Piperazine Compounds Whith a Herbicidal Action

The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, the variables have the following meanings: R1 is selected from the group consisting of halogen, cyano, nitro, ZC(O)R11, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R11 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen ...

Piperazine compounds with a herbicidal action

The invention relates to the use of piperazine compounds of formula (I) or the agriculturally useful salts of piperazine compounds of formula (I) as herbicides, the variables in formula (I) being defined as cited in the claims and the description.

Benzoyl-Substituted Alanines

The present invention relates to benzoyl-substituted alanines of the formula I in which the variables R1 to R12 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Temperature-stable soft-magnetic powder

A soft-magnetic powder coated with a silicon-based coating, wherein the silicon-based coating comprises at least one fluorine containing composition of formula (I), Si 1-0.75c M c O 2-0.5c F d (I), wherein c is in the range of 0.01 to 0.5, d is in the range of 0.04 to 2, and M is B or Al.

NANOPARTICULATE COPPER COMPOUNDS

The present invention relates to processes for the preparation of surface-modified nanoparticulate copper compounds and of aqueous suspensions which comprise surface-modified nanoparticulate copper compounds. The invention furthermore relates to the surface-modified nanoparticulate copper compounds obtainable by these processes and aqueous suspensions of these copper compounds and their use as an antimicrobial active substance or catalyst.

Crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoroethoxymethyl)benzoyl]cyclohexan-1,3-dione

The present invention relates to two crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoro-ethoxymethyl)benzoyl]cyclohexan-1,3-dione, which is also known under the common name tembotrione. The invention also relates to a process for the production of these crystalline forms and formulations for plant protection which contain one of these crystalline forms of tembotrione.

Benzoyl-Substituted Alanines

The present invention relates to benzoyl-substituted alanines of the formula I in which the variables R1 to R13 are as defined in the description, and to agriculturally useful salts thereof, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Heteroaroyl-Substituted Serine Amides

The present invention relates to heteroaroyl-substituted serinamides of the formula (I) in which the variables A and R1 to R6 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Heteroaroyl-Substituted Serineamides

The present invention relates to heteroaroyl-substituted serineamides of the formula I in which the variables A and R 1 to R 6 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Piperazine Compounds With Herbicidal Action

The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, A1, A2 independently of one another are aryl or heteroaryl, where Ra is attached in the ortho-position to the point of attachment of A1 to a carbon atom or a nitrogen atom of A1, Y1, Y2 are oxygen, sulfur or a group NRy1, and the variables Ra, Rb, Rc, Rd, Re, Rf, R1, R2, R3, R4, R5, R6, R7, and R8 have the meanings mentioned in the claims and the description.

Heteroaroyl-substituted serineamides

The present invention relates to heteroaroyl-substituted serineamides of the formula I in which the variables A and R 1 to R 6 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Method for Preparation of Piperazindione Derivatives

A process for preparing piperazinedione derivatives of the formula I in which R1 is hydrogen, alkyl, alkenyl, alkynyl and alkylcarbonyl, R2 is hydrogen, alkyl, alkenyl, C3-C4-alkynyl and C(═O)R11, R3, R4 are each hydrogen, alkyl and haloalkyl, where the groups may be substituted, which comprises reacting amines of the formula II H2N—R1 II in which R1 is hydrogen and alkyl which may optionally be substituted with N-acylated amino acid derivatives of the formula III in which X is halogen, Y is halogen, alkoxy or phenyloxy which may be substituted and R2, R3 and R4 are each as defined at the outset, under basic conditions in an aqueous solvent.

Benzoyl-Substituted Serineamides

The present invention relates to benzoyl-substituted serineamides of the formula I in which the variables Het and R1 to R10 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Benzoyl-substituted serineamides

The present invention relates to benzoyl-substituted serinamides of the formula I in which the variables R1 to R11 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Substituted pyridines having a herbicidal effect

Substituted pyridines of the formula I in which the variables are defined according to the description, their agriculturally suitable salts, processes and intermediates for preparing the pyridines of the formula I, compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one pyridine compound of the formula I to act on plants, their seed and/or their habitat.

Piperazine Compounds with Herbicidal Effect

Piperazine compounds of the formula I in which the variables are defined according to the description, their agriculturally suitable salts, processes and intermediates for preparing the piperazine compounds of the formula I, compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one piperazine compound of the formula I to act on plants, their seed and/or their habitat.

Piperazine Compounds with a Herbicidal Action

The present invention relates to the use of piperazine compounds of the formula I or of the agriculturally useful salts of piperazine compounds of the formula I as herbicides, where in formula I the variables are as defined in the claims and the description. Moreover, the invention relates to compositions comprising, in addition to auxiliaries customary for formulating crop protection agents, piperazine compounds of the formula I or agriculturally useful salts of I, and to a process for preparing these compositions. Furthermore, the invention relates to certain piperazine compounds of the formula I, a process for preparing piperazine compounds of the formula I and a method for controlling unwanted vegetation which comprises treating plants, their seeds and/or their habitat with at least one piperazine compound of the formula I.

