СМАЗОЧНОЕ СРЕДСТВО, СПОСОБ ЕГО ИЗГОТОВЛЕНИЯ И ЕГО ПРИМЕНЕНИЕ, А ТАКЖЕ СПОСОБ ОПТИМИЗАЦИИ ТРИБОЛОГИЧЕСКИХ СВОЙСТВ И ПРОТИВОЗАДИРНОГО ДЕЙСТВИЯ ПРИ ЕГО ИСПОЛЬЗОВАНИИ В ВЫСОКОТЕМПЕРАТУРНЫХ ПЛАСТИЧНЫХ СМАЗКАХ

... 1. Смазочное средство, содержащее в качестве присадки керамические наночастицы, выбранные из группы, включающей Al2О3, AlN, SiO2, TiO2, ZrO2, Y2O3, WO3, Ta2O5, V2O5, Nb2O5, CeO2, карбид бора, титанат алюминия, BN, MoSi2, SiC, Si3N4, TiC, TiN, ZrB2, глинистые минералы и/или их смеси, а также термостабильные карбонаты и/или сульфаты, причем наночастицы обладают формой эллипсоида с тремя полуосями a, b и с, причем а≠b≠с или a=b=c и причем отношение полуосей а:b составляет от 1:1 до 100:1, a:c от 1:1 до 1000:1 и b:c от 1:1:100:1. ! 2. Смазочное средство по п.1, отличающееся тем, что наночастицы обладают размером от 1 до 5000 нм. ! 3. Смазочное средство по п.1, отличающееся тем, что наночастицы обладают теплопроводностью от 1 до 100 Вт/м·К. ! 4. Смазочное средство по п.1, отличающееся тем, что наночастицы диспергированы в жидкой основе. ! 5. Смазочное средство по п.4, отличающееся тем, что в качестве жидкой основы оно содержит воду и/или по меньшей мере одно масло, выбранное из группы, включающей ...

ОМПОЗИЦИЯ КОНСИСТЕНТНОЙ СМАЗКИ

... 1. Консистентная смазка, состоящая из смеси из ! (а) от 5 до 95 мас.% базового масла на основе масел с обычной для промышленных смазочных материалов вязкостью, которая состоит из сложного эфира ароматической или алифатической ди-, три- или тетракарбоновой кислоты с одним или находящимся в смеси от С7- до С22-спиратми, из простого полифенилового эфира или простого алкилированного дифенилового эфира, из сложного эфира триметилолпропана, пентаэритрита или дипентаэритрита с алифатическими от С7- до С22-карбоновыми кислотами, из сложного эфира С18-димерной кислоты с от С7- до С22-спиртами, из сложных комплексных эфиров, как индивидуальные компоненты или в любой смеси, или выбрано из поли-α-олефинов, алкилированных нафталинов, алкилированных бензолов, полигликолей, силиконовых масел, простых перфторполиэфиров, ! (б) от 1 до 30 мас.% ионной жидкости или смеси из нескольких ионных жидкостей, которая в качестве катиона содержит катион фосфония, катион имидазолия, катион пиридиния или катион пирролидиния ...

Schmierstoffzusammensetzungen enthaltend Komplexester

Vorgeschlagen werden Schmierstoffzusammensetzungen mit einer guten Scherstabilität, bestimmt durch den Verlust der kinematischen Viskosität bei 100°C, enthaltend Grundöl und einen synthetischen Komplexester, wobei der Komplexester eine kinematische Viskosität bei 40°C von größer als 400 und bis zu 50000 mm²/s aufweist und durch Umsetzung von a) Polyolen und Monocarbonsäuren und Dicarbonsäuren oder von b) Polyolen und Monoalkoholen und Dicarbonsäuren oder von c) Polyolen und Monoalkoholen und Monocarbonsäuren und Dicarbonsäuren erhalten wird. Des Weiteren wird die Verwendung der genannten Schmierstoffzusammensetzungen, enhaltend die Komplexester, als Fahrzeuggetriebe-, Achsen-, Industriegetriebe-, Kompressoren-, Turbinen- oder Motoröl vorgeschlagen.

LACTONE-MODIFIED ESTER OILS AND A LUBRICATING COMPOSITION CONTAINING THEM

FREEZING OIL COMPOSITION.

POLYOLE/CESTER MIXTURE AS LUBRICANTS FOR HEAT TRANSFER LIQUIDS IN REFRIGERANT PLANTS

A METHOD FOR THE PRODUCTION POLYOLE ESTER LUBRICANTS FOR ABGEDICHTE COOLING COMPRESSORS

Novel ester compounds, method for the production thereof and use thereof

The invention relates to novel ester compounds of general formula (I), to methods for the production thereof, and to their use. These ester compounds can contain a mixture of at least two compounds of general formula (I).

Lubricants with enhanced energy efficiency

Lubricant compositions useful especially for the lubrifcation of gears, having a boundary loss coefficient Xof 0.6 to 0.8 measured at temperatures of 40 to 120 °C with a modified method according to DIN 51354, whereby the lubricant composition contains of a base oil a optional additives, whereby the base oil is selected from complex ester, said, said complex ester having a kinematic viscosity at 40°C of greater than 400 and up to 50 000 mm/s.

Estolide compositions exhibiting high oxidative stability

Provided herein ar estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: IfI in which n is an integer equal to or greater than 0; i. is an integer equal to or greater than i1; RI, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturatd or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses for the compositions and methods of preparing the same, ...

Polyol ester compositions with unconverted hydroxyl groups

Liquid compositions containing complex carboxylic esters

High viscosity complex alcohol esters

FUNCTIONAL FLUID WITH TRIGLYCERIDES, DETERGENT-INHIBITOR ADDITIVES AND VISCOSITY MODIFYING ADDITIVES

DIELECTRIC FLUIDS COMPRISING ESTOLIDE COMPOUNDS AND METHODS OF MAKING AND USING THE SAME

Provided herein are dielectric fluids comprising at least one estolide compound of formula (II); in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses of dielectric fluids and electrical devices such as transformers that comprise a dielectric fluid comprising at least one estolide compound.

PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND OLIGOMERIC COMPOUNDS THAT INCLUDE CROSS METATHESIS

Provided herein are estolide base oils and oligomeric compounds prepared from processes that include cross metathesis. Exemplary processes include the preparation of terminally-unsaturated fatty acids by cross metathesis, and the subsequent oligomerization of terminally-unsaturated fatty acids to provide estolide compounds ...

LIQUID COMPOSITIONS FOR REFRIGERATION SYSTEMS CONTAINING FATTY AMINES, FATTY AMIDES, AND REACTION PRODUCTS OF FATTY ACYLATING AGENTS

Title: LIQUID COMPOSITIONS FOR REFRIGERATION SYSTEMS CONTAINING FATTY AMINES This invention relates to a liquid composition comprising (A) at least one fluorine-containing hydrocarbon containing 1 to 3 carbon atoms, (B) an efficiency improving or wear reducing amount of an additive selected from the group consisting of at least one fatty amine, at least one fatty amide, at least one reaction product of at least one fatty carboxylic acylating agent and at least one amine selected from the group consisting of a polyamine, a hydroxy amine and a mixture thereof, and at least one mixture thereof, and (C) an effective amount of a lubricant selected from the group consisting of at least one carboxylic ester, at least one polyalkylene glycol, at least one polycarbonate, and at least one mixture thereof. The liquid compositions containing the fatty amine, the fatty amide, the reaction product of a fatty carboxylic acylating agent have improved efficiency and antiwear properties. These compositions ...

POLYOL ESTER LUBRICANTS FOR REFRIGERATING COMPRESSORS OPERATING AT HIGH TEMPERATURE

... 2137263 9325629 PCTABS00028 A high quality lubricant for heavy duty service air conditioner and refrigerator compressors, especially those using chlorine free hydrofluorocarbon refrigerant working fluids, is provided by mixed esters of hindered polyols, most desirably di-pentaerythritol, usually mixed with some pentaerythritol, with a mixture of carboxylic acids including at least some of each of iso-pentanoic acid and iso-nonanoic acid.

POLYOL ESTER LUBRICANTS FOR HERMETICALLY SEALED REFRIGERATING COMPRESSORS

A high quality lubricant for hermetically sealed domestic air conditioner an d refrigerator compressors, especially those us- ing chlorine free hydrofluorocarbon refrigerant working fluids, is provided by mixed esters of hindered polyols, most desirably pentaerythritol, with a mixture of carboxylic acids including at least some isopentanoic acid along with either or both of iso-nona- noic acid and dibasic acids such as adipic.

BLENDED POLYOL ESTER LUBRICANTS FOR REFRIGERANT HEAT TRANSFER FLUIDS

An ester blend, including an ester having neopentylglycol and a source of 2- ethylhexanoic acid as its reactive components and an ester having pentaerythritol and a source of 2-ethylhexanoic acid as its reactive components, is especially effective as a lubricant for chlorine-free fluorocarbon refrigerant heat transfer fluids, particularly Refrigerant 134a (1,1,1,2-tetrafluoroethane).

BLENDED POLYOL ESTER LUBRICANTS FOR REFRIGERANT HEAT TRANSFER FLUIDS

... 2137149 9324587 PCTABS00028 From not more than three blending stocks, it is possible to prepare a wide variety of mixtures of esters of hindered polyhydric alcohols that are especially valuable lubricants for chlorine-free fluorocarbon refrigerant heat transfer fluids, particularly Refrigerant 134a (1,1,1,2-tetrafluoroethane).

POLYOL ESTER LUBRICANTS FOR REFRIGERANT HEAT TRANSFER FLUIDS

A variety of specific esters and mixtures of esters of polyhydric alcohols, particularly pentaerythritol, that are especially valuable lubricants for chlorine-free fluocarbon refrigerant heat transfer fluids, particularly Refrigerant 134a (1,1,1,2-tetrafluor-oethane), are described.

BIODEGRADABLE GREASE COMPOSITIONS

Lubricant compositions comprising biodegradable ester base stocks are provided for water-cooled or air-cooled two-cycle engines. Grease compositions comprising biodegradable ester base storks are provided for a wide variety of machinery including chain saws, truck chassis, and the rail, wheel flanges and switches on the railroads.

BIODEGRADABLE GREASE COMPOSITIONS

Lubricant compositions comprising biodegradable ester base stocks are provided for water-cooled or air-cooled two-cycle engines. Grease compositions comprising biodegradable ester base stocks are provided for a wide variety of machinery including chain saws, truck chassis, and the rail, wheel flanges and switches on the railroads.

Synthetische Schmiermittel

Schmiermittel

Lubricating oils based on trimethylolpropane esters and their use in the lubrication of 2-stroke engines

Lubricating oils for 2-stroke engines are described in which the base lubricant contains, in the case of at least 60 % of its weight, at least one ester formed between trimethylolpropane and a combination of carboxylic acids, consisting -of a proportion of 15 to 50 %, as carboxylic equivalents, of at least one saturated aliphatic dicarboxylic acid containing from 4 to 36 carbon atoms, and - of a proportion of 85 to 50 %, as carboxylic equivalents, of a mixture of saturated aliphatic monocarboxylic acid which itself comprises - from 40 to 92 mol % of at least one acid containing 2 to 14 carbon atoms and - from 60 to 8 mol % of at least one acid containing 15 to 30 carbon atoms. The trimethylolpropane esters thus defined exhibit good viscometric characteristics, a high lubricating power, good thermal stability and good biodegradability. They can be employed as a mixture with hydrocarbon oils. The 2-stroke lubricants thus formed can be employed in low concentrations in relation to the fuel ...

LUBRICATING OIL COLD ROLLING FOR METALLIC MATERIAL

COLD ROLLING OIL

HUILE DE LAMINAGE A FROID POUR ACIERS

HUILE DE LAMINAGE A FROID POUR ACIERS CARACTERISEE PAR LE FAIT QU'ELLE COMPREND A 40 A 90 EN POIDS D'UN MONOESTER D'UN ACIDE CARBOXYLIQUE ALIPHATIQUE AYANT 12 A 22 ATOMES DE CARBONE ET D'UN ALCOOL ALIPHATIQUE AYANT 1 A 12 ATOMES DE CARBONE, B 0,5 A 10 EN POIDS D'AU MOINS UN COMPOSE CHOISI PARMI UN ACIDE DIMERE ET UN ACIDE POLYMERISE DERIVE D'UN ACIDE INSATURE ALIPHATIQUE SUPERIEUR AYANT 16 A 20 ATOMES DE CARBONE, C 2 A 40 EN POIDS D'UN POLYESTER AYANT UN POIDS MOLECULAIRE DE 750 A 7500 ET OBTENU EN SOUMETTANT AU MOINS UN COMPOSE CHOISI PARMI UN ACIDE DIMERE ET UN ACIDE POLYMERISE DERIVE D'UN ACIDE INSATURE ALIPHATIQUE SUPERIEUR AYANT 16 A 20 ATOMES DE CARBONE A UNE CONDENSATION AVEC UN POLYOL DANS DES CONDITIONS DE CHAUFFAGE ET EN FAISANT REAGIR LES GROUPES CARBOXYLE OU LES GROUPES HYDROXYLE RESTANTS DU POLYESTER RESULTANT AVEC UN ALCOOL AYANT 1 A 22 ATOMES DE CARBONE OU UN ACIDE ALIPHATIQUE AYANT 12 A 22 ATOMES DE CARBONE, OU 10 A 25 EN POIDS D'UNE GRAISSE OU D'UNE HUILE GRASSE, ET D 0,1 ...

Improved food-grade-lubricant

SOLUBLE OIL CONTAINING OVERBASED SULFONATE ADDITIVES

본 발명은 우수한 성능을 보여주며, 기계를 위한 절삭유와 같은 우수한 유용성을 갖는 안정한 에멀젼을 형성할 수 있는 가용성 오일 조성물에 관한 것이다. 상기 조성물은 내마모 특성을 갖는 과염기화된 알칼리토 금속 술폰산염을 포함한다. The present invention relates to a soluble oil composition which exhibits excellent performance and which is capable of forming a stable emulsion having excellent usability such as cutting oil for machines. The composition comprises an overbased alkaline earth metal sulfonate having abrasion resistance properties. 과염기, 술폰산염, 절삭유 Overbases, sulfonates, coolants

lubricating grease composition

COMPOSITIONS OF LUBRICATION GREASE

The compositions include a mixture of the followingcomponents: hydrocarbon-based oil; perfluoropolyalkylether oilhaving the general formulaA'-(O-CF2)v-(O-C2F4)w-(O-C3F6)x -(O-C4F8)y- (O-CF2CF(CF3))z-O-A"where A- is -CF3, -C2F5, -C3F7, -CF2T, where T means H or Cl, A"can be A' or -CF3, -C2F5, -C3F7, -CF2T, T being H or Cl and v, w,z, y and z being integers larger of equal to O; dicarbamide as athickener; typical additives and organic and inorganic solidlubricants. The invention also relates to a method for thepreparation of the compositions.6 claims ...

composição de lubrificante e método para melhorar a estabilidade hidrolítica de um lubrificante a base de éster

Lubricating oil for refrigerators and hydraulic fluid composition for refrigerator using the same

The present invention proposes a lubricating oil for refrigerators comprising, as the base oil, a polyester-based derivative or a polyvinyl ether derivative and a polycarbonate-based oxygenated compound; a polyoxyalkylene glycol derivative; or a polyester-based derivative or a polyvinyl ether derivative and a polyoxyalkylene glycol derivative. The lubricating oil exhibits excellent miscibility with a refrigerant having one carbon atom and no chlorine atoms and, in particular, with difluoromethane and provides a hydraulic fluid composition exhibiting excellent antiwear, lubricity and stability.

