ПОЛИАМИДНЫЕ КОМПОЗИЦИИ, СОДЕРЖАЩИЕ ПОЛИАМИД 6,6 И СМЕСЬ ДЛИННОЦЕПОЧЕЧНЫХ ПОЛИАМИДОВ, ИХ ПРИМЕНЕНИЕ, А ТАКЖЕ ПОЛУЧАЕМЫЕ ИЗ НИХ ИЗДЕЛИЯ

Изобретение относится к полиамидной композиции. Описана полиамидная композиция для получения изделия, обладающего улучшенной химической стойкостью, содержащая: (a) по меньшей мере одну полиамидную смесь, сформированную из (i) полиамида 6,6, в котором количество концевой группы амина (aeg) больше, чем количество концевой группы карбоновой кислоты (ceg); и (ii) смеси первого длинноцепочечного полиамида, имеющего значение вязкости (vn), равное x, и второго длинноцепочечного полиамида, имеющего значение vn, равное x; (b) по меньшей мере один армирующий наполнитель; (c) по меньшей мере один термостабилизатор; и (d) по меньшей мере один ионный смазочный материал, где xбольше чем x, а значение vn измеряется в соответствии со стандартом iso 307 в растворе полиамида с концентрацией 0,005 г/мл при температуре 25°C. Также описаны применение полиамидной композиции, изделие, и применение смеси первого длинноцепочечного полиамида. Технический результат: улучшение химической стойкости полиамидной композиции ...

ПОЛИАМИДНЫЕ КОМПОЗИЦИИ, СОДЕРЖАЩИЕ ПОЛИАМИД 6,6 И СМЕСЬ ДЛИННОЦЕПОЧЕЧНЫХ ПОЛИАМИДОВ, ИХ ПРИМЕНЕНИЕ, А ТАКЖЕ ПОЛУЧАЕМЫЕ ИЗ НИХ ИЗДЕЛИЯ

Гидравлическая жидкость

Use of amino:carboxylate(s) and betaine(s) - as additives for drilling milk used to punch printed circuit boards

Use of an aminocarboxylate of formula (I) and (II), a betaine of formula (III) and an N-(N-COCO-fatty acid aminopropyl) -N,N-dimethylammonium-N- (2-hydroxypropyl) -sulphonate of formula (IV) as additive for drilling milk for punching printed circuit boards. In formulae, R1 is H, -(CH2)n-(COOR2), -(CH2)n-CH2OH; R2 is H, metal, lower alkyl, phenyl; R3 is alk(en)yl contg. 8-20C atoms; n is 1-5; and X is OH, Cl, Br or I.

FUNKTIONELLE FLUESSIGKEITEN

Zusatzmittel zu Schmieroelen

Verfahren zum Stabilisieren von Fetten, OElen, Wachsen und Kohlenwasserstoffen gegen Oxydation

SCHMIERÖLZUSAMMENSETZUNGEN.

LACTONE-MODIFIED ESTER OILS AND A LUBRICATING COMPOSITION CONTAINING THEM

Synthetic ester lubricants - contg. mineral oil and methacrylate copolymer as pour point depressant

Lubricant compsns. comprise (a) a synthetic ester base oil derived from a pentaerythritol or trimethylolpropane and a 2-12C organic acid and (b) a pour-point depressant comprising a mixt. of a mineral lubricating oil with a pour point of -40 to +35 degrees F and a copolymer of >=2 4-18C alkyl methacrylates having a mol. wt. of 5000-500,000. The lubricants can be used in bus or truck turbine engines. The mineral oil and methacrylate copolymer act synergistically.

Schmierfett

ESTERS OF -3,5-DISUBSTITUTED-4-HYDROXY-PHENYL-ALKANOLS AND THEIR USE AS STABILIZERS

... 1355109 Esters of -(3,5-disubstituted-4-hydroxyphenyl)alkanols GAF CORP 22 Sept 1971 [28 Sept 1970] 44225/71 Heading C2C [Also in Divisions C3 and C5] The invention comprises compounds of formula wherein R1 and R11 each represents a C 1-24 alkyl group, a C 7-18 aralkyl or a C 6-18 cycloalkyl group; R represents a C 1-25 alkyl group, a C 6-18 cycloalkyl group, a C 6-18 aryl group or. a C 7-18 arylalkyl group; m represents an integer of from 2 to 10 and n represents an integer of 1 to 9. The following compounds are prepared in the examples: terephthalate ester of 3-(3,5-di-tert.- butyl - 4 - hydroxyphenyl) - propanol; 1,2,4- benzenetricarboxylate of 3 - (3,5 - di - tert.- butyl - 4 - hydroxyphenyl) - propanol; stearate of 3 - (3,5 - di - teft. - butyl - 4 - hydroxyphenyl)- propanol; 3,6 - endomethylene - 1,2,3,6- tetrahydrophthalic acid ester of 3 - (3,5 - ditert. - butyl - 4 - hydroxyphenyl) - propanol; dimer acid ester of 3-(3,5-di-tert.-butyl-4- hydroxyphenyl) - propanol ...

Improvements in or relating to extreme pressure lubricants

Mineral lubricating oils, for example bright stocks, which have been reacted with from 5-25 per cent by weight of a phosphorus sulphide are stabilized by further reaction with from 2-30 per cent of a reactive olefin. Olefins specified are aliphatic and cycloaliphatic olefins such as isobutylene and diisobutylene and terpenes such as turpentine, dipentene, alpha-pinene and terpinene; the dipentene may be the commercial product containing also terpinolene, alpha-pinene, para-cymene, alpha-terpineol and D 2,4(8)-p-methadiene. Sulphides referred to are P2S5, P2S3, P4S3 and P4S7.ALSO:Lubricating compositions comprise lubricating oil, for example mineral oil, and from 5-30 per cent. by weight of an extreme pressure additive comprising a mineral lubricating oil which has been reacted with from 5-25 per cent. by weight of a phosphorus sulphide and then further reacted with from 2-30 per cent. of a reactive olefin, 0.02-1 per cent. of an oil-soluble petroleum sulphonate and 0.05-2 per cent. of the ...

Aqueous Lubricants Containing Siloxane Polyoxyalkylene Compositions.

... 1,171,787. Lubricants. UNION CARBIDE CORP. 15 Dec., 1966 [15 Dec., 1965], No. 56151/66. Addition to 1,074,575. Heading C5F. A lubricant comprises (1) an aqueous base fluid which is water or a mixture of up to 2 parts by weight per one part by weight water of a lubricant which is (a) a silicon-free polyoxyalkylene compound; (b) a dialkyl ester of an aliphatic dicarboxylic acid; (c) a hydrocarbon lubricating oil and/or (d) a fatty acid ester of a polyhydric compound; (2) 0À0005-0À1 part by weight per one part by weight of base fluid of a siloxane/oxyalkylene copolymer having (i) at least one siloxane block containing at least two siloxane groups of formula where R is a monovalent hydrocarbon group which may or may not be substituted by halo, cyano, amino, amido, carbalkoxy, acyloxy, mercapto, or nitro groups, or a divalent hydrocarbon group, b is 1, 2 or 3 and the block has at least one divalent hydrocarbon R group and (ii) at least one polyoxyalkylene block containing at least two groups ...

Functional Fluid Compositions

... 1,198,321. Functional fluids. MONSANTO CO. 16 May, 1967 [16 May, 1966], No. 22750/67. Heading C5F. Functional fluids comprise (A) as a base stock an organic ester, thioester or amide of phosphorus, an orthosilicate, a polysilicone, an aromatic ether, a mono- or dialkylthiophene or a mixture thereof, each of a given formula and (B) at most 15 vol. per cent of a simple monoester or a mixture thereof with a diester, triester, polyester or complex ester. Exhaustive lists of all ingredients are given. Conventional additives, e.g. polyolefins, polyalkylene oxides, polyphenyls, alkyl benzenes and halogenated aromatic hydrocarbons and ethers (examples given) may also be present.

Improvements in lubricating compositions containing extreme pressure addition agents

An extreme pressure lubricating composition comprises a major proportion of a lubricating oil base, a minor proportion of an oil-soluble extreme pressure addition agent obtained by reacting a phosphorus-and sulphur-containing reagent with an organic material, and a minor proportion of an oil-soluble corrosion inhibitor chosen from a list given. The load carrying ability of the lubricating oil base is substantially increased by the inclusion therein of the minor proportion of the extreme pressure addition agent, which is one whose effectiveness is dependent upon its ability to react chemically with the metallic surfaces to be lubricated, while the inclusion of the corrosion inhibitor does not substantially decrease the extreme pressure proportions imparted by the extreme pressure addition agent. The lubricating oil base may be of mineral, animal, vegetable or synthetic origin or may comprise a mixture of mineral and non-mineral oils. Those fatty acids, such as oleic acid, which are oily ...

ANTIOXIDANTS

... 1393366 Lubricants EXXON RESEARCH & ENG CO 29 Aug 1972 [6 Oct 1971] 46458/71 Heading C5F An antioxidant composition for lubricants comprises (a) an alkylated N-phenyl-naphthylamine having at least one C 3 -C 14 alkyl group and (b) an amino compound of formula where X is hydrogen, C 1 -C 20 hydrocarbyl or the group the mole ratio of (a) : (b) being at least 1 : 1. The lubricant may be a mineral, oxidized mineral, fatty or synthetic oil (many examples are given of fatty oils, esters and polyglycols). The lubricant may also contain sebacic acid, dimethyl-silicone, tricresyl phosphate, neutral alkyl aryl phosphates and neutral phosphonates.

Lubricating oil composition for improved oxidation, viscosity increase, oil consumption and piston deposit control

An engine oil lubricant composition having improved control of oxidation, viscosity, and piston deposits is provided. The composition further exhibits performance on the ASTM Sequence IIIG Test of about 90% or less kinematic viscosity increase at 40{C and about 5.5 or more merits in terms of average weighted piston deposits. The composition meets or exceeds the standards of both the ILSAC GF-4 and the General Motors GM4718M specifications. The lubricant composition comprises a major amount of a synergistic base oil mixture consisting essentially of at least one Group III base oil (with specific ranges of sulfur content, saturates and viscosity index), at least one Group IV base oil (containing polyalphaolefins) and at least one Group V base oil (other oils not included in Groups I to IV).

Improvements relating to lubricants and to lubrication

Lubricating-compositions especially for use under high pressures consist of a major amount of a lubricating - oil base and a halogenated organic compound together with a separate oxygen- or sulphurcontaining compound. Suitable halogenated organic compounds are described in Specifications 451,411, 451,412, 452,914, 453,114, and 453,115. Oxygen-containing organic compounds used consist of, ethers, alcohols, phenols; compounds, containing the CO radicle such as aldehydes ketones, amides, acids, esters, salts of acids and thio esters; hetero-cyclic compounds containing oxygen such as furan; organic compounds containing inorganic radicles such as arsenate, cyanate, chlorate, nitrate, oxime, phosphate, sulphate, sulphone, and thio-phosphate. Examples, oleic or stearic acid, dibutyl phthalate, butyl naphthenate, aniline oleate, quinoline stearate, or fatty oils. Compounds containing oxygen and halogen may be used. Examples, chlorinated phenols, chlorbenzyl alcohol, chlorsalicylic acid, chlorphenyl ...

Calcium carbonate dispersions

A transparent colloidal dispersion of calcium carbonate in oil is obtained in a two-stage reaction in which, in the first stage, CO2 is passed into a suspension of finely-divided calcium oxide (derived by burning CaCO3 above 2000 DEG F.) in methanol of <1% by volume water content in an amount 5-50% of that required to convert CaO to CaCO3 and, in the second stage, the oil and an oil-soluble dispersant are added and further CO2 is passed in to complete absorption, the dispersion then being distilled to remove methanol, treated with water and dehydrated. A thinner such as a "naphtha," particularly Stoddard solvent, kerosene, or preferably varnish maker's and painter's naphtha or alternatively an aromatic solvent such as benzene, toluene or xylene or a chlorinated solvent such as carbon tetrachloride or trichlorethylene may be included in the oil dispersion. Suitable oils are the petroleum lubricating oils, low-viscosity hydraulic oils, synthetic polyolefinic hydrocarbons such as polypropylene ...

Antioxidant compositions

The invention comprises a composition containing (a) an antioxidant mixture of (1) an organic diallyl phosphonate, having a hydrogen atom bonded to phosphorus, in an amount from 0.005% to 1.5% and (2) 0.01 to 5% of a phenol mono-, di-, or tri-sulphide, wherein the phenol nuclei are bridged by Sx, where x is from 1 to 3, both percentages being based on the weight of the composition, and (b) an organic material subject to oxidation by air oxygen or ozone. Examples of organic materials are: diester lubricants formed by the reaction of dibasic C4 to C16 carboxylic acids with monohydric C1 to C10 alcohols; chlorinated organic compounds such as chlorodiphenyls, chloronaphthalenes and chlordiphenyl acids; phosphate esters, which are prepared by the reaction of an alcohol with phosphoric acid, and have the general formula wherein R, R1 and R11 are hydrogen or an organic radical provided that at least one is an organic radical, a typical example is tricresylphosphonate; Vitamins ...

A grease

A grease composition comprises a nitrogencontaining component which is an oleophilic imidazoline and/or an oleophilic aminoamide formed between a fatty acid and a plyethylene polyamine, an oleophilic clay product, a polyethylene glycol and a lubricating oil. The clay product, preferably passing a 250 mesh (U.S.) screen, is formed (see Division C1) by treating an acid-exchanged clay such as hectorite with one or more of the above class of nitrogen-containing components and spray drying in the absence of oil. The product preferably bears 40 to 125% by weight, based on the clay, of the nitrogen compound on its surface. The clay product may contain 0.5-5% moisture and the grease itself preferably contains up to 1% water. The polyethylene glycol is preferably water-soluble and has a molecular weight between 500 and 1600, e.g. "Carbowax." The lubricating oil, present in an amount 10 to less than 100% by weight based on the clay, may be a mineral oil or a synthetic oil, e.g. esters of dibasic ...

Neopentyl compounds

Lubricants or lubricant additives comprise polyesters derived from dibasic acids and the glycols ALSO:The invention comprises the compounds 2,2,11,11 - tetramethyldodecanediol - 1,12, 2,2,9,9 - tetramethyl - 4 - ethyldecanediol - 1,10, and 2,2,7,7 - tetramethyl - 4,5 - diethyloctanediol-1,8 and mixtures thereof; and their preparation by the catalytic hydrogenolysis of at least one of the diethers of formula were R is hydrogen or aryl and R1 is aryl (aryl including aralkyl). The above diethers are prepared by reacting butadiene with a compound to give the compounds (where X is Cl, Br or I), reacting one or both of these by intermolecular dehalogenation and coupling to give the compounds and catalytically hydrogenating. Methallyl benzyl ether is prepared from methallyl alcohol, NaOH solution and benzyl chloride. The glycols of the invention are lubricants and cross-linking agents for polymers ...

Functional fluids

A functional fluid comprises a mixture of (a) a polyalkylamino di- and/or tri-azine and (b) a polyphenyl ether, the weight ratio of a : b being 1 : 9 to 9 : 1. Component (a) may have the formula. where X is N or CH, R1 is H or a C1-C16 alkyl radical, R3 is a C1-C16 alkyl radical and R2, R4, R5 and R5 are C1-C6 alkyl radicals, the sum of the carbon atoms of all nitrogen substituents being at least 12. The polyphenyl ether may have alkyl or alkoxy substituents. The composition may include an anti-oxidant, many examples being given which include amines, phenols, sulphides, selenides, silazines and tocapheral. Additional ingredients are phosphites, phosphates, sulphonized sperm oil, barium or calcium mahogany sulphonates, sacosines, benztriazoles, silicones and grease thickeners such as soaps, bentonites, phthalocyanines and violanthrones.

Synthetic Lubricants

... 1,162,818. Lubricants. BRITISH PETROLEUM CO. Ltd. 25 Nov., 1966 [17 Dec., 1965], No. 53617/65. Heading C5F. A lubricant comprises (a) one or more liquid, neutral complex esters formed from trimethylolpropane, sebacic and/or azelaic acid and one or more C 2 -C 14 aliphatic mono-carboxylic acids and (b) one or more liquid polyethers of formula where at least 20% of the R's are tetramethylene groups and each of the other R's is -CH 2 C(R1)(R2)- where R1 is hydrogen or methyl and R2 is hydrogen, methyl or ethyl; X is C 1 -C 12 alkyl; Y is hydroxyl or C 1 -C 12 alkoxyl; and n is such that the polyether has a viscosity of 5-1000 cs. at 210‹ F.; the proportion of (b) being 0À1-10 wt. per cent of (a) plus (b). The composition may also contain an antioxidant, e.g. phenothiazine, iminodibenzyl and aromatic amines (examples are given), a copper passivator, e.g. imidazoles, pyrazoles, triazoles and salts of 1-salicylalamino-guanidine and C 2 -C 24 fatty acids (examples ...

Improvements relating to lubricating oils

Isobutylene polymers of m.w. up to 300,000 are obtained by polymerizing purified isobutylene in presence of boron fluoride or other halide catalyst at a temperature below -50 DEG C., e.g. -80 to -110 DEG C. This temperature is conveniently obtained by the evaporation of liquefied ethylene in presence of the reacting substances.ALSO:Lubricants.--The leakage and the power consumption of mineral lubricating-oil are reduced by adding less than 1,0 per cent of an oil-soluble linear isobutylene-polymer of m.w. > 30,000, e.g. up to 300,000. Soap, e.g. 0,1--2,0 per cent of alkali soap is advantageously added. Other optional additions are glycerine, glycol, higher alcohols, fatty acids or esters, other polar compounds, lard oil, resins, aluminium soaps, sodium or calcium sulphonate, dyes, oxidation inhibitors, pourpoint reducers, emulsifying agents, graphite, clay, zinc oxide, sludge-dispersers, oil-thickeners voltolized oils, waxes, extreme pressure agents, and organo-metallic compounds. The treated ...

