2-(o-(pyrimidin-4-yl)methylenoxy)phenyl acetic acid derivatives and their use for controlling harmful fungi and animal pests

Agents for controlling harmful fungi

Process and intermediate products for preparing substantially isomer-pure E-2-(2-aryloxymethylene phenyl)-crotonic acid methyl esters

Fungicide mixtures

O-benzyloxime ethers and crop protection agents containing these compounds

O-Benzyloxime ethers of the formula I wherein 5 x is substituted or unsubstituted CH2, NOalkyl Y is O, S, NR5 R1, R2, R5are H, alkyl Z1, Z2are H, halogen, methyl, methoxy, cyano R3, R4are hydrogen, cyano, substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, alkynyl, alkoxy, haloalkoxy, alkylthio, benzylthio, alkylcarbonyl, substituted or unsubstituted benzylcarbonyl, alkoxycarbonyl, substituted or unsubstituted phenoxycarbonyl substituted or unsubstituted benzyloxycarbonyl, N(R6)2, where R6is H, alkyl, substituted or unsubstituted phenyl, —CO—N(R7)2, where R7is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted arylthio, substituted or unsubstituted hetaryl, substituted or unsubstituted hetaryloxy, substituted or unsubstituted hetarylthio, substituted or unsubstituted heterocyclyl, substituted or unsubstituted heterocyclyloxy, R3and R4together may form a carbocyclic or heterocyclic ...

Fungicidal mixtures

Harmful fungi control with an active substance inhibiting respiration by inhibiting the cytochrome complex III, combined with an amide

Imino oxyphenyl acetic acid derivatives, methods and intermediates for their preparation and use thereof

Fungicide mixtures

Carbamates and crop protection agents containing them

Carbamates of the formula Iwhere the substituents have the following meanings:Z is methoxy, NH2, NHCH3, N(CH3)2, CH3, C2H5, CF3 or CCl3,X and Y are identical or different and each is hydrogen, F, Cl, Br, CF3, CN, NO2, alkoxy, alkenyloxy, alkynyloxy, alkyl, alkenyl or alkynyl or may be condensed together to form a substituted or unsubstituted aromatic or heteroaromatic, alicyclic or heterocyclic, partially or completely hydrogenated ring,R1 may also be substituted or unsubstituted and is O-alkyl, O-alkenyl, O-alkynyl, O-cycloalkyl, O-cycloalkenyl or O-CO2-alkyl,A is -O-, -S-, -CR2=CR3-, CHR2-O-, -CHR2-S-, -CHR2-O-N=C(R4)-, -CR2=N-O-, -O-N=C(R4)-, -C=C-, -CHR2-CHR3-, -CHR2-O-CO-, -O-CHR2- or a single bond,B is substituted or unsubstituted and is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, aryl, hetaryl, heterocyclyl, hydrogen, substituted or unsubstituted alkylaryl, substituted or unsubstituted alkylhetaryl, substituted or unsubstituted alkylcycloalkyl, substituted or ...

Fungicidal mixtures

A fungicidal mixture, comprisinga) a carbamate of the formula I, in which X is CH or N, n is 0, 1 or 2 and Y is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals Y to be different if n is 2, or a salt or adduct thereof,andb) an oxime ether carboxamide of the formula II in which R represents hydrogen or halogen in a synergistically effective amount.

Phenylacetic acids, processes for their preparation and agents containing them

Substituted 2-(2'-pyridyloxy)phenylacetamides, as fungicides and pesticides

Substituted 2-(2'-pyridyloxy)phenylacetamides I,whereR1 is fluorine, chlorine, CH3 or halomethyl;R2 is fluorine, bromine, alkyl or halomethyl;R3 is hydrogen or one of the radicals mentioned under R2; andR2 is 6-chloro if R3 is hydrogen,R3 is 5-chloro if R2 is fluorineand the compound in which R1, R2 and R3 are each chlorinewith the proviso that R1 may not be chlorine if R2 is 5-trifluoromethyl and R3 is hydrogen,and processes for their preparation and their use for controlling harmful fungi and animal pests are described.

Fungicidal triazolopyrimidines, method for the production thereof and use thereof in controlling noxious fungi and agents containing said compounds

Triazolopyrimidines of formula (I), wherein the index and substituents have the following meaning: n=0 or a whole number of 1-5; R=halogen, cyano, hydroxy, cyanate, alkyl, alkenyl, alkinyl, halogenalkyl, halogenalkenyl, alkoxy, alkenyloxy, alkinyloxy, halogenalkoxy, cycloalkyl, cycloalkenyl, cycloalkoxy, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoximinoalkyl, alkenyloximinocarbonyl, alkinyloximinoalkyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, cycloalkylcarbonyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S; R1=alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, phenyl, naphthyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S, R and/or R1 being able to be substituted according to the description; R2=alkyl, alkenyl or ...

Pyridine derivatives, process for preparing the same and their use for controlling animal pests and harmful fungi

Pyridine derivatives of the formula Iand their salts, their preparation, and their use for controlling animal pests and harmful fungi.

Use of Strobilurin Type Compounds for Combating Phytopathogenic Fungi Resistant to QO Inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health applications, and to seeds coated with at least one such compound. 116-. (canceled)18Alternaria alternata, Blumeria graminis, Pyriculania oryzaeMagnaporthe gniseaSeptoria triticiMycosphaerella graminicolaMycosphaerella fijiensis, Venturia inaequalis, Pyrenophora teres, Pyrenophona triticirepentisPlasmopara viticola.. The method of claim 17 , wherein the phytopathogenic fungi are selected from the group consisting of (also known as ) claim 17 , (also known as ) claim 17 , -and1916Septoria tritici.. The method of claim claim 17 , wherein the phytopathogenic fungus is20. The method of claim 17 , comprising:treating the phytopathogenic fungi or the materials, plants, the soil or seeds that are at risk of being diseased from phytopathogenic fungi with an effective amount of at least one compound of formula I, or a composition comprising it thereof.21. The method of claim 20 , comprising:a) identifying the phytopathogenic fungi, or the materials, plants, the soil or seeds that are at risk of being diseased from phytopathogenic fungi, andb) treating said fungi or the materials, plants, the soil or seeds with an effective amount of at least one compound of formula I, or a composition comprising it thereof.23. The compound of claim 22 , with the proviso that Ris not CFif Ris 1-methoxycarbonyl-2-methoxy-ethen-1-yl (formula R4-2 claim 22 , wherein X is O).24. The compound of claim 22 , wherein Ris selected from the group consisting of hydrogen claim 22 , halogen claim 22 , C-C-alkyl claim 22 , C-C-chloroalkyl claim 22 , C-C- ...

Fungicidal mixtures

Apparatus for mounting a tip cap on a syringe subassembly

An apparatus for mounting a tip cap having a maximum diameter over a syringe subassembly having a syringe body with an end carrying a needle has a holder holding the subassembly with the needle substantially on an axis and a tubular guide having a feed passage generally centered on the axis adjacent the holder, of an inside diameter greater than the maximum tip-cap diameter, and open toward the holder. A stop can move between a blocking position between the guide and the holder and an unblocking position offset therefrom. The tip cap is fed through the passage to a position arrested on the stop in the blocking position thereof. A nozzle opening into the passage injects pressurized gas into the passage and thereby spins the tip cap in the passage about the axis. The stop can then be moved from the blocking into the unblocking position for displacing the spinning tip cap from the guide onto the syringe subassembly in the holder. The nozzle opens tangentially into the passage.

Fungicidal mixtures

2-(O-(pyrimidin-4-yl)methylene oxy)phenyl acetic acid derivatives and their use in combatting noxious fungi and animal pests

Fungicidal mixture

Fungicidal mixtures

Substituted 6-(2-tolyl)-triazolopyrimidines as fungicides

Substituted 6-(2-tolyl)-triazolopyrimidines of formula (I) in which R1 and R2 independently denote hydrogen or alkyl, alkenyl, alkynyl, or alkadienyl, haloalkyl, haloalkenyl, cycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or where R1 and R2 radicals may be unsubstituted or substituted as defined in the description, or R1 and R2 together with the interjacent nitrogen atom represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted; R3 is halogen, cyano, alkyl, alkoxy, haloalkyl, or C(═O)A, wherein A is hydrogen, hydroxy, alkyl, amino, or mono- or dialkyl-amino; n is an integer from 1 to 4; and X is halogen, cyano, alkyl, alkoxy, haloalkoxy ...

Fungicidal mixture

A fungicidal mixture comprisesa) a phenyl benzyl ether derivate of the formula I.a, I.b or I.c, andb) a carboxamide II selected from the group of the compounds IIa and IIb in a synergistically effective amount.

Fungicide mixtures based on triple oxime ether derivatives and insecticides

Fungicidal mixture

Phenylacetic acid derivatives, process and intermediate products for use in producing them and agents containing them

Salicylic acid derivatives, processes for their preparation, compositions comprising them, and their use

Salicylic acid derivatives of the formula I,where the index and the substituents have the following meanings:X is halogen, NO2, cyano, alkyl or alkoxy;m is 0, 1, 2 or 3, it being possible for the substituents X to be different from each other if n is greater than 1;A is OH, alkoxy, NH2, NHCH3 or N(CH3)2;R1 is phenyl, naphthyl, cycloalkyl, 5-membered or 6-membered hetaryl or 5-membered or 6-membered heterocyclyl, comprising one to three N atoms and/or one O or S atom or one or two O and/or S atoms, the ring systems being unsubstituted or substituted;R2 is hydrogen, cyano, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy or alkylthio,processes for the preparation of these compounds, compositions comprising them, and their use for controlling harmful fungi.

Fungicidal mixtures

Fungicidal mixtures

Fungicidal mixtures

Fungicide mixtures based on triple oxime ether derivatives and rice fungicides

Fungicidal mixtures

Fungicidal mixtures

Combatting parasitic fungi with a combination of an active agent inhibiting respiration in the cytochrome complex III and of fenazaquine

The present nvention relates to compositions for controlling harmful fungi which comprise, as active ingredients, at least one compound which inhibits respiration on the cytochrome complex III and fenazaquin. The compositions according to the invention are useful in particular for controlling botrytis.

Use of phenethyl acrylamides, novel phenethyl acrylamides, method for the production thereof and agents containing the same

The invention relates to the use of phenethyl acrylamides of formula I for controlling phytopathogenic fungi, wherein the substituents of said phenethyl acrylamides have the following significations: X signifies halogen, alkyl, halogenalkyl, alkoxy halogenalkoxy and —O—C(Ra, Rb)—C≡C—R6; Ra, Rband Rchave the signification given in the description; m, n independently signify 1 to 4, the radicals X or Y being potentially different if m or n is higher than 1; Y signifies halogen, nitro, cyano, alkyl, CF3, alkoxy and phenyl; R1, R2independently signify hydrogen, halogen, alkyl, alkoxy, halogenalkoxy and CF3; R3, R4, R5, and R6independently signify hydrogen, alkyl and alkoxy, or R3and R4together form a cyclopropyl ring, whereby the C—R5and C—R6bonds can be in position E or Z in relation to each other. The invention also relates to novel phenethyl acrylamides, a method for the productio thereof, and agents containing the same.

