27-11-2014 дата публикации
Номер: US20140350312A1
Автор:
Chen Shukang,
Fan Jianping,
Jiang En,
Lei Yunlong,
Li Zhong,
Xu Lei,
YANG GANG,
Yang Huie,
Zeng Changhua,
Zhang Wenqing,
Zhao Xintang
Provided are a fluorination catalyst for preparing 2,3,3,3-tetrafluoropropene and a method using the catalyst for preparing 2,3,3,3-tetrafluoropropene. The catalyst has the following structural formula: Crx(Y,Z)OF, where Y is one or a combination of two or more among Al, Zn, and Mg, and where Z is a rare earth element having an oxygen-storing/releasing function. The catalyst has in preparing 2,3,3,3-tetrafluoropropene the advantages of increased raw material conversion rate, great product selectivity, and extended catalyst service life. 1. A fluorination catalyst for preparing 2 ,3 ,3 ,3-tetrafluoropropene , characterized in that the fluorination catalyst has the following formula (I):{'br': None, 'sub': 1', '0.005-0.5', '0.1-10', '1.0-3.0, 'Cr(Y,Z)OF\u2003\u2003(I)'}wherein Y is selected from Al, Zn, Mg, or a combination thereof, and Z is a rare earth element capable of storing/releasing oxygen.2. The fluorination catalyst for preparing 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene according to claim 1 , characterized in that the rare earth element is selected from Ce claim 1 , La claim 1 , Pr claim 1 , or a combination thereof.3. The fluorination catalyst for preparing 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene according to claim 1 , characterized in that the fluorination catalyst was prepared by a process claim 1 , in which a fluorine-containing surfactant was added.4. The fluorination catalyst for preparing 2 claim 3 ,3 claim 3 ,3 claim 3 ,3-tetrafluoropropene according to claim 3 , characterized in that the fluorine-containing surfactant is perfluorooctylsulfonyl fluoride or a soluble salt of perfluorooctylsulfonic acid.5. A method for preparing 2 claim 1 ,3 claim 1 ,3 claim 1 ,3-tetrafluoropropene claim 1 , comprising: reacting 2-chloro-3 claim 1 ,3 claim 1 ,3-trifluoropropene as a starting material with anhydrous hydrogen fluoride claim 1 , under catalysis of the fluorination catalyst of and in the presence of Oand/or O claim 1 , to produce ...
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