Catalyst of nickel compound and ligand in presence of a reducing metal

Aryl and heteroaryl mono chlorides are coupled in an aprotic solvent under an inert atmosphere by a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal.

Polymerization of haloalkynes by a nickel catalyst

Haloalkynes are polymerized to polyunsaturated compounds with a catalyst mixture consisting of a nickel compound, and a ligand in the presence of a reducing metal.

Integrated process for the preparation of substantially linear high molecular weight thermoplastic polymers from aryl polyhalide monomers

Described herein is an integrated process for the preparation of substantially linear high molecular weight thermoplastic polymers derived from aryl polyhalide monomers. Aryl polyhalide monomers are first prepared by the reaction of an alkali metal salt of a phenol compound, e.g., dipotassium salt of bisphenol A, with a dihalobenzenoid compound, e.g., 4,4'-dichlorophenylsulfone, in a liquid phase of an aprotic solvent and an azeotrope former, e.g., toluene. Water is removed from the reaction mass as an azeotrope until substantially anhydrous conditions are attained. The aryl polyhalide monomers are then coupled by contacting the monomers with a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal, e.g., zinc, and an aprotic solvent under substantially anhydrous conditions to form substantially linear high molecular weight thermoplastic polymers.

Reduction of organic halides

Organic halides are reduced to a dechlorinated products with a catalyst mixture consisting essentially of a nickel compound, a triarylphosphine and a halide ion, in the presence of reducing means for maintaining nickel in the zero valent state.

Modified waterborne phenoxy resins

Waterborne, neutralized, carboxyl-bearing phenoxy resin with which is blended a relatively soft, neutral, non-carboxyl-bearing modifier resin. A coalescing solvent is preferably included in the aqueous blend.

Crosslinkable, crystallizable polyarylethers and composites therefrom

Described herein are tough solvent resistant materials from a crystallizable, crosslinkable resin mixture comprising a particular polyarylether and a crystallization promoting plasticizer, and reinforced composites made from such resin mixture.

Coupling of aryl and heteroaryl mono chlorides

Aryl and heteroaryl mono chlorides are coupled in an aprotic solvent under an inert atmosphere by a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal.

High-temperature, aromatic coating materials from aryl polyhalides

High-temperature coating materials are prepared by cross-linking copolymers of oligomers produced by nickel catalyzed coupling of unsubstituted aryl polyhalides with substituted organic halides.

Novel vinyl chloride resins and compositions incorporating such resins

Novel vinyl chloride copolymers including a hydroxyalkyl acrylate or metacrylate or allyl alcohol, an acid functionality from carboxylic acid-containing monomers and optionally an epoxy-containing vinyl monomer in selected proportions provide suitable binder resins for applications such as magnetic recording media, imparting enhanced dispersion and magnetic property characteristics while also having desirable rheological characteristics and, when the epoxy-containing vinyl monomer is used, desirable thermal stability.

Flexible, self-cross-linking binders

Flexible, self-cross-linking binders, useful for, e.g., paints and magnetic media composites, are prepared from hydroxyl-containing thermoplastic polymers reacted with condensates of diisocyanates and unsaturated esters. They can be cured with an electron beam.

Formable coatings

A coating composition capable of substantial deformation without loss of continuity, adhesion or protective properties. The coating composition comprises a phenoxy resin mixed with a relatively soft modifier resin having certain specific properties. In a preferred embodiment, a particulate material, such as a zinc pigment, may also be included. A crosslinker may also be included.

Phosphorylated reaction products and compositions incorporating such products

Novel phosphorylated compositions of a vinyl chloride copolymer or terpolymer, a phenoxy resin, a hydroxyalkyl acrylate or methacrylatelactone adduct or a reaction product of a normally solid pendant-hydroxyl-containing thermoplastic polymer having at least 8 hydroxyl groups per molecular chain and an adduct which is the product of either a hydroxylalkyl acrylate or methacrylate or a lactone-acrylate adduct and an organic diisocyanate having improved dispersion characteristics suitable for use in applications such as magnetic recording media.

Preparation of substituted olefins

Substituted olefins are prepared by the reaction of an organic halide with an olefin in the presence of a catalyst derived from zinc, a triarylphosphine and a nickel salt.