BIODEGRADABLE LUBRICATING OIL COMPOSITION

This biodegradable lubricating oil composition is characterized in being obtained by blending: an ester (A) obtained by reacting a straight-chain saturated aliphatic carboxylic acid, a straight-chain aliphatic divalent carboxylic acid, and a polyhydric alcohol; an ester (B) obtained by reacting a straight-chain saturated aliphatic carboxylic acid and a polyhydric alcohol; and a phosphate ester amine salt (C) obtained by reacting an acidic phosphate ester and an alkylamine, wherein the straight-chain saturated aliphatic carboxylic acid in the component (A) comprises a C8 straight-chain saturated aliphatic carboxylic acid and a C10 straight-chain saturated aliphatic carboxylic acid, and the molar quantity of the C8 straight-chain saturated aliphatic carboxylic acid is greater than the molar quantity of the C10 straight-chain saturated aliphatic carboxylic acid.

Ester compounds, method for the preparation thereof and use thereof

Ester compounds, such as for use in a lubricant, are based on di-, tri- or higher functional carboxylic acids according to formula (I).

COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM

A composition for a heat cycle system comprising a working fluid for heat cycle containing trifluoroethylene, and a refrigerant oil (for example, an ester refrigerant oil, an ether refrigerant oil, a polyglycol refrigerant oil or a hydrocarbon refrigerant oil), and a heat cycle system employing the composition for a heat cycle system.

Estolide compositions having excellent low temperature properties

A lubricant or process fluid composition having excellent low temperature properties comprises a capped estolide ester, a polyalphaolefin, a synthetic ester and/or polyalkylene glycol, and a pour point depressant. The combination of the three base oils plus the pour point depressant produces a synergistic composition that may have a pour point less than -15° C., preferably less than -35° C., while also having more than 50 percent by weight renewable carbons and being economical and effective in a wide variety of applications.

Natural and synthetic ester-containing lubricants having enhanced hydrolytic stability

A lubricant composition comprising (a) from 0.1 to 10 percent by weight of one or more polyalkylene glycols (PAG); and (2) one or more ester base oils selected from the group of natural esters, synthetic esters and combinations thereof; wherein the one or more PAG has a molecular weight in the range 1500 to 5000 g/mole, comprises from 10 to 40 percent by weight of units derived from ethylene oxide and from 90 to 60 percent by weight of units derived from propylene oxide; and wherein the one or more PAGs are in the form of block copolymer, reverse block copolymer or combinations thereof is provided. Also provided is a method of enhancing the hydrolytic stability of an ester base oil.

PROCESSES FOR PREPARING ESTOLIDE BASE OILS AND OLIGOMERIC COMPOUNDS THAT INCLUDE CROSS METATHESIS

SYNERGISTIC COMBINATION OF ADDITIVE PROVIDING HIGH LOAD CAPACITY AND CORROSION INHIBITORS FOR LUBRICANT COMPOSITIONS

Graphite-free lubricating oil

A graphite-free lubricating oil which comprises a base oil having dispersed therein 10 to 40% by weight of a carbohydrate and/or a derivative thereof whose particle size ranges from 10 to 150 µm, 2 to 20% by weight of a film-boosting agent and 0.1 to 20% by weight of a dispersant. Moreover, the lubricating oil is free of black-colored substances such as graphite. Therefore, the oil permits the improvement of working surroundings and exhibits excellent properties such as formability through forging almost comparable to or even greater than that of the commercially available graphite-in-oil type lubricating oils. The lubricating oil can be used instead of the graphite-containing lubricating oils for warm forging, hot forging, rolling, tube-manufacturing, drawing and extrusion in place of the graphite-containing lubricating oils and ensures the improvement in the working surroundings and excellent lubricity.

USE OF ESTER COMPOSITION

LUBRICANT COMPOSITION COMPRISING BRANCHED DIESTERS AND VISCOSITY INDEX IMPROVER

潤滑剤ベースストックと高粘度複合アルコールエステルとのブレンド

... (A)(1)一般式、R(OH)n(式中、Rは脂肪族又は脂環式ヒドロカルビル基であり、nは少なくとも2であり、ヒドロカルビル基が約2乃至20の炭素原子を有する)により表わされるポリヒドロキシル化合物;(2)多塩基酸の当量と、ポリヒドロキシル化合物からのアルコールの当量との比が約1.6:1乃至2:1の範囲である多塩基酸又は多塩基酸の無水物;及び、(3)一価アルコールの当量と多塩基酸の当量との比が約0.84:1乃至1.2:1の範囲である一価アルコールの付加混合物の反応生成物を含み、40℃において約100乃至700cStの範囲の粘度を示し、複合アルコールエステルに基づいて70重量%以下の多塩基酸エステル濃度を有する複合アルコールエステルベースストック並びに(B)少なくとも1つの付加的ベースストックの付加混合物を含む潤滑油。 ...

ПРИМЕНЕНИЕ ИОННЫХ ЖИДКОСТЕЙ ДЛЯ УЛУЧШЕНИЯ СВОЙСТВ СМАЗОЧНОЙ КОМПОЗИЦИИ

FIELD: chemistry. SUBSTANCE: claimed invention relates to application of ionic liquids for improvement of protection against oxidising and thermal destruction of lubricating composition, consisting of mixture of a) from 82.5 to 95 wt % of basic oil or mixture of basic oil based on synthetic, mineral or natural oils, which are applied separately or in combination, b) from 0.1 to 7.5 wt % of ionic liquid and c) from 4.9 to 10 wt % of additive or mixture of additives. EFFECT: obtaining composition, which possesses higher thermal and oxidation resistance. 7 cl, 6 ex, 9 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 516 705 C2 (51) МПК C10M 133/38 (2006.01) C10M 135/10 (2006.01) C10M 137/00 (2006.01) C10N 30/08 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2010101285/04, 20.05.2008 (24) Дата начала отсчета срока действия патента: 20.05.2008 Приоритет(ы): (30) Конвенционный приоритет: (43) Дата публикации заявки: 27.07.2011 Бюл. № 21 (45) Опубликовано: 20.05.2014 Бюл. № 14 (73) Патентообладатель(и): КЛЮБЕР ЛУБРИКАЦИОН МЮНХЕН КГ (DE) 1867706 A1, 19.12.2007. US 2007/027038 A1, 01.02.2007. JP 2005/336309 A, 08.12.2005. RU 2058377 C1, 20.04.1996 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 20.01.2010 2 5 1 6 7 0 5 (56) Список документов, цитированных в отчете о поиске: WO 2006/109652 A1, 19.10.2006. EP R U 20.06.2007 DE 102007028427.8 (72) Автор(ы): Гюнтер БОДЕСХАЙМ (DE), Мартин ШМИДТ-АМЕЛУНКСЕН (DE), Дитер ЗОН (DE), Штефан ГРУНДАЙ (DE), Андреа ХЁПКЕ (DE) 2 5 1 6 7 0 5 R U EP 2008/004036 (20.05.2008) C 2 C 2 (86) Заявка PCT: (87) Публикация заявки PCT: WO 2008/154998 (24.12.2008) Адрес для переписки: 105082, Москва, Спартаковский пер., д. 2, стр. 1, секция 1, этаж 3, "Евромаркпат" (54) ПРИМЕНЕНИЕ ИОННЫХ ЖИДКОСТЕЙ ДЛЯ УЛУЧШЕНИЯ СВОЙСТВ СМАЗОЧНОЙ КОМПОЗИЦИИ (57) Реферат: Настоящее изобретение относится к комбинации, b) от 0,1 до 7,5 мас.% ионной применению ионных жидкостей для улучшения ...

ЭСТОЛИДЫ И КОМПОЗИЦИИ СМАЗЫВАЮЩИХ МАТЕРИАЛОВ, ПОЛУЧЕННЫЕ НА ОСНОВЕ РЕАКЦИИ ДИЛЬСА-АЛЬДЕРА

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2015 123 637 A (51) МПК C10M 105/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2015123637, 06.11.2013 (71) Заявитель(и): БАЙОСИНТЕТИК ТЕКНОЛОДЖИЗ, ЭлЭлСи (US) Приоритет(ы): (30) Конвенционный приоритет: 19.11.2012 US 61/728,108 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 19.06.2015 R U (43) Дата публикации заявки: 10.01.2017 Бюл. № 01 (72) Автор(ы): ТОМПСОН Трэвис (US), ФОРЕСТ Джереми (US), БРЕДСГАРД Джейкоб (US) (86) Заявка PCT: (87) Публикация заявки PCT: WO 2014/078149 (22.05.2014) R U (54) ЭСТОЛИДЫ И КОМПОЗИЦИИ СМАЗЫВАЮЩИХ МАТЕРИАЛОВ, ПОЛУЧЕННЫЕ НА ОСНОВЕ РЕАКЦИИ ДИЛЬСА-АЛЬДЕРА (57) Формула изобретения 1. Композиция, содержащая: по меньшей мере, одно соединение эстолида и по меньшей мере, одно соединение, выбранное из соединений Формулы II: Формула II, где Y1 представляет собой незамещенный C5-C10 алкил, который является насыщенным или ненасыщенным, и неразветвленным; Y2, Y3 и Y4, независимо, для каждого случая, выбирают из незамещенного C4-C10 алкилена, который является насыщенным или ненасыщенным и неразветвленным; U1 и U2, независимо, для каждого случая, выбирают из водорода и -C(=O)OR10; Стр.: 1 A 2 0 1 5 1 2 3 6 3 7 A Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр. 3, ООО "Юридическая фирма Городисский и Партнеры" 2 0 1 5 1 2 3 6 3 7 US 2013/068729 (06.11.2013) R9 и R10, независимо, для каждого случая, выбирают из необязательно замещенного алкила, который является насыщенным или ненасыщенным и разветвленным или неразветвленным; и R5 и R6 представляют собой водород, или R5 и R6, взятые вместе с атомами углерода, к которым они присоединены, образуют необязательно замещенный циклоалкил, где прерывистая линия представляет одинарную связь или двойную связь и где, по меньшей мере, один из U1 или U2 представляют собой -C(=O)OR10, 2. Композиция по п. 1, где Y1 выбирают из C5 алкила и C8 алкила. 3. Композиция по п. 1, где Y2 ...

ПРИМЕНЕНИЕ ИОННЫХ ЖИДКОСТЕЙ ДЛЯ УЛУЧШЕНИЯ СВОЙСТВ КОМПОЗИЦИЙ КОНСИСТЕНТНОЙ СМАЗКИ

... 1. Применение ионных жидкостей для улучшения защиты против окислительной и термической деструкции композиций консистентной смазки, состоящих из смеси из ! a) от 5 до 95 мас.% базового масла или смеси базового масла на основе синтетических, минеральных или природных масел, которые применяют отдельно или в комбинации, ! b) от 0,05 до 40 мас.% ионной жидкости и ! c) от 0,1 до 10 мас.% присадки или смеси присадок. ! 2. Применение по п.1, отличающееся тем, что базовое масло на основе синтетического масла выбрано из сложного эфира алифатической или ароматической ди-, три- или тетракарбоновой кислоты с одним или находящимися в смеси от С7- до С22-спиртами, из простого полифенилового эфира или алкилированного простого ди- или трифенилового эфира, из сложного эфира триметилолпропана, из пентаэритрита или дипентаэритрита с алифатическими от C1- до С22-карбоновыми кислотами, из сложных эфиров C18-димерной кислоты с от С7- до С22-спиртами, из комплексных сложных эфиров как отдельных компонентов или ...

Hydrauliköle mit verbesserter Dichtungsverträglichkeit

ÖLZUSAMMENSETZUNG FÜR KÜHLMASCHINE

Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden

Schmiermittel für Kühlungsverdichter

POLYOLE ESTER AS LUBRICANTS FOR HIGH TEMPERATURE REFRIGERATION COMPRESSORS

LUBRICANT ON BASIS OF POLYOLE ESTER FOR COOLING TRANSMISSION MEANS

LUBRICATING OIL COMPOSITION

USE OF POLYOLE ESTER COMPOSITIONS LUBRICANTS CONTAINING WITH NOT UMGEZETZTEN HYDROXYL GROUPS AS CRANK CASE LUBRICANTS

Lubricating grease compositions

Two-cycle engine oil formed from a blend of a complex alcohol ester and other basestocks

Liquid compositions containing carboxylic esters

The invention relates to liquid compositions which comprises (A) at least one fluorine-containing hydrocarbon containing one to three carbon atoms; and a lubricant comprising (B) at least one carboxylic ester of (I) a polyhydroxy compound, and (II) a combination of (a) a monocarboxylic acylating agent having four or five carbon atoms, (b) a monocarboxylic acylating agent having from about 7 to about 15 carbon atoms and (c) a polycarboxylic acylating agent. In another aspect of the invention, the liquid compositions consist essentially of (A) at least one fluorine-containing hydrocarbon, and (B) at least one ester of (I) at least one polyhydroxy compound described herein and (II) at least one combination of carboxylic acylating agents as described herein. The lubricant may additionally contain (C) an additive selected from the group consisting of an alkyl phosphite, an alkyl phosphonic acid ester, a nitrogen-containing heterocycle, and a mixture thereof. Liquid compositions also are described wherein the fluorine containing hydrocarbons also contain other halogen such as chlorine. The liquid compositions are useful particularly as refrigeration liquids in refrigerators and air-conditioners including automotive, home and industrial air-conditioners.

Blends of lubricant basestocks with high viscosity complex alcohol esters

Lubricants for refrigeration systems

A polyol ester suitable for use as a lubricant or a lubricant base stock has a kinematic viscosity at 40°C greater than or equal to 200 cSt and a viscosity index of greater than or equal to 100. The ester comprises the reaction product of (a) a polyhydric alcohol component comprising at least 50 mole % of penterythritol, and (b) a carboxylic acid component comprising: (i) at least one linear or branched monocarboxylic acid having 2 to 7 carbon atoms; (ii) at least one branched monocarboxylic acid having 8 to 15 carbon atoms; and (iii) at least one polycarboxylic acid having 2 to 8 carbon atoms; wherein the ratio of the number of acid groups derived from the monocarboxylic acid(s) (i) to the number of acid groups derived from the monocarboxylic acid(s) (ii) is between about 0.9 and about 1.1 and the number of acid groups derived from the polycarboxylic acid(s) (iii) is between about 15 % and about 25 % of the total number of acid groups derived from the carboxylic acids (i), (ii) and (iii ...

Improved food-grade-lubricant

REFRIGERATING MACHINE OIL COMPOSITION

A refrigerating machine oil composition which comprises a base oil comprising a mineral oil and/or a synthetic oil and, compounded therewith, (a) a partial ester of a polyhydric alcohol with a fatty acid and (b) an acid phosphoric ester or an amine salt thereof; and a refrigerating machine oil composition which comprises a base oil comprising a mineral oil and/or a synthetic oil and, compounded therewith, (a) an acid phosphoric ester or an amine salt thereof, (b) an alkylene oxide adduct of an acetylenic glycol, (c) the potassium salt of a fatty acid, etc., (d) an organic acid, and (e) a fatty acide amide, etc. The compositions have excellent lubricating performace and produce a satisfactory friction-reducing effect in either an oily region or an extreme pressure region, especially in friction between an aluminum material and an iron material.

SYNERGISTIC COMBINATION OF ADDITIVE PROVIDING HIGH LOAD CAPACITY AND CORROSION INHIBITORS FOR LUBRICANT COMPOSITIONS

The present invention relates to a lubricant composition exhibiting enhanced load-carrying capacity and oxidative/corrosion stability. The lubricant composition of the present invention comprises a major portion of an aliphatic ester base oil having lubrication properties and formed by the reaction of pentaerythritol and an organic carboxylic acid. The lubricant composition further comprises 3-(di-isobutoxythiophosphonylsulfanyl)-2-methyl-propionic acid (DITMPA) as an additive comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition as well as yellow metal passivator comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition. The enhanced load-carrying capacity and oxidative/corrosion stability of lubricant compositions containing DITMPA and yellow metal passivator is achieved without deleteriously affecting other salient properties of the lubricant.

LUBRICANT ADDITIVES FOR IMPROVING THE TRIBOLOGICAL PROPERTIES, NOVEL LUBRICANTS, PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF

The present invention relates to novel lubricant additives for improving the tribological properties, novel lubricants containing these additives, processes for the preparation thereof and the use thereof.

