Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Polythioether polymers, methods for preparation thereof, and compositions comprising them

Dislcosed are poilythioethers that are the reaction product of reactants that include: a) an isocyanurate-containing trithiol; b) a polythiol different from (a); and c) a diene. Also disclosed are compositions, such as sealant compositions, that include such polythioethers.

UV-Curable Coating Compositions, Multi-Component Composite Coatings, and Related Coated Substrates

Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate. 1. A solventborne liquid UV-curable coating composition comprising: (i) an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and', '(ii) an active hydrogen-containing acrylate., 'an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising2. The solventborne liquid UV-curable coating composition of further comprising a photoinitiator composition comprising: (a) a first photoinitiator having a peak absorbance with a wavelength range of 240 to 250 nm; and', '(b) a second photoinitiator having a peak absorbance with a wavelength range of 250 to 260 nm; and, '(i) a first photoinitiator composition comprising(ii) a second photoinitiator composition which absorbs UV light with a wavelength range of 350 to 410 nm.3. The ...

ONE COMPONENT EPOXY STRUCTURAL ADHESIVE COMPOSITION PREPARED FROM RENEWABLE RESOURCES

Curable, one-package, stable adhesive compositions are provided comprising: 1. A curable , one-package , stable adhesive composition comprising:(a) a resin component comprising a polyepoxide containing at least two epoxide groups per molecule, wherein at least a portion of the polyepoxide has been reacted with a carboxy-terminated butadiene acrylonitrile polymer;(b) a polyamine having at least two primary amine, secondary amine, and/or ketimine functional groups; and(c) a curing component comprising dicyandiamide and an accelerator; wherein the accelerator comprises a reaction product comprising a renewable polyol, a diisocyanate, and a dialkyl monoamine containing alkyl groups with at least two carbon atoms each.2. The composition of wherein the resin component (a) further comprises a reaction product comprising a polyepoxide and dimer acid.3. The composition of wherein the dimer acid is derived from a renewable fatty acid.4. The composition of wherein the resin component (a) further comprises a reaction product comprising epichlorohydrin and carboxy-terminated butadiene acrylonitrile polymer.5. The composition of wherein the resin component (a) further comprises a polyester polymer derived from a renewable source.6. The composition of wherein the polyamine (b) comprises a polyether having at least two primary amine claim 1 , secondary amine claim 1 , and/or ketimine functional groups.7. The composition of wherein at least a portion of the polyepoxide in the resin component (a) has been pre-reacted with the amine and/or ketimine functional groups in the polyamine (b).8. The composition of wherein the amine to epoxy equivalent ratio is 0.05:1 to 0.5:1.9. The composition of claim 1 , wherein the polyepoxide comprises an epoxy polyether claim 1 , a polyglycidyl ether of one or more polyhydric alcohols claim 1 , a polyglycidyl ester of one or more polycarboxylic acids claim 1 , epoxidated olefinically unsaturated alicyclic compounds claim 1 , a polyepoxide containing ...

