24-03-2016 дата публикации
Номер: US20160083901A1
Принадлежит:
Nanoparticle treated fibrous articles, such as fabrics, fibers, filaments, or yarns, include a plurality of exposed, nonionic metal nanoparticles non-covalently affixed thereto. Metal nanoparticles, particularly spherical-shaped metal nanoparticles which have solid cores, can be strongly affixed to fibrous articles without covalently bonds and/or without being encapsulated within a polymer or adhesive. Spherical metal nanoparticles appear to adhere to fibrous articles by Van der Waals forces. Because they are nonionic, spherical nanoparticles are not easily removed by solvents, water, surfactants, and soaps and remain after several washings, sometimes up to 50 or more washings. Nonetheless, they readily detach from fibrous articles when contacted by microbes and then kill or denature the microbes. Coral-shaped nanoparticles can be used in conjunction with spherical nanoparticles to assist in affixing the spherical nanoparticles and/or by themselves or in combination with spherical particles to kill or denature microbes. 1. A nanoparticle treated fibrous article , comprising:a fibrous article selected from a fabric, fiber, filament, or yarn; anda plurality of exposed, nonionic metal nanoparticles non-covalently affixed to the fibrous article.2. A nanoparticle treated fibrous article as in claim 1 , wherein the nonionic metal nanoparticles comprise at least one metal selected from the group consisting of silver claim 1 , gold claim 1 , platinum claim 1 , palladium claim 1 , rhodium claim 1 , osmium claim 1 , ruthenium claim 1 , rhodium claim 1 , rhenium claim 1 , molybdenum claim 1 , copper claim 1 , iron claim 1 , nickel claim 1 , tin claim 1 , beryllium claim 1 , cobalt claim 1 , antimony claim 1 , chromium claim 1 , manganese claim 1 , zirconium claim 1 , tin claim 1 , zinc claim 1 , tungsten claim 1 , titanium claim 1 , vanadium claim 1 , lanthanum claim 1 , cerium claim 1 , heterogeneous mixtures thereof claim 1 , and alloys thereof.3. A nanoparticle treated ...
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