Light reactive media

A light reactive medium comprises an imaging layer reactive to radiation of a first frequency to exhibit a visible change, and a further layer above the imaging layer, the further layer being changeable from being substantially transparent to said first frequency to being substantially opaque to said first frequency, in response to electromagnetic radiation of a second frequency substantially different from the first frequency, the at least one other layer being at least partially transparent to visible light reflected from the imaging layer while being opaque to said first frequency. Also disclosed is a lenticular imaging method in which a lenticular layer is provided over the imaging layer, and images to be viewed from different directions are written using light incident at different directions. Also disclosed is a phosphorescent display that may be used to display lenticular images.

Photochromic compounds

A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N 3 , —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSO 2 R′″, and/or —CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R′″ is —CF 3 or a perfluorinated alkyl group having from 2 to 18 carbon atoms. The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound.

Positive Photosensitive Resin Composition

Disclosed is a positive photosensitive resin composition that includes (A) an alkali soluble resin selected from a polybenzoxazole precursor, a polyimide precursor, and a combination thereof, (B) a photosensitive diazoquinone compound, (C) a phenol compound, (D) an organic dye and (E) a solvent, wherein the organic dye (D) includes at least one red dye having an absorption wavelength of 590 to 700 nm, at least one yellow dye having an absorption wavelength of 550 to 590 nm, and at least one blue dye having an absorption wavelength of 450 to 500 nm. 1. A positive photosensitive resin composition , comprising:(A) an alkali soluble resin selected from a polybenzoxazole precursor, a polyimide precursor, and a combination thereof;(B) a photosensitive diazoquinone compound;(C) a phenol compound;(D) an organic dye; and(E) a solvent,wherein the organic dye (D) comprises at least one red dye having an absorption wavelength of 590 to 700 nm, at least one yellow dye having an absorption wavelength of 550 to 590 nm, and at least one blue dye having an absorption wavelength of 450 to 500 nm.4. The positive photosensitive resin composition of claim 1 , wherein the red dye having an absorption wavelength of 590 to 700 nm comprises a compound selected from a xanthene-based compound claim 1 , an azo-based compound claim 1 , an anthraquinone-based compound claim 1 , a cyan-based compound claim 1 , and a combination thereof.5. The positive photosensitive resin composition of claim 1 , wherein the yellow dye having an absorption wavelength of 550 to 590 nm comprises a compound selected from a methane-based compound claim 1 , an azo-based compound claim 1 , or a combination thereof.6. The positive photosensitive resin composition of claim 1 , wherein the blue dye having an absorption wavelength of 450 to 500 nm comprises a compound selected from a triphenylmethane (TPM)-based compound claim 1 , a triarylmethane (TAM)-based compound claim 1 , a xanthene-based compound claim 1 , and a ...

Composition for the Manufacture of an Ophthalmic Lens Comprising an Encapsulated Light-Absorbing Additive

The present invention relates to a thermosetting composition for the manufacture of an ophthalmic lens which efficiently absorbs light rays without degradation of the light-absorbing additive, said composition comprising an allyl monomer or oligomer, a catalyst, at least one light-absorbing additive contained in nanoparticles which are dispersed in said allyl monomer or allyl oligomer. The present invention also relates to the use of said composition and to the ophthalmic lens obtained from said composition. 1. A polymerizable liquid composition for the manufacture of an ophthalmic lens , comprising:a) at least one allyl monomer or allyl oligomer,b) at least one catalyst for initiating the polymerization of said allyl monomer or allyl oligomer,c) at least one light-absorbing additive contained in nanoparticles which are dispersed in said allyl monomer or allyl oligomer.2. The composition according to claim 1 , wherein the light-absorbing additive is selected from the group consisting of a colorant; a colorless light-absorbing additive; and mixtures thereof.3. The composition according to claim 1 , wherein the nanoparticles comprise a polymer.4. The composition according to claim 1 , wherein nanoparticles comprise a mineral oxide.5. The composition according to claim 1 , wherein the refractive index of the nanoparticles is from 1.47 to 1.56 claim 1 , as measured according to the ISO 489:1999.6. The composition according to claim 1 , wherein the nanoparticles exhibit a size of from 1 nm to 10 μm claim 1 , as measured according to the Dynamic Light Scattering method.7. The composition according to claim 1 , wherein the amount of light-absorbing additive in the nanoparticles is from 0.0001 to 90 wt % based on the weight of the nanoparticles.8. The composition according to claim 1 , wherein the amount of nanoparticles in the composition is from 0.01 to 2 wt % based on the weight of the composition.9. The composition according to claim 1 , wherein the allyl monomer or ...

