07-01-2016 дата публикации
Номер: US20160001267A1
Принадлежит:
A method for controllably producing a hematite-containing Fischer-Tropsch catalyst by combining an iron nitrate solution with a precipitating agent solution at a precipitating temperature and over a precipitation time to form a precipitate comprising iron phases; holding the precipitate from at a hold temperature for a hold time to provide a hematite containing precipitate; and washing the hematite containing precipitate via contact with a wash solution and filtering, to provide a washed hematite containing catalyst. The method may further comprise promoting the washed hematite containing catalyst with a chemical promoter; spray drying the promoted hematite containing catalyst; and calcining the spray dried hematite containing catalyst to provide a calcined hematite-containing Fischer-Tropsch catalyst. 1. A method for controllably producing a hematite-containing Fischer-Tropsch catalyst , the method comprising:(a) combining an iron nitrate solution with a precipitating agent solution at a precipitating temperature and over a precipitation time to form a precipitate comprising iron phases, wherein the precipitating temperature is less than or equal to about 95° C.; wherein the iron nitrate, the precipitating agent solution, or both, comprise a refractory material;(b) holding the precipitate from (a) at a hold temperature for a hold time to provide a hematite containing precipitate; and(c) washing the hematite containing precipitate from (b) via contact with a wash solution and filtering, to provide a washed hematite containing Fischer-Tropsch catalyst.2. The method of further comprising adding a hematite promoter to control the amount of hematite in the hematite-containing Fischer-Tropsch catalyst.3. The method of wherein the hematite-containing Fischer-Tropsch catalyst comprises from about 0.5 to about 80 weight percent hematite.4. The method of wherein the hematite promoter is selected from the group consisting of basic silica claim 2 , acidic silica claim 2 , ...
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