04-04-2019 дата публикации
Номер: US20190099744A1
Принадлежит:
This invention relates to a novel nickel catalyst and a novel one-pot solution combustion synthesis of that catalyst for the COreforming and low temperature steam reformation of methane. The novel nickel catalyst has exceptional activity for dry reforming and steam reforming of methane, and exhibits excellent resilience to deactivation due to carbon formation. 1. A catalyst composition comprising:a nickel species, andalumina, the catalyst is in form of nanoparticulate,', {'sub': 2', '4, 'claim-text': {'sub': 2', '4, 'wherein NiAlOis the main form of the nickel species;'}, 'the nickel species comprises NiAlOwith Ni, NiO, or combination of Ni and NiO;'}, 'the nickel species is dispersed on the surface and in the bulk of the alumina, wherein the nickel species has a higher concentration on the surface of the alumina than in the bulk of the alumina., 'wherein'}2. The catalyst composition of claim 1 , wherein the catalyst has a BET surface area of at least 88 m/g.3. The catalyst composition of claim 1 , wherein the catalyst has a BET surface of at least 70 claim 1 , 80 claim 1 , 90 claim 1 , 100 claim 1 , 110 claim 1 , 120 claim 1 , 130 claim 1 , 140 claim 1 , 150 claim 1 , 160 claim 1 , 170 claim 1 , 180 claim 1 , or 190 m/g.4. The catalyst composition of claim 1 , wherein the catalyst has a BET surface in the range of 70 m/g to 200 m/g.5. The catalyst composition of claim 1 , wherein the nickel specie is present in the catalyst at about 5 to about 10 wt %.6. The catalyst composition of claim 1 , wherein the nickel species is present in the catalyst at about 5 wt % claim 1 , about 6 wt % claim 1 , about 7 wt % claim 1 , about 8 wt % claim 1 , about 9 wt % claim 1 , or about 10 wt %.7. The catalyst composition of claim 1 , wherein the nickel specie is present on the surface of the alumina at 7.75-13.52 wt %.8. The catalyst composition of claim 1 , wherein the nickel specie is present on the surface of the alumina at about 6 wt % to about 15 wt %.9. The catalyst ...
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