Photochromic Articles That Include Photochromic-Dichroic Materials

The present invention relates to photochromic articles that include a substrate and at least one photochromic material that is adapted to change from an unactivated form to an activated form by exposure to radiation substantially in the wavelength range from 380 to 450 nanometers when measured over a range of from 380 to 700 nanometers. The photochromic article is also adapted to retain at least 12 percent of the delta OD measured in the Outdoor Test when tested in the Behind the Windshield Test. The photochromic material can be selected from certain compounds including, for example, fluoranthenoxazines, naphthopyrans, phenanthropyrans, fluoranthenopyrans, and indenonaphthopyrans, which each have bonded thereto at least one chiral or achiral lengthening group that provides the photochromic compound with dichroic properties. The present invention also relates to methods of forming a photochromic article.

Photoinitiated reactions

Disclosed is a method for the photoinitiated transformation of a transformable reactive substrate. The method includes an initial step in which a protected ketone photoinitator species which is present in the suhstrate is deprotected to form the corresponding ketone photoinitiator species for use in a subsequent photoinitiated reaction in the method. The ketone group of the photoinitiator is protected by an unsubstituted 1,3 dioxolanc group. Also disclosed are a composition which may be used in the method, the use of the protected ketone photoinitiator in a photoinitiated reaction, as well as the protected ketone photoinitiators themselves.

Photochromic Compounds

A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSOR′″, and/or —CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R″′ is —CFor a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound. 2. (canceled)3. A photochromic composition comprising the photochromic material of incorporated into at least a portion of an organic material claim 1 , said organic material being a polymeric material claim 1 , an oligomeric material claim 1 , a monomeric material or a mixture or combination thereof.4. The photochromic composition of claim 3 , wherein said polymeric material comprises self-assembling materials claim 3 , polycarbonate claim 3 , polyamide claim 3 , polyimide claim 3 , poly(meth)acrylate claim 3 , polycyclic alkene claim 3 , polyurethane claim 3 , poly(urea)urethane claim 3 , polythiourethane claim 3 , polythio(urea)urethane claim 3 , polyol(allyl carbonate) claim 3 , cellulose acetate claim 3 , cellulose diacetate claim 3 , cellulose triacetate claim 3 , cellulose acetate propionate claim 3 , cellulose acetate butyrate claim 3 , polyalkene claim 3 , polyalkylene-vinyl acetate claim 3 , poly(vinylacetate) claim 3 , poly(vinyl alcohol) claim 3 , poly(vinyl chloride) claim 3 , poly(vinylformal) claim 3 , poly(vinylacetal) claim 3 , poly(vinylidene chloride) claim 3 , poly(ethylene terephthalate) claim 3 , polyester claim 3 , polysulfone claim 3 , polyolefin claim 3 , copolymers thereof claim 3 , and/or ...

Photochromic Compounds

A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSOR′″, and/or CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R′″ is —CFor a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound. 115-. (canceled)18. (canceled) This application is a divisional of U.S. patent application Ser. No. 13/452,030, filed Apr. 20, 2012, which is a divisional of U.S. patent application Ser. No. 12/329,092 filed Dec. 5, 2008, which is a continuation-in-part of U.S. patent application Ser. No. 10/846,629, filed May 17, 2004, which claims the benefit of U.S. Provisional Application No. 60/484,100, filed Jul. 1, 2003, all of which are hereby specifically incorporated by reference.Not applicable.Not applicable.Various non-limiting embodiments disclosed herein relate generally to photochromic compounds. Other non-limiting embodiments relate to devices and elements made using the photochromic compounds disclosed herein.Conventional photochromic compounds have at least two states, a first state having a first absorption spectrum and a second state having a second absorption spectrum that differs from the first absorption spectrum, and are capable of switching between the two states in response to at least actinic radiation. Further, conventional photochromic compounds can be thermally reversible. That is, conventional photochromic compounds are capable of switching between a first state and a second state in response to at least ...