Fungicide mixtures

Fungicide mixtures

Method for combating harmful fungi

Fungicide mixtures

Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them

Method of preparing essentially pure isomers of alpha-bis-oximes

Fungicidal mixtures

A fungicidal mixture comprisesa) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, and/or a carbamate of the formula Idwhere X is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, andb) a N-acetonylbenzamide of the formula II where:R1 and R3 independently of one another are each halogen or C1-C4-alkyl;R2 is cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy;R4 is hydrogen or C1-C4-alkyl;R5 is C2-C4-alkyl;R6 is thiocyano, isothiocyano or halogen,or a salt or adduct thereof, in a synergistically effective amount.

2-[pyrazolyl and triazolyl-3'-oxymethylene]-phenyl-isoxazolones, triazolones and tetrazolones as pesticides and fungicides

... 2-[Pyrazolyl- and triazolyl-3'-oxymethylene]phenylisoxazolones, -triazolones and -tetrazolones of formula I where: X is a group A, B or C, where # denotes the bond with the phenyl ring, R^a is hydrogen, halogen, alkyl or alkoxy, R^b is alkyl; Y is N or CR^c, where R^c is hydrogen, halogen or alkyl; n is 0, 1, 2, 3 or 4, where the substituents R¹ may be different if n is greater than 1; R¹ is nitro, cyano, halogen, alkyl with or without substitution or alkoxy with or without substitution or is additionally, if n is 2, an optionally substituted 3 or 4 membered bridge which forms together with the ring to which it is attached a bicyclic partially unsaturated or aromatic radical; R² is hydrogen, nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, alkylthio or alkoxycarbonyl; R³ is optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted hetaryl, their ...

Phenyl acetic acid derivatives, process and intermediate products for their production and their use as parasiticides and fungicides

Phenyl acetic acid derivatives of formula (I) in which: X is NOCH3, CHOCH3 and CHCH3; Y is NMR and O; R, R<1> are hydrogen and C1-4 alkyl; R<2> is hydrogen, C1-C6 alkyl, C1-C4 alkyl halide and C3-C6 cycloalkyl; R<3> is C4-C6 alkyl, substituted C1-C6 alkyl, possibly substituted C2-C6 alkinyl or possibly substituted C2-C6 alkenyl; R<4> is hydrogen, possibly substituted C1-C10 alkenyl, C2-C10 alkinyl, C1-10 alkyl carbonyl, C2-C10 alkenyl carbonyl, C3-C10 alkinyl carbonyl or C1-C10 alkyl sulphonyl, aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl; and their salts, a process and intermediate products for their production and their use.

Fungicidal mixtures

Bisoximether derivatives, methods and intermediate products for the production thereof, and their use for combating fungicidal pests and animal pests

Method for controlling parasitic fungi in cultivated plants

Fungicide mixtures

Combatting parasitic fungi with a combination of an active agent inhibiting respiration in the cytochrome complex III and of fenazaquine

Fungicidal mixture

Use of substituted imidazoazines, novel imidazoazines, methods for the production thereof, and agents containing these compounds

The use of substituted imidazoazines of the formula I, where R1 is alkyl, phenyl, phenylalkyl, naphthyl, anthracenyl, cycloalkyl, 5- or 6-membered hetaryl or 5- or 6-membered heterocyclyl, containing one to three nitrogen atoms and/or one oxygen or sulfur atom or one or two oxygen and/or sulfur atoms, or fused 8- to 12-membered hetaryl or fused 8- to 12-membered heterocyclyl, containing one to four nitrogen atoms and/or one oxygen or sulfur atom or one or two oxygen and/or sulfur atoms, where R1 may be unsubstituted or substituted as in the description; R2, R3. are hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, trialkylsilylalkyl, phenyl, phenylalkyl or R2, R3 together with the bridging nitrogen atom form a 5- or 6-membered heterocyclic or heteroaromatic ring which may be interrupted by one to three nitrogen atoms and/or one oxygen or sulfur atom or one or two oxygen and/or sulfur atoms and which may be substituted; A, B are N or CR4; R4, R5, R6 are hydrogen, halogen ...

Fungicidal mixtures

Fungicidal mixtures

5-phenylpyrimidines, their preparation, intermediates for their preparation, and their use for controlling harmful fungi

... 5-Phenylpyrimidines of the formula I, in which the substituents have the following meanings: R1 is a five- to ten-membered saturated, partially unsaturated or aromatic mono- or bicyclic heterocycle comprising one to four hetero atoms selected from the group consisting of O, N or S, which heterocycle can be substituted as defined in the description, R2 is hydrogen, halogen, cyano, alkyl, haloalkyl or alkoxy; R3, R4 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, alkynyl, haloalkynyl or cycloalkynyl, R3 and R4 together with the nitrogen atom to which they are bonded may also form a five- or six-membered ring which can be interrupted by a hetero atom and have attached to it one or more substituents; R5, R6 are hydrogen, halogen, alkyl, haloalkyl or alkoxy; R7, R8 are hydrogen, halogen, alkyl or haloalkyl; R9 is hydrogen, halogen, alkyl, alkoxy, cycloalkoxy, haloalkoxy or alkoxycarbonyl, Processes and intermediates for the preparation of these ...

Azolyl oxybenzyl alkoxyacrylic acid esters, process for producing them and their use

Fungicide mixture

Fungicide mixtures

6-(2-chloro-6-fluoro-phenyl)-triazolopyrimidines

... 6-(2-Chloro-6-fluoro-phenyl)-triazolopyrimidines of formula (I), in which R1 and R2 independently denote hydrogen or alkyl, alkenyl, alkynyl, alkadienyl, or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or where R1 and R2 radicals may be unsubstituted or partially or fully halogenated or may be substituted as defined in the description. R1 and R2 together with the interjacent nitrogen atom represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted; X is cyano, alkoxy, haloalkoxy or alkenyloxy; processes for their preparation, compositions containing them and to their use for combating phytopathogenic fungi ...

Fungicidal mixtures

A fungicidal mixture comprises a1) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c a2) a carbamate of the formula Id where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or one of its salts or adducts, and b) a dinitrophenol derivative of the formula II.a or II.b in a synergistically effective amount.

6-phenyl-pyrazolopyrimidines

... 6-Phenyl-Pyrazolopyrimidines of formula IwhereinR1 is alkyl, alkenyl, alkynyl, alkadienyl or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, where these radicals may be unsubstituted or substituted as defined in the specification, Y is oxygen, sulfur, NR2 or a single bond; wherein R2is defined in the specification; andR1 and R 2 together with the interjacent nitrogen atom may represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted by one or more Rc radicals;m is 0 or an integer from 1 to 4;L each independently is halogen, nitro, alkyl, alkoxy, andX is halogen;processes and intermediates for preparing these ...

Azolyloxybenzylalkoxyacrylic esters, their preparation and their use

Compounds of formula Iwhereinn is 0, 1, 2, 3, or 4;R is nitro, cyano, halogen, unsubstituted or substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy or two adjacent radicals R form an optionally substituted three or four membered bridge;R1, R2 are C1-C4-alkyl; andR3 is a substituted pyrazole or triazole ring;their preparation and intermediates adapted therefore, and their use for controlling animal and fungal pests.

7-(R)-aminotriazolopyrimidines, their preparation and their use for controlling phytopathogenic fungi

... 7-(R)-Aminotriazolopyrimidines of the formula I where the substituents and the index are as defined below: R1 is hydrogen or methyl; R2 is methyl; R3 is C2-C1o-alkyl, C1-C4-alkoxymethyl, C3-C1o-cycloalkyl; R4 is halogen, Cl-C4-alkyl, C1-C4-haloalkyl or Cl-C4-alkoxy; n is a number from 1 to 5; Y is halogen, cyano, Cl-C4-alkyl or Cl-C4-alkoxy; where * is a center of chirality in the R configuration, processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi are described.

Fungicidal triazolopyrimidines, method for the production thereof and use thereof in controlling noxious fungi and agents containing said compounds

Triazolopyrimidines of formula (I), wherein the index and substituents have the following meaning: n=0 or a whole number of 1-5; R=halogen, cyano, hydroxy, cyanate, alkyl, alkenyl, alkinyl, halogenalkyl, halogenalkenyl, alkoxy, alkenyloxy, alkinyloxy, halogenalkoxy, cycloalkyl, cycloalkenyl, cycloalkoxy, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoximinoalkyl, alkenyloximinocarbonyl, alkinyloximinoalkyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, cycloalkylcarbonyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S; R¹=alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, phenyl, naphthyl or a five to ten membered saturated, partially unsaturated or aromatic heterocycle, containing one to four heteroatoms from the group O, N or S, R and/or R¹ being able to be substituted according to the description ...

5-Phenylpyrimidines, methods and intermediate products for the production thereof and use of the same for controlling pathogenic fungi

The invention relates to 5-phenylpyrimidine of formula (I) wherein the substituents have the following designations: R¹ represents a five to ten-membered saturated, partially unsaturated or aromatic monocyclic or bicyclic heterocycle which contains between one and four heteroatoms from the group O, N or S, and which can be substituted as defined in the description; R² represents hydrogen, halogen, cyano, alkyl, halogenalkyl or alkoxy; R³ and R⁴ represent hydrogen, alkyl, halogenalkyl, cycloalkyl, halogencycloalkyl, alkenyl, halogenalkenyl, cycloalkenyl, alkinyl, halogenalkinyl or cycloalkinyl; together with the nitrogen atom to which they are bonded, R³ and R⁴ can also form a five or six-membered ring which can be split by a heteroatom and can carry at least one substituent; R⁵ and R⁶ represent hydrogen, halogen, alkyl, halogenalkyl or alkoxy; R¹ and R⁸ represent hydrogen, halogen ...

Fungicidal mixtures

A fungicidal mixture, comprising at least one compound selected froma) [sic] carbamates of the formula I, in which T is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, where the radicals R may be different if n is 2,a2) the oxime ether carboxylate of the formula II ora3) the oxime ether carboxamide of the formula III, andb) a compound of the formula IV where the substituents R1 to R3 have the following meaning:R1 is C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkyl-C3-C7-cycloalkyl, where these radicals may carry substituents selected from halogen, cyano and Cl-C4-alkoxy,R2 is C1-C4-alkyl or C1-C4-haloalkyl,R3 is hydrogen, halogen, Cl-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, N-C1-C4-alkylamino, Cl-C4-haloalkyl or C1-C4-haloalkoxy,Y is O, S, CHR4 or NR5, where R4 and R5 may each have the meanings mentioned for R2,n is 0, 1, 2 or 3,in a synergistically effective amount, and methods for controlling harmful fungi using these mixtures are described.

Fungicidal mixtures

A fungicidal mixture containing a) a carbamate of the formula I, where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, and b) a carboxamide II selected from the group consisting of the compounds IIa and IIb in a synergistically active amount is described.

Salicylohydrazide derivatives, processes and intermediates for their preparation, compositions comprising them, and their use

Salicylohydrazide derivatives of the formula Iin which the index and the substituents have the following meanings:X is halogen, NO2, cyano, alkyl or alkoxy;m is 0, 1, 2 or 3, it being possible for the substituents X to differ from each other if n is greater than 1;R1 is NO2, NH2 or NH-CO-A;A is hydrogen, alkyl, alkoxy, NH2, NHCH3 or N(CH3)2;R2 is hydrogen, cyano, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy or alkylthio;it being possible for the hydrocarbon radicals to be unsubstituted or substituted,R3 is phenyl, naphthyl, cycloalkyl, 5-membered or 6-membered hetaryl or 5-membered or 6-membered heterocyclyl containing one to three N atoms and/or one O or S atom or one or two O and/or S atoms, the ring systems being unsubstituted or substituted;the preparation of these compounds, compositions comprising them, and their use for controlling harmful fungi.