Disc drive spindle mortor having hydro bearing with optimized lubricant viscosity

Improvements in or relating to the production, softening and lubricating of textile materials

... 541,749. Lubricants. KILBURN, B. E. D., (National Oil Products Co.). April 26, 1940, No. 7542. [Class 91] [Also in Groups IV and V] Lubricants for textile materials comprise a blown oil or similar substance and an unblown ester of a monohydric alcohol with a fatty or naphthenic acid having eight or more carbon atoms. The composition may be employed as such or it may be dissolved in an organic solvent or dispersed or emulsified in an aqueous medium. The composition may contain an emulsifying agent, or an alkaline substance may be added to saponify a portion of it and thus form a soap, which acts as an emulsifier. The blown oil or similar substance may be an animal or vegetable oil, fat or wax which has been partially or completely oxidized or polymerized. This constituent gives the fibres the desired tackiness. The blown oil may be olive, rapeseed, rice-bran, teaseed, corn, neatsfoot, sperm, cotton-seed, castor, lard or other fatty oil or wax, or a mixture of these. The alkyl ester constituent ...

Improvements relating to lubricants

Lubricants which withstand high pressure consist of a hydrocarbon oil, a soluble lead compound and "corrosive" sulphur, the ratio of lead to "corrosive" sulphur being not substantially less than 6 to 1. "Corrosive" sulphur is that form which will discolour a copper surface, and the amount of "corrosive" sulphur in a compound is measured by the diminution of the sulphur contents which takes place by reaction with finely-divided metals such as copper, iron or mercury. Heavy petroleum residues may be used as base oils. Suitable sulphur-containing materials are elementary sulphur, synthetic organic polysulphides preferably penta - sulphides or higher polysulphides, sulphurized mineral, animal, vegetable or marine oils, such as lard oil, pine oils or fish oils. Suitable lead compounds are lead oleate, naphthenate or sulphonate or mixtures of these, or the lead salt of an acid derived by oxidation of paraffin or other hydrocarbon wax.

Improved lubricant blend

Lubricating oil compositions comprise a mineral oil, less than 20 per cent each of an oil-soluble and of a water-soluble non-ionic surface active agent, and less than 5 per cent of an ionic rust preventive. The rust preventives are defined as alkali metal, alkaline earth metal and ammonium salts of sulphonated petroleum fractions, soaps of fatty acids containing more than 8 carbon atoms, fatty acids, such as oleic acid, straight chain alkylamines containing more than 8 carbon atoms, amine salts, alkanolamines and alkanolamine salts, e.g. triethanolamine and triethanolamine oleate, naphthenic acids and their salts and alkyl mercapto organic acids, e.g. lauryl mercapto acetic acid. Suitable radicals from which the surface-active radicals may be derived are given; water-soluble surface active agents referred to are polyoxyalkylene derivatives of fatty esters of polyhydric alcohols, esterified polyoxyalkylene derivatives of urea, and condensation products of alkyl phenols with polyhydric alcohols ...

Lubricating compositions containing cyclo-organo compounds of phosphorus

A lubricant comprises a major proportion by weight of a lubricating oil as defined below and a minor proportion by weight of a compound of the formula wherein R1, R2, R3, R4, R5 and R6 and hydrogen atoms or alkyl radicals, Y1 and Y2 are oxygen or sulphur, a is a whole number of value 0 or 1 and Z is hydrogen or an alkyl, cycloaliphatic, aryl, aralkyl, alkoxy alkyl, cyanoalkyl, cyanoaryl or alkylol radical. The lubricating oil is defined as any lubricating oil which is not a polyhydric alcohol or ether thereof and may be a mineral oil or synthetic oil or mixture thereof. Animal, vegetable, or fish oils or their hydrogenated, polymerized or voltolized products may also be used either alone or in admixture with mineral oils. The synthetic lubricating oil may be a hydrocarbon oil, simple or complex ester, a halocarbon oil, siloxane, sulphite ester, mercaptol, or formal. Other additives may also be present, e.g. dyes, pour point depressors, heat thickened fatty oils, sulphurized ...

Improvements in chemical compounds and use thereof as antioxidants for organic materials

Hydroxybenzyl sulphides and sulphoxylates of the general formula wherein R and R1 are alkyl, cycloalkyl, or aralkyl groups containing less than 13 carbon atoms, and X is a sulphur atom or sulphoxy group, are used as antioxidants and may be incorporated in fats, petroleum products, and synthetic lubricants. The antioxidant may be incorporated in the organic material subject to oxidative deterioration in a proportion of 0,01 to 5%. Examples describe the incorporation of bis-(3.5-di-t-butyl-4-hydroxybenzyl) sulphoxide and sulphide, and bis-(3-methyl-4-hydroxy-5-t-butyl-benzyl sulphide in pork fat, gasoline, petroleum oils such as turbine oils, and a synthetic ester lubricant based on trimethylol propane.ALSO:Hydroxybenzyl sulphides and sulphoxylates of the general formula wherein R and R1 are alkyl, cycloalkyl, or aralkyl groups containing less than 13 carbon atoms, and X is a sulphur atom or a sulphoxy group, are used as antioxidants inter alia ...

PROCEDURE FOR THE PRODUCTION OF A FOR LUBRICATION MEANS APTITUDE OF ESTER MIXTURE

USE OF CARBON DIOXIDE AS REFRIGERANTS IN AN OIL COMPOSITION FOR REFRIDGERATORS

LONG-TERM-STABLE OIL PTFE DISPERSION AND PROCEDURE FOR YOUR PRODUCTION

ENGINE LUBRICATION

PROCEDURE FOR THE LUBRICATION OF LINES FOR CEMENT GROUTS

3-ARYL-BENZOFURANONE ALS STABILISATOREN

The invention described novel compounds of formulaas defined in claim 1, as stabilisers for protecting organic materials, in particular polymers and lubricants, against thermal, oxidative or light-induced degradation.

PROCEDURE FOR THE HIGH TEMPERATURE STABILIZATION OF POLYCHLORALKANEN

ANTI-NEBULA ADDITIVE FOR WATER-MIXABLE AND WATER-MIXED KÜHLSCHMIERSTOFFE

LUBRICATING OIL ADDITIVES, YOUR PRODUCTION AND YOUR USE

LUBRICANT AND/OR LUBRICANT CONCENTRATE.

GREASE COMPOSITIONS

Liquid lubricant compositions

PROCEDURE FOR THE PRODUCTION OF MIXED ESTERS

PROCEDURE FOR THE PRODUCTION OF NEW CHROMANCARBONSAUREN

VERFAHREN ZUR HERSTELLUNG VON GEMISCHTEN ESTERN

VERFAHREN ZUR HOCHTEMPERATURSTABILISIERUNG VON POLYCHLORALKANEN

Cold-roll from aluminum, in particular from aluminum foils

SILICONE OIL COMPOSITION

LUBRICATING OIL COMPOSITIONS AND CONCENTRATES

Biodegradable vegetable oil compositions

QUENCHING OIL COMPOSITIONS

CONTINUOUSLY VARIABLE TRANSMISSION FLUIDS COMPRISING A COMBINATION OF CALCIUM- AND MAGNESIUM-OVERBASED DETERGENTS

LUBRICANT COMPOSITION

LUBRICATING OIL COMPOSITIONS

High viscosity complex alcohol esters

LUBRICATING FLUIDS WITH LOW TRACTION CHARACTERISTICS

GEAR OIL COMPOSITION

The gear oil composition comprises a base oil (A) and another base oil (B), described, below, and at least one species of additive for gear oil, and has a kinematic viscosity of 80 mm2/s or less at 40~C: (A): a mineral based oil and/or hydrocarbon-based synthetic oil having a kinematic viscosity of 3.5 to 7 mm2/s at 100~C, and (B): a mineral-based oil and/or hydrocarbon-based synthetic oil having a kinematic viscosity of 20 to 52 mm2/s at 100~C.

LOW TEMPERATURE LUBRICANTS

LUBRICATING FLUIDS WITH LOW TRACTION CHARACTERISTICS

The invention relates to lubricating fluids and oil formulations which provide exceptionally low traction, a method of lowering traction coefficients in lubricating compositions, and to uses of such compositions.

ELECTRICAL DEVICES CONTAINING IMPROVED DIELECTRIC FLUIDS

Improved electrical devices are disclosed including transformers and capacitors containing an improved dielectric fluid consisting essentially of a major amount of a liquid polyorganosiloxane and a minor amount of cumene, methyl cinnamate or carbon disulfide.

FUNCTIONAL FLUID COMPOSITIONS

LUBRICANT COMPOSITIONS

HYDRAULIC FLUID ANTIOXIDANT SYSTEM

HYDRAULIC FLUID ANTIOXIDANT SYSTEM A hydraulic fluid comprising (1) a base stock material, and (2) a cycloalkyl epoxide and a phenyl naphthylamine in a ratio of from about 1:10 to about 10:1 by weight. By incorporating about 0.1 to about 10 percent by weight of the hydraulic fluid of said epoxide and amine in said hydraulic fluid, acid buildup therein is controlled.

N-AROYL-N'-(ALKYLHYDROXYPHENYL)ALKANOYLHYDRAZINES

LUBRICANT OR LUBRICANT CONCENTRATE

Lubricant or lubricant concentrate on mineral oil and/or synthetic oil basis having improved lubricating properties, in particular improved load bearing, sliding and corrosion inhibiting properties, which contains a) one or more mineral oils and/or synthetic oils as base oil and b) at least one compound A containing in its molecule at least one quaternary carbon atom and at least one ester bond and/or ether bond, as well as c) further usual additives.

LUBRICATING OIL COMPOSITIONS WITH IMPROVED FRICTION PROPERTIES

The present invention concerns friction reducers for use in lubricating oil compositions which comprise certain groups of aromatic compounds, esters, narrow mixtures of base stocks, and/or amorphous polymers such as amorphous olefin copolymers. These compositions can provide substantial reductions in the coefficient of friction and fuel economy improving benefits when admixed to lubricating oils without deleterious effects such as instability, undesirable high viscosities and deposits. In one aspect of the invention, pentaerythritol esters and optionally triol esters are added to lubricating oil compositions to provide reduced friction and improved fuel economy. In a second aspect of the invention, similar results are obtained by adding hydrocarbyl aromatics to a lubricating oil composition containing one or more of Groups II and III base stock. In a third aspect, the invention concerns a lubricating oil composition comprising an amorphous olefin copolymer and one or more of Groups II and ...

HYDRAULIC FLUIDS CONTAINING CERTAIN QUATERNARY PHOSPHONIUM SALTS OF PHOSPHORUS ACIDS

TRANSESTERIFIED FATTY ESTERS FOR LUBRICANT AND REFRIGERANT OIL SYSTEM

This invention is a composition that includes a transesterified fatty acid ester resulting from the reaction of a fatty acid ester, in the presence of an acid, with a hydroxyl-containing compound. The fatty acid esters of the invention are selected from those with a carbon number of eight to twenty. The hydroxyl-containing compound is an alcohol having a carbon number between one and eighteen. The resulting composition is useful as a lubricant, as a heat transfer agent, as a rheological modifier and as a corrosion/moisture inhibitor, among other uses.

LUBRICATING OIL COMPOSITIONS WITH IMPROVED FRICTION PROPERTIES

The present invention concerns friction reducers for use in lubricating oil compositions which comprise certain groups of aromatic compounds, esters, narrow mixtures of base stocks, and/or amorphous polymers such as amorphous olefin copolymers. These compositions can provide substantial reductions in the coefficient of friction and fuel economy improving benefits when admixed to lubricating oils without deleterious effects such as instability, undesirable high viscosities and deposits. In one aspect of the invention, pentaerythritol esters and optionally triol esters are added to lubricating oil compositions to provide reduced friction and improved fuel economy. In a second aspect of the invention, similar results are obtained by adding hydrocarbyl aromatics to a lubricating oil composition containing one or more of Groups II and III base stock. In a third aspect, the invention concerns a lubricating oil composition comprising an amorphous olefin copolymer and one or more of Groups II and ...

BASE OIL BLENDS HAVING UNEXPECTEDLY LOW BROOKFIELD DYNAMIC VISCOSITY AND LUBRICANT COMPOSITIONS THEREFROM

A base oil having an unexpectedly low dynamic viscosity as measured by ASTM D5133 test method comprises a blend of about 65 to 97.5 wt% of a paraffinic oil having a VI of 130 or greater, a Kv @ 100~C of about 3.8 cSt or greater and a pour point of - 15~C or less and an ester of lubricating viscosity of from about 35 to about 2.5 wt%. The base oil is further characterized as fre e of added viscosity modifiers.

LUBRICANT FOR PERCUSSION EQUIPMENT

This invention discloses a lubricant suitable for use in percussion equipment. The lubricant comprises a base oil selected from the group consisting of Group I or Group II, blended in a synergistic amount with a gear oil package and a friction modifier. The lubricant exhibits superior wear and superior extreme pressure properties due to the synergistic effect of the gear oil package and the friction modifier. In a preferred embodiment, the gear oil package comprises a polyalkyl methacrylate polymer,and the friction modifier comprises a synthetic ester.

PERCUSSION EQUIPMENT LUBRICANT COMPOSITIONS COMPRISING A GROUP I OR II BASE OIL, SULFUR-PHOSPHORUS HYDROCARBONS, AND SYNTHETIC ESTER FRICTION MODIFIER

This invention discloses a lubricant suitable for use in percussion equipment. The lubricant comprises a base oil selected from the group consisting of Group I or Group II, blended in a synergistic amount with a gear oil package and a friction modifier. The lubricant exhibits superior wear and superior extreme pressure properties due to the synergistic effect of the gear oil package and the friction modifier. In a preferred embodiment, the gear oil package comprises a polyalkyl methacrylate polymer,and the friction modifier comprises a synthetic ester.

LUBRICATING COMPOSITIONS

This invention relates to a lubricating composition comprising at least about 30% by weight at least one mineral oil, having a kinematic viscosity of less than about 8 cSt at 100.degree.C, (A) from about 15% to about 40% by weight of at least one polymer, and (B) up to about 30% by weight of at least one fluidizing agent, provided that when the fluidizing agent is a poly.alpha.-olefin having a kinematic viscosity from about 2 to about 30 cSt at 100.degree.C, then the poly.alpha.-olefin is present in an amount up to about 12% by weight, wherein the lubricating composition has a shear loss of less than about 15% in the 20 hour taper bearing shear test. The invention also relates to concentrates used in preparing lubricating compositions. The present combination of components provides good low and high temperature properties especially when used in combination with one or more mineral oils. In one aspect, the compositions provide improved oxidation resistance.

Hitzebeständiges Kohlenwasserstofföl.

Procédé pour neutraliser la tendance des lubrifiants se composant principalement d'esters d'acides organiques à provoquer des corrosions.

Verfahren zur Herstellung eines zur Bildung von Emulsionen geeigneten, Kohlenwasserstoffe enthaltenden Produktes.

Textilöl.

Wasser-in-Öl-Emulsion und ihre Verwendung als Zylinderschmiermittel

Hitzebeständiges Kohlenwasserstofföl.

Präparat zur Verhütung von Korrosion und Rostbildung

Schmierfett

Verfahren zur Schmierung von Verbrennungskraftmaschinen und Wasser-in-Öl-Emulsion zur Ausführung dieses Verfahrens

Verfahren zum Stabilisieren oxydationsempfindlicher organischer Stoffe

Schmierfett.

Schmiermittel.

Verfahren zur Herstellung eines Schmiermittels.

Verfahren zur Herstellung eines öllöslichen als Schmiermittelzusatz geeigneten Kopolymers

Verfahren zur Herstellung von Triazinverbindungen

Verfahren zur Herstellung von Adamantanol-Diestern

Synthetisches Schmiermittel

Als Schmiermittel geeignete Mischung

Als Dielektrikum, Wärmeübertragungs-, Kraftübertragungs- und Schmiermittel geeignete Flüssigkeit und Verwendung derselben

Funktionsflüssigkeitskomposition mit einem Zusatz von Chlorfluoralkan

Method of operating a hybrid engine

The invention relates to a method of operating a hybrid internal combustion engine, which method comprises: fuelling said hybrid internal combustion engine with a combustible fuel; lubricating said engine with an engine oil composition; and maintaining an oil film thickness of the engine oil composition in the big end conrod bearing shells of the engine of at least 0.4 μm; in which the temperature of the engine oil composition is maintained below 123° C. and the engine oil composition has: a high temperature, high shear viscosity of less than 2.6 cP (2.6 millipascal second) at 150° C. and at a shear rate of 10 6 s −1 ; a Noack volatility of at most 13 weight %; and comprises: (A) a base oil which is at least one synthetic basestock, the base oil having a kinematic viscosity of at least 2.0 cSt (2.0 mm2/s) at 100 ° C.; and (B) an additive package which comprises at least one dispersant, at least one detergent, and at least one phosphorus-containing, anti-wear additive in an amount to provide a total concentration of phosphorus-containing, anti-wear additives in the engine oil composition corresponding to 0.01 to 0.2 weight % phosphorus in the engine oil composition.

Application-specific finished lubricant compositions comprising a bio-derived ester component and methods of making same

The present invention is generally directed to methods of making application-specific finished lubricant compositions comprising bio-derived diester species. In some embodiments, bio-derived fatty acid moieties are reacted with Fischer-Tropsch/gas-to-liquids reaction products and/or by-products (e.g., gas-to-liquids-produced α-olefins) to yield bio-derived diester species that can then be selectively blended with base oil and one or more additive species to yield an application-specific finished lubricant product having a biomass-derived component.

Grease composition and bearing

The invention provides a grease composition containing a thickener, a base oil and an antistatic agent, where the antistatic agent includes at least one selected from the group consisting of Li(CF 3 SO 2 ) 2 N and Li(CF 3 SO 2 ) 3 C; and a mechanical part where the above-mentioned grease composition is packed. The composition of the invention shows satisfactory results in the antistatic properties and the acoustic property.