Photochromic Compounds

A photochromic compound is provided, which may be a pyran, an oxazine, or a fulgide. The photochromic compound has at least one substituent Q attached thereto, each Q independently being —N, —CN, —COOR′, —CCR′, —C(R′)C(R′)R′, —OCOR′, —OCOOR′, —SR′, —OSOR″′, and/or —CON(R′)R′, wherein each R′ is hydrogen, an unsubstituted or substituted alkyl group having from 1 to 18 carbon atoms; an unsubstituted or substituted aryl group, an unsubstituted or substituted alkene or alkyne group having from 2 to 18 carbon atoms, wherein the substituents are halo or hydroxyl and R″′ is —CFor a perfluorinated alkyl group having from 2 to 18 carbon atoms The number, locations and nature of the constituents Q are dependent upon the structure of the photochromic compound. 115-. (canceled)17. The naphthol of wherein claim 16 , substituent Q comprises —CN claim 16 , —COOR′ claim 16 , —CCR′ claim 16 , —C(R′)C(R′)R′ claim 16 , —OCOR′ claim 16 , —OCOOR′ claim 16 , —SR′ claim 16 , —OSOR″′ claim 16 , or —CON(R′)R′ claim 16 , and wherein each R′ independently comprises an alkyl group having from 1 to 12 carbon atoms and R″′ comprises —CFor a perfluorinated alkyl group having from 2 to 12 carbon atoms.18. (canceled) This application is a divisional of U.S. patent application Ser. No. 13/452,030, filed Apr. 20, 2012, which is a divisional of U.S. patent application Ser. No. 12/329,092 filed Dec. 5, 2008, which is a continuation-in-part of U.S. patent application Ser. No. 10/846,629, filed May 17, 2004, which claims the benefit of U.S. Provisional Application No. 60/484,100, filed Jul. 1, 2003, all of which are hereby specifically incorporated by reference.Not applicable.Not applicable.Various non-limiting embodiments disclosed herein relate generally to photochromic compounds. Other non-limiting embodiments relate to devices and elements made using the photochromic compounds disclosed herein.Conventional photochromic compounds have at least two states, a first state having a first absorption ...

PHOTOCATALYTIC COLOR SWITCHING OF REDOX IMAGING NANOMATERIALS OF REWRITABLE MEDIA

The production of photocatalytic color switching of redox imaging nanomaterials for rewritable media is disclosed. The new color switching system is based on photocatalytic redox reaction enabling reversible and considerably fast color switching in response to light irradiation. In accordance with an exemplary embodiment, the color switching system can include a photocatalyst and an imaging media. With the assistance of photocatalyst, UV light irradiation can rapidly reduce the redox imaging nanomaterials accompany with obvious color changing, while the resulting reduced system can be switched back to original color state through visible light irradiation or heating in air condition. The excellent performance of the new color switching system promises their potential use as an attractive rewritable media to meet increasing needs for sustainability and environmental protection. 1. A reversible color switching system , comprising:a redox imaging material; anda photocatalyst, which photocatalyzes the imaging material to produce a photocatalytic redox reaction enabling reversible and color switching in response to light irradiation.2. The color switching system of claim 1 , wherein the photocatalyst is selected from the following:{'sub': 2', '2', '3', '2', '5', '2, 'binary metal oxides: TiO, ZnO, SnO, WO, NbOand ZrO; and/or'}{'sub': 2', '2, 'sulfides: CuS, ZnS, CdS, SnS, WSand/or MoS.'}3. The color switching system of claim 1 , wherein the photocatalyst is titanium oxide (TiO).4. The color switching system of claim 1 , wherein the image material comprises a redox dye.5. The color switching system of claim 4 , wherein the redox dye is selected from the following:methylene blue (color of oxidized form: blue and color of reduced form: colorless), methylene green (green and colorless), neutral red (red and colorless), acid green (green and light yellow), safranin T (red-violet and colorless), phenosafranin (red and colorless), indigomono sulfoinic acid (blue and colorless), ...

Holographic light panels and flat panel display systems and method and apparatus for making same

An illumination panel for illuminating an object, comprising a substrate, a light diffractive grating and a light source. The substrate is made from an optically transparent material having first and second area surfaces disposed substantially parallel to each other and a light input surface for conducting a light beam into the substrate. The light diffractive grating is mounted to the first areal surface and has a slanted fringe structure embodied therein for diffracting the light beam falling incident thereto, along a first diffractive order of the slanted fringe structure. The light source produces a light beam for transmission through the input surface and direct passage through the substrate to the slanted fringe structure so as to produce an output light beam of areal extent that emerges from either the first or second areal surface along the first diffractive order, for use in illuminating an object. A spatial-intensity modulation panel can be mounted to the illumination panel to form a color image display device. In the illustrative embodiments, the light diffractive grating is a volume hologram that is pixelated and spectrally-tuned in order to carry out spectral filtering functions within the color image display device.

4-Halogeno-5-(halogenomethyl-phenyl)-oxazole derivatives, a process for the preparation thereof, and radiation-sensitive compositions containing these derivatives

This invention relates to a novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; and to a process for the preparation of the novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivatives.

2-(Halogenomethyl-phenyl)-4-halogeno-oxaxole derivatives, a process for the preparation thereof, and radiation-sensitive compositions containing these derivatives

This invention relates to a novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 2-halogenomethyl-phenyl)-4-halogeno-oxazole derivative; and to a process for the preparation of the novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivatives.

