range 50 to 90 m/g.5. The catalyst according to claim 1 , in which the density of the metal from group VIB is in the range 7 to 25 atoms of metal from group VIB per nmof catalyst claim 1 , preferably in the range 7 to 20 atoms of metal from group VIB per nmof catalyst claim 1 , more preferably in the range 7 to 15 atoms of metal from group VIB per nmof catalyst.6. The catalyst according to claim 1 , in which the metal from group VIB is selected from tungsten and molybdenum and the metal from group VIII is selected from nickel and cobalt.7. The catalyst according to claim 6 , in which the metal from group VIB is molybdenum and the metal from group VIII is cobalt.8. The catalyst according to claim 1 , in which the alumina-based support is obtained from an alumina gel which has been kneaded claim 1 , shaped and calcined.9. The catalyst according to claim 1 , further comprising at least one ...

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02-01-2020 дата публикации

POORLY CRYSTALLINE TRANSITION METAL TUNGSTATE

Номер: US20200001281A1
Принадлежит:

A hydroprocessing catalyst has been developed. The catalyst is a poorly crystalline transition metal tungstate material or a metal sulfide decomposition product thereof. The hydroprocessing using the crystalline ammonia transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The poorly crystalline transition metal tungstate material of wherein the poorly crystalline transition metal tungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt-% binder.3. The poorly crystalline transition metal tungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The poorly crystalline transition metal tungstate material of wherein M is nickel or zinc.5. The poorly crystalline transition metal tungstate material of wherein M is nickel.7. The method of further comprising removing at least some of the NH claim 6 , HO or combination thereof to form an intermediate before reacting the mixture at a temperature from about 90° C. to about 350° C. in an autogenous environment.8. The method of wherein the reacting is conducted from about 30 minutes to 14 days.9. The method of wherein the recovering is by filtration or centrifugation.10. The method of further comprising adding a binder to the poorly crystalline transition metal tungstate material.11. The method of wherein the binder is selected from the group consisting of aluminas claim 10 , silicas claim 10 , and alumina-silicas.12. The method of further comprising decomposing the poorly crystalline transition metal tungstate material by sulfidation to form metal sulfides.14. The process of wherein the conversion process is hydroprocessing.15. The process of wherein the conversion process is selected from the group consisting of ...

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02-01-2020 дата публикации

POORLY CRYSTALLINE TRANSITION METAL MOLYBDOTUNGSTATE

Номер: US20200001282A1
Принадлежит:

A hydroprocessing catalyst or catalyst precursor has been developed. The catalyst is a poorly crystalline transition metal molybdotungstate material or a metal sulfide decomposition product thereof. The hydroprocessing using the crystalline ammonia transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. 2. The poorly crystalline transition metal molybdotungstate material of wherein the poorly crystalline transition metal molybdotungstate material is present in a mixture with at least one binder and wherein the mixture comprises up to 25 wt-% binder.3. The poorly crystalline transition metal molybdotungstate material of wherein the binder is selected from the group consisting of silicas claim 2 , aluminas claim 2 , and silica-aluminas.4. The poorly crystalline transition metal molybdotungstate material of wherein M is nickel or zinc.5. The poorly crystalline transition metal molybdotungstate material of wherein M is nickel.7. The method of further comprising removing at least some of the NH claim 6 , HO claim 6 , or a combination thereof to form an intermediate before reacting the mixture at a temperature from about 90° C. to about 350° C. in an autogenous environment8. The method of wherein the reacting is conducted for a period from about 30 minutes to 14 days.9. The method of wherein the recovering is by filtration or centrifugation.10. The method of further comprising adding a binder to the poorly crystalline transition metal molybdotungstate material.11. The method of wherein the binder is selected from the group consisting of aluminas claim 10 , silicas claim 10 , and alumina-silicas.12. The method of further comprising decomposing the transition metal molybdotungstate material by sulfidation to form metal sulfides.14. The process of wherein the conversion process is hydroprocessing.15. The ...

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07-01-2016 дата публикации

COMMERCIAL FISCHER-TROPSCH REACTOR

Номер: US20160002541A1
Принадлежит:

A method for converting synthesis gas into liquid hydrocarbons by introducing a synthesis gas feed into a Fischer-Tropsch system that includes a catalytic reactor fluidly connected with at least two slurry loops, the reactor comprising at least as many reactor product outlets and slurry return inlets as slurry loops; each slurry loop comprising a separation system comprising at least one separator, an inlet of each separator fluidly connected to a reactor product outlet via a slurry offtake, and an outlet of each separator fluidly connected to a slurry return inlet via a slurry return; separating concentrated catalyst slurry from the reaction product via the slurry loops; removing liquid hydrocarbon product from each separator; and returning concentrated catalyst slurry to the catalytic reactor via the slurry returns and slurry return inlets. A system for converting synthesis gas into liquid hydrocarbons via the method is also disclosed. 1. A method for converting synthesis gas into liquid hydrocarbons , the method comprising:introducing a synthesis gas feed into a Fischer-Tropsch reactor of a Fischer-Tropsch system at a superficial gas velocity greater than the average sedimentation velocity and/or greater than the minimum fluidization velocity of catalyst in the catalytic reactor, wherein the Fischer-Tropsch system comprises: a catalytic reactor fluidly connected with at least two slurry loops, wherein the reactor comprises at least as many reactor product outlets and at least as many slurry return inlets as slurry loops; wherein each slurry loop comprises a separation system comprising at least one separator for separating concentrated catalyst slurry from liquid product; an inlet of the at least one separator fluidly connected to one of the reactor product outlets via a slurry offtake, an outlet of the at least one separator fluidly connected to one of the slurry return inlets via a slurry return, and a product outlet of the at least one separator for removal of ...

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07-01-2016 дата публикации

Processes for converting biomass to btx with low sulfur, nitrogen and olefin content via a catalytic fast pyrolysis process

Номер: US20160002544A1
Принадлежит: Anellotech Inc

Methods of separating and purifying products from the catalytic fast pyrolysis of biomass are described. In a preferred method, a portion of the products from a pyrolysis reactor are recovered and purified using a hydrotreating step that reduces the content of sulfur, nitrogen, and oxygen components, and hydrogenates olefins to produce aromatic products that meet commercial quality specifications.

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04-01-2018 дата публикации

PRODUCTION OF LOW CLOUD POINT DISTILLATE FUELS

Номер: US20180002615A1
Принадлежит:

Systems and methods are provided for catalytically dewaxing a diesel boiling range feed. In some aspects, catalytic dewaxing can be performed at low hydrogen treat gas rates and/or low hydrogen purity conditions. In other aspects, the systems and methods can allow for distillate dewaxing while reducing or minimizing the amount of equipment required. 1. A method for producing distillate fuel boiling range material , comprising:{'sup': 3', '3', '3', '3, 'sub': '2', 'exposing a distillate fuel boiling range feedstock having a sulfur content of about 15 wppm or less to a dewaxing catalyst comprising a molecular sieve and a metal hydrogenation component under dewaxing conditions to produce a dewaxed effluent comprising a distillate fuel boiling range product and/or blendstock having a cloud point that is reduced relative to a cloud point of the feedstock by at least about 5° C., the dewaxing conditions comprising a total pressure of about 200 psig (about 1.4 MPag) or less, a hydrogen partial pressure of about 100 psig (about 700 kPag) or less, and a treat gas rate of about 100 SCF/bbl (about 17 Nm/m) to about 5000 SCF/bbl (about 850 Nm/m) of a treat gas comprising about 5 vol % to about 50 vol % H.'}2. The method of claim 1 , wherein the vol % of Hin the treat gas is lower than a vol % of Hin a gaseous portion of the dewaxed effluent.3. The method of claim 1 , wherein the treat gas has a sulfur content of about 0.001 vol % or less.4. The method of claim 1 , wherein the dewaxing conditions further comprise a temperature of from about 500° F. (˜260° C.) to about 750° F. (˜399° C.) and a space velocity from about 0.3 hrto about 5.0 hr.5. The method of claim 1 , further comprising exposing a second feedstock to a hydrotreating catalyst to form a hydrotreated effluent claim 1 , and separating the hydrotreated effluent to form the distillate fuel boiling range feedstock.6. The method of claim 5 , wherein the effective hydrotreating conditions comprise a pressure from about 200 ...

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04-01-2018 дата публикации

PROCESSING OF HEAVY HYDROCARBON FEEDS

Номер: US20180002617A1
Принадлежит:

Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude. 1. A process for producing a hydroprocessed product , comprising:exposing a feedstock to a catalyst under effective slurry hydroconversion conditions to form a slurry hydroprocessing effluent, the effective slurry hydroconversion conditions being effective for conversion of at least about 90 wt % of the feedstock relative to a conversion temperature, the catalyst comprising catalyst particles having a particle size of at least about 2 μm; andseparating at least about 95 wt % of the catalyst particles having a particle size of at least about 2 μm from the slurry hydroprocessing effluent using a catalyst recovery system comprising one or more drum separators and a cross-flow filter.2. The process of claim 1 , wherein the feedstock has a T95 distillation point of about 600° C. or less.3. The process of claim 1 , wherein the feedstock has a 10% distillation point of at least about 900° F. (˜482° C.) claim 1 , a Conradson carbon residue of at least about 27.5 wt % claim 1 , or a combination thereof.4. The process of claim 1 , wherein the one or more drum separators comprise cyclone separators.5. The process of claim 1 , further comprising exposing the feedstock to a demetallization catalyst under slurry ...

