03-02-2022 дата публикации
Номер: US20220034828A1
Принадлежит:
In a first step, a sample formed of a polyester or decomposition products of a polyester is dissolved in a pretreatment liquid containing a secondary amine to obtain a reaction product (amide) of the sample. In a second step, the obtained reaction product, amide, is mixed into a solvent containing deuterated chloroform and deuterated 1,1,1,3,3,3-hexafluoro-2-propanol to fabricate a sample liquid. In a third step, the amount of the amide in the sample liquid is measured through a nuclear magnetic resonance spectroscopy aiming at hydrogen atoms to determine the amount of acid anhydride in the sample. 16-. (canceled)7. A method for measuring an acid anhydride content , the method comprising:a first step of dissolving a sample formed of a polyester or decomposition products of a polyester in a pretreatment liquid containing a secondary amine to obtain a reaction product of the sample;a second step of mixing the reaction product into a solvent containing deuterated chloroform and deuterated 1,1,1,3,3,3-hexafluoro-2-propanol to fabricate a sample liquid; anda third step of measuring an amount of an amide in the sample liquid through a nuclear magnetic resonance spectroscopy aiming at hydrogen atoms to determine an amount of acid anhydride in the sample.8. The method according to claim 7 , wherein two substituents of the secondary amine each comprise an aliphatic hydrocarbon.9. The method according to claim 8 , wherein the two substituents of the secondary amine each comprise the same aliphatic hydrocarbon.10. The method according to claim 9 , wherein the pretreatment liquid further contains chloroform in addition to the secondary amine.11. The method according to claim 10 , wherein a mixing ratio of the chloroform to the secondary amine in the pretreatment liquid is set to 3 or less in a volume ratio.12. The method according to claim ii claim 10 , wherein claim 10 , in the first step claim 10 , the sample is dissolved in the pretreatment liquid to obtain the reaction ...
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