Photoimaging composition containing admixture of leuco dye and 2,4,5-triphenylimidazolyl dimer

Photoimaging composition comprising an admixture of leuco dye, and at least one 2,4,5-triphenylimidazolyl dimer prepared by an oxidative coupling reaction, a reaction product, 2,2',5-tris-(o-chlorophenyl)-4-(3,4-dimethoxyphenyl)-4',5'-diphenylbiimidazole, being present in an amount of 0.01 to 90.0% by weight based on the weight of solids in the composition. The composition when coated on a support is useful for prepress proofing.

Process for producing optically dense mask-like metallization patterns

红外线感光性显色组合物、红外线固化性显色组合物、平版印刷版原版和制版方法

本发明提供一种感光性显色组合物以及固化性显色组合物，其通过：含有(A)在分子内具有红外线吸收骨架和热致变色骨架、上述红外线吸收骨架与上述热致变色骨架通过共价键或离子键键合的化合物、和(B)粘结剂的所述红外线感光性显色组合物、以及上述红外线感光性显色组合物进一步含有(C)自由基引发剂和(D)聚合性化合物的红外线固化性显色组合物，通过基于红外线激光的曝光，以高浓度显色，而且随时间经过的退色少。通过将具有包含上述红外线固化性显色组合物的图像记录层的平版印刷版原版和上述平版印刷版原版红外线图像曝光后、进行机上显影、由此制作平版印刷版原版的制版方法，由此，提供一种平版印刷版原版和使用上述平版印刷版原版制作平版印刷版的制版方法，上述平版印刷版原版提供：在图像记录层具有上述固化性显色组合物，检版性极为优异，保存稳定性良好且维持高的显色性，机上显影性也优异，具有良好的耐印性的平版印刷版。

Heat-sensitive recording paper

Photosensitive and heat-sensitive type recording member

Composition sensitive to irradiation

Photosensitive and heat sensitive composition and formation of image using it

Diazo copying material for intermediates

制造具有全息图的复合玻璃板的方法

制造具有全息图的复合玻璃板(100)的方法，该方法至少包括以下步骤：a)提供第一玻璃板(1)和第二玻璃板(2)，b)至少在第一玻璃板(1)的表面(III)上的涂覆区域(7)中喷涂作为全息图元件(5)的光敏材料(15)，c)通过对露出的全息图元件(5)进行选择性的激光辐射而产生至少一个全息图，d)由第一玻璃板(1)、热塑性中间层(3)和第二玻璃板(2)形成层堆叠体，其中全息图元件(5)布置在这两个玻璃板(1、2)之间，e)在层压方法中将所述第一玻璃板(1)和所述第二玻璃板(2)经由所述热塑性中间层(3)接合成复合玻璃板(100)。

Light and heat sensitive type copying material

Method of sensitizing photosensitive composition and sensitized photosensitive composition

感光感熱組成物

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熱現像用感光材料

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熱現像型ジアゾ複写材料

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Photochromic material and rewritable optical recording medium

A photochromic material containing a copolymer of a spirobenzothiopyran derivative prepolymer and a liquid crystal prepolymer. In addition, a rewritable optical recording medium using the photochromic material. A rewritable optical recording medium obtained by coating a dispersed material, which is obtained by uniformly dispersing a spirobenzothiopyran derivative compound in a thermoplastic resin, on a substrate. A photochromic material capable of controlling a colored state and a decolorized state in a photon mode or a heat mode using an ultraviolet light source and a near-infrared light source. A rewritable optical recording medium capable of rewriting an information in a photon mode using a semiconductor laser.

Contact reflection printing type photosensitive paper

ジアゾ式感光材料

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Heat development type diazo copying material

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Composite film and utilization thereof

A composite film comprising a first layer comprising a polyolefin resin containing finely divided calcium carbonate dispersed therein and a surface layer comprising a polyolefin resin containing an acidic filler dispersed therein, which surface layer is bonded directly or indirectly to at least one surface of the first layer and has a thickness of at least 3 microns. A diazo copying paper is also disclosed which has a photosensitive diazo layer on the surface layer of the composite film.

Diazo sensitized paper

Patent DE3413121C2

Positive Photoresist Composition

막형성제인 크레졸노블락수지와 감광제인 퀴논디아지도기함유화합물로 이루어진 포지티브형 포토레지스트조성물은, 히드록시알킬치환피리딘화합물의 한정된 양을 첨가함으로써, 패턴프로세스중 레지스트층으로부터 승화된 물질로 인한 문제없이, 기판 표면으로서의 레지스트층의 밀착결합 및 보관에 의한 조성물의 안정성에서 커다란 향상을 얻을 수 있다. The positive photoresist composition consisting of the film formation agent cresol noblock resin and the photosensitive agent quinonediazido group-containing compound is added without limiting the amount of the hydroxyalkyl-substituted pyridine compound, thereby avoiding the problem caused by the sublimation material from the resist layer during the pattern process. A significant improvement can be obtained in the stability of the composition by tight bonding and storage of the resist layer as the substrate surface.