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02-01-2020 дата публикации

PROCESS FOR THE PRODUCTION OF ISOPARAFFINIC FLUIDS WITH LOW AROMATICS CONTENT

Номер: US20200002626A1
Принадлежит: TOTAL MARKETING SERVICES

The invention provides a process for preparing a fluid having a boiling point in the range of from 150 to 260° C. and comprising more than 80% by weight of isoparaffins and less than 50 ppm of aromatics, comprising the step of catalytically hydrogenating a feed comprising more than 85% by weight of oligomerized olefins, at a temperature from 115 to 195° C. and at a pressure from 30 to 70 bars. The invention also provides the fluid obtainable by the process of the invention and the use of said fluid. 116.-. (canceled)17. A method for the preparation of a fluid having a boiling point in the range of from 150 to 260° C. and comprising more than 80% by weight of isoparaffins and less than 50 ppm of aromatics , comprising the step of catalytically hydrogenating a feed comprising more than 85% by weight of oligomerized olefins , at a temperature from 115 to 195° C. and at a pressure from 30 to 70 bars.18. The method of claim 17 , wherein the method comprises three hydrogenation stages.19. The method of claim 17 , wherein the hydrogenation conditions are the following:Pressure: 40 to 60 bars;Temperature: 125 to 185° C.;{'sup': '−1', 'Liquid hourly space velocity (LHSV): 0.1 to 3 hr;'}{'sup': '3', 'Hydrogen treat rate: 50 to 300 Nm/ton of feed.'}20. The method of claim 17 , wherein the feed comprises more than 90% by weight of oligomerized olefins.21. The method of claim 17 , wherein the oligomerized olefinic feed is selected from the group consisting of: trimeric butene claim 17 , and tetrameric propylene cuts.22. The method of claim 17 , wherein the oligomerized olefinic feed comprises a majority of C12 olefins.23. The method of claim 17 , wherein the method comprises (i) a fractionating step carried out before the hydrogenating step claim 17 , or after the hydrogenating step or both claim 17 , or (ii) the method comprises three hydrogenation stages claim 17 , or (iii) both (i) and (ii).24. The method of claim 17 , wherein the fluid has a boiling point in the range of ...

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01-01-2015 дата публикации

Fluidized catalytic cracking apparatus

Номер: US20150004067A1
Принадлежит: Ensyn Renewables Inc

The present application generally relates to a fluidized catalytic cracking apparatus having one or more ports for injecting a renewable fuel oil for co-processing the renewable fuel oil and a petroleum fraction.

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14-01-2016 дата публикации

Procedimiento de obtencion de una formulacion catalitica para la produccion de diesel de ultrabajo azufre, el producto obtenido y su aplicacion

Номер: US20160008792A1

The present invention relates to a catalytic formulation used in the hydroprocessing of light and middle oil fractions, preferably in hydrodesulfurization and hydrodenitrogenation reactions to obtain diesel with ultra low sulfur content less than or equal to 15 ppm in weight. The catalytic formulation, object of the present invention, consists of at least one metal of Group VI B and at least one metal of Group VIII B and one element of Group V A of the periodic table deposited on a support based on surface modified alumina with an inorganic oxide of a metal of Group II A, IV A and/or IV B. And containing an impregnated organic compound containing at least one hydroxyl group and at least one carboxyl group and that can contain or not at least one sulfide group in its structure. The catalytic formulation, object of the present invention, allows processing of the oil fractions with initial and final boiling temperatures between 150 and 450° C., with initial nitrogen and sulfur content between 1 and 3% by weight and 200 to 600 ppm, respectively, reducing sulfur content to concentrations lower or equal to 15 ppm and nitrogen concentrations to lower than 1 ppm.

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14-01-2016 дата публикации

HYDROPROCESSING CATALYST FOR TREATING A HYDROCARBON FEED HAVING AN ARSENIC CONCENTRATION AND A METHOD OF MAKING AND USING SUCH CATALYST

Номер: US20160008795A1
Принадлежит:

A catalyst that is useful for the removal of arsenic from hydrocarbon feedstocks. The catalyst comprises an alumina support, underbedded molybdenum and phosphorus components, and an overlayer of a nickel component. The catalyst further has the unique property of having a surface nickel-to-molybdenum atomic ratio of greater than 1.8 with a bulk nickel-to-molybdenum atomic ratio of less than 2.2. The nickel accessibility factor of the catalyst is greater than 1.2. The catalyst is prepared by the application of two metals impregnation steps with associated calcination steps that in combination provide for the underbedded metals and overlayer of nickel. 1. A catalyst composition for hydroprocessing a hydrocarbon feedstock having a concentration of arsenic compounds , wherein said catalyst composition comprises:an alumina support;an underbedded molybdenum component;an underbedded phosphorus component;an overlaid nickel component;wherein said catalyst composition has a surface nickel metal-to-molybdenum metal atomic ratio of greater than 1.8 as determined by X-ray Photoelectron Spectroscopy.2. A catalyst composition as recited in claim 1 , wherein said catalyst composition has a nickel accessibility factor (i.e. claim 1 , surface Ni/Mo ratio-to-bulk Ni/Mo ratio) greater than 1.2.3. A catalyst composition as recited in claim 1 , wherein said catalyst composition has a bulk nickel metal-to-molybdenum metal atomic ratio of less than 2.2.4. A catalyst composition as recited in claim 3 , wherein said catalyst composition comprises: nickel in an amount in the range of from 7 wt. % to 20 wt. % claim 3 , calculated as elemental nickel and based on the total weight of said catalyst composition; and molybdenum in an amount in the range of from 3 wt. % to 20 wt. % claim 3 , calculated as elemental molybdenum and based on the total weight of said catalyst composition; and phosphorus in an amount in the range of from 0.1 wt. % to 5 wt. % claim 3 , calculated as elemental phosphorus ...

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14-01-2016 дата публикации

HYDROPROCESSING CATALYST, PREPARATION METHOD THEREOF AND USE OF SAME

Номер: US20160008799A1
Принадлежит:

The invention relates to a hydrocarbon hydroprocessing catalyst comprising a support based on at least one refractory oxide, at least one metal from group VIII and at least one metal from group VIB. The inventive catalyst is characterized in that it also comprises at least one organic compound having formula (I) or (II): 2. The activated catalyst as claimed in claim 1 , wherein the organic compound of formula (I) or (II) is selected from alkyl ortho-phthalates claim 1 , alkyl isophthalates claim 1 , alkyl terephthalates claim 1 , malonic acid esters claim 1 , adipic acid esters claim 1 , glutaric acid esters claim 1 , 1 claim 1 ,6-dioxacyclodecane-2 claim 1 ,5-dione claim 1 , dimethyl 2-(methoxymethyl)-succinate claim 1 , dibutyl itaconate claim 1 , diethyl 2 claim 1 ,3-diacetylsuccinate claim 1 , dimethyl cyclohexane-1 claim 1 ,4-dicarboxylate claim 1 , dimethyl 3 claim 1 ,3′-dithiodipropionate claim 1 , glycerol triacetate claim 1 , propylene glycol diacetate claim 1 , ethylene glycol dimethacrylate and pentaerythritol tetrakis(3-mercaptopropionate).3. The activated catalyst as claimed claim 1 , wherein the number of carbon atoms separating the two groups >C═O of formulae (I) and (II) is equal to 1 claim 1 , 2 or 4.4. The activated catalyst as claimed in claim 3 , wherein the organic compound of formula (I) is a C-Cdialkyl succinate.5. The activated catalyst as claimed in claim 1 , wherein the catalyst comprises at least 0.001 mol of at least one organic compound per mole of metals of groups VIB and VIII.6. The activated catalyst as claimed in claim 5 , wherein the catalyst comprises from 0.001 to 10 mol of at least one organic compound per mole of metals of groups VIB and VIII.8. The method as claimed in claim 7 , wherein the catalyst comprising a carrier based on at least one refractory oxide claim 7 , at least one metal of group VIII in the oxide state and at least one metal of group VIB in the oxide state is a regenerated catalyst.9. The method as claimed in ...

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27-01-2022 дата публикации

METHODS OF CO-PROCESSING PETROLEUM DISTILLATES AND BIO-BASED MATERIAL THROUGH A REACTION SERIES

Номер: US20220025279A1
Принадлежит:

Methods of processing bio-based material feed (“bio-feed”) and a petroleum feed, using combinations of hydrotreating beds, dewaxing beds, post-treatment beds, and liquid quenching zones. Some methods comprise processing the petroleum feed through first hydrotreating reactor beds; then processing the output with a bio-feed together through second hydrotreating reactor beds; then processing the output through the plurality of dewaxing beds to create a dewaxed stream; and, processing the dewaxed stream through the plurality of post-treatment beds to create a product stream. Other methods comprise processing the petroleum feed through the plurality of first hydrotreating reactor beds; then processing the output through the plurality of dewaxing beds to create a dewaxed stream; and, processing the dewaxed stream and the bio-feed together through the plurality of liquid quenching beds zones to create a mixed stream; and, processing the mixed stream through the plurality of post-treatment beds to create a product stream. 1. A method of processing a bio-based material feed (“bio-feed”) and a petroleum feed , the method comprising: a plurality of first hydrotreating reactor beds;', 'a plurality of second hydrotreating reactor beds;', 'a plurality of dewaxing beds; and', 'a plurality of post-treatment beds; and, 'providing one or more reactors comprising, in seriesprocessing the petroleum feed through the plurality of first hydrotreating reactor beds to create a first hydrotreated stream;processing the first hydrotreated stream and the bio-feed together through the plurality of second hydrotreating reactor beds to create a second hydrotreated stream;processing the second hydrotreated stream through the plurality of dewaxing beds to create a dewaxed stream; and,processing the dewaxed stream through the plurality of post-treatment beds to create a product stream.2. The method of wherein first hydrotreating reactor beds and the second hydrotreating reactor beds each receive a ...