Heteroaroyl-Substituted Serineamides

The present invention relates to heteroaroyl-substituted serinamides of the formula I in which the variables A, Het and R1 to R5 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Piperazine Compounds Having Herbicidal Action

The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, ZC(O)R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4 ...

Benzoyl-Substituted Serineamides

The present invention relates to benzoyl-substituted serineamides of the formula I in which the variables R 1 to R 11 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Heteroaroyl-substituted Alanines

The present invention relates to heteroaroyl-substituted alanines of the formula I in which the variables A and R1 to R7 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Heteroaroyl-substituted serine amides

The present invention relates to heteroaroyl-substituted serinamides of the formula (I) in which the variables A and R1 to R6 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants.

Substituted Pyridines Having a Herbicidal Effect

Substituted pyridines of the formula I in which the variables are defined according to the description, their agriculturally suitable salts, processes and intermediates for preparing the pyridines of the formula I, compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one pyridine compound of the formula I to act on plants, their seed and/or their habitat.

PIPERAZINE COMPOUNDS WITH A HERBICIDAL ACTION

The invention relates to the use of piperazine compounds of formula (I) or the agriculturally useful salts of piperazine compounds of formula (I) as herbicides, the variables in formula (I) being defined as cited in the claims and the description.

Heteroaroyl-Substituted Alanines with a Herbicidal Action

The present invention relates to heteroaroyl-substituted alanines of the formula I in which the variables A and R1 to R8 are as defined in the description, and to their agriculturally useful salts, to processes and intermediates for their preparation, and to the use of these compounds or of compositions comprising these compounds for controlling unwanted plants.

Cycloaliphatic/aromatic diphosphines and use thereof in catalysis

The present invention concerns novel unsymmetrical chiral diphosphines of a mixed aliphatic-aromatic type and processes for synthesizing them, complexes of these compounds with [lacuna] and their use as catalysts.

Herbicidally Active Composition

The present invention relates to herbicidally active compositions comprising at least one piperazinedione compound of the formula I in which: Rx, Ry are each hydrogen or together are a chemical bond; R1 is cyano or nitro; R2 is hydrogen, fluorine, chlorine, C1-C2-alkyl, ethenyl or C1-C2-alkoxy; R3 is fluorine or hydrogen; R4 is methyl; R5 is hydrogen, methyl or ethyl; R6 is hydrogen, methyl or ethyl; and R7 is hydrogen or halogen; and at least one further active compound selected from the group consisting of b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors, b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose ...

Substituted Pyridines Having a Herbicidal Effect

Substituted pyridines of the formula I in which the variables are defined according to the description, their agriculturally suitable salts, processes and intermediates for preparing the pyridines of the formula I, compositions comprising them and their use as herbicides, i.e. for controlling harmful plants, and also a method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one pyridine compound of the formula I to act on plants, their seed and/or their habitat.

Crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoroethoxymethyl)benzoyl]cyclohexan-1,3-dione

The present invention relates to two crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoro-ethoxymethyl)benzoyl]cyclohexan-1,3-dione, which is also known under the common name tembotrione. The invention also relates to a process for the production of these crystalline forms and formulations for plant protection which contain one of these crystalline forms of tembotrione.

Cycloaliphatic/aromatic diphosphines and use thereof in catalysis

The present invention concerns novel unsymmetrical chiral diphosphines of a mixed aliphatic-aromatic type and processes for synthesizing them, complexes of these compounds and their use as catalysts.

Improved temperature-stable soft-magnetic powder

A soft-magnetic powder coated with a silicon-based coating, wherein the silicon-based coating comprises at least one fluorine containing composition of formula (I), Si1-0.75c MCO2-0.5c Fd (I), wherein c is in the range of 0.01 to 0.5, d is in the range of 0.04 to 2, and M is B or Al.

Insecticidal methods using pyridine compounds

The present invention relates to new insecticidal methods of using compounds of formula (I) wherein A, E, G, M, Y, X, R 1 and R 2 are defined as in the description, and to their enantiomers, diastereomers and agriculturally and veterinary acceptable salts. The present invention relates to methods of administering and applying such Pyridine compounds of formula I for insecticidal use and purposes in agriculture and in the veterinary field. The invention relates also to new derivatives of Pyridine compounds of formula (I).

Substituted cyanobutyrates having herbicidal action

Nanoparticulate copper compounds

The present invention relates to processes for the preparation of surface-modified nanoparticulate copper compounds and of aqueous suspensions which comprise surface--modified nanoparticulate copper compounds. The invention furthermore relates to the surface-modified nanoparticulate copper compounds obtainable by these processes and aqueous suspensions of these copper compounds and their use as an antimicrobial active substance or catalyst.