Phenylacetic acid derivatives, process and intermediate products for their preparation, and their use as fungicides and pesticides

Phenylacetic acid derivatives of the formula Iwhere the variables are as disclosed herein, their salts, processes and intermediates for their preparation, and their use for controlling harmful fungi and animal pests.

2-phenoxyphenylacetic acid derivatives, method and intermediate products for the production thereof, their use, and agents containing the same for combating fungicidal pests

... 2-Phenoxyphenylacetic acid derivatives of the formula Iwhere the substituents and the index have the following meanings:A is whereR1 is halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C4-haloalkoxy, formyl, C(=O)NRaRb or C(Ra)=NORb;Ra is hydrogen or C1-C4-alkyl;Rb is C1-C4-alkyl;n is 1, 2, 3 or 4, where the groups R1 may be different if n is not 1;R2 is halogen, CH3 or CF3;m is 0 or 1; andX is OCH3 or NHCH3;processes and intermediates for preparing the compounds I and the use of the compounds I for controlling harmful fungi are described.

Method for producing alkenyl-substituted bis(oxime ether) derivatives

The process for preparing alkenyl-substituted bis(oxime ether) derivatives of the formula Iwhere:R1 is unsubstituted C1-C4-alkyl or C2-C4-alkenyl-, C2-C4-alkynyl- or phenyl-substituted methyl;R2, R4 independently of one another are hydrogen or methyl;R3, R5 independently of one another are hydrogen or C1-C4-alkyl, trifluoromethyl or phenyl andX is -C(=CHCH3)-COOCH3,-C(=CHOCH3)-COOCH3,-C(=NOCH3)-COOCH3,-C(=NOCH3)-CONHCH3 or-N(OCH3)-COOCH3,and intermediates which are obtainable by this process are described. Alkenyl-substituted bis(oxime ether) derivatives of the formula I are described in the literature as interesting crop protection agents.

Fungicidal mixtures

A fungicidal mixture, comprising at least one compound selected froma) carbamates of the formula I, where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2,a2) the oxime ether carboxylate of the formula II ora3) the oxime ether carboxamide of the formula III, andb) a compound of the formula IVin a synergistically effective amount.

Method and intermediate products for producing bis(oxime)monoethers

A process for preparing bis(oxime) monoethers of the formula I,where:R1 is unsbustituted C1-C4-alkyl or C2-C4-alkenyl-, C2-C4-alkynyl- or phenyl-substituted methyl;R2,R4 independently of one another are hydrogen or methyl;R3,R5 independently of one another are hydrogen or C1-C4-alkyl, trifluoromethyl or phenyl,and intermediates which are obtainable by this process are described.

Combatting parasitic fungi with a combination of an active agent inhibiting respiration in the cytochrome complex III and of fenazaquine

The present invention relates to compositions for controlling harmful fungi which comprise, as active ingredients, at least one compound which inhibits respiration on the cytochrome complex III and fenazaquin. The compositions according to the invention are useful in particular for controlling botrytis.

2-[1', 2', 4'-triazol-3'-yloxymethlene]anilides, their preparation and their use

... 2-[1',2',4'-Triazol-3'-yloxymethylene]anilides of the formula Iwhere the index and the substituents have the following meanings:n is 0, 1, 2, 3 or 4;X is a direct bond, O or NRa;Ra is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl;R1 is nitro, cyano, halogen, unsubstituted or substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy or alkynyloxy;R2 is hydrogen, nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, alkylthio or alkoxycarbonyl;R3 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl or heteroaryl;R4 is hydrogen, unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkylcarbonyl or alkoxycarbonyl;R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl,processes and intermediates for their preparation and their use are described.

Iminooxy-substituted benzyl phenyl ethers, processes and intermediates for their preparation, compositions comprising them, and their use for controlling harmful fungi

Iminooxy-substituted benzyl phenyl ethers of the formula Iin which the substituents and the index are as defined below:Y is H, CH3, F or Cl;Q is C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3, C(=NOCH3)-CONHCH3 or N(-OCH3)-COOCH3;X is hydrogen, halogen, alkyl, alkoxy or CF3;m is 1 or 2, where the radicals X may be different if m=2;R1 is alkyl andR2 is hydrogen or alkyl; orR1 and R2 together are cyclopropyl, cyclopentyl or cyclohexyl;R3 is alkyl or CF3; andR4 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl or haloalkynyl;processes and intermediates for their preparation, compositions comprising them, and their use, are described.

6-(2-trifluoromethyl-phenyl)-triazolopyrimidines

... 6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines of formula Iin whichR1 and R2 independently denote hydrogen oralkyl, alkenyl, alkynyl, alkadienyl, or haloalkyl,cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, orwhere R1 and R2 radicals may be unsubstituted or substituted as defined in the specification; orR1 and R2 together with the interjacent nitrogen atom represents a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted as defined in the specification;R3 is hydrogen, halogen, alkyl, alkoxy and haloalkyl; andX is halogen;processes and intermediates for preparing these compounds, compositions comprising them and their use for ...

Fungicidal mixtures

A fungicidal mixture comprisesa) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, and/or a carbamate of the formula Idwhere X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof,and(b) a N-acetonylbenzamide of the formula II where:R1 and R3 independently of one another are each halogen or C1-C4-alkyl;R2 is cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy;R4 is hydrogen or C1-C4-alkyl;R5 is C2-C4-alkyl;R6 is thiocyano, isothiocyano or halogen,or a salt or adduct thereof,in a synergistically effective amount.

Phenylketiminooxybenzyl compounds, method for the production and use thereof

Phenylketiminooxybenzyl compounds of the general formula Iwhere:X is O or NH;R1 is fluorine, chlorine, alkyl, haloalkyl, alkoxy and haloalkoxy;R2 is halogen, alkyl, haloalkyl and alkoxy;R3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy or CRa=NORb (Ra=hydrogen or alkyl; Rb=alkyl, alkenyl or alkynyl);n is 1, 2 or 3,and salts thereof, processes for their preparation and their use for controlling animal pests and harmful fungi.

Method for controlling parasitic fungi in cultivated plants

A method for controlling harmful fungi in crop plants having modified pathogen resistance to certain harmful fungi, where the crop plant is treated with an active compound from the class of the strobilurins.

6-phenyl-pyrazolopyrimidines

... 6-Phenyl-Pyrazolopyrimidines of formula IwhereinR<1 >is alkyl, alkenyl, alkynyl, alkadienyl or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heterocyclyl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom,where these radicals may be unsubstituted or substituted as defined in the specification,Y is oxygen, sulfur, NR<2 >or a single bond; wherein R<2 >is defined in the specification; andR<1 >and R<2 >together with the interjacent nitrogen atom may represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted by one or more Rradicals;m is 0 or an integer from 1 to 4;L each independently is halogen, nitro, alkyl, alkoxy, andX is halogen;processes and intermediates for preparing ...

2-(0-(Pyrimidin-4-yl)methyleneoxy)phenylacetic acid derivatives and their use for controlling harmful fungi and animal pests

... 2-(O-[pyrimidin-4-yl]methylenoxy)phenylacetic acid derivatives of the general formula Iand the salts and N-oxides thereof where the radicals R1 to R4 and Q have the following meanings:R1 is hydrogen or alkyl;R2 is halogen, alkyl or haloalkyl;R3 is hydrogen; amino; hydroxyl; mercapto; halogen; unsubstituted or phenyl-substituted alkyl; haloalkyl; alkoxyalkyl; alkoxy; monoalkylamino; dialkylamino; alkylthio; alkylsulfoxyl; alkylsulfonyl; cycloalkyl; trialkylsilyloxy, or: phenyl, phenoxy, phenoxymethyl, benzyloxy or hetaryl, unsubstituted or substituted in the aromatic ring;R4 is hydrogen; cyano; halogen; alkyl; haloalkyl or alkoxy;Q isC(=NOCH3)-CONHCH3,C(=NOCH3)-COOCH3 orN(OCH3)-COOCH3,the salts and N-oxides thereof, and their use for controlling harmful fungi and animal pests.

6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines

... 6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines of formula I in which R1and R2independently denote hydrogen or alkyl, alkenyl, alkynyl, alkadienyl, or haloalkyl, cycloalkyl, bicycloalkyl, phenyl, naphthyl, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or 5- or 6-membered heteroaryl, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or where R1and R2radicals may be unsubstituted or substituted as defined in the specification; or R1and R2together with the interjacent nitrogen atom represent a 5- or 6-membered heterocyclic ring, containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, which may be substituted as defined in the specification; R3is hydrogen, halogen, alkyl, alkoxy and haloalkyl; and X is halogen; processes and intermediates for preparing these compounds, compositions comprising them and their use for ...

Substituted benzyl oximino compounds

The present invention relates to benzyloxyimino compounds of the formula I,where: R1 to R4, X, Y, and Z are as defined in the specification.

7-(r)-aminotriazolopyrimidines, the production thereof and use of the same for combatting phytopathogenic fungi

The invention relates to 7-(R) aminotriazolopyrimidines of formula (I), in which the substituents and index have the following definitions: R1 represents hydrogen or methyl; R2 represents methyl; R3 represents C2-C10 alkyl, C1-C4 alkoxymethyl, or C3-C10 cycloalkyl; R4 represents halogen, C1-C4 alkyl, C1-C4 haloalkyl or C1-C4 alkoxy; n represents a number between 1 and 5; Y represents halogen, cyano, C1-C4 alkyl or C1-C4 alkoxy; whereby * is a chirality centre with an R-configuration. The invention also relates to a method for producing said compounds, to agents containing the compounds and to the use thereof for combating harmful fungi.

Fungicidal mixtures

A fungicidal mixture comprises a) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, and b) a N-acetonylbenzamide of the formula II where: R1and R3independently of one another are each halogen or C1-C4-alkyl; R2is cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy; R4is hydrogen or C1-C4-alkyl; R5is C2-C4-alkyl; R6is thiocyano, isothiocyano or halogen, or a salt or adduct thereof, in a synergistically effective amount.

Hetaryl-substituted benzyl phenyl ethers, method for the production thereof, and their use for combating harmful fungi and animal pests

The invention relates to hetaryl-substituted benzyl phenyl ethers of formula (I) in which the substituents have the following meanings: (Q):C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3, C(=NOCH3)-CONHCH3, N(-OCH3)-COOCH3 or a group F, G, H or J, whereby # characterizes the bond with the phenyl ring, and (X) five-linked heteroaryl which is optionally substituted by a group Y2p and which contains one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom. The invention also relates to the salts of the inventive hetaryl-substituted benzyl phenyl ethers, to the production of compounds (I), and to the use of compounds (I) for combating harmful fungi and animal pests.