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27-01-2022 дата публикации

INTEGRATING EBULLATED BED HYDROCRACKING AND COKING UNITS

Номер: US20220025283A1
Принадлежит: LUMMUS TECHNOLOGY LLC

Integrated processes and systems for the production of distillate hydrocarbons and coke. The process may include feeding a hydrocarbon feedstock, comprising a residuum hydrocarbon fraction, to a residue hydrocracking reactor system to convert hydrocarbons therein, producing a hydrocracked effluent. The hydrocracked effluent may then be fed to a separation system, separating the hydrocracked effluent into one or more distillate hydrocarbon fractions and a vacuum residue fraction. The vacuum residue fraction may be fed to a coker system, converting the vacuum residue fraction into a coke product and a coker vapor effluent, recovering the coke product, and feeding the coker vapor effluent to the separation system. The one or more distillate hydrocarbon fractions are hydroprocessed to produce a hydroprocessed effluent, and the hydroprocessed effluent is separated into product distillate hydrocarbon fractions. 1. A process for the production of distillate hydrocarbons and coke , the process comprising:feeding a hydrocarbon feedstock, comprising a residuum hydrocarbon fraction, to a residue hydrocracking reactor system to convert hydrocarbons therein, producing a hydrocracked effluent;in a separation system, separating the hydrocracked effluent into one or more distillate hydrocarbon fractions and a vacuum residue fraction;in a coker system, converting the vacuum residue fraction into a coke product and a coker vapor effluent, recovering the coke product, and feeding the coker vapor effluent to the separation system;hydroprocessing the one or more distillate hydrocarbon fractions to produce a hydroprocessed effluent; andseparating the hydroprocessed effluent into product distillate hydrocarbon fractions.2. The process of claim 1 , comprising feeding a straight run vacuum residue to the separation system.3. The process of claim 1 , wherein the residue hydrocracking reactor system comprises one or more ebullated bed reactors.4. The process of claim 1 , wherein the ...

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08-01-2015 дата публикации

High Density Cyclic Fuels Derived From Linear Sesquiterpenes

Номер: US20150011810A1
Автор: Benjamin G Harvey
Принадлежит: US Department of Navy

A method to generate cyclic hydrocarbons from farnesene to increase both the density and net heat of combustion of the product fuels. The high density hydrocarbons produced by this method have applications for missile, UAV, jet, and diesel propulsion.

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10-01-2019 дата публикации

Multi-Stage Process and Device for Treatment Heavy Marine Fuel Oil and Resultant Composition and the Removal of Detrimental Solids

Номер: US20190010405A1
Принадлежит: Mag&#275;m&#257; Technology, LLC

A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a Detrimental Solids removal unit as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass and a Detrimental Solids content less than 60 mg/kg. A process plant for conducting the process is also disclosed. 1. A process for reducing the environmental contaminants and detrimental solids in a Feedstock Heavy Marine Fuel Oil , the process comprising: contacting a Feedstock Heavy Marine Fuel Oil with Detrimental Solids removal unit to give a pre-treated Feedstock Heavy Marine Fuel Oil; mixing a quantity of the pre-treated Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a Feedstock Mixture; contacting the Feedstock Mixture with one or more catalyst materials under reactive conditions to form a Process Mixture from said Feedstock Mixture; receiving said Process Mixture and separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and , discharging the Product Heavy Marine Fuel Oil.2. The process of wherein said Feedstock Heavy Marine Fuel Oil complies with ISO 8217 (2017) and has a sulfur content (ISO 14596 or ISO 8754) between the range of 5.0 mass % to 1.0 mass %.3. The process of claim 1 , wherein said Product Heavy Marine Fuel Oil complies with ISO 8217 (2017) and has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.01 mass % to 1.0 mass %.4. The process of claim 1 , wherein said Feedstock Heavy Marine Fuel Oil has: a maximum of kinematic viscosity at 50° C. (ISO 3104) between the range from 180 mm/s to 700 mm/s; a ...

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10-01-2019 дата публикации

Multi-Stage Process and Device for Treatment Heavy Marine Fuel Oil and Resultant Composition Including Ultrasound Promoted Desulfurization

Номер: US20190010406A1
Принадлежит: Magema Technology, LLC

A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a ultrasound treatment process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed. 1. A process for reducing the environmental contaminants in a Feedstock Heavy Marine Fuel Oil , the process comprising: contacting a Feedstock Heavy Marine Fuel Oil with ultrasound having a frequency in the range of about 20 kHz and about 100 megahertz and a sonic energy in the range of about 30 watts/cmto about 300 watts/cm , in the presence of desulfurization reaction inducer selected from the group consisting of aqueous peroxides or one or more transition metal catalysts in the presence of hydrogen , to give a pre-treated Feedstock Heavy Marine Fuel Oil; mixing a quantity of the pre-treated Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a Feedstock Mixture; contacting the Feedstock Mixture with one or more transition metal catalysts under reactive conditions to form a Process Mixture from said Feedstock Mixture; receiving said Process Mixture and separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and , discharging the Product Heavy Marine Fuel Oil.2. The process of wherein said Feedstock Heavy Marine Fuel Oil complies with ISO 8217 (2017) except that it has a sulfur content (ISO 14596 or ISO 8754) between the range of 5.0 wt % to 1.0 wt % and wherein the Product Heavy Marine Fuel Oil complies with ISO 8217 (2017) and has a a sulfur content (ISO 14596 or ISO 8754) between the ...

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10-01-2019 дата публикации

Multi-Stage Device and Process for Production of a Low Sulfur Heavy Marine Fuel Oil

Номер: US20190010407A1
Принадлежит: Mag&#275;m&#257; Technology, LLC

A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel contained within a frame work based on ISO 40 foot or ISO 20 foot container dimensions. 1. A device for the production of a Product Heavy Marine Fuel Oil , the device comprising: means for mixing a quantity of Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a Feedstock Mixture; means for heating the Feedstock mixture , wherein the means for mixing and means for heating are in fluid communication with each other; a Reaction System in fluid communication with the means for heating , wherein the Reaction System comprises one or more reactor vessels selected from the group consisting of: dense packed fixed bed trickle reactor; dense packed fixed bed up-flow reactor; ebulliated bed three phase up-flow reactor; fixed bed divided wall reactor; fixed bed three phase bubble reactor; fixed bed liquid full reactor , fixed bed high flux reactor; fixed bed structured catalyst bed reactor; fixed bed reactive distillation reactor and combinations thereof , and wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Mixture to a Process Mixture; means for receiving said Process Mixture and separating the liquid components of the Process Mixture from the ...

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10-01-2019 дата публикации

Multi-Stage Process and Device Utilizing Structured Catalyst Beds for Production of a Low Sulfur Heavy Marine Fuel Oil

Номер: US20190010408A1
Принадлежит: Mag&#275;m&#257; Technology, LLC

A multi-stage process for the distributive production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core process under reactive conditions in a Reaction System composed of one or more reaction vessels, wherein one or more of the reaction vessels contains one or more catalysts in the form of a structured catalyst bed. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize the one or more reaction vessels, wherein one or more of the reaction vessels contains one or more catalysts in the form of a structured catalyst bed. 1. A process for the production of a Product Heavy Marine Fuel Oil , the process comprising: mixing a quantity of Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a Feedstock Mixture; contacting the Feedstock Mixture with one or more catalysts under reactive conditions to promote the formation of a Process Mixture from said Feedstock Mixture , wherein said one or more catalysts are in the form of a structured catalyst bed; receiving said Process Mixture and separating the liquid components of the Process Mixture from the bulk gaseous components of the Process Mixture; and separating any residual gaseous components and by-product hydrocarbon components from the Product Heavy Marine Fuel Oil.2. The process of claim 1 , wherein the structured catalyst bed comprises a plurality of catalyst retention structures claim 1 , each catalyst retention structure composed of a pair of fluid permeable corrugated metal sheets claim 1 , wherein the pair of the fluid permeable corrugated metal sheets are aligned such that the corrugations are out of phase and thereby defining a catalyst rich space and a catalyst lean space within the structured catalyst bed claim 1 , ...

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03-02-2022 дата публикации

Recycle catalytic reforming process to increase aromatics yield

Номер: US20220033721A1
Принадлежит: Saudi Arabian Oil Co

The invention relates to a process and system arrangement to generate benzene, toluene and xylenes in a refinery. The process relies on recycling a C9+ aromatic bottoms stream from an aromatic recovery complex back to rejoining a hydrotreated naphtha stream as it enters a catalytic reformer. The aromatic bottoms can be further reacted through both the reformer and the subsequent aromatic recovery complex to transform to higher value compounds, thereby reducing waste or reducing bottoms' presence in gasoline pools.

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19-01-2017 дата публикации

Production of low sulfur gasoline

Номер: US20170015915A1
Принадлежит: ExxonMobil Research and Engineering Co

Systems and methods are provided for producing naphtha boiling range fractions having a reduced or minimized amount of sulfur and an increased and/or desirable octane rating and suitable for incorporation into a naphtha fuel product. A naphtha boiling range feed can be separated to form a lower boiling portion and a higher boiling portion. The lower boiling portion, containing a substantial amount of olefins, can be exposed to an acidic catalyst without the need for providing added hydrogen in the reaction environment. Additionally, during the exposure of the lower boiling portion to the acidic catalyst, a stream of light olefins (such as C 2 -C 4 olefins) can be introduced into the reaction environment. Adding such light olefins can enhance the C 5 + yield and/or improve the removal of sulfur from thiophene and methyl-thiophene compounds in the naphtha feed.

