Use of tetrahydrobenzoxazines as stabilisers

The use of tetrahydrobenzoxazines I where R 1 is a hydrocarbyl radical and R 2 , R 3 , R 4 and R 5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R 2 to R 5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

Use of tetrahydrobenzoxazines as stabilisers

The use of tetrahydrobenzoxazines I where R 1 is a hydrocarbyl radical and R 2 , R 3 , R 4 and R 5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R 2 to R 5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

Asphaltene inhibition

The technology disclosed herein provides compositions and methods for asphaltene control in a hydrocarbon fluid, such as crude oil, by employing a thiophosphonate ester compound.

Use of tetrahydrobenzoxazines as stabilisers

The use of tetrahydrobenzoxazines I where R 1 is a hydrocarbyl radical and R 2 , R 3 , R 4 and R 5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R 2 to R 5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

USE OF TETRAHYDROBENZOXAZINES AS STABILISERS

The use of tetrahydrobenzoxazines I 110-. (canceled)12: The composition according to wherein the remaining substituents from the group or R claim 11 , R claim 11 , R claim 11 , Rwhich are not polyisobutenyl radicals having a number-average molecular weight Mof from 900 to 1 claim 11 ,100 are each independently a hydrogen atom claim 11 , a hydroxyl group or a linear or branched C- to C-alkyl radical.13: The composition according to wherein the polyisobutenyl radical incorporated into the tetrahydrobenzoxazine I comprises at least 50 mol % of terminal double bonds based on the total number of polyisobutene macromolecules.14: The composition according to wherein the polyisobutenyl radical incorporated into the tetrahydrobenzoxazine I has a polydispersity index (PDI) of from 1.05 to 10.15: The composition according to wherein the polyisobutenyl radical incorporated into the tetrahydrobenzoxazine I is a polymer which is obtained by cationic polymerization and comprises claim 11 , in copolymerized form claim 11 , at least 60% by weight of isobutene and in addition may comprise claim 11 , in copolymerized form claim 11 , further butene isomers such as 1- or 2-butene claim 11 , and also different olefinically unsaturated monomers which are copolymerizable with isobutene under cationic polymerization conditions.16: The composition according to comprising a compound (A) wherein the compound (A) is a succinic anhydride derivative having long-chain hydrocarbon radicals of from 15 to 700 carbon atoms with further functional groups which are selected from hydroxyl claim 11 , amino claim 11 , amido and/or imido groups.17: The composition according to comprising a compound (A) wherein the compound (A) is a derivative of polyalkenylsuccinic anhydride which is obtained by reacting polyalkenes with maleic anhydride by a thermal route or via reaction with a chlorinated hydrocarbon.18: The composition according to comprising a compound (A) wherein the compound (A) is a derivative of a ...

Lubricating oil succinimide dispersants derived from heavy polyamine

A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal "ene" reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.

Dispersants based on succinimide additives derived from heavy polyamine used for lubricating oil

A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal 'ene' reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.

Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920)

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Borated ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Ethylene α-olefin/diene interpolymer-substituted carboxylic acid dispersant additives

The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene/alpha-olefin/diene interpolymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted interpolymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such s amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.

DISPERSANTS BASED ON SUCCINIMIDE ADDITIVES DERIVED FROM HEAVY POLYAMIDE USED FOR LUBRICATING OIL.

UN DISPERSANTE DE SUCCINIMIDA, QUE ES EL PRODUCTO DE REACCION DE HIDROCARBUROS O POLIMEROS FUNCIONALIZADOS POR HALOGENACION (P.EJ. CLORACION), REACCION "ENO" TERMICA O INJERTO DE RADICALES LIBRES, Y DERIVATIZADOS CON UNA POLIAMINA PESADA. UNA POLIAMINA PESADA ES UNA MEZCLA DE POLIALQUILENPOLIAMINAS, QUE COMPRENDE PEQUEÑAS CANTIDADES DE OLIGOMEROS DE POLIAMINAS INFERIORES, COMO TETRAETILEN PENTAMINA Y PENTAHEXIMINA, PERO PRINCIPALMENTE OLIGOMEROS CON 7 O MAS NITROGENOS, 2 O MAS AMINAS PRIMARIAS POR MOLECULA, Y RAMIFICACION MAS EXTENSA QUE EN LAS MEZCLAS DE POLIAMINAS CONVENCIONALES. A SUCCINIMIDE DISPERSANT, WHICH IS THE PRODUCT OF REACTION OF HYDROCARBONS OR POLYMERS FUNCTIONALIZED BY HALOGENATION (eg CHLORATION), REACTION "ENO" THERMAL OR GRAFTING OF FREE RADICALS, AND DERIVATIZED WITH A HEAVY POLYAMINE. A HEAVY POLYAMINE IS A MIXTURE OF POLYALKYLENE POLYAMINES, WHICH INCLUDES SMALL AMOUNTS OF LOWER POLYAMINE OLIGOMERES, SUCH AS TETRAETILEN PENTAMINE AND PENTAHEXIMINE, MAINLY MAJOR OLIGOMERS WITH 7 OR MORE NITROGEN MASTERS, AND MORE OF CONVENTIONAL POLYAMINS.

Continuous process for production of functionalized olefins

A continuous process for functionalizing olefins, especially polymer olefins in a CSTR or pipe reactor. Esters are preferably produced by continuous reaction of the olefin with carbon monoxide and a nucleophilic trapping agent. The liquid-filled pipe reactor operates in plug flow with static mixers and the CSTR is operated in the substantial absence of air at constant liquid level.

Functionalization of polymers based on Koch chemistry and derivatives thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid lubricant dispersant additives

The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 10,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.

Ethylene alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives

The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene/alpha-olefin/diene interpolymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted interpolymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.

Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

Compounded lubricating oil

Ethylene α-olefin block copolymers and methods for production thereof

This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and is generally crystalline. The B block contains an ethylene, α-olefin copolymer segment and optionally contain an ethylene, α-olefin, non-conjugated diene terpolymer segment. If the B block contains a diene containing segment, the diene containing segment is furthest from the junction of the A and the B blocks. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, in bitumen blends, as a component in hot melt adhesives and as a component of roof sheeting compounds.

Mejoras en composicion de aditivos dispersante lubricadores a base de novedosos polimeros etilen alfa-olefinicos sustituidos con acidos mono y dicarboxilicos y proceso para producirlos

La presente invención se refiere a un aditivo para aceite lubricante que comprende un polímero de etilen-alfa-olefina, sustituído cuando menos por algún ácido monocarboxílico productor de porciones monoinsaturadas de C3-C10, y ácido bicarboxílico productor de porciones monoinsaturadas de C4-C10, dicho polímero comprende unidades de monómero, derivadas de etileno y cuando menos una alfa-olefina de la fórmula H2CCHR1, en donde R1 es un grupo alquilo con 1-18 átomos de C, y en donde dicho polímero tiene un número promedio de peso molecular, desde aproximadamente 300 a 10,000 y un promedio de cuando menos cerca de 30 por ciento de dichas cadenas polimericas, contienen una insaturación etenilidenica terminal y en donde dicho aditivo está caracterizado por tener un valor VR menor de aproximadamente 4.1.

Batch Koch carbonylation process

A rapid, batch Koch carbonylation/functionalization reaction of at least one polymer olefin, carbon monoxide, and an aliphatic or aryl alcohol in the presence of an acid catalyst with either an alcohol:polymer olefin mole ratio ≧1:1, or an acid catalyst:polymer olefin mole ratio ≧0.9:1, or both, and recovering at least 80% functionalized polymer which is predominantly ester.

Полимеры, функционализированные реакцией коха, и их производные

Функционализированный по Коху продукт, который является продуктом реакции по меньшей мере одного полимера со среднечисленной молекулярной массой по крайней мере 500 и по меньшей мере с одной этиленовой двойной связью на каждую полимерную цепь, с моноокисью углерода и нуклеофилулавливающим агентом. В объем изобретения включены функционализированный полимер, его производные и способы их получения.

Novel ethylene alpha-olefin polymers for use in preparing lubricant dispersant additives

The present invention is directed to a class of polymer comprising an ethylene alpha-olefin interpolymer having a set of chemical-physical properties rendering it particularly suitable as the 'polymer backbone' for production of dispersants of high active ingredient concentrations which active ingredients have improved properties. The ethylene alpha-olefin interpolymer of this invention comprises that class of ethylene alpha-olefin interpolymer which have a number average molecular weight of from about 300 to about 10,000; at least 90% of the polymer chains contain a unit of unsaturation and the ratio of ethenylidene (also termed a 'vinylidene') units, to ethenyl (also termed 'vinyl') units in the polymer composition is at least 3.5:1, preferably at least about 10:1.

Functionalization of polymers based on Koch chemistry and derivatives thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least one ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Derivatives of polyamines with one primary amine and secondary of tertiary amines

A dispersant derivatized from a functionalized hydrocarbon and a polyamine having one primary amine and 1-10, preferably 3-8 secondary or tertiary amines; preferably where said functionalized hydrocarbon is a Koch-derived hydrocarbon.

Functionalization of polymers based on Koch chemistry and derivatives thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Functionalization of polymers based on Koch chemistry and derivatives thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Functionalization of polymers based on Koch chemistry and derivatives thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least one ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Metal complexes of nitrogen compounds

Multiple metal complexes of nitrogen compounds are prepared by reacting in any desired order (1) an organic reactant, preferably an alkenylsuccinic acid or anhydride or a polyalkylphenol-aldehyde reaction mixture, or a halogenated polyolefin; (2) a polyamine, having one nitrogen atom reactive with the organic reactant and at least one additional nitrogen atom such as an ethylene polyamine and the imidazoline or imidazolidine derivative thereof; (3) and at least two metal compounds, one of which is a metal of Groups IB, IIB, IVA, IVB, VB, VIB, VIIB or VIII of the Periodic Table, capable of both forming a coordinated complex of the Werner type with the polyamine and also forming a complex with the second metal compound, and the said metal compound of metals of the above groups plus alkali and alkaline earth metals. The reactants may be reacted in any order, such as the above order, or the amine reactant may be precomplexed. Lubricant, grease, fuel and aqueous compositions are provided detergency and anti-wear properties by the presence of these multiple complexes.

乙烯α－烯烃嵌段共聚物以及它们的制备方法

本发明涉及到同时含有结晶和弹性体嵌段的嵌段共聚物，该嵌段共聚物有A嵌段和B嵌段。A嵌段为聚乙烯或非必须地含有α-烯烃的乙烯聚合物并且通常是结晶的。B嵌段含有乙烯、α-烯烃共聚物链段并且非必须地含有乙烯、α-烯烃、非共轭二烯三聚物链段。如果B嵌段含有包括二烯的链段，该包含二烯的链段距离A和B嵌段结合点最远。同时公开了制备嵌段共聚物的途径和偶联嵌段共聚物的方法。该偶联嵌段共聚物可用作显示接近那些交联的EP或EPDM弹性体物性但具有偶联后热可加工性的热塑弹性体。本发明的嵌段共聚物可用作润滑油或燃料添加剂、用作塑料共混物组分、用在沥青共混物、作为热熔胶的组分和屋顶板材化合物的组分。

Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

The present invention is directed to an oil-soluble fuel and lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful fuel and lubricating oil additives, e.g., as dispersants.