STABLE AQUEOUS DISPERSIONS OF BIOCIDES

An aqueous dispersion containing BIT and IPBC prepared using nonionic and anionic surfactants exhibits both chemical and physical stability and is suitable for use as a single product which is capable of imparting to a coating composition a high level of resistance against attack by a broad spectrum of organisms, including bacteria, fungi and algae, in both the wet-state and dry film-state. 1. A composition useful for providing resistance to microbiological attack in both a wet state and a dry film state in a single dose , wherein the composition is comprised of:a) water;b) 1% to 12% by weight 1,2-benzisothiazolin-3-one (BIT);c) 2% to 50% by weight 3-iodo-2-propynl butyl carbamate (IPBC), wherein BIT and IPBC are present in amounts effective to provide a weight ratio of BIT:IPBC of from 0.02 to 2;d) at least one nonionic surfactant;e) at least one anionic surfactant; and 'wherein d) and e) are present in an amount effective to provide the composition in the form of a stable aqueous dispersion.', 'f) at least one thickener/suspending agent, in an amount effective to provide the composition with a viscosity of at least 300 centipoise at 25° C.;'}2. The composition of claim 1 , comprising at least two different nonionic surfactants.3. The composition of claim 1 , comprising at least one alkoxylated aliphatic or aromatic mono-alcohol.4. The composition of claim 1 , comprising at least two different alkoxylated aliphatic mono-alcohols.5. The composition of claim 1 , comprising a first alkoxylated aliphatic mono-alcohol and a second alkoxylated aliphatic mono-alcohol each having an aliphatic mono-alcohol segment and an alkoxylated segment claim 1 , wherein the second alkoxylated aliphatic mono-alcohol differs from the first alkoxylated aliphatic mono-alcohol with respect to at least one of a) chain length of the aliphatic mono-alcohol segment claim 1 , b) composition of the alkoxylated segment claim 1 , or c) number of oxyalkylene units in the alkoxylated segment.6. The ...

MODIFIED VATTENBURNA FENOXIHARTSER.

Flexible, self-cross-linking binders

Flexible, self-cross-linking binders, useful for, e.g., paints and magnetic media composites, are prepared from hydroxyl-containing thermoplastic polymers reacted with condensates of diisocyanates and unsaturated esters. They can be cured with an electron beam.

Coupling of aryl and heteroaryl mono chlorides

Aryl and heteroaryl mono chlorides are coupled in an aprotic solvent under an inert atmosphere by a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal.

CROSSLINKABLE CRYSTALLIZABLE POLYARYLERS AND THEIR APPLICATION TO COMPOSITE FORMATION

L'INVENTION CONCERNE UN MELANGE A BASE DE RESINE RETICULABLE CRISTALLISABLE. ELLE A PLUS PARTICULIEREMENT TRAIT A DES MATIERES TENACES RESISTANT AUX SOLVANTS OBTENUES A PARTIR D'UN MELANGE A BASE DE RESINE RETICULABLE CRISTALLISABLE COMPRENANT UN POLYARYLETHER PARTICULIER ET UN PLASTIFIANT ACTIVATEUR DE CRISTALLISATION. APPLICATION A LA REALISATION DE COMPOSITES ARMES OBTENUS A PARTIR D'UN TEL MELANGE A BASE DE RESINE. THE INVENTION RELATES TO A MIXTURE BASED ON A CRYSTALLIZABLE CROSS-LINKABLE RESIN. IT HAS MORE PARTICULARLY DEALING WITH STRENGTH MATERIALS RESISTANT TO SOLVENTS OBTAINED FROM A MIXTURE BASED ON A CRYSTALLIZABLE RESIN CONTAINING A PARTICULAR POLYARYLETHER AND A PLASTICIZER CRYSTALLIZATION ACTIVATOR. APPLICATION TO THE MAKING OF ARMED COMPOSITES OBTAINED FROM SUCH A RESIN-BASED MIXTURE.

Coupling of aryl and heteroaryl monochlorides; catalyst composition

MOLDING COAT COMPOSITION AND CORROSION RESISTANT ITEM

Integrated process for the preparation of substantially linear high molecular weight thermoplastic polymers from aryl polyhalide monomers

Described herein is an integrated process for the preparation of substantially linear high molecular weight thermoplastic polymers derived from aryl polyhalide monomers. Aryl polyhalide monomers are first prepared by the reaction of an alkali metal salt of a phenol compound, e.g., dipotassium salt of bisphenol A, with a dihalobenzenoid compound, e.g., 4,4'-dichlorophenylsulfone, in a liquid phase of an aprotic solvent and an azeotrope former, e.g., toluene. Water is removed from the reaction mass as an azeotrope until substantially anhydrous conditions are attained. The aryl polyhalide monomers are then coupled by contacting the monomers with a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal, e.g., zinc, and an aprotic solvent under substantially anhydrous conditions to form substantially linear high molecular weight thermoplastic polymers.

Vinyl chloride resins and compositions incorporating such resins

Phosphorylated reaction products and compositions incorporating such products

NOVEL PHOSPHORYLATED REACTION PRODUCTS AND COMPOSITIONS INCORPORATING SUCH PRODUCTS ABSTRACT Novel phosphorylated compositions of a vinyl chloride copolymer or terpolymer, a phenoxy resin, a hydroxyalkyl acrylate or methacrylate-lactone adduct or a reaction product of a normally solid pendant-hydroxyl-containing thermoplastic polymer having at least 8 hydroxyl groups per molecular chain and an adduct which is the product of either a hydroxylalkyl acrylate or methacrylate or a lactone-acrylate adduct and an organic diisocyanate having improved dispersion characteristics suitable for use in applications such as magnetic recording media.

