19-11-2020 дата публикации
Номер: US20200362181A1
Автор:
Jeffrey Hendricks,
Kyle Mallires,
Sarah Richardson-Burns,
HENDRICKS JEFFREY,
MALLIRES KYLE,
RICHARDSON-BURNS SARAH,
Hendricks, Jeffrey,
Mallires, Kyle,
Richardson-Burns, Sarah
Принадлежит:
The present invention generally relates to compositions and methods for the preparation of conductive polymer coatings, and methods for application of the coatings to three-dimensional substrates. 1. An electrically conductive polymeric coating on a substrate , wherein the electrically conductive coating is derived from a coating precursor composition comprising:a conductive polymer component comprising poly(3,4-ethylenedioxythiophene) and a primary counterion comprising repeat units, wherein one or more of the repeat units have a negatively charged functional group;a secondary doping agent;a crosslinking agent selected from the group consisting of 3-(trimethoxysilyl)propyl methacrylate, 3-(trimethoxysilyl)propyl acrylate, vinyltrimethoxysilane, allyltrimethoxysilane, tetrakis(trimethylsilyloxy)silane, poly(ethylene glycol) divinyl ether, and a branched trialkyloxy silane;a surfactant component; anda flexibility enhancer comprising poly(acrylamide-co-acrylic acid), polyvinylpyrrolidone, polyvinyl alcohol, polyethylene glycol, polyethylene oxide, or a combination thereof.2. The coating of wherein the electrical resistance of the coating increases by no greater than 50% after 600 flexing cycles when the coating is applied to a substrate having an outer diameter of 0.25 inches and each cycle comprises flexing the coated substrate about a bend radius of 1.25 inches.3. The coating of further comprising a conductive filler comprising metal particles claim 1 , carbon black claim 1 , carbon fiber claim 1 , graphite claim 1 , graphene claim 1 , carbon nanotubes claim 1 , carbon fiber silicon claim 1 , silicon particles claim 1 , or a combination thereof claim 1 , wherein the conductive filler is present in the electrically conductive polymeric coating in an amount sufficient to reduce the contact resistance of the polymeric coating claim 1 , and wherein the conductive filler is present in the coating precursor composition in a concentration of no more than about 25% of the ...
Подробнее