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Применить Всего найдено 16334. Отображено 100.
20-08-2000 дата публикации

УСТРОЙСТВО ДЛЯ РЕГЕНЕРАЦИИ ОТРАБОТАННЫХ ЭЛЕКТРОЛИТОВ ПОЛИРОВАНИЯ И ТРАВЛЕНИЯ ХРОМСОДЕРЖАЩИХ СТАЛЕЙ

Номер: RU0000014735U1

Устройство для регенерации отработанных электролитов полирования и травления хромсодержащих сталей, содержащее образующие замкнутую систему регенерации с рабочими гальваническими ваннами электролизер-регенератор для катодного восстановления ионов тяжелых металлов: хрома (VI) до хрома (III) и железа (III) до железа (II), кристаллизатор для отделения образующегося осадка моногидрата сульфата железа (II), сборники растворов, установленные на трубопроводах вентили и датчики контроля растворов, насос для перекачивания регенерированного раствора в рабочую гальваническую ванну, отличающееся тем, что перед электролизером-регенератором установлены две последовательно соединенные сорбционные колонны: первая - для хитозана, вторая - для твердого полимера, причем вторая колонна соединена на входе с дозатором уксусной кислоты, а на выходе - со сборником раствора уксусной кислоты с хитозаном и связана трубопроводом, имеющим датчик контроля за содержанием ионов хрома в растворе, с электролизером-регенератором, соединенным с кристаллизатором, снабженным дозатором мелкокристаллического сульфата калия и датчиком контроля за содержанием ионов железа в регенерированном растворе перед накопителем. (19) RU (11) 14 735 (13) U1 (51) МПК C23F 1/46 (2000.01) C23G 1/36 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 2000103796/20, 15.02.2000 (24) Дата начала отсчета срока действия патента: 15.02.2000 (46) Опубликовано: 20.08.2000 (72) Автор(ы): Федорова Е.А., Бакаев В.В., Исаев В.В., Мельникова Г.Е., Тишков К.Н. 1 4 7 3 5 R U (57) Формула полезной модели Устройство для регенерации отработанных электролитов полирования и травления хромсодержащих сталей, содержащее образующие замкнутую систему регенерации с рабочими гальваническими ваннами электролизер-регенератор для катодного восстановления ионов тяжелых металлов: хрома (VI) до хрома (III) и железа (III) до железа (II), кристаллизатор для отделения образующегося ...

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10-07-2001 дата публикации

УСТРОЙСТВО ДЛЯ РЕГЕНЕРАЦИИ ОТРАБОТАННЫХ ЭЛЕКТРОЛИТОВ ПОЛИРОВАНИЯ И ТРАВЛЕНИЯ СПЛАВОВ

Номер: RU0000018708U1

Устройство для регенерации отработанных электролитов полирования и травления сплавов, содержащее образующие замкнутую систему регенерации с рабочими гальваническими ваннами две последовательно соединенные сорбционные колонки: первая - для хитозана, вторая - для твердого полимера для извлечения ионов хрома (VI) и хрома (III) из электролита полирования или травления хромистых сталей, дозатор раствора уксусной кислоты, сборники растворов, установленные на трубопроводах вентили и датчики контроля растворов, насосы для перекачивания регенерированных электролитов в рабочие гальванические ванны, отличающееся тем, что после сорбционных колонок для извлечения ионов хрома (VI) и хрома (III) из электролита полирования или травления хромистых сталей и после рабочей гальванической ванны с электролитом полирования или травления алюминиевых сплавов установлены две холодильные камеры, соединенные в верхней части со сборниками регенерированных электролитов, а в нижней через вакуум-фильтры, имеющие слой кислотоустойчивой ткани для отделения гальванических осадков, со смесителем, снабженным дозаторами щелочного агента, трепела и фрезота для приготовления сырьевой смеси и получения керамзитового гравия. (19) RU (11) 18 708 (13) U1 (51) МПК C04B C04B C23F C23G 38/02 33/00 1/46 1/36 (2000.01) (2000.01) (2000.01) (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 2001100452/20, 05.01.2001 (24) Дата начала отсчета срока действия патента: 05.01.2001 (46) Опубликовано: 10.07.2001 (72) Автор(ы): Федорова Е.А., Лысова Е.К., Шувалов А.А., Бакаев В.В., Исаев В.В., Тишков К.Н. 1 8 7 0 8 R U (57) Формула полезной модели Устройство для регенерации отработанных электролитов полирования и травления сплавов, содержащее образующие замкнутую систему регенерации с рабочими гальваническими ваннами две последовательно соединенные сорбционные колонки: первая - для хитозана, вторая - для твердого полимера для извлечения ионов хрома ( ...

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27-04-2002 дата публикации

УСТРОЙСТВО ДЛЯ ОЧИСТКИ ПОВЕРХНОСТИ МЕТАЛЛИЧЕСКИХ ИЗДЕЛИЙ

Номер: RU0000022784U1

1. Устройство для очистки изделий, содержащее динамическую камеру, рабочую камеру и камеру сбора отходов, динамическая камера сообщена с рабочей камерой и выполнена замкнутой с возможностью создания в ней повышенного давления, рабочая камера и камера сбора отходов сообщены с возможностью разобщения и разделены перегородкой, высота, по меньшей мере, части которой меньше высоты стенок рабочей камеры. 2. Устройство по п.1, характеризующееся тем, что динамическая камера и рабочая камера разделены перегородкой с отверстиями в нижней части, обеспечивающими сообщение указанных камер. 3. Устройство по п.1 или 2, характеризующееся тем, что сообщение рабочей камеры и камеры сбора отходов обеспечено посредством трубки с запорным органом, на конце которой, размещенном в камере сбора отходов, установлен фильтр. 4. Устройство по любому из пп.1-3, характеризующееся тем, что в рабочей камере размещен поддон для сбора тяжелых отходов. (19) RU (11) 22 784 (13) U1 (51) МПК C23G 1/00 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К СВИДЕТЕЛЬСТВУ (21), (22) Заявка: 2002100190/20 , 14.01.2002 (24) Дата начала отсчета срока действия патента: 14.01.2002 (46) Опубликовано: 27.04.2002 (72) Автор(ы): Белорусов А.В., Тулупов А.В. (73) Патентообладатель(и): Общество с ограниченной ответственностью Научно-производственный центр "ЧЕКОС" U 1 2 2 7 8 4 R U Ñòðàíèöà: 1 U 1 (57) Формула полезной модели 1. Устройство для очистки изделий, содержащее динамическую камеру, рабочую камеру и камеру сбора отходов, динамическая камера сообщена с рабочей камерой и выполнена замкнутой с возможностью создания в ней повышенного давления, рабочая камера и камера сбора отходов сообщены с возможностью разобщения и разделены перегородкой, высота, по меньшей мере, части которой меньше высоты стенок рабочей камеры. 2. Устройство по п.1, характеризующееся тем, что динамическая камера и рабочая камера разделены перегородкой с отверстиями в нижней части, обеспечивающими ...

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10-11-2013 дата публикации

ТРАНСПОРТАБЕЛЬНЫЙ ТЕХНОЛОГИЧЕСКИЙ КОМПЛЕКС ХИМИЧЕСКОЙ ОЧИСТКИ ВНУТРЕННИХ ПОВЕРХНОСТЕЙ ТРУБОПРОВОДОВ И ОБОРУДОВАНИЯ НЕФТЕГАЗОДОБЫВАЮЩИХ МОРСКИХ ПЛАТФОРМ ИЛИ ТЕРМИНАЛОВ ОТ ОТЛОЖЕНИЙ СОЛЕЙ, ЗАГРЯЗНЕННЫХ ПРИРОДНЫМИ РАДИОНУКЛИДАМИ, СБОРА И УТИЛИЗАЦИИ ОБРАЗОВАВШИХСЯ ЖИДКИХ РАДИОАКТИВНЫХ ОТХОДОВ

Номер: RU0000134173U1

Транспортабельный технологический комплекс химической очистки внутренних поверхностей трубопроводов и оборудования нефтегазодобывающих морских платформ или терминалов от отложений солей, загрязненных природными радионуклидами, сбора и утилизации образовавшихся жидких радиоактивных отходов, содержащий многофункциональные стационарные технические средства по обращению с радиоактивными отходами в виде систем переработки и кондиционирования, и снабженный временным хранилищем утилизированных радиоактивных отходов, отличающийся тем, что он оснащен малогабаритной системой химической очистки путем промывки упомянутых трубопроводов и оборудования морских платформ или терминалов, включающей функциональные модули химической промывки, унифицированные модули емкостей для приготовления промывочного химического раствора и унифицированные модули емкостей для сбора и временного хранения образующихся жидких радиоактивных отходов, помещенные в сухогрузные транспортные морские контейнеры, размещенные на палубе морской платформы или терминала, причем многофункциональные стационарные технические средства по обращению с радиоактивными отходами выполнены в виде функциональных модулей, помещенных в сухогрузные транспортные морские контейнеры, включающие модуль переработки, модуль кондиционирования радиоактивных отходов, также размещенные на палубе морской платформы или терминала, а временное хранилище утилизированных радиоактивных отходов выполнено в виде функционального модуля транспортирования с морской платформы или терминала утилизированных радиоактивных отходов, при этом на палубе морской платформы или терминала предусмотрены временно проложенные магистрали для соединения упомянутых модулей с трубопроводами и оборудованием морской платформы или терминала, кроме того, упомянутые функциональные модули дополнены помещенными в сухогрузные транспортные морские контейнеры вспомогательными модулями, включающими модуль санпропускника для радиационного контроля на входе и выходе из зоны ...

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20-11-2015 дата публикации

УСТРОЙСТВО ДЛЯ ОБЕЗВРЕЖИВАНИЯ ОТРАБОТАННЫХ МЕДНО-АММИАЧНЫХ ТРАВИЛНЫХ РАСТВОРОВ

Номер: RU0000157170U1

Устройство для обезвреживания отработанных медно-аммиачных травильных растворов, содержащее резервуар, снабженный трубопроводами отвода и подачи обрабатываемых растворов, запорную арматуру и электротен, отличающееся тем, что в него дополнительно введен эрлифт с камерой замкнутого газового контура, газовая полость которой соединена трубопроводом с водяным абсорбером, а жидкостная полость которой соединена подающими трубопроводами с двухступенчатым реактором, загруженным магниевыми стружками, при этом реактор соединяется с резервуаром отводящими трубопроводами. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 157 170 U1 (51) МПК C02F 1/62 (2006.01) C23G 1/36 (2006.01) C23F 1/46 (2006.01) C25C 1/12 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ 2015111384/05, 30.03.2015 (24) Дата начала отсчета срока действия патента: 30.03.2015 (45) Опубликовано: 20.11.2015 Бюл. № 32 1 5 7 1 7 0 R U Формула полезной модели Устройство для обезвреживания отработанных медно-аммиачных травильных растворов, содержащее резервуар, снабженный трубопроводами отвода и подачи обрабатываемых растворов, запорную арматуру и электротен, отличающееся тем, что в него дополнительно введен эрлифт с камерой замкнутого газового контура, газовая полость которой соединена трубопроводом с водяным абсорбером, а жидкостная полость которой соединена подающими трубопроводами с двухступенчатым реактором, загруженным магниевыми стружками, при этом реактор соединяется с резервуаром отводящими трубопроводами. Стр.: 1 U 1 U 1 (54) УСТРОЙСТВО ДЛЯ ОБЕЗВРЕЖИВАНИЯ ОТРАБОТАННЫХ МЕДНО-АММИАЧНЫХ ТРАВИЛНЫХ РАСТВОРОВ 1 5 7 1 7 0 Адрес для переписки: 440028, г. Пенза, ул. Г. Титова, 28, Федеральное государственное бюджетное образовательное учреждение высшего Профессионального Образования Пензенский государственный университет архитектуры и строительства (73) Патентообладатель(и): Федеральное государственное бюджетное образовательное учреждение высшего ...

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31-10-2018 дата публикации

УСТРОЙСТВО ДЛЯ ИЗВЛЕЧЕНИЯ ИОНОВ МЕДИ ИЗ АММИАЧНЫХ СРЕД МЕТОДОМ МЕМБРАННОЙ ЖИДКОСТНОЙ ЭКСТРАКЦИИ

Номер: RU0000184583U1

Устройство для извлечения ионов меди из аммиачных сред методом мембранной жидкостной экстракции, содержащее корпус, в котором расположены нижняя вертикальная перегородка, камеры экстракции и реэкстракции, горизонтальная перегородка, на которой размещена верхняя вертикальная перегородка, при этом в камерах расположены турбинные мешалки. Новым, согласно предложенной полезной модели, является то, что корпус устройства выполнен цилиндрическим, вертикальные перегородки выполнены Y-образными, причем нижняя Y-образная перегородка разделяет корпус на 3 камеры, включающие камеру экстракции меди из аммиачных промывных вод с патрубками для ввода аммиачной промывной воды, содержащей ионы меди, и вывода обедненной медью аммиачной промывной воды, камеру экстракции меди из аммиачных растворов травления с патрубками для ввода аммиачного раствора травления, содержащего ионы меди, и вывода обедненного медью аммиачного раствора травления, и камеру реэкстракции с патрубками для ввода сернокислого раствора и вывода насыщенного медью сернокислого раствора, при этом верхняя Y-образная перегородка расположена под углом 60° по оси относительно нижней вертикальной Y-образной перегородки и разделяет каждую из 3-х упомянутых камер на секцию аккумулирования и секцию разделения, причем горизонтальная перегородка в секциях разделения расположена на 10 мм ниже верхнего уровня верхней Y-образной перегородки и выполнена перфорированной, а под секциями аккумулирования - сплошной. Предлагаемая конструкция устройства обеспечивает одновременное извлечение меди из аммиачных растворов травления печатных плат и аммиачных промывных вод методом мембранной жидкостной экстракции. И 1 184583 ко РОССИЙСКАЯ ФЕДЕРАЦИЯ ВУ” 184 583” 4 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ИЗВЕЩЕНИЯ К ПАТЕНТУ НА ПОЛЕЗНУЮ МОДЕЛЬ ММ9К Досрочное прекращение действия патента из-за неуплаты в установленный срок пошлины за поддержание патента в силе Дата прекращения действия патента: 19.11.2018 Дата внесения записи в ...

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21-11-2018 дата публикации

УСТРОЙСТВО ДЛЯ ИЗВЛЕЧЕНИЯ ИОНОВ МЕДИ ИЗ АММИАЧНЫХ СРЕД МЕТОДОМ МЕМБРАННОЙ ЖИДКОСТНОЙ ЭКСТРАКЦИИ

Номер: RU0000185094U1

Устройство для извлечения ионов меди из аммиачных сред методом мембранной жидкостной экстракции, содержащее корпус с образованными в нем камерами экстракции и реэкстракции, в которых расположены турбинные мешалки. Новым, согласно предложенной полезной модели, является то, что устройство снабжено двумя вертикальными сплошными перегородками, расположенными в корпусе с образованием камеры экстракции меди из аммиачных промывных вод с патрубками для ввода аммиачной промывной воды, содержащей ионы меди, и вывода обедненной медью аммиачной промывной воды, камеры экстракции меди из аммиачных растворов травления с патрубками для ввода аммиачного раствора травления, содержащего ионы меди, и вывода обедненного медью аммиачного раствора травления, и камеры реэкстракции, снабженной патрубками для ввода сернокислого раствора и вывода насыщенного медью сернокислого раствора, при этом в верхней части корпуса расположена горизонтальная перегородка, на которой размещена Y-образная вертикальная перегородка, которая разделяет верхнюю часть каждой из упомянутых камер на секцию аккумулирования и секцию разделения, причем горизонтальная перегородка в секциях разделения выполнена перфорированной, а под секциями аккумулирования - сплошной. Предлагаемая конструкция устройства обеспечивает одновременное извлечение меди из аммиачных растворов травления печатных плат и аммиачных промывных вод методом мембранной жидкостной экстракции. И 1 185094 ко РОССИЙСКАЯ ФЕДЕРАЦИЯ ЭВО“” 185 094°° Ц4 ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ИЗВЕЩЕНИЯ К ПАТЕНТУ НА ПОЛЕЗНУЮ МОДЕЛЬ ММ9К Досрочное прекращение действия патента из-за неуплаты в установленный срок пошлины за поддержание патента в силе Дата прекращения действия патента: 13.12.2018 Дата внесения записи в Государственный реестр: 25.02.2020 Дата публикации и номер бюллетеня: 25.02.2020 Бюл. №6 Стр.: 1 па 760981 ЕП

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01-03-2012 дата публикации

High molecular weight polyacrylates for aluminum protection in warewash applications

Номер: US20120053104A1
Принадлежит: ECOLAB USA INC

A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.

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15-03-2012 дата публикации

Extrusion-coated strip for rigid packagings

Номер: US20120064293A1
Принадлежит: Hydro Aluminium Deutschland GmbH

The invention relates to a method for producing a coated aluminium strip, in which the aluminium strip is unwound from a coil and fed into a unilateral or bilateral extrusion coating arrangement, the aluminium strip is extrusion coated with a thermoplastic polymer and after being extrusion coated, the aluminium strip is reheated to a metal temperature above the melting point of the thermoplastic polymer. The object of providing a method for producing an aluminium strip by which an extrusion-coated aluminium strip can be produced which can be processed at high processing speeds in follow-on composite tools is achieved in that the unilateral or bilateral plastics material coating of the aluminium strip is textured, after being reheated, using rolls which have a superficial structure.

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10-05-2012 дата публикации

Degreasing composition and production method thereof

Номер: US20120115766A1
Принадлежит: Yuken Industry Co Ltd

As a method for producing a degreasing composition in the form of a slurry, crystallization of the composition during low-temperature storage being suppressed and the composition being used for preparing a cleaning liquid having little environmental impact, provided is a method including a step of obtaining a slurry by mixing a first liquid and a powdery silicate having a particle diameter ranging from 0.2 mm to 10 mm, wherein the first liquid contains an alkaline component composed of at least one of sodium hydroxide and potassium hydroxide, an alcohol having three or fewer carbon atoms, and water; and the degreasing composition contains, with respect to the total composition, 10 mass % to 60 mass % of the alkaline component, 0.1 mass % to 5 mass % of the alcohol, 1 mass % to 50 mass % of the silicate, and 20 mass % to 50 mass % of water including hydration water of the silicate, and contains no chelating agent.

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14-06-2012 дата публикации

Cleaning Compound and Method and System for Using the Cleaning Compound

Номер: US20120145202A1
Принадлежит: Lam Research Corp

A cleaning compound is provided. The cleaning compound includes about 0.1 weight percent to about 10 weight percent of a fatty acid dispersed in water. The cleaning compound includes an amount of a base sufficient to bring a pH of the fatty acid water solution to about a level where above about 50% of the dispersed fatty acid is ionized. A method for cleaning a substrate, a system for cleaning a substrate, and a cleaning solution prepared by a process are also provided.

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21-06-2012 дата публикации

Galvanic waste sludge treatment and manufacturing of nano-sized iron oxides

Номер: US20120156497A1
Принадлежит: Green Future Ltd

The invention enables processing waste sludge after galvanic treatment of metals, and particularly recycling spent pickling acids after pickling. Provided is an environmentally friendly process, which yields acids for reuse, and pure nano-sized iron pigments as a side product.

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19-07-2012 дата публикации

Processing liquid for suppressing pattern collapse of fine metal structure and method for producing fine metal structure using same

Номер: US20120181249A1
Принадлежит: Mitsubishi Gas Chemical Co Inc

There are provided a processing liquid for suppressing pattern collapse of a fine metal structure, containing at least one member selected from an imidazolium halide having an alkyl group containing 12, 14 or 16 carbon atoms, a pyridinium halide having an alkyl group containing 14 or 16 carbon atoms, an ammonium halide having an alkyl group containing 14, 16 or 18 carbon atoms, a betaine compound having an alkyl group containing 12, 14 or 16 carbon atoms, and an amine oxide compound having an alkyl group containing 14, 16 or 18 carbon atoms, and a method for producing a fine metal structure using the same.

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29-11-2012 дата публикации

Pretreatment process for aluminum and high etch cleaner used therein

Номер: US20120301351A1
Принадлежит: Henkel AG and Co KGaA

A high etch cleaner for aluminum and aluminum alloy substrates that leads to enhanced corrosion protective performance of a variety of anti-corrosion pretreatments. The cleaner comprises low levels of silicate of from 0 to 250 ppm, 50 to 500 ppm of at least one chelator, and has a pH of from 11.0 to 13.5. The cleaner may be used to etch from 0.5 to 4.0 grams per meter squared from substrates. Substrates treated with the cleaner and then coated with a variety of anti-corrosion pretreatments and outer coatings show enhanced corrosion resistance compared to substrates cleaned with standard cleaners that have low etch rates, high silicate levels and no chelating agents followed by anti-corrosion pretreatments and outer coatings.