POLYTHIOETHER POLYMERS, METHODS FOR PREPARATION THEREOF, AND COMPOSITIONS COMPRISING THEM

Disclosed are poilythioethers that are the reaction product of reactants that include: a) an isocyanurate-containing trithiol; b) a polythiol different from (a); and c) a diene. Also disclosed are compositions, such as sealant compositions, that include such polythioethers. 119-. (canceled)21. The polythioether of claim 20 , wherein Ris —[(—CH—)—O—]—(—CH—)— wherein claim 20 ,p is an integer having a value ranging from 2 to 6,q is an integer having a value ranging from 1 to 5, andr is an integer having a value ranging from 2 to 10.22. The polythioether of claim 21 , wherein p is 2 claim 21 , q is 2 claim 21 , and r is 2.23. The polythioether of claim 21 , wherein p is 2; and each of q and r is selected from 1 and 2.24. The polythioether of claim 20 , wherein Ris —(CH)—O—(CH)—O—(CH)—.25. The polythioether of claim 20 , wherein m is 1 to 4.26. The polythioether of claim 20 , wherein Ris ethylene and m is 2.27. The polythioether of claim 20 , wherein Ris n-butylene and Ris ethylene.28. The polythioether of claim 20 , wherein Y comprises a terminal thiol —SH group.29. The polythioether of claim 28 , wherein polythioether is liquid at room temperature.3013. The polythioether of claim 20 , wherein Y is —[—(CH)—O—(R O)—(CH—S—R—S—]—H.31. The polythioether of claim 20 , wherein Y is —[(—CH)—O—(—(CH)—O—)—(CH)—S—(CH)—O—S—(CH)—O—(CH)—S—]—H.32. The polythioether of claim 20 , wherein claim 20 ,{'sub': 2', '2, 'R is —(CH)—;'}{'sup': '1', 'sub': 2', '2', '2', '2', '2', '2, 'Ris —(CH)—O—(CH)—O—(CH)—; and'}{'sup': '2', 'sub': 2', '2', '2', '2', '2', '2', '2, 'Ris —(CH)—O—[—(CH)—O—]—)CH)—.'}33. The polythioether of claim 20 , wherein Y comprises a terminal hydroxyl claim 20 , alkyl claim 20 , alkylene claim 20 , isocyanate claim 20 , epoxy claim 20 , amine claim 20 , or silane group.34. The polythioether of claim 33 , wherein thiol-terminated polythioether has a Tnot higher than −55° C.35. A composition comprising:{'claim-ref': {'@idref': 'CLM-00020', 'claim 20'}, 'the polythioether ...

UV-curable coating compositions, multi-component composite coatings, and related coated substrates

Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.

Aqueous-based polymers for sound deadening applications

Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Aqueous-based polymers for sound deadening applications

Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Aqueous-based polymers for sound deadening applications

Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Highly crosslinked polymer particles and coating compositions containing the same

A latex emulsion that includes crosslinked polymeric microparticles dispersed in an aqueous continuous phase. The microparticles are prepared from a monomer mix of a crosslinking monomer, a monomer having hydrophilic functional groups, and one or more other monomers. Also disclosed is a thermosetting composition that includes a first reactant that has reactive functional groups; a curing agent that has at least two functional groups reactive with the functional groups of the first reactant; and the latex emulsion of crosslinked polymeric microparticles dispersed in an aqueous continuous phase. The thermosetting composition may be used to coat a substrate. The coating may be a multi-layer composite coating that includes a base coat layer deposited from a pigmented film-forming base coat composition containing the thermosetting composition; and a substantially pigment free top coat layer deposited over a portion of the base coat layer from a substantially pigment free top coat composition.

Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Thermosetting acrylic copolymer compositions

Thermosetting acrylic copolymer compositions useful in coating applications are disclosed. The acrylic polymer has a weight average molecular weight of about 15,000 to 100,000 and contains from about 2 to 20 percent by weight of an alkyl ester of an unsaturated carboxylic acid containing from 14 to 20 carbon atoms in the alkyl group, for example, stearyl methacrylate. The compositions are particularly useful as water-based exterior coatings for automobiles and trucks.

Acrylic modified polymers

A liquid, ungelled composition of matter composed of a graft copolymer prepared by the free radical initiated polymerization in an organic medium of a vinyl monomer component which contains at least 0.5 weight percent of an epoxy group containing vinyl monomer in the presence of an acid group containing polymer having an acid value greater than 10 mg KOH/g. One means of graft formation is the condensation reaction between the acid groups of the acid group containing polymer and the epoxy groups of the vinyl monomer component.

Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat

A color-plus-clear coating system is disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent top coat to the base coat. The transparent top coat composition is a liquid crosslinkable composition comprising a polyepoxide and a polyacid curing agent. The polyepoxide-polyacid curing agent in the transparent top coat provides a composite coating with outstanding gloss and distinctness of image making the composite coating particularly useful as an automotive top coat.

