02-05-2019 дата публикации
Номер: US20190127859A1
Автор:
Muthukumar Nagu,
Amutha Nagarajan,
Paul Robert Frail,
Edward Joseph Urankar,
NAGU MUTHUKUMAR,
NAGARAJAN AMUTHA,
FRAIL PAUL ROBERT,
URANKAR EDWARD JOSEPH,
Nagu, Muthukumar,
Nagarajan, Amutha,
Frail, Paul Robert,
Urankar, Edward Joseph
Принадлежит:
Compositions and methods for inhibiting corrosion of metallic surfaces in contact with an aqueous medium such as copper, copper alloy, and steel surfaces of an open recirculating cooling water system. In certain embodiments, an aromatic triazole having an anionic substituent bonded to a nitrogen atom of the triazole (ANST) is used as the corrosion inhibitor. In other embodiments, the corrosion inhibitor is a reaction product of an aromatic triazole and an aldehyde (ATA). 2. (canceled)3. The composition as recited in claim 1 , wherein{'sub': '1', 'Ris phosphate, sulfate, sulfonate, phosphonate, or carboxy group or alkali metal or alkaline earth metal salts thereof or;'}{'sub': 1', '3', '(n)', '3', '1', '6', '1', '6', '1', '6, 'Ris —RZwherein n is an integer of 1 or greater, each Z is independently chosen from carboxy, phosphate, sulfate, sulfonate, phosphonate, or alkali metal or alkaline earth metal salts thereof, and Ris C-Calkyl, C-Calkoxy, or C-Chydroxylated alkyl.'}5. The composition as recited in claim wherein R and R′ are both H or R is H and R′ is methyl.6. The composition as recited in claim wherein Ris COOH claim 1 , SOH claim 1 , or RZwherein Ris CHZ is COOH and n=1; Ris —CHCH— and Z is COOH claim 1 , n=2; Ris C-Chydroxylated alkyl claim 1 , Z=sulfonate and n=1; or Ris CHZ is phosphonate and n=1.7. The composition as recited in claim 6 , wherein Ris RZwherein Ris 2-hydroxypropyl claim 6 , or 1-hydroxypropyl claim 6 , and Z is sulfonate and n=1.8. The composition as recited in claim 6 , wherein Ris RZ(n) wherein Ris CHZ is phosphonate and n=1.9. The composition as recited in claim 6 , wherein Ris COOH.10. The composition as recited in claim 6 , wherein Ris RZ(n) wherein Ris CHZ is carboxy and n is 1.11. The composition as recited in claim 6 , wherein Ris RZ(n) wherein Ris —CH—CH claim 6 , Z is carboxy and n is 2.12. The composition as recited in claim 6 , wherein Ris SOH.13. A method of inhibiting corrosion of metal surfaces in contact with an aqueous ...
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