ETHYLENE α-OLEFIN BLOCK COPOLYMERS AND METHODS FOR PRODUCTION THEREOF

This invention relates to block polymers containing both cristalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and is generally crystalline. The B block contains an ethylene, α-olefin copolymer segment and optionally contain an ethylene, α-olefin, non-conjugated diene terpolymer segment. If the B block contains a diene containing segment, the diene containing segment is furthest from the junction of the A and the B blocks. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of cross-linked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, in bitumen blends, as a component in hot melt adhesives and as a component of roof sheeting compounds.

Acylated nitrogen compounds useful as additives for lubricating oil and fuel compositions

A process for reacting certain carboxylic reactants and at least one aldehyde or ketone with olefinic compounds then reacting the product prepared thereby with ammonia, a hydrazine or an amine, products prepared thereby and, additive concentrates, lubricating oil and fuel compositions.

Ethylene α-olefin block copolymers and a method for preparing the same (ETHYLENE ALPHA-OLEFIN BLOCK COPOLYMERS AND METHODS FOR PRODUCTION THEREOF)

본 발명은 A블록 및 B블록을 갖는 블록 공중합체, 결정성 및 탄성 중합체계 블록을 함유하는 블록 중합체에 관한 것이다. A블록은 선택적으로 α-올레핀을 함유하는 에틸렌 중합체 또는 폴리에틸렌이며, 일반적으로 결정성이다. B블록은 에틸렌, α-올레핀 공중합체 분절을 함유하며, 선택적으로 에틸렌, α-올레핀, 비-공액 디엔 삼원중합체 분절을 함유한다. B블록이 디엔 함유 분절을 함유하는 경우에, 디엔 함유 분절은 A와 B블록의 접합점으로부터 가장 멀리 떨어져 있다. 또한, 본 발명은 블록 공중합체의 제조방법 및 블록 공중합체의 결합방법에 관한 것이다. 결합된 블록 공중합체는, 가교결합된 EP 또는 EPDM에 근접한 물성을 나타내지만 결합 후 가공성을 나타내는 열가소성 탄성 중합체로서 유용하다. 또한, 본 발명의 블록 공중합체는 윤활제 또는 연료 첨가제로서, 역청질 블렌드내의 플라스틱 블렌드 성분으로서, 고온용융 접착제내의 성분으로서, 및 루프 시팅 화합물의 성분으로서 사용될 수도 있다.

Liquid multifunctional additives

Liquid multifunctional additives

Products are described which can be obtained by reacting components a), b), c) and optionally d), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II, component c) is a compound of the formula III (IIIa/IIIb) or a mixture of compounds of the formula III (IIIa/IIIb) and component d) is a compound of the formula IV or a mixture of compounds of the formula IV, (see formula I) (see formula II) (see formula IIIa) (see formula III) (see formula IIIb) (see formula IV) in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, rapeseed oil, coconut fat or castor oil, the compound of the formula IIIa being, for example, 3-tert-butyl-hydroxy-5-methyl-benzylsulfanyl-acetic acid-methylester and the compound of the formula IIIb, for example, 3,5-di-tert-butyl-4-hydroxybenzylsulfanyl-acetic acid-methylester and the compound of the formula IV, being for example, sulfur, diisopropyl dithiophosphate, toluoltriazols or (see formula V) The abovementioned products can be used as liquid antioxidants in fuels, polymers and lubricants and events which lead to friction increase in engines.

Use of tetrahydrobenzoxazines as stabilisers

FIELD: chemistry. SUBSTANCE: invention relates to use of tetrahydrobenzoxazines in which substitute R 1 denotes a hydrocarbyl residue having 1-3000 carbon atoms, and substitutes R 2 , R 3 , R 4 and R 5 independently denote hydrogen atoms, hydroxyl groups or hydrocarbyl residues, having 1-3000 carbon atoms, respectively, and in which substitutes R 3 and R 4 or R 4 and R 5 with a partial structure -O-CH 2 -NR 7 -CH 2 -, bonded to the benzene ring, can also form a second tetrahydrooxazine ring, where R 7 denotes hydrocarbyl residues having 1-3000 carbon atoms, provided that at least one of substitutes R 1 , R 2 , R3, R 4 , R 5 or R 7 are polyisobutenyl, having 3000 carbon atoms and the rest of the substitutes from the group R 1 , R 2 , R 3 , R 4 , R 5 or R 7 , if they denote hydrocarbyl residues, have 1-20 carbon atoms, respectively, as anti-oxidants for stabilising mineral oil and fuel products against the effect of light, oxygen and heat. The invention also describes jet fuel and jet fuel additive concentrate containing tetrahydrobenzoxazine of formula (I). EFFECT: preparation of stabilisers having improved stabilisation of nonliving organic material, particularly jet fuel against the effect of light, oxygen and heat. 9 cl, 14 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 412 234 (13) C2 (51) МПК C10L 1/22 (2006.01) C07D 265/16 (2006.01) C07D 498/04 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2008106666/04, 18.07.2006 (24) Дата начала отсчета срока действия патента: 18.07.2006 (73) Патентообладатель(и): БАСФ СЕ (DE) R U Приоритет(ы): (30) Конвенционный приоритет: 26.07.2005 DE 102005035527.7 (72) Автор(ы): ЛАНГЕ Арно (DE), МАХ Хельмут (DE), РАТ Ханс Петер (DE), ПОССЕЛЬТ Дитмар (DE) (43) Дата публикации заявки: 10.09.2009 Бюл. № 25 2 4 1 2 2 3 4 (45) Опубликовано: 20.02.2011 Бюл. № 5 2 4 1 2 2 3 4 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 26.02.2008 C 2 C ...

Polymers functionalised by koch reaction and derivatives thereof

본 발명은 적어도 500의 수 평균 분자량과 중합체 쇄당 적어도 하나의 에틸렌 이중 결합을 갖는 적어도 하나의 중합체를 일산화 탄소와 친핵성 포획제를 반응시켜 생성된 반응 생성물인 코흐 작용화된 생성물에 관한 것이다. 본 발명은 또한 작용화된 중합체, 그의 유도체 및 그의 제조 방법을 포함한다. The present invention relates to a Koch functionalized product which is a reaction product produced by reacting carbon monoxide and a nucleophilic capture agent with at least one polymer having a number average molecular weight of at least 500 and at least one ethylene double bond per polymer chain. The present invention also includes functionalized polymers, derivatives thereof and methods of making the same.