Two-component type diazo copying material

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Light-sensitive imaging material containing hydrazones

Heat and light sensitive layers containing hydrazones

Certain ketone and aldehyde organic hydrazones exhibit utility in radiation-sensitive layers and elements as a spectral sensitizer for silver halide and as a selective reducing agent in photographic, thermographic and photothermographic layers.

Heat developable photosensitive material

Diazo-based heat-sensitive recording material

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Manufacture of a polymer device

A method of forming a polymer device including the steps (i) of depositing on a substrate a solution containing a polymer or oligomer and a crosslinking moiety, to form a layer, and, (ii) curing the layer formed in step (i) under conditions to form an insoluble crosslinked polymer, wherein the crosslinking moiety is present in step (i) in an amount in the range of from 0.05 mol % to 5 mol % based on the total number of moles or repeat units of the polymer or oligomer and the crosslinking moiety in the solution.

Diazo photosensitive paper

A ketone photoinitiator

변환가능한 반응성 기판의 광개시 제로서, 케톤 그룹에 비치환된 1, 3 디옥살렌 그룹을 이용하는 케톤 광개시제를 제공하는데 있다. As a photoinitiator of a convertible reactive substrate, to provide a ketone photoinitiator using 1, 3 dioxalene groups unsubstituted in the ketone group.

Heat development type diazo copying material

Photo- and heat-sensitive recording material

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Photosensitive material

Positive photosensitive resin composition

본 발명은 포지티브형 감광성 수지 조성물에 관한 것으로서, 상기 포지티브형 감광성 수지 조성물은 (A) 하기 화학식 1로 표시되는 반복단위를 갖는 폴리벤조옥사졸 전구체; (B) 감광성 디아조퀴논 화합물; (C) 실란 화합물; (D) 페놀계 화합물; (E) 용매; 및 (F) 무기물을 포함한다. The present invention relates to a positive photosensitive resin composition, wherein the positive photosensitive resin composition comprises: (A) a polybenzoxazole precursor having a repeating unit represented by Formula 1 below; (B) photosensitive diazoquinone compound; (C) silane compound; (D) phenolic compounds; (E) a solvent; And (F) minerals. [화학식 1] [Formula 1] (상기 화학식 1에서 각 치환기의 정의는 명세서에 정의된 것과 동일하다.) (The definition of each substituent in Formula 1 is the same as defined in the specification.) 포지티브형, 감광성 폴리벤조옥사졸 전구체 조성물, 무기물 나노복합체, 알칼리 수용액, 반도체 장치 Positive type, photosensitive polybenzoxazole precursor composition, inorganic nanocomposite, aqueous alkali solution, semiconductor device

Uv-dosis indicators

The present application provides a composition showing a color change depending on the absorbed radiation-dose, comprising (a) an acid responsive colorant; (b) a photolatent acid; characterized in that (b) is a sulfonyloxime ester compound; and its use as a radiation dose indicator.

Two-component type diazo copying material

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Binary type diazo copying material

Photochromic materials with reactive substituents

本发明公开内容的各种非限制性实施方案涉及含反应性取代基的光致变色材料。例如，本公开内容提供了光致变色材料，例如光致变色性萘并吡喃和具有反应性取代基的茚并稠合萘并吡喃，该反应性取代基包含通过一个或多个连接基与该光致变色性萘并吡喃连接的反应性结构部分。在某些非限制性实施方案中，所述反应性结构部分包括可聚合结构部分。在其它的非限制性实施方案中，所述反应性结构部分包括亲核结构部分或亲电结构部分。本公开内容的其它非限制性实施方案涉及光致变色制品、组合物和该光致变色制品的制备方法，其中该光致变色制品和组合物包含本文描述的光致变色性萘并吡喃。

Photosensitive and heat sensitive recording material

Photosensitive composition

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Heat-sensitive recording material and recording method using the same

Patent JPH042179B2

Method for the production of radiant energy imaged printed circuit boards

Radiant energy imaged printed circuit boards are provided by treating an insulating base with a composition of a reducible metal salt and a radiant energy sensitive compound, exposing the treated base to radiant energy in selected areas to produce metallic nuclei in the form of a non-conducting real image of the desired circuit pattern, rinsing the exposed base to remove unexposed metal salts and exposing the real image to an electroless metal bath to build up conductor lines of electroless metal thereon. In an alternative procedure, conductor lines are built up by electroplating with the same or a different metal and, optionally, solder coating.

Photochromic material and coloring thereof

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Light-sensitive composition

Photosensitive, heat-sensitive composition

Patent JPS509178B1

Auto tranfor soldering apparatus

내용 없음. No content.