Biodegradable lubricant composition

A biodegradable lubricating oil composition includes (A) an ester represented by a formula (1) below, the ester having a kinematic viscosity in a range from 300 mm 2 /s to 1000 mm 2 /s at 40 degrees C. and an acid value of 0.5 mgKOH/g or less; (B) an ester being obtained by reacting a straight-chain saturated aliphatic carboxylic acid with a polyhydric alcohol, the ester having an acid value of 0.5 mgKOH/g or less; and (C) a phosphate amine salt being obtained by reacting an acidic phosphate with an alkylamine. In the formula, Ra is a hydrocarbyl group having 4 to 20 carbon atoms, Rb is a hydrocarbyl group having 4 to 18 carbon atoms, Rc is an acyl group having 1 to 10 carbon atoms, and n is an integer of 3 to 15.

Self-lubricating pharmaceutical syringe stoppers

In one aspect, a self-lubricating component is provided for a pharmaceutical packaging assembly. The self-lubricating component comprises a polymer composition and an effective amount of a lubricating additive such as, for example, boron nitride. In another aspect, a pharmaceutical packaging assembly may be provided having a surface thereof coated with a lubricating composition comprising boron nitride. The pharmaceutical packaging composition may be, for example, a pre-filled syringe comprising a body (barrel) and a plunger assembly.

Lubricating composition containing multifunctional hydroxylated amine salt of a hindered phenolic acid

Multi-functional additives which impart improved antioxidancy to lubricating oil compositions and frictional properties resulting in improved fuel economy in an internal combustion engine are disclosed. More particularly disclosed are lubricating oil compositions for internal combustion engines comprising a) a major amount of an oil of lubricating viscosity; and b) a minor amount of an oil soluble hydroxylated amine salt of a hindered phenolic acid, said salt having the general formula I: wherein A and Q are each independently C 2 -C 6 alkylene group; R is methyl, alkyl or alkenyl group having C 2 -C 24 carbon atoms; Y is hydrogen, C 1 -C 6 alkyl group or A-OH; x is an integer of 1 or 2; and z is an integer of 0 or 1.

Lubricant additives

Processes are described for producing liquid, biobased lubricant additives containing from 50 to 100% biobased carbon according to ASTM D6866 from heat-bodied oils by transesterification with biobased or petroleum based alcohols and by hydrotreatment of at least the resulting diesters, triesters and polyesters.

Process for Making Basestocks from Renewable Feedstocks

A process for converting feedstock triglycerides to lube basestocks. The process has the steps of (a) metathesizing the feedstock triglycerides with ethylene in the presence of a metathesis catalyst to form alpha olefins and medium-chain triglycerides and (b) hydroisomerizing the medium-chain triglycerides in the presence of a hydroisomerization catalyst and hydrogen to form methyl-branched triglycerides. The alpha olefins may be oligomerized in the presence of an oligomerization catalyst to form poly(alpha olefins).

Fuel Additives for Enhanced Lubricity and Anti-Corrosion Properties

The reaction product resulting from the chemical reaction of an alkyl phenol with an acid or an anhydride selected from the group consisting of a saturated dicarboxylic acid, an unsaturated dicarboxylic acid, an anhydride of a saturated dicarboxylic acid, an anhydride of an unsaturated dicarboxylic acid, and combinations thereof, has been discovered to improve the properties of various fluids. In a non-limiting example, the reaction products may have an acid number from about 0 to about 50 that may improve the lubricity and/or corrosion of fuels and lubricants, such as hydrocarbon fuels and lubricants, when added thereto.

Lubricant and synergistic additive formulation

A friction modifying lubricant additive is provided comprising a base oil, colloidal nanocarbon particles, and a fluorine containing oligomeric dispersant. The fluorine containing oligomeric dispersant includes an anchoring group, a lipophilic hydrocarbon group, and a fluorinated oleophobic group. Further, a friction modifying lubricant additive is provided comprising a base oil, colloidal nanocarbon particles, a fluorine containing oligomeric dispersant, and at least one component selected from the group consisting of an antifriction component, an antiwear component, and an extreme pressure component. In another aspect, a method of manufacturing a lubricant additive is provided, the method comprising the step of mixing together a fluorine containing oligomeric dispersant, a dispersion of colloidal nanocarbon particles in a first base oil, and a second base oil.

Lubricant for percussion equipment

This invention discloses a lubricant suitable for use in percussion equipment. The lubricant comprises a base oil selected from the group consisting of Group I or Group II, blended in a synergistic amount with a gear oil package and a friction modifier. The lubricant exhibits superior wear and superior extreme pressure properties due to the synergistic effect of the gear oil package and the friction modifier. In a preferred embodiment, the gear oil package comprises a polyalkyl methacrylate polymer, and the friction modifier comprises a synthetic ester.

Lubricating Composition Containing Friction Modifier and Viscosity Modifier

A lubricant composition suitable for lubricating an internal combustion engine comprises: (a) an oil of lubricating viscosity having a viscosity index of at least 105 and a kinematic viscosity at 100 C of less than 7 mm2s-1; (b) 0.01 to 2 weight percent of a friction modifier represented by the structure [I]; (c) 0.5 to 4 weight percent of a poly(meth)acrylate viscosity modifier polymer; (d) 0 to 500 parts per million by weight of molybdenum in the form of an oil-soluble molybdenum compound; and (e) 0 to 200 parts per million by weight of boron in the form of an oil-soluble boron compound.

Organic tungsten complexes

This invention relates to an organic tungsten complex prepared by providing a strongly acidic tungsten precursor having pH≦2.5, and either reacting the tungsten precursor with a nitrogenous base to form a tungsten salt intermediate having a pH ranging from ≧5 to ≦8.5, and further reacting the tungsten salt intermediate with a fatty acid derivative of an alcohol, wherein the fatty acid derivative of an alcohol contains at least one free hydroxyl group; or reacting the tungsten precursor with a fatty acid derivative of an alcohol, wherein the fatty acid derivative of an alcohol contains at least one free hydroxyl group and a nitrogenous base. Further, this invention relates to lubricating compositions containing the inventive tungsten complexes.

Lubricating Composition Containing a Compound Derived from a Hydroxy-carboxylic Acid

The invention relates to a lubricating composition comprising (a) a compound derived from a hydroxy-carboxylic acid, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.

Compositions with Fast and Slow Release Components

The present invention relates to controlled release compositions that include: (a) a slow release component, comprising one or more performance additives in the form of a solid or semi-solid mass; and (b) a fast release component comprising (i) a matrix material and (ii) one or more additives that can be dissolved and/or dispersed into the matrix material as well as additive delivery systems and processes using such compositions, and which release one or more additives into a fluid.

Rock Drill Oil

Provided is a lubricating oil composition suitable for use in rotary pneumatic and reciprocating tools, comprising a Fischer-Tropsch base oil, a friction modifier based on synthetic ester and a sulfurized extreme pressure agent. The present lubricating oil composition has superior wear, friction and extreme pressure characteristics.

High Viscosity Lubricant Compositions Meeting Low Temperature Performance Requirements

A lubricant composition characterized as having a viscosity of less than about 150,000 cP at −40° C., a kinematic viscosity of less than about 150,000 cSt at −40° C., and a kinematic viscosity of at least about 18.5 cSt at 100° C. for use in association with a device involving metal to metal contact of moving parts comprising: (a) base-stock comprising (i) at least one relatively low viscosity polyalphaolefin, (ii) at least one ester, and at least one Group III base oil; (b) viscosity improver comprising (i) at least one relatively high viscosity polyalphaolefin, and (ii) a least one olefin copolymer; (c) a performance additive comprising at least one additive effective to improve at least one property of the lubricant and/or the performance of the equipment in which the lubricant is to be used; (d) at least one pour-point depressant; and, optionally, (e) at least one antifoam agent.

Thickener, grease, method for producing the same,and grease-packed bearing

The present invention provides a thickener which allows grease having an excellent durability in a high-temperature and high-speed condition to be produced, the grease containing the thickener, a method of producing the thickener and the grease, and a grease-packed bearing. A grease ( 7 ) to be packed in a bearing ( 1 ) is obtained by adding a thickener for a grease comprising a compound shown by a chemical formula (1) shown below or a compound shown by a chemical formula (2) shown below; In the chemical formula (1) or the chemical formula (2), R 1 shows a diamine residue or a diisocyanate residue; R 2 shows a residue of a dicarboxylic acid in which two adjacent carbon atoms form an imide ring or residues of derivative of the dicarboxylic acid; R 3 shows a tetracarboxylic acid residue or residues of derivatives of the tetracarboxylic acid; R 4 shows a hydrogen atom residue, a monoamine residue or a monoisocyanate residue; and n indicates integers of 0 through 5.

Antiwear Composition and Method of Lubricating Driveline Device

The present invention relates to a method of driveline device by supplying to the driveline device a lubricating composition containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes: (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) a phosphorus compound. The invention further provides lubricating compositions containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) an amine or metal salt of a phosphorus compound that is either (i) a hydroxy-substituted di-ester of (thio)phosphoric acid, or (ii) a phosphorylated hydroxy-substituted di- or tri-ester of (thio)phosphoric acid.

Lubricating Compositions Containing Polyalkylene Glycol Mono Ethers

Provided are lubricating compositions comprising in admixture at least 40 wt % of a base stock selected from the group consisting of Group I, Group II, Group III, Group IV and Group V base stocks, or any combination thereof, one or more polyalkylene glycol mono ethers, and at least one additive. Also provided are methods of improving the friction and wear properties of a base stock selected from the group consisting of Group I, Group II, Group III, Group IV and Group V base stocks, or any combination thereof, comprising blending the base stock with one or more polyalkylene glycol mono ethers and at least one additive, to form a lubricating composition.

Low-Ash Lubricating Oils for Diesel Engines

The lubricant for a sump-lubricated, compression-ignited engine may contain an amount of a C12-C24 carboxylic acid-based fuel additive or component obtained by migration from the fuel. Good lubricant performance is obtained by including in the lubricant a boron-containing additive in an amount to provide about 2 to about 500 ppm B to the lubricant, provided that the total sulfated ash level is less than 0.8 weight percent.

Novel materials as additives for advanced lubrication

This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials have various shapes, sizes, and structures and are synthesized by autogenic reactions under extreme conditions of high temperature and pressure. The lubricant compositions comprise carbon-based particles suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.

Lubricating Composition Containing Multifunctional Hydroxylated Amine Salt Of A Hindered Phenolic Acid

Multi-functional additives which impart improved antioxidancy to lubricating oil compositions and frictional properties resulting in improved fuel economy in an internal combustion engine are disclosed. More particularly disclosed are lubricating oil compositions for internal combustion engines comprising a) a major amount of an oil of lubricating viscosity; and b) a minor amount of an oil soluble hydroxylated amine salt of a hindered phenolic acid, said salt having the general formula I: wherein A and Q are each independently C 2 -C 6 alkylene group; R is methyl, alkyl or alkenyl group having C 2 -C 24 carbon atoms; Y is hydrogen, C 1 -C 6 alkyl group or A-OH; x is an integer of 1 or 2; and z is an integer of 0 or 1.

High- and low-viscosity estolide base oils and lubricants

Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; R 2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R 1 , R 3 , and R 4 , independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein compositions comprising the compounds are characterized by particular combinations of values for estolide number, kinematic viscosity, and pour point. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Pentaerythritol tetraester

A pentaerythritol tetraester which is a mixed ester of pentaerythritol and carboxylic acids is provided, wherein the carboxylic acids consist of isobutyric acid and 3,5,5-trimethylhexanoic acid and the molar ratio of isobutyric acid to 3,5,5-trimethylhexanoic acid in the carboxylic acids is 36/64 to 80/20. The pentaerythritol tetraester may be used in a refrigerant oil or the like which exhibits excellent miscibility with a difluoromethane refrigerant among other properties.

Microencapsulated engine lubricant additives

An engine lubricating system for an internal combustion engine. The system comprises a vehicle engine; a circulation system for providing a continuing flow of lubricant to the vehicle engine and engine components; and a lubricant disposed within the circulation system. The lubricant comprises a base oil and at least one microencapsulated oil additive. The microencapsulated oil additive is selectively released into the lubricant based one or more localized event. The localized event may include a predetermined temperature change, a predetermined pH change, a localized high friction contact, and combinations thereof.

Glycerol-containing functional fluid

A functional fluid comprising a major amount of an oil of lubricating viscosity, and at least about 0.05 wt-% glycerol. A method of preparing a functional fluid comprising adding glycerol to a functional fluid, wherein the glycerol is not glycerol monooleate. A method of preparing an additive concentrate comprising adding glycerol to a diluent oil wherein the concentrate contains from about 1% to about 99% by weight of said diluent. A method of reducing wear comprising contacting a metal surface with a functional fluid comprising a major amount of an oil of lubricating viscosity and at least about 0.05 wt-% glycerol.

Lubricating compositions for continuous casting processes and methods for making and using same

Lubricating compositions for use in the casting of steel, in particular in continuous casting processes are provided. Methods for making and using such compositions are also provided.

Tetrafluoropropene compositions and uses thereof

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a tetrafluoropropene and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Low viscosity oligomer oil product, process and composition

The present invention relates to a low viscosity lubricant process, product, and composition characterized by low Noack volatility, low pour point, useful low temperature viscometrics, and high viscosity index and more particularly concerns a PAO composition having a kinetic viscosity at 100° C. in the range of about 4 cSt.

Terpene derived compounds

This invention relates to terpene derived compounds and farnesene derived compounds, and to the use of such terpene derived compounds and farnesene derived compounds in lubricants, detergents, dispersants, functional fluids, fuels, polymer compositions, cold flow improvers, and the like.

Dry lubricant for conveying containers

The passage of a container along a conveyor is lubricated by applying to the container or conveyor a mixture of a water-miscible silicone material and a water-miscible lubricant. The mixture can be applied in relatively low amounts, to provide thin, substantially non-dripping lubricating films. In contrast to dilute aqueous lubricants, the lubricants of the invention provide drier lubrication of the conveyors and containers, a cleaner conveyor line and reduced lubricant usage, thereby reducing waste, cleanup and disposal problems.

Lubricant system and method of forming the same

A lubricant system is disclosed that is formed by contacting a fibrous network with oil and/or lubricating fluid having an affinity for the fibrous network. The fibrous network comprises oleophilic fibers having a diameter between 50 nm and 10 microns and a length that is at least times the diameter. In addition, the oleophilic fibers have an affinity for the oil and/or lubricating fluid.

Apparatus for use in a system containing a lubricating fluid and method of forming the same

An apparatus is disclosed for use in a system containing at least one of an oil and a lubricating fluid. The apparatus comprises a surface in need of lubrication during operation of the apparatus, and oleophilic fibers disposed on the surface. The oleophilic fibers have a diameter between 50 nm and 10 microns and a length that is at least 5 times the diameter. In addition, the oleophilic fibers have an affinity for at least one of the oil and the lubricating fluid.

Hydrophilic composition for use with a lubricating system as well as an apparatus and method for using the same

A hydrophilic composition for use with a lubricating system comprises hydrophilic fibers having a diameter between 50 nm and 10 microns and a length that is at least 5 times the diameter. The hydrophilic fibers having a strong affinity for at least one of water and other hydrophilic fluids and may remove or eliminate free or dissolved water in a lubricating system comprising at least one of an oil and a lubricating fluid.

Lubricating Compositions For Turbine And Hydraulic Systems With Improved Antioxidancy

The present invention relates to a synergistic combination of an antioxidant and an antiwear additive that results in improved antioxidancy performance in turbine, hydraulic, and other industrial lubricating compositions. The invention further relates to the processes to make the improved lubricating compositions and methods of their use in industrial fluids.

Use of block-copolymeric polyalkylene oxides as friction reducers in synthetic lubricants

The invention relates to the use of block copolymers containing at least a block of aromatic oxyalkylene groups and a block of nonaromatic oxyalkylene groups as friction-reducing additive and also compositions and lubricant formulations containing the block copolymers of the invention.

Stabilized Blends Containing Friction Modifiers

The present invention relates to functional fluid compositions containing friction modifiers, and specifically stable compositions containing friction modifiers with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and friction modifiers that contain one or more amide functional groups, where the friction modifier is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.

Production of Polyol Ester Lubricants for Refrigeration Systems

A poly(neopentylpolyol) ester composition is produced by reacting a neopentylpolyol having the formula: wherein each R is independently selected from the group consisting of CH 3 , C 2 H 5 and CH 2 OH and n is a number from 1 to 4, with at least one monocarboxylic acid having 2 to 15 carbon atoms in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition. Then the partially esterified poly(neopentylpolyol) composition is reacted with additional monocarboxylic acid having 2 to 15 carbon atoms to form a final poly(neopentylpolyol) ester composition.

