10-09-1957 дата публикации
Номер: GB1053105A
Автор:
Принадлежит:
1,053,105. Semi-conductor devices. INTERNATIONAL BUSINESS MACHINES CORPORATION. Aug. 18, 1964 [Aug. 19, 1963], No. 33635/64. Heading H1K. A plurality of PN junction devices are simultaneously manufactured by coating selected areas of a semi -conductor wafer of one conductivity type with metal, immersing the coated wafer in a melt saturated with said metal and containing also dopant characteristic of the opposite conductivity type, withdrawing the wafer with dopant combining material adhering to the coated areas, cooling, and then heating to form alloy junctions beneath the films. In a typical case pairs of holes 12, 13 (Fig. 3) are formed by photo-engraving in a film consisting of silicon oxide overlaid with glass (the method of making which is described) on a degenerate P-type germanium or gallium arsenide wafer. Gold, silver or, with germanium, copper is vapour deposited into the holes through an apertured molybdenum mask. After dipping in solder flux the wafer is slowly heated to 200 C. and then plunged into the melt. This contains a solid lump of the vapour deposited metal and consists of arsenic and tin, or arsenic, lead and tin if the wafer is germanium or of tin, tin-gold alloy, or indium or gold doped with tin, sulphur, selenium or tellurium if the wafer is gallium arsenide. After withdrawal from the melt and cooling, the wafer is reheated to 500-600 C. to form PN junctions beneath the holes. The metal residues are then etched away and replaced by evaporated gold contacts. which for use with germanium are doped with antimony. After annealing at 400 C. to reduce the peak currents of the resulting tunnel diodes the wafer is split into devices each containing one small and one large junction. The devices which may then be further annealed are used with the small junction forward biased.
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