18-10-2018 дата публикации
Номер: US20180297016A1
Принадлежит:
Provided is a catalyst for the selective reduction of NOx comprising a two molecular sieve materials having a CHA structure, wherein the first molecular sieve has a mean crystal size of about 0.01 to 1 μm and the second molecular sieve has a mean crystal size of about 1-5 μm, and wherein the first molecular sieve contains a first extra-framework metal, the second molecular sieve contains a second extra-framework metal, and wherein said first and second extra-framework metals are independently selected from the group consisting of cesium, copper, nickel, zinc, iron, tin, tungsten, molybdenum, cobalt, bismuth, titanium, zirconium, antimony, manganese, chromium, vanadium, niobium, and combinations thereof. 1. A catalyst composition comprising a blend of two molecular sieve materials each having a CHA structure , wherein the first molecular sieve has a first silica-to-alumina ratio (SAR) of about 10-25 and contains a first extra-framework metal , the second molecular sieve has second SAR of about 20-35 and contains a second extra-framework metal , and wherein said first and second SAR are different and said first and second extra-framework metals are independently selected from the group consisting of cesium , copper , nickel , zinc , iron , tin , tungsten , molybdenum , cobalt , bismuth , titanium , zirconium , antimony , manganese , chromium , vanadium , niobium , and combinations thereof ,and wherein at least one of the first and second extra-framework metals comprises manganese.2. The catalyst of claim 1 , wherein the two molecular sieve materials are aluminosilicates.3. The catalyst of claim 1 , wherein said first and second extra-framework metals are independently selected from the group consisting of copper claim 1 , iron claim 1 , and manganese claim 1 , and wherein at least one of the first and second extra-framework metals comprises manganese.4. The catalyst of claim 1 , wherein at least one of the first molecular sieve and the second molecular sieve is an ...
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