POLYOL ESTER HEAVY DUTY COMPRESSOR LUBRICANTS

A high quality heavy duty lubricant for refrigerating compressors, especially those using chlorine free hydrofluorocarbon refrigerant working fluids, is provided by mixed esters of hindered polyols, most desirably pentaerythritol with a mixture of carboxylic acids including at least some iso-pentanoic acid along with at least 13 % of dibasic acids such as adipic.

LIQUID COMPOSITIONS CONTAINING CARBOXYLIC ESTERS

Title: LIQUID COMPOSITIONS CONTAINING CARBOXYLIC ESTERS Abstract of the Disclosure This invention relates to a liquid composition comprising (A) at least one fluorine-containing hydrocarbon containing one to three carbon atoms, and a lubricant comprising (B) at least one ester lubricant selected from the group consisting of (i) an ester of a polyhydroxy compound and a monocarboxylic acylating agent having from about 4 to about 15 carbon atoms, and (ii) an ester of polyhydroxy compound and a combination of a dicarboxylic acylating agent and a monocarboxylic acylating agent having about 7 to about 15 carbon atoms, and (C) at least one additive selected from the group consisting of an alkyl phosphite, an alkyl phosphonic acid ester, a nitrogen-containing heterocycle, and a mixture thereof. Liquid compositions also are described wherein the fluorine-containing hydrocarbons also contain other halogens such as chlorine. Methods of lubricating refrigeration systems are also described. The liquid compositions are useful particularly as refrigeration liquids in refrigerators and air-conditioners including automotive, home, commercial and industrial air-conditioners.

LIQUID COMPOSITIONS CONTAINING CARBOXYLIC ESTERS

... 2617B This invention relates to a liquid composition comprising (A) at least one fluorine-containing hydrocarbon containing one to three carbon atoms; and (B) at least one carboxylic ester of (I) a neo hydroxy compound selected from the group consisting of (i) a neo hydroxy compound with two or three hydroxyl groups, (ii) a mixture of neo hydroxy compounds having an average of less than about 3.5 hydroxyl groups per hydroxy compound, (iii) a neo hydroxy compound having five or more hydroxyl groups per hydroxy compound, and (iv) a mixture of neo hydroxy compounds having an average of greater than 4.5 hydroxyl groups per hydroxy compound, and (II) a combination of (a) a monocarboxylic acylating agent having four or five carbon atoms and (b) a monocarboxylic acylating agent having from about 7 to about 15 carbon atoms, provided that when (I) is (i) or (ii) then greater than 55% of the ester groups are derived from (IIa), and provided that when (I) is (iii) or (iv) then greater than 55% of ...

OIL THICKENED WITH ESTOLIDES OF HYDROXY-CONTAINING TRIGLYCERIDES

A thickened composition is disclosed which comprises (A) at least one triglyceride estolide of the formula wherein R1 is an aliphatic group or an aliphatic group containing an ester moiety R2COO- with the proviso that at least one R1 is an aliphatic group containing the ester moiety, and contains from about 5 to about 23 carbon atoms, and R2 is a hydrocarbyl group containing from 1 to 100 carbon atoms and (B) at least one oil comprising (1) a synthetic ester base oil (2) a mineral oil, or (3) a polyalphaolefin.

SYNTHETIC LUBRICANT ANTIOXIDANT FROM MONOSUBSTITUTED DIPHENYLAMINES

An oligomer from diarylamines is disclosed which has desirable antioxidant properties in lubricating oils which contain synthetic ester lubricants. The oligomer is desirable for use at higher temperatures where i t has less volatility than simple diarylamines. The oligomer has substantial portions of monosubstituted diphenylamine repeat units which result in linear oligomers. Di and polysubstitued diphenylamines may optionally be present as repeat units. These di and polysubstituted diphenylamines generally react as monofunctional reactants in oligomerization and tend to reduce the number of repeat units in the average oligomer.

Improvements with compositions containing esters

PROCESS AND COMPOSITION Of LUBRICATING OIL CONTAINING SYNTHETIC ESTER GIVING OF the MOTOR OILS RESISTING the HYDROLYSIS

COMPRESSOR FOR REFRIGERATION AND AIR-CONDITIONING, AND REFRIGERATING AND AIR-CONDITIONING APPARATUS

ESTOLIDE COMPOUND AND METHOD FOR PREPARING THE SAME

The present invention comprises the following steps: changing biomass fat into fatty acid, separating C16 saturated fatty acid and C18 unsaturated fatty acid from the fatty acid, preparing linear internal olefin (LIO), increasing the amount of oleic acid through partial hydro-treating of the C18 unsaturated fatty acid, synthesizing estolide polymer through cross metathesis of the oleic acid, capping the C16 saturated fatty acid into the estolide polymer and reacting the estolide polymer and the internal olefin. The estolide polymer from the invention has great oxidation stability and stability at low temperature with no unsaturated synthesis. It is produced by changing remaining fatty acid in biomass fatty acid into linear internal olefin, requires least dependence on oleic acid in making the estolide polymer by increasing the amount of the oleic acid and is efficient in processing and economically because of no need for alcohol. COPYRIGHT KIPO 2016 (S10) Change biomass fat into fatty acid ...

LUBRICANTS FOR REFRIGERATION SYSTEMS

A lubricating composition which comprises: (A) a polyalkyleneglycol of the general formula (I) : RO (RaO) x (RbO) y (RcO) zRd (I); wherein: R is a C4 to C6 substituent comprising a heterocyclic ring, in which the heteroatom (s) in said ring(s) is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is a hydrogen atom or a C1-C20 alkyl or C1-C20 acyl group, x, y, z are each independently 0 or an integer in the range of from 1 to 100, and x + y + z = 4 to 100 ; and (B) an ester of a alcohol containing two or more hydroxyl groups with a mono- or dicarboxylic acid, or an ester of an dicarboxylic acid with an alcohol containing one hydroxyl group.

LUBRICATING GREASE COMPOSITION

The invention relates to lubricating grease compositions, having a base oil mixture based on oils having viscosities (ISO VG 2 to ISO VG 1500) that are standard for industrial lubricants, an ionic liquid, a thickening agent, e.g. based on a polyurea compound and conventional additives that can be used at current service temperatures that are higher than 120°C to 260°C, in particular at a service temperature in the region of high service temperatures that are higher than 180°C to 260°C and also at low temperatures as low as -6O°C. The invention also relates to a method for producing said type of lubricating grease compositions.

SILICONE BASED LUBRICANT COMPOSITIONS

Compositions comprising silicone fluids are formulated to provide improved metal -to- metal lubrication. Such Lubricating compositions comprise a major amount of (1) one or more siloxane polymer ("silicone fluids") selected from dimethyl siloxane polymers (also known as dimethyl silicone) and/or phenylmethyl dimethyl siloxane copolymers (also known as phenyl silicone), and lesser amounts of (2) synthetic and/or bio-based ester co- fluid, and (3) an alkoxylated aliphatic polyamine derivative. Unexpectedly, the compositions show a significant improvement in metal-to-metal lubrication, performing better than either the silicone fluids alone or and a combination of silicone with-ester and or silicone with-alkoxylated aliphatic polyamine combinations.

BIODEGRADABLE NON-TOXIC GEAR OIL

A biodegradable lubricating oil composition especially useful as a gear oil employs a synthetic alcohol ester basestock formed from mono- and dipentaerythritol with certain mono- and dicarboxylic acids or dicarboxylic acid anhydrides and an effective amount of a polyoxyalkylene alcohol demulsifying agent, a combination of alkylated organic acid and ashless succinimide rust inhibitors and an ashless dithiocarbamate antiwear and extreme pressure agent.

LUBRICANT FOR HIGH-TEMPERATURE BELT PRESSES

The invention relates to a synthetic high-temperature lubricant for lubricating high-temperature belt presses, said lubricant comprising a synthetic base oil mixture [A)] containing a base material [a)] based on naphthalene or a naphthalene derivative, a polyester base material [b)], and a complex ester base material [c)], and an additive packet [B)] containing a corrosion inhibitor [a], an extreme pressure additive [b)], an antioxidant [c)], a nonferrous metal deactivator [d)], and a wear-reducing means [e)]. The aim of the invention is to obtain a synthetic high-temperature lubricant for high-temperature belt presses, which has a corrosive action on copper according to DIN EN ISO 2160 at 150 °C after 24 hours with a degree of corrosion of (1), and passes a steel corrosion test according to DIN ISO 7120.

METHOD FOR LUBRICATING HIGH PRESSURE HYDRAULIC SYSTEM USING PHOSPHATE ESTER HYDRAULIC FLUID

The present invention is a method for operating a hydraulic system at pressures of about 4000 psi or higher, preferably about 5000 psi or higher by using as the lubricant a phosphate ester hydraulic oil comprising a fire resistant phosphate esters base stock, a viscosity index improver, an anti erosion agent, an acid scavenger. The fluid used in the present method can also contain rust inhibitors and/or antioxidants.

LUBRICATING OIL FOR REFRIGERATOR

A lubricating oil for a refrigerator using a chlorofluorocarbon substitute as the refrigerant, which contains a polymer of a fumaric ester or a copolymer of a fumaric ester with a copolymerizable alkylene and, if desired, an organic carboxylic ester or a polyalkylene glycol with a kinematic viscosity of 2 to 30 cSt. The oil is compatible with a refrigerant comprising a chloroflurocarbon substitute such as a hydrochlorofluorocarbon, in particular, R134a in a wide temperature range, has a high viscosity index, is thermally and chemically stable, and has an excellent lubricity.

Lubricating oil composition for refrigerating machine, working fluid, and refrigerating machine

The present invention relates to a refrigeration oil for a refrigerating machine using Flon as a refrigerant. In particular, the present invention relates to a lubricating oil composition for a refrigerating machine using hydrofluorocarbon (HFC) containing no chlorine as a refrigerant, also relates to a working fluid and a refrigerating machine.

Ball bearing

A ball bearing is described, which comprises an outer ring having on its inner periphery an outer raceway, an inner ring having on its outer periphery an inner raceway, plural balls rotatably disposed between the outer raceway and the inner raceway, a cage holding the plural balls in a freely rotatable manner, and a grease packed in a space between the outer raceway and the inner raceway, wherein the inner peripheral surface of each pocket of the cage contains a spherical part consisting of a spherical concave surface whose radius of curvature is slightly larger than that of each ball and a curved part which has the radius of curvature being larger than that of the spherical part and is smoothly continuous from the end of the spherical part toward the end thereof on the opening side of the pocket.

METHOD FOR PRODUCING A TWO PHASE LUBRICANT COMPOSITION

This invention provides a method for producing a lubricant composition that is comprised of a continuous phase and a discontinuous phase. The method involves mixing together high viscosity ester, ether or combination thereof, and polar diluent or solvent, to produce a solution. The solution is then added to a low viscosity Group IV base oil to produce a discontinuous phase dispersed throughout a continuous phase.

BIODEGRADABLE LUBRICANT COMPOSITION

A biodegradable lubricating oil composition includes (A) an ester being obtained by reacting a saturated aliphatic carboxylic acid, a straight-chain aliphatic dicarboxylic acid and a polyhydric alcohol together, the ester having a kinematic viscosity in a range from 400 mm2/s to 1000 mm2/s at 40 degrees C and an acid value of 0.5 mgKOH/g or less; (B) an ester being obtained by reacting a straight-chain saturated aliphatic carboxylic acid with a polyhydric alcohol, the ester having an acid value of 0.5 mgKOH/g or less; and (C) a phosphate amine salt being obtained by reacting an acidic phosphate with an alkylamine.

Lubricating oil for refrigerator and refrigerator fluid composition for refrigerator using the same

The present invention proposes a lubricating oil for refrigerators comprising, as the base oil, a polyvinyl ether derivative and a polyoxyalkylene glycol derivative. The lubricating oil exhibits excellent miscibility with a refrigerant having one carbon atom and no chlorine atoms and, in particular, with difluoromethane and provides a hydraulic fluid composition exhibiting excellent antiwear, lubricity and stability.

Refrigerating machine oil composition

Disclosed is a refrigerating machine oil composition, comprising a base oil and a metal salt of a carboxylic aid having from 3 to 60 carbon atoms. The refrigerating machine oil (lubricating oil) of the present invention is very well miscible with hydrogen-containing Flon refrigerants such as Flon 134a, achieves an excellent lubrication performance and is good enough to bring forth marked improvement of a wear resistance, particularly a wear resistance of aluminum-steel friction surfaces.

ЭСТОЛИДЫ И КОМПОЗИЦИИ СМАЗЫВАЮЩИХ МАТЕРИАЛОВ, ПОЛУЧЕННЫЕ НА ОСНОВЕ РЕАКЦИИ ДИЛЬСА-АЛЬДЕРА

В настоящем изобретении предлагаются смазочные композиции, содержащие по меньшей мере одно соединение эстолида и по меньшей мере одно соединение ена и/или соединение, полученное с помощью реакции Дильса-Альдера. В определенных вариантах осуществления добавление по меньшей мере одного соединения ена и/или соединения, полученного с помощью реакции Дильса-Альдера, к композиции, содержащей эстолид, может улучшить низкотемпературные, вискозиметрические и/или противоизносные свойства композиции. 17 з.п. ф-лы, 4 табл., 12 пр.

РАСТВОРИМОЕ МАСЛО, СОДЕРЖАЩЕЕ СВЕРХЩЕЛОЧНЫЕ СУЛЬФОНАТНЫЕ ПРИСАДКИ

FIELD: chemistry. SUBSTANCE: invention relates to a soluble oil composition for use as lubricant and coolant oil, containing:| a) base oil; b) an emulsion stabilising amount of neutralised carboxylic acid obtained from tall oil; c) at least one ultra-alkaline sulphonate of an alkali-earth metal; and, optionally, d) at least one additive selected from a group consisting of an antiscoring agent, an antiwear agent, an emulsifier, an antirust agent, a corrosion inhibitor, an anti-foaming agent, antioxidant additives, surfctants, a friction modifier and stabilisers. EFFECT: environmentally safe stable lubricant-coolant oil emulsions for cutting metal with improved cutting properties. 12 cl, 53 ex, 12 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 458 110 (13) C2 (51) МПК C10M C10M C10N C10N C10N C10N 163/00 173/00 10/02 10/04 30/06 40/22 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2009119512/04, 06.09.2007 (24) Дата начала отсчета срока действия патента: 06.09.2007 (72) Автор(ы): РИФФ Игор (US), КОСТЕЛЛО Майкл Т. (US) (73) Патентообладатель(и): КЕМТУРА КОРПОРЕЙШН (US) R U Приоритет(ы): (30) Конвенционный приоритет: 24.10.2006 US 11/586,195 (43) Дата публикации заявки: 27.11.2010 Бюл. № 33 2 4 5 8 1 1 0 (45) Опубликовано: 10.08.2012 Бюл. № 22 (56) Список документов, цитированных в отчете о поиске: US 4228021 А, 14.10.1980. US 3311561 А, 28.03.1967. ЕР 0512425 А1, 11.11.1992. WO 2004/106475 А, 03.12.2004. GB 778468 А, 10.07.1957. US 6774165 В1, 10.08.2004. RU 2114160 С1, 27.06.1998. 2 4 5 8 1 1 0 R U (86) Заявка PCT: US 2007/019497 (06.09.2007) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 25.05.2009 (87) Публикация заявки РСТ: WO 2008/051330 (02.05.2008) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр.3, ООО "Юридическая фирма Городисский и Партнеры" (54) РАСТВОРИМОЕ МАСЛО, СОДЕРЖАЩЕЕ СВЕРХЩЕЛОЧНЫЕ СУЛЬФОНАТНЫЕ ПРИСАДКИ ...

