24-03-2016 дата публикации
Номер: US20160085000A1
Принадлежит:
A process for positive microcontact printing, including inking a patterned mold with a thiol; contacting the mold with a metal surface of a substrate; backfilling the metal surface with a solution containing an aromatic amine to form a backfilling layer; etching the metal surface of the substrate; and rinsing the substrate to remove the backfilling layer. 1. A process for positive microcontact printing , comprising:inking a patterned mold with a thiol;contacting the mold with a metal surface of a substrate;backfilling the metal surface with a solution containing an aromatic amine to form a backfilling layer;etching the metal surface of the substrate; andrinsing the substrate to remove the backfilling layer.2. The process of claim 1 , wherein the aromatic amine is represented by formula (I){'br': None, 'sub': 'n', 'sup': 'm+', '[Ar—(NRR′)]\u2003\u2003(I)'}wherein Ar represents an aryl group having 6 to 18 carbon atoms or a heteroaromatic group having 4 to 17 carbon atoms; each of R and R′ independently represents a hydrogen atom, a methyl group, or a ethyl group; n is 1, 2, or 3; and m is 0, 1, 2, or 3.3. The process of claim 2 , wherein n is 2.4. The process of claim 2 , wherein the aromatic amine is selected from the group consisting of 2 claim 2 ,4 claim 2 ,6-trimethyl-benzene-1 claim 2 ,3 claim 2 ,5-triamine claim 2 , tri-hydrochloride; 3 claim 2 ,6-diaminoacridine hydrochloride claim 2 , 3 claim 2 ,7-bis(Dimethylamino)phenazathionium chloride claim 2 , 9-aminoacridine dydrochloride and 2-(4-dimethylaminophenylazo)benzoic acid.5. The process of claim 1 , wherein the surface is backfilled with a solution containing an aromatic amine to form a backfilling layer through dewetting.6. The process of claim 1 , wherein the aromatic amine is dissolved in a mixture of at least one monohydroxyl alcohol and one or more glycol ethers to obtain the solution containing the aromatic amine.7. The process of claim 5 , wherein the monohydroxyl alcohol is selected from the group ...
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