05-05-2023 дата публикации
Номер: CN116060138A
Принадлежит:
The invention relates to a pre-activation method of a supported metal catalyst for catalyzing a hydrogenolysis reaction of polyol. The catalyst is composed of a carrier and active components A and B, the carrier is one of aluminum oxide, silicon oxide, zirconium oxide, titanium oxide or a molecular sieve, the active component A is one of tungsten oxide, molybdenum oxide and niobium oxide, and the active component B is one of noble metals ruthenium, rhodium, palladium, iridium and platinum. According to the technical scheme, pure hydrogen or mixed gas containing hydrogen and inert gas and liquid water are adopted as reducing agents, and under the condition that the pre-activation temperature is 80-500 DEG C, hydrogen dissolved in liquid is in contact with a catalyst, according to the technical scheme, the high-valence metal oxide in the catalyst is slowly reduced into the low-valence active metal oxide or metal simple substance, so that the problem of sintering of the catalyst in the hydrogen ...
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