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29-11-2012 дата публикации

Photoresist removal

Номер: US20120302483A1
Принадлежит: Advanced Technology Materials Inc

Disclosed herein is a composition and method for semiconductor processing. In one embodiment, a wet-cleaning composition for removal of photoresist is provided. The composition comprises a strong base; an oxidant; and a polar solvent. In another embodiment, a method for removing photoresist is provided. The method comprises the steps of applying a wet-cleaning composition comprising about 0.1 to about 30 weight percent strong base; about one to about 30 weight percent oxidant; about 20 to about 95 weight percent polar solvent; and removing the photoresist.

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20-12-2012 дата публикации

Oxygen displacement technology (odt) to remove rust from iron and iron-based tools and structures

Номер: US20120318167A1
Принадлежит: JACKSON STATE UNIVERSITY

A novel method for the removal and prevention of rust from corroded iron surfaces is disclosed. This is done by inducing reducing conditions at the interphase between the rusted surface and the attached aluminum surface. An iron coating provided by the reducing conditions surrounds the clean iron and creates a barrier against future rust. Our technology is an oxygen displacement technology which essentially removes rust from iron and iron based tools and structures. It is cost effective, non-invasive, environmentally friendly and can be mass produced

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17-01-2013 дата публикации

Methods of Removing a Protective Layer

Номер: US20130014780A1
Принадлежит: Chevron Phillips Chemical Co LP

A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer with one or more chemical removal agents to remove at least a portion of the metal protective layer from the reactor component. A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer to remove the metal protective layer from the reactor component, and determining a thickness of the reactor component following treatment.

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14-02-2013 дата публикации

Methods and apparatus for cleaning deposition chamber parts using selective spray etch

Номер: US20130037062A1
Принадлежит: QUANTUM GLOBAL TECHNOLOGIES LLC

In one aspect, a method of cleaning an electronic device manufacturing process chamber part is provided, including a) spraying the part with an acid; b) spraying the part with DI water; and c) treating the part with potassium hydroxide. Other aspects are provided.

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28-02-2013 дата публикации

Instrument for Cleaning an Aluminum Workpiece

Номер: US20130048033A1
Принадлежит: Hydro Aluminium Deutschland GmbH

A method of conditioning the surface of a work piece, in particular of a litho-strip or litho-sheet, consisting of an aluminum alloy enables an increase in manufacturing speed in surface roughening while maintaining a high quality of the electro-chemical grained surface of the work piece with relative low effort related to facility equipment. The method of conditioning comprises at least the step of degreasing the surface of the work piece with a degreasing medium, wherein the degreasing medium contains at least 1.5 to 3% by weight of a composite of 5-40% sodium tripolyphosphate, 3-10% sodium gluconate, 3-8% of a composite of non-ionic and anionic surfactants and optionally 0.5 to 70% soda, wherein sodium hydroxide is added to the degreasing medium such that the concentration of sodium hydroxide in the aqueous degreasing medium is 0.01 to 5% by weight.

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14-03-2013 дата публикации

Cleaning Formulations and Method of Using the Cleaning Formulations

Номер: US20130061882A1
Принадлежит: Air Products and Chemicals Inc

A water-rich hydroxylamine formulation for photoresist and post-etch/post-ash residue removal in applications wherein a semiconductor substrate comprises aluminum. The cleaning composition comprises from about 2 to about 15% by wt. of hydroxylamine; from about 50 to about 80% by wt. of water; from about 0.01 to about 5.0% by wt. of a corrosion inhibitor; from about 5 to about 45% by wt. of a component selected from the group consisting of: an alkanolamine having a pKa<9.0, a water-miscible solvent, and a mixture thereof. Employment of such composition exhibits efficient cleaning capability for Al substrates, minimal silicon etch while protecting aluminum for substrates comprising both materials.

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21-03-2013 дата публикации

Method of Treating Rolled Steel Article

Номер: US20130068249A1
Принадлежит:

A process is disclosed in which hot rolled or cold rolled steel articles, such as tube, pipe, plate and sheet are cleaned of mill scale, surface rust and oils. The cleaning compositions compromise a solution mixture of diluted hydrochloric acid, a non-anionic surfactant, a non-ionic, non denaturing detergent, sodium carbonate, a water conditioner and water and a drying compound of an aqueous alcohol solution. The solutions are used independently within the 5 step process that cleans, rinses and removes all moisture from the steel to provide a surface that optimizes subsequent manufacturing a fabrication process including welding, laser cutting and the coating process. 1. A method of treating a rolled steel article , the method comprising:providing a first solution comprising an acid arranged to separate mill scale components from steel and a surfactant arranged to suspend separated mill scale components in the first solution;applying the first solution to a surface of the rolled steel article for a prescribed duration;rinsing the first solution from the surface of the rolled steel article by applying a rinse liquid to the rolled steel article;directing a first flow of air onto the surface of the rolled steel article to remove moisture from the surface of the rolled steel article;providing a second solution which is more volatile than water;applying the second solution to the surface of the rolled steel article; anddirecting a second flow of air onto the surface of the rolled steel article subsequent to application of the second solution until remaining moisture on the rolled steel article is substantially removed.2. The method according to wherein the surfactant comprises a non-anionic surfactant.3. The method according to wherein the first solution comprises a non-ionic claim 1 , non-denaturing detergent.4. The method according to wherein the first solution comprises a water conditioner.5. The method according to wherein the first solution comprises a non-butyl ...

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02-05-2013 дата публикации

ANTI-CORROSIVE AGENT FOR WASHING OF METAL WITH ACID, DETERGENT SOLUTION COMPOSITION, AND METHOD FOR WASHING OF METAL

Номер: US20130109607A1
Принадлежит: NITTO BOSEKI CO., LTD.

An anti-corrosive agent for washing of a metal with an acid, which comprises an amphoteric polymeric compound (P) having at least one cationic constituent unit (A) having a specific structure, at least one anionic constituent unit (B) having a specific structure and a specific sulfur-containing constituent unit (C). 2. The anti-corrosive agent according to claim 1 , wherein the counter ion Xis an anion derived from an organic acid or an inorganic acid.3. The anti-corrosive agent according to claim 1 , wherein at least a part of the cationic constituent unit (A) is derived from a cationic monomer selected from the group consisting of diallylamines and inorganic acid salts and organic acid salts thereof.4. The anti-corrosive agent according to claim 1 , wherein at least a part of the cationic constituent unit (A) is derived from diallyldimethylammonium chloride and at least a part of the anionic constituent unit (B) is derived from maleic acid.6. A detergent solution composition comprising an acid solution and an anti-corrosive agent according to claim 1 , wherein the content of the amphoteric polymer compound (P) or the amphoteric polymer compound (P′) is 0.1 to 50000 mg based on 1 L of the acid solution.7. A method for washing a metal claim 6 , characterized in that the detergent solution composition according to is sprayed to the surface of the metal or the surface of the metal is immersed in the detergent solution composition to carryout the washing.8. A detergent solution composition comprising an acid solution and an anti-corrosive agent according to claim 5 , wherein the content of the amphoteric polymer compound (P) or the amphoteric polymer compound (P′) is 0.1 to 50000 mg based on 1 L of the acid solution.9. A method for washing a metal claim 8 , characterized in that the detergent solution composition according to is sprayed to the surface of the metal or the surface of the metal is immersed in the detergent solution composition to carryout the washing. The ...

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30-05-2013 дата публикации

Composition for dissolving and/or inhibiting deposition of scale on a surface of a system

Номер: US20130137622A1
Принадлежит: BASF SE

A composition for dissolving and/or inhibiting deposition of scale on a surface of a system comprises an acidic component, a wetting agent, and a corrosion inhibitor. The composition may further comprise water. The acidic component comprises an alkanesulfonic acid, e.g. methanesulfonic acid (MSA). The wetting agent comprises a surfactant. The corrosion inhibitor comprises an amphoteric surfactant. The alkanesulfonic acid is present in an amount of at least about 50 weight percent (wt %), the surfactant is present in an amount of from about 0.1 to about 30 wt %, and the amphoteric surfactant is present in an amount of from about 0.025 to about 20 wt %, each based on 100 wt % of the alkanesulfonic acid, the surfactant, and the amphoteric surfactant combined. A method of dissolving and/or inhibiting deposition of scale on the surface of the system comprises the step of contacting the surface of the system with the composition.

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13-06-2013 дата публикации

Method of producing cold-rolled steel sheet as well as cold-rolled steel sheet and members for automobile

Номер: US20130149526A1
Принадлежит: JFE Steel Corp

In a method of producing a cold-rolled steel sheet being excellent in not only the phosphate treatability but also the corrosion resistance after coating under severe corrosion environment such as hot salt water immersion test or composite cycle corrosion test, a continuously annealed steel sheet after cold rolling preferably including 0.5-3.0 mass % of Si is pickled to remove a Si-containing oxide layer on a surface layer of the steel sheet and further repickled so that a surface covering ratio of an iron-based oxide on the surface of the steel sheet is not more than 40% and preferably a maximum thickness of the iron-based oxide is not more than 150 nm, as well as a cold-rolled steel sheet produced by this method and a member for automobile using the cold-rolled steel sheet.

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13-06-2013 дата публикации

METHOD OF PRODUCING COLD-ROLLED STEEL SHEET AS WELL AS COLD-ROLLED STEEL SHEET AND MEMBERS FOR AUTOMOBILE

Номер: US20130149529A1
Принадлежит: JFE STEEL CORPORATION

In a method of producing a cold-rolled steel sheet being excellent in not only the phosphate treatability but also the corrosion resistance after coating under severe corrosion environment such as hot salt water immersion test or composite cycle corrosion test, a continuously annealed steel sheet after cold rolling is pickled with a mixture of nitric acid and hydrochloric acid having a nitric acid concentration of more than 100 g/L but not more than 200 g/L and a ratio R (HCl/HNO) of hydrochloric acid concentration to nitric acid concentration of 0.01-0.25 to remove Si-containing oxide formed on the steel sheet surface by continuous annealing, and a ratio of covering the surface of the steel sheet with an iron-based oxide formed by the pickling is not more than 85% and preferably a maximum thickness of the iron-based oxide existing on the surface of the steel sheet is not more than 200 nm. 1. A method of producing a cold-rolled steel sheet having Si with a range of 0.5-3.0 mass % , characterized in that a continuously annealed steel sheet after cold rolling is pickled with a mixture of nitric acid and hydrochloric acid having a nitric acid concentration of more than 100 g/L but not more than 200 g/L and a ratio R (HCl/HNO) of hydrochloric acid concentration to nitric acid concentration of 0.01-0.25.2. A method of producing a cold-rolled steel sheet according to claim 1 , wherein the mixture of nitric acid and hydrochloric acid has a nitric acid concentration of more than 110 g/L but not more than 140 g/L and a ratio R (HCl/HNO) of hydrochloric acid concentration to nitric acid concentration of 0.03-0.25.3. A method of producing a cold-rolled steel sheet according to claim 1 , wherein the pickling is carried out at a temperature of a pickling solution of 20-70° C. for 3-30 seconds.4. A method of producing a cold-rolled steel sheet according to claim 1 , wherein the steel sheet has a chemical composition comprising claim 1 , in addition to Si claim 1 , C: 0.01-0.30 ...

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04-07-2013 дата публикации

CLEANING LIQUID, AND ANTICORROSIVE AGENT

Номер: US20130172224A1
Принадлежит: TOKYO OHKA KOGYO CO., LTD.

In a cleaning liquid containing (A) an anticorrosive agent, and (B) a solvent, a compound represented by the following formula (1): 2. The cleaning liquid according to claim 1 , wherein the mercapto compound (A) is the compound represented by the above formula (1).3. The cleaning liquid according to claim 2 , wherein the position of binding of R is a meta- or para-position with respect to the position at which —(CH)—SH binds.4. The cleaning liquid according to claim 2 , wherein R represents a hydroxyl group.5. The cleaning liquid according to claim 1 , wherein the mercapto compound (A) is the compound represented by the above formula (2).6. The cleaning liquid according to claim 5 , wherein x is an integer of no less than 3 and no greater than 10.7. The cleaning liquid according to claim 1 , which is used for cleaning a substrate having a metal layer consisting of copper or a copper-containing alloy. This application is based on and claims the benefit of priority from Japanese Patent Application Nos. 2011-288930 and 2011-288931, filed on 28 Dec. 2011, the contents of which are incorporated herein by reference.1. Field of the InventionThe present invention relates to a cleaning liquid, and an anticorrosive agent for copper or a copper-containing metal.2. Related ArtSemiconductor devices are formed by laminating a metal wiring layer, a low dielectric layer, an insulating layer or the like on a substrate such as a silicon wafer, and such semiconductor devices are manufactured via processing of each of these layers by a lithography method including carrying out an etching treatment using a resist pattern as a mask.Residual matter derived from a resist film and a temporarily laminated film (may be also referred to as “sacrificial film”) used in the lithography method, as well as the metal wiring layer and the low dielectric layer generated in an etching step are eliminated using a cleaning liquid so as not to be a hindrance for the semiconductor device, and not to ...

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01-08-2013 дата публикации

AQUEOUS CLEANING AGENT

Номер: US20130196889A1
Автор: Kawasaki Hiroshi
Принадлежит: IDEMITSU KOSAN CO., LTD.

An aqueous detergent according to the invention contains substantially no polyalkylene glycol, but contains a salt of at least one of the following carboxylic acids A, B and C: A: an aliphatic monobasic carboxylic acid having a total carbon number of 9 or 10 and including a branched alkyl group; B: sebacic acid; and C: an aromatic monobasic carboxylic acid having a total carbon number of 11 to 13. 1. An aqueous detergent that comprises substantially no polyalkylene glycol , the aqueous detergent comprising a salt of at least one of carboxylic acids A , B and C below:A: an aliphatic monobasic carboxylic acid having a total carbon number of 9 or 10 and comprising a branched alkyl group;B: sebacic acid; andC: an aromatic monobasic carboxylic acid having a total carbon number of 11 to 13.2. The aqueous detergent according to claim 1 , wherein the salt of the carboxylic acid is at least one of an amine salt and alkali metal salt.3. The aqueous detergent according to claim 1 , which is suitable for rust prevention.4. The aqueous detergent according to claim 1 , wherein a concentration of the salt of the carboxylic acid is in a range from 0.5 g/dL to 30 g/dL based on a total amount of the aqueous detergent.5. The aqueous detergent according to claim 2 , which is suitable for rust prevention.6. The aqueous detergent according to claim 2 , wherein a concentration of the salt of the carboxylic acid is in a range from 0.5 g/dL to 30 g/dL based on a total amount of the aqueous detergent.7. The aqueous detergent according to claim 3 , wherein a concentration of the salt of the carboxylic acid is in a range from 0.5 g/dL to 30 g/dL based on a total amount of the aqueous detergent. The present invention relates to an aqueous detergent used for washing machine components and the like.Metalworking fluid used in metalworking and subsequent washing is generally categorized into oil-type fluid and water-type fluid, the latter of which is more frequently used because such water-type ...

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15-08-2013 дата публикации

ALUMINUM SAFE COMPOSITIONS FOR REMOVING CURED POLYSULFIDE RESINS

Номер: US20130206166A1
Автор: Moorre John Cleaon
Принадлежит:

A metal-safe dissolving composition for cured resins, comprising a solvent blend that includes a metal safe solvent mixture with addition of a soluble alkali that exhibits a pKa value ≧12. The solvent mixture may include the preferred solvent for metal safety, gamma-butyrolactone (GBL), and the preferred soluble amine, 1,8-diazabicyclo(5.4.0)undec-7-ene (DBU). The solvent, n,n-dimethylacetamide (DMAC) or others, are chosen for high penetration and solvency to polar resins. To this mixture, a surfactant, inhibitor, and cellulose derivative may be added to produce a gel-form property. The product may be used to remove coatings and sealants present on vertical and horizontal surfaces and hard to reach areas commonly encountered when performing maintenance on aviation fuel tanks and similar equipment. Of key importance for the remover is its safety to aluminum and aluminum alloy substrates as demonstrated by modified test methods for sandwich corrosion, for example, ASTM F1110. 1. A metal-safe composition effective for dissolving a cured polysulfide resin comprising:(a) a solvent mixture exhibiting a high penetration and solvency capacity for polar resins such as polysulfide; and,(b) a soluble alkali component exhibiting a high pKa value ≧12.2. The composition of wherein (a) comprises a solvent shown to be metal safe by sandwich corrosion tests using methods that follow a modified ASTM F1110.3. The composition of wherein (b) the soluble alkali of pKa≧12 is an organic or inorganic origin to include hydroxides claim 2 , alkanolamines claim 2 , alkoxides claim 2 , or amines.4. The composition of wherein (b) the soluble alkali of pKa≧12 is 1 claim 3 ,8-diazabicyclo(5.4.0)undec-7-ene (DBU).5. The composition of claim 3 , which includes a compatible surfactant.6. The composition of claim 5 , which includes a hydroxypropylcellulose.7. The composition of claim 6 , which includes a corrosion inhibitor.8. The composition of wherein the corrosion inhibitor is an organosilane.9. ...

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24-10-2013 дата публикации

Treatment process for an isomerization unit

Номер: US20130276825A1
Принадлежит: UOP LLC

One exemplary embodiment can be a process for treating an interior of equipment for an isomerization unit. Generally, the isomerization unit includes at least one of a drying zone, an isomerization reaction zone, and a stabilizer zone, for receiving a feed stream. Usually, the feed stream includes one or more C4-C8 hydrocarbons. The process can include combining an anhydrous hydrogen stream and anhydrous organic chloride stream to form a hydrogen chloride feedstock, and passing the hydrogen chloride feedstock to a reaction zone containing a catalyst including at least one of nickel, palladium, and platinum on an alumina support to form a hydrogen chloride stream, and passing the hydrogen chloride stream upstream of the isomerization reaction zone.

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07-11-2013 дата публикации

Water-rich stripping and cleaning formulation and method for using same

Номер: US20130296215A1
Принадлежит: Air Products and Chemicals Inc

The present invention relates to water-rich formulations and the method using same, to remove bulk photoresists, post-etched and post-ashed residues, residues from Al back-end-of-the-line interconnect structures, as well as contaminations. The formulation comprises: hydroxylamine; corrosion inhibitor containing a mixture of alkyl dihydroxybenzene and hydroxyquinoline; an alkanolamine, a water-soluble solvent or the combination of the two; and at least 50% by weight of water.

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28-11-2013 дата публикации

METHOD FOR SURFACE TREATMENT OF A PROTECTIVELY COATED SUBSTRATE

Номер: US20130316192A1
Принадлежит: VOESTALPINE STAHL GMBH

A method is shown for surface-treating a protectively coated substrate (), more particularly steel strip, for the purpose of enhancing the strength of adhesion with an adhesive (), where the at least partly multi-phase protective coat () comprises at least zinc and magnesium. In order to provide a particular suitability for adhesive bonding, it is proposed that the protective coat () be subjected to a pickling treatment, directed substantially at at least one intermetallic Zn—Mg phase () of the protective coat (), with acidic pickle, more particularly acid. 11102242. Method for surface treatment of a protectively coated substrate () , particularly steel strip , for improvement of the adhesion strength , with an adhesive () , wherein the at least partly multi-phase protective coating () comprises at least zinc and magnesium , wherein the protective coating () is subjected to a pickling treatment , which is essentially directed at at least one intermetallic Zn—Mg phase () of the protective coating () , with acidic pickle , particularly acid.2292. Method according to claim 1 , wherein in the pickling step for selective pickling of the protective coating () claim 1 , an oxide layer () of the protective coating () is also removed by pickling.32. Method according to claim 1 , wherein the protective coating () is subjected to a pickling treatment essentially directed at MgZn.427. Method according to claim 1 , wherein the protective coating () claim 1 , which additionally comprises aluminum claim 1 , is subjected to a pickling treatment essentially directed at a particularly ternary eutectic ().5. Method according to claim 1 , wherein an acid having a pKvalue less than 0 is used as an acidic pickle.6. Method according to claim 5 , wherein a non-oxidizing acid claim 5 , particularly HSO claim 5 , is used as an acidic pickle.72. Method according to claim 1 , wherein the protective coating () is subjected to a pickling duration of 0.5 to 20 seconds claim 1 , with an acid at a ...

