05-05-2023 дата публикации
Номер: CN116063164A
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The invention discloses a method for preparing 2, 5-hexanedione by using 5-chloromethylfurfural, which comprises the following steps: adding 5-chloromethylfurfural, a catalyst, polymethylhydrosiloxane, tetrahydrofuran and water into a thick-wall pressure bottle, and catalyzing the 5-chloromethylfurfural to synthesize the 2, 5-hexanedione. According to the method, polymethylhydrosiloxane is used as one of the raw materials for the first time, efficient synthesis of 2, 5-hexanedione is achieved through 5-chloromethylfurfural, and the used raw material 5-chloromethylfurfural can be directly prepared from biomass at a high yield. The polymethylhydrosiloxane is low in price, non-toxic and stable, the reaction process is safe, green and environment-friendly, the product selectivity is high, the yield of the 2, 5-hexanedione exceeds that of all reaction systems which take 5-hydroxymethylfurfural as a raw material and are reported at present, and the method has great industrial application value ...
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