PROCESS FOR PREPARING NEW DETERGENTS

Patent FR2265771A1

Patent FR2281422B1

Functionalization of Polymers Based on Koch Chemistry and Derivatives Thereof

A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.

Process for the manufacture of additives soluble in petroleum oils

Lubricating oil

Process for the preparation of adducts for improving the properties of lubricating oils

Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid lubricant dispersant additives

The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 10,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.

Corrosion inhibitors

Gel additives for fuel that reduce soot and/or emissions from engines

使润滑油中烟灰的含量和/或发动机中的排放物减少的燃料用的添加剂凝胶。以及使用用于燃料系统中的燃料中的添加剂凝胶以减少发动机润滑油中烟灰的量和/或减少发动机的排放物的方法。

Process for the manufacture of additives soluble in petroleum oils

Improved fuels

Oils derived from hydrocarbons having improved tolerance to water

Substituted polyamines and their preparation process

Continuous process for production of functionalized olefins

A continuous process for functionalizing olefins, especially polymer olefins in a CSTR or pipe reactor. Esters are preferably produced by continuous reaction of the olefin with carbon monoxide and a nucleophilic trapping agent. The liquid-filled pipe reactor operates in plug flow with static mixers and the CSTR is operated in the substantial absence of air at constant liquid level.

Acylated nitrogen compounds useful as additives for lubricating oil and fuel compositions

DISCONTINUOUS COOKING CARBONYLATION PROCEDURE

Additive for lubricant or fuel, lubricating oil composition or fuel composition containing it, and novel substituted hydroxyaromatic ester derivative

There are herein disclosed an additive for a lubri-cant or a fuel which comprises at least one selected from the group consisting of substituted hydroxyaromatic ester derivatives represented by the general formulae (I) and (II) wherein R1 to R5 are each an organic group having 6 or more carbon atoms, a, b, d, e, k and m are from 1 to 3, c, f, g, i and j are from 0 to 3, and h is from 0 to 4, but (f+g) is from 1 to 3, and (h+i) is from 1 to 6, an additive composition for a lubricant or a fuel, and a lubricating oil composition or a fuel composition contain-ing the above-mentioned additive. The above-mentioned additive for the lubricant or the fuel is desirable as an ashless detergent excellent in high-temperature stability in place of a metal detergent, and the lubricating oil composition or the fuel composition containing this additive can suitably be used as the lubri-cant or the fuel for an internal combustion engine which can comply with future exhaust gas controls.

FUEL PRODUCTS.

FUEL PRODUCTS.

Ethylene/alpha-olefin block copolymers and methods for preparation thereof

FIELD: polymer production. SUBSTANCE: invention provides novel block copolymers including both crystalline and elastomer blocks and which, more specifically, consists of so called A and B blocks. The former includes ethylene polymer and its melting point is at least 110 C. The latter includes first polymer segment adjacent to A and B block joint location and containing ethylene and α-alpha-olefin units. B block includes tip segment most distanced from joint location and represents polymer of ethylene, C 3 -C 8 -alpha-olefin, and optionally unconjugated diene. Molar percentage of unconjugated diene units, if present, is up to 10% of total number of monomer units in block copolymers. Intramolecular distribution of constituents in B block is such that at least two fragments (5 wt % of B block each) differ from each other by at least 5 wt % in content of ethylene units. Associated block copolymers can be used as thermoplastic elastomers manifesting physical properties close to those of vulcanized elastomers but capable of being thermally processed after association. Block copolymers can also be used as lube oil and fuel additives, as plastic components, in bitumen mixtures, as components in glue melts, and as roof deck compound component. EFFECT: expanded application possibilities. 38 cl, 6 dwg, 13 tbl зЗ14зЗ6У7Ес ПЧ Го РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (19) (51) МПК? ВИ "” 2149 878 ' 13) СЛ С 08 Е 297/08, 4/68, С 10 1/18, 1/22, С 10 М 143/14 12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ (21), (22) Заявка: 96121911/04, 06.04.1995 (24) Дата начала действия патента: 06.04.1995 (30) Приоритет: 06.04.1994 Ш$ 08/223.873 (46) Дата публикации: 21.05.2000 (56) Ссылки: СВ 1175670 А, 23.12.1969. ЗЦ 1130573 А, 23.12.1984. $Ц 851240 А, 23.08.1981. \!О 86/037Ъ55 А, 03.07.1986. ЕР 0299608 А, 18.01.1989. ЕР 0515898 АЗ, 02.11.1992. ОЕ 2049491 А, 22.04.1971. Ц$ 4959436 А, 25.09.1990. ($ 4716207 А, 29.12.1987. ($ 4692268 А, 08.09.1987. СВ 1303014 А, 17.01.1973. ...

Hydrocarbonaceous fuel compositions and additives therefor

Hydrocarbonaceous fuels and additive compositions therefor which comprise: a) one or more fuel-soluble manganese carbonyl compounds; b) one or more fuel-soluble alkali or alkaline earth metal-containing neutral or basic detergent salts; and c) one or more fuel-soluble metal deactivators of the chelation type. These compositions preferably contain, in addition to components a), b) and c) above, one or more of the following: d) at least one fuel-soluble ashless dispersant; e) at least one fuel-soluble demulsifying agent; and f) at least one aliphatic or cycloaliphatic amine. Component c) enhances the stability of fuel compositions containing at least components a) and b). The compositions possess improved combustion characteris-tics (e.g., formation of less soot, smoke, carbonaceous products and/or noxious emissions), and form on combustion carbonaceous products of reduced acidity. The deposition of sludge on critical engine or burner parts or surfaces is reduced and the fuels have improved demulsibility characteristics. And the fuel compositions can result in decreased fuel consumption in diesel engines.