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05-12-2013 дата публикации

Washing method and apparatus for removing contaminations from article

Номер: US20130319468A1
Автор: Keita Yanagawa
Принадлежит: Denso Corp

A method for washing an article to remove contaminations such as oils and fats, foreign substances and the like from a surface of the article is provided. The washing method comprises the steps of: cooling a washing solution to obtain a super-cooled washing solution; heating an article to increase its surface temperature to the temperature which is not lower than the boiling point of the washing solution; and washing and drying the article concurrently, while spraying the super-cooled washing solution to the heated article. The washing apparatus for carrying out this washing method is also provided. Using these washing method and apparatus, it becomes possible to downsize a scale of the washing apparatus, and to operate the washing apparatus under the energy-saving conditions as a result of reduction in an amount of the consumed energies, and the washing process at an accelerated speed.

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09-01-2014 дата публикации

Methods of Removing a Protective Layer

Номер: US20140007903A1
Принадлежит: CHEVRON PHILLIPS CHEMICAL COMPANY LP

A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer with one or more chemical removal agents to remove at least a portion of the metal protective layer from the reactor component. A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer to remove the metal protective layer from the reactor component, and determining a thickness of the reactor component following treatment. 1. A method of removing a first metal protective layer from a surface of a component of a catalytic reforming reactor comprising:converting at least a portion of a hydrocarbon feed stream to provide aromatic hydrocarbons by contacting the hydrocarbon feed stream with a first reforming catalyst in the catalytic reforming reactor, wherein the hydrocarbon feed and the aromatic hydrocarbons contact the first metal protective layer;removing the first reforming catalyst from the catalytic reforming reactor;treating the first metal protective layer of the component of the catalytic reforming reactor to mobilize at least a portion of the first metal protective layer from the surface of the component of the catalytic reforming reactor; andloading the catalytic reforming reactor with a second reforming catalyst comprising a zeolitic reforming catalyst or a bimetallic reforming catalyst.2. The method of wherein the first reforming catalyst is a zeolitic reforming catalyst selected from the group consisting of rhenium on an alumina support claim 1 , iridium on an alumina support claim 1 , platinum on a type X zeolite claim 1 , platinum on a type Y zeolite claim 1 , platinum on a cation exchanged type L zeolite claim 1 , and a large-pore zeolite including an alkali or alkaline earth metal charged with one or more Group VIII metals.3. The method of wherein the second reforming catalyst is a bimetallic reforming catalyst comprising:platinum, palladium, or ...

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16-01-2014 дата публикации

CLEANING LIQUID AND ANTICORROSIVE AGENT

Номер: US20140018281A1
Принадлежит: TOKYO OHKA KOGYO CO., LTD.

A method of cleaning a substrate having a metal layer including copper or a copper-containing alloy, the method including cleaning the substrate using a cleaning liquid that includes a mercapto compound represented by one or both of the following formulas (1) and (2), and a solvent containing water and a water-soluble organic solvent: 2. The method according to claim 1 , wherein the mercapto compound (A) is the compound represented by the above formula (1).3. The method according to claim 2 , wherein the position of binding of R is a meta- or para-position with respect to the position at which —(CH)—SH binds.4. The method according to claim 2 , wherein R represents a hydroxyl group.5. The method according to claim 1 , wherein the mercapto compound (A) is the compound represented by the above formula (2).6. The method according to claim 5 , wherein x is an integer of no less than 3 and no greater than 10. This application is a divisional of U.S. patent application Ser. No. 13/728,728, filed on Dec. 27, 2012, which claims priority to Japanese Patent Application Nos. 2011-288930 and 2011-288931, both filed Dec. 28, 2011, the entire contents of which are incorporated herein by reference.1. Field of the InventionThe present invention relates to a cleaning liquid, and an anticorrosive agent for copper or a copper-containing metal.2. Related ArtSemiconductor devices are formed by laminating a metal wiring layer, a low dielectric layer, an insulating layer or the like on a substrate such as a silicon wafer, and such semiconductor devices are manufactured via processing of each of these layers by a lithography method including carrying out an etching treatment using a resist pattern as a mask.Residual matter derived from a resist film and a temporarily laminated film (may be also referred to as “sacrificial film”) used in the lithography method, as well as the metal wiring layer and the low dielectric layer generated in an etching step are eliminated using a cleaning liquid ...

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01-01-2015 дата публикации

METHOD FOR SMUT REMOVAL DURING STRIPPING OF COATING

Номер: US20150000696A1
Принадлежит:

Stripping a metallic bond coat from an article using a wet chemical process. An article removed from service and having a metallic bond coat applied over a surface of its metallic substrate is provided. The metallic bond coat is used to improve the adhesion of a TBC to the article, so grit blasting to first remove any TBC applied over the bond coat and which still remains on the article initially may be required. The bond coated article is then immersed in an acid solution of HCl/HPOat a predetermined temperature for a predetermined amount of time, the HCl/HPOsolution reacting with the bond coat applied over the metallic substrate to form a smut on the surface. The article is then removed from the HCl/HPOsolution and quickly immersed in a solution of NaOH for a predetermined amount of time to at least partially desmut the surface. 1. A method for stripping a metallic coating from a component , comprising the steps of:providing a component having a metallic coating applied over a surface of a metallic substrate;{'sub': 3', '3, 'immersing the metallic coated component in a solution of predetermined concentration of HCl/HPOfor a predetermined amount of time at a predetermined temperature, wherein the solution reacts with the bond coat to form a smut; then'}{'sub': 3', '3, 'removing the component from the solution of HCl/HPOand immersing the turbine component in a solution of predetermined concentration of NaOH for a predetermined amount of time to remove the smut; then'}removing the component from the basic solution and rinsing the component with water to remove any residual smut; then{'sub': 3', '3, 'immersing the metallic coated component in a solution of predetermined concentration of HCl/HPOfor a second immersion for a predetermined amount of time at a predetermined temperature, wherein the solution reacts with any remaining metallic coat to form a smut; then'}{'sub': 3', '3, 'removing the component from the solution of HCl/HPOand immersing the turbine component a ...

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01-01-2015 дата публикации

OXIDIZING AQUEOUS CLEANER FOR THE REMOVAL OF POST-ETCH RESIDUES

Номер: US20150000697A1
Принадлежит:

An oxidizing aqueous cleaning composition and process for cleaning post-plasma etch residue and/or hardmask material from a microelectronic device having said residue thereon. The oxidizing aqueous cleaning composition includes at least one oxidizing agent, at least one oxidizing agent stabilizer comprising an amine species selected from the group consisting of primary amines, secondary amines, tertiary amines and amine-N-oxides, optionally at least one co-solvent, optionally at least one metal-chelating agent, optionally at least one buffering species, and water. The composition achieves highly efficacious cleaning of the residue material from the microelectronic device while simultaneously not damaging the interlevel dielectric and metal interconnect material also present thereon. 1. An aqueous cleaning composition , comprising at least one oxidizing agent , at least one oxidizing agent stabilizer comprising an amine species selected from the group consisting of primary amines , secondary amines , and tertiary amines , optionally at least one organic co-solvent , optionally at least one metal-chelating agent , optionally at least one buffering species , and water , wherein the pH of the cleaning composition is about 3 to about 9.24.-. (canceled)5. The aqueous cleaning composition of claim 1 , wherein the at least one oxidizing agent comprises hydrogen peroxide.6. The aqueous cleaning composition of claim 1 , wherein the at least oxidizing agent stabilizer comprises an amine species selected from the group consisting of monoethanolamine claim 1 , amino ethoxyethanol (diglycolamine) claim 1 , monoisopropanolamine claim 1 , isobutanolamine claim 1 , C-Calkanolamines claim 1 , methylethanolamine claim 1 , N-methylaminoethanol claim 1 , diethanolamine claim 1 , triethanolamine claim 1 , methyldiethanolamine claim 1 , triethylamine claim 1 , N claim 1 ,N-dimethylglycolamine claim 1 , N claim 1 ,N-dimethyldiglycolamine claim 1 , pentamethyldiethylenetriamine claim 1 , ...

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06-01-2022 дата публикации

WELDED STEEL SHEETS, AND SHEETS THUS PRODUCED

Номер: US20220002833A1
Принадлежит:

A steel sheet that is welded and then cold rolled to a thickness between 0.5 mm and 3 mm, the deformation ratio created by cold rolling in the base metal is equal to ε, for which the deformation ratio created by the cold rolling in the welded joint is equal to ε, where: 2. The steel sheet as recited in wherein the steel sheet has a tensile strength Rm greater than 600 MPa.3. The steel sheet as recited in wherein a composition of the base metal includes claim 1 , as contents expressed as weight percent:0.05%≤C≤0.17%;1.1%≤Mn≤2.76%;0.07%≤Si≤0.7%;S≤0.008%;P≤0.030%;0.015%≤Al≤0.61%;Mo≤0.13%;Cr≤0.55%;Cu<0.2%;Ni≤0.2%;Nb≤0.050%;Ti≤0.045%;V≤0.010%;B≤0.005%;Ca<0.030%; andN≤0.007%,a remainder being iron and unavoidable impurities due to processing.4. The steel sheet as recited in wherein the steel sheet has a tensile strength Rm greater than 690 MPa.5. The steel sheet as recited in wherein a composition of the base metal includes claim 4 , the contents being expressed as weight percent:0.13%≤C≤0.3%;1.8%≤Mn≤3.5%;0.1%≤Si≤2%;0.1%≤Al≤2%;1%≤S1+Al≤2.5%; andN≤0.010%;a remainder being iron and unavoidable impurities due to processing.6. The steel sheet as recited in wherein the composition of the base metal includes claim 5 , the contents being expressed as weight percent:Ni+Cr+Mo<1%;Ti≤0.1%;Nb≤0.1%; andV≤0.1%.7. The steel sheet as recited in wherein the steel sheet is suitable for press-hardening for the manufacture of parts having tensile strength Rm greater than 1000 MPa.8. The steel sheet as recited in wherein the composition of the base metal includes claim 7 , the contents being expressed as weight percent:0.15%≤C≤0.5%;0.4%≤Mn≤3%;0.1≤Si≤1%;Cr≤1%;Ti≤0.2%;Al≤0.1%; andB≤0.010%;a remainder being iron and unavoidable impurities due to processing.9. The steel sheet as recited in wherein the composition of the base metal includes at least one of claim 8 , the contents being expressed as weight percent:0.25%≤Nb≤2%; andNb≤0.060%.10. The steel sheet as recited in wherein the base metal is ...

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06-01-2022 дата публикации

METHODS FOR REFURBISHING AEROSPACE COMPONENTS

Номер: US20220002883A1
Принадлежит:

Embodiments of the present disclosure generally relate to methods for refurbishing aerospace components by removing corrosion and depositing protective coatings. In one or more embodiments, a method of refurbishing an aerospace component includes exposing the aerospace component containing corrosion to an aqueous cleaning solution. The aerospace component contains a nickel superalloy, an aluminide layer disposed on the nickel superalloy, and an aluminum oxide layer disposed on the aluminide layer. The method includes removing the corrosion from a portion of the aluminum oxide layer with the aqueous cleaning solution to reveal the aluminum oxide layer, then exposing the aluminum oxide layer to a post-rinse, and forming a protective coating on the aluminum oxide layer. 1. A method of refurbishing an aerospace component , comprising:exposing the aerospace component containing corrosion to an aqueous cleaning solution, wherein the aerospace component comprises a nickel superalloy, an aluminide layer disposed on the nickel superalloy, and an aluminum oxide layer disposed on the aluminide layer, and wherein the corrosion is contained on a first portion of the aluminum oxide layer while a second portion of the aluminum oxide layer is free of the corrosion;removing the corrosion from the first portion of the aluminum oxide layer with the aqueous cleaning solution to reveal the first portion of the aluminum oxide layer; thenexposing the first and second portions of the aluminum oxide layer to a post-rinse; andforming a protective coating on the first and second portions of the aluminum oxide layer.2. The method of claim 1 , wherein the aqueous cleaning solution comprises water claim 1 , a complexing agent claim 1 , and a base.3. The method of claim 2 , wherein the complexing agent comprises ethylenediaminetetraacetic acid (EDTA) and/or a salt thereof claim 2 , and wherein the base comprises a hydroxide.4. The method of claim 2 , further comprising:exposing the aerospace ...

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04-01-2018 дата публикации

CLEANING DEVICE

Номер: US20180001355A1
Автор: Masuda Akio, Shibata Yohei
Принадлежит: Mitsubishi Electric Corporation

A cleaning device is configured to include a first cleaning tank that holds water to which a small amount of an additive is added as a first cleaning fluid, a second cleaning tank that holds water, a water-based cleaning agent, an alkaline cleaning fluid, or a hydrophilic organic solvent as a second cleaning fluid, a first microscopic air bubble generation device, a first circulating pump, an ultrasonic wave emitting device, and a carrier device. Hydrophobic oil is removed by a cleaning target being exposed to the first cleaning fluid including microscopic air bubbles sprayed from a nozzle in an interior of the first cleaning tank, after which hydrophilic oil is removed by ultrasonic cleaning in the second cleaning tank. 112-. (canceled)13. A cleaning device , comprising:a first cleaning tank that holds a first cleaning fluid;a first microscopic air bubble generation device that generates microscopic air bubbles in the first cleaning fluid;a first circulating pump that causes the first cleaning fluid to circulate and supplies the first cleaning fluid including microscopic air bubbles to the first cleaning tank;a second cleaning tank that holds a second cleaning fluid;an ultrasonic wave emitting device that irradiates an interior of the second cleaning tank with an ultrasonic wave; anda carrier device that holds a cleaning target, conveys the cleaning target to the first cleaning tank, and subsequently continues by conveying the cleaning target to the second cleaning tank, whereinwater to which an additive that prevents air bubble coalescence is added is used as the first cleaning fluid, one of water, a water-based cleaning agent, an alkaline cleaning fluid, or a hydrophilic organic solvent is used as the second cleaning fluid, the first cleaning tank has a nozzle that sprays the first cleaning fluid above a surface of the first cleaning fluid in an interior of the first cleaning tank, and the carrier device conveys the cleaning target into the interior of the first ...

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07-01-2016 дата публикации

PROCESS OF MANUFACTURING HIGH-STRENGTH COLD ROLLED STEEL SHEETS

Номер: US20160002807A1
Принадлежит: JFE STEEL CORPORATION

A process of manufacturing high-strength cold rolled steel sheets containing 0.5 to 2.0 mass % silicon includes a pickling step of thermally annealing a steel sheet in a non-oxidizing atmosphere and thereafter pickling the steel sheet to dissolve away 0.5 g/mto less than 2.0 g/mof the steel sheet, and an electroplating step of electroplating the surface of the pickled steel sheet with zinc under such conditions that a coating mass of 100 to 5000 mg/mis obtained. 13.-. (canceled)4. A process of manufacturing high-strength cold rolled steel sheets containing 0.5 to 2.0 mass % silicon , comprising:{'sup': 2', '2, 'a pickling step of thermally annealing a steel sheet in a non-oxidizing atmosphere and thereafter pickling the steel sheet to dissolve away 0.5 g/mto less than 2.0 g/mof the steel sheet, and'}{'sup': '2', 'an electroplating step of electroplating the surface of the pickled steel sheet with zinc under such conditions that a coating mass of 100 to 5000 mg/mis obtained.'}5. The process according to claim 4 , wherein the non-oxidizing atmosphere is obtained by introducing a mixture gas containing nitrogen and hydrogen claim 4 ,the hydrogen content in the non-oxidizing atmosphere is not more than 10 vol %, andthe temperature of heating during the thermal annealing is not more than 900° C.6. The process according to claim 4 , further comprising an aqueous solution contact step of bringing the steel sheet after the electroplating step into contact with a P-containing aqueous solution having a concentration of not less than 0.001 g/L at a temperature of the P-containing aqueous solution of not less than 30° C.7. The process according to claim 5 , further comprising an aqueous solution contact step of bringing the steel sheet after the electroplating step into contact with a P-containing aqueous solution having a concentration of not less than 0.001 g/L at a temperature of the P-containing aqueous solution of not less than 30° C. This disclosure relates to a process ...

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07-01-2021 дата публикации

WATER-SOLUBLE FLUX AND COPPER MATERIAL PICKLING METHOD

Номер: US20210002550A1
Принадлежит:

The present invention belongs to the technical field of solder fluxes, and in particular relates to a water-soluble flux and a copper material pickling method. The water-soluble flux provided by the present invention includes an organic acid, an alcohol ether solvent, and deionized water. The organic acid is used as an active component of the present invention, and under the action of the alcohol ether solvent, oxides and impurities on the surface of a part to be welded can be sufficiently removed, and adhering residue of an acidic substance on the surface of the part to be welded can be reduced. In the process of tin plating of the part to be welded treated by the water-soluble flux provided by the present invention, the splash of tin liquid can be effectively inhibited, and the utilization rate of tin is improved. 1. A water-soluble flux , comprising the following components: an organic acid , an alcohol ether solvent , and deionized water.2. The water-soluble flux according to claim 1 , comprising the following components by mass parts claim 1 , 10-20 parts of the organic acid claim 1 , 1-10 parts of the alcohol ether solvent and 70-90 parts of the deionized water.3. The water-soluble flux according to claim 1 , wherein the organic acid comprises formic acid and/or acetic acid.4. The water-soluble flux according to claim 1 , wherein the alcohol ether solvent comprises one or more of ethylene glycol monobutyl ether claim 1 , dipropylene glycol methyl ether claim 1 , diethylene glycol monoethyl ether claim 1 , and tripropylene glycol monomethyl ether.5. The water-soluble flux according to claim 4 , wherein the alcohol ether solvent is ethylene glycol monobutyl ether and tripropylene glycol monomethyl ether.6. The water-soluble flux according to claim 5 , wherein the ratio of the mass of the ethylene glycol monobutyl ether to the mass of the tripropylene glycol monomethyl ether is (3-5):1.7. A copper material pickling method claim 5 , comprising:{'claim-ref': {'@ ...

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04-01-2018 дата публикации

HIGH-STRENGTH STEEL SHEET AND METHOD FOR MANUFACTURING THE SAME

Номер: US20180002778A1
Принадлежит: JFE STEEL CORPORATION

Provided are a high-strength steel sheet and a method for manufacturing the steel sheet. The high-strength steel sheet has a specified chemical composition with the balance being Fe and inevitable impurities, a microstructure including, in terms of area ratio, 25% or less of a ferrite phase, 75% or more of a bainite phase and/or a martensite phase, and 5% or less of cementite, in which, in a surface layer that is a region within 50 μm from the surface in the thickness direction, the area ratio of a ferrite phase is 5% to 20%, and a tensile strength is 1180 MPa or more. 1. A high-strength steel sheet havinga chemical composition containing, by mass %, C: 0.100% to 0.150%, Si: 0.30% to 0.70%, Mn: 2.20% to 2.80%, P: 0.025% or less, S: 0.0020% or less, Al: 0.020% to 0.060%, N: 0.0050% or less, Nb: 0.010% to 0.060%, Ti: 0.010% to 0.030%, B: 0.0005% to 0.0030%, Sb: 0.005% to 0.015%, Ca: 0.0015% or less, and the balance being Fe and inevitable impurities,a microstructure including, in terms of area ratio, 25% or less of a ferrite phase, 75% or more of a bainite phase and/or a martensite phase, and 5% or less of cementite,wherein, in a surface layer that is a region within 50 μm from the surface in the thickness direction, the area ratio of a ferrite phase is 5% to 20%, anda tensile strength being 1180 MPa or more.2. The high-strength steel sheet according to claim 1 , wherein the chemical composition further contains at least one element selected from at least one group consisting of claim 1 , by mass % claim 1 ,Group I: one or more elements selected from Cr: 0.30% or less V: 0.10% or less Mo: 0.20% or less, Cu: 0.10% or less, and Ni: 0.10% or less, andGroup II: REM: 0.0010% to 0.0050%.3. The high-strength steel sheet according to claim 1 , the steel sheet further having a YR of 0.85 or less.4. The high-strength steel sheet according to claim 2 , the steel sheet further having a YR of 0.85 or less.5. A method for manufacturing a high-strength steel sheet having a tensile ...

