06-02-2020 дата публикации
Номер: US20200044132A1
Принадлежит:
An alloy is provided that consists essentially of 1. An alloy consisting essentially of{'br': None, 'sub': x', 'y', 'z', 'c', '1-x-y-z-c', '1-d', 'd', 'a', '1-e', 'e', 'b, '(TiTaVANb)(FeMn)(SbSn),'}wherein0.06≤x≤0.24,0.01≤y≤0.06,0.05≤z≤0.4,0.9≤(a, b)≤1.1,0≤c≤0.05,0≤d≤0.05,0≤e≤0.1,Wherein A is one or more of the elements in the group consisting of Zr, Hf, Sc, Y, La, and up to 5 atom % impurities.2. An alloy according to claim 1 , wherein the alloy has a positive Seebeck coefficient.3. An alloy according to claim 1 , wherein the alloy has a Half-Heusler structure.4. An alloy according to claim 1 , wherein the alloy has a maximum thermoelectric figure of merit ZTof ≥0.8.5. An alloy according to claim 4 , wherein the alloy has a thermoelectric figure of merit ZT of ZT≥0.8 claim 4 , where T=500° C.6. An alloy according to claim 1 , wherein 0.01≤y≤0.045.7. An alloy according to claim 1 , wherein 0.075≤z≤0.3.8. An alloy according to claim 1 , wherein c=0 claim 1 , d=0 and e=0.9. A sintered article comprising an alloy according to .10. A sintered article according to claim 9 , wherein the sintered article has an average grain size of greater than 1.25 μm.11. A sintered article according to claim 9 , wherein the sintered article has a density D claim 9 , D being ≥90% of the theoretic density D.12. A thermoelectric module comprising at least one thermoelectric element made of an alloy according to and having at least one thermoelectric element made of an N-type alloy.13. A thermoelectric module comprising at least one thermoelectric element comprising a sintered article according to and having at least one thermoelectric element made of an N-type thermoelectric alloy.14. A method for the production of a sintered article claim 9 , comprising: {'br': None, 'sub': x', 'y', 'z', 'c', '1-x-y-z-c', '1-d', 'd', 'a', '1-e', 'e', 'b, '(TiTaVANb)(FeMn)(SbSn),'}, 'providing a starting material consisting essentially of'}wherein0.06≤x≤0.24,0.01≤y≤0.06,0.05≤z≤0.4,0.9≤(a, b)≤1.1,0≤c≤0.05,0 ...
Подробнее