Phosphorylated and/or boronated dispersants as thermal stability additives for distillate fuels

The present invention relates to phosphorylated and/or boronated dispersants useful as thermal stability additives in distillate fuels, such as jet or diesel fuel, and fuel compositions containing said dispersants.

DISCONTINUOUS COOKING CARBONYLATION PROCEDURE

DISPERSING AGENT BASED ON AMERIC ACID IMID ADDITIVES FROM HEAVY POLYAMINE FOR USE IN LUBRICATING OILS

Patent JPS63500602A

(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。

Improved fuel oils

Improvements in or relating to lubricating oil additive having improved copper corrosion properties

Phospho-sulphurized metal salts of alkyl phenol sulphides are prepared by heating a sulphide of phosphorus in a mol. ratio of less than 0.25 : 1.0 at 100-200 DEG C. with a metal alkyl phenol sulphide containing less than 0.3 per cent by weight of water. The reaction may be conducted in a solvent such as a mineral oil or a hydrocarbon, such as xylol. The phosphorus sulphides specified are the pentasulphide (P2S5), the trisulphide (P4S3) or the heptasulphide (P4S7). The metal alkyl phenol sulphide may have the general formula <FORM:0755170/IV(a)/1> where R is one or more alkyl groups each containing from 5 to 25 carbon atoms such as t.-octyl- and t.-amyl-, M is a metal and x is an integer between 1 and 4. Metal alkyl phenol sulphides specified are those of alkaline-earth metals such as barium, calcium or strontium or of mixtures thereof such as calcium tert.-octyl phenol sulphide, barium-2:4-di-tert.-amyl phenol sulphide, strontium tert.-amyl phenol sulphide and the mixed calcium-barium tert.-octyl phenol sulphide. After the reaction with phosphorus sulphide, the reaction mixture is filtered and nitrogen is blown through at 100-120 DEG C. to remove unwanted products and to yield a solution of the product which may be added as an antioxidant and detergent to mineral oils and motor fuels (see Group III), to natural or synthetic rubber, asphalts, road oils and waxes (see Group V), and in organic materials generally. Examples illustrate the effect on the characteristics of the product of the use of various mol. ratios of phosphorus sulphide and metal alkyl phenol sulphide and of various degrees of dryness of the metal alkyl phenol sulphide. Metal alkyl phenol sulphides.-The metal alkyl phenol sulphides are prepared by adding the corresponding metal or metallic oxide, hydroxide or sulphide at an elevated temperature to a mineral oil solution of the alkyl phenol sulphide. The solution may contain sufficient higher alcohol as an anti-foaming agent to give a ...

Fuel products

ABSTRACT A fuel composition for internal combustion engines is disclosed. The composition comprises a major amount of a liquid hydrocarbon fuel, containing less than about 0.5 grams of lead per liter of fuel, and a minor amount of (A) at least one hydrocarbon-soluble alkaline metal or alkaline earth metal salt of a sulfur acid, a carboxylic acid or a phenol, (B) at least one hydrocarbon-soluble ashless dispersant, present an amount sufficient to reduce valve seat recession when the fuel is used in an internal combustion engine. Fuel compositions according to the invention act not only to control valve seat recession, but also to reduce and modify deposit formation, and thereby enhance engine combustion.

Fuel oil compositions

디젤 또는 제트연료에 거대환상 폴리아민, 특히 PIBSA 로부터 유도된 거대환상 폴리아민, 또는 하이드로카빌 폴리아민을 특히 유기 질산염 세탄 개선제와 함께 가하여 입자 배출을 감소시킨다. Macrocyclic polyamines, especially macrocyclic polyamines derived from PIBSA, or hydrocarbyl polyamines are added to diesel or jet fuels, in particular with organic nitrate cetane improvers to reduce particle emissions.

Stabilizing agents for hydrocarbon compositions and the like

Ethylene .alpha.-olefin block copolymers and methods for production thereof

This invention relates to block polymers containing both cristalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and is generally crystalline. The B block contains an ethylene, .alpha.-olefin copolymer segment and optionally contain an ethylene, .alpha.-olefin, non-conjugated diene terpolymer segment. If the B block contains a diene containing segment, the diene containing segment is furthest from the junction of the A and the B blocks. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of cross-linked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, in bitumen blends, as a component in hot melt adhesives and as a component of roof sheeting compounds.

HYDROCARBON FUEL COMPOSITIONS AND ADDITIVES FOR THEM.