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21-01-2016 дата публикации

CONVERSION OF TRIACYLGLYCERIDES-CONTAINING OILS TO HYDROCARBONS

Номер: US20160017239A1
Принадлежит:

A process for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels is disclosed. The process may include: reacting a triacylglycerides-containing oil-water-hydrogen mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides and recovering a reaction effluent comprising water and one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics; hydrotreating the reaction effluent to form a hydrotreated effluent. 1. A process for converting triacylglycerides-containing oils into crude oil precursors and/ordistillate hydrocarbon fuels, the process comprising:reacting a triacylglycerides-containing oil-water-hydrogen mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides and recovering a reaction effluent comprising water and one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics;hydrotreating the reaction effluent to form a hydrotreated effluent.2. The process of claim 1 , further comprising mixing a triacylglycerides-containing oil with water and hydrogen to form the triacylglycerides-containing oil-water-hydrogen mixture.3. The process of claim 1 , further comprising mixing a triacylglycerides-containing oil with water to form a triacylglyceride-containing oil-water mixture.4. The process of claim 3 , further comprising mixing the triacylglyceride-containing oil-water mixture with hydrogen to form the triacylglyceride-containing oil-water-hydrogen mixture.5. The process of claim 1 , wherein the triacylglycerides-containing oil-water-hydrogen mixture has a water to triacylglycerides mass ratio in the range from about 0.001:1 to about 1:1.6. The process of claim 1 , wherein the triacylglycerides-containing oil-water-hydrogen mixture has a ...

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21-01-2016 дата публикации

Extruded resid demetallation catalyst

Номер: US20160017240A1
Принадлежит: ADVANCED REFINING TECHNOLOGIES LLC

Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt % or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.

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18-01-2018 дата публикации

METHOD FOR PRODUCING HYDROTREATED OIL AND METHOD FOR PRODUCING CATALYTIC CRACKED OIL

Номер: US20180016505A1
Автор: MATSUSHITA Koichi
Принадлежит: JXTG NIPPON OIL & ENERGY CORPORATION

There is provided a method for producing hydrotreated oil comprising: a step of passing heavy hydrocarbon oil through a reactor filled with a hydrotreating catalyst to obtain hydrotreated oil, wherein the hydrotreating catalyst contains phosphorus, an iron group element, and a group 6 element; the ratio C/Cof a content Cof the iron group element to a content Cof phosphorus in the hydrotreating catalyst is less than 0.60 in a molar ratio; and the average pore diameter of the hydrotreating catalyst is larger than 7.5 nm and smaller than 9.5 nm. 1. A method for producing hydrotreated oil comprising:a step of passing heavy hydrocarbon oil through a reactor filled with a hydrotreating catalyst to obtain hydrotreated oil, whereinthe hydrotreating catalyst contains phosphorus, an iron group element, and a group 6 element;{'sub': 2', '1', '2', '1, 'a ratio C/Cof a content Cof the iron group element to a content Cof phosphorus in the hydrotreating catalyst is less than 0.60 in a molar ratio; and'}an average pore diameter of the hydrotreating catalyst is larger than 7.5 nm and smaller than 9.5 nm.2. The production method according to claim 1 , wherein claim 1 , in the hydrotreating catalyst claim 1 ,{'sub': 2', '3', '2', '3, 'a ratio C/Cof the content Cof the iron group element to a content Cof the group 6 element is less than 0.45 in a molar ratio, and'}{'sub': 1', '3', '1', '3, 'a ratio C/Cof the content Cof phosphorus to the content Cof the group 6 element is larger than 0.23 in a molar ratio.'}3. A method for producing catalytic cracked oil comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'a step of obtaining hydrotreated oil by the production method according to ; and'}a step of obtaining catalytic cracked oil by fluid catalytic cracking of the hydrotreated oil. The present invention relates to a production method for obtaining hydrotreated oil from heavy hydrocarbon oil, and to a production method for obtaining catalytic cracked oil from heavy hydrocarbon ...

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17-01-2019 дата публикации

Systems and methods for processing heavy oils by oil upgrading followed by distillation

Номер: US20190016971A1
Принадлежит: Saudi Arabian Oil Co

According to one embodiment, a heavy oil may be processed by a method that may include upgrading at least a portion of the heavy oil to form an upgraded oil, where the upgrading comprises contacting the heavy oil with a hydrodemetalization catalyst, a transition catalyst, a hydrodenitrogenation catalyst, and a hydrocracking catalyst to remove at least a portion of metals, nitrogen, or aromatics content from the heavy oil and form the upgraded oil. The method may further include passing at least a portion of the upgraded oil to a separation device that separates the upgraded oil into one or more transportation fuels; and where the final boiling point of the upgraded oil is less than or equal to 540° C.

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21-01-2021 дата публикации

HYDROPROCESSING OF HEAVY CRUDES BY CATALYSTS IN HOMOGENOUS PHASE

Номер: US20210017457A1
Принадлежит:

This disclosure relates to a procedure, which through the application of a catalyst in homogeneous phase, allows the transformation of heavy hydrocarbons (vacuum residue, atmospheric residue, heavy and extra-heavy crudes) into hydrocarbons of lower molecular weight, characterized because after its application, the hydrocarbons obtain greater API gravity, lower kinematic viscosity and different composition by hydrocarbon families (SARA) that increases the proportion of saturated and aromatic resins and asphalts. The sulphur and nitrogen content is also reduced, resulting in higher yields to high commercial value distillates and a lighter product as compared to the original crude. 1. A catalyst to transform heavy and extra-heavy crude oils into lighter oils , wherein organic metal salts that includes a metal from one of Groups VIIB , VIB or IB are used for preparation of the catalyst.2. A catalyst in accordance with claim 1 , wherein the metal in the metal salt is one of Fe claim 1 , Co claim 1 , Ni claim 1 , Cu claim 1 , Mo claim 1 , or W.3. A procedure for the preparation of a catalyst claim 1 , comprising:1) mixing a mineral acid and ammonium salts, and shaking the mixture at a temperature of 25° C. until a clear solution is obtained, with a pH variation between 1 and 2;2) incorporating Nickel salts into the clear solution and solubilize at 40-100° C., then dissolving in water, and maintaining agitation of the solution for a time of 3 h at a temperature of 25° C., resulting in a green and translucent solution;3) storing the green and translucent solution in a closed container under ambient conditions; and [{'sub': '2', 'wherein the catalyst has a final molar ratio of 1.0 Ni, 0.084 Mo, 0.295 H+, 14.42 HO, at pH 1 to 3;'}, 'and wherein the catalyst transforms heavy and extra-heavy crude oils into lighter oils., '4) dehydrating the catalyst at 90° C.,'}4. The procedure for the preparation of a catalyst claim 3 , in accordance with claim 3 , wherein during preparation ...

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21-01-2021 дата публикации

Fuel compositions from light tight oils and high sulfur fuel oils

Номер: US20210017460A1
Принадлежит: MAWETAL LLC

Methods are provided to prepare a low sulfur fuel from hydro-carbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

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26-01-2017 дата публикации

PROCESS FOR GENERATING SYNGAS FROM A CO2-RICH HYDROCARBON-CONTAINING FEED GAS

Номер: US20170022057A1
Принадлежит:

A process for generating a syngas from a CO-rich and hydrocarbon-containing feed gas, wherein a CO-rich and hydrocarbon-containing feed gas is provided and is reacted in a syngas generation step by means of partial oxidation or steam reforming to give an H- and CO-comprising syngas. At least COis removed from the feed gas in a scrubbing of the feed gas by means of a scrubbing medium, before the feed gas is fed to the syngas generation step. 1. Process for generating a syngas from a CO2-rich and hydrocarbon-containing feed gas , wherein a CO2-rich and hydrocarbon-containing feed gas is provided and is reacted in a syngas generation step by means of partial oxidation or steam reforming to give an H2- and CO-comprising syngas ,characterized in that at least CO2 is removed from the feed gas in a scrubbing of the feed gas by means of a scrubbing medium, before the feed gas is fed to the syngas generation step, wherein, during the scrubbing, a CO2-rich stream is generated that has a pressure in the range from 20 bar to 100 bar, and wherein the CO2-rich stream is used as feed for a synthesis or to support the extraction of oil, wherein the CO2-rich stream is injected into an oil deposit in order to increase the pressure in the oil deposit.2. Process according claim 1 , characterized in that the feed gas is conducted downstream of the scrubbing through an adsorber unit claim 1 , wherein one or more sulfur compounds that are still present in the feed gas are adsorbed in the adsorber unit and in this case removed from the feed gas.3. Process according to claim 1 , characterized in that the syngas that is generated is divided into first and second syngas substreams claim 1 , wherein the first syngas substream is used as feed for a synthesis claim 1 , and wherein the second syngas substream is subjected to a water-gas shift reaction claim 1 , wherein CO of the second syngas substream is reacted with H2O to form H2 and CO2 in order to reduce the CO content in the second syngas ...

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28-01-2016 дата публикации

METHODS AND SYSTEMS FOR REMOVING SULFUR COMPOUNDS FROM A HYDROCARBON STREAM

Номер: US20160024396A1
Принадлежит:

Methods and apparatus for removing sulfur compounds from a hydrocarbon stream are disclosed. In one exemplary embodiment, a method for removing sulfur compounds from a hydrocarbon stream includes the steps of steam stripping a mixed hydrocarbon stream to form a steam stripped overhead stream comprising naphtha and lighter hydrocarbons and a steam stripped bottoms stream comprising naphtha and heavier hydrocarbons; fractionating the steam stripped bottoms stream to form a fractionated overhead stream comprising naphtha hydrocarbons; combining the steam stripped overhead stream with a portion of the fractionated overhead stream and an H2-rich makeup gas stream; and hydrodesulfurizing the combined stream to form an HDS reaction effluent stream. 1. A method for removing sulfur compounds from a hydrocarbon stream that comprises the steps of:steam stripping a mixed hydrocarbon stream to form a steam stripped overhead stream comprising naphtha and lighter hydrocarbons and a steam stripped bottoms stream comprising naphtha and heavier hydrocarbons;fractionating the steam stripped bottoms stream to form a fractionated overhead stream comprising naphtha hydrocarbons;combining the steam stripped overhead stream with a portion of the fractionated overhead stream and an H2-rich makeup gas stream; andhydrodesulfurizing the combined stream to form an HDS reaction effluent stream.2. The method of claim 1 , wherein the H2-rich makeup gas stream comprises from 50-250 volume parts per million hydrogen sulfide.3. The method of claim 1 , wherein fractionating the steam stripped bottoms stream further forms a first side cut stream comprising kerosene hydrocarbons.4. The method of claim 3 , wherein fractionating the steam stripped bottoms stream further forms a second side cut stream comprising diesel hydrocarbons.5. The method of claim 4 , wherein fractionating the steam stripped bottoms stream further forms a fractionated bottoms stream comprising a liquid recycle stream.6. The method ...