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04-01-2018 дата публикации

Methods and Compositions for Acid Treatment of a Metal Surface

Номер: US20180002818A1
Автор: Basaly Mores
Принадлежит:

The invention relates to compositions and methods that are useful in etching a metal surface. In particular, the invention relates to novel acid compositions and methods of using such compositions in etching a metal surface, preferably an aluminum surface prior to anodizing to dissolve impurities, imperfections, scale, and oxide. The compositions are effective in maintaining their etching capacity and in removing smut produced by the etching of a surface as well as in general cleaning. 1. (canceled)2. A composition consisting essentially of:(a) one or more fluoride ion compounds; and(b) one or more grain refiners.3. The composition according to claim 2 , consisting essentially of ammonium bifluoride and diammonium phosphate.4. The composition according to claim 2 , consisting essentially of ammonium bifluoride and a mixture of ammonium phosphate and diammonium phosphate.5. A composition consisting essentially of:(a) about 20 to about 80 grams per liter of ammonium bifluoride; and(b) about 1 to about 50 grams per liter of diammonium phosphate or a mixture of ammonium phosphate and diammonium phosphate.6. The composition according to claim 5 , which has a pH of about 2 to about 5.7. The composition according to claim 5 , consisting essentially of about 5 to about 30 grams per liter of diammonium phosphate or a mixture of ammonium phosphate and diammonium phosphate.8. The composition according to claim 7 , consisting essentially of about 10 to about 20 grams per liter of diammonium phosphate or a mixture of ammonium phosphate and diammonium phosphate.9. The composition according to claim 5 , consisting essentially of about 60 to 70 grams per liter of ammonium bifluoride.10. The composition according to claim 5 , consisting essentially of:(a) about 20 to about 80 grams per liter of ammonium bifluoride; and(b) about 1 to about 50 grams per liter of diammonium phosphate.11. The composition according to claim 10 , which has a pH of about 2 to about 5.12. The composition ...

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07-01-2021 дата публикации

SUBSTRATE LIQUID PROCESSING APPARATUS, SUBSTRATE LIQUID PROCESSING METHOD AND RECORDING MEDIUM

Номер: US20210002770A1
Принадлежит:

A substrate processing apparatus includes a substrate holder configured to horizontally hold and rotate a substrate which has a recess and a base metal layer exposed from a bottom surface of the recess; and a pre-cleaning liquid supply configured to supply a pre-cleaning liquid such as dicarboxylic acid or tricarboxylic acid onto the substrate being held and rotated by the substrate holder, to thereby pre-clean the base metal layer. A temperature of the pre-cleaning liquid on the substrate is equal to or higher than 40° C. 1. A substrate liquid processing apparatus , comprising:a substrate holder configured to horizontally hold and rotate a substrate which has a recess and a base metal layer exposed from a bottom surface of the recess; anda pre-cleaning liquid supply configured to supply a pre-cleaning liquid such as dicarboxylic acid or tricarboxylic acid onto the substrate being held and rotated by the substrate holder, to thereby pre-clean the base metal layer,wherein a temperature of the pre-cleaning liquid on the substrate is equal to or higher than 40° C.2. The substrate liquid processing apparatus of claim 1 , further comprising:a plating liquid supply configured to supply a plating liquid onto the pre-cleaned substrate.3. The substrate liquid processing apparatus of claim 2 ,wherein the temperature of the pre-cleaning liquid is within ±5° C. of a temperature of the plating liquid.4. The substrate liquid processing apparatus of claim 1 ,wherein the temperature of the pre-cleaning liquid is in a range from 60° C. to 70° C.5. The substrate liquid processing apparatus of claim 1 , further comprising:an additional pre-cleaning liquid supply configured to supply an additional pre-cleaning liquid onto the substrate before being pre-cleaned, to thereby accelerate oxidation of the base metal layer.6. The substrate liquid processing apparatus of claim 1 , further comprising:a deaerating device configured to deaerate the pre-cleaning liquid before being supplied onto ...

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07-01-2021 дата публикации

PICKLING FACILITY AND OPERATION METHOD OF PICKLING FACILITY

Номер: US20210002774A1
Принадлежит: PRIMETALS TECHNOLOGIES JAPAN, LTD.

A pickling facility includes: a pickling tank for storing an acid solution; a conveyance part for continuously conveying a steel plate immersed in the acid solution; a measurement part for measuring at least one parameter which has a correlation with a heat transfer coefficient between the acid solution and a reference surface disposed in the acid solution so as to face the steel plate; and a conveyance speed decision part configured to decide a conveyance speed of the steel plate conveyed by the conveyance part, on the basis of a measurement result of the at least one parameter. 1. A pickling facility , comprising:a pickling tank for storing an acid solution;a conveyance part for continuously conveying a steel plate immersed in the acid solution;a measurement part for measuring at least one parameter which has a correlation with a heat transfer coefficient between the acid solution and a reference surface disposed in the acid solution so as to face the steel plate; anda conveyance speed decision part configured to decide a conveyance speed of the steel plate conveyed by the conveyance part, on the basis of a measurement result of the at least one parameter.2. The pickling facility according to claim 1 , calculate the heat transfer coefficient from the measurement result of the at least one parameter obtained by the measurement part; and', 'decide the conveyance speed of the steel plate on the basis of the calculation result of the heat transfer coefficient., 'wherein the conveyance speed decision part is configured to3. The pickling facility according to claim 1 , comprising:a heat conductor forming at least a part of the reference surface; anda heat source disposed in contact with the heat conductor at an opposite side of the reference surface of the heat conductor,wherein the measurement part is configured to measure a temperature inside the heat conductor as one of the at least one parameter.4. The pickling facility according to claim 3 , comprising:a heat ...

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13-01-2022 дата публикации

ULTRASOUND DEGREASING EQUIPMENT

Номер: US20220008961A1
Принадлежит:

A continuous cleaning installation of a passing strip S includes a tank , an aqueous solution inside the tank . It also includes at least a roller immerged in the aqueous solution , at least an ultrasound emitter-, a feed for feeding an aqueous solution and emptying the tank. Moreover, it also includes an aqueous solution level estimator for estimating the aqueous solution level, a distance calculator for calculating for each ultrasound emitter its distance to the aqueous solution level and a power controller for controlling the power of the at least one ultrasound emitter and at least an impermeable closable opening on at least a lateral side of the tank through which the at least one ultrasound emitter can pass. 112-. (canceled)13: An equipment for continuous cleaning of a moving strip comprising:a tank containing an aqueous solution;at least one roll for guiding the strip into the tank;at least one ultrasound emitter;an aqueous solution feed for feeding the aqueous solution inside the tank;a tank emptier for emptying the tank;an aqueous solution level estimator for estimating an aqueous solution level in the tank;a distance calculator for calculating for each ultrasound emitter a distance to the aqueous solution level;a power controller for controlling a power of the at least one ultrasound emitter;at least one impermeable closable opening on at least one lateral side of the tank, the at least one ultrasound emitter is introducible though the at least one impermeable closable opening; anda wire connecting the power controller and the at least one ultrasound emitter.14: The equipment as recited in wherein the at least one ultrasound emitter is immerged into the aqueous solution.15: The equipment as recited in wherein the at least one ultrasound emitter is a resonator rod vibrating thanks to at least one piezo-electric transducer.16: The equipment as recited in wherein the resonator rod has a length parallel to a strip width of the moving strip.17: The equipment as ...

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01-01-2015 дата публикации

Corrosion resistance when using chelating agents in carbon steel-containing equipment

Номер: US20150005216A1
Принадлежит: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.

The present invention relates to the use of solutions containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) in treating subterranean formations, wherein the solutions contact carbon steel-containing equipment, and to a system containing a carbon steel-containing material in contact with a solution containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA), at elevated temperatures and/or employing carbon steel types as usually found in subterranean formations. 1. A method of treating subterranean formations using a solution containing glutamic acid N ,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N ,N-diacetic acid or a salt thereof (MGDA) , comprising contacting carbon steel-containing equipment with the solution at a temperature of at least 100° C.2. The method of claim 1 , wherein the carbon steel-containing equipment is cleaned or descaled.3. The method of claim 1 , wherein the solution is an acidic solution.4. The method of claim 1 , wherein the subterranean formation is used in oil and/or gas production claim 1 , in pickling claim 1 , completions claim 1 , stimulation by acidizing claim 1 , or fracturing.5. The method of claim 1 , wherein the solution in addition contains water and a corrosion inhibitor.6. The method of claim 5 , wherein the amount of corrosion inhibitor is more than 0 up to 3 vol % on total volume of the solution.7. The method of claim 1 , wherein the solution in addition contains one or more of water claim 1 , solvents claim 1 , alcohols claim 1 , glycols claim 1 , organic solvents claim 1 , mutual solvents claim 1 , soaps claim 1 , surfactants claim 1 , dispersants claim 1 , emulsifiers claim 1 , pH control additives claim 1 , acids or bases claim 1 , biocides/bactericides claim 1 , water softeners claim 1 , bleaching agents claim 1 , enzymes claim 1 , brighteners claim 1 , ...

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01-01-2015 дата публикации

Use of phenol compounds as activator for metal surface corrosion

Номер: US20150005219A1
Принадлежит:

Use of a compound of Formula (I) as a metal surface corrosion activator, a formulation containing the same compound and a process by using the same compound for providing a clean metal surface. Said formulation may further comprise water, a solvent such as a dipolar aprotic solvent, a water miscible organic solvent, or an organic base. 2. The method according to claim 1 , wherein said compound of Formula (1) is a monophenol compound or diphenol compound.3. The method according to claim 1 , wherein said compound of Formula (1) is selected from the group consisting of catechol; 2 claim 1 ,3 dihydroxy benzoic acid; 4-methyl catechol; and 4-tertio-butyl catechol.4. (canceled)5. (canceled)6. The method according to claim 1 , wherein said compound of Formula (1) is present in an amount of about 0.1% to about 20% by weight of said formulation.7. The method according to claim 1 , wherein said formulation further comprises water.8. The method according to claim 1 , wherein said formulation further comprises a dipolar aprotic solvent.9. The method according to claim 1 , wherein said formulation further comprises a water miscible organic solvent.10. The method according to claim 1 , wherein said formulation further comprises a diester of formula (II):{'br': None, 'sup': 1', '2, 'R—OOC-A-COO—R,'} [{'sup': 1', '2, 'sub': 1', '20, 'Rand R, dentical or different in said Formula (II), are C-Calkyl, aryl, alkyaryl, or arylalkyl groups, which are linear or branched, and which are cyclic or non-cyclic, and'}, 'A in said Formula (II) is a linear or branched divalent alkylene group., 'wherein12. The method according to claim 1 , wherein said formulation further comprises an organic base to adjust pH of said formulation.14. The process according to claim 13 , wherein said compound of Formula (1) is a monophenol compound or diphenol compound.15. The process according to claim 13 , wherein said compound of Formula (1) is selected from the group consisting of catechol; 2 claim 13 ,3 ...

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12-01-2017 дата публикации

Selective etching of reactor surfaces

Номер: US20170009136A1
Принадлежит: ASM America Inc

Compositions, methods, and systems permit selectively etching metal oxide from reactor metal parts (e.g., titanium and/or titanium alloys). The etching composition comprises an alkali metal hydroxide and gallic acid. The method is useful for cleaning reaction chambers used in the deposition of metal oxide films such as aluminum oxide.

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12-01-2017 дата публикации

METHOD OF MANUFACTURING SPUTTERING TARGET AND SPUTTERING TARGET

Номер: US20170009336A1
Принадлежит:

The manufacturing cost of a sputtering target is reduced and the impurity concentration of the manufactured sputtering target is also reduced. A method of manufacturing a sputtering target includes: surface-treating at least one of a used sputtering target and a scrap material; melting at least one of the used sputtering target and the scrap material after the surface treatment to form an ingot; and manufacturing a sputtering target by subjecting the ingot to forging, rolling, heat treating, and machining. 1. A method of manufacturing a sputtering target , comprising:surface-treating at least one of a used sputtering target including a first face and a scrap material including a second face to expose at least one of the first and second faces and remove at least one of a part of the used sputtering target and a part of the scrap material by 1 mm or more in an inward direction from at least one of the first and second faces, the used sputtering target and the scrap material each containing a metal element, and the first and second faces each having uniform metallic color;melting at least one of the used sputtering target and the scrap material after the surface treatment to form an ingot; andmanufacturing a sputtering target by subjecting the ingot to forging, rolling, heat treating, and machining.2. The method according to claim 1 , wherein at least one of the used sputtering target and the scrap material is surface-treated by at least one of a pickling removal and a mechanical removal.3. The method according to claim 2 , wherein the pickling removal is performed using a mixture containing two acids or more out of hydrofluoric acid claim 2 , nitric acid claim 2 , hydrochloric acid claim 2 , and acetic acid.4. The method according to claim 3 , wherein the pickling removal is performed using the mixture containing the hydrofluoric acid having a first mixture ratio and the nitric acid having a second mixture ratio higher than the first mixture ratio.5. The method ...

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11-01-2018 дата публикации

HIGH-STRENGTH PLATED STEEL SHEET AND METHOD FOR PRODUCING SAME

Номер: US20180010207A1

Disclosed herein is a high-strength plated steel sheet containing an internal oxidized layer, a soft layer including the internal oxidized layer, and a hard layer including a structure having metallic structure containing a low-temperature-transformation produced phase in a proportion of 70% or more by area of the whole of the metallic structure, in which polygonal ferrite is in a proportion of 0% or more by area, and 10% or less by area of the same, and retained austenite is in a proportion of 5% or more by volume of the same. The high-strength plated steel sheet satisfies the average depth D of the soft layer is 20 μm or more, the average depth d of the internal oxidized layer is 4 μm or more and less than D, and a tensile strength of 980 MPa or more. 1: A high-strength plated steel sheet having a hot-dip galvanized layer or a hot-dip galvannealed layer on a surface of a base steel sheet , the base steel sheet comprising , in % by mass:C: 0.10 to 0.5%,Si: 1 to 3%,Mn: 1.5 to 8%,Al: 0.005 to 3%,P: more than 0% to 0.1% or less,S: more than 0% to 0.05% or less, andN: more than 0% to 0.01% or less,wherein: an internal oxidized layer comprising at least one an oxide selected from the group consisting of Si and Mn,', 'a soft layer comprising the internal oxidized layer, and having a Vickers hardness of 90% or less of a Vickers hardness of a portion of t/4 of the base steel sheet where “t” is a sheet thickness of the base steel sheet, and', 'a hard layer comprising a structure having metallic structure which comprises, when the metallic structure is observed through a scanning electron microscope, a low-temperature-transformation produced phase in a proportion of 70% or more by area of the whole of the metallic structure, and polygonal ferrite in a proportion of 0 to 10% by area of the whole of the metallic structure;, 'the plated steel sheet sequentially comprises, from an interface between the base steel sheet and the galvanized layer or galvannealed layer toward the ...

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11-01-2018 дата публикации

METHOD FOR PRETREATING MAGNESIUM-ALLOY WASTE MATERIAL

Номер: US20180010210A1
Автор: TAN Heyi, TANG Lunyuan

A method comprises sorting and removing impurities from magnesium alloy waste material, and cleaning and drying said material, the cleaning being high-pressure rinsing, pickling, and water washing, performed in sequence. The method employs high-pressure rinsing during the pretreatment of magnesium alloy waste material; the cleaning effectiveness is excellent, the effectiveness of the removal of impurities from the surface of the magnesium alloy waste material is much better than in conventional processes, and the amount of clean waste material can exceed 90% of the total amount of processed waste material; the clean magnesium alloy waste material obtained from the pretreatment method may be used as the entire raw materials for casting national-standard alloy ingots, the addition of costly high-purity magnesium is unnecessary, and the amount of alloy raw material that must be added is significantly reduced; during processing, little waste material is lost, costs are low, and efficiency is high. 1. A method for pretreating magnesium alloy waste material , involving sorting and removing impurities from , cleaning and drying magnesium alloy waste material , wherein the cleaning includes high-pressure cleaning , pickling , and water rinse performed in sequence.2. The method of claim 1 , wherein the pressure of high-pressure cleaning is 5-20 MPa.3. The method of claim 1 , wherein the pressure of high-pressure cleaning is 10-15 MPa.4. The method of claim 1 , wherein the large magnesium alloy waste material is cut into plural smaller pieces of the magnesium alloy waste material before sorted and having impurities removed therefrom.5. The method of claim 4 , wherein the cut magnesium alloy waste material is smaller than 300 mm in all dimensions.6. The method of claim 1 , wherein sorting and removing impurities refers to screening waste with inseparable screws claim 1 , rubber claim 1 , or plastic claim 1 , waste with surface coating claim 1 , and non-magnesium waste out of ...

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11-01-2018 дата публикации

PICKLING PRODUCTION LINE AND APPLICATION THEREOF FOR MAGNESIUM ALLOY WASTE MATERIAL

Номер: US20180010254A1
Автор: TAN Heyi, TANG Lunyuan

A pickling production line comprises a material-holding apparatus, a pickling zone, and a water wash zone; the pickling zone and the water wash zone are independently arranged; the material-holding apparatus is filled with magnesium alloy waste, and self-rotates successively in the pickling zone and the water wash zone for pickling and water washing respectively. In the pickling production line for magnesium alloy waste material, the magnesium alloy waste material is pickled and washed more thoroughly; coatings and impurities on the surface of the magnesium alloy waste material are removed, the efficiency of the cleaning and the consistency of the cleaning are high, and each piece of equipment in the entire production line is connected in a compact manner; the invention has a high degree of automation, low environmental pollution, conserves resources, is highly efficient in production, and is suitable for the bulk pickling and cleaning of magnesium alloy waste material. 1. A pickling production line for magnesium alloy waste material , being characterized in comprising: a batch-containing device , a pickling area , and a water-rinse area ,wherein the batch-containing device contains the magnesium alloy waste material, and the pickling area is independent of the water-rinse area; andwherein the material travels in the pickling production line in such manner: after fed into the batch-containing device, the magnesium alloy waste material is sent by the batch-containing device to the pickling area and the water-rinse area for pickling and water rinse in sequence.2. A pickling production line for magnesium alloy waste material , being characterized in comprising: a batch-containing device , a pickling area , a water-rinse area , and a hoisting device ,wherein the batch-containing device contains the magnesium alloy waste material, and the pickling area is independent of the water-rinse area, and the hoisting device drives the batch-containing device to travel between the ...

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15-01-2015 дата публикации

METHOD FOR PREVENTION OF YELLOWING ON SURFACE OF STEEL SHEET AFTER PICKLING

Номер: US20150013716A1
Принадлежит:

In a method for prevention of yellowing on a surface of a steel sheet subjected to re-pickling, washing with water and drying after a surface of a continuously annealed steel sheet is pickled to remove Si-containing oxide layer from a surface layer of the steel sheet, the surface of the steel sheet is held at a wet state between the pickling and the re-pickling and between the re-pickling and the washing, and more preferably the washing is carried out with water having an iron ion concentration decreased to not more than 20 g/L, whereby the yellowing on the surface of the steel sheet after the pickling is prevented. Thus, cold rolled steel sheets being excellent in not only the appearance quality but also the phosphatability and corrosion resistance after painting are manufactured stably. 114-. (canceled)15. A method for prevention of yellowing on a surface of a steel sheet subjected to re-pickling , washing with water and drying after a surface of a continuously annealed steel sheet is pickled to remove Si-containing oxide layer from a surface layer of the steel sheet , characterized in that the surface of the steel sheet is held at a wet state between the pickling and the re-pickling and between the re-pickling and the washing.16. The method for prevention of yellowing on a surface of a steel sheet according to claim 15 , wherein the washing is carried out with washing water having an iron ion concentration decreased to not more than 20 g/L.17. The method for prevention of yellowing on a surface of a steel sheet according to claim 16 , wherein the washing water is further characterized by decreasing a concentration of nitric acid ion to not more than 10 g/L claim 16 , a concentration of chloride ion to not more than 5 g/L claim 16 , a concentration of fluoride ion to not more than 5 g/L and a concentration of sulfuric acid ion to not more than 5 g/L.18. The method for prevention of yellowing on a surface of a steel sheet according to claim 15 , wherein the washing ...

