06-02-2020 дата публикации
Номер: US20200038835A1
Принадлежит:
Systems and methods for separating hydrocarbons on an internal combustion powered vehicle via one or more metal organic frameworks are disclosed. Systems and methods can further include utilizing separated hydrocarbons and exhaust to generate hydrogen gas for use as fuel. 1. A method of optimizing fuel for an internal combustion engine (ICE) , the method comprising:contacting a fuel with a metal organic framework (MOF), wherein the MOF is one or more of a hexafluorosilicate (SIFSIX) MOF, a fcu-MOF, an ana-ZMOF, a sod-ZMOF, and a cation-exchanged ZMOF, wherein ZMOF is a zeolite-like MOF;separating one or more constituents of the fuel, via the metal organic framework, to define a first fuel stream and a second fuel stream; andstoring at least a portion of the second fuel stream or injecting at least a portion of the second fuel stream into the ICE, or both.2. The method of claim 1 , wherein the first fuel stream has a higher research octane value than the second fuel stream.3. The method of claim 1 , wherein the first fuel stream has a higher cetane number value than the second fuel stream.4. The method of claim 1 , further comprising injecting the stored second fuel stream into an ICE claim 1 , or discharging or removing the stored second fuel stream.5. The method of claim 1 , wherein the SIFSIX MOF comprises a metal and a ligand claim 1 , wherein the metal is Cu claim 1 , Zn claim 1 , Co claim 1 , Mn claim 1 , Mo claim 1 , Cr claim 1 , Fe claim 1 , Ca claim 1 , Ba claim 1 , Cs claim 1 , Pb claim 1 , Pt claim 1 , Pd claim 1 , Ru claim 1 , Rh claim 1 , or Cd and wherein the ligand is a nitrogen-containing heterocyclic ligand.6. The method of claim 1 , wherein the fcu-MOF comprises a rare earth metal and a ligand claim 1 , wherein the ligand comprises a carboxylate group claim 1 , tetrazole group claim 1 , or a combination thereof.7. The method of claim 1 , wherein the ana-ZMOF comprises one or more metals and a ligand claim 1 , wherein the one or more metals are ...
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