3,3-dimethyl-spiro(indolino-2,3'-naphtho(2,1-b)-(1,4) oxazine)derivative

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Photosensitive composition having high sensitivity

Fixable-type thermal recording material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Patent JPH0416776B2

Diazo-based heat-sensitive recording material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Diazo base heat-sensitive recording material

Diazo heat-sensitive recording material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Dry type and two component type diazo copying material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Dry type and two component type diazo copying material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Heat-developable diazo copying material

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Negative type diazo copying material and its fixing method

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Crystal comprising photomerocyanine component of indolinospirobenzopyran derivative, method for producing the same, and thermochromic and photochromic materials comprising the crystal

Patent JPH0360414B2

Novel spirobenzoxazine compound

Photosensitive material containing a diaryliodium compound, a sensitizer and a color former

A photosensitive admixture comprising a diaryliodonium compound and a compound capable of sensitizing 2-methyl-4,6bis(trichloromethyl)-s-triazine.

Novel photosensitive systems comprising diaryliodonium compounds and their use

A PHOTOSENSITIVE ADMIXTURE COMPRISING A DIARYLIODONIUM COMPOUND AND A COMPOUND CAPABLE OF SENSITIZING 2METHYL-4,6-BIS(TRICHLOTOMETHYL)-S-TRIAZINE.

Sunshine and light interrupting film

(57)【要約】本公報は電子出願前の出願データであるた め要約のデータは記録されません。

Method for manufacturing photochromic articles

Uv radiation dose indicators

FIELD: physics. SUBSTANCE: invention relates to a composition which changes colour depending on the absorbed radiation dose, and use thereof as a UV radiation dose indicator. Described is a composition which changes colour depending on the absorbed radiation dose. The composition contains (a) an acid-sensitive dye and (b) a photolatent acid - sulphonyl oxime of formula . The invention also describes a method of determining radiation dose and a UV radiation dose indicator using a substrate coated with said composition. EFFECT: invention provides efficient determination of energy dose onto a substrate having said coating, and determination of critical parts of the coating, for which radiation is insufficiently intense to ensure sufficient curing. 11 cl, 10 tbl, 6 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 453 886 (13) C2 (51) МПК G03C 1/685 G03C 1/73 G01T 1/08 G03F 7/004 (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (21)(22) Заявка: 2009110250/05, 15.08.2007 (24) Дата начала отсчета срока действия патента: 15.08.2007 (73) Патентообладатель(и): ЦИБА ХОЛДИНГ ИНК. (CH) (43) Дата публикации заявки: 27.09.2010 Бюл. № 27 2 4 5 3 8 8 6 (45) Опубликовано: 20.06.2012 Бюл. № 17 (56) Список документов, цитированных в отчете о поиске: US 6004724 А, 21.12.1999. RU 2116634 С1, 27.07.1998. US 5028792 А, 02.07.1991. US 4736055 A, 05.04.1988. US 5237059 А, 17.08.1993. US 5296275 А, 22.03.1994. RU 2046302 C1, 20.10.1995. 2 4 5 3 8 8 6 R U (86) Заявка PCT: EP 2007/058422 (15.08.2007) C 2 C 2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 24.03.2009 (87) Публикация заявки РСТ: WO 2008/022952 (28.02.2008) Адрес для переписки: 105082, Москва, Спартаковский пер., 2, стр. 1, секция 1, этаж 3, "Евромаркпат" (54) ИНДИКАТОРЫ ДОЗЫ УФ-ИЗЛУЧЕНИЯ . (57) Реферат: Изобретение относится к композиции, меняющей цвет в зависимости от дозы поглощенного излучения, и ее применению в качестве индикатора дозы УФ- ...

Patent JPS576096B2

Photosensitive process for producing printed circuits employing electroless deposition

An adhesive system which provides adhesive compositions to be applied to an insulating base and form printed images thereon. The adhesive compositions include agents which render them photosensitive, and receptive to electroless metals.

Spiropyran compounds of piperidine or thiazine rings

The invention relates to spiropyran compounds. They have the general formula (I): ##STR1## in which: X represents the CH 2 group or a sulfur atom; R 1 and R 2 represent electron donor and/or acceptor groups selected for instance from the group NO 2 , COC 6 H 5 , CN, the halogens, the acyl substituents, alkoxy substituents, the hydrogen atom, the alkyl and mercaptoalkyl groups, the ethers of the formula CH 2 OR, thioethers of the formula CH 2 SR and amines of the formula CH 2 NR 2 in which R represents an alkyl group; R 3 is a linear or branched alkyl group, having 1 to 18 carbon atoms, or an arylalkyl or alkenyl group. --R 4 ,R 5 ,R 6 ,R 7 ,R 8 and R 9 have one of the meanings indicated for R 3 or represent, two by two, with the group in ortho position, a --(CH 2 ) n -- group in which n is a number between 5 and 10. R 10 represents a hydrogen atom if X=S and if X=CH 2 a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an arylalkyl group in which the alkyl group has 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 carbon atoms. The compounds in accordance with the invention have photochromic properties and are suitable for the recording of information on transparent or opaque supports.