Bisimino-substituted phenyl compounds and their use as pesticides

Imino-substituted phenyl compounds of the formula Iwhere the substituents have the following meanings:z is a group A or B where # denotes the bond with the phenyl ring and Ra is halogen, alkyl or alkoxy;y is halogen, alkyl, haloalkyl or alkoxy;n is 0, 1 or 2, it being possible for the radicals Y to be different if n=2;R1 is halogen, haloalkyl or alkoxy;R2 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl;R3 is cyano, alkyl, haloalkyl, alkoxy, cycloalkoxy, alkoxyalkyl; unsubstituted or substituted cycloalkyl, aryl, aryloxy or arylmethylene, heteroaryl, heterocyclyl, C(R3a)=N-OR3b or C(R3a)=CR3cR3d, whereR3a, R3b, R3c, R3d independently of one another are hydrogen, alkyl or unsubstituted or substituted phenyl,processes for their preparation, and their use.

O-benzyloxime ethers and crop protection agents containing these compounds

O-Benzyloxime ethers of the formula IwhereX is substituted or unsubstituted CH2, NOalkylY is O, S, NR5R1, R2, R5 are H, alkylZ1, Z2 are H, halogen, methyl, methoxy, cyanoR3, R4 are hydrogen, cyano, substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, alkynyl, alkoxy, haloalkoxy, alkylthio, benzylthio, alkylcarbonyl, substituted or unsubstituted phenylcarbonyl, substituted or unsubstituted benzylcarbonyl, alkoxycarbonyl, substituted or unsubstituted phenoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl,N(R6)2, where R6 is H, alkyl, substituted or unsubstituted phenyl,-CO-N(R7)2, where R7 is H, substituted or unsubstituted alkyl,substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted arylthio, substituted or unsubstituted hetaryl, substituted or unsubstituted hetaryloxy, substituted or unsubstituted hetarylthio, substituted or unsubstituted heterocyclyl, substituted or unsubstituted heterocyclyloxy,R3 and R4 together ...

Fungicidal mixtures

A fungicidal mixture comprisesa.1) a carbamate of the formula I.a,in which X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, ora.2) the oxime ether carboxamide of the formula I.b andb.1) 4-[2-methyl-3-(4-tert-butylphenyl)propyl]-2,6-dimethylmorpholine orb.2) 4-(C10-C13-alkyl)-2,6-dimethylmorpholine orb.3) (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine andc) a further active ingredient from the class of the strobilurin fungicides (III),in a synergistically effective amount.

Phenylacetic acid derivatives, process for their preparation and their use as pesticides and fungicides

Phenylacetic acid derivatives of the formula Iwhere the substituents and the indexes have the meanings given in the specification, their salts, their preparation and their use.

7-amino triazolopyrimidines for controlling harmful fungi

The invention relates to 7-amino triazolopyrimidines of formula (I), in which the substituents have the following meanings: R¹, R² represent hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, phenyl, naphthyl; or 5-membered or 6-membered heterocyclyl containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; or 5-membered or 6-membered heteroaryl containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or R¹ and R² can, together with the nitrogen atom, which binds them, form a 5-membered or 6-membered ring containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; R³ represents alkyl, alkenyl, alkynyl, cycloalkyl, phenylalkyl and alkyl halide; whereby R³ and R² can be unsubstituted or partially or completely substituted according to the description; X represents halogen, cyano, alkoxy, alkyl ...

Fungicidal mixture

A composition comprising effective amounts ofa) a carbamate (I) wherein T is CH or N, n is 0, 1 or 2, and R is halogen, C1-C4-al-kyl or C1-C4-haloalkyl, where the radicals R are identical or different if n is 2, andb) an azole (IV) as defined in the specification which exhibits a synergistically enhanced fungicidal effect is described.

7-(r)-aminotriazolopyrimidines, the production thereof and use of the same for combatting phytopathogenic fungi

A 7-(R)-Aminotriazolopyrimidines of formula Iwhere the substituents and index are as defined below:R<1 >is hydrogen or methyl;R<2 >is methyl;R<3 >is C2-C10-alkyl, C1-C4-alkoxymethyl, C3-C10-cycloalkyl;Y is halogen, cyano, C1-C4-alkyl or C1-C4-alkoxy;where * is a center of chirality in the R configuration,processes for their preparation, compositions comprising them and their use for controlling harmful fungi.

Use of 2-(n-phenylamino)pyrimidines as fungicides, and novel 2-(n-phenylamino) pyrimidines

... 2-(N-phenylamino)pyrimidines of the formula I,where:R1, R3 independently of one another are cyano, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or are C3-C8-cycloalkyl or a group C(=NORx)RyR2 is halogen, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, orR1 and R2 together with the two linking carbon atoms form a fused-on partially unsaturated 4- to 8-membered ring which may be up to trisubstituted by identical or different substituents selected from the group consisting of C1-C4-alkyl, halogen and C1-C4-alkoxy-carbonyl, which may contain a carbonyl group and/or, in addition to the multiple bond of the pyrimidine ring, a double bond and/or which may be interrupted by O, S or N-(C1-C4-alkyl);the substituents R4 to R8, Rx, Ry, Ra and Rb are as defined in the ...

Fungicide mixture

A composition comprising effective amounts of a) a carbamate of the formula I where T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, and c) a compound III selected from the group consisting of the oxime ether carboxylate IIIa, the oxime ether carboxamide IIIb and the methoxyacrylate IIIc and optionally an oxime ether (II) and/or an azole (IV) as defined in the specification which exhibits a synergistically enhanced fungicidal effect is described.

5-Phenylpyrimidines, methods and intermediate products for the production thereof and use of the same for controlling pathogenic fungi

The invention relates to 5-phenylpyrimidine of formula (I) wherein the substituents have the following designations: R1 represents a five to ten-membered saturated, partially unsaturated or aromatic monocyclic or bicyclic heterocycle which contains between one and four heteroatoms from the group O, N or S, and which can be substituted as defined in the description; R2 represents hydrogen, halogen, cyano, alkyl, halogenalkyl or alkoxy; R3 and R4 represent hydrogen, alkyl, halogenalkyl, cycloalkyl, halogencycloalkyl, alkenyl, halogenalkenyl, cycloalkenyl, alkinyl, halogenalkinyl or cycloalkinyl; together with the nitrogen atom to which they are bonded, R3 and R4 can also form a five or six-membered ring which can be split by a heteroatom and can carry at least one substituent; R5 and R6 represent hydrogen, halogen, alkyl, halogenalkyl or alkoxy; R1 and R8 represent hydrogen, halogen, alkyl or halogenalkyl; and R9 represents hydrogen, halogen, alkyl, alkoxy, cycloalkoxy, halogenalkoxy or alkoxycarbonyl ...

Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them

Phenylacetic acid derivatives of the formula Iwhere the substituents and the index have the following meanings:X is oxygen or sulfur;R is hydrogen or alkyl;R1 is hydrogen or alkyl;R2 is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy;m is 0, 1 or 2, it being possible for the R2 radicals to be different if m is 2;R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino or dialkylamino;R4 is hydrogen, cyano, nitro, hydroxyl, amino, halogen,unsubstituted or substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkynyl, alkynyloxy, alkynylthio, alkynylamino, N-alkynyl-N-alkylamino;unsubstituted or substituted cycloalkyl, cycloalkoxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino ...

Salicylohydrazide derivatives, processes and intermediates for their preparation, compositions comprising them, and their use

Salicylohydrazide derivatives of the formula I in which the index and the substituents have the following meanings: X is halogen, NO2, cyano, alkyl or alkoxy; m is 0, 1, 2 or 3, it being possible for the substituents X to differ from each other if n is greater than 1; R1is NO2, NH2or NH—CO—A; A is hydrogen, alkyl, alkoxy, NH2, NHCH3or N(CH3)2; R2is hydrogen, cyano, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy or alkylthio; it being possible for the hydrocarbon radicals to be unsubstituted or substituted, R3is phenyl, naphthyl, cycloalkyl, 5-membered or 6-membered hetaryl or 5-membered or 6-membered heterocyclyl containing one to three N atoms and/or one O or S atom or one or two O and/or S atoms, the ring systems being unsubstituted or substituted; the preparation of these compounds, compositions comprising them, and their use for controlling harmful fungi.

Fungicidal mixtures

A fungicidal mixture comprisinga.1) a carbamate of the formula I.a, in which X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, where the radicals R can be different if n is 2, andb) a copper-containing fungicidal active compound (II) in a synergistically active amount.

Use of Strobilurin Type Compounds for Combating Phytopathogenic Fungi Resistant to QO Inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health applications, and to seeds coated with at least one such compound.

Use of Strobilurin Type Compounds for Combating Phytopathogenic Fungi Resistant to QO Inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health applications, and to seeds coated with at least one such compound. 1. (canceled)3. The compound of claim 2 , wherein Ris selected from the group consisting of hydrogen claim 2 , halogen claim 2 , C-C-alkyl claim 2 , C-C-chloroalkyl claim 2 , C-C-alkoxy claim 2 , C-C-alkoxy-C-C-alkyl and C-C-haloalkoxy-C-C-alkyl.4. The compound of claim 3 , wherein Ris methyl or ethyl.5. The compound of claim 2 , wherein Ris hydrogen.6. The compound of claim 2 , wherein Y is selected from the group consisting of —OCH— claim 2 , —CHCH— claim 2 , —C(CH)═N—O—CH— claim 2 , —O—N═C(CH)—C(CH)═N—O—CH— and —C(═N—O—CH)—C(CH)═N—O—CH—.7. The compound of claim 1 , wherein Ris phenyl claim 1 , wherein said phenyl is optionally substituted by 1 claim 1 , 2 claim 1 , 3 or up to the maximum possible number of identical or different groups R claim 1 , which may be the same or different to any other R claim 1 , wherein Ris selected from the group consisting of halogen claim 1 , C-C-alkyl claim 1 , C2-C4-alkenyl claim 1 , C-C-haloalkyl claim 1 , C-C-alkoxy claim 1 , C-C-haloalkoxy claim 1 , C-C-alkoxyimino-C-C-alkyl claim 1 , phenyl and a 5-membered saturated claim 1 , partially unsaturated or aromatic heterocyclyl which claim 1 , in addition to carbon atoms claim 1 , contains one to three heteroatoms selected from the group consisting of N claim 1 , O and S as ring members; and wherein the aforementioned heterocyclyl groups Rare attached via a direct bond claim 1 , an oxygen or sulfur atom and for their part may carry 1 claim 1 , 2 claim 1 , 3 or up ...

Processo para preparar hidroxílaminas aromáticas ou heteroaromáticas

CARBAMATES AND PHYTOSANITARY AGENTS CONTAINING THESE.

CARBAMATO DE LA FORMULA (I) COMO PRODUCTO DE ADICION ACIDA TOLERABLE POR LAS PLANTAS Y PRODUCTOS DE ADICION DE BASE, Y LOS FUNGICIDAS QUE LO CONTIENE. CARBAMATE OF THE FORMULA (I) AS A TOLERABLE ACID ADDITION PRODUCT FOR THE BASE ADDITION PLANTS AND PRODUCTS, AND THE FUNGICIDES CONTAINING IT.

Compositions and methods for controlling harmful fungi

The invention pertains to agents intended for use against harmful fungi and containing as active substances at least one compound which inhibits respiration by inhibiting the cytochrome complex III, and at least one amide compound of formula (II) A-CO-NR1R2 in which A, R1 and R2 have the meanings indicated in the description. The proposed agents are especially suitable for use against Botrytis.