Heteroaryl-substituted serine amides

Substituted cyanobutyrates having a herbicidal effect

The invention relates to substituted cyanobutyrates of the formula (I), wherein the variables are defined according to the description, to a method and intermediate products for producing the compounds of the formula (I) and the N-oxides thereof, to the agriculturally useful salts thereof, to agents comprising the same, and to the use thereof as herbicides, and to a method for treating undesirable plant growth.

Piperazine compounds with herbicidal action

Benzoyl-substituted alanines

The invention relates to benzoyl-substituted alanines of formula (I), in which the variables R1 to R13 are defined as cited in the description, and to their agriculturally useful salts. The invention also relates to methods and intermediates for the production of said compounds, to the use of said compounds or to agents containing the latter for controlling undesirable plants.

Cycloaliphatic/aromatic diphosphines and use thereof in catalysis

Heteroaroyl-substituted serine amides utilized as herbicides

The invention relates to heteroaroyl-substituted serine amides of formula (I), wherein the variables A, Het, and R<SUP>1</SUP> to R<SUP>5</SUP> have the meanings indicated in the description, the agriculturally useful salts thereof, methods and intermediate products for manufacturing the same, and the use of said compounds or agents containing said compounds for controlling unwanted plants.

CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT

Cianobutiratos sustituidos de la fórmula I donde las variables tienen las definiciones indicadas en la descripción, sus sales útiles en la agricultura, procesos y productos intermedios para la preparación de los compuestos de la fórmula I y sus N-óxidos, sus sales útiles en la agricultura, agentes que los contienen y su uso como herbicidas, así como procesos para combatir el crecimiento de plantas indeseadas.

Benzoyl-substituted serine amides

The invention relates to benzoyl-substituted serine amides of formula (I), wherein the variables Het and R1 to R10 have the meanings indicated in the description, the agriculturally useful salts thereof, methods and intermediate products for manufacturing the same, and the use of said compounds or agents containing said compounds for controlling unwanted plants.

Heteroaroyl-substituted alanines

The present invention relates to heteroaroyl-substituted alanines of the formula I in which the variables A and R1 to R7 have the meanings stated in the description, and to their agriculturally usable salts, methods and intermediates for their preparation, and the use of these compounds or compositions comprising these compounds for controlling unwanted plants.

Substituted cyanobutyrates having a herbicidal effect

The invention relates to substituted cyanobutyrates of the formula (I), wherein the variables are defined according to the description, to a method and intermediate products for producing the compounds of the formula (I) and the N-oxides thereof, to the agriculturally useful salts thereof, to agents comprising the same, and to the use thereof as herbicides, and to a method for treating undesirable plant growth.

SERINAMIDES REPLACED BY BENZOYL

SE REFIERE A UN COMPUESTO DE FORMULA I DONDE HET ES HETEROARILO MONO O BICICLICO CON 5-10 MIEMBROS DEL ANILLO SUSTITUIDO CON 1-4 HETEROATOMOS DE N, O, S PARCIAL O TOTALMENTE SUSTITUIDO; R1 ES HALOGENO, CIANO, ALQUILO C1-C6, HALOGENOALQUILO C1-C6, HALOGENOALCOXI C1-C6; R2, R3, R4 Y R5 SON CADA UNO H, HALOGENO, CIANO, ALQUILO C1-C6, ENTRE OTROS; R6 Y R7 SON CADA UNO H, HIDROXI, ALCOXI C1-C6; R8 ES ALQUILO C1-C6, CIANOALQUILO C1-C4, HALOGENOALQUILO C1-C6; R9 ES H, ALQUILO C1-C6, CICLOALQUILO C3-C6, ALQUINILO C3-C6, FORMILO, ALQUILCARBONILO C1-C6, ENTRE OTROS. SON COMPUESTOS PREFERIDOS: (2S,3R)-TREO-4-FLUORO-N-(2-HIDROXI-1-METILCARBAMOIL-2-TIOFEN-3-IL-ETIL)-2-TRIFLUOROMETIL-BENZAMIDA; RAC-ERITRO-4-FLUORO-N-(2-HIDROXI-1-METILCARBAMOIL-2-PIRIDIN-3-IL-ETIL)-2-TRIFLUOROMETIL-BENZAMIDA; ENTRE OTROS. SE REFIERE TAMBIEN A UNA COMPOSICION FARMACEUTICA Y A UN PROCEDIMIENTO DE PREPARACION. DICHOS COMPUESTOS TIENEN ACTIVIDAD HERBICIDA UTILIZADOS EN LA AGRICULTURA REFERS TO A COMPOUND OF FORMULA I WHERE HET IS MONO OR BICYCLE HETEROARYL WITH 5-10 MEMBERS OF THE RING REPLACED WITH 1-4 HETEROATOMS OF N, O, S PARTIALLY OR TOTALLY REPLACED; R1 IS HALOGEN, CYANE, C1-C6 ALKYL, C1-C6 HALOGENOALKYL, C1-C6 HALOGENOALCOXY; R2, R3, R4 AND R5 ARE EACH H, HALOGEN, CYANE, C1-C6 ALKYL, AMONG OTHERS; R6 AND R7 ARE EACH H, HYDROXY, C1-C6 ALCOXY; R8 is C1-C6 ALKYL, C1-C4 CYANOALKYL, C1-C6 HALOGENOALKYL; R9 IS H, C1-C6 ALKYL, C3-C6 CYCLOALKYL, C3-C6 ALKYNYL, FORMYL, C1-C6 ALKYLCARBONYL, AMONG OTHERS. THE PREFERRED COMPOUNDS ARE: (2S, 3R) -TREO-4-FLUORO-N- (2-HYDROXY-1-METHYLCARBAMOYL-2-THIOPHEN-3-IL-ETHYL) -2-TRIFLUORomethyl-BENZAMIDE; RAC-ERYTHRO-4-FLUORO-N- (2-HYDROXY-1-METHYLCARBAMOYL-2-PYRIDIN-3-IL-ETHYL) -2-TRIFLUOROMETHYL-BENZAMIDE; AMONG OTHERS. IT ALSO REFERS TO A PHARMACEUTICAL COMPOSITION AND A PREPARATION PROCEDURE. SAID COMPOUNDS HAVE HERBICIDAL ACTIVITY USED IN AGRICULTURE