LIQUID COMPOSITIONS FOR HAIR REMOVAL DEVICES COMPRISING METATHESIZED UNSATURATED POLYOL ESTERS

The invention relates to liquid compositions for use with hair removal devices comprising a metathesized unsaturated polyol ester for improved lubrication. 1. A composition-dispensing hair removal device , the device comprising a composition comprising from 0.1% to 60 by weight of a metathesized unsaturated polyol ester , the metathesized unsaturated polyol ester having a free hydrocarbon content , based on total weight of the metathesized unsaturated polyol ester , of from 0.1% to 5% , and having at least one of:(i) a weight average molecular weight of from 5,000 Daltons to 50,000 Daltons;(ii) an iodine value of from 30 to 200; or(iii) an oligomer index from greater than 0 to 1.2. The device according to claim 1 , wherein the metathesized unsaturated polyol ester has a weight average molecular weight of from about 5 claim 1 ,000 Daltons to about 50 claim 1 ,000 Daltons.3. The device according to claim 1 , wherein the metathesized unsaturated polyol ester has an iodine value of from about 30 to about 200.4. The device according to claim 1 , wherein the metathesized unsaturated polyol ester has an oligomer index from about 0.001 to 1.5. The device according to claim 1 , wherein the metathesized unsaturated polyol ester is metathesized at least once.6. The device according to claim 1 , wherein the metathesized unsaturated polyol ester is derived from at least one of a natural polyol ester or a synthetic polyol ester claim 1 , wherein the natural polyol ester is selected from the group consisting of a vegetable oil claim 1 , an animal fat claim 1 , an algae oil claim 1 , and mixtures thereof; and the synthetic polyol ester is derived from a material selected from the group consisting of ethylene glycol claim 1 , propylene glycol claim 1 , glycerol claim 1 , polyglycerol claim 1 , polyethylene glycol claim 1 , polypropylene glycol claim 1 , poly(tetramethylene ether) glycol claim 1 , pentaerythritol claim 1 , dipentaerythritol claim 1 , tripentaerythritol claim 1 , ...

MIXED ESTER

The present invention provides a mixed ester of pentaerythritol or a mixed polyhydric alcohol and carboxylic acids; the mixed polyhydric alcohol consisting of pentaerythritol and dipentaerythritol represented by formula (I), and the carboxylic acids comprising 3,5,5-trimethylhexanoic acid and 2-propylheptanoic acid. The mixed ester exhibits excellent properties (e.g., miscibility with a refrigerant that comprises fluoropropene, low-temperature properties, oxidation stability, oxidation-hydrolysis stability, and lubricity) in a well-balanced manner while having the viscosity within the range required for a refrigerant oil, and may be used in an industrial lubricant (e.g., refrigerant oil) and the like.

Lubricant for Low Global Warming Potential Refrigerant Systems

The disclosed technology relates to a working fluid for a low global warming potential (GWP) refrigeration system that includes a compressor, where the working fluid includes an ester based lubricant and a low GWP refrigerant, and where the ester based lubricant includes an ester of one or more branched carboxylic acids where said branched carboxylic acid contains 8 or less carbon atoms. The disclosed technology provides commercially useful low GWP working fluids (commercially useful working fluids based on low GWP refrigerants) that do not have the solubility and/or miscibility problems commonly seen in low GWP fluids, including high viscosity fluids and applications. 1. A working fluid for a low global warming potential refrigeration system comprising a compressor , the working fluid comprising an ester based lubricant and a low global warming potential refrigerant;wherein the ester based lubricant comprises an ester of one or more branched carboxylic acids where said branched carboxylic acid contains 8 or less carbon atoms.2. The working fluid of wherein said branched carboxylic acid contains 5 carbon atoms.3. The working fluid of wherein said branched carboxylic acid comprises 2-methylbutanoic acid claim 1 , 3-methylbutanoic acid claim 1 , or a combination thereof.4. The working fluid of wherein said ester is formed by the reaction of said acid and one or more polyols claim 1 , wherein said polyol comprises neopentyl glycol claim 1 , glycerol claim 1 , trimethylol propane claim 1 , pentaerythritol claim 1 , dipentaerythritol claim 1 , tripentaerythritol.5. The working fluid of wherein said working fluid further comprises: (i) one or more esters of one or more linear carboxylic acids claim 1 , (ii) one or more polyalphaolefin (PAO) base oils claim 1 , (iii) one more alkyl benzene base oils claim 1 , (iii) one or more polyalkylene glycol (PAG) base oils claim 1 , (iv) one or more alkylated naphthalene base oils claim 1 , or (v) any combination thereof claim 1 , in ...

WORKING FLUID FOR HEAT CYCLE, COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM

To provide a working fluid for heat cycle which has high durability, which is excellent in the compatibility with a greater variety of refrigerant oils, and which is excellent in the cycle performance (capacity), a composition for a heat cycle system, and a heat cycle system. A working fluid for heat cycle, which contains trifluoroethylene and difluoromethane, wherein the proportion of the total amount of trifluoroethylene and difluoromethane based on the entire amount of the working fluid for heat cycle is higher than 90 mass %, and the mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 21/79 to 39/61, a composition for a heat cycle system, and a heat cycle system employing the composition. 1. A working fluid for heat cycle , which contains trifluoroethylene and difluoromethane , whereinthe proportion of the total amount of trifluoroethylene and difluoromethane based on the entire amount of the working fluid for heat cycle is higher than 90 mass % and at most 100 mass %, andthe mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 21/79 to 39/61.2. The working fluid for heat cycle according to claim 1 , wherein the mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 23/77 to 39/61.3. The working fluid for heat cycle according to claim 1 , wherein the mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 23/77 to 37/63.4. The working fluid for heat cycle according to claim 1 , wherein the mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 25/75 to 37/63.5. The working fluid for heat cycle according to claim 1 , wherein the mass ratio represented by trifluoroethylene/difluoromethane in the working fluid for heat cycle is from 25/75 to 35/65.6. The working fluid for heat cycle according to claim 1 , wherein the ...

Working Fluid Composition for Refrigerating Machine and Refrigerating Machine Oil

The present invention provides a working fluid composition for a refrigerating machine containing: a refrigerating machine oil containing, as a base oil, a mixed ester of (A) a complex ester synthesized from a polyhydric alcohol such as neopentyl glycol, a polybasic acid having 6 to 12 carbon atoms, a monohydric alcohol having 4 to 18 carbon atoms and the like, and (B) a polyol ester synthesized from a polyhydric alcohol such as neopentyl glycol and a monocarboxylic fatty acid having 4 to 18 carbon atoms, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and a refrigerant such as carbon dioxide. 1. A working fluid composition for a refrigerating machine , comprising:a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester synthesized from a polyhydric alcohol comprising at least one selected from neopentyl glycol, trimethylolpropane and pentaerythritol, at least one selected from polybasic acids having 6 to 12 carbon atoms, and at least one selected from monohydric alcohols having 4 to 18 carbon atoms and monocarboxylic fatty acids having 4 to 18 carbon atoms, and (B) a polyol ester synthesized from at least one polyhydric alcohol selected from neopentyl trimethylolpropane, pentaerythritol and dipentaerythritol, and at least one selected from monocarboxylic fatty acids having 4 to 18 carbon atoms, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; anda refrigerant selected from carbon dioxide, 1,1,1,2-tetrafluoroethane, a mixture of difluoromethane and pentafluoroethane, a mixture of difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane, and a mixture of pentafluoroethane, 1,1,1,2-tetrafluoroethane and 1,1,1-trifluoroethane.2. The working fluid composition for a refrigerating machine according to claim 1 , wherein the polyhydric alcohol constituting (A) the complex ester further comprises a dihydric alcohol having 2 to 10 carbon atoms except neopentyl glycol.3. The ...

LUBRICANT ADDITIVE AND PROCESS FOR MANUFACTURING THE SAME

It is an object of this invention to provide a lubricant additive applicable integrally to all of different types of lubricants for various applications. A lubricant additive adapted to be blended to a lubricating oil, which is characterized by comprising a synthesized base oil of the polyolester type, the content of which to be contained in the lubricant additive is in a range of from 30.0 w/w % to 60.0 w/w %, calcium sulfonate containing calcium carbonate formed in the calcite crystal structure, the content of which to be contained in the lubricant additive is in a range of from 5.0 w/w % to 30.0 w/w %, a poly-alpha-olefin oligomer, an anti-oxidant of the zinc dithiophosphate type, succinimide, an extreme pressure agent of the thiadiazole type and an anti-oxidant of the phenol type, is provided. 1. A lubricant additive adapted to be blended to a lubricating oil , characterized in that the lubricant additive comprising:a synthesized base oil of the polyester type,calcium sulfonate containing calcium carbonate formed in the calcite crystal structure,a poly-alpha-olefin oligomer, an anti-oxidant of the zinc dithiophosphate type, succinimide, an extreme pressure agent of the thiadiazole type and an anti-oxidant of the phenol type.2. A lubricant additive of characterized in that:the content of the synthesized base oil of the polyolester type to be contained in the lubricant additive is in a range of from 35.0 w/w % to 60.0 w/w %, andthe content of the calcium sulfonate to be contained in the lubricant additive is in a range of from 5.0 w/w % to 30.0 w/w %.3. A lubricant additive of characterized in that the synthesized base oil of the polyolester type comprises normal saturated fatty acids comprising 8 to 18 carbon atoms.4. A lubricant additive of characterized in that the synthesized base oil of the polyolester type comprises decanoic acid claim 1 , mixed esters with hexanoic acid claim 1 , octanoic acid and trimethylolpropane.5. A lubricant additive of characterized ...

LUBRICATING OIL COMPOSITION, METHOD FOR PRODUCING LUBRICATING OIL COMPOSITION, AND CONTINUOUSLY VARIABLE TRANSMISSION

To provide a lubricating oil composition achieving both of high traction coefficient and excellent low temperature fluidity at a higher level and having a high flash point, which contains a naphthene-based synthetic oil (A) having a flash point of 140° C. or higher, a longifolene (B), and a predetermined monoester-based synthetic oil (C), a method for producing the lubricating oil composition, and a continuously variable transmission using the lubricating oil composition. 2: The lubricating oil composition according to claim 1 , wherein the naphthene-based synthetic oil (A) is a synthetic oil having at least one ring selected from a cyclohexane ring claim 1 , a bicycloheptane ring claim 1 , and a bicyclooctane ring.3: The lubricating oil composition according to claim 1 , wherein the naphthene-based synthetic oil (A) is a synthetic oil represented by the following general formula (2):{'br': None, 'sup': 21', '22', '23, 'sub': p', {'sub2': '21'}, '21', '22', 'p', {'sub2': '22'}], 'R—X—R—X—R\u2003\u2003(2)'}{'sup': 21', '23', '22, 'sub': 21', '22', '21', '22, 'wherein Rand Reach independently represent a hydrocarbon group, Rrepresents a hydrocarbon group, Xand Xeach independently represent a cyclohexane ring, a bicycloheptane ring, or a bicyclooctane ring, and pand peach independently represent an integer of 1 or more and 6 or less.'}4: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Xand Xare each independently a cyclohexane ring claim 3 , a bicyclo[2.2.1]heptane ring claim 3 , a bicyclo[3.2.1]octane ring claim 3 , or a bicyclo[2.2.2]octane ring.5: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Rand Reach independently represent an alkyl group or an alkenyl group claim 3 , and Rrepresents an alkylene group or an alkenylene group.6: The lubricating oil composition according to claim 3 , wherein in the general formula (2) claim 3 , Rand Reach independently represent ...

Lubricating oil base oil, lubricating oil composition containing same, and continuously variable transmission using said lubricating oil composition

Provided are: a lubricant base oil capable of achieving both a high traction coefficient and an excellent low-temperature fluidity at a higher level and having a high flash point, which contains a ring-containing compound having at least (i) a crosslinked bicyclic ring where two rings are bonded while sharing 3 or more carbon atoms, and (ii) an acyloxy group or a hydrocarbyloxycarbonyl group each containing a branched hydrocarbon group with a main chain having 4 or more carbon atoms, a lubricating oil composition containing the lubricant base oil, and a continuously variable transmission using the lubricating oil composition.

LUBRICATING OIL COMPOSITION

Provided is a lubricating oil composition containing a mineral base oil (A) having a temperature gradient Δ|Dt| of a distillation temperature between two points of a distillation amount of 2.0% by volume and a distillation amount of 5.0% by volume in a distillation curve of 6.8° C./% by volume or less, and an antioxidant (B) containing an amine-based antioxidant (B1), a phenol-based antioxidant (B2), and a phosphorus-based antioxidant (B3), wherein the content of the component (B3) is 0.06 to 1.0% by mass based on the total amount of the lubricating oil composition. The lubricating oil composition is a long-life lubricating oil composition that maintains excellent oxidation stability even for long-term use in a high-temperature environment, and has a high effect of suppressing the generation of sludge for a long period of time. 1. A lubricating oil composition comprising:a mineral base oil (A) having a temperature gradient Δ|Dt| of a distillation temperature of 6.8° C./% by volume or less between two points of a distillation amount of 2.0% by volume and a distillation amount of 5.0% by volume in a distillation curve; andan antioxidant (B) containing an amine-based antioxidant (B1), a phenol-based antioxidant (B2), and a phosphorus-based antioxidant (B3),wherein the content of the component (B3) is 0.06 to 1.0% by mass based on the total amount of the lubricating oil composition.2. The lubricating oil composition according to claim 1 , wherein the content ratio [(B2)/(B1)] of the component (B2) to the component (B1) is 0.1 to 5.0 in terms of a mass ratio.3. The lubricating oil composition according to claim 1 , wherein the content ratio [(B3)/(B1)] of the component (B3) to the component (B1) is 0.01 to 0.60 in terms of a mass ratio.4. The lubricating oil composition according to claim 1 , wherein the content of the component (B1) is 0.10 to 3.8% by mass based on the total amount of the lubricating oil composition.5. The lubricating oil composition according to claim ...

LUBRICANT COMPOSITIONS FOR HIGH EFFICIENCY ENGINES

The instant disclosure is directed to a method of lubricating a sump-lubricated, high efficiency, gasoline-fueled internal combustion engine. Said method involves supplying to the engine a lubricating composition comprising an oil of lubricating viscosity, an anti-wear agent, an ashless antioxidant, a metal-containing detergent, an ashless polyolefin dispersant, and (f) a polymeric viscosity modifier. The disclosure further provides a method of operating a high efficiency sump-lubricated gasoline-fueled internal combustion engine while maintaining or improving at least one of durability, deposit control, oxidation control, fuel economy, and resistance to knock and stochastic pre-ignition. 1. A method of lubricating an internal combustion engine , comprising supplying to a sump-lubricated , high efficiency , gasoline-fueled internal combustion engine a lubricating composition comprising (a) an oil of lubricating viscosity , (b) an anti-wear agent in an amount 0.15 weight percent to 6 weight percent of the composition , (c) an ashless antioxidant in an amount 1.2 weight to 7 weight percent of the composition , and (d) a metal-containing detergent in an amount to deliver 0.2 weight percent sulfated ash up to 1.5 weight percent sulfated ash to the composition , (e) an ashless polyolefin dispersant in an amount 0.8 weight percent to 8 weight percent of the composition , and (f) a polymeric viscosity modifier , dispersant viscosity modifier , or mixtures thereof in an amount 0.1 weight percent to 4.5 weight percent of the composition.2. The method of claim 1 , wherein the internal combustion engine is operated at an effective compression ratio of at least 15:1.3. The method of claim 1 , wherein the internal combustion engine is operated under a load with a brake mean effective pressure (BMEP) of greater than or equal to 18 bars.4. The method of claim 1 , wherein the gasoline has an octane rating of at least 95 by the (R+M)/2 method.5. The method of claim 1 , wherein the ...

LUBRICANT COMPOSITION COMPRISING BRANCHED DIESTERS AND VISCOSITY INDEX IMPROVER

The invention refers to lubricant compositions comprising a specific diester together with a viscosity index improver. 2. Lubricant composition of claim 1 , wherein in the formula (I): n is 1;the total amount of carbon atoms being more than 15 and less than 40.3. Lubricant composition of claim 1 , wherein in the formula (I):R1 represents a linear or branched, saturated or unsaturated C5-C15 a Iky I group;R′ represents a linear or branched, saturated or unsaturated C3-C8 a Iky I group; R represents a linear or branched, saturated or unsaturated C1-C15 alkyl group.4. Lubricant composition according to claim 1 , wherein in the compound of formula (I) claim 1 ,R1 represents a saturated linear C5-C15 alkyl group, more preferably a saturated linear C5-C12 alkyl group; R′ represents a saturated linear C3-C8 alkyl group, more preferably a saturated linear C5-C8 alkyl group;R represents a saturated linear or branched C5-C15 alkyl group, more preferably a saturated linear or branched C5-C10 alkyl group.5. Lubricant composition according to claim 1 , wherein in the formula (I):R1 represents a saturated linear C5-C10 alkyl group, more preferably a saturated linear C5-C8 alkyl group;R′ represents a saturated linear C5-C8 alkyl group;R represents a saturated, linear or branched C5-C10 alkyl group, preferably a saturated linear C5-C10 alkyl group.7. Lubricant composition according to claim 1 , wherein in the formula (I):R1 represents a saturated linear or branched C5-C 5 alkyl group, more preferably a saturated linear C8-C12 alkyl group;R′ represents a saturated linear C5-C8 alkyl group;R represents a saturated, linear or branched C5-C10 alkyi group, preferably a saturated branched C5-C10 alkyl group.9. Lubricant composition according to claim 1 , wherein the viscosity index improver is a polymeric viscosity index improver claim 1 , preferably chosen among: polyacrylates and polymethacrylates claim 1 ,olefin homopolymers or copolymers, preferably ethylene/propylenestyrene ...

