09-02-2017 дата публикации
Номер: US20170040123A1
Принадлежит:
Disclosed here is a method for making a nitrogen-doped carbon aerogel, comprising: preparing a reaction mixture comprising formaldehyde, at least one nitrogen-containing resorcinol analog, at least one catalyst, and at least one solvent; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel; and thermally annealing the dry gel to produce the nitrogen-doped carbon aerogel. Also disclosed is a nitrogen-doped carbon aerogel obtained according to the method and a supercapacitor comprising the nitrogen-doped carbon aerogel. 1. A method for making a nitrogen-doped carbon aerogel , comprising:preparing a reaction mixture comprising formaldehyde, at least one nitrogen-containing resorcinol analog, at least one catalyst, and at least one solvent;curing the reaction mixture to produce a wet gel;drying the wet gel to produce a dry gel; andthermally annealing the dry gel to produce the nitrogen-doped carbon aerogel.2. The method of claim 1 , wherein the resorcinol analog is selected from (a) an aromatic compound comprising a nitrogen-containing ring linked to at least two hydroxyl groups and (b) an aromatic compound comprising a benzene ring or nitrogen-containing ring linked to at least one hydroxyl group and at least one amine group claim 1 , wherein the nitrogen-containing ring is selected from the group consisting of pyridine claim 1 , pyrazine claim 1 , pyrimidine claim 1 , pyridazine claim 1 , pyrrole claim 1 , pyrazole and imidazole.3. The method of claim 1 , wherein the resorcinol analog is pyridinediol.4. The method of claim 1 , wherein the resorcinol analog is aminophenol.5. The method of claim 1 , wherein the solvent is water and/or an organic solvent.6. The method of claim 1 , wherein the catalyst is selected from the group consisting of acetic acid claim 1 , nitric acid claim 1 , ascorbic acid claim 1 , hydrochloric acid claim 1 , sulfuric acid claim 1 , sodium carbonate claim 1 , sodium hydroxide claim 1 , ammonium hydroxide ...
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