Substituted pyridines having a herbicidal effect

Disclosed are substituted pyridines of formula I in which the variables are defined as indicated in the description, the agriculturally suitable salts thereof, methods and intermediate products for manufacturing the pyridines of formula I, substances containing said pyridines and the use thereof as herbicides, i.e. to control weeds, and a method for controlling unwanted plant growth in which a herbicidal amount of at least one pyridine compound of formula I is made to act on plants, the seeds and/or the habitat thereof.

PIRIDINES REPLACED WITH HERBICITY ACTION

Piridinas sustituidas de la fórmula I en donde las variables se definen según la descripción, sus sales apropiados en agricultura, procedimientos y productos intermediarios para la preparación de las piridinas de la fórmula I, agentes que los contienen y su uso como herbicidas, es decir, para el combate de plantas dañinas, así como un procedimiento de plantas no deseadas, en el que se deja actuar una cantidad de eficacia herbicida de al menos un compuesto de piridina de la fórmula I sobre plantas, sus semillas y/o su hábitat.

Substituted pyridines having herbicidal action

Disclosed are substituted pyridines of formula (I) in which the variables are defined as indicated in the description, the agriculturally suitable salts thereof, methods and intermediate products for manufacturing the pyridines of formula (I), substances containing said pyridines and the use thereof as herbicides, i.e. to control weeds, and a method for controlling unwanted plant growth in which a herbicidal amount of at least one pyridine compound of formula (I) is made to act on plants, the seeds and/or the habitat thereof.

Heteroaroyl-substituted serineamides

Piperazine compounds having herbicidal action

Crystalline forms of 2-ý2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoroethoxymethyl)benzoyl¨cyclohexan-1,3-dione

The present invention relates to two crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoro-ethoxymethyl)benzoyl]cyclohexan-1,3-dione, which is also known under the common name tembotrione. The invention also relates to a process forthe production of these crystalline forms and formulations for plant protection which contain one of these crystalline forms of tembotrione.

Benzoyl-substituted serine amides

The invention relates to benzoyl-substituted serine amides of formula (I) wherein the variables R1 to R11 have the designations cited in the description. The invention also relates to the salts thereof which are useful for agriculture, to methods and intermediate products for the production of said serine amides, and to the use of said compounds or agents containing said compounds for controlling undesired plants.

compound, process for preparing compounds, composition, process for preparing compositions, process for combating unwanted vegetation, and use of the compound

COMPOSTO, PROCESSO PARA PREPARAR COMPOSTOS, COMPOSIçãO, PROCESSO PARA PREPARAR COMPOSIçõES, PROCESSO PARA COMBATER VEGETAçãO INDESEJADA, E, USO DO COMPOSTO. A invenção refere-se a alaninas substituidas por benzoila de fórmula (I), em que as variáveis R^ 1^ a R^ 13^ são definidas como citado na descrição, e a seus sais agriculturalmente utilizáveis. A invenção também refere-se a processos e intermediários para a produção de referidos compostos, ao uso de referidos compostos ou a agentes contendo os últimos para combater plantas indesejáveis. COMPOUND, PROCESS TO PREPARE COMPOUNDS, COMPOSITION, PROCESS TO PREPARE COMPOSITIONS, PROCESS TO COMBAT UNWANTED VEGETATION, AND USE OF COMPOUND. The invention relates to benzoyl-substituted alanines of formula (I), in which the variables R ^ 1 ^ to R ^ 13 ^ are defined as mentioned in the description, and their agriculturally usable salts. The invention also relates to processes and intermediates for the production of said compounds, the use of said compounds or agents containing the latter to combat undesirable plants.