СПОСОБ СНИЖЕНИЯ МОЛЕКУЛЯРНОЙ МАССЫ ОЛЕФИНОВЫХ СОПОЛИМЕРОВ

Изобретение относится к способам снижения молекулярной массы олефиновых сополимеров для использования их в качестве добавки в смазочных маслах. Описан способ снижения молекулярной массы олефиновых сополимеров, включающий контактирование олефинового сополимера и базового масла, содержащего менее чем приблизительно 0,05 мас.% серы, в присутствии кислорода и при температуре, по меньшей мере, равной приблизительно 60°С и до приблизительно 120°С. Технический эффект – более быстрое снижение молекулярной массы олефиновых сополимеров при технологически мягких условиях. 5 з.п. ф-лы.

KALTEMASCHINENOLZUSAMMENSETZUNG

COLD ROLLING OIL FOR STEELS

Improvements in or relating to ester-base compositions

A lubricant composition comprises an ester base oil and 0.002-2 weight per cent of a 1,2,4-triazole of formula where R1, R2, R3 and R4 are hydrogen, alkyl, aryl, alkaryl, aralkyl, cycloalkyl, acyl or aroyl, the symbol (R4) meaning that R4 is attached to any one of the ring nitrogen atoms or is a labile substituent if R4 is hydrogen. The ester base oil may be a diester of a dibasic acid, a complex ester or a polyester formed from a polyol having 3 or more hydroxyl groups (examples of all types of esters are given). The composition may contain a thickener e.g. polyacrylates and methacrylates, polyglycol ethers and copolymers of ethylene and propylene oxides, an anti-oxidant e.g. phenothiazine, substituted phenothiazines together with secondary aromatic amines, and alkylated phenols, extreme pressure additives e.g. esters of phosphorus acids preferably in admixture with secondary amines; diaryl haloalkyl phosphates such as diphenyl-2,2-bis (chloromethyl) 3-chloro propyl ...

Process to produce low shear strength base oils

A lubricating fluid comprising a base oil, which utilizes carboxylic esters of carboxyl di-end-capped-polyethylene glycols, or a mixture thereof with carboxylic esters of carboxyl di-end-capped-polytetramethylene glycols, to improve low temperature performance, as well as minimize elastohydrodynamic shear strength, and enables the production of high efficiency fluids with enhanced low temperature properties for machines or machine elements that operate in the elastohydrodynamic regime in lubrication.

PHOSPHORUS CONTAINING COMPOSITIONS FOR REFRIGERANT PLANTS.

Modified vegetable oil lubricants

Lubricants based on renewable feedstocks and methods of making them.

Sulfurized estolides and methods of making and using the same

Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; m is an integer equal to or greater than 1; R 2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R 1 , R 3 , and R 4 , independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein at least one of R 1 , R 2 , R 3 , or R 4 is sulfurized or epoxidized. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Working Fluid Composition for Refrigerating Machine and Refrigerating Machine Oil

The present invention provides a working fluid composition for a refrigerating machine containing: a refrigerating machine oil containing, as a base oil, a mixed ester of (A) a complex ester synthesized from a polyhydric alcohol such as neopentyl glycol, a polybasic acid having 6 to 12 carbon atoms, a monohydric alcohol having 4 to 18 carbon atoms and the like, and (B) a polyol ester synthesized from a polyhydric alcohol such as neopentyl glycol and a monocarboxylic fatty acid having 4 to 18 carbon atoms, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and a refrigerant such as carbon dioxide. 1. A working fluid composition for a refrigerating machine , comprising:a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester synthesized from a polyhydric alcohol comprising at least one selected from neopentyl glycol, trimethylolpropane and pentaerythritol, at least one selected from polybasic acids having 6 to 12 carbon atoms, and at least one selected from monohydric alcohols having 4 to 18 carbon atoms and monocarboxylic fatty acids having 4 to 18 carbon atoms, and (B) a polyol ester synthesized from at least one polyhydric alcohol selected from neopentyl trimethylolpropane, pentaerythritol and dipentaerythritol, and at least one selected from monocarboxylic fatty acids having 4 to 18 carbon atoms, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; anda refrigerant selected from carbon dioxide, 1,1,1,2-tetrafluoroethane, a mixture of difluoromethane and pentafluoroethane, a mixture of difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane, and a mixture of pentafluoroethane, 1,1,1,2-tetrafluoroethane and 1,1,1-trifluoroethane.2. The working fluid composition for a refrigerating machine according to claim 1 , wherein the polyhydric alcohol constituting (A) the complex ester further comprises a dihydric alcohol having 2 to 10 carbon atoms except neopentyl glycol.3. The ...

Processes of preparing estolide base oils and lubricants that include transesterification

Provided herein are processes of producing estolide base oils, including the process comprising providing at least one fatty acid ester, and contacting the at least one fatty acid ester with at least one fatty acid to form an estolide base oil. Exemplary processes include the use of transesterification to form the at least one fatty acid ester and/or estolide base oil.

Novel Ester Compounds, Method for the Production Thereof and Use Thereof

The invention relates to ester compounds of the general formula (I) 5. The mixture of at least two ester compounds as claimed in claim 1 , wherein two of the at least two ester compounds in each case are regioisomers of one another.6. The mixture of least two ester compounds as claimed in claim 2 , wherein two of the at least two ester compounds in each case are regioisomers of one another.7. The mixture of least two ester compounds as claimed in claim 3 , wherein two of the at least two ester compounds in each case are regioisomers of one another.8. The mixture of least two ester compounds as claimed in claim 4 , wherein two of the at least two ester compounds in each case are regioisomers of one another.9. The mixture of least two ester compounds as claimed in claim 1 , further comprising at least one further ester not having the general formula (I).10. The mixture of least two ester compounds as claimed in claim 9 , wherein the at least one further ester is selected from the group consisting of trimethylolpropane and pentaerythritol esters claim 9 , TMP complex esters in fully or partly esterified form with saturated and/or mono- or polyunsaturated carboxylic acids of chain length C6-C36 claim 9 , where these may be linear or branched claim 9 , complex esters of dimer acids claim 9 , dimer acid esters claim 9 , ethylhexyl dimerate claim 9 , aliphatic carboxylic claim 9 , dicarboxylic esters claim 9 , phosphate esters claim 9 , trimellitic and pyromellitic esters claim 9 , and natural glyceride ester. This application is a divisional of co-pending U.S. application Ser. No. 16/493,830, which issued as U.S. Pat. No. 10,829,436, on Nov. 10, 2020, and which is a 35 U.S.C. 371 National Stage application of PCT/EP2018/000197, filed Apr. 11, 2018 and claiming priority to German Application Nos. DE 10 2017 003 647.0, filed on Apr. 13, 2017, DE 10 2018 002 891.8, filed on Apr. 10, 2018. The entire contents of the above-mentioned patent applications are incorporated herein ...

Novel Ester Compounds, Method for the Preparation Thereof and Use Thereof

Ester compounds, such as for use in a lubricant, are based on di-, tri- or higher functional carboxylic acids according to formula (I) 2. The ester compound as claimed in claim 1 , in which the radical Z is selected from the group consisting of hydrogenated or non-hydrogenated dimer acid claim 1 , hydrogenated or non-hydrogenated trimer acid claim 1 , phthalic acid claim 1 , itaconic acid claim 1 , oxalic acid claim 1 , 2 claim 1 ,2′-thiodiacetic acid claim 1 , 3 claim 1 ,3′-thiodipropionic acid claim 1 , admergic acid claim 1 , 2 claim 1 ,5-furandicarboxylic acid claim 1 , cyclohexane-1 claim 1 ,4-dicarboxylic acid claim 1 , cyclohexane-1 claim 1 ,2-dicarboxylic acid claim 1 , phenyl succinic acid claim 1 , diglycolic acid.4. The ester compound as claimed in claim 3 , in which the radical Z is selected from the group consisting of hydrogenated or non-hydrogenated dimer acid claim 3 , phthalic acid claim 3 , oxalic acid claim 3 , 2 claim 3 ,2′- thiodiacetic acid claim 3 , 3 claim 3 ,3′-thiodipropionic acid claim 3 , admergic acid claim 3 , cyclohexane-1 claim 3 ,4-dicarboxylic acid claim 3 , cyclohexane-1 claim 3 ,2-dicarboxylic acid claim 3 , phenylsuccinic acid claim 3 , diglycolic acid.6. The method for producing the ester compound of the general formula (I) or (II) as claimed in claim 5 , in which the unsaturated fatty acid is selected from the group consisting of oleic acid and erucic acid; the alcohol is selected from the group consisting of 2-ethylhexan-1-ol claim 5 , 2-hexyldecan-1-ol claim 5 , 2-octyldodecan-1-ol claim 5 , 2-propylheptan-1-ol and isoamyl alcohol and the catalyst in reaction step (A) is perchloric acid and in reaction step (D) is p-toluenesulfonic acid.7. A method for producing the ester compound of the general formulae (I) or (II) obtainable by(A) reacting a di-, tri- or higher functional carboxylic acid with a long-chain fatty acid having hydroxyl groups in the presence of a catalyst at 120 to 150° C.,(B) reducing the pressure,(C) ...

Bio-based estolide compositions

Levulinic-capped estolides having improved physical properties that make them more desirable and suitable as bio-based industrial or commercial products are disclosed. The physical properties of the disclosed estolide compositions have surprisingly low pour points that are substantially lower than previously known estolide compounds and superior to petroleum-based compounds designed for similar applications.

HEAT PUMP APPARATUS

A heat pump apparatus is provided in which refrigerant circulates between an indoor unit and an outdoor unit, wherein the refrigerant is a mixed refrigerant of HFO-1123 and an HFC refrigerant other than HFO-1123, the outdoor unit has a cooling capacity (kW) in the range of 2.2 to 9.5 kW, the outer diameter φ (mm) of a gas pipe between the indoor unit and the outdoor unit and the cooling capacity (kW) of the outdoor unit satisfy the relation (1.00≦outer diameter φ (mm) of gas pipe/cooling capacity (kW) of outdoor unit≦5.77), and the outer diameter φ (mm) of a liquid pipe between the indoor unit and the outdoor unit and the cooling capacity (kW) of the outdoor unit satisfy the relation (0.67≦outer diameter φ (mm) of liquid pipe/cooling capacity (kW) of outdoor unit≦5.77). 1. A heat pump apparatus comprising:an indoor unit;an outdoor unit having a cooling capacity (kW) in the range of 2.2 to 9.5 kW;a refrigerant circulating between the indoor unit and the outdoor unit, the refrigerant being a mixed refrigerant of HFO-1123 and an HFC refrigerant other than HFO-1123;a gas pipe communicating between the indoor unit and the outdoor unit; anda liquid pipe communicating between the indoor unit and the outdoor unit, [{'br': None, '1.00≦an outer diameter φ(mm) of the gas pipe/the cooling capacity (kW) of the outdoor unit≦5.77\u2003\u2003(1)'}, {'br': None, '0.67≦an outer diameter φ(mm) of the liquid pipe/the cooling capacity (kW) the of outdoor unit≦5.77\u2003\u2003(2)'}], 'the gas pipe and the outdoor unit being configured to satisfy the following formula (1), and the liquid pipe and the outdoor unit being configured to satisfy the following formula (2)2. A heat pump apparatus comprising:a plurality of indoor units;at least one outdoor unit having a cooling capacity (kW) of 10 kW or more and less than 40 kW;a refrigerant circulating between the plurality of indoor units and the at least one outdoor unit, the refrigerant being a mixed refrigerant of HFO-1123 and an HFC ...

Branched diesters and methods of making and using the same

The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds. In certain embodiments, a vegetable oil-based diester (1,6-hexyldioleate) was branched with propanoic acid (C3) using a green synthetic approach involving solvent-free and catalyst-free epoxide ring opening followed by in situ normal esterification. A total of three branched ester derivatives possessing varied numbers of internal protruding branched ester groups and hydroxyl groups were obtained. All of the pure branched derivatives were comprised of mixtures of positional isomers and/or stereoisomers. Differential scanning calorimetry (DSC) showed that regardless of the composition inhomogeneity of each branched derivative, crystallization was suppressed completely in all of the branched compounds, and they all demonstrated glass transitions below −65° C. Without being bound by any theory, it is believed that this unique thermal behavior is attributed to the internal protruding branched moieties and hydroxyl groups, which dramatically slowed down mass transfer starting with the least branched compound (2-branched derivative). The viscosity of the branched compounds was one order of magnitude larger than that of the starting di ester due to the increased branching and increased resistance to flow associated with hydrogen bonding introduced by the OH groups. Overall, these branched diesters demonstrated superior low temperature and flow properties comparable to existing non-sustainable commercial lubricants and analogous biobased materials which makes them suitable alternatives for use in lubricant formulations particularly in high ...

Novel Ester Compounds, Method for the Production Thereof and Use Thereof

The invention relates to novel ester compounds of the general formula (I) 5. The mixture of ester compounds as claimed in claim 1 , characterized in that two of the at least two ester compounds in each case are regioisomers of one another.7. The process as claimed in claim 6 , characterized in that claim 6 , as a further reaction step (D) claim 6 , the Rgroup is subjected to an esterification or transesterification reaction.8. The process as claimed in claim 6 , characterized in that claim 6 , as a further reaction step (E) claim 6 , in the case of a free hydroxyl group in the Rradical claim 6 , the further esterification thereof is conducted.9. The process as claimed in claim 6 , characterized in that the starting compound used is at least one unsaturated fatty acid selected from the group consisting of oleic acid claim 6 , linoleic acid claim 6 , linolenic acid claim 6 , erucic acid claim 6 , nervonic acid claim 6 , gadoleic acid and/or another ω-n-fatty acid.11. The process as claimed in claim 10 , characterized in that claim 10 , as a further reaction step (D) claim 10 , the Rgroup is subjected to an esterification or transesterification reaction.12. The process as claimed in claim 10 , characterized in that claim 10 , as a further reaction step (E) claim 10 , in the case of a free hydroxyl group in the Rradical claim 10 , the further esterification thereof is conducted.13. The process as claimed in claim 10 , characterized in that the starting compound used is at least one unsaturated fatty acid selected from the group consisting of oleic acid claim 10 , linoleic acid claim 10 , linolenic acid claim 10 , erucic acid claim 10 , nervonic acid claim 10 , gadoleic acid and/or another ω-n-fatty acid.14. The process as claimed in claim 6 , characterized in that a biocatalyst selected from the enzyme class of the hydrolases is used for at least one of the esterification reactions involved.15. The process as claimed in claim 6 , characterized in that at least one of ...

ESTOLIDE COMPOSITIONS EXHIBITING HIGH OXIDATIVE STABILITY

Provided herein are estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: 1131-. (canceled)133. The base oil according to claim 132 , whereinx is, independently for each occurrence, an integer selected from 0 to 14;y is, independently for each occurrence, an integer selected from 0 to 14;n is an integer selected from 0 to 8;{'sub': 1', '1', '22, 'Ris an optionally substituted Cto Calkyl that is saturated or unsaturated, and branched or unbranched; and'}{'sub': 2', '1', '22, 'Ris an optionally substituted Cto Calkyl that is saturated or unsaturated, and branched or unbranched,'}wherein each fatty acid chain residue is unsubstituted.134. The base oil according to claim 133 , whereinx+y is, independently for each chain, an integer selected from 13 to 15; andn is an integer selected from 0 to 6.135. The base oil according to claim 134 , wherein Ris branched.136. The base oil according to claim 135 , wherein Ris selected from Cto Calkyl.137. The base oil according to claim 136 , wherein Ris 2-ethylhexyl.138. The base oil according to claim 135 , wherein Ris unbranched.139. The base oil according to claim 132 , wherein the base oil claim 132 , when combined with an antioxidant claim 132 , exhibits a time of at least 700 minutes when tested in a rotating pressurized vessel oxidation test using ASTM Method 2272-11.140. The base oil according to claim 132 , wherein the base oil claim 132 , when combined with an antioxidant claim 132 , exhibits a time of at least 1000 minutes when tested in a rotating pressurized vessel oxidation test using ASTM Method 2272-11.141. The base oil according to claim 132 , wherein the antioxidant comprises at least one of an amine antioxidant or a phenolic antioxidant.142. The base oil according to claim 141 , the estolide base oil has an acid value equal to or less than 0.1 mg KOH/g143. The base oil according to claim 142 , wherein the antioxidant comprises a diarylamine antioxidant ...