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09-01-2020 дата публикации

MOLYBDENUM CONTAINING TARGETS

Номер: US20200013598A1
Принадлежит:

The invention is directed at sputter targets including 50 atomic % or more molybdenum, a second metal element of titanium, and a third metal element of chromium or tantalum, and deposited films prepared by the sputter targets. In a preferred aspect of the invention, the sputter target includes a phase that is rich in molybdenum, a phase that is rich in titanium, and a phase that is rich in the third metal element. 121.-. (canceled)22. A process comprising:providing a sputtering target and a substrate within a sputtering chamber; andsputtering the sputtering target to remove atoms therefrom, whereby at least some of the atoms removed from the sputtering target are deposited over the substrate as a layer, a continuous first phase comprising at least 50 atomic % molybdenum;', 'dispersed within the first phase, a discrete second phase comprising at least 50 atomic % of a first element selected from the list consisting of titanium, tantalum, chromium, hafnium, zirconium, and tungsten; and', 'dispersed within the first phase and/or within the second phase, a discrete third phase comprising at least 50 atomic % of a second element selected from the list consisting of titanium, tantalum, chromium, hafnium, zirconium, and tungsten, wherein the first and second elements are different., 'wherein (i) the layer comprises molybdenum and at least two additional elements selected from the list consisting of titanium, tantalum, chromium, hafnium, zirconium, and tungsten, and (ii) the sputtering target comprises23. The process of claim 22 , wherein the sputtering target is sputtered at a pressure of about 100 Torr or less.24. The process of claim 22 , wherein the sputtering target is sputtered using a magnetic field and/or an electric field.25. The process of claim 22 , wherein a thickness of the layer is about 200 nm or less.26. The process of claim 22 , wherein the substrate comprises silicon.27. The process of claim 22 , wherein the substrate comprises glass.28. The process of ...

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03-02-2022 дата публикации

HOT-BAND ANNEALING EQUIPMENT, HOT-BAND ANNEALING METHOD AND DESCALING METHOD FOR SI-CONTAINING HOT ROLLED STEEL SHEET

Номер: US20220033928A1
Принадлежит: JFE STEEL CORPORATION

Provided is a hot-band annealing method comprising subjecting a Si-containing hot rolled steel sheet, having an oxidized scale formed on a surface of the steel sheet by hot rolling, to hot-band annealing with a hot-band annealing equipment provided with a heating zone, a soaking zone, a cooling zone, and a rapid heating device at an upstream side of the heating zone and/or in an inlet side of the heating zone, wherein the hot rolled steel sheet is heated by not lower than 50° C. at a heating rate of not less than 15° C./s by using the rapid heating device to improve a descaling property. Also, provided is a descaling method characterized by subjecting the Si-containing hot rolled steel sheet, after the hot-band annealing, to descaling only by pickling without requiring mechanical descaling or heating the steel sheet in the pickling process. 1. A hot-band annealing method comprising: (i) a rapid heating device is disposed at an upper stream side of the heating zone and/or an inlet side of the heating zone, and', '(ii) a start temperature for heating the Si-containing hot-rolled steel sheet in the rapid heating device is in a range of room temperature to 700° C. and the Si-containing hot rolled steel sheet is heated by not lower than 50° C. at a heating rate of not less than 15° C./s by using the rapid heating device., 'subjecting a Si-containing hot rolled steel sheet, having an oxidized scale formed on a surface of the steel sheet by hot rolling, to hot-band annealing with a hot-band annealing equipment provided with a heating zone, a soaking zone and a cooling zone, characterized in that'}2. The hot-band annealing method according to claim 1 , wherein the rapid heating device is an induction heating device or an electric heating device.3. A descaling method claim 1 , characterized by subjecting the Si-containing hot rolled steel sheet claim 1 , after the hot-band annealing by the method according to claim 1 , to pickling without conducting mechanical descaling.4. A ...

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19-01-2017 дата публикации

TWO-STAGE PRE-TREATMENT OF ALUMINUM COMPRISING PICKLING AND PASSIVATION

Номер: US20170016119A1
Принадлежит:

A method for anti-corrosion treatment of components produced from aluminium, comprising a pre-treatment stage and subsequent painting. The pre-treatment stage includes steps of pickling and passivation wherein passivation of the components includes contacting them with an acidic, aqueous composition based on water-soluble compounds of the elements Zr and/or Ti. The pickling and passivation are coordinated with each other so that a re-dosing of active components of the passivation solution can occur in substantial parts from the pickling solution. 1. A method for anti-corrosion treatment of components at least partly produced from aluminum , comprising a pre-treatment stage and subsequent painting stage , wherein steps in the pre-treatment stage comprise:a. contacting an aluminum component with an aqueous pickling solution that has a pH value of 1 to 3, a free acid content in points of at least 8 and a total fluoride content of at least 40 mmol/l; andb. contacting the component from step a) with an aqueous passivation solution that has a pH value of 1 to 3, a free acid content in points of below 8 and a total fluoride content of less than 60 mmol/l but at least 5 mmol/l, and also contains less than 10 mmol/l but at least 0.1 mmol/l of water-soluble compounds of the elements Zr and/or Ti for each respective element, whereby after the component is brought into contact with the pickling solution and before it is brought into contact with the passivation solution, no rinsing or drying step takes place.2. The method according to claim 1 , wherein the pickling solution has a free acid content in points of at least 12.3. The method according to claim 1 , wherein the pickling solution has a pH value of less than 2.4. The method according to claim 1 , wherein the pickling solution has a total acid content in points of at least 15.5. The method according to claim 1 , wherein the pickling solution also contains at least 7 mmol/l and not more than 30 mmol of water-soluble ...

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18-01-2018 дата публикации

METHOD OF TREATING A METAL SUBSTRATE

Номер: US20180016528A9
Принадлежит: XEROS LIMITED

A method of removing at least a portion of an oxide layer from the surface of a metal substrate comprising exposing the metal substrate to a body of treatment liquor comprising a treatment formulation and a multiplicity of solid particles which comprise or consists of a multiplicity of polymeric particles and wherein said treatment formulation comprises one or more promoters selected from the group consisting of acids, bases and surfactants wherein the method further comprises causing the solid particles and the metal substrate to enter into contacting relative movement. 1. A method of removing at least a portion of an oxide layer from the surface of a metal substrate comprising exposing the metal substrate to a body of treatment liquor comprising a treatment formulation and a multiplicity of solid particles which comprise or consists of a multiplicity of polymeric particles and wherein said treatment formulation comprises one or more promoters selected from the group consisting of acids , bases and surfactants wherein the method further comprises causing the solid particles and the metal substrate to enter into contacting relative movement.2. The method according to wherein the treatment formulation further comprises a solvent.3. The method according to or wherein the acids have a pKa greater than about −1.7.4. The method according to any one of the preceding claims wherein the one or more promoters comprise at least one organic acid.5. The method according to any of the preceding claims wherein the bases have a pKb greater than about −1.7.6. The method according to any one of the preceding claims wherein the one or more promoters comprise at least one carboxylic acid moiety.7. The method according to any one of the preceding claims wherein the one or more promoters comprise two or more carboxylic acid moieties.8. The method according to any one of the preceding claims wherein the one or more promoters comprise at least one citrate moiety.9. The method according to ...

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16-01-2020 дата публикации

METHOD AND DEVICE FOR COOLING A STEEL STRIP TRAVELLING IN A CONTINUOUS LINE COOLING SECTION

Номер: US20200017934A1
Автор: MAGADOUX Eric
Принадлежит:

Process and device for cooling a steel strip () running through the cooling section () of a continuous line, whereby cooling is achieved by projecting the strip with an aqueous solution of formic acid with a concentration of formic acid between 0.1% and 6%, and preferably between 0.5% and 2%. 112. Cooling process for a steel strip () running through the cooling section () of a continuous line , including a projection onto the said strip of a projecting solution , said solution being a liquid or a mixture of a liquid solution and a gas , characterized by the said liquid solution having a formic acid concentration of between 0.1% and 6% by mass.2. Process as per claim 1 , where the liquid solution has a formic acid concentration of between 0.5% and 2% by mass.3. Process as per claim 1 , where the solution is projected onto the steel strip by spraying.413. Process as per claim 1 , also including a continuous or periodic check of the solution to be projected claim 1 , said check including a measurement of at least one physico-chemical datum of the said solution—from the group including pH claim 1 , density and formic acid concentration claim 1 , or a combination of these physico-chemical data claim 1 , and claim 1 , when this measurement does not fall within a predetermined range of tolerance claim 1 , a predetermined volume of the projected solution is drawn off and the same predetermined volume of a formic acid solution is injected into the projection unit () claim 1 , said predetermined volume of formic acid solution having a concentration of formic acid such that the liquid solution to be projected claim 1 , following the injection claim 1 , is of a concentration of formic acid between 0.1% and 6%.5. Process as per claim 4 , where the liquid solution to be projected following the injection has a formic acid concentration between 0.5% and 2% by mass.6. Process as per claim 1 , where the solution drawn off is treated through oxidation with oxygenated water claim 1 , ...

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21-01-2021 дата публикации

METHOD FOR MANUFACTURING GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND GRAIN-ORIENTED ELECTRICAL STEEL SHEET

Номер: US20210017619A1
Принадлежит: NIPPON STEEL CORPORATION

A method for manufacturing a grain-oriented electrical steel sheet according to an aspect of the present invention includes a step of obtaining a hot-rolled steel sheet by carrying out hot rolling on a slab containing a predetermined component composition with a remainder including Fe and impurities, a step of obtaining a hot-rolled annealed sheet by carrying out hot-rolled sheet annealing as necessary, a step of carrying out pickling to obtain a pickled sheet, a step of carrying out cold rolling to obtain a cold-rolled steel sheet, a step of carrying out primary recrystallization annealing, a step of applying an annealing separating agent including MgO to a surface and then carrying out final annealing to obtain a final-annealed sheet, and a step of applying an insulating coating and then carrying out flattening annealing. 1. A method for manufacturing a grain-oriented electrical steel sheet , the method comprising:a step of heating a slab havinga component composition containing, by mass %,C: 0.02% or more and 0.10% or less,Si: 2.5% or more and 4.5% or less,Mn: 0.01% or more and 0.15% or less,S and Se in total: 0.001% or more and 0.050% or less,acid-soluble Al: 0.01% or more and 0.05% or less,N: 0.002% or more and 0.015% or less,Cu: 0% or more and 0.30% or less,Sn: 0% or more and 0.30% or less,Ni: 0% or more and 0.30% or less,Cr: 0% or more and 0.30% or less, andSb: 0% or more and 0.30% or less,with a remainder including Fe and impurities to 1,280° C. to 1,450° C. and carrying out hot rolling to obtain a hot-rolled steel sheet;a step of carrying out pickling on the hot-rolled steel sheet to obtain a pickled sheet, or carrying out hot-rolled sheet annealing on the hot-rolled steel sheet to obtain a hot-rolled annealed sheet and pickling on the hot-rolled annealed sheet to obtain a pickled sheet;a step of carrying out cold rolling on the pickled sheet to obtain a cold-rolled steel sheet;a step of carrying out primary recrystallization annealing on the cold-rolled ...

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21-01-2021 дата публикации

ALLOYED HOT-DIP GALVANIZED STEEL SHEET AND ALLOYED HOT-DIP GALVANIZED STEEL SHEET PRODUCTION METHOD

Номер: US20210017621A1

In one aspect of the present invention, a hot-dip galvannealed steel sheet includes a steel sheet and a hot-dip galvannealed layer on the surface of the steel sheet. The steel sheet has a predetermined composition and has an average oxygen concentration of 0.10 mass % or less in the region of 1 μm from the interface between the steel sheet and the hot-dip galvannealed layer toward the steel sheet. The metal microstructure of the steel sheet at a position of t/4 where t represents the sheet thickness of the hot-dip galvannealed steel sheet includes 50 to 85 area % of martensite, 15 to 50 area % of bainite, and 5 area % or less of ferrite. 1. A hot-dip galvannealed steel sheet comprising:a steel sheet; and a hot-dip galvannealed layer on a surface of the steel sheet, wherein the steel sheet comprises, in mass %,C: 0.10% or more and 0.25% or less,Si: more than 0% and 0.50% or less,Mn: more than 2.0% and 3.5% or less,P: more than 0% and 0.1% or less,S: more than 0% and 0.05% or less,Al: 0.01% or more and 0.10% or less,Ti: more than 0% and 0.1% or less,B: 0.0020% or more and 0.0050% or less,N: more than 0?/ and 0.01% or less,Cr: more than 0% and 0.5% or less, andMo: more than 0% and 0.5% or less,Wherein the steel sheet has an average oxygen concentration of 0.10 mass % or less in a region of 1 μm from an interface between the steel sheet and the hot-dip galvannealed layer toward the steel sheet, andwherein a metal microstructure of the steel sheet at a position of t/4, where t represents a sheet thickness of the hot-dip galvannealed steel sheet, comprises 50 to 85 area % of martensite, 15 to 50 area % of bainite, and 5 area % or less of ferrite.2. A method for manufacturing the hot-dip galvannealed steel sheet of claim 1 , the method comprising:{'b': '1100', 'soaking a steel having a composition of the steel sheet at ° C. to 1300° C., hot-rolling the steel at a finishing temperature of 850° C. to 950° C., and coiling the hot-rolled steel at 630° C. to 680° C., to provide ...

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16-01-2020 дата публикации

COMPOSITION FOR CLEANING MASK AND METHOD FOR CLEANING MASK USING THE SAME

Номер: US20200017978A1
Принадлежит:

The present invention provides a composition for cleaning a mask comprising a) 0.2 to 10% by weight of two or more alkali compounds selected from alkali hydroxides and alkali carbonates, b) 0.1 to 8% by weight of nitrate, c) 1 to 8% by weight of an oxidizer, and d) residual water, wherein the pH is 11.5 to 14. 1. A composition for cleaning a mask comprising:a) 0.2 to 10% by weight of two or more alkali compounds selected from alkali hydroxides and alkali carbonates,b) 0.1 to 8% by weight of nitrate,c) 1 to 8% by weight of an oxidizer, andd) residual water,wherein the pH is 11.5 to 14.2. The composition for cleaning a mask of claim 1 , wherein the composition is used for cleaning a mask on which one or more selected from a metal film including one or more of silver and magnesium; and an aluminum oxide (AlO) film are deposited.3. The composition for cleaning a mask of claim 1 , wherein the material of the mask is one or more metals selected from stainless steel or a nickel alloy.4. The composition for cleaning a mask of claim 3 , wherein the material of the mask is one or more alloys selected from a steel use stainless (SUS) alloy claim 3 , an invariable (INVAR) alloy claim 3 , and a KOVAR alloy.5. The composition for cleaning a mask of claim 1 , wherein a) two or more alkali compounds comprises potassium hydroxide and sodium hydroxide.6. The composition for cleaning a mask of claim 5 , wherein a) the potassium hydroxide and sodium hydroxide have an amount of 0.1 to 5% by weight based on 100% by weight of the total weight of the composition for cleaning a mask (a+b+c+d).7. The composition for cleaning a mask of claim 1 , wherein b) nitrate is one or more selected from potassium nitrate claim 1 , sodium nitrate claim 1 , ammonium nitrate claim 1 , calcium nitrate claim 1 , aluminum nitrate claim 1 , and magnesium nitrate.8. The composition for cleaning a mask of claim 1 , wherein c) oxidizer is a sulfate compound.9. The composition for cleaning a mask of claim 8 , ...

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26-01-2017 дата публикации

RESIN-METAL COMPOSITE MATERIAL AND TIRE USING SAME

Номер: US20170021670A1
Автор: TOYOSAWA Shinichi
Принадлежит: BRIDGESTONE CORPORATION

Provided is a resin-metal composite material that ensures high adhesion between a resin material and a metal material. Additionally provided is a tire that achieves high durability by using the resin-metal composite material. The resin-metal composite material includes a metal material and a resin material that coats at least a part of the surface of the metal material. The resin material includes, as a main component, a thermoplastic resin having a polar group. The surface of the metal material is treated with a buffer solution having a pH of from 5 to 7.2, and an abundance ratio of copper to a total amount of copper and zinc (Cu/(Cu+Zn)×100) in the surface of the metal material is from 55 to 95% by mass. The tire includes a circular tire frame formed of a resin material and a reinforcing layer composed of a reinforcing member wound around an outer circumference of the tire frame, in which the reinforcing member includes the resin-metal composite material. 1. A resin-metal composite material comprising a metal material and a resin material that coats at least a part of a surface of the metal material , whereinthe resin material comprises, as a main component, a thermoplastic resin having a polar group; the surface of the metal material is treated with a buffer solution having a pH of from 5 to 7.2; and an abundance ratio of copper to a total amount of copper and zinc (Cu/(Cu+Zn)×100) in the surface of the metal material is from 55 to 95% by mass.2. The resin-metal composite material according to claim 1 , wherein the thermoplastic resin having a polar group is a maleic acid-modified polyolefin.3. The resin-metal composite material according to claim 1 , wherein the surface of the metal material treated with the buffer solution is additionally treated with an aqueous solution of a heterocyclic compound having two or more heteroatoms.4. The resin-metal composite material according to claim 3 , wherein the heterocyclic compound is triazoles.5. The resin-metal ...

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28-01-2016 дата публикации

CLEANING SOLUTION AND METHODS OF CLEANING A TURBINE ENGINE

Номер: US20160024438A1
Принадлежит:

A cleaning solution for a turbine engine includes water within a range between about 68.65 percent and about 99.63 percent by volume of the cleaning solution; a first organic acidic component within a range between about 0.1 percent and about 15 percent by volume of the cleaning solution; wherein the organic acid comprises citric acid; a second organic acidic component within a range between about 0.1 percent and about 15 percent by volume of the cleaning solution; wherein the organic acid comprises glycolic acid; isoropylamine sulphonate within a range between about 0.07 percent and 0.14 percent by volume of the cleaning solution; alcohol ethoxylate within a range between about 0.035 percent and 0.07 percent by volume of the cleaning solution; triethanol amine within a range between about 0.035 percent and 0.07 percent by volume of the cleaning solution; sodium lauriminodipropionate within a range between about 0.03 percent and 1.0 percent by volume of the cleaning solution. The cleaning solution has a pH value in the range between about 2.5 and about 7.0. 1. A method of cleaning a turbine engine , the method comprising: a first organic acidic component within a range between about 0.1 percent and about 15 percent by volume of the cleaning solution; wherein the organic acid comprises citric acid;', 'a second organic acidic component within a range between about 0.1 percent and about 15 percent by volume of the cleaning solution; wherein the organic acid comprises glycolic acid;', 'isoropylamine sulphonate within a range between about 0.07 percent and 0.14 percent by volume of the cleaning solution;', 'alcohol ethoxylate within a range between about 0.035 percent and 0.07 percent by volume of the cleaning solution;', 'triethanol amine within a range between about 0.035 percent and 0.07 percent by volume of the cleaning solution;', 'sodium lauriminodipropionate within a range between about 0.03 percent and 1.0 percent by volume of the cleaning solution;', 'wherein ...

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28-01-2016 дата публикации

GEL SOLVENT AND METHOD OF REMOVING DIFFUSION AND OVERLAY COATINGS IN GAS TURBINE ENGINES

Номер: US20160024444A1
Принадлежит: UNITED TECHNOLOGIES CORPORATION

A method of stripping an engine component may comprise applying an acidic gel solvent to a coating of a surface of the engine component, leaving the acidic gel solvent on the surface of the engine component for a predetermined duration, and removing the acidic gel solvent from the surface of the engine component. The method may further include mixing an acid with a gelling agent to form the acidic gel solvent. The acid may comprise hydrochloric acid. The gelling agent may comprise a cellulosic material. The gelling agent may comprise a carbohydrate. The method may further include rinsing the acidic gel solvent from the surface of the engine component. The coating may comprise at least one of a diffusion coating or an overlay coating. 1. A method of stripping an engine component , comprising:applying an acidic gel solvent to a coating of a surface of the engine component;leaving the acidic gel solvent on the surface of the engine component for a first duration; andremoving the acidic gel solvent from the surface of the engine component.2. The method of claim 1 , further including mixing an acid with a gelling agent to form the acidic gel solvent.3. The method of claim 2 , wherein the acid comprises hydrochloric acid.4. The method of claim 2 , wherein the gelling agent comprises a cellulosic material.5. The method of claim 2 , wherein the gelling agent comprises a carbohydrate.6. The method of claim 1 , further comprising rinsing the acidic gel solvent from the surface of the engine component.7. The method of claim 1 , wherein the coating comprises at least one of a diffusion coating or an overlay coating.8. The method of claim 1 , wherein the coating comprises aluminum.9. The method of claim 1 , further comprising removing an additive layer of the coating while leaving a diffused layer of the coating.10. The method of claim 1 , wherein the acid comprises a mineral acid.11. The method of claim 1 , further including:determining a thickness of a remainder of the coating ...