Benzoyl-substituted serine amides

The invention relates to benzoyl-substituted serine amides of formula (I), wherein the variables Het and R1 to R10 have the meanings indicated in the description, the agriculturally useful salts thereof, methods and intermediate products for manufacturing the same, and the use of said compounds or agents containing said compounds for controlling unwanted plants.

Benzoyl-substituted serine amides

The invention relates to benzoyl-substituted serine amides of formula (I), in which the variables R1 to R11 are defined as cited in the description and to their salts that can be used for agricultural purposes. The invention also relates to a method and intermediate products for producing said amides and to the use of the compounds or to agents containing said compounds for controlling weeds.

COMPOUNDS DERIVED FROM SERINAMIDS REPLACED BY BENZOIL; PROCESS TO PREPARE SUCH COMPOUNDS; BENZOIL DERIVATIVE COMPOUND; COMPOSITION; PREPARATION PROCESS OF SUCH COMPOSITION; METHOD TO CONTROL UNWANTED VEGETATION; AND ITS USE

Herbicidally active composition

Benzoyl-substituted serine amides

Heteroaroyl-substituted serine amides utilized as herbicides

The invention relates to heteroaroyl-substituted serine amides of formula (I), wherein the variables A, Het, and R1 to R5 have the meanings indicated in the description, the agriculturally useful salts thereof, methods and intermediate products for manufacturing the same, and the use of said compounds or agents containing said compounds for controlling unwanted plants.

use of piperazine compounds or agriculturally used salts of the piperazine compounds, composition, process for preparing compositions, method for controlling unwanted vegetation, piperazine compound, and process for preparing piperazine compounds

USO DE COMPOSTOS DE PIPERAZINA OU DE SAIS AGRJCOLAMENTE USADOS DOS COMPOSTOS DE PIPERAZINA, COMPOSIçãO, PROCESSO PARA PREPARAR COMPOSIçõES, MéTODO PARA CONTROLAR VEGETAçãO INDESEJADA, COMPOSTO DE PIPERAZINA, E, PROCESSO PARA PREPARAR COMPOSTOS DE PIPERAZINA. A presente invenção diz respeito ao uso de compostos de piperazina da fórmula I ou aos sais agricolamente usados de compostos de piperazina da fórmula 1 como herbicidas, onde na fórmula 1 as variáveis são da forma definida nas reivindicações e descrição. Além disso, a invenção diz respeito a composições compreendendo, além de auxiliares comuns para formular agentes de proteção de safra, compostos de piperazina da fórmula 1 ou sais agricolamente usados de 1 e a um processo para preparar estas composições. Além disso, a invenção diz respeito a certos compostos de piperazina da fórmula 1, um processo para preparar compostos de piperazina da fórmula 1 e um método para controlar vegetação indesejada que compreende tratar plantas, suas sementes e/ou seu habitat com pelo menos um composto de piperazina da fórmula 1. USE OF PIPERAZINE COMPOUNDS OR AGRICULTURALLY USED SALTS OF PIPERAZINE COMPOUNDS, COMPOSITION, PROCESS TO PREPARE COMPOSITIONS, METHOD TO CONTROL VEGETATION COMPOSITE, AND PROCESS TO PREPARE COMPOUNDS. The present invention relates to the use of piperazine compounds of formula I or the agriculturally used salts of piperazine compounds of formula 1 as herbicides, wherein in formula 1 the variables are as defined in the claims and description. In addition, the invention relates to compositions comprising, in addition to common aids for formulating crop protection agents, piperazine compounds of formula 1 or agriculturally used salts of 1 and a process for preparing these compositions. Further, the invention relates to certain piperazine compounds of formula 1, a process for preparing piperazine compounds of formula 1 and a method for controlling unwanted vegetation comprising treating plants, their seeds and ...

Heteroaroylsubstituierte serin-amide

Piperazinverbindungen mit herbizider wirkung

Benzoylsubstituierte serin-amide

Piperazinverbindungen mit herbizider wirkung

Cycloaliphatisch-aromatische diphosphine und ihre verwendung in der katalyse

Improved temperature-stable soft-magnetic powder

A soft-magnetic powder coated with a silicon-based coating, wherein the silicon-based coating comprises at least one fluorine containing composition of formula (I), Si1-0,75c MCO2-0,5c Fd (I), wherein c is in the range of 0.01 to 0.5, d is in the range of 0.04 to 2, and M is B or Al.

Improved temperature-stable soft-magnetic powder

A soft-magnetic powder coated with a silicon-based coating, wherein the silicon-based coating comprises at least one fluorine containing composition of formula (I), Si1 -0,75c MCO2-0,5c Fd (I), wherein c is in the range of 0.01 to 0.5, d is in the range of 0.04 to 2, and M is B or Al.