Lubricant base oil, refrigerator oil and working fluid composition for refrigerators

The lubricating base oil of the present invention comprises an ester synthesized from: a first component that is at least one selected from polyhydric alcohols having 2 to 4 hydroxyl groups; a second component that is at least one selected from polybasic acids having 6 to 12 carbon atoms; and a third component that is at least one selected from monohydric alcohols having 4 to 18 carbon atoms and monocarboxylic acids having 2 to 12 carbon atoms. In addition, the refrigerating machine oil and the working fluid composition for a refrigerating machine of the present invention each comprise the above lubricating base oil.

Method for producing biolubricant from vegetable oil, and biolubricant

The present invention describes a process for obtaining a biolubricant from vegetable oil, which comprises the steps of (a) esterification reaction of the product of vegetable oil hydrolysis using a branched aliphatic alcohol; (b) epoxidation reaction of the esters obtained in step (a); and (c) nucleophilic substitution reaction of the epoxidated esters obtained in step (b) using a branched aliphatic alcohol. The present invention also describes a biolubricant obtained from the process. More specifically, a biolubricant is described that is produced from a ricinoleic fatty acid, whose formula is illustrated in FIG. 1 of the present invention, and where R1 is a hydroxyl or it is from the formula R3COO−, with R3 being an alkyl radical C1-C3, preferably a methyl radical; and R2 consists of a straight chain of hydrocarbons C4-C8 and a branched chain of hydrocarbons C1-C3.

LUBRICANT BASE OIL

A lubricant base oil which contains an ester. The ester constituting the lubricant base oil includes: a component (A) derived from pentaerythritol in a molar percentage Aof 20 to 30 mol %; a component (B) derived from a straight-chain fatty acid having a carbon number of 14 to 22 in a molar percentage Bof 55 to 79 mol %; and a component (C) derived from adipic acid in a molar percentage Cof 1 to 15 mol %. A molar ratio (C/C) of the component (C) derived from adipic acid and the component (B) derived from the straight-chain fatty acid having a carbon number of 14 to 22 is 0.02 to 0.25, and the ester has a hydroxyl value of 10 to 100 mgKOH/g. 1{'sub': 'mol %', 'a component (A) derived from pentaerythritol in a molar percentage Aof 20 to 30 mol %;'}{'sub': 'mol %', 'a component (B) derived from a straight-chain fatty acid having a carbon number of 14 to 22 in a molar percentage Bof 55 to 79 mol %; and'}{'sub': 'mol %', 'a component (C) derived from adipic acid in a molar percentage Cof 1 to 15 mol %,'}{'sub': mol', 'mol, 'wherein a molar ratio (C/B) of said component (C) derived from adipic acid and said component (B) derived from said straight-chain fatty acid having a carbon number of 14 to 22 is 0.02 to 0.25, and'}wherein said ester has a hydroxyl value of 10 to 100 mgKOH/g.. A lubricant base oil comprising an ester, said ester comprising: The present invention relates to a lubricant base oil. Specifically, the present invention relates to a lubricant base oil having excellent biodegradability, excellent lubricating property (wear resistance) and excellent rust prevention property against sea water. The lubricant base oil may be suitably used for a bearing oil, hydraulic oil, gear oil or the like and more suitably used for a stern tube bearing oil used in oceans.Recently, it is demanded new trials for environmental preservation as important mission worldwide. Such mission is also demanded in the field of a lubricating oil, and it is further demanded a lubricating ...

WORKING FLUID COMPOSITION FOR REFRIGERATOR

The present invention provides a working fluid composition for a refrigerating machine, comprising: a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a C6-C12 polybasic acid, and a C4-C18 monohydric alcohol or a C4-C18 monocarboxylic fatty acid, and (B) a polyol ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane, pentaerythritol and dipentaerythritol, and a C4-C18 monocarboxylic fatty acid, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; and a hydrocarbon refrigerant having 3 or 4 carbon atoms, wherein a refrigerant dissolved viscosity, at a temperature of 80° C. and an absolute pressure of 1.5 MPa, is 1.0 mm/s or more. 1. A working fluid composition for a refrigerating machine , comprising:a refrigerating machine oil comprising, as a base oil, a mixed ester of (A) a complex ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a C6-C12 polybasic acid, and a C4-C18 monohydric alcohol or a C4-C18 monocarboxylic fatty acid, and (B) a polyol ester obtainable by synthesis of at least one polyhydric alcohol selected from neopentyl glycol, trimethylolpropane, pentaerythritol and dipentaerythritol, and a C4-C18 monocarboxylic fatty acid, in a mass ratio of (A) the complex ester/(B) the polyol ester of 5/95 to 95/5; anda hydrocarbon refrigerant having 3 or 4 carbon atoms,{'sup': '2', 'wherein a refrigerant dissolved viscosity, at a temperature of 80° C. and an absolute pressure of 1.5 MPa, is 1.0 mm/s or more.'}2. The working fluid composition for a refrigerating machine according to claim 1 , wherein the polyhydric alcohol constituting (A) the complex ester is neopentyl glycol and/or trimethylolpropane.3. The working fluid ...

COMPOSITIONS COMPRISING ESTOLIDE COMPOUNDS AND METHODS OF MAKING AND USING THE SAME

Provided herein are compositions comprising at least one estolide compound of formula: 1128-. (canceled)130. The composition of claim 129 , wherein x is 3.131. The composition of claim 130 , wherein y is 12.132. The composition of claim 129 , wherein x is 7.133. The composition of claim 132 , wherein y is 8.134. The composition of claim 133 , wherein Ris an unsubstituted C-Calkyl.135. The composition of claim 134 , wherein Ris saturated.136. The composition of claim 135 , wherein Ris unbranched.137. The composition of claim 133 , wherein Ris an unsubstituted Calkyl that is unbranched.138. The composition of claim 137 , wherein Ris saturated.139. The composition of claim 138 , wherein Ris unbranched.140. The composition of claim 129 , wherein the synthetic compound is purified.141. The composition of claim 140 , wherein the synthetic compound is racemic.142. The composition of claim 140 , wherein the synthetic compound is optically active.143. The composition of claim 140 , wherein the synthetic compound is enantiomerically pure.144. The composition of claim 129 , wherein the at least one additive is selected from an antioxidant claim 129 , a surfactant claim 129 , or a stability enhancer.145. The composition of claim 139 , wherein the synthetic compound is racemic.146. The composition of claim 139 , wherein the synthetic compound is optically active.147. The composition of claim 139 , wherein the synthetic compound is enantiomerically pure.148. The composition of claim 139 , wherein the at least one additive is selected from an antioxidant claim 139 , a surfactant claim 139 , and a stability enhancer. This application claims the benefit under 35 U.S.C. § 119(e) of U.S. Provisional Patent Application No. 61/498,499, filed Jun. 17, 2011, and U.S. Provisional Patent Application No. 61/569,046, filed Dec. 9, 2011, which are incorporated herein by reference in their entireties for all purposes.The present disclosure relates to compositions comprising estolide compounds ...

PROCESSES OF PREPARING ESTOLIDE BASE OILS AND LUBRICANTS THAT INCLUDE TRANSESTERIFICATION

Provided herein are processes of producing estolide base oils, including the process comprising providing at least one fatty acid ester, and contacting the at least one fatty acid ester with at least one fatty acid to form an estolide base oil. Exemplary processes include the use of transesterification to form the at least one fatty acid ester and/or estolide base oil. 1. A process of producing an estolide base oil comprisingproviding at least one fatty acid ester; andcontacting the at least one fatty acid ester with at least one fatty acid to form an estolide base oil.2. The process according to claim 1 , wherein the at least one fatty acid ester is a fatty acid alkyl ester.3. The process according to claim 2 , wherein the alkyl residue of the fatty acid alkyl ester is unsubstituted.4. The process according to any one of - claim 2 , wherein the fatty acid residue of the at least one fatty acid ester comprises at least one site of unsaturation.5. The process according to any one of - claim 2 , wherein the at least one fatty acid ester is monounsaturated.6. The process according to any one of - claim 2 , wherein the at least one fatty acid is saturated.7. The process according to any one of - claim 2 , wherein the contacting the at least one fatty acid ester with the at least one fatty acid occurs in the presence of at least one catalyst.8. The process according to claim 7 , wherein the at least one catalyst is a Lewis acid.9. The process according to claim 8 , wherein the at least one catalyst is a triflate.10. The process according to claim 7 , wherein the at least one catalyst is a Bronsted acid.11. The process according to claim 10 , wherein at least one catalyst is selected from one or more of hydrochloric acid claim 10 , nitric acid claim 10 , methanesulfonic acid claim 10 , sulfuric acid claim 10 , phosphoric acid claim 10 , perchloric acid claim 10 , triflic acid claim 10 , or p-TsOH.12. The process according to any one of - claim 10 , wherein the process of ...

LUBRICATING OIL COMPOSITION

A lubricating oil composition including 100 mass parts of (A) an ester compound, 0.05 to 1.5 mass parts of (B) an amine salt of an acidic phosphoric ester and 0.01 to 0.50 mass parts of (C) a monoesterified compound, wherein (A) the ester compound is an ester compound of trimethylolpropane, a straight-chain saturated fatty acid having a carbon number of 8 to 10 and adipic acid; (B) the amine salt is an amine salt of an acidic phophoric ester; and (C) the monoesterified compound is a monoesterified compound of an alkane diol having a carbon number of 3 to 8 and of succinic acid having an alkyl group having a carbon number of 8 to 18 or an alkenyl group having a carbon number of 8 to 18. 1100 mass parts of (A) an ester compound described below;0.05 to 1.5 mass parts of (B) an amine salt of an acidic phosphoric ester described below; and0.01 to 0.50 mass parts of (C) a monoesterified compound described below, wherein:{'sub': mol %', 'mol %', 'mol %', 'mol %', 'mol %', 'mol %, '(A) said ester compound of trimethylolpropane, a straight-chain saturated fatty acid having a carbon number of 8 to 10 and adipic acid, said ester compound satisfying the relationship of TMP:FA:ADof 20 to 40%:40 to 70%:5 to 25%, respectively, provided that TMPis assigned to a molar percentage of a component derived from trimethylolpropane, FAis assigned to a molar percentage of a component derived from said straight-chain saturated fatty acid having a carbon number of 8 to 10, and ADis assigned to a molar percentage of adipic acid'}(B) said amine salt of said acidic phosphoric ester represented by the following formula (1):. A lubricating oil composition comprising:wherein n represents an integer of 1 or 2,R′ represents an alkyl group having a carbon number of 4 to 6, andR″ represents hydrogen atom or an alkyl group having a carbon number of 11 to 14; and(C) said monoesterified compound of an alkane diol having a carbon number of 3 to 8 and of succinic acid having an alkyl group having a carbon ...

COMPOSITION FOR HEAT CYCLE SYSTEM, AND HEAT CYCLE SYSTEM

To provide a composition for a heat cycle system having favorable lubricating properties and comprising a working fluid for heat cycle which has a low global warming potential and which can replace R410A and a heat cycle system employing the composition. A composition for a heat cycle system comprising a working fluid for heat cycle containing trifluoroethylene, and a refrigerant oil (for example, an ester refrigerant oil, an ether refrigerant oil, a polyglycol refrigerant oil or a hydrocarbon refrigerant oil), and a heat cycle system employing the composition for a heat cycle system. 1. A composition for a heat cycle system , comprising: a working fluid for heat cycle; and a refrigerant oil , wherein the working fluid for a heat cycle comprises trifluoroethylene (HFO-1123) , difluoromethane (HFC-32) , and (E)-1 ,3 ,3 ,3-tetrafluoropropene (HFO-1234ze(E)) in amounts of:{'br': None, '10 mass %≤HFO-1123≤80 mass %;'}{'br': None, '10 mass %≤HFC-32≤75 mass %; and'}{'br': None, 'i': ze', 'E, '5 mass %≤HFO-1234()≤60 mass %.'}2. The composition for a heat cycle system according to claim 1 , wherein the refrigerant oil is at least one member selected from an ester refrigerant oil claim 1 , an ether refrigerant oil claim 1 , a polyglycol refrigerant oil and a hydrocarbon refrigerant oil.3. The composition for a heat cycle system according to claim 2 , wherein the refrigerant oil is at least one member selected from a dibasic acid ester claim 2 , a polyol ester claim 2 , a complex ester claim 2 , a polyol carbonate ester claim 2 , a polyvinyl ether claim 2 , a polyalkylene glycol and an alkylbenzene.4. The composition for a heat cycle system according to claim 1 , wherein the kinematic viscosity of the refrigerant oil at 40° C. is from 1 to 750 mm/s.5. The composition for a heat cycle system according to claim 1 , wherein the kinematic viscosity of the refrigerant oil at 100° C. is from 1 to 100 mm/s.6. The composition for a heat cycle system according to claim 1 , wherein a ...

TWO-CYCLE LUBRICANTS COMPRISING ESTOLIDE COMPOUNDS

Estolide compounds and compositions, including two-cycle lubricating compositions comprising at least one estolide compound. Exemplary two-cycle lubricating compositions comprise an estolide base oil and an additive package. 190-. (canceled)92. The two-cycle lubricating composition according to claim 91 , wherein the estolide base oil has a kinematic viscosity of about 4 to about 10 cSt at 100° C.93. The two-cycle lubricating composition according to claim 91 , wherein the polybutene polymer comprises a number average molecular weight of 300 to 1500.94. The two-cycle lubricating composition according to claim 91 , wherein the at least one solvent exhibits a boiling point not higher than 380° C. at atmospheric pressure.95. The two-cycle lubricating composition according to claim 91 , wherein the at least one antioxidant comprises an aminic antioxidant.96. The two-cycle lubricating composition according to claim 95 , wherein the aminic antioxidant comprises a diarylamine antioxidant.97. The two-cycle lubricating composition according to claim 91 , wherein Ris selected from Cto Calkyl.98. The two-cycle lubricating composition according to claim 91 , wherein the estolide base oil has an EN that is an integer or fraction of an integer selected from 1 to 1.5.99. The two-cycle lubricating composition according to claim 91 , wherein the estolide base oil has an EN less than or equal to 1.6.100. The two-cycle lubricating composition according to claim 91 , wherein the overbased calcium detergent exhibits a total base number of 150 to 450.102. The two-cycle lubricating composition according to claim 101 , wherein the estolide base oil has a kinematic viscosity of about 4 to about 10 cSt at 100° C.103. The two-cycle lubricating composition according to claim 102 , wherein the polybutene polymer comprises a number average molecular weight of 300 to 1500.104. The two-cycle lubricating composition according to claim 102 , wherein the at least one solvent exhibits a boiling point ...

Lubricant composition

An object of the present invention is to provide a lubricant composition having excellent lubrication properties in rigorous conditions such as a high temperature and/or a high pressure. The present invention relates to lubricant composition containing a condensate A which is obtained by condensing at least: an alkylene oxide adduct a1 of trihydric or more polyhydric alcohol formed by adding alkylene oxide to at least one hydroxyl group of the trihydric or more polyhydric alcohol; a divalent or more polyvalent carboxylic acid a2 or a precursor of the divalent or more polyvalent carboxylic acid a2; and at least one of a monovalent carboxylic acid a3, a precursor of the monovalent carboxylic acid a3, or monohydric alcohol a4.