COMPOSICIONES DE COMBUSTIBLES HIDROCARBONOSOS Y ADITIVOS PARA LOS MISMOS QUE CONSTAN DE: A) UNO O MAS COMPUESTOS CARBONIL MANGANESO COMBUSTIBLE-SOLUBLE; B) UNA O MAS SALES DETERGENTES NEUTRAS O BASICAS ALCALI O ALCALINA TERRESTRE COMBUSTIBLE-SOLUBLE QUE CONTENGAN METAL; Y C) UNO O MAS DESACTIVADORES METALICOS COMBUSTIBLE-SOLUBLE DEL TIPO QUELATIO. ESTAS COMPOSICIONES CONTIENEN PREFERIBLEMENTE, ADEMAS DE LOS COMPONENTES A), B) Y C) ANTES MENCIONADOS UNO O MAS DE LOS SIGUIENTES: D) AL MENOS UN DISPERSANTE SIN CENIZAS COMBUSTIBLE-SOLUBLE; E) AL MENOS UN AGENTE DEMULSIFICADOR COMBUSTIBLE-SOLUBLE; F) AL MENOS UNA AMINA ALIFATICA O CICLOALIFATICA. EL COMPONENTE C) AUMENTA LA ESTABILIDAD DE LAS COMPOSICIONES DE COMBUSTIBLE QUE CONTIENEN AL MENOS LOS COMPONENTES A) Y B) . LAS COMPOSICIONES POSEEN REFORZADAS CARACTERISTICAS DE COMBUSTION (V.GR. FORMACION DE MENOS HUMO, HOLLIN, PRODUCTOS CARBONOSOS Y/O EMISIONES NOCIVAS), Y GENERAN PRODUCTOS CARBONOSOS DE COMBUSTION DE ACIDEZ REDUCIDA. LA DEPOSICIONDE SEDIMENTOS EN MOTORES CRITICOS Y PARTES O SUPERFICIES QUEMADORAS SE REDUCE Y LOS COMBUSTIBLES AUMENTAN SUS CARACTERISTICAS EN ESTABILIDAD Y DEMULSIBILIDAD. Y LAS COMPOSICIONES DE COMBUSTIBLES PUEDEN RESULTAR EN UN MENOR CONSUMO DE COMBUSTIBLES EN LOS MOTORES DIESEL. COMPOSITIONS OF HYDROCARBON FUELS AND ADDITIVES FOR THE SAME CONSISTING OF: A) ONE OR MORE CARBONYL MANGANESE COMBUSTIBLE-SOLUBLE COMPOUNDS; B) ONE OR MORE NEUTRAL OR BASIC DETERGENT SALTS ALCALI OR ALKALINE TERRESTRIAL FUEL-SOLUBLE CONTAINING METAL; AND C) ONE OR MORE COMBUSTIBLE-SOLUBLE METALLIC DEACTIVATORS OF THE CHELATIO TYPE. THESE COMPOSITIONS PREFERABLY CONTAIN, IN ADDITION TO COMPONENTS A), B) AND C) ABOVE MENTIONED ONE OR MORE OF THE FOLLOWING: D) AT LEAST ONE DISPERSANT WITHOUT COMBUSTIBLE-SOLUBLE ASH; E) AT LEAST ONE FUEL-SOLUBLE DEMULSIFYING AGENT; F) AT LEAST ONE ALIPHATIC OR CYCLOALIFATIC AMINE. COMPONENT C) INCREASES THE STABILITY OF FUEL COMPOSITIONS CONTAINING AT LEAST COMPONENTS A) AND B). THE ...

Derivatives of polyamines with one primary amine group and secondary or tertiary amines groups

A dispersant derivatized from a functionalized hydrocarbon and a polyamine having one primary amine and 1-10, preferably 3-8 secondary or tertiary amines; preferably where said functionalized hydrocarbon is a Koch-derived hydrocarbon.

Polymers functionalised by koch reaction, derivatives thereof and producing process thereof

Low pressure derived mixed phosphorous- and sulfur_containing reaction products useful in power transmitting compositions and process for preparing same

A phosphorous- and sulfur-containing additive and its use to impart anti-wear and/or antioxidant properties to oleaginous compositions such as fuels and lubricating oils, particularly power transmission compositions, such as automatic transmission fluids, is disclosed. The additive comprises a mixture of products formed by simultaneously reacting (1) a beta-hydroxy thioether, such as thiobisethanol, and (2) a phosphorous-containing reactant, such as tributyl phosphite. The reaction is carried out under reduced pressure conditions (e.g., -40 KPa to -100 KPa) to limit the amount of thioether species in said additive to less than about 45 mole %.

Process for producing ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives

Patent FR1567540A

Novel additive to inhibit corrosion by naphthenic acid and its use procedure

Un aditivo para la inhibición de la corrosión por ácido nafténico a temperaturas elevadas que comprende una mezcla química de: a) una cantidad inhibidora de la corrosión de poliisobutilensulfuro fosforoso, el compuesto A; y b) una cantidad inhibidora de la corrosión de sulfuro trifosforoso, el compuesto C, en el que dicho compuesto A de poliisobutilensulfuro fosforoso se obtiene haciendo reaccionar una olefina con pentasulfuro fosforoso en presencia de una cantidad catalítica de azufre, formando una mezcla de reacción, en el que la relación molar entre dicha olefina y dicho pentasulfuro fosforoso está comprendida entre 1:0,05 y 1:2, dicha olefina es poliisobutileno (HRPIB) altamente reactivo, dicho azufre es azufre en polvo, y en el que dicho azufre en polvo está presente en cantidad catalítica de 0,5 % a 5 % de dicha olefina en peso; en el que dicho compuesto C de sulfuro trifosforoso tiene la fórmula 2, se obtiene haciendo reaccionar un compuesto B de sulfuro trifosforoso con óxido de etileno, y en el que la fórmula 2 comprende el compuesto C resultante obtenido después de la reacción de dicho compuesto B con dicho óxido de etileno, en el que dicho compuesto C de sulfuro trifosforoso incluye monoéster, diéster, mezclas de los mismos; en la que X es independientemente bien azufre o bien oxígeno, y al menos una X es azufre, y en la que R1 y R2 son hidrógeno o hidrocarbilo que tiene de 5 a 18 átomos de carbono; en el que dicho compuesto B es un éster de ácido tiofosforoso de la fórmula 1 en la que X es independientemente bien azufre o bien oxígeno y al menos una X es azufre y en la que R1 y R2 son hidrógeno o hidrocarbilo que tiene de 5 a 18 átomos de carbono, en la que dicho éster de ácido tiofosforoso de fórmula 1 incluye monoéster, diéster, mezclas de los mismos; en el que la proporción en peso entre el compuesto A y el compuesto C está comprendido entre 1:1 y 4:1. An additive for the inhibition of corrosion by naphthenic acid at elevated temperatures comprising a ...

