02-06-2016 дата публикации
Номер: US20160152782A1
Принадлежит:
Arkema France
The invention concerns a method for the surface crosslinking of a polymer, in particle form, having one or a plurality of labile hydrogen functions, comprising a step of implementing a crosslinking agent comprising at least two functions likely to react with the labile hydrogen functions of the polymer, the crosslinking method being carried out at a temperature lower than the melting point of the polymer. The invention also concerns a powder particle and the uses of same. 1. A process for the surface crosslinking of a polymer , in particle form , having one or more labile-hydrogen functions , comprising a step using a crosslinking agent comprising at least two functions capable of reacting with the labile-hydrogen functions of the polymer , the crosslinking process being carried out at a temperature lower than the melting point of the polymer.2. The process as claimed in claim 1 , wherein the polymer is selected from the group consisting of polymers comprising one or more amide functions.3. The process as claimed in claim 2 , wherein the polymer is selected from the group consisting of polyamides and polyamide-imides and blends thereof.4. The process as claimed in claim 3 , wherein the polymer is selected from the group consisting of PA6 claim 3 , PA11 claim 3 , PA12 claim 3 , PA6/12 claim 3 , PA6.12 claim 3 , PA6.10 claim 3 , PA10.10 claim 3 , PA10.12 claim 3 , PA6.6 claim 3 , PA8 claim 3 , PA4 and PA4.6 claim 3 , and blends of these polymers.5. The process as claimed in claim 4 , wherein the polymer is PA12.6. The process as claimed in claim 1 , wherein the polymer particles have an average diameter which ranges from 1 to 200 μm.7. The process as claimed in claim 1 , wherein the crosslinking agent is selected from the group consisting of a) compounds bearing one or more of the following functions: isocyanate claim 1 , carbodiimide claim 1 , epoxy claim 1 , acyllactam claim 1 , oxazoline and its isomers claim 1 , oxazine and its isomers claim 1 , and b) PCI.8. The ...
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