Lubricating Base Oils from Esterified Alkoxylated Polyols Using Saturated Long-Chain Fatty Acids

The present disclosure relates to methods and compositions for making bio-based, biodegradable, and non-bioaccumulating lubricating base oils generated by esterifying alkoxylated polyols (average alkoxylation ≥3) with long-chain (≥C14) saturated and unsaturated fatty acids (FA) or fatty acids modified using industry recognized techniques. 1. A synthetic ester lubricating base oil comprising:at least one alkoxylated polyol, wherein the average degree of alkoxylation is from ≥3; andat least one fatty acid, wherein the fatty acid is substantially long-chain, equal to or greater than C14.2. The synthetic lubricating base oil ester of claim 1 , wherein the at least one alkoxylated polyol comprises glycerol claim 1 , trimethylol propane claim 1 , neopentyl glycol claim 1 , or sorbitol.3. The synthetic ester lubricating base oil of claim 1 , wherein the at least one alkoxylated polyol comprises propoxylated glycerol.4. The synthetic ester lubricating base oil of claim 1 , wherein the at least one fatty acid is substantially fully saturated.5. The synthetic ester lubricating base oil of claim 1 , wherein the at least one fatty acid is substantially unsaturated.6. The synthetic ester lubricating base oil of claim 1 , further comprising at least one additional fatty acid having a chain length of Подробнее

Food-grade-lubricant

The present invention discloses an improved food-grade-lubricant useful as hydraulic oil, circulating oil, drip oil, general purpose oil, grease base oil, cable oil, chain oil, spindle oil, gear oil, and compressor oil for equipment in the food service industry. The lubricant comprises at least one vegetable oil, at least one polyalphaolefin, and at least one antioxidant. The lubricant has improved properties when subjected to thermal and mechanical stress.

基于第尔斯‑阿尔德的交内酯和润滑剂组合物

本发明提供含有至少一种交内酯化合物和至少一种烯和/或第尔斯‑阿尔德化合物的组合物。在某些实施方案中，向含有交内酯的组合物加入至少一种烯和/或第尔斯‑阿尔德化合物可以改进组合物的低温性能、粘度和/或抗磨损性能。

Diels Alder based estolide and lubricant compositions

Provided herein are compositions containing at least one estolide compound and at least one ene and/or Diels Alder compound. In certain embodiments, the addition of at least one ene and/or Diels Alder compound to an estolide-containing composition may improve the cold temperature, viscometric, and/or anti-wear properties of the composition.

链条润滑剂组合物及其制备方法

本发明提供一种链条润滑剂组合物及其制备方法。以所述链条润滑剂组合物的总质量为100％计，包含以下组分：基础油：67‑90质量％，分散剂：3‑5质量％，润湿剂：5‑8质量％，抗磨添加剂：1‑5质量％，抗氧剂：1‑5质量％，金属钝化剂：0.5‑5质量％，金属防锈剂：0.5‑5质量％。由本发明提供的组合物具备优异的相容性，其优异的油漆相容性彻底防止汽车车身在烤漆过程中由于润滑油滴落造成的油漆缩孔或烤漆不均等危害。本发明的链条润滑剂组合物的制备方法简单易行，原料易于获取，适合大批量生产。

含复合酯的润滑剂组合物

润滑剂组合物，其具有由100℃时运动粘度损失所确定的良好剪切稳定性，其包含基础油和合成复合酯，其中所述复合酯40℃时的运动粘度大于400高至50,000mm 2 /s且可通过a)多元醇和一元羧酸和二元羧酸、或b)多元醇和一元醇和二元羧酸、或c)多元醇和一元醇以及一元羧酸和二元羧酸反应得到。此外还建议了所述包含复合酯的润滑剂组合物作为车辆齿轮油、轴用油、工业用齿轮油、压缩机油、涡轮机油或发动机油的应用。

从甘油三酯制备的交内酯衍生物

制备交内酯衍生物组合物的方法，所述方法包括：将不饱和水平小于0.1mEq/g的甘油三酯与具有2至22个碳原子的醇在能够形成包含具有残留羟基的低聚酯的产物的条件下进行反应；和将所述产物与封端剂在能够形成交内酯衍生物组合物的条件下进行反应。所述组合物可以表现出理想的低倾点、理想的粘度和热氧化稳定性、和高水平的可再生碳，使得它们适合用作生物润滑剂、工艺流体、增塑剂、或聚氨酯聚合物的起始材料。

Oil-in-oil compositions and methods of making

This invention is directed to a lubricant composition that is comprised of a continuous phase and a discontinuous phase, i.e., a two phase lubricant composition. The continuous phase and the discontinuous phase of the lubricant of this invention are oil or oil type compositions that are essentially insoluble in one another. The lubricant composition is comprised of a continuous phase base oil that is comprised of a low viscosity Group II, III, IV or GTL base stock or a blend of at l east two of the Group II, III, IV and GTL base stocks, optionally including a low viscosity Group V base stock, with the continuous phase base oil having, independently, a viscosity of from 1 to 100 cSt at 100°C. The lubricant composition is further comprised of a discontinuous phase that is comprised of an ester composition having a mean average droplet size of from 0.01 microns to 20 microns, in which the ester composition is comprised of an ester compound having no ether linkages.

A method for producing a two phase lubricant composition

This invention provides a method for producing a lubricant composition that is comprised of a continuous phase and a discontinuous phase. The method involves mixing together high viscosity ester, ether or combination thereof, and polar diluent or solvent, to produce a solution. The solution is then added to a low viscosity Group IV base oil to produce a discontinuous phase dispersed throughout a continuous phase.

High efficiency lubricating composition

The lubricating composition of this invention is primarily comprised of an admixture of an API Group V base oil component and a polvolefin base oil component. In general, the blend components include at least 45 wt. % of a Group V base oil component having a kinematic viscosity of less than 20 cSt at i00°C, and from 10 wt. % to 60 wt. % of a polvolefin base oil component having a kinematic viscosity of at least 500 cSt and not greater than 4000 cSt at 100°C. The lubricating composition has improved efficiency and lower operating temperatures, comparable to polyalkylene glycol-based lubricant level, which provides improved machine life and seal life, relative to other lubricating compositions.

High efficiency lubricating composition

The lubricating composition of this invention is primarily comprised of an admixture of an API Group V base oil component and a polyolefin base oil component. In general, the blend components include at least 45 wt. % of a Group V base oil component having a kinematic viscosity of less than 20 cSt at 100° C., and from 10 wt. % to 60 wt. % of a polyolefin base oil component having a kinematic viscosity of at least 500 cSt and not greater than 4000 cSt at 100° C. The lubricating composition has improved efficiency and lower operating temperatures, comparable to polyalkylene glycol-based lubricant level, which provides improved machine life and seal life, relative to other lubricating compositions.

Oil-in-oil compositions and methods of making

This invention is directed to a lubricant composition that is comprised of a continuous phase and a discontinuous phase, i.e., a two phase lubricant composition. The continuous phase and the discontinuous phase of the lubricant of this invention are oil or oil type compositions that are essentially insoluble in one another. The lubricant composition is comprised of a continuous phase base oil that is comprised of a low viscosity Group II, III, IV or GTL base stock or a blend of at least two of the Group II, III, IV and GTL base stocks, optionally including a low viscosity Group V base stock, with the continuous phase base oil having, independently, a viscosity of from 1 to 100 cSt at 100° C. The lubricant composition is further comprised of a discontinuous phase that is comprised of an ester composition having a mean average droplet size of from 0.01 microns to 20 microns, in which the ester composition is comprised of an ester compound having no ether linkages.

Polyol ester compositions with unconverted hydroxyl groups

A synthetic ester composition which exhibits thermal and oxidative stability, lower friction coefficient and lower wear, wherein the ester composition comprises the reaction product of a branched or linear alcohol having the general formula R(OH)n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched mono-carboxylic acid which has a carbon number in the range between about C5 to C13; wherein the synthetic ester composition has between about 5-35 % unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol.

Liquid compositions containing carboxylic esters

본 발명은 (A) 1-3의 탄소 원자를 함유하는 적어도 하나의 플루오르-함유 탄화수소 ; 및 (B) (I) 폴리히드록시 화합물 및 (II) (a) 4 또는 5 탄소 원자를 가지는 모노카르복실 산 아실화제, (b) 약 7-약 15 탄소 원자를 가지는 모노카르복실 산 아실화제, 및 (c) 폴리카르복실 산 아실화제의 조합물의 적어도 하나의 카르복실 산 에스테르로 구성되는 윤활제로 구성되는 액체 조성물에 관한 것이다. 본 발명의 다른 면에서, 액체 조성물은 본질적으로 (A) 적어도 하나의 플루오르-함유 탄화수소, 및 (B) (I) 여기 서술된 적어도 하나의 폴리히드록시 화합물 및 (II) 여기 서술된 바와같이 카르복실 산 아실화제의 적어도 하나의 조합물의 적어도 하나의 에스테르로 구성된다. 윤활제는 부가적으로 (c) 알킬 포스파이트, 알킬 인산 에스테르, 질소-함유 헤테로사이클, 및 그의 혼합물로 구성되는 군으로부터 선택되는 부가물을 함유할 수 있다. 또한 플푸오르 함유 탄화수소가 또한 염소같은 다른 할로겐을 함유하는 액체 조성물이 서술된다. 액체 조성물은 냉동기 및 자동차용, 가정용, 및 산업용 공기조화기를 포함하는 공기조화기에서 냉동액으로서 특히 유용하다. The present invention provides a composition comprising (A) at least one fluorine-containing hydrocarbon containing a carbon atom of 1-3; And (B) (I) a polyhydroxy compound and (II) (a) a monocarboxylic acid acylating agent having 4 or 5 carbon atoms, (b) a monocarboxylic acid acylating agent having about 7 to about 15 carbon atoms And (c) a lubricant consisting of at least one carboxylic acid ester of a combination of polycarboxylic acid acylating agents. In another aspect of the invention, the liquid composition consists essentially of (A) at least one fluorine-containing hydrocarbon, and (B) (I) at least one polyhydroxy compound described herein, and (II) a carbon as described herein. At least one ester of at least one combination of carboxylic acid acylating agents. The lubricant may additionally contain an adduct selected from the group consisting of (c) alkyl phosphites, alkyl phosphate esters, nitrogen-containing heterocycles, and mixtures thereof. Also described are liquid compositions in which the flufurur containing hydrocarbons also contain other halogens such as chlorine. Liquid compositions are particularly useful as freezing liquids in refrigerators and air conditioners, including automotive, domestic, and industrial air conditioners.

含羧酸酯的液体组合物

本发明涉及包含以下成分的液体组合物：(A)至 少一种含1至3个碳原子的含氟烃和由(B)构成的 润滑剂，(B)为(I)多羟基化合物与(II)所生成的至 少一种羧酸酯，(II)为(1)含4或5个碳原子的单羧 酸酰化剂，(2)含约7至约15个碳原子的单羧酸酰化 剂与(3)多羧酸酰化剂的组合。

Lubricating grease compositions

Lubricant compounds containing complex esters

Proposed are lubricant compounds with a good shear stability defined by the loss of the kinematic viscosity at 100 °C, containing base oil and a synthetic complex ester, the complex ester having a kinematic viscosity at 40°C of greater than 400 and up to 50,000 mm2/s and being obtained by conversion of a) polyols and monocarbonic acids and dicarbonic acids, or of b) polyols and mono-alcohols and dicarbonic acids, or of c) polyols and mono-alcohols and monocarbonic acids and dicarbonic acids. In addition the use of the said lubricant compounds containing the complex esters as oils for vehicle transmission, axles, industrial drives, compressors, turbines or engines is proposed.

Esters for use as a base stock and in lubricant applications

This invention relates to base ester compounds and complex ester compounds that can be used as a base stock for lubricant applications or a base stock blend component for use in a finished lubricant or for particular applications, and methods of making the same. The base ester compounds and complex esters described herein comprise dimer and/or trimer esters, and their respective branched derivatives.

The preparation of biopolyol esters for lubricant application

ALCOHOL-ESTER COMPLEXES, LUBRICANT THAT UNDERSTANDS IT AND PROCEDURE TO PRODUCE IT

Un complejo alcohol-éster, un lubricante que lo comprende y un procedimiento para producirlo. El complejo alcohol-éster comprende elproducto de reaccion de una mezcla de adicion que tiene lo siguiente: un compuesto polihidroxilor epresentando por la formula general: R(OH(n, donde Res cualquier grupo hidrocarbilo alifático o ciclo-alifático y n es por lo menos 2, con la condicion de que el grupo hidrocarbilo contenga deaproximadamente 2 a 20 átomos de carbono; unácido o anhídrido polibásico de un ácido polibásico, con la condicion de que la relacion de equivalentes delácido polibásico a equivalentes de alcohol del compuesto polihidroxilo está en el rango de entre aproximadamente 1,6:1 a 2:1; y unalcohol monohí drico conla condicion de que la relacion de equivalentes del alcohol monohídrico a equivalentes del ácido polibásico esté en el rango de entre aproximadamente0,84:1 a 1,2:1; donde el complejo alcohol éster exhiba un punto de escurr imiento de menos de o igual a -20°C, una viscosidad en el rango de entreaproximadamente 100-700 cSt a 40°C y tiene una concentracion de éster de ácido polibásico de menos de o igual a 70% en peso, basada en el complejoalcohol-éster. An alcohol-ester complex, a lubricant comprising it and a process to produce it. The alcohol-ester complex comprises the reaction product of an addition mixture having the following: a polyhydroxyl compound representing by the general formula: R (OH (n, where Res any aliphatic or cycloaliphatic hydrocarbyl group and n is at least 2 , with the proviso that the hydrocarbyl group contains approximately 2 to 20 carbon atoms; a polybasic acid or anhydride of a polybasic acid, with the proviso that the ratio of equivalents of the polybasic acid to alcohol equivalents of the polyhydroxyl compound is in the range of between about 1.6: 1 to 2: 1, and a monohydric alcohol provided that the ratio of equivalents of monohydric alcohol to equivalents of polybasic acid is in the range of between about 0.84: 1 to 1.2: 1; ...

Release agent composition and die casting method

Polyol ester compositions with unconverted hydroxyl groups

A synthetic ester composition exhibiting thermal and oxidative stability which comprises the reaction product of: a branched or linear alcohol having the general formula K(OH) n , wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched mono-carboxylic acid which has a carbon number in the range between about C 5 to C 13 ; wherein the synthetic ester composition has between 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol.

Release agent composition and die casting method

離型剤組成物に高分子エステルを含有させることにより、型温度が上昇した際においても、良好な離型性を発揮できる離型剤組成物、および、該組成物を用いたダイカスト方法を提供する。 Disclosed is a release agent composition which contains a polymer ester in the release agent composition and can exhibit good release properties even when the mold temperature rises, and a die casting method using the composition. To do.

Lubricant base oil, refrigerator oil and working fluid composition for refrigerators

본 발명의 윤활유 기유는, 2 내지 4개의 하이드록실기를 갖는 다가 알코올로부터 선택되는 적어도 1종인 제1 성분과, 탄소수 6 내지 12의 다염기산으로부터 선택되는 적어도 1종인 제2 성분과, 탄소수 4 내지 18의 1가 알코올 및 탄소수 2 내지 12의 1가 지방산으로부터 선택되는 적어도 1종인 제3 성분으로부터 합성되는 에스테르를 함유한다. 또한, 본 발명의 냉동기유 및 냉동기용 작동 유체 조성물은, 상기의 윤활유 기유를 함유한다.

Blended polyol ester lubricants for refrigerant heat transfer fluids

본 발명은 네오펜틸글리콜 및 이것의 반응성 성분으로서 2-에틸헥산산의 공급원을 갖는 에스테르, 및 펜타에리트리톨 및 이것의 반응성 성분으로서 2-에틸헥산산의 공급원을 갖는 에스테르를 포함하며, 염소 비함유 플루오로카아본 냉매 열전달 유체, 특히 냉매 134a(1,1,1,2-테트라플루오로에탄)용 윤활제로서 특히 효과적인 에스테르 배합물에 관한 것이다. The present invention includes neopentyl glycol and esters having a source of 2-ethylhexanoic acid as the reactive component thereof, and pentaerythritol and esters having a source of 2-ethylhexanoic acid as the reactive component thereof, and are free of chlorine. A fluorocarbon refrigerant refrigerant heat transfer fluid, particularly an ester formulation particularly effective as a lubricant for refrigerant 134a (1,1,1,2-tetrafluoroethane).