Low chlorine polyalkylene substituted carboxylic acylating agent compositions and compounds derived therefrom

Polyalkylene substituted carboxylic acylating agents which contain chlorine are synthesized by chlorine induced condensation of polyalkylenes and ∝-β unsaturated carboxylic groups are treated with sulfur to reduce chlorine content of the carboxylic acylating agent.

Dispersant compositions having polyalkylene succinimides

A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1000 to 5000. The unsaturated acidic reagent copolymer is a copolymer of an unsaturated acidic reagent and an alkylene group. That alkylene group can be an α-olefin having 8 to 42 carbon atoms, a polyalkylene having from 8 to 28 carbon atoms, ethylene, styrene, 1,3-butadiene, vinyl alkyl ether having at least 3 carbon atoms, or vinyl alkanoate having at least 4 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 0.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.0 moles of polyamine per equivalent of alkenyl or alkylsuccinic acid derivative plus unsaturated acidic reagent copolymer.

New process for making detergent inhibiting additives

1,239,879. Lubricant and fuel compositions. ESSO CHIMIE. 1 Aug., 1969 [20 Aug., 1968], No. 38640/69. Headings C5F and C5G. A colloidal dispersion of an alkali metal or alkaline earth metal salt is made by treating a mixture containing an alkali metal base or an alkaline earth metal base and oil solution of nonyl phenol and a thiophosphonic acid (in an amount of 10-25% of the total thiophosphonic to be added) derived from the reaction of a polyolefin of molecular weight above 300 with 5-20 wt. per cent of P 2 S 5 , with an acidic gas, then making at least one further addition of base, each addition of base being separate from and preceding an addition of acidic gas, and finally adding the balance of the thiophosphonic acid after the neutralization of substantially all of the base. Suitable bases are monohydrated barium hydroxide or a hydroxide of Li, Na, K, or Ca. Suitable acid gases carbon dioxide or ACl, NO 2 , SO 2 or N 2 O 3 . The preparation is carried out at 100-150‹ C. with each addition of base being followed by purging with N 2 to remove the water formed. The dispersion can be used in amounts of 0À5-5 wt. per cent as a combustion improver for fuel oils and in amounts of 1-7 wt. per cent as an inhibitor detergent in lubricants together with a zinc dialkyldithiophosphate.

Hydroxy-group containing acylated nitrogen compositions useful as additives for lubricating oil and fuel compositions

Fuel products

PRODUCTION PROCESS FOR COMPOSITIONS SUITABLE AS INTERMEDIATE PRODUCTS IN THE PRODUCTION OF LUBRICANTS AND FUEL ADDITIVES AND THEIR DERIVATIVES

Oil soluble dispersants suitable for use in fuels and lubricants

The dispersants are formed by reacting (a) at least one dispersant having at least one primary or secondary amino group and/or at least one hydroxyl group, with (b) at least one polyolefinic compound substituted at each terminal position by a succinic group. Suitable substances for use as reactant (b) include compounds derived from at least one telechelic compound having up to 5000 carbon atoms and at least two terminal methylene groups by reaction with maleic anhydride or the like. The products are deemed to be effective dispersant/detergents for use in fuels and lubricants. In fuels the products are deemed to exhibit the property of inhibiting and/or reducing deposit formation such as intake valve deposits. In crankcase lubricants, the products are deemed to provide desirable viscosity index improving properties.

Method of preparing alkyl phenol-formaldehyde condensates.

L'invention concerne des additifs destinés à améliorer les propriétés d'écoulement à basse température ainsi que la stabilité d'oxydation d'huiles d'hydrocarbure, obtenus par alkylation d'un phénole en présence d'un cosolvant aprotique polaire afin de produire un phénole alkylé linéaire condensé à l'aide d'un aldéhyde pour produire l'agent améliorant l'écoulement à basse température. L'invention est caractérisée en ce que: a) la composition des polymères a une masse moléculaire moyenne en nombre d'au moins environ 3000 et une répartition de la masse moléculaire d'au moins environ 1,5; b) dans le réactif de phénole alkylé les groupes alkyles (i) sont essentiellement linéaires, (ii) possédent entre 6 et 50 atomes de carbone, et (iii) ont un nombre moyen d'atomes de carbone compris entre 12 et 26; et c) environ 10 moles pourcent au plus des groupes alkyles se trouvant sur le phénole alkylé possèdent moins de 12 atomes de carbone et pas plus d'environ 10 moles pourcent des groupes alkyles sur le phénole alkylé possèdent plus de 26 atomes de carbone. Les additifs peuvent également être produits sous forme d'un squelette ramifié dans lequel des réactifs monomères sont copolymérisés avec certains comonomères tri ou tétrafonctionnels. L'invention concerne également des mélanges de ces additifs avec diverses huiles d'hydrocarbure, et notamment divers distillats moyens ainsi que diverses compositions d'huiles de graissage dont les propriétés d'écoulement à basse température et la stabilité d'oxydation sont ainsi améliorées de manière significative. The invention relates to additives for improving the flow properties at low temperatures and the oxidation stability of hydrocarbon oils, obtained by alkylation of a phenole in the presence of a polar aprotic cosolvent in order to produce a linear alkylated phenol condensed with an aldehyde to produce the low temperature flow improving agent. ...

Lubricating oil additives and their manufacturing process

Additive for lubricant or fuel, lubricating oil composition or fuel composition containing it, and novel substituted hydroxyaromatic ester derivative

There are herein disclosed an additive for a lubri- cant or a fuel which comprises at least one selected from the group consisting of substituted hydroxyaromatic ester derivatives represented by the general formulae (I) and (II) <IMGS> wherein R1 to R5 are each an organic group having 6 or more carbon atoms, a, b, d, e, k and m are from 1 to 3, c, f, g, i and j are from 0 to 3, and h is from 0 to 4, but (f+g) is from 1 to 3, and (h+i) is from 1 to 6, an additive composition for a lubricant or a fuel, and a lubricating oil composition or a fuel composition contain- ing the above-mentioned additive. The above-mentioned additive for the lubricant or the fuel is desirable as an ashless detergent excellent in high-temperature stability in place of a metal detergent, and the lubricating oil composition or the fuel composition containing this additive can suitably be used as the lubri- cant or the fuel for an internal combustion engine which can comply with future exhaust gas controls.