BRANCHED DIESTERS FOR USE TO REDUCE THE FUEL CONSUMPTION OF AN ENGINE

The invention refers to use of lubricant compositions comprising a specific diester and additives to reduce the fuel consumption of an engine. 2. Method according to claim 1 , wherein in the formula (I):n is 1;the total amount of carbon atoms being more than 15 and less than 40.3. Method according according to claim 1 , wherein in the formula (I) claim 1 ,R1 represents a linear or branched, saturated or unsaturated C5-C15 alkyl group;R′ represents a linear or branched, saturated or unsaturated C3-C8 alkyl group; R represents a linear or branched, saturated or unsaturated C1-C15 alkyl group.4. Method according according to claim 1 , wherein in the formula (I) claim 1 ,R1 represents a saturated linear C5-C15 alkyl group, more preferably a saturated linear C5-C12 alkyl group;R′ represents a saturated linear C3-C8 alkyl group, more preferably a saturated linear C5-C8 alkyl group;R represents a saturated linear or branched C5-C15 alkyl group, more preferably a saturated linear or branched C5-C10 alkyl group.5. Method according according to claim 1 , wherein in the formula (I) claim 1 ,R1 represents a saturated linear C5-C10 alkyl group, more preferably a saturated linear C5-C8 alkyl group;R′ represents a saturated linear C5-C8 alkyl group;R represents a saturated, linear or branched C5-C10 alkyl group, preferably a saturated linear C5-C10 alkyl group.7. Method according to claim 1 , wherein in the formula (I):R1 represents a saturated linear or branched C5-C15 alkyl group, more preferably a saturated linear C8-C12 alkyl group;R′ represents a saturated linear C5-C8 alkyl group;R represents a saturated, linear or branched C5-C10 alkyl group, preferably a saturated branched C5-C10 alkyl group.9. Method according to claim 1 , wherein the lubricant composition comprises from 0.1 to 50% claim 1 , preferably from 1 to 50% claim 1 , more preferably from 5 to 30% by weight based on the total weight of lubricant composition claim 1 , of a compound of formula (I).10. Method ...

REFRIGERATION OIL, AND COMPOSITION FOR USE IN REFRIGERATING MACHINE

A refrigerator oil according to one embodiment of the present invention contains: a base oil containing an oxygen-containing organic compound; a polyphosphate ester compound; and a metal salt of an organic carboxylic acid having 6 to 60 carbon atoms. 1: A refrigerator oil , comprising:a base oil comprising an oxygen-containing organic compound;a polyphosphate ester compound; anda metal salt of an organic carboxylic acid having 6 to 60 carbon atoms.2: The refrigerator oil according to claim 1 , wherein a content of the polyphosphate ester compound is from 0.01 to 5.0% by mass based on the total amount of the refrigerator oil.3: The refrigerator oil according to claim 1 , wherein a content of the metal salt of an organic carboxylic acid is 1 ppm or more in terms of metal concentration based on the total amount of the refrigerator oil.4: The refrigerator oil according to claim 1 , wherein the oxygen-containing organic compound is at least one selected from the group consisting of a polyvinyl ether compound claim 1 , a polyoxyalkylene glycol compound claim 1 , a copolymer of a poly(oxy)alkylene glycol or a monoether thereof and a polyvinyl ether claim 1 , and a polyol ester compound.6: The refrigerator oil according to claim 5 , wherein in the general formula (1) Rcomprises an arylene group.9: The refrigerator oil according to claim 1 , wherein the metal salt of an organic carboxylic acid is an alkali metal salt of an organic carboxylic acid.10: The refrigerator oil according to claim 1 , wherein the metal salt of an organic carboxylic acid is a metal salt of an organic carboxylic acid having 16 to 20 carbon atoms.11: The refrigerator oil according to claim 1 , wherein the metal salt of an organic carboxylic acid is potassium oleate.12: A composition for a refrigerator claim 1 , the composition comprising a refrigerant and the refrigerator oil according to .13: The composition for a refrigerator according to claim 12 , wherein the refrigerant is at least one selected ...

Grease wear resistance

Grease wear test device includes a body in a form of a collar having an outer surface, a first side and an opposing second side, which are open to form a hollow, open channel through the body, which has a center axis, into which opposing vee blocks can be inserted; and perpendicular to the center axis, a pair of opposing holes through and open to the outer surface of the body and the cylindrical inside wall, through which a cylindrical test journal (falex pin) can be inserted for contact in general with opposing vee-shaped channels of the inserted, opposing vee blocks, and for rotation during testing. The device can be used to modify a falex pin and vee block device, to receive and contain a small sample of grease or another organic paste product for testing such as a modified version of an ASTM D2670 test method for measuring wear properties of fluid lubricants (falex pin and vee block method). 1. A method for evaluating wear resistance and its effects on a grease or another organic paste product , which comprises carrying out the following steps , which are not necessarily conducted in series: a body in a form of a collar having an outer surface, a first side and an opposing second side;', 'the first and second sides being open so as to form a hollow, open channel through the body having a center axis, into which opposing vee blocks can be inserted; and', 'perpendicular to the center axis, a pair of opposing holes through and open to the outer surface of the body and the cylindrical inside wall, through which a cylindrical test journal (falex pin) can be inserted for contact in general with opposing vee-shaped channels of the inserted, opposing vee blocks, and for rotation during testing—, 'providing a modified falex pin and vee block device so as to further include a grease wear test device, the grease wear test device includingwherein the modified falex pin and vee block device can receive and contain a small sample of grease or another organic paste product ...

ACETIC ACID-CAPPED ESTOLIDE BASE OILS AND METHODS OF MAKING THE SAME

Provided herein are compounds, including those of the Formula II 2. The composition according to claim 1 , whereinn is an integer selected from 1 to 8; and{'sub': 2', '1', '22, 'Ris optionally substituted Cto Calkyl that is saturated or unsaturated, and branched or unbranched,'}wherein each fatty acid chain residue is unsubstituted.3. The composition according to claim 2 , whereinn is an integer selected from 1 to 6.4. (canceled)5. (canceled)6. The composition according to claim 1 , wherein Ris a branched or unbranched Cto Calkyl that is saturated or unsaturated.7. The composition according to claim 6 , wherein Ris selected from methyl claim 6 , ethyl claim 6 , propyl claim 6 , butyl claim 6 , pentyl claim 6 , hexyl claim 6 , heptyl claim 6 , octyl claim 6 , nonyl claim 6 , decanyl claim 6 , undecanyl claim 6 , dodecanyl claim 6 , tridecanyl claim 6 , tetradecanyl claim 6 , pentadecanyl claim 6 , hexadecanyl claim 6 , heptadecanyl claim 6 , octadecanyl claim 6 , nonadecanyl claim 6 , and icosanyl claim 6 , which are saturated or unsaturated and branched or unbranched.8. The composition according to claim 1 , wherein Ris selected from Cto Calkyl.9. The composition according to claim 8 , wherein Ris 2-ethylhexyl.10. The composition according to claim 1 , wherein Ris optionally substituted Cto Calkyl that is saturated or unsaturated claim 1 , and branched or unbranched.11. The composition according to claim 1 , wherein Ris optionally substituted Cto Calkyl that is saturated or unsaturated claim 1 , and branched or unbranched.12. The composition according to claim 1 , wherein Ris a branched or unbranched Cto Calkyl that is saturated and unsubstituted.13. The composition according to claim 1 , wherein said composition has an EN selected from an integer or fraction of an integer that is equal to or greater than 2 claim 1 , wherein the EN is the average number of estolide linkages in compounds according to Formula I claim 1 , a kinematic viscosity equal to or less than 5 ...

ENGINE OIL LUBRICANT COMPOSTIONS AND METHODS FOR MAKING SAME WITH SUPERIOR ENGINE WEAR PROTECTION AND CORROSION PROTECTION

Provided is an engine oil lubricant composition with improved fuel efficiency and engine wear protection. The lubricant composition may include a major amount of an oil basestock from any one or more Group I, Group II, Group III, Group IV or Group V base oils. The resulting engine oil lubricant composition may have a kinematic viscosity at 100° C. of 6 cSt or less, and a corrosion protection of at least 90, as measured according the ASTM D6557 Ball Rust Test. The resulting engine oil lubricant composition may also have a kinematic viscosity at 100° C. of 6 cSt or less, an HTHS (ASTM D4683) of less than or equal to 2.2 cP at 150° C. and a FZG failure load stage of at least 6, as measured by the FZG A10/16.6R/130 test procedure. 1. An engine oil lubricant composition comprising:a major amount of an oil basestock,about 0.1 wt % to about 5.0 wt % of a polymeric ethylene oxide friction modifier, andabout 0.1 wt % to about 8.0 wt % of at least one viscosity modifier, where the weight percents are based on the total weight of the engine oil lubricant composition, andwherein the engine oil lubricant composition has a kinematic viscosity at 100° C. of 6 cSt or less, and a corrosion protection of at least 90, as measured according the ASTM D6557 Ball Rust Test.2. The lubricant composition of claim 1 , wherein the lubricant composition further has an HTHS (ASTM D4683) of less than or equal to 2.2 cP at 150° C.3. The lubricant composition of claim 1 , wherein the at least one viscosity modifier comprises a styrenic block copolymer and the oil basestock comprises a Group I claim 1 , Group II claim 1 , Group III claim 1 , Group IV or Group V base oil.4. The lubricating engine oil of claim 1 , wherein the oil basestock comprises a Group IV base oil.5. The lubricant composition of claim 1 , wherein the major amount of the oil basestock comprises about 69 wt % to 95 wt % of a Group IV base oil claim 1 , based on the total weight of the engine oil lubricant composition.6. The ...

Lubricating oils and greases

A lubricating oil composition comprises an amide and at least one additive. A lubricating grease composition comprises a liquid amide, a thickener comprising a metal soap, and at least one additive. The amide in each composition is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant oil or grease composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant oil or grease composition.

Liquid compositions for hair removal devices comprising metathesized unsaturated polyol esters

The invention relates to liquid compositions for use with hair removal devices comprising a methathesized unsaturated polyol ester for improved lubrication.

Working Fluid Composition for Refrigerator and Refrigeration Oil

Disclosed is a working fluid composition for a refrigerating machine, comprising a refrigerating machine oil comprising an ester of a polyhydric alcohol and a fatty acid, a carbodiimide compound, and a phosphorous compound, and at least one refrigerant selected from 1, 1, 1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene, the fatty acid comprises at least one selected from fatty acids having 4 to 9 carbon atoms, and the carbodiimide compound and the phosphorus compound satisfy the conditions represented by the formula (1): 0.11 ≦ ( N C M C · W C ) ( N P M P · W P ) ≦ 4.70 ( 1 ) wherein, N c represents the number of carbodiimide groups per molecule of the carbodiimide compound, M c represents the molecular weight of the carbodiimide compound, W c represents the content of the carbodiimide compound, N p represents the number of phosphorus atoms per molecule of the phosphorus compound, M p represents the molecular weight of the phosphorus compound, and W p represents the content of the phosphorus compound.

COMPOSITION AND METHOD FOR PREVENTING OR REDUCING ENGINE KNOCK AND PRE-IGNITION IN HIGH COMPRESSION SPARK IGNITION ENGINES

A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains (i) a lubricating oil base stock comprising at least one branched ester having at least about 15% of the total carbons in the form of methyl groups, and (ii) at least one ashless antiwear additive selected from a phosphorus-containing ashless antiwear additive, a sulfur-containing ashless antiwear additive, and a phosphorus/sulfur-containing ashless antiwear additive. A lubricating engine oil having a composition that contains (i) a lubricating oil base stock comprising at least one branched ester having at least about 15% of the total carbons in the form of methyl groups, and (ii) at least one ashless antiwear additive selected from a phosphorus-containing ashless antiwear additive, a sulfur-containing ashless antiwear additive, and a phosphorus/sulfur-containing ashless antiwear additive. The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products. 1. A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil , said formulated oil having a composition comprising (i) a lubricating oil base stock comprising at least one branched ester having at least 15% of the total carbons in the form of methyl groups , and (ii) at least one ashless antiwear additive selected from the group consisting of a phosphorus-containing ashless antiwear additive , a sulfur-containing ashless antiwear additive , and a phosphorus/sulfur-containing ashless antiwear additive.2. The method of wherein the formulated oil is an ashless formulated oil.3. The method of wherein the lubricating oil base stock comprises at least one branched polyol ester having at least 30% of the total carbons ...

LUBRICATING COMPOSITION

Lubricating composition for use in the crankcase of an engine comprising: (i) a base oil comprising at least one monoester or a mixture of monoesters, wherein said monoester or mixture of monoesters has a kinematic viscosity at 100° C. of not more than 4 mm/s, a viscosity index of at least 130 and a Noack evaporation loss of not more than 20 wt %; and (ii) a polymeric viscosity index improvers selected from (a) one or more comb polymers; (b) a poly(meth)acrylate polymer having 1 to 70 mol % of one or more (meth)acrylate structural units represented by formula (1) below (1) wherein Ris a hydrogen atom or a methyl group, and Ris a straight chain or branched hydrocarbon group having not less than 16 carbon atoms; (c) styrene-diene hydrogenated copolymers; and (d) mixtures thereof. The lubricating composition of the present invention provides improved fuel economy properties. 2. A lubricating composition according to wherein said monoester or mixtures of monoesters has a kinematic viscosity at 100° C. of not more than 3.3 mm/s.3. A lubricating composition according to wherein said monoester or mixtures of monoesters has a Noack evaporation loss of not more than 15 wt %.4. A lubricating composition according to wherein the at least one monoester or mixture of monoesters is present at a total level of at least 10 wt % claim 1 , by weight of the lubricating composition.5. A lubricating composition according to wherein the at least one monoester or mixture of monoesters is present at a total level of at most 75 wt % claim 1 , by weight of the lubricating composition.6. A lubricating composition according to wherein the polymeric viscosity index improver is a comb polymer.7. A lubricating composition according to wherein the polymeric viscosity index improver is present in a solid polymer amount of from 0.1 wt % to 7 wt % claim 1 , by weight of the lubricating composition.8. A lubricating composition according to wherein said at least one monoester or mixture of said ...

Compositions and methods for inhibiting fouling in hydrocarbons or petrochemicals

Antifoulant compositions and methods are used for inhibiting fouling on structural parts of a system exposed to a fluid hydrocarbon or petrochemical stream. The antifoulant compositions may comprise at least one polyalkylene anhydride ester (“PAAE”) dispersant. Other antifoulant compositions may comprise an alkylphenol sulfide (“APS”).

LUBRICATING MEMBERS FOR RAZOR CARTRIDGES COMPRISING A METATHESIZED UNSATURATED POLYOL ESTER

The invention relates to a lubricating member for a razor cartridge comprising a lipid phase comprising a lipophilic structurant and a liquid phase, wherein said liquid phase comprises a metathesized unsaturated polyol ester which can be manufactured in a simple one batch process without thermal degradation and exhibiting improved lubricating and skin care properties over a sustained period. 1. A lubricating member comprising ,a) a liquid phase comprising a metathesized unsaturated polyol ester, said metathesized unsaturated polyol ester having one or more of the following properties:(i) a weight average molecular weight of from about 5,000 Daltons to about 50,000 Daltons;(ii) an oligomer index from greater than 0 to 1;(iii) an iodine value of from about 30 to about 200;b) a lipophilic structurant; andc) Optionally a water soluble polymer.2. A lubricating member according to claim 1 , wherein said metathesized unsaturated polyol ester having a weight average molecular weight of from about 5 claim 1 ,000 Daltons to about 50 claim 1 ,000 Daltons.3. A lubricating member according to claim 1 , wherein said metathesized unsaturated polyol ester has an iodine value of from about 30 to about 200.4. A lubricating member comprising claim 1 ,a) a liquid phase comprising a metathesized unsaturated polyol ester, said metathesized unsaturated polyol ester having a weight average molecular weight of from about 2,000 Daltons to about 50,000 Daltons; and one or more of the following properties:(i) a free hydrocarbon content, based on total weight of metathesized unsaturated polyol ester of from about 0% to about 5%;(ii) an oligomer index from greater than 0 to 1;(iii) an iodine value of from about 8 to about 200;b) a lipohilic structurant; andc) optionally a water soluble polymer5. A lubricating member according to claim 4 , wherein said metathesized unsaturated polyol ester has an iodine value of from about 10 to about 200.6. A lubricating member according to claim 4 , wherein ...

Use of a Hydrocarbyl-Substituted Salicylic Acid Detergent as an Inhibitor of Lead Corrosion

This invention relates to the use of a metallic or non-metallic detergent which is a hydrocarbyl-substituted salicylic acid or a derivative thereof in a non-aqueous lubricant composition as an inhibitor of lead corrosion associated with ashless, organic ester, anti-wear additives and/or friction modifiers. 114-. (canceled)15. A method of improving anti-corrosion properties of a non-aqueous lubricant composition comprising admixing the non-aqueous lubricant composition with a metallic or non-metallic detergent which is a hydrocarbyl-substituted salicylic acid or a derivative thereof.16. The method of claim 15 , wherein the non-aqueous lubricant composition is used to lubricate an internal combustion engine.17. The method of claim 15 , wherein the non-aqueous lubricant composition comprises an ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier.18. The method of claim 16 , wherein an ashless claim 16 , organic ester claim 16 , anti-wear additive and/or friction modifier is provided in a liquid fuel composition used to operate the internal combustion engine claim 16 , and a portion of said ashless claim 16 , organic ester claim 16 , anti-wear and/or friction modifier ingresses into the non-aqueous lubricant composition during operation of said engine.19. The method of claim 15 , wherein the hydrocarbyl-substituted salicylic acid or a derivative thereof is a metallic hydrocarbyl substituted salicylic acid or a derivative thereof.20. The method of claim 19 , wherein the metal salt is selected from the group consisting of calcium claim 19 , magnesium claim 19 , sodium and combinations thereof.21. The method of claim 15 , wherein the metallic or non-metallic detergent is a sulphurised derivative of a hydrocarbyl-substituted salicylic acid.22. The method of wherein the ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier isi) at least one fatty acid ester of a polyol,ii) at least one oil-soluble mono, di ...