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10-02-2022 дата публикации

METHOD FOR REGENERATING A CATALYST WHICH IS SPENT AND REGENERATED BY A HYDRODESULFURIZATION PROCESS OF GASOLINES

Номер: US20220040680A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for rejuvenating an at least partially spent catalyst resulting from a hydrodesulfurization process of a sulfur-containing olefinic gasoline cut, where the at least partially spent catalyst result is from a fresh catalyst a metal from group VIII, a metal from group VIb, and an oxide support, where the process includes 1. A process for the rejuvenation of an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut , said at least partially spent catalyst resulting from a fresh catalyst comprising at least one metal from group VIII , at least one metal from group VIb , an oxide support , and optionally phosphorus , said process comprising the following stages:a) the at least partially spent catalyst is regenerated in an oxygen-containing gas stream at a temperature of between 350° C. and 550° C. so as to obtain a regenerated catalyst,b) the regenerated catalyst is brought into contact with at least one impregnation solution containing at least one compound comprising a metal from group VIb, the molar ratio of the metal from group VIb added per metal from group VIb already present in the regenerated catalyst being between 0.15 and 2.5 mol/mol,c) a drying stage is carried out at a temperature of less than 200° C. so as to obtain a rejuvenated catalyst.2. The process as claimed in claim 1 , in which claim 1 , in stage b) claim 1 , the impregnation solution additionally contains a compound comprising a metal from group VIII; the molar ratio of the metal from group VIII added per metal from group VIII already present in the regenerated catalyst is between 0.1 and 2.5 mol/mol.3. The process as claimed in claim 1 , in which claim 1 , in stage b) claim 1 , the impregnation solution additionally contains phosphorus; the molar ratio of the phosphorus added per metal from group VIb already present in the regenerated catalyst is between 0.1 and 2.5 mol/mol.4. The process as claimed in claim 1 , ...

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26-01-2017 дата публикации

FIXED BED HYDROPROCESSING OF DEASPHALTER ROCK

Номер: US20170022433A1
Принадлежит:

Systems and methods are provided for fixed bed hydroprocessing of deasphalter rock. Instead of attempting to process vacuum resid in a fixed bed processing unit, vacuum resid is deasphalted to form a deasphalted oil and deasphalter residue or rock. The rock can then be hydroprocessed in a fixed bed reaction zone, optionally after combining the rock with an aromatic co-feed and/or a hydroprocessing solvent. This can allow for improved conversion of the deasphalter rock and/or improved combined conversion of the deasphalter rock and deasphalted oil. 1. A method for fixed bed processing of deasphalter rock , comprising:exposing a feedstock comprising deasphalter rock and a co-feed comprising a catalytic slurry oil, a lubes extract, a heavy coker gas oil, a vacuum gas oil derived from a heavy oil, or a combination thereof, to a fixed bed of hydroprocessing catalyst under hydroprocessing conditions effective for conversion of at least 40 wt % of the deasphalter rock relative to a conversion temperature of 1050° F. (566° C.) to form a hydroprocessed effluent, the feedstock comprising at least about 20 wt % of the co-feed and at least about 10 wt % of the deasphalter rock.2. The method of claim 1 , wherein the feedstock comprises at least about 30 wt % of the deasphalter rock.3. The method of claim 1 , further comprising performing solvent deasphalting on a resid feedstock to form at least the deasphalter rock and a deasphalted oil fraction claim 1 , the resid feedstock having a T10 distillation point of at least about 650° F. (˜343° C.) claim 1 , the deasphalter rock comprising at least about 10 wt % of the resid feedstock.4. The method of claim 1 , wherein the feedstock comprises at least about 20 wt % of the catalytic slurry oil.5. The method of claim 1 , wherein the feedstock comprises at least about 30 wt % of the co-feed.6. The method of claim 1 , wherein the feedstock further comprises an aromatic solvent claim 1 , the aromatic comprising at least 50 wt % of ...

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22-01-2015 дата публикации

Lubricating grease composition

Номер: US20150024982A1

The invention provides a grease composition containing a thickener and a base oil, wherein the base oil contains (a) a hydrocarbon oil extracted from Botryococcus braunii and/or (b) a hydrocarbon oil obtainable by hydrogenating the hydrocarbon oil (a).

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24-01-2019 дата публикации

PROCESS FOR COMBINED HYDRODESULFURIZATION AND HYDROCRACKING OF HEAVY HYDROCARBONS

Номер: US20190023996A1
Принадлежит:

The present invention relates to a process for combined hydrodesulfurization and hydrocracking of a heavy hydrocarbon feed comprising contacting the hydrocarbon feed in the presence of hydrogen with a catalyst comprising a mixture of a solid acid catalyst and a hydrodesulfurization catalyst. 1. A process for combined hydrodesulfurization and hydrocracking of a heavy hydrocarbon feed comprising:contacting said heavy hydrocarbon feed in the presence of hydrogen at process conditions comprising a temperature of 350-475° C. and a pressure of 2500-4500 kPa, with a catalyst comprising a mixture of a solid acid catalyst and a hydrodesulfurization catalyst,wherein said hydrodesulfurization catalyst comprises 1-30 wt-% of an element selected from Group 6 of the Periodic Table of Elements based on the total weight of the hydrodesulfurization catalyst, and 0.1-10 wt-% of an element selected from Groups 9 and 10 of the Periodic Table of Elements based on the total weight of the hydrodesulfurization catalyst and a solid catalyst support, and{'sub': 2', '2', '3, 'wherein said solid acid catalyst is comprises an aluminosilicate zeolite having a SiO/AlOmolar ratio of 50-120.'}2. The process according to claim 1 , wherein the element selected from Groups 9 and 10 of the Periodic Table of Elements is Co and/or Ni.3. The process according to claim 1 , wherein the element in the hydrodesulfurization catalyst is in sulfide form.4. The process according to claim 1 , wherein the hydrodesulfurization catalyst comprises one or more selected from the group consisting of CoMoS claim 1 , NiMoS claim 1 , NiWSand CoWS.5. The process according to claim 1 , wherein the solid acid catalyst comprises aluminosilicate zeolite having a 12-ring structure.6. The process according to claim 5 , wherein the aluminosilicate zeolite has super cages having a size of 12-14 Å.7. The process according to claim 5 , wherein the aluminosilicate zeolite is zeolite Y.8. The process according to claim 5 , wherein the ...

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24-04-2014 дата публикации

High rate reactor system

Номер: US20140109465A1
Принадлежит: Applied Research Associates Inc

A process and system for upgrading an organic feedstock including providing an organic feedstock and water mixture, feeding the mixture into a high-rate, hydrothermal reactor, wherein the mixture is rapidly heated, subjected to heat, pressure, and turbulent flow, maintaining the heat and pressure of the mixture for a residence time of less than three minutes to cause the organic components of the mixture to undergo conversion reactions resulting in increased yields of distillate fuels, higher-quality kerosene and diesel fuels, and the formation of high octane naphtha compounds. Hydrocarbon products are cooled at a rate sufficient to inhibit additional reaction and recover of process heat, and depressurizing the hydrocarbon products, and separating the hydrocarbon products for further processing. The process and system can include devices to convert olefinic hydrocarbons into paraffinic hydrocarbons and convert olefinic byproduct gas to additional high-octane naphtha and/or heavier hydrocarbons by one of hydrogenation, alkylation, or oligomerization.

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02-02-2017 дата публикации

OPTIMISATION OF THE USE OF HYDROGEN FOR HYDROTREATMENT OF HYDROCARBON FEEDSTOCKS

Номер: US20170029717A1
Принадлежит: IFP ENERGIES NOUVELLES

A process for the hydrotreatment of a hydrocarbon feedstock in which: 1. A process for the hydrotreatment of a hydrocarbon feedstock comprising sulphurous and nitrogenous compounds , in which the following steps are effected:{'b': 9', '400, 'a) at least one hydrotreatment step is implemented in which at least a part of said feedstock and a gaseous flow comprising hydrogen is brought into contact with at least one hydrotreatment catalyst to obtain a hydrotreated effluent (,) comprising hydrogen, and sulphurous and nitrogenous compounds;'}{'b': 9', '400', '23', '240', '11', '600, 'b) gas/liquid separation of said hydrotreated effluent (,) obtained in step a) is implemented to produce at least one first gaseous effluent (,) and at least one first liquid effluent (,);'}{'b': 11', '600', '11', '600', '41', '410', '43', '430, 'c) the first liquid effluent (,) obtained in step b) is expanded to a pressure of between 0.5 and 4 MPa and said first liquid effluent (,) is separated to obtain at least one second gaseous effluent (,) comprising hydrogen and sulphurous and nitrogenous compounds, and at least one second liquid effluent (,);'}{'b': 41', '410', '41', '410', '49', '490', '45', '450, 'd) said second gaseous effluent (,) obtained in step c) and comprising hydrogen and sulphurous and nitrogenous compounds is cooled and then separation of said second gaseous effluent (,) is effected to obtain at least one third gaseous effluent (,) comprising hydrogen, sulphurous and nitrogenous compounds and at least one third liquid effluent (,); and'}{'b': 49', '490, 'e) at least a part of said third gaseous effluent (,) obtained in step d) comprising hydrogen and sulphurous and nitrogenous compounds is recycled to step a) as a gaseous flow comprising hydrogen provided to step a).'}230301. A process according to characterised in that in step e) said part of said third gaseous effluent is mixed with a gaseous hydrogen make-up flow ( claim 1 ,).3. A process according to characterised in ...