Piperazinverbindungen mit herbizider wirkung

Die vorliegende Erfindung betrifft Piperazinverbindungen der im Folgenden definierten allgemeinen Formel (I) und deren Verwendung als Herbizide. Die Erfindung betrifft außerdem Mittel für den Pflanzenschutz und ein Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs. R1 ist ausgewählt ist unter Halogen, Cyano, Nitro, Z-C(=O)-R12, Phenyl und einem 5- oder 6-gliedrigen heterocyclischen Rest, der 1, 2, 3 oder 4 Heteroatom, ausge- wählt unter O, N und S als Ringatome aufweist, worin Phenyl und der heterocyclische Rest unsubstituiert sind oder 1, 2, 3 oder 4 Substituenten R1a aufweisen; Z für eine kovalente Bindung oder eine CH2-Gruppesteht; R12 Wasserstoff, C1-C6-Alkyl, C3-C6-Cycloalkyl, C2-C6-Alkenyl, C5-C6- Cycloalkenyl, C2-C6-Alkinyl und dergleichen; R2 bedeutet Wasserstoff, Halogen, Nitro, Cyano, C1-C4-Alkyl, C1-C4-Haloalkyl, C2- C4-Alkenyl, C1-C4-Alkoxy, C1-C4-Haloalkoxy, Benzyl oder eine Gruppe S(O) nR21,worin R21 für C1-C4-Alkyl oder C1-C4-Haloalkyl steht und n für 0, 1 oder 2 steht; R3 bedeutet Wasserstoff oder Halogen; R4 bedeutet C1-C4-Alkyl, C3- C4-Alkenyl oder C3-C4-Alkinyl; R5 bedeutet Wasserstoff, C1-C4-Alkyl, C3-C4-Alkenyl, C3-C4-Alkinyl oder eine Gruppe C(=O)R51, worin R51 für Wasserstoff, C1-C4-Alkyl, C1-C4-Haloalkyl,C1-C4-Alkoxy oder C1-C4-Haloalkoxy steht; R6 steht für C1-C4-Alkyl, C1-C4-HydroxyalkyloderC1-C4-Haloalkyl; R7, R8 stehen unabhängig voneinander für Wasserstoff, OH, C1-C4-Alkoxy, C1-C4- Haloalkyoxy, C1-C4-Alkyloder C1-C4-Haloalkyl; R9, R10 sind unabhängig voneinander ausgewählt unter Wasserstoff, Halogen, CN, NO2, C1-C4-Alkyl, C1-C4-Haloalkyl, C2-C4-Alkenyl, C1-C4-Alkoxy und C1-C4- Haloalkoxy; und R11 bedeutet Wasserstoff oder C1-C4-Alkyl; sowie die landwirtschaftlich geeigneten Salze dieser Verbindungen.

Spojine piperazinov s herbicidno aktivnostjo

Jedinjenja piperazina sa herbicidnim delovanjem

Ενωσεις πιπεραζινης με ζιζανιοκτονα δραση

Η παρούσα εφεύρεση αφορά ενώσεις πιπεραζίνης του προσδιορισμένου ακολούθως γενικού τύπου (I) και την χρησιμοποίηση τους σαν ζιζανιοκτόνα. Η εφεύρεση αφορά ακόμη μέσα για την φυτοπροστασία και μία μέθοδο για την καταπολέμηση ανεπιθύμητης φυτικής ανάπτυξης. R1 επιλέγεται από αλογόνο, κυανό, νίτρο, Z-C(=Ο)-R12, φαινύλιο και μία 5-ή 6-σκελή ετεροκυκλική ρίζα, η οποία παρουσιάζει 1, 2, 3 ή 4 ετεροάτομα, επιλεγμένα από Ο, Ν και S, σαν άτομα δακτυλίου, όπου το φαινύλιο και η ετεροκυκλική ρίζα δεν είναι υποκατεστημένα ή μπορούν να παρουσιάζουν 1, 2, 3 ή 4 υποκατάστατες R1a, Ζ στέκει για έναν ομοιοπολικό δεσμό ή για μία ομάδα CH2, R12 σημαίνει υδρογόνο, C1-C6-αλκύλιο, C3-C6-κυκλοαλκύλιο, C2-C6-αλκενύλιο, C5-C6-κυκλοαλκενύλιο, C2-C6-αλκινύλιο και παρόμοια, R2 σημαίνει υδρογόνο, αλογόνο, νίτρο, κυανό, C1-C4-αλκύλιο, C1-C4-αλοαλκύλιο, C2-C4-αλκενύλιο, C1-C4-αλκοξυ, C1-C4-αλοαλκοξυ, βενζύλιο ή μία ομάδα S(O)nR21, όπου R21 στέκει για C1-C4-αλκύλιο ή C1-C4-αλοαλκύλιο και n στέκει για 0, 1 ή 2, R3 σημαίνει υδρογόνο ή αλογόνο, R4 σημαίνει C1-C4-αλκύλιο, C3-C4-αλκενύλιο ή C3-C4-αλκινύλιο, R5 σημαίνει υδρογόνο, C1-C4-αλκύλιο, C3-C4-αλκενύλιο, C3-C4-αλκινύλιο ή μία ομάδα C(=O)R51, όπου R51 στέκει για υδρογόνο, C1-C4-αλκύλιο, C1-C4-αλοαλκύλιο, C1-C4-αλκοξυ ή C1-C4-αλοαλκοξυ, R6 στέκει για C1-C4-αλκύλιο, C1-C4-υδροξυαλκύλιοΙ ή C1-C4-αλοαλκύλιο, R7, R8 ανεξάρτητα μεταξύ τους στέκουν για υδρογόνο, ΟΗ, C1-C4-αλκοξυ, C1-C4-αλοαλκοξυ, C1-C4-αλκύλιο ή C1-C4-αλοαλκύλιο, R9, R10 ανεξάρτητα μεταξύ τους επιλέγονται από υδρογόνο, αλογόνο, CN, ΝO2, C1-C4-αλκύλιο, C1-C4-αλοαλκύλιο, C2-C4-αλκενύλιο, C1-C4-αλκοξυ και C1-C4-αλοαλκοξυ, και R11 σημαίνει υδρογόνο ή C1-C4-αλκύλιο. Η εφεύρεση αφορά επίσης γεωργικά κατάλληλα άλατα των ενώσεων αυτών.