Photochromic compositions, preparation thereof and articles made therefrom or coated therewith

The present invention relates to novel cross-linkable or crosslinked photochromic compositions, articles made from or coated with the compositions and method of making the compositions. The compositions contain (i) at least one segmented or non-segmented polyurethane-type or polyurethane-urea-type linear polymer having at least one non-terminal moiety that comprises at least one unsaturated group; and (ii) an effective amount of at least one photochromic organic compound, advantageously selected from spiroxazines, chromenes, spiropyrans fulgides and fulgimides.

Photochromic materials with reactive substituents

本发明公开内容的各种非限制性实施方案涉及含反应性取代基的光致变色材料。例如，本公开内容提供了光致变色材料，例如光致变色性萘并吡喃和具有反应性取代基的茚并稠合萘并吡喃，该反应性取代基包含通过一个或多个连接基与该光致变色性萘并吡喃连接的反应性结构部分。在某些非限制性实施方案中，所述反应性结构部分包括可聚合结构部分。在其它的非限制性实施方案中，所述反应性结构部分包括亲核结构部分或亲电结构部分。本公开内容的其它非限制性实施方案涉及光致变色制品、组合物和该光致变色制品的制备方法，其中该光致变色制品和组合物包含本文描述的光致变色性萘并吡喃。

Spiro-oxazine compounds and preparation thereof and photochromic shaped article

A spiro-oxazine compound of the formula (A): wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 independently represent hydrogen, (C1 or 2) alkyl, halogenated C 1-2 alkyl, C 1-2 alkoxy, halogen or nitro, R is unsubstituted or substituted phenyl or naphthyl, and n is 1 to 5, is valuable as a photochromic material and exhibits enhanced fatigue resistance in photocolorability. The spiro-oxazine compound is prepared by reacting a precursor of the spiro-oxazine compound of the formula (A), which has a substituent of the formula: -(CH 2 ) n - R in the nitrogen atom of the indoline nucleus, with an α-nitroso-β-naphthol.

Manufacture of a polymer device

(i) 기판상에 고분자 또는 올리고머 및 가교 결합 부분을 포함하는 용액을 증착시켜 층을 형성하는 단계와, (ii) 단계 (i)에서 형성된 층을 불용성 가교 결합 고분자를 형성하기 위한 조건하에 경화시키는 단계를 포함하고, 단계 (i)에서의 상기 가교 결합 부분은 용액 중의 고분자 또는 올리고머 및 가교 결합 부분의 총몰수를 기준으로 하여 0.05 내지 5 몰%의 양으로 존재하는 것을 특징으로 하는 고분자 소자의 제조 방법.  (i) depositing a solution comprising a polymer or oligomer and a crosslinking moiety on a substrate to form a layer, and (ii) curing the layer formed in step (i) under conditions for forming an insoluble crosslinking polymer. Wherein the crosslinking moiety in step (i) is present in an amount of 0.05 to 5 mole percent, based on the total moles of polymer or oligomer and crosslinking moiety in solution. Way.

PHOTOCHROMIC COMPOUNDS WITH A SPIRO STRUCTURE (INDOLINE- (2,3 ') - BENZOXAZINE) WITH A CYANO GROUP IN 6', AND THEIR USE IN THE FIELD OF OPHTHALMIC OPTICS

6'-cyano or phenylsulphonyl-substitued spiro[indoline-[2,3']-benzoxazine]-type photochromic compounds, wherein said cyano or phenylsulphonyl group is bound to the 6' carbon atom by the sulphur atom, and having a 7', 8'-condensed benzene ring, and use of same in ophthalmic optics.

Photochromatic recording material - contg indoline or benzothiazoline-spiropyrans ketones and doped oxides

Copies are prepd. by (a) exposing a photochromatic recording material consisting of a substrate supporting a photosensitive layer contg. a spiropyran cpd. having formulae : (where R1 and R2 each is 1-3C alkyl; r3 is 1-3C alkyl or Ph; R4 is H, halogen, or 1-3C alkyl or alkoxy; r5 is H, halogen, or -NO2; R6 is 1-6C alkyl, benzyl or phenyl-methyl; r7 is 1-3C alkyl, naphthyl, opt. halogen-substd. Ph, cyclohexyl or methoxy-, hydroxy- or thio-phenyl; R8 is H, OH or -S-Me and R9 is OH or 1-3C alkoxy), an aromatic or cyclic ketone and a semiconductive metal oxide doped with >=1 metals, using light of lambda 1 wave-length, falling within range of (I) or (II) absorption wave-lengths, and then (B) exposing recording material surface to light of lambda 2 wave-length, suitable for decompsn. of aromatic ketone in presence of an alcohol, and of a cyclic ketone in absence of an alcohol or reversing steps (a) and (b).