Oxirane phenyl esters and fungicides containing these

Esters of the general formula I ##STR1## where A is hydrogen, alkyl, cycloalkyl, cycloalkenyl, naphthyl, biphenyl, hetaryl or phenyl, these radicals being substituted or unsubstituted, and X is CH or N, and fungicides containing these esters.

Ortho-substituierte 2-methoxyiminophenylessigsäuremethylamide

Pyridyl phenyl and benzyl ethers, processes and intermediates for their preparation and their use

The invention concerns pyridyl-phenyl- and benzylethers of formula (I), and their salts and N-oxides, in which the substituents and indices have the following meanings: Q is C(CO2CH3)=CHCH3, C(CO2CH3)=CHOCH3, C(CONH2)=NOCH3, C(CO2CH3)=NOCH3, C(CONHCH3)=NOCH3 or N(OCH3)-CO2CH3; n is 0 or 1; R<1> is hydrogen or an organic group bonded via a carbon atom; R<2> is hydrogen, cyano, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; R<3> is hydrogen, halogen, C1-C4 alkyl or C1-C2 alkyl halide; x is 0, 1 or 2; R<4> is cyano, nitro, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; y is 0, 1, 2 or 3; and R<5> is cyano, halogen, C1-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy. The invention further concerns a process and intermediate products for preparing these substances and their use.

Use of strobilurin type compounds for combating phytopathogenic fungi resistant to qo inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health 10 applications, and to seeds coated with at least one such compound.

Fungicidal mixtures

NEW 3-METHOXIMINOPROPIONIC ACID ESTERS AND FUNGICIDES CONTAINING THEM

Method for combating harmful fungi

Salicylic acid derivatives, process for their preparation, agents containing the same as well as their use in combatting harmful fungi

3-ANILINO-BENZISOTHIAZOLE AND FUNGICIDES CONTAINING THEM

ORTHO-SUBSTITUTED 1-NAPHTHYL ETHER AND FUNGICIDES CONTAINING THEM

Benzyl ketones and fungicides containing them

FUNGICIDES CONTAINING NEW 7-AMINO-AZOLO (1,5-A) -PYRIMIDINE AS ACTIVE SUBSTANCES

Die Erfindung betrifft fungizide Mittel, enthaltend einen festen oder fluessigen Traegerstoff und ein Aminoazolopyrimidin der Formel I, worin R1 Alkyl oder Arylalkyl, R2 und R3 Wasserstoff oder Alkyl, A ein Stickstoffatom oder eine CR4-Gruppe bedeutet, wobei R4 die Bedeutung Wasserstoff, Alkyl oder Halogen hat. The invention relates to fungicidal compositions containing a solid or liquid Traegerstoff and an aminoazolopyrimidine of the formula I, wherein R 1 is alkyl or arylalkyl, R 2 and R 3 is hydrogen or alkyl, A is a nitrogen atom or a CR 4 group, wherein R 4 is hydrogen, alkyl or Halogen has.

Dibenzofurane derivatives, process for their preparation and their use as fungicides

Pyridinium salts and fungicides and bactericides containing them

5-isoxazolecarboxamides, their preparation and their use as fungicides

THIADIAZOLYL URINE CONTAINING AGENT FOR DEBELING PLANTS

SALTS OF ALPHA -AMINOACETANILIDES

1-Azolyl-2,2-di:carbonyl substd. ethane derivs. - useful as soil nematocides

Substituted crotonates and fungicides containing them

ABSTRACT OF THE DISCLOSURE: Substituted crotonates of the formula

Use of strobilurin type compounds for combating phytopathogenic fungi resistant to qo inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health 10 applications, and to seeds coated with at least one such compound.

Fungicide mixtures

The invention relates to a fungicide mixture, containing at least one active agent chosen from al) carbamates of formula (Ia), wherein T means CH or N, n stands for 0, 1 or 2 and R is halogen, C1-C4 alkyl or C1-C4alkyl halide and the radicals R can be different when n is 2; and a2) oximether carboxylic acid ester of formula (Ib), a3) oximether carboxylic acid amide of formula (Ic), and b) at least one active agent of for-mulae (II.1) to (II.5), in a synergetically ef-fective quantity. The invention also relates to a method for using the inventive mix-tures as fungicides.

Preparation of phenoxy-substituted esters and intermediates therefor

- 13 - O.Z. 0050/38855 Abstract of the Disclosure: Compounds of the formula I I where R1 is or where A is C1-C4 alkyl, phenyl or C7-C12-aralkyl and l is 0 or 1, R2 is C1-C4-alkyl, n is 0, 1, 2 or 3, m is 1, 2 or 3 and Y is hydrogen, fluorine, chlorine, brom-ine, C1-C3-alkyl, C1-C3-alkoxy, trifluoromethyl, phenyl or phenoxy, and, when m is greater than 1, the individual atoms or groups Y are identical or different, are pre-pared by a process in which, in a first stage, a diester of the formula II II is hydrolyzed with one equivalent of an aqueous alkali metal hydroxide to give the alcohol of the formula IIIa IIIa, in a second stage this alcohol is converted with a halo-genating agent or a sulfonyl chloride or bromide into a compound of the formula IIIb IIIb where X is a nucleophilically displaceable leaving group, such as chlorine, bromine, mesyl or tosyl, and then, in a third stage, the compound IIIb is reacted with a pheno-late of the formula IV IV - 14 - O.Z. 0050/38855 where Y and m have the abovementioned meanings, in the presence of an aprotic solvent to give compound I. Fur-thermore, diesters of the formula II and a process for their preparation are provided, the said diesters being prepared by reacting a lactone of the formula V v with a Grignard compound VI R1MgZ VI where 2 is chlorine or bromine, in a nonpolar organic solvent, from 2 to 3 moles of the Grignard compound being used per mole of lactone, and the reaction mixture then being treated with from 2 to 3 moles of anhydride VII VII per mole of lactone.

Fungicidal mixtures

5-phenylpyrimidine, methods and intermediate products for the production thereof and use of the same for controlling pathogenic fungi

The invention relates to 5-phenylpyrimidine of formula (I) wherein the substituents have the following designations: R1 represents a five to ten-membered saturated, partially unsaturated or aromatic monocyclic or bicyclic heterocycle which contains between one and four heteroatoms from the group 0, N or S, and which can be substituted as defined in the description; R2 represents hydrogen, halogen, cyano, alkyl, halogenalkyl or alkoxy; R3 and R4 represent hydrogen, alkyl, halogenalkyl, cycloalkyl, halogencycloalkyl, alkenyl, halogenalkenyl, cycloalkenyl, alkinyl, halogenalkinyl or cycloalkinyl; together with the nitrogen atom to which they are bonded, R3 and R4 can also form a five or six-membered ring which can be split by a heteroatom and can carry at least one substituent; R5 and R6 represent hydrogen, halogen, alkyl, halogenalkyl or alkoxy; R7 and R8 represent hydrogen, halogen, alkyl or halogenalkyl; and R9 represents hydrogen, halogen, alkyl, alkoxy, cycloalkoxy, halogenalkoxy or alkoxycarbonyl. The invention also relates to methods and intermediate products for producing said compounds and the use of the same for controlling pathogenic fungi.

Fungicidal mixtures

Fungicidal mixture containing in a synergistically active quantity: a) a carbamate of the formula (I) in which T is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4alkyl or C1-C4 alkylhalide, where the radicals R may be different if n is 2; and/or b) an oxime ether of the formula (II) in which X is oxygen or amino (NH), Y is CH or N, Z is oxygen, sulphur, amino (NH) or C1-C4 alkylamino (N-C1-C4-alkyl), R' is C1-C6 alkyl, C1-C6 alkylhalide, C3-C6 alkenyl, C2-C6 halogen alkenyl, C3-C6 alkinyl, C3-C6 halogen alkinyl, C3-C6 cycloalkyl methyl or benzyl which may be partially of fully halogenated and/or may contain one to three of the radicals cyano, C1-C4 alkyl, C1-C4 alkylhalide, C1-C4 alkoxy, C1-C4 alkoxyhalide and C1-C4 alkylthio; and c) a dinitroaniline of the formula (III).

2-[(dihydro)pyrazol-3'-yloxymethylene]anilide derivatives, fungicides and pest-control agents

2-[(Dihydro)pyrazol-3'-yloxymethylene]anilides of the formula I processes and intermediates for their preparation and their use as pesticides and fungicides.

Thiocarboxylic esters and fungicides containing them

O.Z. 0050/41237 ABSTRACT OF THE DISCLOSURE: Thiocarboxylic esters of the formula I I where the substituents have the following meanings: X is oxygen, sulfur, oxymethylene, methyleneoxy, thiomethylene, methylenethio, ethylene, ethenylene or ethynylene, Y,Z are each sulfur or oxygen, but Y and Z are not simultaneously oxygen, R is alkyl, mononuclear, dinuclear or trinuclear aryl or hetaryl, where aryl and hetaryl may be substituted, and fungicidal agents containing these compounds.

Fungicide mixtures

Phenylacetic acid derivatives, method and intermediates of their production, their use and substances containing them

Opisujú sa zlúčeniny všeobecného vzorca (I), kde substituenty a index majú význam: X je kyslík alebo síra, R1 znamená vodík a alkyl, R2 znamená kyano, nitro, trifluórmetyl, halogén, alkyl a alkoxy, m znamená 0, 1 alebo 2, pričom zvyšky R2 môžu byť rovnaké alebo rozdielne, ak m znamená 2, R3 znamená vodík, kyano, nitro, hydroxy, amino, halogén, alkyl, halogénalkyl, alkoxy, halogénalkoxy, alkyltio, alkylamino alebo dialkylamino, R4 znamená vodík, kyano, nitro, hydroxy, amino, halogén, prípadne substituovaný alkyl, alkoxy, alkyltio, alkylamino, di-alkylamino, alkenyl, alkenyloxy, alkenyltio, alkenylamino. Význam ostatných substituentov je uvedený v opise. Vzhľadom na svoje vlastnosti sa uvedené deriváty kyseliny fenyloctovej používajú pri ničení živočíšnych škodcov a škodlivých húb.ŕ Described are compounds of formula (I) wherein the substituents and the index are: X is oxygen or sulfur, R 1 is hydrogen and alkyl, R 2 is cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy, m is 0, 1 or 2, wherein the radicals R2 can be identical or different when m is 2, R3 is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino or dialkylamino, R4 is hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, di-alkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino. The meaning of the other substituents is given in the description. Due to their properties, said phenylacetic acid derivatives are used in the control of animal pests and harmful fungi.

Fungicidal mixture

Azole compounds, their preparation, and plant growth regulators

ABSTRACT OF THE DISCLOSURE: Azole compounds of the formula I (I) where R is fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, trifluoromethyl, phenyl or phenoxy and m is 0 or an integer from 1 to 5 and, when m is greater than 1, the individual atoms or groups may be identical or different, is tert-butyl, 5-methyl-1,3-dioxan-5-yl, 1-methylcyclohexyl, 2-methyltetrahydropyran-2-yl or

TRIAZOLIC COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND FUNGICIDES CONTAINING THEM

Phenylacetic acid derivatives, their preparation, and their use

The invention concerns phenylacetic acid derivatives of formula (I) in which the substituents and the indices have the following meanings: X denotes NOCH3, CHOCH3 and CHCH3; Y denotes oxygen or NRa; Ra denotes hydrogen or alkyl; R denotes cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m stands for 0, 1 or 2, wherein the rests R can be different if m is 2; R1 denotes hydrogen or alkyl; R2 and R3, independently of each other, denote hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino and N-hetaryl-N-alkylamino; R4 denotes one of the groups mentioned in the case of R2 or a CRd=NORe group; Rd denotes one of the groups mentioned in the case of R2; and Re denotes hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl. The invention also concerns their salts, a process for the preparation of these substances and their use.