Esters for use as a base stock and in lubricant applications

本发明涉及基础酯类化合物和复合酯类化合物及其制备方法，该基础酯类化合物和复合酯类化合物可用作润滑剂基础油，或作为成品润滑剂中的基础油调和组分，或用于特殊用途。本申请所述的基础酯类化合物和复合酯包括二聚酯和/或三聚酯，以及它们的分枝状衍生物。

Preparation of biopolyol esters for lubricant applications

本发明涉及用于润滑剂应用的生物多元醇酯的制备。酯多元醇酯是一类独特的润滑剂，其具有可根据其反应材料和相对比例的特点而调节的分子量、粘度和倾点。本发明提供制备至少一种酯多元醇酯的方法，该方法包括，制备包含至少一种多元醇化合物、至少一种二羧酸和至少一种单羧酸的反应混合物，其中所述至少一种多元醇化合物用所述至少一种二羧酸和所述至少一种单羧酸酯化，其中所述反应混合物的羟基对羧基比(HCR)对应于羟基的摩尔数对羧基的摩尔数之比，并且HCR小于约1。

New ester compounds, process for their preparation and their use

Die Erfindung betrifft neue Esterverbindungen der allgemeinen Formel (I)ein Verfahren zu ihrer Herstellung sowie ihre Verwendung. Diese Esterverbindungen können ein Gemisch aus mindestens zwei Verbindungen, der allgemeinen Formel (I) enthalten. The invention relates to new ester compounds of general formula (I) a process for their preparation and their use. These ester compounds may contain a mixture of at least two compounds of the general formula (I).

Working fluid composition for refrigerating machine and refrigerator oil

本发明提供一种冷冻机用工作流体组合物，其含有：冷冻机油，其含有混合酯作为基础油，所述混合酯是将(A)由新戊二醇等多元醇、碳数6～12的多元酸、和碳数4～18的一元醇等合成的复合酯、以及(B)由新戊二醇等多元醇和碳数4～18的一元脂肪酸合成的多元醇酯以(A)复合酯/(B)多元醇酯的质量比5/95～95/5进行混合而得到的；和，二氧化碳等制冷剂。

Working fluid composition for refrigerator, refrigerator oil and method for producing the same

Refrigeration oil, application thereof and compressor

本发明提供一种冷冻油、该冷冻油的应用以及一种压缩机，其中，所述冷冻油的基础油为多元醇酯，所述多元醇酯由选自二元醇、三元醇或四元醇的多元醇与由戊酸、庚酸和己酸组成的混合脂肪酸反应得到。可以实现冷冻油和常见制冷剂，例如R410A或R32等在低温下能够很好的相容，可以有效改善低温下压缩机的可靠性，且空调系统无需采用电阻丝等对油池辅助加热的部件，降低空调系统功耗，提高系统能效。

Low viscosity, good fuel combustion polyol ester base cooling agent containing polyether and antioxidant with or without phosphate ester

(57)【要約】 （修正有） 【課題】 優れた潤滑剤および冷却剤相溶性を表わし、 良好な耐摩耗性能を示す潤滑剤／冷却剤潤滑剤組成物を 提供すること。 【解決手段】 （Ａ）約１０重量％〜約９０重量％の１ 個または２個の炭素原子を含有する少なくとも１種のフ ッ素含有炭化水素；および以下（Ｂ）、（Ｃ）を含有す る効果的な量の少なくとも１種の混和性有機潤滑剤を含 有する液状冷却組成物、（Ｂ）約５重量％〜約９０重量 ％のカルボン酸および多価ヒドロキシ化合物の少なくと も１種のエステル：（Ｃ）約０．１重量％〜約５重量％ の以下（１）、（２）を含有する性能添加剤：（１）ア ルコキシル化アルコールまたはフェノール：または （２）アルコキシル化グリコール：

Grease lubricant composition

FIELD: chemistry. SUBSTANCE: described is a grease lubricant which contains a base oil mixture which is based on oils with viscosity which is common for industrial lubricant materials (from ISO VG 2 to ISO VG 1500), an ionic liquid, a thickener selected from a group consisting of a urea thickener as well as common additives. The grease lubricant can be used at common operating temperatures from higher than 120°C to 260°C, especially at high operating temperatures from higher than 180°C to 260°C, and at low temperatures of up to -60°C. The invention also relates to a method of preparing similar grease lubricant compositions. EFFECT: longer service life of the grease lubricant, negligible wearing of antifriction bearings, high oil separation. 10 cl, 13 tbl, 6 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 480 516 (13) C2 (51) МПК C10M C10M C10M C10M C10M 169/06 133/38 115/08 117/00 137/04 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2010101286/04, 20.05.2008 (24) Дата начала отсчета срока действия патента: 20.05.2008 (73) Патентообладатель(и): КЛЮБЕР ЛУБРИКАЦИОН МЮНХЕН КГ (DE) (43) Дата публикации заявки: 27.07.2011 Бюл. № 21 2 4 8 0 5 1 6 (45) Опубликовано: 27.04.2013 Бюл. № 12 (56) Список документов, цитированных в отчете о поиске: WO 2006109652 A1, 19.10.2006. EP 1867706 A1, 19.12.2007. US 3243372 A, 29.03.1966. US 5670461 A, 23.09.1997. US 3376223 A, 02.04.1968. 2 4 8 0 5 1 6 R U (86) Заявка PCT: EP 2008/004035 (20.05.2008) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 20.01.2010 (87) Публикация заявки РСТ: WO 2008/154997 (24.12.2008) Адрес для переписки: 105082, Москва, Спартаковский пер., 2, стр.1, секция 1, этаж 3, "ЕВРОМАРКПАТ" (54) КОМПОЗИЦИЯ КОНСИСТЕНТНОЙ СМАЗКИ (57) Реферат: Изобретение относится к композиции консистентной смазки. Описана консистентная смазка, которая включает базовую масляную смесь на основе масел с обычной для ...

Lubricating grease composition

본 발명은 산업용 윤활유 표준점도(ISO VG 2 내지 ISO VG 1500)를 갖는 기름 성분의 베이스 오일 혼합물, 이온성 액상물, 폴리우레아계 화합물과 같은 증점제 및 일반적인 첨가제를 포함하는, -60 ℃의 낮은 온도에서 뿐만 아니라, 120 내지 260 ℃에서도 정상적으로 기능할 수 있는 윤활용 그리스(grease) 조성물에 관한 것이다. 본 발명은 또한 상기 윤활용 그리스 조성물을 제조하는 방법에 관한 것이다.

Fluid composition for cutting or grinding system employing trace amount of fluid

극미량의 오일을 공기와 함께 절삭 또는 연삭 지점에 공급하는 절삭 또는 연삭 시스템에 유용한 오일 조성물에 있어서, 조성물은 베이스 오일로서 에스테르, 특히 특정 성질을 가진 에스테르를 포함함을 특징으로 함. 오일은 윤활성과 점착면에서 뚜렷히 향상됨.

Working fluid composition for refrigerating machine and refrigerating machine oil

본 발명은 (A) 네오펜틸글리콜 등의 다가 알코올과, 탄소수 6 내지 12의 다염기산과, 탄소수 4 내지 18의 1가 알코올 등으로 합성되는 콤플렉스 에스테르, 및, (B) 네오펜틸글리콜 등의 다가 알코올과, 탄소수 4 내지 18의 1가 지방산으로 합성되는 폴리올에스테르를, (A) 콤플렉스 에스테르/(B) 폴리올에스테르의 질량비 5/95 내지 95/5로 혼합한 혼합 에스테르를 기유로서 함유하는 냉동기유와, 이산화탄소 등의 냉매를 함유하는 냉동기용 작동 유체 조성물을 제공한다. The present invention relates to (A) a complex ester synthesized from a polyhydric alcohol such as neopentyl glycol, a polybasic acid having 6 to 12 carbon atoms, a monohydric alcohol having 4 to 18 carbon atoms, and the like, and (B) a polyhydric alcohol such as neopentyl glycol And a polyol ester synthesized from a monohydric aliphatic acid having 4 to 18 carbon atoms in a ratio of (A) a complex ester / (B) polyol ester in a mass ratio of 5/95 to 95/5 as a base oil, , And a refrigerant such as carbon dioxide.

Estolide and lubricant compositions based on Diels Alder

本发明提供含有至少一种交内酯化合物和至少一种烯和/或第尔斯‑阿尔德化合物的组合物。在某些实施方案中，向含有交内酯的组合物加入至少一种烯和/或第尔斯‑阿尔德化合物可以改进组合物的低温性能、粘度和/或抗磨损性能。

Refrigerator oil composition

본 발명은 윤활성이 우수하고, 특히 알루미늄 물질과 강철 물질 사이의 윤활성을 향상시켜, 타서 눌러 붙거나 마모되는 것을 방지할 수 있고, 환경 오염을 유발하지 않는 1,1,1,2-테트라플루오로에탄 등의 수소 함유 플론 냉매를 사용한 냉동기의 윤활유로서 적합한 냉동기 오일 조성물에 관한 것이다. 상기 조성물은 광유 또는 합성유로 이루어진 기제 오일에 1종 이상의 폴리옥시에틸렌계 비이온성 계면활성제를 배합하여 이루어진다. 이러한 비이온성 계면활성제로서는 바람직하게는 옥시에틸렌기의 부가 몰수가 1 내지 40이거나, 친수-친유성 밸런스(HLB, hydrophile-lipophile balance) 값이 2 내지 30인 것을 사용한다. 비이온성 계면활성제의 종류로는 폴리옥시에틸렌 알킬에테르, 폴리옥시에틸렌 알케닐에테르, 폴리옥시에틸렌 아릴에테르, 폴리옥시에틸렌 지방산 에스테르, 폴리옥시에틸렌 소르비탄 지방족 에스테르, 폴리옥시에틸렌 소르비톨 지방산 에스테르 등이 있다.

High-temperature lubricant for use in the food industry.

La invención es concerniente con un lubricante de alta temperatura de grado alimenticio, más en particular un aceite de alta temperatura y una grasa de alta temperatura, que comprende los siguientes componentes: a) por lo menos un aceite seleccionado de un éster trimelítico o una mezcla de diferentes ésteres trimelíticos, alquilaromáticos, preferiblemente un naftaleno alifáticamente sustituido, o estólidos; b) un poliisobutileno hidrogenado o completamente hidrogenado o una mezcla de poliisobutileno hidrogenado o totalmente hidrogenado y c) aditivos individualmente o en combinación. En el caso de la grasa de alta temperatura, se agrega un espesante.

Esters for use as a base stock and in lubricant applications

本发明涉及基础酯类化合物和复合酯类化合物及其制备方法，该基础酯类化合物和复合酯类化合物可用作润滑剂基础油，或作为成品润滑剂中的基础油调和组分，或用于特殊用途。本申请所述的基础酯类化合物和复合酯包括二聚酯和/或三聚酯，以及它们的分枝状衍生物。

There is the estolide composition of high oxidation stability

本文提供具有高氧化稳定性的交内酯组合物，所述组合物包含至少一种下式(I)化合物，其中n为等于或大于0的整数；m为等于或大于1的整数；R 1 每次出现时独立地选自饱和或不饱和且支化或非支化的任选取代烃基；R 2 选自氢和饱和或不饱和且支化或非支化的任选取代烃基；且R 3 和R 4 每次出现时独立地选自饱和或不饱和且支化或非支化的任选取代烃基。本文还提供该组合物的用途及其制备方法。

Dielectric fluids comprising estolide compounds and methods of making and using the same

Provided herein are dielectric fluids comprising at least one estolide compound of formula (II); in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses of dielectric fluids and electrical devices such as transformers that comprise a dielectric fluid comprising at least one estolide compound.

The preparation of biopolyol esters for lubricant application

Ester polyol esters are a unique class of lubricants that have adjustable molecular weights, viscosities, and pour points based on the character of their reaction materials and relative ratios. There is provided a method for preparing at least one ester polyol ester, the method comprising the method comprising preparing a reaction mixture comprising at least one polyol compound; at least one dicarboxylic acid; and at least one monocarboxylic acid, wherein the at least one polyol compound is esterified with the at least one dicarboxylic acid and the at least one monocarboxylic acid, wherein the reaction mixture has a hydroxyl group to carboxyl group ratio (HCR) corresponding to a ratio of moles of hydroxyl groups to moles of carboxyl groups, and the HCR is less than about 1.

alde diol based solid and lubricant compositions

resumo patente de invenção: "estolida à base de diels alder e composições lubrificantes". a invenção refere-se a composições contendo pelo menos um composto tipo estolida e pelo menos um composto eno e/ou de diels alder. em certas modalidades, a adição de pelo menos um composto eno e/ou de diels alder a uma composição contendo estolida pode aperfeiçoar as propriedades à baixa temperatura, viscosimétricas, e/ou antidesgaste da composição. patent summary: "diels alder-based solidified and lubricating compositions". The invention relates to compositions containing at least one solid type compound and at least one ene and / or diels alder compound. In certain embodiments, the addition of at least one non-and / or diels alder compound to a solid-containing composition may enhance the low temperature, viscosimetric, and / or anti-wear properties of the composition.

Patent FR2579986A1

HUILE DE LAMINAGE A FROID POUR ACIERS CARACTERISEE PAR LE FAIT QU'ELLE COMPREND A 40 A 90 EN POIDS D'UN MONOESTER D'UN ACIDE CARBOXYLIQUE ALIPHATIQUE AYANT 12 A 22 ATOMES DE CARBONE ET D'UN ALCOOL ALIPHATIQUE AYANT 1 A 12 ATOMES DE CARBONE, B 0,5 A 10 EN POIDS D'AU MOINS UN COMPOSE CHOISI PARMI UN ACIDE DIMERE ET UN ACIDE POLYMERISE DERIVE D'UN ACIDE INSATURE ALIPHATIQUE SUPERIEUR AYANT 16 A 20 ATOMES DE CARBONE, C 2 A 40 EN POIDS D'UN POLYESTER AYANT UN POIDS MOLECULAIRE DE 750 A 7500 ET OBTENU EN SOUMETTANT AU MOINS UN COMPOSE CHOISI PARMI UN ACIDE DIMERE ET UN ACIDE POLYMERISE DERIVE D'UN ACIDE INSATURE ALIPHATIQUE SUPERIEUR AYANT 16 A 20 ATOMES DE CARBONE A UNE CONDENSATION AVEC UN POLYOL DANS DES CONDITIONS DE CHAUFFAGE ET EN FAISANT REAGIR LES GROUPES CARBOXYLE OU LES GROUPES HYDROXYLE RESTANTS DU POLYESTER RESULTANT AVEC UN ALCOOL AYANT 1 A 22 ATOMES DE CARBONE OU UN ACIDE ALIPHATIQUE AYANT 12 A 22 ATOMES DE CARBONE, OU 10 A 25 EN POIDS D'UNE GRAISSE OU D'UNE HUILE GRASSE, ET D 0,1 A 10 EN POIDS D'UN COMPOSE POLYMERE AYANT DES ATOMES D'AZOTE DANS UNE MOLECULE AYANT UN POIDS MOLECULAIRE DE 1000 A 1000000. COLD ROLLING OIL FOR STEELS CHARACTERIZED IN THAT IT COMPRISES 40 TO 90 BY WEIGHT OF A MONOESTER OF AN ALIPHATIC CARBOXYLIC ACID HAVING 12 TO 22 CARBON ATOMS AND OF AN ALIPHATIC ALCOHOL HAVING 1 TO 12 ATOMS CARBON, B 0.5 TO 10 BY WEIGHT OF AT LEAST ONE SELECTED COMPOUND AMONG A DIMERED ACID AND A POLYMERIZED ACID DERIVED FROM A SUPERIOR ALIPHATIC UNSATURATED ACID HAVING 16 TO 20 CARBON ATOMS, C 2 TO 40 BY WEIGHT POLYESTER HAVING A MOLECULAR WEIGHT OF 750 TO 7500 AND OBTAINED BY SUBMITTING AT LEAST ONE SELECTED COMPOUND AMONG DIMER ACID AND A POLYMERIZED ACID DERIVED FROM A HIGHER ALIPHATIC UNSATURATED ACID HAVING 16 TO 20 CARBON ATOMS IN CONDENSATION WITH POLYOLS HEATING AND REACTING CARBOXYL GROUPS OR REMAINING HYDROXYL GROUPS OF THE POLYESTER RESULTING WITH AN ALCOHOL HAVING 1 TO 22 CARBON ATOMS OR AN ...