Polythioether polymers, methods for preparation thereof, and compositions comprising them

Disclosed are polythioethers that are the reaction product of reactants that include: a) an isocyanurate-containing trithiol; b) a polythiol different from (a); and c) a diene. Also disclosed are compositions, such as sealant compositions, that include such polythioethers.

Cationic latices useful for thermoplastic and thermosetting applications

Abstract of the Disclosure A process for preparing stable latices with cationic surfactant having their gegen-ions derived from methanesulfonic acid; the cationic surfactant is present in relatively low but effective concentrations.

Low molecular weight acrylic polymers

Abstract of the Disclosure An ungelled polymeric reaction product having a number average molecular weight of up to about 3000 and having a polydispersity of within 1.2 to 2.5 is prepared by a process involving the vinyl addition polymerization of a vinyl monomer component. At least 30 percent by weight of the vinyl monomer component is an active hydrogen- containing vinyl monomer, and the polymerization is conducted in the presence of an active hydrogen-containing polymer having a number average molecular weight of less than 3000.

Thermosetting cationic acrylic latex compositions containing blocked isocyanates

Abstract of the Disclosure An improved cationic thermosetting latex, coating compositions prepared therefrom, articles coated therewith, and the process for preparing the same are disclosed. Compositions of the instant latices formulated with isocyanate curing agents display improved cure; the improvement resid-ing in selection of surfactants, with particular reference to their gegen-ions, which are used therein.

Polythioether polymers, methods for preparation thereof, and compositions comprising them

Dislcosed are poilythioethers that are the reaction product of reactants that include: a) an isocyanurate-containing trithiol; b) a polythiol different from (a); and c) a diene. Also disclosed are compositions, such as sealant compositions, that include such polythioethers.

Oleophilic compositions, coatings employing the same, and devices formed therefrom

Oleophilic compositions, coatings employing the same, and devices formed therefrom that exhibit one or more improved coating properties. The compositions may comprise a film-forming binder and, when at least partially coated and cured on a substrate, comprise: (a) a contact angle with water ranging from 50 to less than 78; and (b) a contact angle with squalene of less than 25. The coating compositions may include various binder compositions, including, for example, thermosetting acrylic polymers, thermoplastic acrylic polymers, radiation curable coating compositions, and alkoxide compositions. The resultant coatings exhibit one or more improved physical properties, such as improved gloss, improved stain and sebum resistance, and/or improved cleaning ability relative to existing coating systems when deposited over various substrates.

Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Aqueous-based polymers for sound deadening applications

Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Fast drying clear coat composition

A fast-drying coating composition intended primarily as an automotive clear coat contains (A) 25 to 80 weight percent of an acrylic polyol which is the polymerization product of unsaturated monomers of which 0.5 to 15 percent by weight (based on resin solids weight of the monomers) is an acrylate having the structure: where R 1 =H or CH 3 , R 3 is H or an alkyl group, R 4 is an alkyl group, and R 5 is an alkyl group containing at least four carbon atoms; and (B) 20 to 75 weight percent of a curing agent reactive with hydroxyl groups, particularly polyisocyanates.

Acrylic modified polymers

ABSTRACT OF THE DISCLOSURE A liquid, ungelled composition of matter composed of a graft copolymer prepared by the free radical initiated polymerization in an organic medium of a vinyl monomer component which contains at least 0.5 weight percent of an epoxy group containing vinyl monomer in the presence of an acid group containing polymer having an acid value greater than 10mg KOH/g. One means of graft formation is the condensation reaction between the acid groups of the acid group containing polymer and the epoxy groups of the vinyl monomer component. The composition of matter according to the invention are useful in coating compositions.