Gel additives for fuel that reduce soot and/or emissions from engines

An additive gel for fuels that reduces the soot content in lubricating oil and/or emission in an engine. Further a process employing an additive gel for fuel in a fuel system to decrease the amount of soot in the lubricating oil of an engine and/or decrease the emissions from an engine.

Lipophilic detergent compositions

A SERIES OF NEW COMPOSITIONS COMPRISING SALTS OF PARTIAL FATTY ACID-PHOSPHORIC ACID ESTERS OF POLYALKOXYLATED POLYOLS HAVING 4 TO 6 CARBON ATOMS HAVE BEEN FOUND ESPECIALLY USEFUL AS LIPOPHILIC DETERGENTS. AMINE SALTS OF COMPOSITION HAVING FROM 1 TO 8 POLYOXYALKYLENE GROUPS, 1 TO 4 FATTY ACID ESTER GROUPS, AND 1 TO 2 PHOSPHORIC ACID GROUPS PER MOL OF POLYOL ARE PARTICULARLY USEFUL AS ASHLESS FUEL OIL SLUDGE DISPERSANTS.

Improved recovery and transportation of heavy crude oils

Novel amine-chelate complexes are useful in significantly reducing the viscosity of heavy crude oils, facilitating the recovery and transportation of such heavy crude oils. The amine-chelate complexes are formed by heating together an organic amine with a chelating agent.

Conductivity of middle distillate fuels with a combination of detergent and cold flow improver

The disclosure provides conductivity improving concentrates and methods for improving conductivity and reducing risks associated with static discharge in middle distillate fuel compositions, particularly diesel fuels. The conductivity improvement is provided by the combination of a detergent and a cold flow improver, which are preferably and advantageously pre-blended in an additive concentrate. The disclosure is particularly beneficial for ultra-low sulfur fuel compositions in that it provides a conductivity benefit without adding sulfur into the fuel composition.

Use of tetrahydrobenzoxazines as stabilisers

본 발명은 광, 산소 및 열 작용에 대하여 무생물성 유기 재료, 특히 터빈 연료를 안정화시키기 위한 안정화제로의 하기 화학식 I의 테트라히드로벤조옥사진의 용도에 관한 것이다: The present invention relates to the use of tetrahydrobenzooxazines of the general formula (I) as stabilizers for stabilizing non-living organic materials, in particular turbine fuels, against light, oxygen and thermal actions: [화학식 I] (I) 여기서, R 1 은 히드로카르빌 라디칼이고, R 2 , R 3 , R 4 및 R 5 는 각각 독립적으로, 수소 원자, 히드록실 기 또는 히드로카르빌 라디칼이며, 여기서 R 2 ∼R 5 는 또한 제2 및 제3 테트라히드로옥사진 고리를 형성할 수 있고, 단, 치환기들 중 하나 이상은 탄소 원자 수가 4∼3000개이고, 나머지 치환기들이 히드로카르빌 라디칼인 경우, 이들은 각각 탄소 원자수가 1∼20개이다. Wherein R 1 is a hydrocarbyl radical and R 2 , R 3 , R 4 and R 5 are each independently a hydrogen atom, a hydroxyl group or a hydrocarbyl radical, where R 2 to R 5 are also second And a third tetrahydrooxazine ring, provided that at least one of the substituents has 4 to 3000 carbon atoms and the remaining substituents are hydrocarbyl radicals, each having 1 to 20 carbon atoms. 테트라히드로벤조옥사진, 터빈 연료, 제트 연료 Tetrahydrobenzoxazine, turbine fuel, jet fuel

Hydrocarbonaceous fuel compositions and additives therefor

Hydrocarbonaceous fuels and additive compositions therefor which comprise: a) one or more fuel-soluble manganese carbonyl compounds; b) one or more fuel-soluble alkali or alkaline earth metal-containing neutral or basic detergent salts; and c) one or more fuel-soluble ashless dispersants. These compositions preferably contain, in addition to components a), b) and c) above, one or more of the following: d) at least one fuel-soluble demulsifying agent; e) at least one aliphatic or cycloaliphatic amine; and f) at least one metal deactivator. The compositions possess improved combustion characteristics (e.g., formation of less soot, smoke, carbonaceous products and/or noxious emissions), and form on combustion carbonaceous products of reduced acidity. The deposition of sludge on critical engine or burner parts or surfaces is reduced and the fuels have improved stability and demulsibility characteristics. And the fuel compositions can result in decreased fuel consumption in diesel engines.

Anti-knock compositions

Metal complexes of nitrogen compounds in fluids

Multiple metal complexes of nitrogen compounds are prepared by reacting in any desired order (1) an organic reactant, preferably an alkenylsuccinic acid or anhydride or a polyalkylphenol-aldehyde reaction mixture, or a halogenated polyolefin; (2) a polyamine, having one nitrogen atom reactive with the organic reactant and at least one additional nitrogen atom such as an ethylene polyamine and the imidazoline or imidazolidine derivative thereof; (3) and at least two metal compounds, one of which is a metal of Groups IB, IIB, IVA, IVB, VIB, VIIB or VIII of the Periodic Table, capable of both forming a coordinated complex of the Werner type with the polyamine and also forming a complex with the second metal compound, and the said metal compound of metals of the above groups plus alkali and alkaline earth metals. The reactants may be reacted in any order, such as the above order, or the amine reactant may be precomplexed. Lubricant, grease, fuel and aqueous compositions are provided detergency and anti-wear properties by the presence of these multiple complexes.

Advanced fuel oils

Phosphorylated thermal stability additives for distillate fuels