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25-01-2018 дата публикации

METHOD FOR PRODUCING NATIONAL-STANDARD MAGNESIUM ALLOY INGOTS ON THE BASIS OF MAGNESIUM ALLOY WASTE MATERIAL

Номер: US20180023164A1
Автор: TAN Heyi, TANG Lunyuan

A method comprises: sorting and removing impurities from magnesium alloy waste material, and cleaning and drying said material, the cleaning comprising high-pressure rinsing, pickling, and water washing, performed in sequence; preheating the magnesium alloy waste material obtained in step a, and adding material, melting, refining, removing impurities, and alloying to obtain a magnesium alloy liquid; casting ingots from the magnesium alloy liquid obtained in step b, to obtain magnesium alloy ingots conforming to national standards. The method directly takes magnesium alloy waste material as a raw material to produce magnesium alloy ingots conforming to national standards; the addition of costly high-purity magnesium is unnecessary, and the number of castings in which the amount of harmful elements meets specifications accounts for 98% or more of the total number of castings; 2% slightly exceed specifications, which does not constitute a severe number of times specifications are exceeded. 1. A method for producing GB-standard magnesium alloy ingots from magnesium alloy waste material , comprising the following steps:Step a. sorting, removing impurities from, cleaning and drying the magnesium alloy waste material, wherein the cleaning involves high-pressure cleaning, pickling, and water rinse performed in sequence;Step b. preheating, melting, refining, removing impurities from, and alloying the magnesium alloy waste material obtained in Step a, so as to obtain magnesium alloy liquid; andStep c. casting ingots using the magnesium alloy liquid obtained in Step b, so as to obtain GB-standard magnesium alloy ingots.2. The method of claim 1 , wherein in Step a claim 1 , the high-pressure cleaning is performed under a pressure of 5 to 20 MPa.3. The method of claim 1 , wherein Step a involves cutting claim 1 , sorting and removing impurities from claim 1 , high-pressure cleaning claim 1 , pickling claim 1 , water rinse and drying the magnesium alloy waste material claim 1 , ...

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10-02-2022 дата публикации

SURFACE TREATMENT OF FLAT PRODUCTS MADE OF ALUMINIUM ALLOYS COMPRISING COLOUR MEASUREMENTS

Номер: US20220042904A1
Принадлежит: Speira GmbH

A method for the surface treatment of flat products made of aluminium alloys. The method includes pickling the flat product, in particular for degreasing the flat product. The method includes carrying out a colour measurement on the surface of the flat product to determine at least one measured colour value after pickling the flat product. The method includes generating output information on the basis of the at least one measured colour value. The output information is indicative of compliance with at least one rule for the measured colour value and outputting or triggering the output of the output information. The invention further relates to a device for the surface treatment of flat products made of aluminium alloys and to a use of a colorimeter which is configured to determine at least one measured colour value in a surface treatment of flat products made of aluminium alloys. 1. Method for the surface treatment of flat products made of aluminium alloys , the method comprising:pickling the flat product;carrying out a colour measurement on the surface of the flat product to determine at least one measured colour value after pickling the flat product;generating output information on the basis of the at least one measured colour value, wherein the output information is indicative of compliance with at least one rule for the measured colour value;outputting or triggering the output of the output information, wherein the output information is characteristic of a need for error search and carrying out the error search; andwherein the output information can provide an indication that there is an error in the process flow, which is not directly attributed to the composition of at least one treatment solution for the pickling.2. Method according to claim 1 , wherein the output information is further characteristic of whether there is compliance with at least one rule parameter of the at least one treatment solution for the pickling of the flat product.3. Method according ...

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29-01-2015 дата публикации

SI-CONTAINING HIGH-STRENGTH COLD ROLLED STEEL SHEET, METHOD OF PRODUCING THE SAME, AND AUTOMOTIVE MEMBERS (AS AMENDED)

Номер: US20150027600A1
Принадлежит: JFE STEEL CORPORATION

A Si-containing high-strength cold rolled steel sheet has a chemical composition comprising C: 0.0˜20.3 mass %, Si: 0.8˜2.0 mass %, Mn: 1.0˜5.0 mass % and the remainder being Fe and inevitable impurities with a ratio of Si content to Mn content (Si/Mn) exceeding 0.4, and has a tensile strength TS of not less than 780 MPa, wherein a metallic structure of the steel sheet surface contains polygonal ferrite and/or bainitic ferrite having a Si concentration of not more than 3.0 mass % and a grain size of not more than 10 μm and does not have a Si-containing oxide layer on the steel sheet surface. 16-. (canceled)7. A Si-containing high-strength cold rolled steel sheet having a chemical composition comprising C: 0.02˜0.3 mass % , Si: 0.8˜2.0 mass % , Mn: 1.0˜5.0 mass % and the remainder being Fe and inevitable impurities with a ratio of Si content to Mn content (Si/Mn) exceeding 0.4 and having a tensile strength TS of not less than 780 MPa , wherein a metallic structure of the steel sheet surface contains polygonal ferrite and/or bainitic ferrite having a Si concentration of not more than 3.0 mass % and a grain size of not more than 10 μm and does not have a Si-containing oxide layer on the steel sheet surface.8. A method for manufacturing a Si-containing high-strength cold rolled steel sheet claim 7 , characterized in that a steel slab having a chemical composition as claimed in is hot rolled claim 7 , cold rolled claim 7 , subjected to a continuous annealing wherein a cooling stop temperature in the cooling after soaking annealing is higher than 300° C. claim 7 , and then pickled to remove a Si-containing oxide layer from the surface of the steel sheet.9. The method for manufacturing a Si-containing high-strength cold rolled steel sheet according to claim 8 , wherein the pickling is conducted by using either one of a mixed acid of nitric acid and hydrochloric acid claim 8 , a mixed acid of hydrofluoric acid and hydrochloric acid claim 8 , and a mixed acid of nitric acid ...

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23-01-2020 дата публикации

FERRITE-BASED STAINLESS STEEL SHEET HAVING LOW SPECIFIC GRAVITY AND PRODUCTION METHOD THEREFOR

Номер: US20200024682A1

This ferritic stainless steel sheet contains, by mass %: C: 0.001% to 0.020%; Si: 0.01% to 4.00%; Mn: 0.01% to 3.00%; P: 0.010% to 0.040%; S: 0.0001% to 0.0100%; Cr: 10.0% to 15.0%; N: 0.001% to 0.020%; Al: 0.50% to 10.0%; and either one or both of Ti: 0.05% to 0.40% and Nb: 0.05% to 0.40%, with the balance being Fe and unavoidable impurities, in which Cr/(Si+Al) is 10.0 or less, and a specific gravity is 7.6 g/cmor less. 1. A ferritic stainless steel sheet having a low specific gravity comprising , by mass %:C: 0.001% to 0.020%;Si: 0.01% to 4.00%;Mn: 0.01% to 3.00%;P: 0.010% to 0.040%;S: 0.0001% to 0.0100%;Cr: 10.0% to 15.0%;N: 0.001% to 0.020%;Al: 0.50% to 10.0%; andeither one or both of Ti: 0.05% to 0.40% and Nb: 0.05% to 0.40%,with the balance being Fe and unavoidable impurities,{'sup': '3', 'wherein Cr/(Si+Al) is 10.0 or less, and a specific gravity is 7.6 g/cmor less.'}2. The ferritic stainless steel sheet having a low specific gravity according to claim 1 ,wherein a precipitation amount of AlN is 0.010% or less by mass %.3. The ferritic stainless steel sheet having a low specific gravity according to claim 1 ,wherein a sum of a maximum value of an Al concentration and a maximum value of a Si concentration in a region from a steel sheet surface to a depth of 5 nm is 15 at % or more.4. The ferritic stainless steel sheet having a low specific gravity according to claim 1 , further comprising one or more of claim 1 , by mass %:Cu: 0.01% to 3.00%;Ni: 0.01% to 2.00%;Mo: 0.01% to 3.00%;V: 0.01% to 0.50%;B: 0.0002% to 0.0050%;Ca: 0.0005% to 0.0100%;W: 0.1% to 3.0%;Zr: 0.01% to 0.10%;Ta: 0.01% to 0.10%;Hf: 0.01% to 0.10%;Sn: 0.005% to 0.50%;Co: 0.03% to 0.30%;Mg: 0.0002% to 0.010%;Sb: 0.005% to 0.50%;REM: 0.002% to 0.20%; andGa: 0.0002% to 0.30%.5. A method for producing the ferritic stainless steel sheet having a low specific gravity according to claim 1 , the method comprising:a step of annealing a cold-rolled sheet; anda pickling step that is performed after the ...

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10-02-2022 дата публикации

Alkaline electrolyte regeneration

Номер: US20220045390A1
Принадлежит: PHINERGY LTD

Methods and systems for electrolyte regeneration are provided, which regenerate a spent alkaline electrolyte (SE) comprising dissolved aluminum hydrates from an aluminum-air battery, by electrolysis, to precipitate aluminum tri-hydroxide (ATH) and form regenerated alkaline electrolyte, and adding a same-cation salt to an anolyte used in the electrolysis to supplant a corresponding electrolyte cation. The regeneration may be carried out continuously and further comprise mixing the SE and the same-cation salt in a salt tank configured to deliver the anolyte, removing the regenerated alkaline electrolyte from a catholyte tank configured to deliver the catholyte, and filtering the ATH from a solution delivered from the salt tank to the anolyte. Optionally, the salt may be a buffering salt, and in some cases chemical reactions may be used to enhance the regeneration by electrolysis.

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24-01-2019 дата публикации

CHEMICAL DECONTAMINATION METHOD USING CHELATE FREE CHEMICAL DECONTAMINATION REAGENT FOR REMOVAL OF THE DENSE RADIOACTIVE OXIDE LAYER ON THE METAL SURFACE

Номер: US20190027263A1
Принадлежит:

A chemical decontamination reagent containing a reducing agent, a reductive metal ion, and an inorganic acid is provided to remove a radioactive oxide layer on a metal surface. The reagent can dissolve the radioactive oxide layer on the metal surface effectively at a relatively low temperature and enables a simple process of contacting the reagent to the radioactive oxide, thus economically effective in terms of cost and time required for the process. Since the decontamination does not use a conventional organic chelating agent such as oxalic acid, but the reducing agent as a main substance, the residuals of the reducing agent remained after decontamination can be decomposed and removed with an oxidizing agent. Due to the easy decomposition with the chemical decontamination reagent, secondary wastes can be minimized and the radionuclides remained in the decontamination reagent solution can be removed effectively. 1. A chemical decontamination method , comprising a step of contacting chemical decontamination reagent to a metal of a nuclear power plant covered with a dense radioactive oxide layer at temperature range of 70° C. to 140° C. and pH range of 1.0 to 3.7 ,Wherein the chemical decontamination reagent comprises a reducing agent, a reductive metal ion, and an acid, the acid consisting only inorganic acid, for removal of a dense radioactive oxide layer on a metal surface, and{'sub': 2', '4', '3', '2', '4, 'sup': '+', 'wherein the reducing agent is NH, the reductive metal ion is Cu, and the inorganic acid is HNOor HSO.'}2. The chemical decontamination method according to claim 1 , wherein the metal is one or more selected from the group consisting of stainless steel claim 1 , Inconel steel claim 1 , and zirconium alloy.3. The chemical decontamination method according to claim 1 , wherein the concentration of the reducing agent is in the range of 5×10-0.5 M.4. The chemical decontamination method according to claim 1 , wherein the concentration of the reductive ...

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02-02-2017 дата публикации

METHOD FOR MANUFACTURING MICROPORE FILTER

Номер: US20170028474A1
Принадлежит: Pureron Japan Co., Ltd.

Provided is a method for manufacturing a micropore filter usable as SCE. Stainless steel particles having particle diameters of 3 to 60 μm are subjected to milling in a bead mill using zirconia beads to prepare powder having a flakiness of 0.03 to 0.4. The zirconia adhered to the surface of the powder is removed by pickling. A load of 10 to 15 kN is applied to 0.5 to 1.0 g of the pickled powder, thereby compacting the powder into a columnar compact body. The compact body is kept and fired in a vacuum atmosphere of 10to 10Pa at a temperature of 1000 to 1300° C. for 1 to 3 hours to form a sintered body. The sintered body is pressed into a pipe having an inner diameter of 0.90 to 0.99 times of the outer diameter of the sintered body, and extruded to obtain a micropore filter. 1a step of treating stainless steel particles having particle diameters in a range of 3 to 60 μm in a bead mill using zirconia beads to prepare powder having a flakiness expressed by a ratio of a thickness with respect to a long diameter (thickness/long diameter) in a range of 0.03 to 0.4;a step of pickling the powder to remove zirconia adhered to a surface of the powder due to treatment in the bead mill;a step of applying a load of 10 to 15 kN to 0.5 to 1.0 g of the powder after the pickling, thus compacting the powder to obtain a compact body having a columnar shape;{'sup': −5', '−3, 'a step of keeping the compact body in a vacuum atmosphere in a range of 10to 10Pa at a temperature in a range of 1000 to 1300° C. for 1 to 3 hours, thus firing the compact body to obtain a sintered body; and'}a step of pressing the sintered body into a pipe having an inner diameter in a range of 0.90 to 0.99 times of an outer diameter of the sintered body, and extruding the sintered body.. A method for manufacturing a micropore filter comprising: The present invention relates to a method of manufacturing a micropore filter used for calibration of vacuum gauges such as ionization vacuum gauges and diaphragm vacuum ...

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01-02-2018 дата публикации

Gold evaporative sources with reduced contaminants and methods for making the same

Номер: US20180029096A1
Принадлежит: Praxair ST Technology Inc

A unique sequence of steps is provided to reduce contaminants along one or more surfaces and faces of gold evaporative sources without deleteriously impacting the structure of the gold evaporative sources. Edges are deburred; contaminants are successfully removed therealong; and surface smoothness is substantially retained. The resultant gold evaporative source is suitable for use in evaporative processes as a precursor to gold film deposition without the occurrence or a substantial reduction in the likelihood of spitting by virtue of significantly reduced levels of contaminants, in comparison to gold evaporative sources subject to a standard cleaning protocol.

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31-01-2019 дата публикации

TITANIUM PLATE

Номер: US20190032182A1
Принадлежит:

A titanium plate is provided in which a Vickers hardness Hvat a load of 0.245 N at a surface is 150 or less, and an average length of the profile elements RSm is 80 μm or less and a maximum height Rz is less than 1.5 μm, RSm and Rz being as defined in JIS B 0601: 2013. The titanium plate has good surface deformability. 1. A titanium plate , wherein:{'sub': '0.025', 'a Vickers hardness Hvat a load of 0.245 N at a surface is 150 or less, and an average length of profile elements RSm is 80 μm or less and Rz is less than 1.5 μm, RSm and Rz being as defined in JIS B 0601: 2013.'}2. The titanium plate according to claim 1 , wherein:when a carbon concentration at a depth of 5 μm from the surface is represented by “Cs”, and a carbon concentration at a depth of 20 μm from the surface is represented by “Cb”, Cs/Cb is in a range of values less than 2.0. The present invention relates to a titanium plate.Because of their excellent corrosion resistance, titanium plates are used as the starting material for heat exchangers in various plants such as chemical plants, power plants and food processing plants. For a plate-type heat exchanger, among others, it is intended to raise the heat exchanging efficiency by increasing the surface area of a titanium sheet by forming recesses and protrusions in the sheet by press forming, which requires excellent formability.Patent Document 1 discloses a technique including: forming an oxide film and a nitride film by heating in an oxidizing atmosphere or a nitriding atmosphere; thereafter performing bending or pulling out to introduce fine cracks into these films and to expose the titanium metal; and thereafter scarfing in an acid aqueous solution in which titanium metal is soluble to form dense and deep irregularities. Patent Document 1 discloses that the oil retainability of a lubricating oil increases and the lubricity improves, and that by causing an oxide film and a nitride film to remain on the surface or by the formation thereof, the ...

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01-02-2018 дата публикации

Method of decontaminating metal surfaces in a cooling system of a nuclear reactor

Номер: US20180033506A1
Принадлежит: AREVA GMBH

A method of decontaminating metal surfaces in a cooling system of a nuclear reactor comprises conducting a plurality of treatment cycles, with each of the treatment cycles comprising: an oxidation step wherein metal oxides including radioisotopes on the metal surfaces are contacted with an aqueous solution of a permanganate oxidant; a decontamination step after the oxidation step wherein the metal oxides are contacted with an aqueous solution of an organic acid selected from the group consisting of oxalic acid, formic acid, citric acid, tartaric acid, picolinic acid, gluconic acid, glyoxylic acid and mixtures thereof so as to dissolve at least part of the metal oxides and the radioisotopes; and a cleaning step wherein at least the radioisotopes are immobilized on an ion exchange resin; wherein the oxidation step comprises at least one acidic oxidation step and at least one alkaline oxidation step carried out one after another in either the same or different treatment cycles; and wherein the plurality of treatment cycles comprises at least one treatment cycle including a high temperature oxidation step, wherein the permanganate oxidant solution is kept at a temperature of at least 100° C. and, wherein the at least one reactor coolant pump is used to circulate and heat the oxidation solution inside the primary loop, and the residual heat removal system is used to control the temperature of the oxidant solution during the high temperature oxidation step.

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30-01-2020 дата публикации

Process for manufacturing cold-rolled and annealed steel sheet with a very high strength, and sheet thus produced

Номер: US20200032366A1
Принадлежит: ArcelorMittal SA

A process for manufacturing a cold-rolled steel sheet with a strength of at least 1200 MPa and an elongation at break greater than 10%. A steel is provided having a microstructure comprising 65 to 90% bainite. A semifinished product is cast from the steel and heated to a temperature greater than 1150° C. The semifinished product is hot rolled to obtain a hot-rolled sheet; the coiled and pickled. Cold-rolling occurs with a reduction ratio of between 30 and 80% so as to obtain a cold-rolled sheet; and then reheating occurs at a rate V c between 5 and 15° C./s up to a temperature T 1 between Ac3 and Ac3+20° C. and held at said temperature T 1 for a time t 1 between 50 and 150 s. The sheet is cooled at a rate V R1 greater than 40° C./s but below 100° C./s down to a temperature T 2 between (M s −30° C. and M s +30° C.). The sheet is maintained at temperature T 2 for a time t 2 between 150 and 350 s, and then cooled at a rate V R2 of less than 30° C./s down to an ambient temperature.

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30-01-2020 дата публикации

NOVEL CORROSION INHIBITION PACKAGE

Номер: US20200032400A1
Принадлежит:

An inhibition corrosion package for use with an acidic composition, where the package comprises a terpene component; a propargyl alcohol or derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are acidic compositions combining the corrosion inhibition package according to a preferred embodiment of the present invention for use in various industrial operations including but not limited to oil and gas operations. Also disclosed are methods of use of such compositions. 1. A corrosion inhibition package for use with an aqueous acid composition , said package comprising:a terpene;a propargyl alcohol or derivative thereof;at least one amphoteric surfactant; anda solvent.2. The corrosion inhibition package as claimed in claim 1 , wherein the terpene is selected from the group consisting of:citral;ionone;ocimene; andcymene.3. The corrosion inhibition package as claimed in claim 1 , wherein the at least one amphoteric surfactant is selected from the group consisting of:a sultaine surfactant; a betaine surfactant; and combinations thereof.4. The corrosion inhibition package as claimed in claim 3 , wherein the sultaine surfactant and betaine surfactant are selected from the group consisting of:an amido betaine surfactant; an amido sultaine surfactant; and combinations thereof.5. The corrosion inhibition package as claimed in claim 4 , wherein the amido betaine surfactant and is selected from the group consisting of:an amido betaine comprising a hydrophobic tail from C8 to C16.6. The corrosion inhibition package as claimed in claim 5 , wherein the amido betaine surfactant comprising a hydrophobic tail from C8 to C16 is cocamidobetaine7. The corrosion inhibition package as claimed in claim 1 , further comprising an anionic surfactant.8. The corrosion inhibition package as claimed in claim 7 , wherein the anionic surfactant is a carboxylic surfactant or a sulfonic surfactant.9. The corrosion inhibition package as claimed in claim 8 , wherein the ...

