18-06-2015 дата публикации
Номер: US20150167588A1
Автор:
Beutel Tilman Wolfram,
Brody John Francis,
CHOI Eugine,
Hajkowski Keith Robert,
Kliewer Chris Esther,
Madiara Paul Dmitri,
Marella Michael Anthony,
Nandi Partha,
Raman Sumathy,
Skic George,
Strohmaier Karl Gottlieb,
Weiss Brian Michael,
Weissman Walter
Catalyst compositions suitable for use in the exhaust gas recycle stream of an internal combustion engine are provided. Such catalyst compositions typically provide significant amounts of methane in addition to syngas. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and and a method of operating an internal combustion engine using methane-assisted combustion are also described. 1. A method of increasing the octane rating of an internal combustion engine exhaust gas stream , said method comprising:(a) providing an exhaust gas-containing mixture to an exhaust gas recycle reformer, the exhaust gas-containing mixture comprising engine exhaust gas and a first hydrocarbon-containing fuel, said engine exhaust gas having an initial octane rating, and{'sub': 2', '2', '2', '2', '4, '(b) converting under reforming conditions at least a portion of the exhaust gas-containing mixture in the presence of a hydrocarbon-reforming catalyst composition comprising at least about 0.25 wt % of a hydrocarbon-reforming catalyst selected from Co, Ru, Pt, Pd, Ni, Ir, Rh, Zn, Re, and mixtures thereof, and at least about 10 wt % of a small pore molecular sieve to form a reformed gaseous mixture, the reformed gas mixture comprising H, CO, CO, HO, N, and greater than about 1.0 mol % CHbased on the total moles of gas in the reformed gaseous mixture.'}2. The method of claim 1 , wherein the small pore molecular sieve is a molecular sieve having the framework type AEI claim 1 , AFT claim 1 , AFX claim 1 , ATT claim 1 , DDR claim 1 , EAB claim 1 , EPI claim 1 , ERI claim 1 , KFI claim 1 , LEV claim 1 , LTA claim 1 , MER claim 1 , MON claim 1 , MTF claim 1 , PAU claim 1 , PHI claim 1 , RHO claim 1 , or SFW.3. The method of claim 1 , wherein the small pore molecular sieve is chabazite claim 1 , ...
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