Compuestos de piperazina con accion herbicida

SE REFIERE A UN COMPUESTO DE FORMULA I, DONDE R1 Y R2 SON CADA UNO CIANO, ALQUILO C1-C6, CICLOALQUILO C3-C6, ALQUENILO C3-C6, FENILO, ENTRE OTROS; R3 ES H, ALQUILO C1-C6, CICLOALQUILO C3-C6, OH, ENTRE OTROS; R4, R5 Y R6 SON CADA UNO H, ALQUILO C1-C6, ALCOXI C1-C6, ENTRE OTROS; R7 Y R8 SON CADA UNO H, HIDROXI, ALQUILO C1-C6, HALOGENADO EN FORMA PARCIAL O TOTAL, ENTRE OTROS; A1, A2 SON CADA UNO ARILO, HETEROARILO, ENTRE OTROS; Ra ES HALOGENO, CIANO, NITRO, ALQUILO C1-C6, ENTRE OTROS; Rb, Rc, Rd, Re Y Rf SON CADA UNO H, HALOGENO, NITRO, ENTRE OTROS. SON COMPUESTOS PREFERIDOS: 3-BENCIL-6-(2-ETINILBENCIL)-1,4-DIMETIL-PIPERAZIN-2,5-DIONA; 3-[(2-NITRO-4-TRIFLUOROMETIL)BENCIL]6-BENCIL-1,4-DIMETIL-2,5-DIONA; ENTRE OTROS. REFERIDA TAMBIEN A UN PROCEDIMIENTO DE PREPARACION. DICHOS COMPUESTOS SON UTILES COMO HERBICIDAS

Process for producing an improved temperature-stable soft-magnetic powder, improved temperature-stable soft-magnetic powder, use thereof and electronic component comprising same

Piperazinverbindungen mit herbizider wirkung

Piperazinverbindungen mit herbizider wirkung

Die vorliegende Erfindung betrifft die Verwendung von Piperazinverbindungen der Formel (I) oder der landwirtschaftlich brauchbaren Salze von Piperazinverbindungen der Formel (I) als Herbizide, wobei die Variablen in Formel (I) die in den Ansprüchen und der Be- schreibung angegebenen Bedeutungen haben.

Piperazinverbindungen mit herbizider wirkung

Die vorliegende Erfindung betrifft die Verwendung von Piperazinverbindungen der Formel (I) oder der landwirtschaftlich brauchbaren Salze von Piperazinverbindungen der Formel (I) als Herbizide, wobei die Variablen in Formel (I) die in den Ansprüchen und der Be- schreibung angegebenen Bedeutungen haben.

具除草作用之哌化合物

Związki piperazynowe o działaniu chwastobójczym

Piperazine compounds with a herbicidal action

Disclosed is the use of piperazine compounds of formula I or of the agriculturally useful salts of piperazine compounds of formula I as herbicides, the substituents being defined in the specification.

Compuestos de piperizina con accion herbicida.