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30-01-2020 дата публикации

Compositions and Methods for Activating Titanium Substrates

Номер: US20200032411A1
Принадлежит: The Boeing Company

A method for pretreating a substrate prior to depositing a material thereon, the method including immersing the substrate in an activation solution for a predetermined period of time, the activation solution including a fluoride salt, hydrofluoric acid, sulfuric acid and water. 1. An activation solution comprising:water;a fluoride salt;hydrofluoric acid; andsulfuric acid.2. The activation solution of wherein the fluoride salt comprises at least one of an alkali metal cation and an alkaline earth metal cation.3. The activation solution of wherein the fluoride salt comprises at least one of potassium fluoride claim 1 , lithium fluoride claim 1 , sodium fluoride claim 1 , rubidium fluoride claim 1 , barium fluoride and strontium fluoride.4. The activation solution of wherein the fluoride salt is potassium fluoride.5. The activation solution of wherein the fluoride salt is present at a concentration ranging from about 5 grams per liter to about 120 grams per liter claim 1 , based on a total volume of the activation solution.6. The activation solution of wherein the fluoride salt is present at a concentration ranging from about 10 grams per liter to about 100 grams per liter claim 1 , based on a total volume of the activation solution.7. The activation solution of wherein the fluoride salt is present at a concentration of about 20 grams per liter claim 1 , based on a total volume of the activation solution.8. The activation solution of wherein the hydrofluoric acid is present at a concentration ranging from about 5 milliliters per liter to about 250 milliliters per liter claim 1 , based on a total volume of the activation solution.9. The activation solution of wherein the hydrofluoric acid is present at a concentration ranging from about 20 milliliters per liter to about 150 milliliters per liter claim 1 , based on a total volume of the activation solution.10. The activation solution of wherein the sulfuric acid is present at a concentration ranging from about 1 percent ...

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04-02-2021 дата публикации

FERRITIC STAINLESS STEEL SHEET AND PRODUCTION METHOD THEREOF, AND FERRITIC STAINLESS MEMBER

Номер: US20210032718A1

A ferritic stainless steel sheet is provided that has a chemical composition consisting of, in mass %, C: 0.001 to 0.020%, Si: 0.02 to 1.50%, Mn: 0.02 to 1.50%, P: 0.01 to 0.05%, S: 0.0001 to 0.01%, Cr: 10.0 to 25.0%, Ti: 0.01 to 0.30%, N: 0.001 to 0.030%, and optional elements, with the balance being Fe and unavoidable impurities, wherein: a grain size number is 6 or more; the ferritic stainless steel sheet satisfies the formulas [A+B≥12.0/t], [X+Y≥12.0/(t−0.3)] and [(X+Y)−(A+B)≤5.0] with respect to crystal orientation intensities of a ferrite phase obtained by X-ray diffraction; and the sheet thickness is 1.0 mm or more. 1. A ferritic stainless steel sheet , comprising a chemical composition consisting of , in mass % ,C: 0.001 to 0.020%,Si: 0.02 to 1.50%,Mn: 0.02 to 1.50%,P: 0.01 to 0.05%,S: 0.0001 to 0.01%,Cr: 10.0 to 25.0%,Ti: 0.01 to 0.30%,N: 0.001 to 0.030%,Nb: 0 to less than 0.10%,Sn: 0 to 0.500%,Mg: 0 to 0.0100%,B: 0 to 0.0050%,V: 0 to 1.0%,Mo: 0 to 3.0%,W: 0 to 3.0%,Al: 0 to 0.5%,Cu: 0 to 2.0%,Zr: 0 to 0.30%,Co: 0 to 0.50%,Sb: 0 to 0.50%,REM: 0 to 0.05%,Ni: 0 to 2.0%,Ca: 0 to 0.0030%,Ta: 0 to 0.10%,Ga: 0 to 0.1%, andthe balance: Fe and unavoidable impurities,wherein:a grain size number is 6.0 or more,the ferritic stainless steel sheet satisfies formula (i), formula (ii) and formula (iii) described hereunder with respect to crystal orientation intensities of a ferrite phase obtained by X-ray diffraction, [{'br': None, 'i': A+B≥', 't, '12.0/\u2003\u2003(i)'}, {'br': None, 'i': X+Y≥', 't−, '12.0/(0.3)\u2003\u2003(ii)'}, {'br': None, 'i': X+Y', 'A+B, '()−()≤5.0\u2003\u2003(iii)'}], 'and a sheet thickness is 1.0 mm or more;'}where, each symbol in the above formulas is defined as follows:t: sheet thickness (mm)A: a {111}<112> crystal orientation intensity at a center portion of sheet thicknessB: a {111}<112> crystal orientation intensity at a ¼ portion of the sheet thicknessX: a {322}<236> crystal orientation intensity at a center portion of sheet thicknessY: a { ...

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04-02-2021 дата публикации

CORROSION INHIBITOR COMPOSITION AND METHODS OF INHIBITING CORROSION DURING ACID PICKLING

Номер: US20210032759A1

A corrosion inhibitor composition, which includes i) an aqueous alcohol base fluid, ii) a mixture of at least three polysaccharides selected from carboxymethyl cellulose, gum arabic, pectin, a salt of alginic acid, chitosan, dextran, hydroxyethyl cellulose, and soluble starch, with each polysaccharide that is present in the mixture being present in an amount of 0.05 to 0.5 wt. %, based on a total weight of the corrosion inhibitor composition, iii) silver nanoparticles, and iv) a pineapple leaves extract. A method of inhibiting corrosion of metal during acid cleaning/pickling whereby the metal is treated with an acidic treatment fluid containing an acid and the corrosion inhibitor composition. 1. A corrosion inhibitor composition , comprising:a base fluid comprising water and an alcohol;a mixture of at least three polysaccharides selected from the group consisting of carboxymethyl cellulose, gum arabic, pectin, a salt of alginic acid, chitosan, dextran, hydroxyethyl cellulose, and soluble starch, with each polysaccharide that is present in the mixture being present in an amount of 0.05 to 0.5 wt. %, based on a total weight of the corrosion inhibitor composition;silver nanoparticles; anda pineapple leaves extract.2. The corrosion inhibitor composition of claim 1 , wherein the alcohol is a monoalcohol.3. The corrosion inhibitor composition of claim 1 , wherein the alcohol is isopropanol.4. The corrosion inhibitor composition of claim 1 , wherein a ratio of water to the alcohol by volume is 2:1 to 1:2.5. The corrosion inhibitor composition of claim 1 , wherein three polysaccharides are present in the mixture.6. The corrosion inhibitor composition of claim 5 , wherein each of the three polysaccharides is present in an amount of 30 to 40 wt. % claim 5 , based on a total weight of the mixture.7. The corrosion inhibitor composition of claim 1 , wherein the mixture consists of carboxymethyl cellulose claim 1 , gum arabic claim 1 , and pectin.8. The corrosion inhibitor ...

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09-02-2017 дата публикации

METHOD AND FORMULATIONS FOR REMOVING RUST AND SCALE FROM STEEL AND FOR REGENERATING PICKLING LIQUOR IN HOT-DIP GALVANIZATION PROCESS

Номер: US20170037520A1
Принадлежит: GREEN FUTURE LTD.

This invention provides a cost-effective hot-dip galvanization process for ferrous metals, which is regardful to the environment and to the health of the personnel. 1. A hot-dip galvanization process for stabilizing the surface of ferrous metals comprising steps ofi) removing metal oxide scales and rust from said surface, comprising contacting said surface with a liquid composition comprising phosphoric acid, a hydrophilic polymer, a non-ionic surfactant, and an anti-smut agent (said liquid composition being denoted GF2), wherein said GF2 solubilizes iron oxides forming said scales and rust without solubilizing non-oxidized metal in said surface, thereby preparing said surface for zinc-coating; andii) binding the solubilized iron from said GF2 in an insoluble iron oxalate complex by contacting said GF2 with a solid composition comprising oxalic acid, a nucleation crystallization agent, and an anionic surfactant (said solid composition being denoted GF1), and removing said insoluble iron oxalate complex from said liquid composition, thereby releasing phosphoric acid in GF2 for further use;wherein the use of GF2 in said step i) enables to avoid the formation of dangerous gaseous side products during said surface stabilizing, and to make a uniform and thin zinc coating during said zinc-coating, and wherein the use of GF1 in said step ii) enables to recover and recycle phosphoric acid;wherein the combination of steps i) and ii) results in an environmentally safe and cost-effective hot-dip galvanization process.2. The process of claim 1 , wherein said GF2 comprises 7-40 wt % phosphoric acid claim 1 , 0.5-3 wt % hydrophilic polymer claim 1 , 0.1-1 wt % non-ionic surfactant claim 1 , and 0.05-0.5 wt % anti-smut agent.3. The process of claim 1 , wherein said GF1 comprises 96.5-99 wt % oxalic acid dihydrate claim 1 , 1-3 wt % of iron oxide as the nucleation agent claim 1 , and 0.05-0.5 wt % of the anionic surfactant.4. The process of claim 1 , wherein said hydrophilic ...

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08-02-2018 дата публикации

HIGH-STRENGTH COLD-ROLLED STEEL SHEET AND METHOD OF PRODUCING THE SAME

Номер: US20180037969A1
Принадлежит:

A steel sheet contains C: 0.15% to 0.22%, Si: 1.0% to 2.0%, Mn: 1.7% to 2.5%, P: 0.05% or less, S: 0.02% or less, Al: 0.01% to 0.05%, N: 0.005% or less, O: 0.01% or less, and the balance being iron and unavoidable impurities while satisfying [Si]/[Mn]≧0.5 ([Si] and [Mn] represent Si and Mn contents, wherein the steel sheet has a structure including, in terms of area fraction, 60% to less than 100% of tempered martensite, 5% or less including 0% of untransformed austenite, and the balance being ferrite, and the ferrite has an average crystal grain size of less than 3.5 μm, wherein less than 10 particles/100 μmof Si—Mn compound oxide particles having a circle equivalent diameter of 5 μm or less are present on a surface of the steel sheet, and the surface is covered with Si-based oxide at a coverage of 1% or less. 19- (canceled)11. The high-strength cold-rolled steel sheet according to claim 10 , wherein the composition further comprises at least one element selected from at least one group consisting of claim 10 , in terms of % by mass claim 10 ,group I: Ti: 0.010% or more and 0.020% or less,group II: Nb: 0.02% or more and 0.10% or less,group III: B: 0.0002% or more and 0.0020% or less,group IV: at least one selected from V: 0.01% or more and 0.30% or less, Mo: 0.01% or more and 0.30% or less, and Cr: 0.01% or more and 0.30% or less,group V: at least one selected from Cu: 0.01% or more and 0.30% or less and Ni: 0.01% or more and 0.30% or less, andgroup VI: at least one selected from Sn: 0.001% or more and 0.100% or less, Sb: 0.001% or more and 0.100% or less, Ca: 0.0002% or more and 0.0100% or less, W: 0.01% or more and 0.10% or less, Co: 0.01% or more and 0.10% or less, and REM: 0.0002% or more and 0.0050% or less.12. A method of producing a high-strength cold-rolled steel sheet claim 10 , comprising:{'claim-ref': {'@idref': 'CLM-00010', 'claim 10'}, 'heating a steel having the composition according to to a temperature of 1,200° C. or higher, performing hot rolling ...

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24-02-2022 дата публикации

Method for manufacturing a composite of aluminum alloy

Номер: US20220055346A1
Принадлежит: Taisei Purasu Co Ltd

An aluminum alloy material is prepared that has surface configuration of threefold irregularities such that rough surface having surface roughness of 10 to 100 μm period is observed with an electron microscope in a magnification of 1000 times, surface having fine irregularities of 1 to 5 μm period based on crystal grain boundary is observed with an electron microscope in a magnification of 10000 times and surface having ultrafine irregularities of 30 to 100 nm period is confirmed with an electron microscope in a magnification of 100000 times. Aluminum alloy material is integrally joined with a resin composition consisting of a total resin part containing polyphenylene sulfide resin by 70 mass % or more of the resin part, modified polyolefin resin by 30 mass % or less of the resin part and a resin of third component having ability for promoting compatibility of polyphenylene sulfide resin and modified polyolefin resin.

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24-02-2022 дата публикации

AQUEOUS CLEANING SOLUTION FOR REMOVAL OF ROUGING DEPOSITS ON MEDIA-CONTACTED SURFACES OF STAINLESS STEELS, USE THEREOF AND PROCESS FOR PRODUCTION THEREOF

Номер: US20220056381A1
Принадлежит:

An aqueous cleaning solution for removing rouging deposits on media-contacted surfaces of stainless steels comprises a first component and a second component. The first component is an alkali sulfite and the second component is an alkali formate, wherein the concentrations thereof are adjusted in such manner that formate is present in a molar ratio of 1.5 to 4.2 relative to sulfite, and that the pH value of the cleaning solution is 4.0 to 4.8. For preparing the aqueous cleaning solution, an aqueous solution of an alkali hydroxide is provided initially, thereafter a first amount of concentrated aqueous formic acid is admixed in an excess in such manner that a pH value of 3.5 to 4.5 is established, then a second amount of solid alkali sulfite is admixed in accordance with the sulfite concentration to be established, thus resulting in a pH value of 5.5 to 6.5, and finally a third amount of concentrated aqueous formic acid is admixed until a pH value of 4.0 to 4.8 is attained. 1. An aqueous cleaning solution comprising:a first component and a second component,wherein the first component is an alkali sulfite and the second component is an alkali formate,wherein the concentrations of the first component and second component are adjusted such that formate is present in a molar ratio of 1.5 to 4.2 relative to sulfite, and that the pH value of the cleaning solution is 4.0 to 4.8,wherein the aqueous cleaning solution is adapted to remove rouging deposits on media-contacted surfaces of stainless steels.2. The aqueous cleaning solution according to claim 1 , wherein the molar ratio of formate relative to sulfite is 3.0 to 4.2 and the pH value of the cleaning solution is 4.1 to 4.5.3. The aqueous cleaning solution according to claim 1 , wherein the alkali sulfite is sodium sulfite and the alkali formate is sodium formate.4. The aqueous cleaning solution according to claim 1 , wherein the sulfite is present in a concentration of 0.05 to 1.5 mol/kg.5. Method for removing rouging ...

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07-02-2019 дата публикации

DEVICE AND METHOD FOR HYDROGEN PRODUCTION WITH WASTE ALUMINUM, AND METHOD FOR HYDROGEN PRODUCTION WITH ALUMINUM

Номер: US20190039888A1
Автор: Ho Ching-Yuan
Принадлежит: CHUNG YUAN CHRISTIAN UNIVERSITY

A device for hydrogen production with waste aluminum includes a treatment apparatus for waste aluminum and a reaction tank. The apparatus includes a first crusher, a pickling tank, and a second crusher. The first crusher is for preliminarily crushing waste aluminum to obtain first aluminum chips. The pickling tank is for receiving and pickling the first aluminum chips crushed by the first crusher. The second crusher is for receiving and fine crushing the first aluminum chips to obtain second aluminum chips. The second aluminum chips are received by the reaction tank and then hydrolyzed with an alkaline solution in the reaction tank to produce hydrogen. Since waste aluminum is used as the raw material of hydrogen production, and a specific device is used for waste aluminum treatment, so the effects of recovering waste metal, reducing environmental damage, and saving costs can be achieved at the same time. 1. A device for hydrogen production with a waste aluminum , comprising: a first crusher for preliminarily crushing the waste aluminum to obtain first aluminum chips;', 'a pickling tank for receiving and pickling the first aluminum chips crushed by the first crusher; and', 'a second crusher for receiving and performing a fine crushing on the first aluminum chips pickled by the pickling tank to obtain second aluminum chips; and, 'a treatment apparatus for the waste aluminum, comprisinga reaction tank for receiving the second aluminum chips obtained from the treatment apparatus to hydrolyze the second aluminum chips with an alkaline solution in the reaction tank.2. The device for hydrogen production with the waste aluminum of claim 1 , wherein the treatment apparatus for the waste aluminum further comprises a stamping device for receiving and stamping the second aluminum chips crushed by the second crusher.3. The device for hydrogen production with the waste aluminum of claim 1 , further comprises an anti-corrosion layer is disposed on an inner surface of the reaction ...

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07-02-2019 дата публикации

Reduced Corrosion Iron Sulfide Scale Removing Fluids

Номер: US20190040300A1
Принадлежит: Saudi Arabian Oil Company

A low-corrosivity composition suitable for dissolving scale on metals. The scale includes iron sulfide scale. The composition includes an aqueous hydrogen peroxide solution comprising hydrogen peroxide; and an acidic solution comprising at least one acid, where the hydrogen peroxide and acid are present at concentrations such that the hydrogen peroxide does not break down to form visible bubbles at about room temperature, where the hydrogen peroxide and acid are present at concentrations such that iron sulfide scale is removed from a metal with iron sulfide scale, after the composition contacts the metal and iron sulfide scale at an elevated temperature greater than room temperature, and where the hydrogen peroxide and acid are present at concentrations such that pitting is not caused on the metal, the metal comprising carbon steel. 1. A low-corrosivity composition suitable for dissolving scale on metals , where the scale comprises iron sulfide scale , the composition comprising:an aqueous hydrogen peroxide solution comprising hydrogen peroxide; and where the hydrogen peroxide and acid are present at concentrations such that iron sulfide scale is removed from a metal with iron sulfide scale, after the composition contacts the metal and iron sulfide scale at an elevated temperature greater than room temperature, and', 'where the hydrogen peroxide and acid are present at concentrations such that pitting is not caused on the metal, the metal comprising carbon steel., 'an acidic solution comprising at least one acid, where the hydrogen peroxide and acid are present at concentrations such that the hydrogen peroxide does not break down to form visible bubbles at about room temperature,'}2. The composition according to claim 1 , further comprising a hydrogen peroxide stabilizer.3. The composition according to claim 2 , where the hydrogen peroxide stabilizer is selected from the group consisting of: stannates; acetanilide; phenol; pyrophosphates; nitrate; organophosphonates ...

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16-02-2017 дата публикации

Method of making sound interface in overcast bimetal components

Номер: US20170043394A1
Принадлежит: GM GLOBAL TECHNOLOGY OPERATIONS LLC

A method of forming a bi-metallic casting. The method includes providing a metal preform of a desired base shape defining a substrate surface and removing a natural oxide layer and surface contamination from the substrate surface to yield a cleaned metal preform. The method further includes galvanizing the cleaned metal preform, yielding a galvanized metal preform followed by electroplating a thin nickel film on at least a portion of the substrate surface of the galvanized metal preform. Additionally, the method includes metallurgically bonding the portion of the metal preform having the nickel film with an overcast metal to form a bi-metallic casting. The nickel film promotes a metallurgical bond between the metal preform and the overcast metal.

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18-02-2021 дата публикации

System for Treating A Metal Substrate

Номер: US20210047737A1
Принадлежит: PPG Industries Ohio, Inc.

Disclosed is a system for treating a substrate surface. The system includes a conditioner composition and a first pretreatment composition. The conditioner composition comprises a hydroxide source and the first pretreatment composition comprises a magnesium element, a halide element, and an oxidizing agent. Methods of treating a substrate surface using the conditioner composition and the first pretreatment composition also are disclosed. Also disclosed are substrates treated with the system and method. 1. A system for treating a metal substrate , comprising:a conditioner composition comprising a hydroxide source; anda first pretreatment composition comprising a magnesium element, a halide element, and an oxidizing agent.2. The system of claim 1 , wherein the conditioner composition has a pH of 9.0 to 13.5.3. The system of claim 1 , wherein the magnesium element and the halide element are derived from a single source.4. The system of claim 1 , wherein the magnesium element is derived from a first source and the halide element is derived from a second source.5. The system of claim 1 , wherein the magnesium element is present in the first pretreatment composition in an amount of 500 ppm to 6 claim 1 ,000 ppm based on total weight of the first pretreatment composition.6. The system of claim 1 , wherein the halide element is present in the first pretreatment composition in an amount of 3000 ppm to 40 claim 1 ,000 ppm based on total weight of the first pretreatment composition.7. The system of claim 1 , wherein the oxidizing agent is present in the first pretreatment composition in an amount of 100 ppm to 3 claim 1 ,000 ppm based on total weight of the first pretreatment composition.8. The system of claim 1 , wherein the first pretreatment composition has a pH of 1.0 to 7.0.9. The system of claim 1 , further comprising a cleaning composition.10. The system of claim 1 , further comprising a deoxidizer.11. The system of claim 1 , further comprising a second pretreatment ...