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04-02-2016 дата публикации

Vapor Phase Catalytic Reactor for Upgarde of Fuels Produced by Fast Pyrolysis of Biomass

Номер: US20160032196A1
Принадлежит:

Vapor phase catalytic reactors and methods for using the same for upgrade of fuels produced by fast pyrolysis of biomass are disclosed. 1103-. (canceled)104. A biofuel production system , comprising:a catalytic vapor phase reactor (VPR);a pyrolysis reactor operatively connected to the catalytic VPR;a quench system operatively connected to the catalytic VPR;a water gas shift reactor operatively connected to the quench system; anda hydrotreatment system operatively connected to the quench system.1051. The biofuel production system of claim , the pyrolysis reactor being configured to pyrolyze a biomass to produce a pyrolysis vapor and char , the system further comprising a char removal system configured to remove the char from the pyrolysis reactor.1061. The biofuel production system of claim , further comprising a heater operatively coupled to the pyrolysis reactor , the heater being configured to at least one of internally and externally heat pyrolysis reactor to a temperature between about 300° C. and about 600° C.107. The biofuel production system of claim 106 , the heater comprising one or more of a resistive heating element claim 106 , a combustor claim 106 , a heat exchanger claim 106 , or a microwave generator.1081. The biofuel production system of claim claim 106 , the catalytic VPR comprising a catalyst comprising one or more of: a granulated catalyst; a powdered catalyst; a fluid catalytic cracking catalyst (FCC); fresh FCC; spent FCC; catalyst impregnated on top of the fresh FCC; catalyst impregnated on top of the spent FCC;the granulated catalyst characterized by a granule size between about 50 μm and about 100 μm;the granulated catalyst characterized by a size distribution of granules, a substantial fraction of the size distribution being greater than about 20 μm; anda catalyst selected to catalyze at least one of: deoxygenation, cracking, water-gas shift, and hydrocarbon formation.1091. The biofuel production system of claim claim 106 , the pyrolysis ...

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17-02-2022 дата публикации

PROCESS AND PLANT FOR PRODUCING HYDROCARBONS WITH REDUCED CO2-FOOTPRINT AND IMPROVED HYDROGEN INTEGRATION

Номер: US20220049166A1
Принадлежит: Haldor Topsoe A/S

Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its HS content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size. 1. A process for producing a hydrocarbon product , said process comprising the steps of:i) passing a feedstock originating from a renewable source through a hydroprocessing stage for producing a main hydrotrotreated stream;{'claim-text': ['an aqueous stream,', 'a hydrogen-rich stream as a first recycle gas stream,', 'an off-gas stream comprising hydrocarbons,', 'and said hydrocarbon product, boiling at above 50° C.;'], '#text': 'ii) passing the main hydrotreated stream to a separation stage for producing:'}iii) passing the first recycle gas stream to the hydroprocessing stage;iv) passing the off-gas stream as a second recycle gas stream to a hydrogen producing unit for producing a hydrogen stream as a make-up hydrogen stream; andv) passing the make-up hydrogen stream to the hydroprocessing stage;{'sub': '2', '#text': 'wherein prior to conducting step iv), said off-gas stream passes to a separation stage for removing HS and thereby producing said second recycle gas stream.'}2. Process according to claim 1 , wherein the process further comprises: vi) splitting said hydrogen-rich stream into said first recycle gas stream and a third recycle gas stream claim 1 , and passing said third recycle gas stream to said hydrogen producing unit.3. Process ...

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31-01-2019 дата публикации

PROCESS AND APPARATUS FOR RECOVERING HYDROGEN FROM RESIDUE HYDROPROCESSING

Номер: US20190031965A1
Принадлежит:

A membrane unit is able to recover hydrogen from a resid waste gas stream. Two membrane units provide even greater hydrogen recovery. The membrane separation is performed at conditions that allow the pressure of the recovered hydrogen to enter into a second stage of compression, saving the expense of the first stage of compression. 1. A process for hydroprocessing a hydrocarbon resid stream comprising:hydroprocessing a resid stream in the presence of hydrogen and a hydroprocessing catalyst to provide a hydroprocessed resid stream;separating said hydroprocessed resid stream to provide a vapor stream comprising hydrogen and methane and a liquid stream;taking a purge vapor stream from said vapor stream;feeding said purge vapor stream to a membrane unit comprising a membrane and contacting said vapor stream on one side of the membrane to allow more of the hydrogen to diffuse through the membrane than the methane; andremoving from an opposite side of the membrane a permeate stream comprising a higher concentration of hydrogen than a concentration of hydrogen in said vapor stream.2. The process of wherein said membrane unit is a first membrane unit and the permeate stream is a first permeate stream and further comprising removing a first retentate stream from said one side of said membrane comprising a higher concentration of methane than a concentration of methane in said purge vapor stream and feeding said first retentate stream to a second membrane unit comprising a second membrane and contacting said first retentate stream on one side of the second membrane to allow more of the hydrogen to diffuse through the second membrane than the methane; and removing from an opposite side of the second membrane a second permeate stream comprising a higher concentration of hydrogen than a concentration of hydrogen in said first retentate stream.3. The process of further comprising feeding said first permeate stream to a compressor.4. The process of further comprising feeding said ...

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31-01-2019 дата публикации

METHOD FOR CONVERTING HEAVY OIL BY MEANS OF HIGH ASPHALTENE DISPERSION

Номер: US20190031966A1
Принадлежит:

The present invention relates to a method for converting heavy oil by means of high dispersion of asphaltenes, comprising the steps of: preparing a mixture by mixing an amphiphilic additive and the heavy oil; and performing a hydrogenation reaction on the mixture, wherein the amphiphilic additive comprises both a polar group and a nonpolar group. 1. A method for converting heavy oil by means of high dispersion of asphaltenes , comprising the steps of:preparing a mixture by mixing an amphiphilic additive and the heavy oil; andperforming a hydrogenation reaction on the mixture, wherein the amphiphilic additive comprises both polar and non-polar functional group.2. The method of claim 1 , wherein:the dipole moment of the polar group is greater than or equal to 1.1 Debye (D);the dipole moment of the non-polar group is less than or equal to 0.5 Debye (D); andthe net dipole moment of the amphiphilic additive is greater than or equal to 0.6 Debye (D).3. The method of claim 2 , wherein the amphiphilic additive is in the form of a polymer having a number average molecular weight of 100 to 500 claim 2 ,000.4. The method of claim 3 , wherein the polar group comprises at least one selected from amine claim 3 , imide claim 3 , amide claim 3 , alcohol claim 3 , phenol claim 3 , ester claim 3 , and methacrylate; and the non-polar group comprises a polymer induced from any one or combination of ethylene claim 3 , propylene claim 3 , isobutylene claim 3 , diene claim 3 , and styrene.5. The method of claim 2 , wherein the amphiphilic additive is used in an amount of 0.01 wt % to 5 wt % in the mixture.6. The method of claim 2 , wherein the amphiphilic additive comprises at least one from polyisobutylene succinimide claim 2 , polyisobutylene phenol-based dispersant claim 2 , and polyacrylic-based dispersant.7. The method of claim 2 , wherein the amphiphilic additive comprises a product obtained from a bottom stream in which waste oil is distilled.8. The method of claim 7 , further ...

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11-02-2016 дата публикации

METHOD AND APPARATUS FOR IMPROVING HYDROGEN UTILIZATION RATE OF HYDROGENATION APPARATUS

Номер: US20160038854A1
Принадлежит:

A method and apparatus for improving a hydrogen utilization rate in a hydrogenation hot high-pressure separation process. Hydrogenated distillate oil, a gas product and hydrogen pass through an inertia separation distributor arranged in an inlet of a hot high-pressure separator under high pressure for preliminary gas-liquid separation, and a gas phase goes to a subsequent system; a liquid phase goes into a hot low-pressure separator. Releases a part of low-pressure separated gas (mainly hydrogen) after preliminary separation through an injection flash separator in the hot low-pressure separator, and is divided into a gas phase and a liquid phase based on gravitational settling; hydrogen and some micro bubbles that are still dissolved in hot low-pressure separated oil under the pressure are separated from the oil through a centrifugal degassing device; the gas phase exits from the apparatus after carried liquid droplets are removed completely through hydrocyclone separation or coalescence separation, and distillate oil goes to a subsequent facility. 1. A method for improving the hydrogen utilization in a hydrogenation high pressure hot separation process , characterized in that , it comprises the following steps:Step 1: distillate oil and hydrogen mixture undergo high pressure separation, comprising the following steps:Step 1.1: the distill oil and hydrogen mixture undergoes inertial separation of distribution to realize initial gas-liquid separation, and the gas-liquid mixture after separation is radially uniformly distributed in a hot high-pressure separator, wherein the pressure drop of the inertial separation is 0.0001-0.01 MPa;Step 1.2: the gas-liquid mixture after inertia separation undergoes a second gas-liquid separation via gravity settling;Step 2: the liquid phase after high pressure separation undergoes hot low-pressure separation, comprising the following steps:Step 2.1: the gas phase dissolved in the liquid phase is separated via jet flash, wherein the ...

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09-02-2017 дата публикации

Process for rejuvenating hydrotreating catalysts

Номер: US20170036196A1
Принадлежит: Catalyst Recovery Europe SA

The invention refers to a process for rejuvenating a hydrotreating catalyst comprising a group VIB hydrogenation metal and/or a group VIII hydrogenation metal, which comprises the steps of: (a) regenerating the catalyst by contacting said catalyst with an oxygen containing gas at a temperature from about 300° C. to 550° C. to obtain a regenerated carbon-reduced catalyst, (b) impregnating the regenerated carbon-reduced catalyst with a solution which consists of a mixture of water and citric acid, (c) aging the impregnated catalyst for at least 6 hours and (d) drying the aged catalyst. The invention also refers to the rejuvenated catalyst obtained and its use for hydrotreating hydrocarbon feedstocks.