Patent FR2688782B1

Diazo type product contg. mica or having prelayer contg. mica - giving copy with a smooth fine grain appearance

HIGH CONDUCTIVITY IMAGE RECORDING MEDIUM

Light-sensitive emulsion contg. halo-hydrocarbon and N-vinyl cpd. - with phenol deriv. as antioxidant, improving keeping qualities

The light-sensitive compsn. comprises (1) a disperse phase in the form of individual particles of a light-sensitive combination of a chloro-, bromo- or iodo-hydrocarbon (I), which can form free radicals or ions on exposure with actinic light, an N-vinyl cpd. (II) which can become coloured under the influence of actinic light on (I) and, as antioxidant, a phenol deriv. (III) of the formula (in which R1 and R2 are H or 1-4 C alkyl; R3 is H, 1-4C alkyl or 1-4C alkoxyl) in an amt. of 0.001-0.1 wt. % of (II), in (2) a hydrophilic binder (IV), forming a solid film, in which (1) is practically insol. The matl. has high intrinsic speed and the addn. of (III) improves its keeping qualities with minimum redn. in the speed.

PHOTOSENSITIVE MATERIAL

Photochromic indilynic or benzothiazolic spiropyran compsn. - contg. vinyl chloride (co)polymer as binder, giving stable colour images

Photochromic compsns. which after colour formation are stable to light, darkness or heat, and do not require further development, comprise a dispersion ofindolynic- or benzothiazolic spiropyrans of formula (I) or (II) respectively in a binder comprising vinyl chloride homo- or copolymer contg. 50-100, pref. 80-90% vinyl chloride (where R1 is alkyl or phenyl, R2 is H, CH, Cl, Br, NO2, OMe or OEt, and R3 is H, Cl, Br, NO2, OMe or OEt; R4 is alkyl, phenyl, alkoxy, phenoxy or thioalkyl and R5 is H or alkyl, OMe or SMe). In a pref. embodiment the binder also contains 20-80% polyvinylidene chloride (PVDC). Prodn. of (positive) images either (a) from negatives by exposure to 2000-4000 angstroms radiation or (b) by photothermal recording process in which e.g. a thermal bead pref. at >=120 degrees C is used to inscribe a pattern and the background then stabilised by exposure to 2000-4000 Angstroms radiation. In (a) the unexposed parts may be used to superpose further images or may be permanently stabilised by the PVDC by exposure to pref. 1600-2600 Angstroms radiation.

New spirooxazines and their use in the field of ophthalmic optics.

Film manufacturing process

New products usable in photography and process for their preparation

HIGH-INTENSITY PHOTON IMAGE RECORDING

1. L'invention concerne un procédé d'enregistrement d'images de photons de haute intensité. 2. Le procédé est caractérisé en ce qu'il consiste à exposer un élément d'enregistrement sous forme d'une information à des rayons ultraviolets se situant dans la gamme de 200 à 400 nm de telle sorte que l'élément d'enregistrement reçoive une dose d'énergie de radiation d'au moins 1 x 10**7 erg/cm** 2, cet élément d'enregistrement contenant : (A) au moins un composé précurseur de colorant qui est un composé de spiropyranne ou un composé répondant à une des formules générales définies dans la spécification ci-dessus, et (B) au moins un composé organique sensible aux rayons ultraviolets et pouvant éliminer un atome d'halogène lors de l'exposition à des rayons ultraviolets. 3. L'invention est utilisée dans les procédés d'enregistrement au moyen d'un rayon laser dans lequel on forme des images en temps réel, c'est-à-dire que des images visibles sont formées directement au moment de l'irradiation de l'élément d'enregistrement sous forme d'une image. 1. The invention relates to a method for recording images of high intensity photons. 2. The method is characterized in that it comprises exposing a recording element as information to ultraviolet rays in the range of 200 to 400 nm so that the recording element receives a radiation energy dose of at least 1 x 10 ** 7 erg / cm ** 2, that recording element containing: (A) at least one dye precursor compound which is a spiropyran compound or a compound corresponding to one of the general formulas defined in the above specification, and (B) at least one organic compound sensitive to ultraviolet rays and capable of eliminating a halogen atom upon exposure to ultraviolet rays. 3. The invention is used in the recording methods by means of a laser beam in which images are formed in real time, that is, visible images are formed directly at the time of irradiation ...

Patent FR2409992B1