Fast drying clear coat composition

A fast-drying coating composition intended primarily as an automotive clear coat contains (A) 25 to 80 weight percent of an acrylic polyol which is the polymerization product of unsaturated monomers of which 0.5 to 15 percent by weight (based on resin solids weight of the monomers) is an acrylate having structure (I) where R1=H or CH¿3; R?2 = (II) or (III), R3 is H or an alkyl group, R4 is an alkyl group, and R5 is an alkyl group containing at least four carbon atoms; and (B) 20 to 75 weight percent of a curing agent reactive with hydroxyl groups, particularly polyisocyanates.

Aqueous coating composition for plastic substrates

Azetidinol reaction products

An ungelled reaction product is prepared from a carboxylic acid group containing polymeric material and an azetidinol containing material having one azetidinol moiety per molecule. The ungelled reaction product is particularly useful as a grind vehicle for pigment grind compositions.

WATER-BASED POLYMERS FOR NOISE REDUCTION APPLICATIONS

A stable, one-package, non-gelled coating composition curable under ambient conditions

Acrylic polymers

An acrylic copolymer reaction product of a primary amine group-containing copolymerizable vinyl monomer and an ethylenically unsaturated copolymerizable monomer is disclosed. Further, pigment dispersions, including the copolymer reaction product, pigment, and a liquid carrier, are disclosed.

Oleophilic compositions, coatings employing the same, and devices formed therefrom

Oleophilic compositions, coatings employing the same, and devices formed therefrom that exhibit one or more improved coating properties. The compositions may comprise a film-forming binder and, when at least partially coated and cured on a substrate, comprise: (a) a contact angle with water ranging from 50 to less than 78; and (b) a contact angle with squalene of less than 25. The coating compositions may include various binder compositions, including, for example, thermosetting acrylic polymers, thermoplastic acrylic polymers, radiation curable coating compositions, and alkoxide compositions. The resultant coatings exhibit one or more improved physical properties, such as improved gloss, improved stain and sebum resistance, and/or improved cleaning ability relative to existing coating systems when deposited over various substrates.

Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Waterborne coating compositions, related methods and coated substrates

Disclosed are coating compositions that include a continuous phase that includes water and a dispersed phase that includes a microgel having a mean particle size of greater than 50 nanometers. The microgel is formed from reactants selected so as to provide a copolymer having a certain calculated Tg and includes a cycloaliphatic (meth)acrylate.

Aqueous coating composition for plastic substrates

Aqueous coating compositions containing an aqueous chlorinated polyolefin dispersion and an aqueous polyurethane dispersion are disclosed. These coating compositions are particularly useful for coating plastic substrates. A method of coating plastic substrates comprising the use of these coating compositions and a coated plastic article prepared by the above method are also disclosed.

Waterborne coating compositions, related methods and coated substrates

Film-forming compositions substantially free of organic solvent, multi-layer composite coatings and related methods

Film-forming compositions are disclosed that are substantially free of organic solvent. The film-forming compositions include a resinous binder and at least one water dilutable additive including the reaction product of (i) a reactant including at least one isocyanate functional group with (ii) an active hydrogen containing alkoxypolyalkylene compound. Also disclosed are multi-layer composite coatings that include such film-forming compositions and methods of applying such multi-component composite coatings to a substrate.

Waterborne coating compositions, related methods and coated substrates

DISCLOSED ARE COATING COMPOSITIONS THAT INCLUDE A CONTINUOUS PHASE THAT INCLUDES WATER AND A DISPERSED PHASE THAT INCLUDES A MICROGEL HAVING A MEAN PARTICLE SIZE OF GREATER THAN 50 NANOMETERS. THE MICROGEL IS FORMED FROM REACTANTS SELECTED SO AS TO PROVIDE A COPOLYMER HAVING A CERTAIN CALCULATED TG AND INCLUDES A CYCLOALIPHATIC (METH) ACRYLATE.