FORMABLE EPOXY COATING AGENTS

Stable aqueous dispersions of biocides

An aqueous dispersion containing BIT and IPBC prepared using nonionic and anionic surfactants exhibits both chemical and physical stability and is suitable for use as a single product which is capable of imparting to a coating composition a high level of resistance against attack by a broad spectrum of organisms, including bacteria, fungi and algae, in both the wet-state and dry film-state.

Method of stabilizing biocidal compositions of haloalkynyl compounds

This invention is directed to a method for stabilizing a composition which comprises a mixture of a halopropargyl compound. The composition can be used broadly in industrial systems and more particularly with substrates such as paints, coatings, stucco, concrete, stone, cementaceous surfaces, wood, caulking, sealants, textiles, and the like.

PHOSPHORYLATED REACTION PRODUCTS AND COMPOSITIONS CONTAINING SUCH PRODUCTS.

Novel phosphorylated compositions of a vinyl chloride copolymer or terpolymer, a phenoxy resin, a hydroxyalkyl acrylate or methacrylate-­lactone adduct or a reaction product of a normally solid pendant-hydroxyl-containing thermoplastic polymer having at least 8 hydroxyl groups per molecular chain and an adduct which is the product of either a hydroxyalkyl acrylate or methacrylate or a lactone-acrylate adduct and an organic diisocyanate having improved dispersion characteristics suitable for use in applications such as magnetic recording media.

Crosslinkable, crystallisable polyaryl ethers, and corresponding composite materials

Non-aqueous compositions containing a haloalkynyl compound and a buffer for providing biocidal activity and for stabilizing end-use formulations

Crosslinkable, crystallizable, polyarylethers and composites therefrom

CROSSLINKABLE, CRYSTALLIZABLE POLYARYLETHERS AND COMPOSITES THEREFROM ABSTRACT OF THE DISCLOSURE Described herein are tough solvent resistant materials from a crystallizable, crosslinkable resin mixture comprising a particular polyarylether and a crystallization promoting plasticizer, and reinforced composites made from such resin mixture.

Coupling of aryl and heteroaryl monochlorides

Aryl and heteroaryl mono chlorides are coupled in an aprotic solvent under an inert atmosphere by a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal; catalyst composition comprising a nickel compound, at least one ligand, magnesium or manganese, and a promoter.

Modified waterbone phenoxy resins

Waterborne, neutralized, carboxyl-bearing phenoxy resin with which is blended a relatively soft, neutral, non-carboxyl-bearing modifier resin. A coalescing solvent is preferably included in the aqueous blend.

Formable coatings

A coating composition capable of substantial deformation without loss of continuity, adhesion or protective properties. The coating composition comprises a phenoxy resin mixed with a relatively soft modifier resin having certain specific properties. In a preferred embodiment, a particulate material, such as a zinc pigment, may also be included. A crosslinker may also be included.

Modified aqueous phenoxy resins.

Coupling of aryl and heteroaryl monochlorides

AUXILIARY COATING MATERIALS CONTAINING A NEUTRALIZED, CARBOXYL-BEARING PHENOXY RESIN AND PROCEDURE FOR ITS MANUFACTURING

Halogen propargyl-containing biocidal material and paints, where included

Catalytically active composition for coupling aryl and heteroaryl mono chlorides

Formable coatings

ABSTRACT A coating composition capable of substantial deformation without loss of continuity, adhesion, or protective properties. The coating composition comprises a phenoxy resin mixed with a relatively soft modifier resin having certain specific properties. In a preferred embodiment, a particulate material, such as a zinc pigment, may also be included. A crosslinker may also be included.

Phosphorylated reaction products and compositions incorporating such products

Novel phosphorylated compositions of a vinyl chloride copolymer or terpolymer, a phenoxy resin, a hydroxyalkyl acrylate or methacrylate-­lactone adduct or a reaction product of a normally solid pendant-hydroxyl-containing thermoplastic polymer having at least 8 hydroxyl groups per molecular chain and an adduct which is the product of either a hydroxyalkyl acrylate or methacrylate or a lactone-acrylate adduct and an organic diisocyanate having improved dispersion characteristics suitable for use in applications such as magnetic recording media.

Integriertes verfahren zur herstellung von im wesentlichen linearen hochmolekularen thermoplastischen polymeren aus polyhalogenaryl- monomeren.

Verknuepfung von aryl- und heteroaryl-polyhaliden.

Katalytisch aktive zusammensetzung zur kupplung von aryl und heteroarylmonochloriden.

Nicht-wässrige zusammensetzungen enthaltend eine haloalkynyl-verbindung und einen puffer zur verleihung biozider eigenschaften und zur stabilisierung der endformulierungen

Wässrige zusammensetzungen enthaltend eine haloalkynyl-verbindung und einen puffer zur verleihung biozider eigenschaften und zur stabilisierung der endformulierungen

Modifizierte wässrige phenoxyharze.

Stable aqueous dispersions of biocides

An aqueous dispersion containing BIT and IPBC prepared using nonionic and anionic surfactants exhibits both chemical and physical stability and is suitable for use as a single product which is capable of imparting to a coating composition a high level of resistance against attack by a broad spectrum of organisms, including bacteria, fungi and algae, in both the wet-state and dry film-state.