DISPERSING AGENT FOR LUBRICATING OIL, METHOD FOR PRODUCING SAME, AND LUBRICATING OIL COMPOSITION

A dispersant for a lubricating oil, containing at least one compound selected from a specific nitrogen-containing compound which is obtained by using, as raw materials, (A) at least one polyolefin selected from polybutene and polyisobutene, (B) at least one maleic acid compound selected from maleic acid and maleic anhydride, and (C) polyamine; a boride of the specific nitrogen-containing compound; and an acylated product of the specific nitrogen-containing compound. The polyolefin (A) satisfies at least one of the following conditions (α) and (β). (α) a ratio (Sb/Sa) of an integrated value (Sb) of a peak present at 4.40 to 5.00 ppm in a H-NMR spectrum to an integrated value (Sa) of a peak present at 5.01 to 5.60 ppm in the 1H-NMR spectrum is 2 or more. (β) a ratio (Sd/Sc) of an integrated value (Sd) of a peak present at 1.76 to 2.10 ppm in the 1H-NMR spectrum to an integrated value (Sc) of a peak present at 1.65 to 1.75 ppm in the H-NMR spectrum is 1 or more. 2. The dispersant for a lubricating oil according to claim 1 , wherein Sb/Sa is 10 or more claim 1 , and Sd/Sc is 5 or more.3. A lubricating oil composition comprising the dispersant for a lubricating oil according to claim 1 , and a lubricant base oil.4. The lubricating oil composition according to claim 3 , further comprising an alkyl-substituted hydroxy aromatic ester derivative.6. A method of lubricating a combustion engine claim 4 , comprising: contacting a combustion engine with the lubricating oil composition of .7. A method for producing the dispersant for a lubricating oil according to claim 1 , the method comprising:(S1) reacting the at least one polyolefin (A) with the at least one maleic acid compound (B), and(S2) reacting the reaction product obtained in the (S1) with the polyamine (C) to obtain a nitrogen-containing compound.8. The method according to claim 7 , further comprising after (S1) and (S2) claim 7 ,(S3A) reacting the nitrogen-containing compound obtained in the reaction step (S2) with a ...

Lubricants for electric and hybrid vehicle applications

The present disclosure relates to methods of lubricating an electric or a hybrid-electric transmission using a lubricant including a solvent system with a blend of one or more base oils with a branched diester and one or more poly(meth)acrylate copolymers, transmissions therefor, and lubricating compositions suitable for such applications that exhibit good lubricant properties, good electrical properties, and good cooling efficiency at the same time.

BASE OIL OR LUBRICANT ADDITIVE

The present invention is toward a base oil or lubricant additives, methods of using the same, lubricant compositions including the same, and methods of forming the lubricant compositions. A base oil or lubricant additive has Structure I or Structure II as described herein. 2. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant comprises one and not more than one —R.3. The base oil or lubricant additive of claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare independently chosen from —H claim 1 , methyl claim 1 , and R.4. The base oil or lubricant additive of claim 1 , wherein each occurrence claim 1 , Ris independently chosen from —C(O)—O—R.5. The base oil or lubricant additive of claim 1 , wherein at each occurrence claim 1 , Ris independently (C-C)alkyl.6. The base oil or lubricant additive of claim 1 , wherein at each occurrence claim 1 , Ris independently —((CH—CH)—O)—CH claim 1 , wherein n is 1 to 10; —(C-C)alkyl-O-phenyl; or —(C-C)alkyl-O-naphthyl.7. The base oil or lubricant additive of claim 1 , wherein X is —O—.8. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is a lubricant additive.9. The base oil or lubricant additive of claim 1 , whereinthe base oil or lubricant additive has the structure I,{'sup': 1', '2', '3', '4', 'b, 'R, R, R, and Rare independently chosen from —H and —R,'}{'sup': b', 'b, 'the base oil or lubricant additive comprises one Rand not more than one R, and'}{'sup': 'b', 'sub': 8', '14', '22', '10', '15, 'Ris —C(O)—O—(C)alkyl, —C(O)—O—(C)alkyl, —C(O)—O—(C)alkyl, —C(O)—O—(C)alkyl, or —C(O)—O—(C)alkyl.'}12. The base oil or lubricant additive of claim 1 , wherein the base oil or lubricant additive is ocyl coumalate claim 1 , tetradecyl coumalate claim 1 , docosyl coumalate claim 1 , 4-tetradecyloxy-6-methyl-2-pyrone claim 1 , or 4-tetradecyloxy coumarin.13. The base oil or lubricant additive of claim 1 , wherein ...

COMPOSITION CONTAINING ESTER COMPOUNDS AND A METHOD OF LUBRICATING AN INTERNAL COMBUSTION ENGINE

The invention provides a lubricating composition containing a β-amino compound. The invention further relates to a method of lubricating an internal combustion engine by lubricating the engine with the lubricating composition. The invention further relates to the use of the β-amino carbonyl compound as copper corrosion inhibitors, friction control agents, antiwear and/or extreme pressure agents. 2. The lubricating composition of claim 1 , wherein one of Ror Ris hydrogen and the other of Ror Ris a hydrocarbyl group or substituted hydrocarbyl group selected from the group consisting of(i) an acyl-substituted hydrocarbyl group with no primary amines,(ii) an optionally substituted alk(en)yl chain containing 1 to 30 carbon atoms; and(iii) an ether-substituted hydrocarbyl group containing 1 to 30 carbon atoms.3. The lubricating composition of claim 1 , wherein each of Rare Rare a hydrocarbyl group or substituted hydrocarbyl group selected from the group consisting of(i) an acyl-substituted hydrocarbyl group with no primary amines,(ii) an optionally substituted alk(en)yl chain containing 1 to 30 carbon atoms; and(iii) an ether-substituted hydrocarbyl group containing 1 to 30 carbon atoms.4. The lubricating composition of further comprising an amide claim 1 , ester or imide derivative of a hydroxy-carboxylic acid claim 1 , or mixtures thereof.5. The lubricating composition of claim 4 , wherein the amide claim 4 , ester or imide derivative of a hydroxy-carboxylic acid is a compound derived from tartaric acid or citric acid.6. The lubricating composition of claim 4 , wherein the amide claim 4 , ester or imide derivative of a hydroxy-carboxylic acid is a compound derived from tartaric acid.7. The lubricating composition of claim 4 , wherein the β-amino carbonyl compound is present at 0.05 to 5 wt % of the lubricating composition claim 4 , and (b) the amide claim 4 , ester or imide derivative of a hydroxy-carboxylic acid is present at 0.05 to 5 wt % of the lubricating ...

REFRIGERATOR OIL AND REFRIGERATOR WORKING FLUID COMPOSITION

The present invention provides a refrigerating machine oil comprising at least one oxygen-containing oil having a carbon/oxygen molar ratio of 2.5 or more and 5.8 or less as a base oil, and the refrigerating machine oil being used with a trifluoroethylene refrigerant. 1. A refrigerating machine oil comprising at least one oxygen-containing oil having a carbon/oxygen molar ratio of 2.5 or more and 5.8 or less as a base oil , and the refrigerating machine oil being used with a trifluoroethylene refrigerant.2. The refrigerating machine oil according to claim 1 , comprising an ester of a fatty acid and a polyhydric alcohol as the oxygen-containing oil claim 1 , the fatty acid comprising a branched fatty acid having 4 to 9 carbon atoms in a proportion of 20 to 100 mol %.3. A working fluid composition for a refrigerating machine comprising:a refrigerating machine oil comprising at least one oxygen-containing oil having a carbon/oxygen molar ratio of 2.5 or more and 5.8 or less as a base oil; anda trifluoroethylene refrigerant.4. The working fluid composition for a refrigerating machine according to claim 3 , wherein the refrigerating machine oil comprises an ester of a fatty acid and a polyhydric alcohol as the oxygen-containing oil claim 3 , the fatty acid comprising a branched fatty acid having 4 to 9 carbon atoms in a proportion of 20 to 100 mol %.5. (canceled)6. (canceled) The present invention relates to a refrigerating machine oil and a working fluid composition for a refrigerating machine.Against the background of the recent problem of ozone layer depletion, CFC (chlorofluorocarbon) and HCFC (hydrochloro-fluorocarbon) conventionally used as refrigerants for refrigerating machines are subject to regulation and, instead of them, HFC (hydrofluorocarbon) is becoming widely used as a refrigerant. However, one of the HFC refrigerants, HFC-134a, which is commonly used as a refrigerant for car air conditioners, is subject to regulation in Europe due to its high global ...

UNSATURATED POLYOL ESTERS USED IN HYDRAULIC FLUID APPLICATIONS

This invention relates to unsaturated polyol esters that can be used in hydraulic fluid applications, including fire-resistant hydraulic fluid applications, marine hydraulic fluid applications, metalworking fluid applications, food grade fluid applications, and transformer fluid applications, and methods for making the same. 2. The unsaturated polyol ester composition of claim 1 , wherein the composition comprises a: (i) total acid number of less than 1 claim 1 , (ii) a kinematic viscosity at 100° C. of between about 4.6 cSt and about 6.2 cSt claim 1 , (iii) a kinematic viscosity at 40° C. of between about 20.3 cSt and about 28.3 cSt claim 1 , (iv) a viscosity index of between about 154.2 and 173.7 claim 1 , (v) a pour point of less than about −42° C. claim 1 , (vi) an iodine value of between about 109.8 and about and 127.7 claim 1 , (vii) a hydroxy value of between about 12.1 and about 14.8 claim 1 , and (viii) an aniline point of less than 20.3. The unsaturated polyol ester composition of claim 1 , wherein the composition comprises about a 1.6 fold to about 8.95 fold increase an oxidation onset time when loaded with 0.5% w/w antioxidant.4. The unsaturated polyol ester composition of claim 1 , wherein the composition comprises about a 2.86 fold to about 9.67 fold increase an oxidation onset time when loaded with 1.5% w/w antioxidant.5. The unsaturated polyol ester composition of claim 1 , wherein the composition comprises a coefficient of friction: (i) at 50° C. of between about 0.06 and about 0.08 claim 1 , (ii) at 75° C. of between about 0.06 and about 0.1 claim 1 , and (iii) at 100° C. of between about 0.07 and about 0.09.6. The unsaturated polyol ester composition of claim 1 , wherein the composition is used in a hydraulic fluid application.8. The unsaturated polyol ester composition of claim 7 , wherein the composition comprises a: (i) total acid number of less than 1 claim 7 , (ii) a kinematic viscosity at 100° C. of between about 6.9 cSt and about 8.9 cSt ...

Use of Glycerides of Hydroxy Polycarboxylic Acids as Anti-Camshaft-Wear Additives in Lubricants and Fuels

This invention relates to the use of an oil-soluble mono-, di-, or tri-glyceride of at least one hydroxy polycarboxylic acid, or a derivative thereof, as an anti-camshaft-wear additive in a non-aqueous lubricant composition and/or in a fuel composition. 117-. (canceled)18. A method of improving anti-camshaft-wear properties of a non-aqueous lubricant composition and/or fuel composition comprising admixing an oil-soluble mono- , di- , or tri-glyceride of at least one hydroxy polycarboxylic acid , or a derivative thereof , in the non-aqueous lubricant composition and/or in the fuel composition.19. The method of claim 18 , wherein the oil-soluble mono- claim 18 , di- claim 18 , or tri-glyceride of at least one hydroxy polycarboxylic acid claim 18 , or a derivative thereof claim 18 , reduces camshaft wear as measured in the OM646LA engine test.20. The method of claim 18 , wherein the lubricant composition is used to lubricate an internal combustion engine.21. The method of claim 20 , wherein the oil-soluble mono- claim 20 , di- claim 20 , or tri-glyceride of at least one hydroxy polycarboxylic acid claim 20 , or a derivative thereof claim 20 , is provided in a liquid fuel composition used to operate the internal combustion engine claim 20 , and a portion at least claim 20 , of said glyceride ingresses into the lubricating oil composition during operation of said engine.22. The method of claim 18 , wherein the hydroxy polycarboxylic acid has at least one hydroxy group which is in an alpha position with respect to a carboxylic moiety.23. The method of claim 22 , wherein the hydroxy polycarboxylic acid is citric acid.24. The method of claim 18 , wherein the glyceride is a glyceride of at least one hydroxy polycarboxylic acid and at least one second carboxylic acid which is a saturated claim 18 , mono-unsaturated or poly-unsaturated claim 18 , branched or linear claim 18 , monocarboxylic or polycarboxylic acid having 4 to 22 carbon atoms claim 18 , or a derivative thereof. ...

REFRIGERATION OIL COMPOSITION AND WORKING FLUID FOR REFRIGERATION SYSTEM

A refrigeration oil composition includes: a mixture of a naphthenic mineral oil and at least one of a polyol ester oil and a polyvinyl ether oil; and at least one of a sorbitan compound and a glycerin fatty acid ester and a working fluid for a refrigeration system includes: the refrigeration oil composition; and one or more refrigerants selected from a hydrofluorocarbon refrigerant, a hydrofluoroolefin refrigerant and a carbon dioxide refrigerant. 1. A refrigeration oil composition comprising:a mixture of a naphthenic mineral oil and at least one of a polyol ester oil and a polyvinyl ether oil; andat least one of a sorbitan compound and a glycerin fatty acid ester.2. The refrigeration oil composition according to claim 1 , comprising the mixture of the naphthenic mineral oil and the polyol ester oil claim 1 , and the sorbitan compound.3. The refrigeration oil composition according to claim 1 , comprising the mixture of the naphthenic mineral oil and the polyvinyl ether oil claim 1 , and the at least one of the sorbitan compound and the glycerin fatty acid ester.4. The refrigeration oil composition according to claim 1 , wherein in the mixture claim 1 , a mass ratio of the naphthenic mineral oil to the at least one of the polyol ester oil and the polyvinyl ether oil is that the naphthenic mineral oil:the at least one of the polyol ester oil and the polyvinyl ether oil=from 60:40 to 90:10.5. The refrigeration oil composition according to claim 1 , wherein a content of the at least one of the sorbitan compound and the glycerin fatty acid ester is from 0.5 mass % to 5 mass % of a total amount of the refrigeration oil composition.6. The refrigeration oil composition according to claim 1 , wherein a kinematic viscosity of the naphthenic mineral oil at 40° C. is from 5 mm/s to 460 mm/s claim 1 , and a kinematic viscosity of the at least one of the polyol ester oil and the polyvinyl ether oil at 40° C. is from 5 mm/s to 350 mm/s.7. The refrigeration oil composition ...

Shear-Stable Oil Compositions and Processes for Making the Same

An oil composition comprising a first component having pendant groups and a second component but free of a third component and process for making such oil composition, where a single molecule of the third component can form large shearable stable complex structure with two molecules of the first component via van der Waals force between pendant groups and the terminal carbon chains, and a single molecule of the second component is capable of adjoining no more than one molecule of the first type. The oil composition has high shear stability making it suitable for use in lubricants subject to repeated high shear stress events. 1. An oil composition comprising a first component and a second component differing from the first component and free of a third component , wherein:the first component is a base stock comprising multiple molecules of a first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≧5.0; and (ii) a portion of the molecules of the first type have molecular weight greater than or equal to 20,000;the second component comprises multiple molecules of a second type each of which individually is capable of adjoining no more than one molecule of the first type via van der Waals force between straight carbon chains to form a stable first complex structure; andthe third component comprises molecules of a third type each comprising two terminal carbon chains, where (i) the number average molecular weight of the third component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom.2. The oil composition of claim 1 , wherein:the molecules of the second type comprise one or zero terminal carbon chain that has a chain length equal to or greater than 5.0.3. The oil composition of claim ...

Shear-Stable Oil Compositions and Processes for Making the Same

An oil composition comprising a first component having pendant groups, a second component having two or more terminal carbon chains, and optionally a third component, where a single molecule of the second component can form shearable stable structure with two molecules of the first component via van der Waals force between pendant groups and the terminal carbon chains. Shear stability of the oil can be improved if the total concentration of the heavy fraction of the shearable stable structure is controlled at a low concentration. 1. An oil composition comprising a first component and a second component different from the first component , wherein:the first component is a base stock comprising multiple molecules of a first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≧5.0; and (ii) a portion of the molecules of the first type have a number-average molecular weight greater than or equal to 20,000;the second component comprises multiple molecules of a second type each comprising two terminal carbon chains, where (i) the number-average molecular weight of the second component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom;a single molecule of the second type is capable of adjoining two molecules of the first type via van der Waals force between the pendant groups of the molecules of the first type and the two terminal carbon chains in the single molecule of the second type to form a first complex structure, the first complex structures comprising a first heavy fraction thereof having an equivalent number-average molecular weight of at least 45,000; {'br': None, 'i': 'C', '11(max)≦20.'}, 'the total maximum theoretical concentration of the first heavy fraction of the first ...

Use of a Boron-Containing Additive as an Inhibitor of Lead Corrosion

This invention relates to the use of a boron-containing additive in a non-aqueous lubricant composition as an inhibit or of lead corrosion associated with ashless, organic ester, anti-wear additives and/or friction modifiers. 114-. (canceled)15. A method of improving anti-corrosion properties of a non-aqueous lubricant composition comprising admixing the non-aqueous lubricant composition with a boron-containing additive.16. The method of claim 15 , wherein the non-aqueous lubricant composition is used to lubricate an internal combustion engine.17. The method of claim 15 , wherein the non-aqueous lubricant composition comprises an ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier.18. The method of claim 16 , wherein an ashless claim 16 , organic ester claim 16 , anti-wear additive and/or friction modifier is provided in a liquid fuel composition used to operate the internal combustion engine claim 16 , and a portion of said ashless claim 16 , organic ester claim 16 , anti-wear and/or friction modifier ingresses into the non-aqueous lubricant composition during operation of said engine.19. The method of claim 15 , wherein the boron-containing additive is a borated dispersant.20. The method of claim 19 , wherein the borated dispersant is a borated ester.21. The method of claim 20 , wherein the borated ester is a borated succinate ester or a borated succinate ester amide.22. The method of wherein the ashless claim 15 , organic ester claim 15 , anti-wear additive and/or friction modifier isi) at least one fatty acid ester of a polyol,ii) at least one oil-soluble mono, di-, or tri-glyceride of at least one hydroxy polycarboxylic acid, or a derivative thereof;iii) at least one long chain fatty acid ester of a hydroxy carboxylic acid in which the long chain fatty acid has at least 4 carbon atoms and the ester is an oil-soluble ester of a mono- or poly-hydroxy carboxylic acid containing 1 to 4 groups which are independently carboxylic ...

