23-11-2011 дата публикации
Номер: CN0102250023A
Автор:
FEI QI,
BO LUAN,
JIANLIN ZHANG,
YINGXIAN LIU,
SHUAI CAO,
HONGKUI GAO,
QI FEI,
LUAN BO,
ZHANG JIANLIN,
LIU YINGXIAN,
CAO SHUAI,
GAO HONGKUI
Принадлежит:
The invention relates to a synthetic method for quizalofop-p-ethyl, a high efficiency herbicide. The method comprises the four steps of water straining, substitution, rinsing and crystallization. According to the method, 6-chlorine-2-(4-hydroxyphenoxy)quinoxaline reacts with R(-)p-toluenesulfonyl ethyl lactate, alkali metal and salts thereof are employed as acid binding agents, a single organic solvent is employed as a reaction system, and solid-liquid separation is used for separating a product; the yield of the product exceeds 90%, the content of the product is about 97.5%, and the content of the active substance R is more than 94%. Compared to the conventional technology, the preparation method provided in the invention has the characteristics of little side reaction, a short flow, a stationary process, high yield of the product, high content of the active substance and low energy consumption.
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