.gamma.-AZOLYL COMPOUNDS AGENTS CONTAINING THEM FOR REGULATING PLANT GROWTH, AND THE MANUFACTURE THEREOF

ABSTRACT OF THE DISCLOSURE: A new ?-azolyl compound of the formula

Benzaldehyde oxime ethers and fungicides containing these compounds

Benzaldehyde oxime ethers of the general formula <IMAGE> in which R<1> denotes alkyl, alkenyl, alkinyl, haloalkyl, haloalkenyl, alkoxyalkyl, cycloalkyl, cycloalkyl-alkyl, cyanoalkyl, alkoxycarbonyl-alkyl, arylalkyl, heteroaryl-alkyl, aryl-alkenyl and aryloxy-alkyl, the aromatic or heteroaromatic ring optionally being substituted, R<2> and R<3> denote hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano or nitro X denotes CH or N, and fungicides containing these compounds.

Fungicidal mixtures

PCT No. PCT/EP96/03358 Sec. 371 Date Jan. 20, 1998 Sec. 102(e) Date Jan. 20, 1998 PCT Filed Jul. 31, 1996 PCT Pub. No. WO97/06678 PCT Pub. Date Feb. 27, 1997Fungicidal mixture, comprising a) an oxime ether carboxamide of the formula I where R is hydrogen or halogen and b) an azole derivative II selected from the group of the compounds II.1 to II.17 1-[(2RS,4RS;2RS,4SR)-4-bromo-2-(2,4-dichlorophenyl)-tetrahydrofuryl]-1H-1,2,4-triazole (II.1) 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (II.2) (+/-)-4-chloro-4-[4-methyl-2-(1H-1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-2-yl]phenyl 4-chlorophenyl ether (II.3) (E)-(R,S)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol (II.4) (Z)-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(4-fluorophenyl)-3-(2-chlorophenyl)oxirane (II.5) 4-(4-chlorophenyl)-2-phenyl-2-(1H-1,2,4-triazolylmethyl)butyronitrile (II.6) 3-(2,4-dichlorophenyl)-6-fluoro-2-(1H-1,2,4-triazol-1-yl) quinazolin-4(3H)-one (II.7) bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-yl-methyl)silane (II.8) (R,S)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol (II.9) (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimenthyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol [sic] (II.10) N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide (II.11) (+/-)-1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole (II.12) (R,S)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol (II.13) (+/-)-2-(2,4-dichlorophenyl)-3-(1H-1,2,4-triazolyl)-propyl 1,1,2,2-tetrafluoroethyl ether (II.14) and (E)-1-[1-[[4-chloro-2-(trifluoromethyl)phenyl]imino]-2-propoxyethyl]-1H-imidazole (II.15) (RS)-2,4'-difluoro- alpha -(1H-1,2,4-triazol-1-ylmethyl)-benzhydryl alcohol (II.16) 2-p-chlorophenyl-2-(1H-1,2,4-triazol-1-ylmethyl)-hexanenitrile (II.17) in a synergistically active amount.

Use of strobilurin type compounds for combating phytopathogenic fungi resistant to Qo inhibitors

The present invention relates to the use of strobilurine type compounds of formula I and the N-oxides and the salts thereof for combating phytopathogenic fungi containing a mutation in the mitochondrial cytochrome b gene conferring resistance to Qo inhibitors, and to methods for combating such fungi. The invention also relates to novel compounds, processes for preparing these compounds, to compositions comprising at least one such compound, to plant health applications, and to seeds coated with at least one such compound.

Preparation of .alpha.-methoxyiminocarboxylic acid methylamides and intermediates therfore

The invention concerns a method of preparing .alpha.-methoxyiminocarboxylic acid methylamides of formula (I)(X = nitro, trifluoromethyl, halogen, alkyl or alkoxy; n = 0, 1, 2, 3 or 4; Y = an organic carbon group) by the Pinner reaction of cyanoketone of formula (II) with an alcohol, followed by reaction of the ester of formula (IV) formed in the Pinner reaction with hydroxylamine to give an oxime of formula (V), methylation of (V) to give an oxime ether of formula (VI) and subsequent reaction of (VI) with methylamine. The invention also concerns the intermediates used in the method.

Fungicidal mixtures

The invention relates to a fungicidal mixture characterized in that it contains in synergistically effective quantities a) a phenyl-benzylether derivative of the formula (I.a), (I.b) or (I.c), and/or a carbamate of the formula (Id), in which X is CH and N, n is 0, 1 or 2 and R is a halogen, C1-C4-alkyl and C1-C4- halogen alkyl, whereby the R radicals can be different if n equals 2, or one of its salts or adducts; and b) an N-acetonyl-benzamide of the formula (II) in which the substituents have the following meaning: R1 and R3 independently of each other are a halogen or C1-C4-alkyl; R2 is a cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy; R4 is a hydrogen or C1-C4-alkyl; R5 is a C2-C4-alkyl; and R6 is a thiocyano, isothiocyano or halogen or one of its salts or adducts.

Preparation of -methoxyiminocarboxylic acid methylamides by pinner reaction of -ketonitriles, oxime formation and methylation

Fungicidal mixture

The invention relates to a fungicidal mixture, containing a synergistically effective amount of a) a phenyl-benzyl ether derivative of formula (I.a) or (I.b) and b) (~)-(2-chlorophenyl)(4-chlorophenyl)(pyrimidin-5-yl) methanol (II).

Method for controlling parasitic fungi in cultivated plants

The invention relates to a method for controlling parasitic fungi in cultivated plants with modified pathogenic resistance against certain parasitic fungi, wherein the cultivated plants are treated with an active substance from the strobilurin class.

Unsaturated cyclohexylacetic acid derivatives, and crop-protection agents containing same

O.Z. 0050/41358 ABSTRACT OF THE DISCLOSURE: Unsaturated cyclohexylacetic acid derivatives of the formula I I where U is =NOCH3, =CHOCH3, =CH2, =CH-CH3, =CH-CH2-CH3, =N-NH-CH3 or =CH-S-CH3, n is from 0 to 10, A is hydrogen or substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl, and X is a single bond when n is O, and oxygen, sulfur or a single bond when n is not O, and the plant-compatible acid addition products and base addition products thereof, and fungicides and insecticides containing these compounds.

Bisoximether derivatives, intermediate products, and their use for combating fungicidal pests and animal pests

The invention relates to bisoximether derivatives of formula (I) in which th e variables have the following meanings: R1 represents halogen, C1-C4 alkyl, C 1- C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; n is 1 to 5, whereby t he radicals R1 can be different if n is not equal to 1; R2 represents C1-C4 alkyl, C3-C6 alkenyl or C3-C6 alkynyl, whereby these groups can be partially or completely halogenated; Q represents C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3 or C(=NOCH3)-CONHCH3. The invention also relates to the sal ts of the bisoximether derivatives, to methods and intermediate products for th e production of these compounds and to their use for combating animal pests an d fungicidal pests.

Benzyl derivatives and pesticides containing them

Benzyl derivatives of the formula I <IMAGE> I where A is CH2, CHCl, CH-alkyl, CH-alkoxy, CH-alkylthio or N-alkoxy, B is OH, alkylthio, alkoxy or alkylamino, U, V, W are hydrogen, halogen, alkyl or alkoxy, D is <IMAGE> <IMAGE> <IMAGE> where R' is hydrogen or alkyl and R is hydrogen, alkyl, cycloalkyl, haloalkyl, halocycloalkyl, cycloalkylalkyl, alkoxyalkyl, alkylthioalkyl, arylthioalkyl, aryloxyalkyl, aryl, arylalkyl, hetaryl, hetaryl-alkyl, hetaryloxyalkyl or heterocyclyl, and fungicides containing these compounds.

FUNGICIDE BLENDS.

Mezcla fungicida que contiene a) un derivado éter fenil-bencílico de las fórmulas I.a, I.b o I.c. y/o un carbamato de la fórmula Id. en la que X signica CH y H, n representa 0, 1 ó 2 y H significa halógeno, alquilo C1-C4 y halogenoalquilo C1-C4, donde los restos R pueden ser diferentes cuando n representa 2, una de sus sales o aductos, así como b) una N-acetonil-benzamida de la fórmula II en la que los sustituyentes tienen el signicado siguiente: R 1 , R 3 independientes entre sí, halógeno o alquilo C1-C4; R 2 ciano, alquilo C1-C4, alquenilo C2-C4, alquinilo C2-C4 o alcoxiC1-C4; R 4 hidrógeno o alquilo C1-C4; R 5 alquilo C1-C4; R 6 tiociano, isotiociano o halógeno, o una de sus sales o aductos. Fungicidal mixture containing a) a phenyl benzyl ether derivative of the formulas I.a, I.b or I.c. and / or a carbamate of the formula Id in which X means CH and H, n represents 0, 1 or 2 and H means halogen, C1-C4 alkyl and halogenoalkyl C1-C4, where the R moieties may be different when n represents 2, one of its salts or adducts, as well as b) an N-acetonyl-benzamide of the formula II in which the substituents have the following meaning: R 1, R 3 independent from each other, halogen or C1-C4 alkyl; R 2 cyano, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl or C 1 -C 4 alkoxy; R 4 hydrogen or C1-C4 alkyl; R 5 C1-C4 alkyl; R 6 thiocyan, isothiocyan or halogen, or one of its salts or adducts.

Derivatives of phenyloacetic acid, method of and intermediate products for obtaining them and agents containing such derivatives

Fungicidal mixtures of an oximether carboxylic acid amide with anilinopyrimidines

A fungicidal mixture contains synergistically effective amounts of (a) an oximether carboxylic acid amide having the formula (I), in which R stands for hydrogen or halogen; and (b) a pyrimidine derivative having the formula (II), in which R stands for methyl, propin-1-yl or cyclopropyl.