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09-02-2017 дата публикации

PROCESS FOR REJUVENATING HYDROTREATING CATALYST

Номер: US20170036202A1
Принадлежит: CATALYST RECOVERY EUROPE S.A.

The invention refers to a process for rejuvenating a hydrotreating catalyst comprising a group VIB hydrogenation metal and/or a group VIII hydrogenation metal, which comprises the steps of: (a) regenerating the catalyst by contacting said catalyst with an oxygen containing gas at a temperature from about 300° C. to 550° C., (b) impregnating the regenerated carbon-reduced catalyst with an impregnation solution which comprises a mixture of water and a combination of MoOand HPO, (c) aging the impregnated catalyst and (d) drying the aged catalyst. The invention also refers to the rejuvenated catalyst obtained and its use for hydro-treating hydrocarbon feedstocks. 1. A process for rejuvenating a hydrotreating catalyst comprising a group VIB hydrogenation metal and/or a group VIII hydrogenation metal , which comprises the steps of:a) regenerating the catalyst by contacting said catalyst with an oxygen containing gas at a temperature from about 300° C. to 550° C.,{'sub': 3', '3', '4, 'b) impregnating the regenerated carbon-reduced catalyst with an impregnation solution comprising a mixture water and a combination of MoOand HPO,'}c) aging the impregnated catalyst andd) drying the aged catalyst.2. The process according to claim 1 , wherein the temperature of the drying step d) is comprised from 80° C. to 200° C. and preferably is about 120° C.3. The process according to any of the preceding claims claim 1 , wherein the content of carbon at the end of the regeneration step a) is inferior to 0.5 wt % based on the total weight of the catalyst.4. The process according to any of the preceding claims claim 1 , wherein the concentration of MoOis comprised from 0.10 mol of MoO/mol of hydrogenation metals to 1.0 mol of MoO/mol of hydrogenation metals.5. The process according to any of the preceding claims claim 1 , wherein the concentration of HPOis comprised from 0.10 mol of HPO/mol of hydrogenation metals to 1.0 mol of HPO/mol of hydrogenation metals.6. The process according to any ...

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08-02-2018 дата публикации

Portable fuel synthesizer

Номер: US20180036709A1
Принадлежит: Portable Gtl Systems LLC

A portable fuel synthesizer, comprising multiple shipping containers, the various modules within one of the multiple shipping containers, a boiler utilizing a hydrocarbon gas as fuel, a cooling system module connected to the boiler, the cooling system adjusts a temperature of the boiler, a syngas reformer, a reactor connected to the syngas reformer and the boiler, the reactor converts the syngas to a hydrocarbon liquid, a hot separator connected to the reactor, a cold separator connected to the hot separator separates liquid hydrocarbons and gaseous hydrocarbons at a lower temperature and pressure than the hot separator, a distillation unit connected to the cold separator performs fractional distillation and separation of hydrocarbon products received from the cold separator, a recycle module connected to the cold separator and distillation unit recycles unreacted gases to the reactor, and a fuel testing and blending unit to receive separated hydrocarbons from the distillation unit.

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11-02-2016 дата публикации

CONVERSION OF TRIACYLGLYCERIDES-CONTAINING OILS TO HYDROCARBONS

Номер: US20160040078A1
Принадлежит:

A process for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels is disclosed. The process may include: reacting a triacylglycerides-containing oil-water-hydrogen mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides and recovering a reaction effluent comprising water and one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics; hydrotreating the reaction effluent to form a hydrotreated effluent. 1. A system for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels , the system comprising:a mixing device for mixing a triacylglycerides-containing oil feed with water to form an oil-water mixture;a mixing device for mixing the oil-water mixture with hydrogen to form a feed mixture;a hydrothermolysis reactor for reacting the feed mixture at a temperature in the range of 250° C. to about 525° C. and a pressure greater than about 75 bar to produce a reaction effluent;a hydrotreater for hydrotreating the reaction effluent;a separator for separating water and hydrogen from hydrocarbons in the hydrotreated effluent.2. The system of claim 1 , further comprising one or more fluid conduits for recycling the hydrogen to the mixing device for mixing hydrogen.3. The system of claim 1 , further comprising a feed-effluent exchanger configured to preheat with feed mixture via indirect heat exchange with the reaction effluent.4. The system of claim 1 , wherein the hydrotreater comprises at least two catalyst beds claim 1 , and wherein:a first catalyst bed comprises a catalyst having hydrogenation activity;a second catalyst bed comprises a catalyst having hydrocracking activity.5. The system of claim 1 , wherein the catalyst bed proximate an inlet of the hydrotreater comprises a catalyst useful for at least one of:decarboxylation;{'b': 5 ...

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11-02-2016 дата публикации

Systems and Methods for Renewable Fuel

Номер: US20160040080A1
Принадлежит:

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom. 120-. (canceled)21. A method of upgrading a crude oil , comprising: co-processing the crude oil and an unenriched renewable fuel oil as reactants in a field upgrader system , said field upgrader system comprising a hydrotreater.22. The method of claim 21 , wherein the unenriched renewable fuel oil is 0.05-20 wt. % of the reactants and the crude oil is 80-99.95 wt. % of the reactants.23. The method of claim 21 , wherein the unenriched renewable fuel oil is the product of a mechanical and thermal conversion of a cellulosic biomass comprising grinding and non-catalytic rapid thermal processing.24. The method of claim 23 , wherein the non-catalytic thermal processing of the cellulosic biomass converts at least 60 wt. % of the cellulosic biomass to the unenriched renewable fuel oil.25. The method of claim 24 , wherein the unenriched renewable fuel oil comprises: a carbon content of at least 40 wt. % on a moisture-free basis claim 24 , an oxygen content in the range of between 20-50 wt. % on a moisture-free basis claim 24 , and a water content in the range of between 10-40 wt. %.26. The method of claim 25 , wherein the unenriched renewable fuel oil is 0.05-20 wt. % of the reactants and the crude oil is 80-99.95 wt. % of the reactants.27. The method of claim 21 , wherein the crude oil is derived from West Canadian oil sands.28. The method of claim 21 , ...

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09-02-2017 дата публикации

HYDROPROCESSING METHOD WITH HIGH LIQUID MASS FLUX

Номер: US20170037325A1
Принадлежит:

In a method of hydroprocessing, hydrogen gas for the hydroprocessing reaction is combined with a liquid feed composition comprising a feedstock to be treated and a diluent to form a feed stream, at least a portion of the hydrogen gas being dissolved in the liquid feed composition of the feed stream, with non-dissolved hydrogen gas being present in the feed stream in an amount of from 1 to 70 SCF/bbl of the liquid feed composition. The feed stream is contacted with a hydroprocessing catalyst, within a reactor while maintaining a liquid mass flux within the reactor of at least 5000 lb/hr-ftto form a hydroprocessed product. 1. A method of hydroprocessing comprising:combining hydrogen gas for the hydroprocessing reaction with a liquid feed composition comprising a feedstock to be treated and a diluent to form a feed stream, at least a portion of the hydrogen gas being dissolved in the liquid feed composition of the feed stream, with non-dissolved hydrogen gas being present in the feed stream in an amount of from 1 SCF to 70 SCF per bbl of the liquid feed composition; and{'sup': '2', 'contacting the feed stream with a hydroproces sing catalyst within a reactor while maintaining a liquid mass flux within the reactor of at least 5000 lb/hr·ftto form a hydroprocessed product.'}2. The method of claim 1 , wherein:the feedstock comprises at least one of a petroleum feedstock, a non-petroleum feedstock, a bio oil, a pyrolysis oil, a high-contaminant feedstock, and a high-olefinic feedstock.3. The method of claim 1 , wherein:the feed stream is contacted with a hydroproces sing catalyst contained in at least two catalyst beds within the reactor.4. The method of claim 1 , wherein:the non-dissolved hydrogen gas in the feed stream is present in an amount of from 1 SCF to 50 SCF per bbl of the liquid feed composition.5. The method of claim 1 , wherein:{'sup': 2', '2, 'the liquid mass flux within the reactor is maintained at from 5000 lb/hr·ftto 100,000 lb/hr·ft.'}6. The method of ...

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09-02-2017 дата публикации

METHOD, APPARATUS AND CHEMICAL PRODUCTS FOR TREATING PETROLEUM EQUIPMENT

Номер: US20170037327A1
Автор: FERRARA Marcello
Принадлежит:

The present invention provides a method, an apparatus and chemical products for treating petroleum equipment wherein a fluid is flowing, preferably of the hydrocarbon type, and wherein treating is performed by establishing a closed or semi-closed flow circulation loop, during the normal production operations of the equipment. The treatment can refer to the cleaning of equipment, to yield improvement as compared to normal run conditions and/or to a reduction of coke formation and/or to coke removal on catalysts. 1. A method for treating a petroleum plant or equipment of the petroleum plant during a running of the petroleum plant , comprising:maintaining, during a treatment period, the petroleum plant under a production operating condition, typical of the plant itself, which includes providing fresh feed to the petroleum plant;while maintaining the petroleum plant under the production operating condition, there is carried out one or both of a) and b);a) introducing in the petroleum plant, during the treatment period, a hydrocarbon-based treatment fluid;b) varying an established feed rate, present at initiation of the treatment of the petroleum plant or equipment of the petroleum plant, which established feed rate ranges from a maximum operation rate for the petroleum plant, which is inclusive of a design rate for the petroleum plant, to a minimum operation rate which is set at a level for satisfying a minimum production operating state in the petroleum plant;wherein said introduction of a hydrocarbon-based treatment fluid and/or said variation to the treatment feed rate generates an additional source or sources for distillation with respect to the amount provided by the established rate; anddistilling said additional source or sources for distillation for the purpose of plant treatment.2. The method of wherein the additional source or sources of distillate generated by the variation to the treatment feed rate is fed into the current fresh feed of the plant as the ...

