02-11-2011 дата публикации
Номер: CN0101955452B
Автор:
WANG ZHIQIANG,
GUO TONGXIN,
WANG PINGSHENG,
YUE FALIANG,
CHEN HEQUN,
SHI ZONGHAO,
XU ZHISONG,
WANG FEI,
ZHIQIANG WANG,
TONGXIN GUO,
PINGSHENG WANG,
FALIANG YUE,
HEQUN CHEN,
ZONGHAO SHI,
ZHISONG XU,
FEI WANG
Принадлежит:
The invention provides a method for preparing zinc dibenzyl dithiocarbamate (ZBDC) thiofide, which comprises that: the raw materials used are dibenzylamine, carbon disulfide, sodium hydroxide and anionic surfactant, wherein the stoichiometric molar ratio of dibenzylamine to carbon disulfide to sodium hydroxide and anionic surfactant to zinc chloride to sulfuric acid is 1:1.05-1.2:1.05-1.2:0.020-0.025:0.53-0.58:0.005-0.015; and the process comprises: adding dibenzylamine, carbon disulfide, sodium hydroxide and anionic surfactant in a given amount into a reaction kettle holding purified water with stirring in turn, lower the temperature by 10 to 20 DEG C totally, dripping carbon disulfide liquid in a given amount within 6 to 7 hours, stirring for 0.5 to 1 hours after the dripping is finished, keeping the temperature at 30 to 38 DEG C constantly, dripping solution of zinc chloride, performing replacement reaction, regulating the pH value of the reaction liquid to 7 to 9 with sulfuric acid ...
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