Fungicidal mixtures

A fungicidal mixture containing a) the oxime ether carboxamide of the formula I (see formula I) and b) an azole derivative II selected from the group of compounds II.1. to II.16 - 1-[(2RS,4RS;2R5,4SR)-4-bromo-2-(2,4-dichlorophenyl)tetra- hydrofuryl]-1H-1,2,4-triazole (II.1) - 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-tri- azol-1-yl)butan-2-ol (II.2) - (~)-4-chloro-4-[4-methyl-2-(1H-1,2,4-triazol-1-yl- methyl)-1,3-dioxolan-2-yl]phenyl 4-chlorophenyl ether (II.3) - (E)-(R,S)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1H- 1,2,4-triazol-1-yl)pent-1-en-3-ol (II.4) - (Z)-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(4-fluorophenyl)-3- (2-chlorophenyl)oxirane (II.5) - 4-(4-chlorophenyl)-2-phenyl-2-(1H-1,2,4-triazolyl methyl)butyronitrile (II.6) - 3-(2,4-dichlorophenyl)-6-fluoro-2-(1H-1,2,4-tri- azol-1-y1)quinazolin-4(3H)-one (II.7) - bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-yl- methyl)silane (II.8) - (R,S)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)- hexan-2-of (II.9) - (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimethyl-1-(1H- 1,2,4-triazol-1-ylmethyl)cyclopentanol (II.10) - N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]- imidazole-1-carboxamide (II.11) - (~)-1-(2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxo- lan-2-ylmethyl]-1H-1,2,4-triazole (II.12) - (R,S)-1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-tri- azol-1-ylmethyl)pentan-3-ol (II.13) - (~)-2-(2,4-dichlorophenyl)-3-(1H-1,2,4-triazol-1-yl) propyl 1,1,2,2-tetrafluoroethyl ether (II.14) - (E)-1-[1-[[4-chloro-2-(trifluoromethyl)phenyl]imino]-2- propoxyethyl]-1H-imidazole (II.15) and - (RS)-2,4'-difluoro-.alpha.-(1H-1,2,4-triazol-1-yl- methyl)benzhydryl alcohol (II.16) in a synergistically active amount is described.

7-amino triazolopyrimidines for controlling harmful fungi

The invention relates to 7-amino triazolopyrimidines of formula (I), in which the substituents have the following meanings: Rl, R2 represent hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, phenyl, naphthyl; or 5-membered or 6-membered heterocyclyl containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; or 5-membered or 6-membered heteroaryl containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom, or R1 and R2 can, together with the nitrogen atom, which binds them, form a 5-membered or 6-membered ring containing one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; R3 represents alkyl, alkenyl, alkynyl, cycloalkyl, phenylalkyl and alkyl halide; whereby R3 and R2 can be unsubstituted or partially or completely substituted according to the description; X represents halogen, cyano, alkoxy, alkyl halide, phenyl or phenyl that is substituted by Ra. The invention also relates to methods and intermediate products for producing said compounds, to agents containing the same, and to their use.

Device for placing needle caps on medical syringes

Die Vorrichtung dient zum Aufsetzen von Nadelschutzkappen (1) auf medizinische Spritzen (2), insbesondere auf Spritzen (2) mit eingeklebter Kanüle (5). Sie besteht aus einem Halteelement (3) für eine oder mehrere Spritzen (2) sowie einem Zuführelement (4) für die Nadelschutzkappen (1), wobei das Halteelement (3) und das Zuführelement (4) zum Aufsetzen der Nadelschutzkappen (1) gegeneinander verstellbar sind. Das Zuführelement (4) weist für jede Nadelschutzkappe (1) eine Führungshülse (7) auf, deren Durchmesser größer als der maximale Außendurchmesser der Nadelschutzkappe (1) ist. In die Führungshülse (7) mündet wenigstens eine Druckluftzuführung (8), über die Luft in den zwischen der Wand der Führungshülse (7) und der Mantelfläche der Nadelschutzkappe (1) gebildeten Ringraum (9) eingeblasen werden kann. Zwischen dem Halteelement (3) und der nach unten offenen Führungshülse (7) ist eine Verschlußeinrichtung (10) angeordnet, die sich zum Aufsetzen der Nadelschutzkappe (1) öffnen läßt. The device is used to place needle protection caps (1) on medical syringes (2), in particular on syringes (2) with glued-in cannula (5). It consists of a holding element (3) for one or more syringes (2) and a feed element (4) for the needle protection caps (1), the holding element (3) and the feed element (4) being adjustable against each other for fitting the needle protection caps (1) are. The feed element (4) has a guide sleeve (7) for each needle protection cap (1), the diameter of which is larger than the maximum outer diameter of the needle protection cap (1). At least one compressed air supply (8) opens into the guide sleeve (7), via which air can be blown into the annular space (9) formed between the wall of the guide sleeve (7) and the outer surface of the needle protection cap (1). A closure device (10) is arranged between the holding element (3) and the guide sleeve (7) which is open at the bottom and which can be opened to put on the needle protection cap (1).

Carbamates and crop protection agents containing them

2127110 9315046 PCTABScor01 Carbamate having the formula (I), its plant-compatible acid addition and basic addition products, and fungicides containing the same are disclosed.

Oxirane phenyl esters and fungicides containing these

O.Z. 0050/40709 ABSTRACT OF THE DISCLOSURE: Esters of the general formula I

Aniline derivatives and fungicides containing them

O.Z. 0050/41142 ABSTRACT OF THE DISCLOSURE: Aniline derivatives of the formula where R is hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, alkenyl, alkoxy, haloalkyl, haloalkoxy, or substituted or unsubstituted phenyl, phenoxy, benzyl or benzyloxy, m is an integer from 1 to 5 or the group

N-methylamides, their preparation and intermediates therefor and control of pests therewith

N-Methylamides, their preparation and intermediates therefor and control of pests therewith ABSTRACT OF THE DISCLOSURE: N-Methylamides of the formula I, where R is C1-C?-alkyl or cyclopropyl, A is hydrogen, halogen, cyano, nitro, alkyl, cycloalkyl, OR1, cycloalkyloxy, haloalkyl, haloalkyloxy, alkenyl, al-kenyloxy, alkynyl, alkoxyalkyl, cyanoalkyl, nitroalkyl, phenyl, phenoxy, C(O)R1, CO2R1, C(O)NR1R2, C(S)NR1R2, NR1R2, NR1C(O)R2, NR1CO2R2, OC(O)R1, SR1, S(O)R1, S(O)2R1, -C(R1)=NR2, -N=CR1R2,

Azolyl methyl allyl alcohols, and fungicides containing them

Azolyl methylallyl alcohols of the general formula I <IMAGE> in which R1 and R2 represent alkyl, naphthyl, biphenyl, cycloalkyl, cycloalkenyl or phenyl, these radicals optionally being substituted, X represents CH or N, and their phytophysiologically acceptable acid addition salts and metal complexes, and fungicides containing these compounds.

Fungicidal mixtures

Fungicidal mixtures Abstract A fungicidal mixture containing a) the oxime ether carboxamide of the formula I

Novel azole compounds,their preparation,their use for crop treatment,and agents for this purpose

Iminooxyphenylacetic acid derivatives, their preparation, intermediates for their preparation, and their use

The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R1 is C(CO2CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R2 is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R3 is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R4 is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R5)=N-Y1-R6 or -Q-O-N=CR7R8; R3 and R4 together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C1-C4-alkyl)groups; wherein R3 and R4 are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.

Fungicidal composition

A fungicidal composition of~~~ a) methyl .alpha.-methoximino-2-[(2-methylphenoxy)-methyl]-phenylacetate (see formula I) and b) 4-(2-methyl-3-[4-tert-butylphenyl]-propyl)-2,6-dimethylmorpholine (fenpropimorph) (see formula II) or the active ingredient tridemorph or the active ingredient fen-propidin, and methods of combating fungi with this composition.

2 - [(Dihydro) pyrazolyl-3'-oxylmethylene] anilides, their use, and an agent containing the compound and intermediates for the preparation of the compound

Cyanimino oxime ethers, processes and intermediates for their preparation and their use in combating harmful fungi and animal pests

The invention relates to cyanimino oxime ethers of formula (I), in which X is NOCH3, CHOCH3, CHCH3; Y is O, NZ, where Z is H, alkyl; R<1> is H, alkyl; R<2> is cyano, nitro, trifluoromethyl, halogen, alkyl, alcoxy; m is 0, 1, 2, the radicals R<2> possibly being different when m is 2; R<3> is H, cyano, alkyl, alkylhalide, alkoxy or cycloalkyl; R<4> is H, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl. The invention also relates to salts of said ethers, and the process and intermediates for the preparation and use thereof for the control of noxious fungi and animal pests.

Azole compounds, their preparation, and fungicides which contain these compounds

O.Z, 0050/35247 Abstract of the Disclosure: Azole compounds of the formula I I where X is hydrogen, halogen or trifluoromethyl, m is an integer from 1 to 5, Z is N or CH, R1 is C2-C4-alkenyl or C2-C4-alkynyl, and R2 is hydrogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alXynyl or C2-C4-alkanoyl, and their crop-tolerated addition salts with acids, and metal complexes, as well as fungicides which contain these compounds.

N-methylamides, their preparation and intermediates therefor and control of pests therewith

Agent for the abscission of plant parts

The agents contain at least one urea derivative of the formula I <IMAGE> in which the substituents and the index have the following meaning: <IMAGE> B denotes cyclopentyl, cyclohexyl, phenyl or phenyl substituted by one, two or three chlorine, bromine or fluorine atoms, where R denotes hydrogen or methyl, R<1> denotes fluorine, chlorine or bromine and n denotes the integers 1, 2 or 3, and either a) an oxyethylated tallow fatty amine of the formula II <IMAGE> in which the substituent and the indices have the following meaning: R<2> denotes C16-C18-n- or iso-alkyl and x and y together denote an integer between 8 and 20, or b) a fatty alcohol of the formula III <IMAGE> in which the substituent and the indices have the following meaning: R<3> denotes C10-C18-n-alkyl, w denotes the integers from 3 to 7 and z denotes the integers from 0 to 7, where the weight ratio of urea derivative I and oxyethylated tallow fatty amine II or fatty alcohol III is between 0.01:1 and 10:1.

Substituted oxime ethers, their preparation and their use for controlling pests and fungi

Substituted oxime ethers, their preparation and their use for controlling pests and fungi ABSTRACT OF THE DISCLOSURE: Substituted oxime ethers of the general formula I I where R1 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxyalkyl, cy-cloalkyl, cycloalkylalkyl, cyanoalkyl, alkoxycarbonylalkyl, aryl-alkyl, heteroarylalkyl, arylalkenyl or aryloxyalkyl, the aromatic or heteroaromatic ring being substituted or unsubstituted, R2 and R3 are hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano or nitro, R4 is hydrogen, alkyl, cycloalkyl, haloalkyl or aryl, the aromatic ring being substituted or unsubstituted, and R5 and R6 are identical or different and each is hydrogen or alkyl, and X is CH or N, and fungicides and pesticides containing these com-pounds.

Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them

Phenyl acetic acid derivatives of formula (I) in which the components and index have the following meanings: X is NOCH3, CHOCH3 CHCH3 and CHCH2CH3; R1 is hydrogen and alkyl; R2 is cyano, nitro, trifluoro methyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, in which the radicals R2 may be different if m is 2; R3 is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R4 is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, possibly substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, Ncycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R5 is hydrogen, possibly substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkyl carbonyl, alkenyl carbonyl, alkinyl carbonyl or alkyl sulphonyl; possibly substituted aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl; and their salts, process and intermediate products for their production and their use.