Auxiliary Emergency Protective Lubrication System for Metal Mechanical Components

An auxiliary lubricant comprising a composition, the comprising intermediate molecular weight surfactant-functionalized nanoparticles dispersed in a base oil. 1. An auxiliary lubricant comprising:a composition comprising intermediate molecular weight surfactant-functionalized nanoparticles dispersed in a base oil.2. The auxiliary lubricant according to claim 1 , wherein said nanoparticles comprises at least one of a carbon-containing phase and an inorganic phase.3. The auxiliary lubricant according to claim 2 , wherein said nanoparticles in said inorganic phase are selected from the group consisting of boric acid claim 2 , metal sulfides claim 2 , and alkali silicates.4. The auxiliary lubricant according to claim 3 , wherein said metal sulfide comprises Zn claim 3 , W claim 3 , and Mo.5. The auxiliary lubricant according to claim 3 , wherein said alkali silicate comprises Na and K.6. The auxiliary lubricant according to claim 2 , wherein said carbon-containing phase comprises at least one of graphene claim 2 , ultra-dispersed nano-crystalline diamond and graphite claim 2 , spheroidal carbons claim 2 , and carbon nanorods.7. The auxiliary lubricant according to claim 1 , wherein said nanoparticles comprise a dimension ranging from about 1 nanometer to about 20 nanometers.8. The auxiliary lubricant according to claim 1 , wherein said nanoparticles comprise a dimension less than 1 nanometer.9. The auxiliary lubricant according to claim 1 , wherein said nanoparticles comprise a narrow-size distribution with an aspect ratio greater than 2.10. The auxiliary lubricant according to claim 1 , wherein said nanoparticles are functionalized with amphoteric surfactants containing alcohol claim 1 , amine claim 1 , carboxylic acid claim 1 , carbonate claim 1 , ester claim 1 , ether alcohol claim 1 , sulfate claim 1 , sulphonate claim 1 , phosphate claim 1 , phosphite claim 1 , or phosphonate head groups and intermediate molecular weight hydrocarbon claim 1 , fluorocarbon claim 1 , ...

REFRIGERATOR OIL AND WORKING FLUID COMPOSITION FOR REFRIGERATORS

The present invention provides a refrigerating machine oil comprising: a base oil containing an ester of dipentaerythritol with 2-methylbutanoic acid and n-pentanoic acid; and at least one epoxy compound selected from the group consisting of a glycidyl ester compound and a glycidyl ether compound, the refrigerating machine oil being used with a difluoromethane refrigerant. 1. A refrigerating machine oil comprising:a base oil comprising an ester of dipentaerythritol with 2-methylbutanoic acid and n-pentanoic acid; andat least one epoxy compound selected from the group consisting of a glycidyl ester compound and a glycidyl ether compound.2. The refrigerating machine oil according to claim 1 , wherein a ratio of the ester in the base oil is 30% by mass or more and 100% by mass or less.3. The refrigerating machine oil according to claim 1 , wherein a content of the epoxy compound is 0.01% by mass or more and 5.0% by mass or less based on a total amount of the refrigerating machine oil.4. A working fluid composition for a refrigerating machine claim 1 , comprising: a base oil comprising an ester of dipentaerythritol with 2-methylbutanoic acid and n-pentanoic acid; and', 'at least one epoxy compound selected from the group consisting of a glycidyl ester compound and a glycidyl ether compound; and, 'a refrigerating machine oil comprisinga refrigerant comprising a difluoromethane refrigerant.5. The working fluid composition for a refrigerating machine according to claim 4 , wherein a ratio of the ester in the base oil is 30% by mass or more and 100% by mass or less.6. The working fluid composition for a refrigerating machine according to claim 4 , wherein a content of the epoxy compound is 0.01% by mass or more and 5.0% by mass or less based on a total amount of the refrigerating machine oil. The present invention relates to a refrigerating machine oil and a working fluid composition for a refrigerating machine.Refrigerating machines such as refrigerators, car air- ...

Estolide Compositions Exhibiting Superior High-Performance Properties

Compounds and compositions, including engine oils and lubricant formulations comprising at least one estolide compound. Exemplary compositions comprise an estolide base oil and an additive package.

Water-Based Lubricants for Conveyor Belts

The invention relates to water-based lubricants for conveyor belts. More particularly, the invention relates to water-based lubricants for conveyor belts for the drinks industry. 1. Water-based lubricant composition for conveyor belts , comprising:4% to 30% by weight of at least one viscosifying component,0.05% to 10% by weight of preservative substances that provide protection from soiling,water to 100% by weight,characterized in that the viscosifying component is a water-soluble carboxylic ester, or a mixture of a water-soluble carboxylic ester and a low molecular weight polyalkylene glycol.2. Lubricant composition according to claim 1 , further comprising one or more components selected from the group consisting of:0.05% to 5% by weight of antiwear agent,0.05% to 15% by weight of antifreeze,0.05% to 15% by weight of anticorrosive,0.05% to 5% by weight of antiwear agent,0.05% to 5% by weight of defoamer,0.05% to 5% by weight of wetting agent,0.05% to 5% by weight of biocides,0.005% to 2% by weight of fragrances.3. Lubricant composition according to claim 1 , characterized in that the preservative substances that provide protection from soiling are a compound or mixture selected from the group consisting of foaming or non-foaming emulsifiers from the class of ionic and nonionic surfactants.4. Lubricant composition according to claim 2 , characterized in that the antiwear agent is a water-soluble compound containing sulfur claim 2 , phosphorus and/or nitrogen.5. Lubricant composition according to claim 2 , characterized in that the antifreeze is a compound selected from the group consisting of mono- and polyhydric alcohols and derivatives thereof.6. Lubricant composition according to claim 2 , characterized in that the anticorrosive is a compound selected from the group consisting of neutralized and non-neutralized carboxylic acids claim 2 , neutralized phosphoric acids and/or phosphoric acid derivatives claim 2 , benzoic acid and/or benzoic acid derivatives claim 2 ...

System and method for retrofitting a refrigeration system from hcfc to hfc refrigerant

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture. The polyol ester lubricant may be present in a range exceeding about 5-15% by weight, e.g., 8%.

ANTIOXIDANT MIXTURE FOR HIGH VISCOUS POLYALKYLENE GLYCOL BASESTOCK

The invention relates to a lubricant comprising a polyalkylene glycol basestock, a phenol selected from an ester of 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid with a Caliphatic alcohol, and an aromatic amine of the formula (I) as defined hereinafter. The invention further relates to a method for preparing the lubricant comprising the step of contacting the polyalkylene glycol basestock, the phenol, and the aromatic amine of the formula (I); and to a method for reducing the oxidative degradation of the polyalkylene glycol basestock comprising the step of contacting the polyalkylene glycol basestock, the phenol, and the aromatic amine of the formula (I). 115.-. (canceled)17. The lubricant according to claim 16 , where the phenol is an ester of 3-(3 claim 16 ,5-di-tert-butyl-4-hydroxyphenyl) propionic acid with methanol claim 16 , ethanol claim 16 , n-octanol claim 16 , isooctanol claim 16 , octadecanol claim 16 , 1 claim 16 ,6-hexanediol claim 16 , 1 claim 16 ,9-nonanediol claim 16 , ethylene glycol claim 16 , 1 claim 16 ,2-propanediol claim 16 , neopentyl glycol claim 16 , diethylene glycol claim 16 , triethylene glycol claim 16 , pentaerythritol claim 16 , trimethylhexanediol claim 16 , trimethylolpropane.18. The lubricant according to claim 16 , where the phenol is an ester of 3-(3 claim 16 ,5-di-tert-butyl-4-hydroxyphenyl) propionic acid with isooctanol or 1 claim 16 ,6-hexanediol.19. The lubricant according to claim 16 , where the polyalkylene glycol basestock has a kinematic viscosity at 40° C. in the range from 500-3000 mm/s.20. The lubricant according to claim 16 , where the polyalkylene glycol basestock is an ethoxylated and propoxylated C-Calkanol or C-Calkandiol.21. The lubricant according to claim 16 , where the polyalkylene glycol basestock is an ethoxylated and propoxylated C-Calkandiol.22. The lubricant according to claim 16 , where the polyalkylene glycol basestock is an alkoxylated alcohol with a number average molecular weight Mn in the ...

COMPOSITION BASED ON 1,3,3,3-TETRAFLUOROPROPENE

A composition including a lubricant based on polyol esters (POEs) or PVE and a refrigerant F including from 1 to 99% by weight of trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze) and from 1 to 99% by weight of 1,1,1,2-tetrafluoroethane. Also, the use of the composition including a lubricant and refrigerant in refrigeration, air conditioning and heat pumps. 17-. (canceled)8. A composition comprising at least one lubricant comprising at least one polyol ester or at least one polyvinyl ether and a refrigerant comprising from 5 to 10% by weight of trans-1 ,3 ,3 ,3-tetrafluoropropene (trans-HFO-1234ze) and from 10 to 30% by weight of 1 ,1 ,1 ,2-tetrafluoroethane.9. The composition according to claim 8 , wherein the refrigerant comprises from 5 to 10% by weight of trans-1 claim 8 ,3 claim 8 ,3 claim 8 ,3-tetrafluoropropene (trans-HFO-1234ze) and from 20 to 30% by weight of 1 claim 8 ,1 claim 8 ,1 claim 8 ,2-tetrafluoroethane.10. The composition according to claim 8 , wherein the at least one lubricant comprises at least one polyol ester claim 8 , wherein the at least one polyol ester is obtained from a polyol having a neopentyl backbone.11. The composition according to claim 10 , wherein the polyol having a neopentyl backbone is selected from the group consisting of neopentyl glycol claim 10 , trimethylolpropane claim 10 , and dipentaerythritol.12. The composition according to claim 8 , wherein the at least one lubricant comprises at least one polyol ester claim 8 , wherein the at least one polyol ester is obtained from a linear or branched carboxylic acid containing from 2 to 15 carbon atoms.13. The composition according to claim 8 , wherein the at least one lubricant comprises at least one polyol ester claim 8 , wherein the at least one polyol ester is between 10 and 50% by weight of the composition.14. The composition according to claim 8 , wherein the polyvinyl ether represents between 10 and 50% by weight of the composition.16. The composition according to claim ...

Lubricant composition promoting sustained fuel economy

A lubricant composition includes a controlled release friction modifier (CRFM), a highly paraffinic base stock, a dispersant and a detergent. The CRFM includes an ionic tetrahedral borate compound including a cation and a tetrahedral borate anion, wherein the tetrahedral borate anion comprises a boron atom having two bidentate di-oxo ligands of C18 tartrimide. The lubricant composition can also include at least one of a Group V co-base stock, an inorganic friction modifier, a viscosity modifier, and a cleanliness booster.

LUBRICATING OIL COMPOSITION, LUBRICATION METHOD, AND TRANSMISSION

Provided are: a lubricating oil composition containing a mineral oil (A) having a kinematic viscosity at 40° C. of 5 to 15 mm/s and a flash point of 180° C. or higher, a synthetic oil (B) having a kinematic viscosity at 40° C. of 5 to 15 mm/s and a flash point of 190° C. or higher, an amide compound (C) and a polyol ester compound (D), which has a low viscosity and fuel saving performance, which can be used in high-temperature environments, and which has excellent gear anti-seizing property and anti-shudder performance; and a lubrication method and a transmission using the lubricating oil composition. 1. A lubricating oil composition , comprising:{'sup': '2', '(A) a mineral oil (A) having a kinematic viscosity at 40° C. of 5 to 15 mm/s and a flash point of 180° C. or higher;'}{'sup': '2', '(B) a synthetic oil (B) having a kinematic viscosity at 40° C. of 5 to 15 mm/s and a flash point of 190° C. or higher;'}(C) an amide compound (C); and(D) a polyol ester compound (D).2. The lubricating oil composition according to claim 1 , wherein the amide compound (C) is a reaction product of an amine compound and a carboxylic acid compound.3. The lubricating oil composition according to claim 2 , wherein the amine compound is an aliphatic polyamine having 6 to 30 carbon atoms claim 2 , and the carboxylic acid compound is a carboxylic acid having 6 to 30 carbon atoms.4. The lubricating oil composition according to claim 1 , wherein the polyol ester compound (D) is a reaction product of a polyol and a carboxylic acid compound.5. The lubricating oil composition according to claim 4 , wherein the polyol is an aliphatic polyol having 2 to 15 carbon atoms claim 4 , and the carboxylic acid compound is a carboxylic acid having 12 to 24 carbon atoms.6. The lubricating oil composition according to claim 1 , wherein the content of the synthetic oil (B) is from 3 to 50% by mass based on the total amount of the composition.7. The lubricating oil composition according to claim 1 , wherein ...

Heat transfer compositions having improved miscibility with lubricating oil

A composition including 2,3,3,3-tetrafluoropropene and a lubricating oil including a polyalkylene glycol and a polyol ester, the polyol ester content in the lubricating oil being less than or equal to 25%. A method of lubricating a vapor compression circuit, the method including using a mixture including a polyalkylene glycol and a polyol ester as lubricating oil in the vapor compression circuit, in combination with a heat transfer fluid comprising 2,3,3,3-tetrafluoropropene, the content of polyol ester in the lubricating oil being less than or equal to 25%. Further, the use of said composition in methods for heating or cooling.

LOW VISCOSITY LOW VOLATILITY BENZOATE MONOESTER LUBRICATING OIL BASE STOCKS AND METHODS OF USE THEREOF

A composition including one or more benzoate monoester compounds represented by the formulae (I), (II), (III), (IV) and (V) as defined herein. The composition has a viscosity (K) from about 1 cSt to about 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from about −100 to about 300 as determined by ASTM D2270, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition. 2. The composition of which has a viscosity (K) from about 2 cSt to about 8 cSt at 100° C. as determined by ASTM D445 claim 1 , a viscosity index (VI) from about 25 to about 150 as determined by ASTM D2270 claim 1 , and a Noack volatility of no greater than 25 percent as determined by ASTM D5800.3. The composition of claim 1 , wherein the composition is selected from the group consisting of 2-butyloctyl 4-butyl benzoate claim 1 , 2-ethylhexyl 4-heptylbenzoate claim 1 , butyloctyl 4-cyano benzoate claim 1 , 2-hexyldecyl 4-methyl benzoate claim 1 , 2-hexyldecyl 2-methyl benzoate claim 1 , 2-hexyldecyl 3-methyl benzoate claim 1 , 2-hexyldecyl 2 claim 1 ,6 dimethyl benzoate claim 1 , 2-hexyldecyl 2-ethylbenzoate claim 1 , 2-hexyldecyl 2-methoxybenzoate claim 1 , 2-hexyldecyl 3-methoxybenzoate claim 1 , 2-hexyldecyl 4-methoxybenzoate claim 1 , 2-hexyldecyl 2-fluorobenzoate claim 1 , 2-hexyldecyl 3-fluorobenzoate claim 1 , 2-hexyldecyl 4-fluorobenzoate claim 1 , and combinations thereof.5. The composition of which has a viscosity (K) from about 2 cSt to about 8 cSt at 100° C. as determined by ASTM D445 claim 4 , a viscosity index (VI) from about 25 to about 150 as determined by ASTM D2270 claim 4 , ...

LUBRICATING OIL COMPOSITIONS WITH OXIDATIVE STABILITY IN DIESEL ENGINES USING BIODIESEL FUEL

A method for improving oxidative stability of a lubricating oil in a diesel engine, in which biodiesel fuel is used with diesel fuel in the diesel engine, by using as the lubricating oil a formulated oil. The formulated oil has a composition including at least one Group V lubricating oil base stock. The at least one Group V lubricating oil base stock is present in an amount from 1 to 75 weight percent, based on the total weight of the lubricating oil. Oxidative stability is improved in a diesel engine lubricated with the lubricating oil, as compared to oxidative stability achieved in a diesel engine lubricated with a lubricating oil not having the at least one Group V lubricating oil base stock, as determined by a CEC L-109-16 Bio-Diesel Oxidation Bench test. The lubricating oils are useful as passenger vehicle engine oil (PVEO) products or commercial vehicle engine oil (CVEO) products. 1. A method for improving oxidative stability of a lubricating oil in a diesel engine , wherein biodiesel fuel is used with diesel fuel in the diesel engine , by using as the lubricating oil a formulated oil , said formulated oil having a composition comprising at least one Group V lubricating oil base stock; wherein the at least one Group V lubricating oil base stock is present in an amount from 1 to 75 weight percent , based on the total weight of the lubricating oil; and wherein oxidative stability is improved in a diesel engine lubricated with the lubricating oil , as compared to oxidative stability achieved in a diesel engine lubricated with a lubricating oil not having the at least one Group V lubricating oil base stock , as determined by a CEC L-109-16 Bio-Diesel Oxidation Bench test.2. The method of wherein claim 1 , in a CEC L-109-16 Bio-Diesel Oxidation Bench test claim 1 , the time for a relative kinematic viscosity at 100° C. (KV100) increase of 100% of said lubricating oil claim 1 , is greater than the time for a relative kinematic viscosity at 100° C. (KV100) increase ...