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12-02-2015 дата публикации

Hydrotreating process and apparatus relating thereto

Номер: US20150041365A1
Принадлежит: UOP LLC

One exemplary embodiment can be a process for treating a hydroprocessing fraction. The process can include obtaining a bottom stream from a fractionation zone, and passing at least a portion of the bottom stream to a film generating evaporator zone for separating a first stream containing less heavy polynuclear aromatic compounds than a second stream.

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24-02-2022 дата публикации

Supported Hydrotreating Catalysts Having Enhanced Activity

Номер: US20220055024A1
Принадлежит:

This invention provides supported catalysts comprising a carrier, phosphorus, at least one Group VI metal, at least one Group VIII metal, and a polymer. In the supported catalyst, the molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12, the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, and the polymer has a carbon backbone and comprises an amido group. Also provided are a process for preparing such supported catalysts, as well as methods for hydrotreating, hydrodenitrogenation, and/or hydrodesulfurization, using supported catalysts. 1. A supported catalyst comprising a carrier , phosphorus , at least one Group VI metal , at least one Group VIII metal , and a polymer , wherethe molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12,the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, andthe polymer has a carbon backbone and comprises an amido group.2. A supported catalyst as in wherein:said carrier is carbon, carbon in combination with one or more inorganic oxides, boria, titania, silica, alumina, silica-alumina, alumina with silica-alumina dispersed therein, alumina-coated silica, silica-coated alumina, alumina containing boron, alumina containing silicon, alumina containing titanium, or a combination of any two or more of these;the polymer is polyacrylamide, polymethacrylamide, poly(N-isopropyl)acrylamide, poly(N-hydroxymethyl)acrylamide, poly(N-hydroxyethyl)acrylamide, poly(N-methoxymethyl)acrylamide, poly(N-ethoxymethyl)acrylamide, or a co-polymer of any two or more of the foregoing; and/orsaid Group VI metal is molybdenum and/or tungsten, and/or wherein said Group VIII metal is nickel and/or cobalt.3. A supported catalyst as in wherein the polymer is polyacrylamide.4. A supported catalyst as in wherein the molar ratio of phosphorus to Group VI metal is about 1:2.5 to less than about 1:12 claim 1 , and/or wherein the catalyst has a ...

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07-02-2019 дата публикации

NICKEL CONTAINING MIXED METAL-OXIDE/CARBON BULK HYDROPROCESSING CATALYSTS AND THEIR APPLICATIONS

Номер: US20190039052A1
Принадлежит:

The current invention relates a bulk catalyst precursor (i.e. no support material is added as such) comprising Ni and Mo and/or W and an organic component, wherein the molar ratio of C:(Mo+W) ranges from 1.5 to 10. The bulk catalyst precursor is prepared from a mixture of metal-precursors with an organic agent. The organic agent is partly decomposed to form a mixed metal-oxide/C phase which is in effect the bulk catalyst precursor. This bulk catalyst precursor (i) is effectively insoluble in water (ii) does not have any appreciable pore volume or surface area and (iii) does not contain a (nano)crystalline metal-oxide phase as characterized by XRD. A bulk catalyst is made from the bulk catalyst precursor. 1. A NiW , NiMo or NiMoW bulk catalyst precursor composition comprising nickel oxide , and molybdenum oxide or tungsten oxide or mixtures thereof , and an organic component prepared from an organic additive , wherein the total amount of molybdenum oxide and tungsten oxide is at least 30 wt % , the molar ratio of nickel to molybdenum plus tungsten is higher than 0.05 , the molar ratio of carbon to molybdenum plus tungsten is between 1.5 and 10; and wherein the organic additive is selected from Acetic acid , Aspartic acid , Citric acid , Formic acid , Fumaric acid , Gluconic acid , Glutamic acid , Glyoxylic acid , Ketoglutaric acid , Maleic acid , Malic acid , Oxaloacetic acid , Propionic acid , Pyruvic acid , Succinic acid , Fructose , Glucose , Lactose , Saccharose , Sorbitol , Xylitol , Serine and mixtures thereof.2. The bulk catalyst precursor of further comprising a BET-SA as measured by Nphysisorption of <40 m/g.3. The bulk catalyst precursor of further comprising Ni-crystals detected by transmission electron microscopy technique (TEM).4. The bulk catalyst precursor of further comprising a peak at 45° 2 theta in a XRD pattern recorded using X-ray radiation with a wavelength of 1.54 Å.5. The bulk catalyst precursor of characterized by the absence of any peaks ...

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24-02-2022 дата публикации

SULFER REDUCTION METHODS AND SYSTEMS

Номер: US20220056347A1
Принадлежит:

Methods and systems for reducing sulfur content in crude oil are provided. The methods and systems apply a first alkaline aqueous solution to crude oil to produce alkaline-treated crude oil, apply an acid aqueous solution to the alkaline-treated crude oil to produce acid-treated crude oil, apply a second alkaline aqueous solution to the acid-treated crude oil to produce neutralized crude oil; and separate residual water that contains sulfur from the neutralized crude oil to produce treated crude oil that has less sulfur content than the crude oil before the treatment. 1. A method for reducing sulfur content in crude oil comprising:applying a first alkaline aqueous solution to crude oil to produce alkaline-treated crude oil having an aqueous solution pH higher than 7.0;applying an acid aqueous solution to the alkaline-treated crude oil to produce acid-treated crude oil having an aqueous solution pH lower than 7.0;applying a second alkaline aqueous solution to the acid-treated crude oil to produce neutralized crude oil having an aqueous solution pH about 7.0; andseparating residual water that contains sulfur from the neutralized crude oil to produce treated crude oil,wherein at least one of the first alkaline aqueous solution, the acid aqueous solution, and the second alkaline aqueous solution comprises a metal ion catalyst, andwhereby the treated crude oil contains less sulfur content than the crude oil.2. The method of further comprises recovering and recycling at least one of the first alkaline aqueous solution claim 1 , the acid aqueous solution claim 1 , and the second alkaline aqueous solution.3. The method of further comprises supplying compressed air to a location where at least one of the alkaline-treated crude oil claim 1 , the acid-treated crude oil and the neutralized crude oil is being formed.4. The method of further comprises supplying metal ions to a location where at least one of the alkaline-treated crude oil claim 1 , the acid-treated crude oil and ...

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24-02-2022 дата публикации

PROCESS FOR THE HYDROSULFURIZATION OF SULFUR-CONTAINING OLEFINIC GASOLINE CUTS USING A REGENERATED CATALYST HAVING AN ORGANIC COMPOUND

Номер: US20220056348A1
Принадлежит: IFP ENERGIES NOUVELLES

The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a rejuvenated catalyst are brought into contact, said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 hand a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII, at least one metal from group VIb, an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur. 1. A process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut , hydrogen and a rejuvenated catalyst are brought into contact , said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C. , a total pressure of between 1 and 3 MPa , an hourly space velocity , defined as being the flow rate by volume of feedstock relative to the volume of catalyst , of between 1 and 10 hand a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l , said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII , at least one metal from group VIb , an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur.2. The process as claimed in claim 1 , in which the organic compound containing oxygen and/or nitrogen and/or sulfur is chosen from a compound comprising one or more chemical functional groups chosen from a carboxylic claim 1 , alcohol claim 1 , thiol claim 1 , thioether claim 1 , sulfone claim 1 , sulfoxide claim 1 , ether claim 1 , aldehyde claim 1 , ketone claim 1 , ester claim 1 , carbonate ...

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24-02-2022 дата публикации

Reactivated Hydroprocessing Catalysts for Use in Sulfur Abatement

Номер: US20220056349A1
Принадлежит:

Disclosed herein are methods, systems, and compositions for providing catalysts for tail gas clean up in sulfur recovery operations. Aspects of the disclosure involve obtaining catalyst that was used in a first process, which is not a tailgas treating process and then using the so-obtained catalyst in a tailgas treating process. For example, the catalyst may originally be a hydroprocessing catalyst. A beneficial aspect of the disclosed methods and systems is that the re-use of spent hydroprocessing catalyst reduces hazardous waste generation by operators from spent catalyst disposal. Ultimately, this helps reduce the environmental impact of the catalyst life cycle. The disclosed methods and systems also provide an economically attractive source of high-performance catalyst for tailgas treatment, which benefits the spent catalyst generator, the catalyst provider, and the catalyst consumer. 1. A method of forming a reactivated catalyst for a tailgas treating process , the method comprising:obtaining a spent catalyst from a hydrotreating process, andreactivating the catalyst to form the reactivated catalyst, wherein{'sub': 2', '2', '2', '2, 'the reactivated catalyst, when contacted with a gas stream comprising one or more sulfur-containing species selected from the group consisting of elemental sulfur (Sx), sulfur dioxide (SO), carbonyl sulfide (COS), and carbon disulfide (CS), is capable of catalyzing the conversion of the one or more sulfur-containing species to hydrogen sulfide (HS) in the presence of hydrogen (H).'}2. The method of claim 1 , wherein the hydrotreating process is selected from the group consisting of petroleum hydrotreating processes claim 1 , hydrodesulfurization (HDS) claim 1 , hydrodenitrogenation (HDN) claim 1 , hydrogenation claim 1 , hydrodemetallization (HDM) claim 1 , naphtha hydrotreating (NHT) claim 1 , diesel hydrotreating (DHT) claim 1 , kerosene hydrotreating (KHT) claim 1 , jet fuel hydrotreating (JHT) claim 1 , atmospheric gas oil ...

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