Preparation of e-oxime ethers of phenylglyoxylic esters

E-oxime ethers of phenyl-glyoxylic esters of the formula I (see formula I) where X and Y are each halogen, C1-C4-alkyl, C1-C4-alkoxy or trifluoromethyl; m is an integer from 0 to 4; n is an integer from 0 to 3; are prepared by a) converting a phenol of the formula II (see formula II) into the phenolate b) mixing this phenolate with a lactone of the formula III (see formula III) c) reacting the mixture in the melt, and d) converting the resulting 2-phenoxymethylbenzoic acid of the formula IV (see formula IV) e) into the corresponding 2-phenoxymethylbenzoyl chloride of the formula V (see formula V) and f) reacting the 2-phenoxymethylbenzoyl chloride V with a cyanide, and g) reacting the resulting 2-phenoxymethylbenzoyl cyanide of the formula VI (see formula VI) with methanol, h) if required cleaving the keto carboxylic ester dimethyl acetal byproduct of the formula VIIb (see formula VIIb) and, if required, subjecting the .alpha.-veto carboxamide byproduct of the formula VIIc (see formula VIIc) to step (g) again or i) reacting an o-phenoxymethylbenzoic ester of the formula Va (see formula Va) where R is alkyl, with dimethyl sulfoxide, mixing the resulting .beta.-keto sulfoxide of the formula VIa (see formula VIa) with a halogenating agent and reacting this mixture with methanol k) and reacting the resulting methyl 2-phenoxymethyl-glyoxylate of the formula VIIa (see formula VIIa) or an acetal of the formula VIIb (see formula VIIb) or a mixture of compounds VIIa and VIIb with O-methylhydroxylamine and treating with an acid.

Azolylmethylcycloalkyloxiranes and their use as crop protection agents

Azolylmethyloxiranes of the general formula I <IMAGE> I where A and B are cycloalkyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl, norbornyl, cycloalkenyl or phenyl, each of these radicals being unsubstituted or substituted, with the proviso that A and Z are not simultaneously phenyl, D is O, X is CH or N, and their plant-tolerated acid addition salts or metal complexes, and fungicides containing these compounds.

Pyrazolyl derivatives, their preparation and their use as pesticides

DERIVATIVES OF 1-HYDROXY-1,2,4-TRIAZOL AND ITS FUNGICIDES CONTAINING THEM AND GROWTH REGULATING AGENTS

Imidazolylmethyloxiranes and imidazolylpropenes; processes for preparation and combating fungi and fungicidal compositions

Method for combating harmful fungi

New fungicidal cpds.

Thiolcarboxylic acid ester derivs. of formula (I) are new; X = O, S, oxymethylene, methyleneoxy, thiomethylene, methylenethio, ethylene, ethenylene or ethynylene; Y and Z = S or O, provided that they are not both O; R = 1-6C alkyl, mono- di- or tri-nuclear aryl or heteroaryl, these aryl and heteroaryl gps. opt. substd. by R1; R1 = halogen, CN, NO2, 1-6C alkyl, 3-6C cycloalkyl, 1-6C alkoxy, trifluoromethyl, mono or dinuclear aryloxy or mono, di or trinuclear aryl, these aryloxy and aryl gps. being themselves opt. susbtd. by R1.

Substituted imidazolylmethyloxiranes and substituted imidazolylpropenes, their preparation and fungicides containing them

Substituierte Imidazolylmethyloxirane und substituierte Imidazolylpropene der allgemeinen Formel in welcher R¹ und R² Alkyl, Cycloalkyl, Cycloalkenyl, Tetrahydropyranyl, Norbornyl, Pyridyl, Naphthyl, Biphenyl oder Phenyl bedeuten, D den Rest 0 oder eine Einfachbindung bedeutet, E den Rest H, F, Cl oder Br bedeutet, X, Y und Z Wasserstoff, Halogen, Nitro, Cyano, Alkyl, Halogenalkyl, Alk­ oxy, Amino, gegebenenfalls durch substituiertes Amino, Mercapto, gegebe­ nenfalls substituiertes Mercapto, Acyl, Alkoxycarbonyl, Hydroxyalkyl und gegebenenfalls substituiertes Phenyl bedeuten, sowie deren für Pflanzen verträgliche Säureadditionssalze und Metall­ komplexe, Verfahren zu ihrer Herstellung und sie enthaltende Fungizide. Substituted imidazolylmethyloxiranes and substituted imidazolylpropenes of the general formula in which R¹ and R² are alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, D represents the radical 0 or a single bond, E represents the remainder H, F, Cl or Br, X, Y and Z are hydrogen, halogen, nitro, cyano, alkyl, haloalkyl, alk oxy, amino, optionally substituted by amino, mercapto, optionally substituted mercapto, acyl, alkoxycarbonyl, hydroxyalkyl and optionally substituted phenyl, as well as their acid addition salts and metal complexes which are compatible with plants, processes for their preparation and fungicides containing them.

Defoliating agent containing thiadiazolyl urea

Harmful fungi control with an active substance inhibiting respiration by inhibiting the cytochrome complex III, combined with an amide

Fungicidal mixtures

Process for the preparation of 4-alkanoylaryl-benzylethers.

Oximethers and fungicides containing them.

Fungicidal mixtures

The invention relates to fungicidal mixtures containing a synergistically effective quantity of at least one compound selected from the following: a) carbamates of formula (I) wherein T means CH or N, n represents 0, 1 or 2 and R means halogen, C1-C4 alkyl or C1-C4 alkyl halide, and the radicals R can be different if n represents 2; a2) the oximethercarboxylic acid ester of formula (II) or a3) the oximethercarboxylic acid amide of formula (III); and b) a compound of formula (IV) wherein the substituents R1 to R3 have the following meaning: R1 is C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkinyl, C1-C4-alkyl-C3-C7-cycloalkyl and these radicals may carry substituents chosen from the following: halogen, cyano and C1-C4 alkoxy, R2 is C1-C4 alkyl or C1-C4 alkyl halide; R3 is hydrogen, halogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, N--C1-C4-alkylamino, C1-C4 alkyl halide or C1-C4 halogenalkoxy; Y is O, S, CHR4 or NR5, R4 and R5 having the meanings given for R2 and n has the value 0, 1, 2 or 3. The invention also relates to methods for combating harmful fungi using these mixtures.

Oxime ethers, and fungicides containing same

O.Z. 0050/40854 ABSTRACT OF THE DISCLOSURE: Oxime ethers of the formula

Alpha-phenyl-acrylic acid derivatives, process for their preparation and their use as parasiticides and fungicides

Azole compounds, their preparation, their use for crop treatment, and agents for this purpose

Azole compounds of the formula ##STR1## where X is hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, trifluoromethyl or phenyl and m is an integer from 1 to 5, and, if m is greater than 1, the X's can be identical or different, n is an integer from 2 to 5, Z is N or CH and Y is CO or CR 1 OR 2 , where R 1 is hydrogen or C 1 -C 4 -alkyl and R 2 is hydrogen, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl or C 1 -C 4 -alkanoyl, and their crop-tolerated addition salts with acids, and metal complexes. The compounds act as fungicides and growth regulators.

Preparation of essentially isomerically pure methyl e-2-(2-aryloxymethylene-phenyl) crotonates, and intermediates therefor

A process for preparing substantially isomer-pure E-2-(2-aryloxymethylene phenyl)-crotonic acid methyl esters having formula (Ia), in which R stands for an aromatic residue substitued by the usual groups and R' stands for a C1-C3 alkyl group, is characterised in that a corresponding 2-(2-aryloxymethylene phenyl)-.alpha.-keto-acetic acid methyl ester having formula (II) with an alkyl metal compound having formula (III), in which M stands for a metal ion equivalent, first yields the corresponding 2-(2-aryloxymethylene phenyl).alpha.-hydroxybutyric acid methyl ester having formula (IV), which is then dehydrated in the presence of an acid into a mixture of E- et Z-2-(2-aryloxymethylene phenyl)-crotonic acid methyl esters having formulas (Ia) and (Ib). This mixture is finally converted into the substantially isomer-pure E-2- (2-aryloxymethylene phenyl)-crotonic acid methyl ester (Ia) in the presence of a base in an inert polar solvent.

Pyrazoyly derivatives and their use

Pyrazolyl derivatives of the general formula I ##STR1## where the indices and the substituents have the following meanings: n is is 0, 1, 2, 3 or 4, it being possible for the radicals R 1 to be different if n is greater than 1; m is 0, 1 or 2, it being possible for the radicals R 3 to be different if m is greater than 1; R 1 is nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, unsubstituted or substituted phenyl or phenoxy; R 2 is hydrogen, unsubstituted or substituted alkyl, alkenyl or alkynyl, an unsubstituted or substituted, saturated or mono- or diunsaturated ring, an unsubstituted or substituted, mono- or binuclear aromatic radical; R 3 is nitro, cyano, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R 4 is hydrogen, cyano, halogen, alkyl or haloalkyl, processes for their preparation and their use are described.

Fungicide mixtures based on triple oxime ether derivatives and insecticides

The invention relates to a) phenylacetic acid derivatives of formula (I) in which the substituents and the index have the meanings cited in the description, and to the salts thereof, and to b) at least one compound of formulas (II) to (XI) in a synergistically effective quantity.

PROCESS FOR THE COMBAT OF PATOGENIC FUNGI IN CULTURAL PLANTS

Substituted 4,5-dimethoxypyridazones, process for their preparation, herbicides containing them and their use in combating the growth of undesirable plants

Die Erfindung betrifft 4,5-Dimethoxypyridazone der Formel <IMAGE> in der X und Y Sauerstoff, Schwefel, eine Sulfinylgruppe oder eine Sulfogruppe, R¹ und R² Wasserstoff oder Alkyl, Z¹, Z² und Z³ Wasserstoff,Halogen,Nitro, Cyano, Alkyl, Halogenalkyl, Alkoxy, Halogenalkoxy, Alkylmercapto, Halogenalkylmercapto, Alkylsulfinyl oder Alkylsulfonyl bedeuten und n und p für die zahlen 0 oder 1, m und q für eine Zahl von 0 bis 8 stehen, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung unerwünschten Pflanzenwuchses. The invention relates to 4,5-dimethoxypyridazones of the formula <IMAGE> in which X and Y are oxygen, sulfur, a sulfinyl group or a sulfo group, R¹ and R² are hydrogen or alkyl, Z¹, Z² and Z³ are hydrogen, halogen, nitro, cyano, alkyl, Haloalkyl, alkoxy, haloalkoxy, alkylmercapto, haloalkylmercapto, alkylsulfinyl or alkylsulfonyl and n and p represent the numbers 0 or 1, m and q represent a number from 0 to 8, processes for their preparation and their use for controlling unwanted vegetation.

2-(o-[pyrimidin-4-yl]methylene oxy)phenyl acetic acid derivatives and their use in combatting noxious fungi and animal pests

2-(O-¢pyrimidin-4-yl! methylene oxy)phenyl acetic acid derivatives of general formula (I) and their salts and N oxides, in which R1 is halogen, alkyl or alkyl halide; R2 is hydrogen, amino, hydroxy, mercapto, halogen, possibly phenyl-substituted alkyl, alkyl halide, alkoxy alkyl, alkoxy, monoalkyl amino, dialkyl amino, alkylthio, alkyl sulphoxyl, alkylsulphonyl, cycloalkyl, trialkyl silyloxy or phenyl, phenoxy, phenoxy methyl, benzyloxy or heteroaryl possibly substituted in the aromatic ring, R2 being different from R1; R3 is hydrogen, cyano, halogen, C1-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy, and Q is C(=CHCH3)-COOCH3 or C(=CHOCH3)-COOCH3, and their use in combatting noxious fungi and animal pests.

Acetylenic derivatives and plant-protective agents containing them

O-benzyl oxime ether and crop protection agents containing these compounds

Preparation of O-iminooxymethylbenzoic acid