Uso de compuestos de piperazina de la fórmula I **(Ver fórmula)** o de las sales útiles en la agricultura de los compuestos de piperazina de la fórmula I como herbicidas, y en la fórmula I las variables tienen los siguientes significados: R1 y R2, independientemente uno de otro, ciano, alquilo de C1-C6, cicloalquilo de C3-C6, alquenilo de C3-C6, cicloalquenilo de C3-C6, alquinilo de C3-C6, cicloalquinilo de C3-C6, fenilo, fenil-alquilo de (C1-C6), heterociclilo, heterociclil-alquilo de (C1-C6); fenil-[alcoxi(de C1-C6)carbonil]-alquilo de (C1-C6) o fenilheterociclil-alquilo de C1-C6; o COR21, donde R21 significa hidrógeno, alquilo de C1-C6, cicloalquilo de C3-C6, alquenilo de C2-C6, cicloalquenilo de C3-C6, alquinilo de C2-C6, cicloalquinilo de C3-C6, hidroxi, alcoxi de C1-C6, alqueniloxi de C3-C6, alquiniloxi de o de C3-C6, amino, alquilo(de C1-C6)amino, [di-alquil(de C1-C6)]amino, alquenil(de C3-C6)amino, alquinil(de C3-C6)amino, alquil(de C1-C6)sulfonilamino, N-(alquenilo de C2-C6)-N-(alquilo de C1-C6)-amino, N-(alquinilo de C2-C6)-N-(alquilo de C1-C6)-amino, N-(alcoxi de C1-C6)-N-(alquilo de C1-C6)-amino, N-(alquenilo de C2-C6)-N-(alcoxi de C1-C6)-amino, N-(alquinilo de C2-C6)-N-(alcoxi de C1-C6)-amino, fenilo, fenilamino, fenoxi, naftilo o heterociclilo; o NR22R23, donde R22 y R23, independientemente uno de otro, significan hidrógeno, alquilo de C1-C6, cicloalquilo de C3-C6, alquenilo de C3-C6, cicloalquenilo de C3-C6, alquinilo de C3-C6, cicloalquinilo de C3-C6 o alquil(de C1-C6)carbonilo; o OR24, donde R24 significa alquilo de C1-C6, cicloalquilo de C3-C6, alquenilo de C3-C6, cicloalquenilo de C3-C6, alquinilo de C3-C6, cicloalquinilo de C3-C6, fenilo o fenil-alquilo de C1-C6; o SO2R25, donde R25 significa alquilo de C1-C6 o fenilo; Las partes alifáticas, cíclicas o aromáticas nombradas de los sustituyentes de R1 y R2 pueden estar parcial o totalmente halogenadas y/o pueden tener uno a tres de los siguientes grupos: ciano, hidroxi, alquilo de C1-C4, ...

Piperazine compounds with a herbicidal action

The invention relates to the use of piperazine compounds of formula (I) or the agriculturally useful salts of piperazine compounds of formula (I) as herbicides, the variables in formula (I) being defined as cited in the claims and the description.

Piperazine compounds with a herbicidal action

Composicion de efecto herbicida

REFERIDA A COMPOSICIONES QUE COMPRENDEN: A) EL COMPUESTO DE FORMULA I; EN EL QUE Rx Y Ry ES H O JUNTOS SON UN ENLACE QUIMICO; R1 ES CIANO O NITRO; R2 ES H, FLUOR, CLORO, ALQUILO(C1-C2), ETENILO O ALCOXI(C1-C2); R3 ES FLUOR O H; R4 ES METILO; R5 Y R6 SON H, METILO O ETILO Y R7 ES H O HALOGENO; B)UN PRINCIPIO ACTIVO SELECCIONADO DE: a) INHIBIDORES DE BIOSINTESIS DE LIPIDOS, TAL COMO BUTROXIDIM, DICLOFOP, TIOCARBAZIL, ENTRE OTROS; b) INHIBIDORES DE FOTOSINTESIS, TAL COMO KARBUTILAT, PARAQUAT, TERBACIL, ENTRE OTROS; c) INHIBIDORES DE PROTOPORFIRINOGENO-IX-OXIDASA, TAL COMO, AZAFENIDIN, FLUMIOXAZIN, OXADIAZON, ENTRE OTROS; d) SULFOSAT, CAFENSTROL, DINOTERB, BUTAFENACIL, ENTRE OTROS; C) POR LO MENOS UN PROTECTOR C, TAL COMO, BENOXACOR, FLURAZOL, ANHIDRIDO NAFTALICO, OXABETRINIL, ENTRE OTROS. SE REFIERE TAMBIEN A COMPUESTOS PREFERENTES DE FORMULA I SELECCIONADOS DE 2-[5-BENCIL-1,4-DIMETIL-3,6-DIOXOPIPERAZIN-2-ILIDENMETIL]-BENZONITRILO, 3-(4-FLUOROBENCIL)-6-(2-METOXI-6-NITROBENCIL)-1,3-DIMETILPIPERAZIN-2,5-DIONA, ENTRE OTROS; Y UN PROCEDIMIENTO DE PREPARACION DE DICHA COMPOSICION CON EFECTO HERBICIDA

Benzoylsubstituierte serin-amide

Die vorliegende Erfindung betrifft benzoylsubstituierte Serin-Amide der Formel I in der die Variablen R1 bis R11 die in der Beschreibung genannten Bedeutungen haben, sowie deren landwirtschaftlich brauchbaren Salze, Verfahren und Zwischenprodukte zu ihrer Herstellung, sowie die Verwendung dieser Verbindungen oder diese Verbindungen enthaltende Mittel zur Bekämpfung uner¬ wünschter Pflanzen.