Oils thickened with estolides of hydroxy-containing triglycerides

A thickened composition is disclosed which comprises (A) at least one triglyceride estolide of the formula <IMAGE> wherein R1 is an aliphatic group or an aliphatic group containing an ester moiety R2COO- with the proviso that at least one R1 is an aliphatic group containing the ester moiety, and contains from about 5 to about 23 carbon atoms, and R2 is a hydrocarbyl group containing from 1 to 100 carbon atoms and (B) at least one oil comprising (1) a synthetic ester base oil (2) a mineral oil, or (3) a polyalphaolefin.

Working fluid composition for refrigerator

Compositions comprising estolide compounds and methods of making and using the same

Provided herein are compositions comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R 1 , independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R 2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R 3 and R 4 , independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.

Use of a lubricant for compressors using a hydrofluorocarbon refrigerant containing no chlorine.

Food grade lubricant

The present invention discloses an improved food-grade-lubricant useful as hydraulic oil, circulating oil, drip oil, general purpose oil, grease base oil, cable oil, chain oil, spindle oil, gear oil, and compressor oil for equipment in the food service industry. The lubricant comprises at least one vegetable oil, at least one polyalphaolefin, and at least one antioxidant. The lubricant has improved properties when subjected to thermal and mechanical stress.

Biodegradable non-toxic gear oil

A biodegradable lubricating oil composition especially useful as a gear oil employs a synthetic alcohol ester basestock formed from mono- and dipentaerythritol with certain mono- and dicarboxylic acids or dicarboxylic acid anhydrides and an effective amount of a polyoxyalkylene alcohol demulsifying agent, a combination of alkylated organic acid and ashless succinimide rust inhibitors and an ashless dithiocarbamate antiwear and extreme pressure agent.

Phosphorus-containing compositions for refrigeration systems

This invention relates to a composition comprising: (A) a major amount of a fluorine-containing hydrocarbon containing one or two carbon atoms; and (B) a minor amount of a phosphorus-containing composition comprising at least one compound characterized by formula (1) or (2) wherein R1 and R2 are each independently hydrocarbyl groups or hydrocarbyloxyalkylene groups and R1 and R2 taken together have a total of 2 to about 24 carbon atoms excluding any oxyalkylene carbon atom; a is 0 or 1; b is 1 or 2; c is 1, 2 or 3; d is 0, 1 or 2, provided that c+d=3; if b is 1, Z is selected from the group consisting of -R5, -XR5, -N(H)R5, -N(R5)2, -C(X)R5, -CN, -S(O)R5, -S(O)2R5, -S(O)2N(R3)(R4) and (α); if b is 2, Z is -N(R5)-, X is oxygen or sulfur; Y is a hydrocarbylene group having 1 to about 20 carbon atoms; R5 is a hydrocarbyl group having 1 to about 18 carbon atoms; R3 and R4 are each independently hydrogen; or a hydrocarbyl group having 1 to about 24 carbon atoms; or R3 and R4 taken together form a heterocyclic ring. The present invention provides compositions which are useful as refrigeration liquids in refrigerators and air-conditioners including auto, home and industrial air-conditioners. The invention provides phosphorus-containing compositions which are compatible with fluorine-containing hydrocarbons used in refrigerators and air-conditioners. The phosphorus-containing compositions act as a lubricant additive for air-conditioners.

Refrigerator oil and working fluid composition for refrigerator

本发明的一个方式为一种冷冻机油，其含有基础油、二硫代磷酸酯和膦酸酯。

Polyol ester lubricants for hermetically sealed refrigerating compressors

A high quality lubricant for hermetically sealed domestic air conditioner and refrigerator compressors, especially those us-ing chlorine free hydrofluorocarbon refrigerant working fluids, is provided by mixed esters of hindered polyols, most desirably pentaerythritol, with a mixture of carboxylic acids including at least some isopentanoic acid along with either or both of iso-nona-noic acid and dibasic acids such as adipic.

Cooling oils for use with hydrogen-containing halogen carbon refrigerants

Plasticized compositions containing estolide compounds

Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; m is an integer equal to or greater than 1; R 2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R 1 , R 3 , and R 4 , independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein at least one of R 1 , R 2 , R 3 , or R 4 is sulfurized or epoxidized. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Oil for cutting and grinding by ultra low volume oil feed system and for sliding surface and method for cutting and grinding by ultra low volume feed system using the oil

An oil for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester, and is used as a lubricating oil for cutting and grinding suitable for a cutting and grinding method by minimal quantity lubrication system, and also used as a lubricating oil for sliding surface.

Refrigerator oil composition

본 발명은 냉동기유 조성물에 관한 것이며, 더 구체적으로는 냉매로서 하이드로플루오로카본계, 플루오로카본계, 하이드로카본계, 에테르계, 이산화탄소계 또는 암모니아계 화합물, 바람직하게는 환경 오염에서 문제가 되고 있는 냉매인 클로로플루오로카본의 대체물이 될 수 있는 하이드로플루오로카본계 화합물을 사용한 경우, 우수한 윤활성능을 가지며, 특히 알루미늄 강철재와의 사이의 윤활성을 향상시켜 마모를 억제할 수 있고, 또한 모세관이 폐색되기 어려운 냉동기유 조성물에 관한 것이다. The present invention relates to a refrigeration oil composition, and more particularly to a hydrofluorocarbon-based, fluorocarbon-based, hydrocarbon-based, ether-based, carbon dioxide-based or ammonia-based compound, preferably environmental pollution as a refrigerant In the case of using a hydrofluorocarbon-based compound which can be a substitute for chlorofluorocarbon, which is a refrigerant, it has excellent lubricating performance, and in particular, it can improve the lubrication between aluminum steel and suppress wear, and also the capillary tube It is related with the refrigeration oil composition which is hard to occlude.

Estolide base oils and oligomeric compounds that include cross metathesis

Provided herein are compounds according to Formula III: wherein n is an integer selected from 1 to 50; R 1 is an unsubstituted, branched or unbranched alkyl that is saturated or unsaturated; R 2 is a branched or unbranched C 1 to C 20 alkyl that is saturated or unsaturated; and R 3 and R 4 , independently for each occurrence, are selected from wherein R 3 and R 4 are unsubstituted and z is, independently for each occurrence, an integer selected from 2 to 15.

Compressor for refrigeration and air-conditioning, and refrigerating and air-conditioning apparatus

The purpose of the present invention is to improve the abrasion resistance of a compressor for refrigeration and air-conditioning which utilizes difluoromethane (HFC32) as a cooling medium to thereby improve the long-term reliability of the compressor, and to improve the efficiency of a refrigerating and air-conditioning cycle of a refrigerating and air-conditioning apparatus by the use of the compressor. A compressor (100) is equipped with a cooling medium compression section having a sliding member, and has difluoromethane that acts as a cooling medium and a refrigerating machine oil both enclosed therein, wherein the refrigerating machine oil to be used has a kinematic viscosity of 30-100 mm 2 /s at 40˚C and a lower-temperature-side critical solution temperature between the cooling medium and the refrigerating machine oil is +10˚C or lower.

Grease composition

Refrigeration oil composition containing a fluoroethane and an ester compound

The refrigeration oil composition comprises (1) a hydrogenated fluoroethane and (2) an ester compound obtained from (2-a) an aliphatic polyhydric alcohol having 1 to 6 primary hydroxyl groups, (2-b) a saturated aliphatic monocarboxylic acid having 2 to 9 carbon atoms, straight or branched, or a derivative thereof and (2-c) a saturated aliphatic dicarboxylic acid having 2 to 10 carbon atoms, straight or branched, or a derivative thereof, said ester compound having a kinematic viscosity at 100 degree C. of 1 to 100 cst.

Production method for composite polyester composition, composite polyester composition, lubricant composition, and lubricant

　本発明は、優れた潤滑性能を有する潤滑剤を提供することを課題とする。さらに、本発明は、環境への負荷が少なく、量産適性があるポリエステル組成物を製造することも課題とする。　本発明は、多価アルコールと、炭素数が５以上であり少なくとも２つのカルボキシル基を含む多価カルボン酸と、少なくとも１つのオキシアルキレン基を有する１価アルコールとを無溶媒で縮合させ複合ポリエステル組成物を得る工程を含み、複合ポリエステル組成物のＧＰＣチャートの重量平均分子量が１３００以下の成分は４３面積％以下となる複合ポリエステル組成物の製造方法に関する。さらに、本発明は、複合ポリエステル組成物、潤滑剤組成物及び潤滑剤に関する。

Phosphorus-containing compositions for refrigeration systems

This invention relates to a composition comprising: (A) a major amount of a fluorine-containing hydrocarbon containing one or two carbon atoms; and (B) a minor amount of a phosphorus-containing composition comprising at least one compound characterized by formula (1) or (2) wherein R1 and R2 are each independently hydrocarbyl groups or hydrocarbyloxyalkylene groups and R1 and R2 taken together have a total of 2 to about 24 carbon atoms excluding any oxyalkylene carbon atom; a is 0 or 1; b is 1 or 2; c is 1, 2 or 3; d is 0, 1 or 2, provided that c+d=3; if b is 1, Z is selected from the group consisting of -R5, -XR5, -N(H)R5, -N(R5)2, -C(X)R5, -CN, -S(O)R5, -S(O)2R5, -S(O)2N(R3)(R4) and (.alpha.); if b is 2, Z is -N(R5)-, X is oxygen or sulfur; Y is a hydrocarbylene group having 1 to about 20 carbon atoms; R5 is a hydrocarbyl group having 1 to about 18 carbon atoms; R3 and R4 are each independently hydrogen; or a hydrocarbyl group having 1 to about 24 carbon atoms; or R3 and R4 taken together form a heterocyclic ring. The present invention provides compositions which are useful as refrigeration liquids in refrigerators and air-conditioners including auto, home and industrial air-conditioners. The invention provides phosphorus-containing compositions which are compatible with fluorine-containing hydrocarbons used in refrigerators and air-conditioners. The phosphorus-containing compositions act as a lubricant additive for air-conditioners.

Lubricating oil for refrigerator and refrigerator fluid composition for refrigerator using the same

The present invention proposes a lubricating oil for refrigerators comprising, as the base oil, a polyvinyl ether derivative and a polycarbonate-based oxygenated compound. The lubricating oil exhibits excellent miscibility with a refrigerant having one carbon atom and no chlorine atoms and, in particular, with difluoromethane and provides a hydraulic fluid composition exhibiting excellent antiwear, lubricity and stability.

Lubricating grease compositions

The invention relates to lubricating grease compositions which consist of (a) an oil based on hydrocarbons; (b) a perfluorinated polyalkyl ether oil of the general formula A' - (O-CF2)v-(O-C2F4)w-(O-C3F6)x-(O-C4F8)y-(O-CF2CF(CF3))z-O-A'', in which A' is equivalent to -CF3, -C2F5, -C3F7, -CF2T, T being H or Cl, and v, w, x, y and z are integers ≥ 0; (c) a diurea as the thickening agent; (d) conventional additives; and (e) organic and inorganic solid lubricating grease compositions. The invention also relates to a process for preparing said lubricating grease compositions.

METHOD FOR THE MANUFACTURE OF ESTOLIDES AND COMPOSITION OF ESTOLIDES

L’invention concerne un procédé de préparation d’une composition d’estolides comprenant la réaction d’un composé insaturé de type acide ou ester avec un acide gras saturé, en présence d’un catalyseur de type acide sulphonique, ledit procédé ne comprenant pas d’étape de distillation sous vide permettant de séparer les monoestolides des polyestolides. L’invention concerne également une composition d’estolides susceptible d’être obtenue par le procédé de l’invention et son utilisation dans des compositions lubrifiantes. The invention relates to a process for the preparation of a composition of estolides comprising the reaction of an unsaturated compound of the acid or ester type with a saturated fatty acid, in the presence of a catalyst of the sulphonic acid type, said process not comprising vacuum distillation step to separate the monoestolides from the polyestolides. The invention also relates to a composition of estolides which can be obtained by the process of the invention and its use in lubricating compositions.

Lubricating grease compositions

The invention relates to lubricating grease compositions which consist of (a) an oil based on hydrocarbons; (b) a perfluorinated polyalkyl ether oil of the general formula A' - (O-CF2)v-(O-C2F4)w-(O-C3F6)x-(O-C4F8)y-(O-CF2CF(CF3))z-O-A'', in which A' is equivalent to -CF3, -C2F5, -C3F7, -CF2T, T being H or Cl, and v, w, x, y and z are integers ≥ 0; (c) a diurea as the thickening agent; (d) conventional additives; and (e) organic and inorganic solid lubricating grease compositions. The invention also relates to a process for preparing said lubricating grease compositions.

Mixtures of lubricant base materials with high viscosity complex alcohol esters

Patente de Invenção: <B>"MISTURAS DE MATERIAIS DE BASE LUBRIFICANTES COM éSTERES DE áLCOOIS COMPLEXOS DE ALTA VISCOSIDADE"<D>. Um óleo lubrificante compreendendo uma mistura por adição dos seguintes componentes: (A) um material de base de éster de álcool complexo que compreende o produto da reação de uma mistura por adição do seguinte: (1) um composto de polihidroxila representado pela fórmula geral: R(OH)~ n~, na qual R é qualquer um grupo hidrocarbila alifático ou ciclo-alifático e n é, pelo menos, 2, contanto que o referido grupo hidrocarbila contenha a partir de cerca de 2 até 20 átomos de carbono; (2) um ácido polibásico ou um anidrido de um ácido polibásico, contanto que a proporção de equivalentes do referido ácido polibásico para os equivalentes de álcool do referido composto de polihidroxila esteja na faixa entre cerca de 1,6:1 até 2:1, e (3) um álcool monoídrico, contanto que a proporção de equivalentes do referido álcool monoídrico para os equivalentes do referido ácido polibásico esteja na faixa entre cerca de 0,84:1 até 1,2 ;1; em que o referido éster de álcool complexo exiba uma viscosidade na faixa entre cerca de 100 a 700 cSt a 40°C e tenha uma concentração do éster do ácido polibásico de menos que ou igual a 70 por cento em peso, com base no referido éster de álcool complexo; e (B) pelo menos um material de base adicional.

Non-graphite lubricating oil dispersed in oil

Design and preparation method of high-viscosity ester base oil

本发明提供了一种高粘度酯类基础油设计及其制备方法；所设计并合成的高粘度酯类基础油为“桥联型”新戊基多元醇酯，具有式(I)所示的结构；在式(I)中，n为聚合度，n 0 为二元羧酸的碳原子数，n 1 、n 2 和n 3 为支链数，其中0≤n 1 ≤3，0≤n 2 ≤3，2≤(n 1 +n 2 )≤3，1≤n 3 ≤2；R、R 1 和R 2 为不同的烷基，R i 为R 1 或R 2 。本发明从分子构型设计、酯化催化剂、合成工艺及精制方法四方面入手，设计并合成了“桥联型”新戊基多元醇酯。该油品可作为环保型高性能润滑油基础油使用。与文献报道的高粘度酯类基础油不同，本发明设计的“桥联型”新戊基多元醇酯的分子构型更为合理，在保持较好粘温性能与低温流动性的前提下，具有极高的储存稳定性。