17-03-2016 дата публикации
Номер: US20160077012A1
Принадлежит:
The present invention relates to methods for determining the level of intermolecular interaction of a polymer based on the fraction of intermolecular interaction (f) relative to the inter, total molecular interaction, which includes both intermolecular and intramolecular interactions. Further provided herein is a method of identifying a suitable viscosity index improver based on the value of f. The identified suitable viscosity index improver can be used in a lubricating oil composition for, e.g., a power transmission system. 122-. (canceled)23. A method for identifying a viscosity index improver suitable for use in a lubricant composition , the method comprising:(a) providing a first solution comprising a candidate polymer that is labeled by a fluorescent dye,(b) providing a second solution comprising the labeled candidate polymer, wherein the concentration of the labelled polymer in the second solution is lower than the concentration of the labelled polymer in the first solution,{'sub': E', 'M, '(c) measuring fluorescence intensities of excimers (I) and fluorescence intensities of monomers (I) of the first and second solutions at a predetermined temperature,'} {'br': None, 'i': f', 'I', '/I', 'I', '/I', 'I', '/I, 'sub': inter', 'E', 'M', 'E', 'M', 'E', 'M, 'sup': H', 'L', 'H, '=[()−()]/(),'}, '(d) determining a level of intermolecular interaction of the candidate polymer based on a formula set forth as{'sub': inter', 'E', 'M', 'E', 'M, 'sup': H', 'L, 'in which fis the fraction of intermolecular interaction relative to the total molecular interaction which includes intermolecular and intra molecular interactions, (I/I)represents the fluorescence intensity ratio of excimer to monomer of the first solution, and (I/I)represents the fluorescence intensity ratio of excimer to monomer of the second solution; and'}{'sub': 'inter', '(e) selecting the candidate polymer as a viscosity index improver for use in a lubricant composition, if the fvalue of the candidate polymer ...
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