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16-02-2017 дата публикации

FILAMENT FOR HIGH STRENGTH STEEL CORD

Номер: US20170044642A1

A filament for a high strength steel cord has a wire diameter R of 0.1 mm to 0.4 mm, and includes, in a chemical composition, by mass %: C: 0.70% to 1.20%; Si: 0.15% to 0.60%; Mn: 0.10% to 1.00%; N: 0.0010% to 0.0050%; Al: more than 0% and 0.0100% or less; and a remainder of Fe and impurities, in which a surface part and a central part are included, a thickness of the surface part is 0.01×R to 0.10×R, the central part includes a pearlite structure in a proportion of 95% to 100% by area %, a C content of the surface part is 40% to 95% of a C content of the central part, and a ratio of a thickness of a lamellar cementite at a center of the thickness of the surface part to a thickness of a lamellar cementite in the central part is 95% or less, whereby high strength and workability can be achieved and cracking or the like caused by a delamination phenomenon can be prevented. 1. A filament for a high strength steel cord , which has a wire diameter R of 0.1 mm to 0.4 mm , comprising , in a chemical composition , by mass %:C: 0.70% to 1.20%;Si: 0.15% to 0.60%;Mn: 0.10% to 1.00%;N: 0.0010% to 0.0050%;Al: more than 0% and 0.0100% or less; anda remainder of Fe and impurities,wherein a surface part and a central part are included, the surface part covers the central part,a thickness of the surface part is 0.01×R to 0.10×R,the central part includes a pearlite structure in a proportion of 95% to 100% by area %,a C content of the surface part is 40% to 95% of a C content of the central part, anda ratio of a thickness of a lamellar cementite at a center of the thickness of the surface part to a thickness of a lamellar cementite in the central part is 95% or less.2. The filament for a high strength steel cord according to claim 1 , further comprising claim 1 , in the chemical composition claim 1 , by mass % claim 1 ,one or two or more ofTi: more than 0% and 0.1000% or less,Cr: more than 0% and 0.5000% or less,Co: more than 0% and 0.5000% or less,V: more than 0% and 0.5000% or less, ...

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15-02-2018 дата публикации

STEEL SHEET FOR HOT STAMPING AND METHOD FOR PRODUCING STEEL SHEET FOR HOT STAMPING, AND HOT STAMP FORMED BODY

Номер: US20180044754A1

A steel sheet for hot stamping includes a composition including at least, in mass %, C: 0.100% to 0.600%, Si: 0.50% to 3.00%, Mn: 1.20% to 4.00%, Ti: 0.005% to 0.100%, B: 0.0005% to 0.0100%, P: 0.100% or less, S: 0.0001% to 0.0100%, Al: 0.005% to 1.000%, and N: 0.0100% or less, with a balance of Fe and impurities, surface roughness of the steel sheet satisfies Rz>2.5 μm, and 50 mg/mto 1500 mg/mof coating oil is applied to a surface. 1. A steel sheet for hot stamping , comprising a composition containing:in mass %,C: 0.100% to 0.600%;Si: 0.50% to 3.00%;Mn: 1.20% to 4.00%;Ti: 0.005% to 0.100%;B: 0.0005% to 0.0100%;P: 0.100% or less;S: 0.0001% to 0.0100%;Al: 0.005% to 1.000%;N: 0.0100% or less;Ni: 0% to 2.00%;Cu: 0% to 2.00%;Cr: 0% to 2.00%;Mo: 0% to 2.00%;Nb: 0% to 0.100%;V: 0% to 0.100%;W: 0% to 0.100%, anda total of one kind or two or more kinds selected from a group consisting of REM, Ca, Ce and Mg: 0% to 0.0300%,with a balance being Fe and impurities,{'sup': 2', '2, 'wherein surface roughness of the steel sheet satisfies Rz>2.5 μm, and coating oil in an amount of 50 mg/mto 1500 mg/mis applied onto a surface.'}2. The steel sheet for hot stamping according to claim 1 ,wherein an amount of S contained in the coating oil which is applied onto the steel sheet is 5% or less in mass %.3. The steel sheet for hot stamping according to claim 1 ,wherein the composition of the steel sheet contains, in mass %,one kind or two or more kinds selected from a group consisting ofNi: 0.01% to 2.00%,Cu: 0.01% to 2.00%,Cr: 0.01% to 2.00%,Mo: 0.01% to 2.00%,Nb: 0.005% to 0.100%,V: 0.005% to 0.100%, andW: 0.005% to 0.100%.4. The steel sheet for hot stamping according to claim 1 ,wherein the composition of the steel sheet contains, in mass %,a total of 0.0003% to 0.0300% of one kind or two or more kinds selected from the group consisting of REM, Ca, Ce and Mg.5. A method for producing a steel sheet for hot stamping claim 1 , comprising:a step of casting a slab containing,in mass %,C: 0. ...

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08-05-2014 дата публикации

Method for producing electrodes

Номер: US20140123999A1
Автор: Tim Schaefer
Принадлежит: Li Tec Battery GmbH

The invention relates to a method for producing an electrode, in particular a negative electrode, of an electrochemical cell having a metal substrate, wherein the method includes the steps of treating the metal substrate with UV irradiation and treating the metal substrate using an organic acid.

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13-02-2020 дата публикации

ALLOY SURFACE ACTIVATION BY IMMERSION IN AQUEOUS ACID SOLUTION

Номер: US20200048774A1
Принадлежит:

A process for surface activation or depassivation of an article, in particular an alloy, by immersion of the alloy in an aqueous acid solution. The surface activation methods of the present invention can be performed during a relatively short period of time and achieve reductions in production costs and provide environmental friendliness as compared to prior art processes. In a further embodiment, after surface activation, the article is immersed in a second liquid that prevents re-formation of a passivating oxide layer on the surface of the article. In a further embodiment the surface-activated alloys are subjected to surface engineering by a process that infuses carbon or nitrogen through the surface at a temperature sufficiently low to suppress precipitation of carbides or nitrides. 1. A surface activated article-containing composition , comprising:an article having at least one portion of its surface activated; anda liquid covering the at least one portion for temporarily preventing the formation of a passivating layer on the at least one activated portion, the liquid comprising one or more of an aqueous acid, a fatty acid, an alcohol, water, and oil.2. The composition according to claim 1 , wherein the liquid comprises the aqueous acid.3. The composition according to claim 1 , wherein the liquid comprises one or more of the alcohol claim 1 , the fatty acid claim 1 , the oil claim 1 , and the water.4. The composition according to claim 2 , wherein the article is immersed in the liquid.5. The composition according to claim 3 , wherein the article is immersed in the liquid.6. The composition according to claim 1 , wherein the article comprises one or more of stainless steel claim 1 , a nickel-base alloy claim 1 , a cobalt-base alloy claim 1 , and a titanium-base alloy.7. The composition according to claim 6 , wherein the article comprises stainless steel. This invention was made with Government support under Contract No. NEUP-3451 awarded by the Department of ...

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22-02-2018 дата публикации

SEPARATOR FOR POLYMER ELECTROLYTE FUEL CELL AND METHOD FOR PRODUCING THE SAME

Номер: US20180053948A1
Автор: TARUTANI Yoshio
Принадлежит:

There is provided a separator for polymer electrolyte fuel cells having a substrate of a ferritic, having a chemical composition comprising, in mass %, C: 0.001 to 0.012%, Si: 0.01 to 0.6%, Mn: 0.01 to 0.6%, P: 0.035% or less, S: 0.01% or less, Cr: 22.5 to 35.0%, Mo: 0.01 to 4.5%, Ni: 0.01 to 2.5%, Cu: 0.01 to 0.6%, Sn: 0.01 to 1.0%, In: 0.001 to 0.30%, N: 0.015% or less, V: 0.01 to 0.35%, and Al: 0.001 to 0.050%, and the calculated value of {Content of Cr (%)+3×Content of Mo (%)} being 22.5 to 45.0, and includes a surface modified layer containing O: less than 30% and the balance: Sn and In. A polymer electrolyte fuel cell including the separator is remarkably excellent in corrosion resistance in an in-cell environment. 1. A separator for polymer electrolyte fuel cells having a substrate of a ferritic stainless steel , having a chemical composition comprising , in mass %:C: 0.001 to 0.012%;Si: 0.01 to 0.6%;Mn: 0.01 to 0.6%;P: 0.035% or less;S: 0.01% or less;Cr: 22.5 to 35.0%;Mo: 0.01 to 4.5%;Ni: 0.01 to 2.5%;Cu: 0.01 to 0.6%;Sn: 0.01 to 1.0%;In: 0.001 to 0.30%;N: 0.015% or less;V: 0.01 to 0.35%;Al: 0.001 to 0.050%;REM: 0 to 0.1%;Nb: 0 to 0.35%;Ti: 0 to 0.35%; andthe balance: Fe and inevitable impurities, whereina calculated value of {Content of Cr (mass %)+3×Content of Mo (mass %)} is 22.5 to 45.0 mass %, and further comprisinga surface modified layer that has an oxygen concentration of less than 30 mass % and includes the balance containing Sn and In.2. A method for producing a separator for polymer electrolyte fuel cells , the method comprisingforming, into a separator shape, a ferritic stainless sheet having a chemical composition including, in mass %:C: 0.001 to 0.012%;Si: 0.01 to 0.6%;Mn: 0.01 to 0.6%;P: 0.035% or less;S: 0.01% or less;Cr: 22.5 to 35%;Mo: 0.01 to 4.5%;Ni: 0.01 to 2.5%;Cu: 0.01 to 0.6%;Sn: 0.01 to 1.0%;In: 0.001 to 0.30%;N: 0.015% or less;V: 0.01 to 0.35%;Al: 0.001 to 0.050%;REM: 0 to 0.1%;Nb: 0 to 0.35%;Ti: 0 to 0.35%; andthe balance: Fe and ...

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04-03-2021 дата публикации

Solution for removing various types of deposits from a surface

Номер: US20210062113A1
Принадлежит: Angara Industries Ltd

The invention relates to the field of removing various types of deposits from a surface, specifically to means for cleaning metallic and ceramic surfaces of industrial equipment, and can be used for removing deposits, such as oxides of metals (iron, chromium, nickel, etc.), carbonate and salt deposits, asphaltene-resin-paraffin deposits and deposits of a petroleum nature, and deposits of an organic and biological deposits. The proposed solution for removing various types of deposits contains hydrogen peroxide, complexone, an anti-foaming agent, water-soluble calixarene and water in the following ratio: hydrogen peroxide, a catalyst for decomposing peroxide compounds, an antifoaming agent, complexone, water-soluble calixarene and water in the following quantitative ratio: 2-35% by mass of hydrogen peroxide; 2-20% by mass of a catalyst for decomposing peroxide compounds; 3-10% by mass of complexone; 0.1-5% by mass of surface-active agent; 0.01%-1.0% by mass of anti-foaming agent; 0.01-1% by mass of water-soluble calixarene, with the remainder being water. The technical result is an increase in the effectiveness of action of a solution (degree of cleaning) for cleaning surfaces soiled with deposits having a high content of organic substances, while simultaneously extending the field of use of said solution.

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17-03-2022 дата публикации

MANUFACTURING METHOD OF GRAIN-ORIENTED ELECTRICAL STEEL SHEET

Номер: US20220081749A1
Принадлежит: NIPPON STEEL CORPORATION

This manufacturing method of a grain-oriented electrical steel sheet is a manufacturing method of a grain-oriented electrical steel sheet having no forsterite film, in which in a decarburization annealing process, a cold-rolled steel sheet is (i-1) heated at an average heating rate (HR1) of 40 to 500° C./sec in a temperature range of 550° C. or higher and lower than 720° C., (i-2) heated at an average heating rate (HR2), which is 5 to 50° C./sec, in a temperature range of 720° C. to T1° C. (770° C.≤T1 (° C.)≤900° C.), and (ii) retained at the temperature of T1° C. for 50 to 1000 seconds to make an amount of C 25 ppm or less in an atmosphere of an oxygen partial pressure (P1) which is 0.0010 to 0.20. 1. A manufacturing method of a grain-oriented electrical steel sheet comprising:a hot rolling process in which a steel piece containing 0.10% by mass or less of C, 0.80 to 7.00% by mass of Si, 0.01 to 0.07% by mass of acid-soluble Al, 0.012% by mass or less of N, 1.00% by mass or less of Mn, and 0.08% by mass or less of S, and including a remainder of Fe and impurities is hot-rolled into a hot-rolled steel sheet;an annealing process in which the hot-rolled steel sheet is annealed;a pickling process in which the hot-rolled steel sheet after the annealing process is pickled;a cold rolling process in which the hot-rolled steel sheet after the pickling process is cold-rolled into a cold-rolled steel sheet;a decarburization annealing process in which the cold-rolled steel sheet is decarburized; anda final annealing process in which the steel sheet after the decarburization annealing process is final-annealed, whereinthe decarburization annealing process includes:{'b': '1', '(i-1) a first heat treatment of heating at an average heating rate HR, which is 40 to 500° C./sec, in a temperature range of 550° C. or higher and lower than 720° C.;'}{'b': '2', '(i-2) a second heat treatment of heating at an average heating rate HR, which is 5 to 50° C./sec, in a temperature range of 720 ...

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28-02-2019 дата публикации

Methods, Systems And Apparatuses For Copper Removal From Aluminum Desmutting Solutions

Номер: US20190062928A1
Принадлежит:

Methods, systems and apparatuses for treating operating aluminum desmutting solutions by reacting, mixing and filtering a partial desmutting solution flow are disclosed. 1. A method of treating an aluminum desmutting tank , the method comprising the steps of:directing at least a portion of an aluminum desmutting solution from the aluminum desmutting tank to a mixing section;directing an aqueous reagent solution from an aqueous reagent solution feed line to the mixing section, said aqueous reagent solution comprising an iron cyanide compound;contacting copper ions present in the aluminum desmutting solution with the aqueous reagent solution at the mixing section to form a precipitate, said precipitate comprising a copper-containing compound;filtering the precipitate to form a first filtered flow; anddirecting the first filtered flow to a recirculating line;wherein the recirculating line returns the filtered flow to the aluminum desmutting tank.2. The method of claim 1 , wherein claim 1 , in the step of directing at least a portion of the aluminum desmutting solution claim 1 , the aluminum desmutting tank is an operating aluminum desmutting solution tank.3. The method of claim 1 , wherein claim 1 , in the step of directing at least a portion of the aluminum desmutting solution claim 1 , the portion of the aluminum desmutting solution comprises a flow rate ranging from about 1 gallons/min. to about 50 gallons/min.4. The method of claim 1 , wherein claim 1 , in the step of directing an aqueous reagent solution claim 1 , the iron cyanide compound comprises a ferricyanide; a ferrocyanide; or a nitroprusside.5. The method of claim 1 , wherein claim 1 , in the step of directing an aqueous reagent solution claim 1 , the iron cyanide compound comprises one or more of potassium ferricyanide; potassium ferrocyanide; sodium ferricyanide; sodium ferrocyanide; potassium nitroprusside or sodium nitroprusside.6. The method of claim 1 , wherein claim 1 , in the step of directing an ...

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27-02-2020 дата публикации

METHOD OF REMOVING MINERAL SCALES FROM A SUBSTRATE WITH MINIMIZED CORROSION OF THE SUBSTRATE

Номер: US20200063017A1
Автор: Todd Michael A.
Принадлежит: SOLENIS TECHNOLOGIES, L.P.

A method of removing mineral scales from a substrate with minimized corrosion of the substrate includes the steps of providing an acid solution providing a corrosion inhibitor solution, applying the acid solution to the substrate to remove mineral scales therefrom, and applying the corrosion inhibitor solution to the substrate to minimize corrosion thereof. The acid solution includes a mineral acid, an organic acid, or a combination thereof. The corrosion inhibitor solution includes an alpha-beta unsaturated aldehyde, a hydrophobic amine, and an oxime. The corrosion inhibitor solution optionally includes formic acid, a surfactant, and a solvent. 1. A method of removing mineral scales from a substrate with minimized corrosion of the substrate , said method comprising the steps of:providing an acid solution comprising a mineral acid, an organic acid, or a combination thereof; an alpha-beta unsaturated aldehyde;', 'a hydrophobic amine; and', 'an oxime; and optionally formic acid;', 'a surfactant; and', 'a solvent;, 'providing a corrosion inhibitor solution comprisingapplying the acid solution to the substrate to remove mineral scales therefrom; andapplying the corrosion inhibitor solution to the substrate to minimize corrosion thereof.2. The method of wherein the alpha-beta unsaturated aldehyde is cinnamaldehyde.3. The method of wherein the corrosion inhibitor solution further comprises the formic acid claim 1 , the surfactant claim 1 , and the solvent.4. The method of wherein the hydrophobic amine is chosen from oleyl-propanediamine claim 1 , cocopropanediamine claim 1 , soyapropanediamine claim 1 , tallowpropanediamine claim 1 , and combinations thereof.5. The method of wherein the hydrophobic amine is oleyl-propanediamine.6. The method of wherein the oxime is chosen from methyl ethyl ketoxime claim 1 , cyclohexanone oxime claim 1 , and combinations thereof.7. The method of wherein the oxime is methyl ethyl ketoxime.8. The method of further comprising the step of ...

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11-03-2021 дата публикации

METAL CLEANING COMPOSITIONS COMPRISING FUROATE ESTERS AND USES THEREFOR

Номер: US20210071309A1
Принадлежит:

Disclosed are metal cleaning formulations and methods of use. A formulation of the present teachings comprises one or more furoate esters such as ethyl 5-methyl-2-furoate and methyl 5-methyl-2-furoate. The formulations further comprise a base oil, which can be, for example, a naphthenic oil, a synthetic oil or a combination thereof. In some embodiments, a formulation can further comprise a metal protection additive and a lubrication additive. A variety of base oils, metal protection additives, and lubrication additives are suitable for use in the present teachings. Formulations of the present teachings are especially useful for the cleaning of metal products such as firearms. The cleaning power of a formulation of the instant teachings can exceed that required for US Military Specifications. 1. A metal cleaner comprising:i) 20% to 70% by weight of at least one base oil; andii) 3% to 60% by weight of at least one furoate ester.2. A metal cleaner in accordance with claim 1 , further comprising:iii) 0.1% to 15% by weight of at least one metal protection additive; andiv) 0.5% to 20% by weight of at least one lubrication additive.3. A metal cleaner in accordance with or claim 1 , wherein the 20% to 70% by weight of at least one base oil is 20% to 50% by weight of the at least one base oil.4. A metal cleaner in accordance with claim 2 , wherein the 0.1% to 20% by weight of at least one metal protection additive is 0.1% to 5% by weight of the at least one metal protection additive claim 2 , and the 0.5% to 15% by weight of at least one lubrication additive is 1% to 15% by weight of the at least one lubrication additive.5. A metal cleaner in accordance with or claim 2 , wherein the 20% to 70% by weight of at least one base oil is 35% to 50% of the at least one base oil claim 2 , and the 3% to 60% of at least one furoate ester is 10% to 40% of the at least one furoate ester.6. A metal cleaner in accordance with claim 2 , wherein the 0.1% to 15% by weight of at least one ...

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17-03-2016 дата публикации

Copper cleaning and protection formulations

Номер: US20160075971A1
Принадлежит: Advanced Technology Materials Inc

A cleaning composition and process for cleaning post-chemical mechanical polishing (CMP) residue and contaminants from a microelectronic device having said residue and contaminants thereon. The cleaning compositions include corrosion inhibitor(s) and surfactant(s). The composition achieves highly efficacious cleaning of the post-CMP residue and contaminant material from the surface of the microelectronic device without compromising the low-k dielectric material or the copper interconnect material.

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15-03-2018 дата публикации

COMPOSITIONS, SYSTEMS, AND METHODS FOR REMOVING IRON SULFIDE SCALE FROM OILFIELD COMPONENTS USING METHYL ACRYLATE

Номер: US20180072940A1
Принадлежит:

The present disclosure relates to compositions, systems and methods for removing iron sulfide scale from a solid object, such as an oilfield component. The compositions include a carbon-carbon (C—C) double bond with an electron withdrawing group bonded to at least one of the double-bonded carbons. 1. A method of removing iron sulfide scale from an oilfield component with iron sulfide scale , the method comprising applying to the oilfield component a removal material comprising methyl acrylate or a methyl-acrylate containing composition in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component.3. The method of claim 1 , wherein the removal material further comprises a polar solvent.4. The method of claim 1 , wherein the removal material further comprises an additional composition able to remove iron sulfide scale from the oilfield component.5. The method of claim 1 , wherein at least 80% of the iron sulfide scale is removed from the oilfield component.6. The method of claim 1 , wherein applying occurs in a sealed container.7. The method of claim 1 , further comprising recovering the removal material.8. The method of claim 1 , wherein the oilfield component comprises a perforation claim 1 , a casing claim 1 , a production tubular claim 1 , a valve claim 1 , a pump claim 1 , or downhole completion equipment with iron sulfide scale.9. A system for removing iron sulfide scale from an oilfield component with iron sulfide scale claim 1 , the system comprising:a removal material comprising comprising methyl acrylate or a methyl-acrylate containing composition; anda system for applying the removal material to the oilfield component in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component.11. The system of claim 9 , wherein the removal material further comprises a polar solvent.12. The system of claim 9 , wherein the removal material further comprises an additional composition able to remove iron ...

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