24-09-2014 дата публикации
Номер: CN104059240A
Принадлежит:
The invention relates to a preparation method of a polyvinylidene fluoride grafted styrene sulfonate electrolyte membrane, and belongs to the field of battery electrolyte materials. The method is as follows: firstly, polyvinylidene fluoride powder is dispersed in a methanol solution in a nitrogen atmosphere, and a quaternary ammonium base is added for mixing, sedimentation, filtration, drying to obtain modified polyvinylidene fluoride powder; the modified powder, styrene and benzoyl peroxide are added into methanol for heating in the nitrogen atmosphere for reaction, the precipitation is filtered, then extracted by use of trichloromethane, and then dried to obtain the modified polyvinylidene fluoride grafted styrene powder; the powder is dissolved in an organic solvent, stirred, cooled, spread on a glass plate, then dried, and sulfonated in concentrated sulfuric acid to obtain the electrolyte membrane. The modified modified polyvinylidene fluoride grafted styrene sulfonate electrolyte membrane ...
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