LUBRICANT COMPOSITION, COMPOSITION FOR REFRIGERATING MACHINES, AND METHOD FOR DETECTING LEAKAGE POINT

Provided is a lubricant composition which is excellent in thermal stability and chemical stability while making it possible to detect a leakage point of the lubricant composition, etc. with a fluorescent agent. The lubricant composition is one containing a base oil (A) and a fused ring compound (B) being fluorescent, having a tri- or higher fused ring, and not having nitrogen, oxygen, and sulfur in a molecule thereof, wherein the fused ring compound (B) is contained in an amount of 0.001 to 1.0% by mass on a basis of the whole amount of the lubricant composition. 1: A lubricant composition , comprising(A) a base oil (A); and(B) a fluorescent fused ring compound (B) being fluorescent, having a tri- or higher fused ring, and not having nitrogen, oxygen, and sulfur in a molecule thereof,wherein the fused ring compound (B) is contained in an amount of 0.001 to 1.0% by mass on a basis of the whole amount of the lubricant composition.2: The lubricant composition according to claim 1 , wherein the base oil (A) is at least one selected from the group consisting of a mineral oil claim 1 , a polyalkylene glycol claim 1 , a polyvinyl ether claim 1 , a polyol ester claim 1 , an alkylbenzene claim 1 , and a poly-α-olefin.3: The lubricant composition according to claim 1 , wherein the fused ring compound (B) is at least one selected from the group consisting of a perylene-based compound claim 1 , a naphthacene-based compound claim 1 , and an anthracene-based compound.4: The lubricant composition according to claim 1 , further comprising(C) a coloring agent (C).5: The lubricant composition according to claim 1 , which is adapted to function as a lubricant composition for any of a refrigerator oil claim 1 , a hydraulic oil claim 1 , a bearing oil claim 1 , a gear oil claim 1 , a turbine oil claim 1 , a transmission oil claim 1 , a shock absorber oil claim 1 , and a motor cooling oil.6: A composition for refrigerating machines claim 1 , the composition comprising the lubricant ...

Lubricant for preventing and removing carbon deposits in internal combustion engines

A lubricant formulation which is effective to remove or prevent carbon deposits in internal combustion engines has a solvency as defined by aniline point from about 20 to about 115, a volatility (as measured by NOACK) of less than 15%, an oxidative stability (as measured by PDSC) of above 40 minutes and a base oil viscosity of above 2 and below 10 cSt. The lubricant formulation can be formed from a blend of Group III, IV and V lubricants, in particularly polyalphaolefins, alkylated naphthalenes and polar Group V base stocks such as polyol esters. The carbon deposits can be removed from the engine piston by simply running the engine with the lubricant for one required cycle, or can be used continuously in the engine to prevent buildup.

LUBRICANT ADDITIVES AND COMPOSITIONS

Embodiments are described herein to provide a functional composition that can be added to the lubricant of the HVAC system to help prevent/reduce the lubricant breakdown. The functional composition can also help prevent/reduce material deposition on, for example, an orifice of an expansion or heat transfer surface(s) or heat transfer surface(s). The functional composition can be added as an additive to a lubricant of a HVAC system to form a lubricant composition. The lubricant composition can be added to a HVAC system to help prevent/reduce the material deposition. In some embodiments, the functional composition can be added to a HVAC system during operation of the HVAC system to help remove/reduce existing material deposition. 1. A functional composition of a lubricant in a HVAC system , comprising one or a combination of:a compound that interferes with lubricant breakdown,a compound that interferes with formation of metal carboxylates on a load bearing surface;a compound that coats the load bearing surfaces so as to reduce deposition of metal-carboxylates on the loading surface;a compound that reduces a catalytic effect of the metal carboxylates;a compound that changes a polarity and/or acidity of the lubricant so as to remove the deposited lubricant breakdown;a compound that coats an expansion device or heat transfer surface of the HVAC system so as to prevent deposition of the lubricant breakdown; anda compound that changes the polarity of the lubricant so as to increase a solubility of metal carboxylates.2. The functional composition of claim 1 , wherein the lubricant is selected from a group comprising polyolester polyvinyl ether claim 1 , alkylbenzene claim 1 , polyalphaolefins claim 1 , alkylated naphthenics claim 1 , mineral oil claim 1 , and a combination thereof.3. The functional composition of claim 1 , wherein the HVAC system includes a HFC refrigerant.4. A method of treating a lubricant composition of a HVAC system claim 1 , comprising:adding a ...

Heat transfer methods, systems and compositions

Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of: from about 40% by weight to about 49% by weight difluoromethane (HFC-32), from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125), from about 33% by weight to about 40% by weight trifluoroiodomethane (CF 3 I); and from about 2% by weight to about 12% by weight of trans 1,3,3,3-tetrafluoropropene (trans HFO-1234ze), wherein the percentages are based on the total weight of the three compounds in the blend, and systems and method using same.

HEAT TRANSFER METHODS, SYSTEMS AND COMPOSITIONS

Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of: 1. A refrigerant comprising at least about 97% by weight of a blend of three compounds , said blend consisting of:from about 38% by weight to about 48% by weight difluoromethane (HFC-32),from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125),{'sub': '3', 'from about 33% by weight to about 41% by weight trifluoroiodomethane (CFI) and'}from about 2% by weight to about 16% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)wherein the percentages are based on the total weight of the three compounds in the blend.2. The refrigerant of wherein said blend consists of:from about 46% by weight to about 48% by weight difluoromethane (HFC-32),from about 11% by weight to about 12% by weight pentafluoroethane (HFC-125),{'sub': '3', 'from about 34% by weight to about 36% by weight trifluoroiodomethane (CFI) and'}from about 5% by weight to about 7% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)wherein the percentages are based on the total weight of the three compounds in the blend.3. The refrigerant of wherein said blend consists of:about 47% by weight difluoromethane (HFC-32),about 12% by weight pentafluoroethane (HFC-125),{'sub': '3', 'about 35% by weight trifluoroiodomethane (CFI) and'}about 6% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)wherein the percentages are based on the total weight of the three compounds in the blend.4. The refrigerant of wherein the refrigerant comprises at least about 98.5% by weight of said blend.5. The refrigerant of wherein the refrigerant comprises at least about 99.5% by weight of said blend.6. The refrigerant of wherein the refrigerant consists essentially of said blend.7. The refrigerant of wherein the refrigerant consists of said blend.8. The refrigerant of wherein the weight ratio of (HFC-32+HFO-1234yf):(CF3I+HFC-125) is from greater than about 1:1 to less than 1.2:1.9. The refrigerant of ...

Fluids for Extreme Pressure and Wear Applications

Provided are compositions, additives for forming compositions, methods of operating apparatus in fluid communication with the compositions, and apparatus comprising the compositions. For example, the composition may include a polyalphaolefin component of from about 95% to about 99.5% w/w. The composition may include an additive component. The additive component may include an anti-wear agent. The anti-wear agent may be from about 0.1% to about 2% w/w. The anti-wear component may be characterized by an acid value of at least about 1 mg KOH/g. The additive component may include an aryl amine antioxidant agent, an anti-rust agent, and a metal deactivator agent. The composition may be characterized by a kinematic viscosity at 100° C. of at least about 5 centiStokes, a viscosity index of at least about 80, and an acid value in mg KOH/g of between about 0.1 and about 1. 1. A composition , comprising:a polyalphaolefin component in a percentage, w/w of the composition, of from about 95% to about 99.5%; and an anti-wear agent in a percentage, w/w of the composition, of from about 0.1% to about 2%, the anti-wear component characterized by an acid value of at least about 1 mg KOH/g;', 'an aryl amine antioxidant agent;', 'an anti-rust agent; and', 'a metal deactivator agent;, 'an additive component, comprising a kinematic viscosity at 100° C. of at least about 5 centiStokes;', 'a viscosity index of at least about 80; and', 'an acid value in mg KOH/g of between about 0.1 and about 1., 'the composition being characterized by2. The composition of claim 1 , comprising the additive component claim 1 , in a percentage claim 1 , w/w of the composition claim 1 , of from about 0.5% to about 5%.3. The composition of claim 1 , the anti-wear agent comprising a partly esterified phosphate ester.4. The composition of claim 1 , the anti-wear agent comprising one or more of: a C-Calkylated triarylphosphate claim 1 , a C-Calkyl phosphate claim 1 , a diarylether phosphate ester and a diarylether ...

Method for improving deposit control and cleanliness performance in an engine lubricated with a lubricating oil

wherein [Gn] is the weight percent of each of n dispersants in the formulated oil, [Bm] is the weight percent of each of m viscosity modifiers in the formulated oil, dV/d[Gn] is the kinematic viscosity (Kv100) increase of the lubricating oil per the weight percent of each of n dispersants in the formulated oil, and dV/d[Bm] is the kinematic viscosity (Kv100) increase of the lubricating oil per the weight percent of each of m viscosity modifiers in the formulated oil.

LUBRICATING OIL COMPOSITIONS WITH ENGINE CORROSION PROTECTION

A method for improving corrosion resistance, while maintaining or improving fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition comprising a lubricating oil base stock as a major component, and at least one friction modifier having an elemental composition comprising one or more of nitrogen (N), oxygen (O), and phosphorus (P), as a minor component. The formulated oil has a corrosion factor, based on the elemental composition of the at least one friction modifier, of less than 500, as determined by the formula: 2. The method of wherein said formulated oil has a corrosion factor claim 1 , based on the elemental composition of the at least one friction modifier claim 1 , of less than 400.3. The method of wherein said formulated oil has a corrosion factor claim 1 , based on the elemental composition of the at least one friction modifier claim 1 , of less than 200.4. The method of wherein said formulated oil has a corrosion factor claim 1 , based on the elemental composition of the at least one friction modifier claim 1 , of less than 100.5. The method of wherein said formulated oil has a corrosion factor claim 1 , based on the elemental composition of the at least one friction modifier claim 1 , of less than 50.6. The method of wherein the lubricating oil base stock comprises a Group I claim 1 , Group II claim 1 , Group III claim 1 , Group IV or Group V base oil.7. The method of wherein the at least one friction modifier comprises an inorganic compound claim 1 , an alkoxylated fatty acid ester claim 1 , an alkanolamide claim 1 , a polyol fatty acid ester claim 1 , a borated glycerol fatty acid ester claim 1 , a fatty alcohol ether claim 1 , or mixtures thereof.8. The method of wherein the inorganic compound comprises molybdenum amine claim 7 , molybdenum diamine claim 7 , an organotungstenate claim 7 , a molybdenum dithiocarbamate claim 7 , ...

LUBRICATING OIL COMPOSITION

Disclosed is a lubricating oil composition comprising: a lubricating base oil comprising 0.5% to 70% by mass of an ester base oil based on the total amount of the lubricating base oil, and having a kinematic viscosity at 40° C. of 18 to 28 mm/s; and an organic molybdenum compound in an amount of 100 to 1000 mass ppm in terms of the molybdenum element based on the total amount of the lubricating oil composition, wherein the lubricating oil composition has a kinematic viscosity at 40° C. of 50 mm/s or less. 14-. (canceled)5. A lubricating oil composition comprising:{'sup': '2', 'a lubricating base oil comprising 1% to 70% by mass of an ester base oil based on the total amount of the lubricating base oil, and said lubricating base oil having a kinematic viscosity at 40° C. of 22 to 26 mm/s; wherein the amount of the lubricating base oil is 67.5% by mass or more; and'}molybdenum dithiocarbamate in an amount of 100 to 1000 mass ppm in terms of molybdenum element based on the total amount of the lubricating oil composition, wherein{'sup': '2', 'the lubricating oil composition has a kinematic viscosity at 40° C. of 10 of 50 mm/s or less,'}the lubricating oil composition further comprising 2.5% to 24% by mass of a copolymer of an α-olefin and an α,β-ethylenically unsaturated dicarboxylic acid diester, based on the total amount of the lubricating oil composition, wherein the weight-average molecular weight of the copolymer is 6000 to 15000,the lubricating oil further comprising a boron-containing dispersant in an amount of 100 to 500 mass ppm in terms of boron element based on the total amount of the lubricating oil composition,wherein the lubricating oil composition is free of styrene-maleic anhydride ester.6. The lubricating oil composition according to claim 5 , wherein the lubricating base oil comprises a synthetic base oil comprising a poly-α-olefin.7. A method of lubricating a hypoid gear comprising utilizing the lubricating oil composition of . The present invention ...

REFRIGERANT COMPRESSOR AND FREEZING APPARATUS USING SAME

Refrigerant compressor includes electromotive element, and compression element that is driven by electromotive element, includes a slider, and compresses a refrigerant. Freezer oil that lubricates the slider is added with fullerene having a diameter that ranges from 100 pm to 10 nm. 1. A refrigerant compressor comprising:an electromotive element; anda compression element that is driven by the electromotive element, includes a slider, and compresses a refrigerant,wherein a freezer oil that lubricates the slider is added with a fullerene having a diameter that ranges from 100 pm to 10 nm.2. The refrigerant compressor according to claim 1 , wherein one of a C60 fullerene, a C70 fullerene, and a higher-order fullerene including a larger number of carbons than a number of carbons of the C70 fullerene; or', 'a mixed fullerene obtained by mixing at least two of the C60 fullerene, the C70 fullerene, and the higher-order fullerene., 'the fullerene is3. The refrigerant compressor according to claim 1 , wherein a shape of the fullerene is spherical or elliptic.4. The refrigerant compressor according to claim 1 , wherein an additive amount of the fullerene is less than or equal to a saturating amount of dissolution with respect to the freezer oil.5. The refrigerant compressor according to claim 1 , whereinthe refrigerant compressed by the compression element is a hydrofluorocarbon (HFC) refrigerant or a mixed refrigerant including the HFC refrigerant, and one of ester oil, alkylbenzene oil, polyvinyl ether, and polyalkylene glycol; or', 'mixed oil of at least two of the ester oil, the alkylbenzene oil, the polyvinyl ether, and the polyalkylene glycol., 'the freezer oil is6. The refrigerant compressor according to claim 1 , wherein one natural refrigerant of R600a, R290, and R744; or', 'a mixed refrigerant that includes at least one of the R600a, the R290, and the R744, and, 'the refrigerant compressed by the compression element is one of mineral oil, ester oil, alkylbenzene oil ...

Lubricating oil composition for shock absorber

To provide a lubricating oil composition for a shock absorber for preventing wearing a piston rod and a guide bush in a shock absorber, which composition lowers the friction coefficient at the interface between bronze and chromium and reduces wear area of bronze. The lubricating oil composition for a shock absorber contains (A) a base oil composed of a mineral oil and/or a synthetic oil, and (B) a polyhydric alcohol partial ester having a C10 to C20 fatty acid residue, in an amount of 0.05 mass % to 10 mass %, with respect to the total amount of the composition.

Lubricating oil composition

A lubricating oil composition of the invention contains a first base oil having a kinematic viscosity at 100 degrees C. in a range from 0.6 mm 2 /s to 3.5 mm 2 /s and a first poly(meth)acrylate having a mass average molecular weight in a range from 3×10 4 to 5×10 4 .

COMPOSITION BASED ON 2,3,3,3-TETRAFLUOROPROPENE

A composition including a lubricant based on polyol esters (POEs) or polyvinyl ether (PVE) and a refrigerant F including from 1 to 99% by weight of 2,3,3,3-tetrafluoropropene (HFO-1234yf) and from 1 to 99% by weight of trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze). Also, the use of the composition in refrigeration, air conditioning and heat pumps. 1. Composition comprising at least one lubricant comprising polyol esters or polyvinyl ether and a refrigerant F comprising from 1 to 99% by weight of 2 ,3 ,3 ,3-tetrafluoropropene (HFO-1234yf) and from 1 to 99% by weight of trans-1 ,3 ,3 ,3-tetrafluoropropene (trans-HFO-1234ze).2. Composition according to claim 1 , characterized in that the refrigerant F comprises from 5 to 70% by weight of 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (HFO-1234yf) and from 30 to 95% by weight of trans-1 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (trans-HFO-1234ze).3. Composition according to claim 1 , characterized in that the refrigerant F comprises from 25 to 55% by weight of 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (HFO-1234yf) and from 45 to 75% by weight of trans-1 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (trans-HFO-1234ze).4. Composition according to claim 1 , characterized in that the polyol esters are obtained from polyols having a neopentyl backbone.5. Composition according to claim 4 , characterized in that the polyol having a neopentyl backbone is selected from the group consisting of neopentyl glycol claim 4 , trimethylolpropane claim 4 , pentaerythritol and dipentaerythritol.6. Composition according to claim 1 , characterized in that the polyol esters are obtained from a linear or branched carboxylic acid containing from 2 to 15 carbon atoms.7. Composition according to claim 1 , characterized in that the polyol esters comprise between 10 and 50% by weight of the composition. The present application is a continuation of U.S. application Ser. No. 13/232,165, filed on Sep. 14, 2011 ...

WORKING FLUID COMPOSITION FOR REFRIGERATOR, AND REFRIGERATOR OIL

The present invention provides a working fluid composition for a refrigerating machine, comprising a refrigerating machine oil that comprises an ester of a polyhydric alcohol and a fatty acid, an epoxy compound, and a phosphorus compound, and a fluoropropene refrigerant, wherein the polyhydric alcohol constituting the ester comprises pentaerythritol and dipentaerythritol, the fatty acid constituting the ester comprises at least one selected from fatty acids having 4 to 9 carbon atoms, and the epoxy compound and the phosphorus compound satisfy a condition represented by the following formula (1). 2. The working fluid composition for a refrigerating machine according to claim 1 , wherein the ester comprises a mixture of a first ester being an ester of pentaerythritol and at least one fatty acid selected from fatty acids having 4 to 9 carbon atoms and a second ester being an ester of dipentaerythritol and at least one fatty acid selected from fatty acids having 4 to 9 carbon atoms.3. The working fluid composition for a refrigerating machine according to claim 2 , wherein a content of the second ester is 10% by mass or more and 40% by mass or less based on a total of a content of the first ester and the content of the second ester.4. The working fluid composition for a refrigerating machine according to claim 1 , further comprising 0.1% by mass or more and 0.4% by mass or less of 2 claim 1 ,6-di-tert.-butyl-p-cresol based on the total amount of the refrigerating machine oil.5. The working fluid composition for a refrigerating machine according to claim 1 , wherein the fluoropropene refrigerant is at least one selected from 1 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (HFO-1234ze) and 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene (HFO-1234yf). The present invention relates to a working fluid composition for a refrigerating machine and to a refrigerating machine oil.CFC (chlorofluorocarbons) and HCFC (hydrochloro-fluorocarbons), which have conventionally ...