18-10-2018 дата публикации
Номер: US20180298023A1
Принадлежит:
The present invention is directed to polyisocyanates and polyurethanes derived therefrom. In various embodiments, the present invention provides polyisocyanates, methods of making the polyisocyanates from fused bicyclic alcohols, polyurethanes, and methods of making the polyurethanes from the polyisocyanates. 1. (canceled)324. The method of claim , wherein m=n=1.42425. The method of any one of claims - , wherein the acid anhydride is succinic anhydride.52426. The method of any one of claims - , wherein the acyl halide generator is at least one of thionyl chloride , thionyl bromide , phosphorous pentachloride , phosphorus pentabromide , cyanuric fluoride , phosgene , diphosgene , triphosgene , oxalyl chloride , phosphorus tribromide , phosphorus trichloride , and phosphoryl chloride.62427. The method of any one of claims - , wherein the azide generator is at least one of sodium azide , trimethylsilyl azide , triethylsilyl azide , lithium azide , potassium azide , tetrabutylammonium azide , tert-butyldimethylsilyl azide , and tert-butyldiphenylsilyl azide.72428. The method of any one of claims - , wherein contacting the polyacyl halide with an azide generator provides a polyacyl azide having the structure of Formula (I) wherein R″=—C(O)N , wherein the polyacyl azide undergoes a Curtius rearrangement to provide the polyisocyanate.82429. The method of any one of claims - , wherein the contacting the polyacyl halide and the azide generator is performed in a biphasic solution comprising at least an aqueous phase and an organic phase and optionally further comprising a phase transfer catalyst.9. The method of claim 2 , wherein R′ is unsubstituted.10. The method of claim 2 , wherein R′ is —CH—CH—.11. The method of claim 2 , wherein rings A and B are unsubstituted with the exception of the ester substituents including R′ and R″.12. The method of claim 2 , wherein m=n=1 claim 2 , and one of the ester substituents including R′ and R″ is alpha to at least one carbon atom shared ...
Подробнее