25-06-2020 дата публикации
Номер: US20200198386A1
The present invention relates to method of manufacturing a tamper-proof medium for thermal printing, wherein a liquid treatment composition comprising at least one acid is deposited on a substrate which comprises a thermochromic coating layer comprising at least one halochromic leuco dye. 1. A method of manufacturing a tamper-proof medium for thermal printing , the method comprising the following steps:a) providing a substrate, wherein the substrate comprises on at least one side a thermochromic coating layer comprising at least one halochromic leuco dye,b) providing a liquid treatment composition comprising at least one acid, andc) applying the liquid treatment composition onto at least one region of the thermochromic coating layer in form of a preselected pattern.2. The method of claim 1 , wherein the substrate is selected from the group consisting of paper claim 1 , cardboard claim 1 , containerboard claim 1 , plastic claim 1 , cellophane claim 1 , textile claim 1 , wood claim 1 , metal claim 1 , glass claim 1 , mica plate claim 1 , and nitrocellulose.3. The method of claim 1 , wherein the at least one halochromic leuco dye is colourless.4. The method of claim 1 , wherein the at least one halochromic leuco dye is selected from the group consisting of arylmethane phthalide dyes claim 1 , quinone dyes claim 1 , triarylmethane dyes claim 1 , triphenylmethane dyes claim 1 , fluoran dyes claim 1 , phenothiazine dyes claim 1 , rhodamine lactam dyes claim 1 , spiropyran dyes claim 1 , and mixtures thereof.5. The method of claim 1 , wherein the thermochromic coating layer comprises the at least one halochromic leuco dye in an amount from 1 to 60 wt.-% claim 1 , based on the total weight of the thermochromic coating layer.6. The method of claim 1 , wherein the thermochromic coating layer further comprises a colour developing agent.7. The method of claim 1 , wherein the at least one acid is selected from the group consisting of hydrochloric acid claim 1 , sulphuric acid ...
Подробнее