Single component, waterborne coating compositions, related multi-component composite coatings and methods

Disclosed are single component storage stable, waterborne coating compositions. The coating compositions comprise a film-forming resin composition comprising a first film-forming resin comprising an acrylic polyol, a second film-forming resin, and a curing agent. Also disclosed are substrates at least partially coated with a coating deposited from such compositions, multi-component composite coatings wherein at least one coating layer is deposited from such compositions, and methods for improving the mar and/or chemical resistance of a coating deposited from a single component storage stable waterborne coating composition.

Non-isocyanate ambient temperature curable coating compositions

Color plus clear coating method utilizing addition interpolymers from isobornyl (meth)acrylate which contain alkoxysilane and/or acyloxysilane groups

Disclosed is a method of coating a substrate comprising the steps of (a) forming a basecoat by coating the substrate with one or more applications of a pigmented basecoating composition; and (b) thereafter forming a topcoat by coating the basecoat with one or more applications of an essentially clear topcoating composition; wherein the basecoating composition and/or the topcoating composition comprises an addition interpolymer containing at least one silicon atom directly bonded to a hydrolyzable group, which addition interpolymer (vinyl type) is derived from a mixture of copolymerizable ethylenically unsaturated monomers containing an isobornyl group-containing monomer selected from the group consisting of isobornyl methacrylate, isobornyl acrylate and a mixture thereof. The amount of isobornyl group-containing monomer based on the total weight of the mixture of copolymerizable ethylenically unsaturated monomers ranges from 10 percent to 60 percent by weight.

Dual cure coating compositions, multi-component composite coatings, and related coated substrates

Disclosed herein are dual cure coating compositions that include a melamine group-containing polyethylenically unsaturated compound and a polysiloxane. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.

Film-forming compositions containing alkoxysilane functional acrylic polymers

A storage-stable, curable film-forming composition is provided comprising: (i) a cross-linking agent selected from an aminoplast, a blocked polyisocyanate, and mixtures thereof; and (ii) a hydroxyl functional acrylic polymer further containing a plurality of alkoxysilane groups of structure (1) wherein R1 is hydrogen or methyl, and R2 is a divalent group. The acrylic polymer is prepared in a solvent medium comprising an alcohol. The curable film-forming composition is suitable for use in color-plus-clear composite coating compositions.

Aqueous emulsion polymers prepared with crosslinkable non-ionic surfactants

ABSTRACT A stable aqueous polymer emulsion contains an aqueous continuous phase, a dispersed polymeric phase and a polyhydroxyl functional, non-ionic surfactant wherein the hydroxyl groups are separated by 4 or more carbon atoms and the surfactant is substantially free of oxyethylene units.

Powder coating compositions and coated substrates with multilayered coatings

Curable powder clear coating composition and coated substrate with multilayered coatings have as the predominant film-forming polymer in the coating at least one epoxy acrylic copolymer in an amount from 60 to 99.99 percent by weight and 10 to 40 percent by weight of a polycarboxylic acid crosslinking agent. The percentages by weight are based on solids of the curable coating composition. A single predominant film-forming epoxy acrylic copolymer has a number average molecular weight in the range of about 1000 to 5500; a calculated Tg in the range of 50 to 85°C; epoxy content in the range of 35 to 85, and a styrene content resulting from an amount of styrene monomer in the range of up to about 25 weight percent based on the weight percent of the monomers to form the copolymer. The blend of epoxy acrylic copolymer has one polymer which is the single epoxy acrylic copolymer or one having a number average molecular weight in the range of about 1000 to about 10,000, a calculated Tg in the range of about 40°C to 85°C, and an epoxy content from 40 to 60 weight percent of the total weight of the monomers to prepare the epoxy acrylic copolymer. The other polymer of the blend has a number average molecular weight in the range of about 500 to about 3000, a calculated Tg in the range of about 35°C to about 125°C, and an epoxy content from glycidyl functional ethylenically unsaturated monomer that is higher than that of the first epoxy functional acrylic copolymer of the blend and in the range of about 50 to about 100.

Dual cure coating compositions, multi-component composite coatings, and related coated substrates

Disclosed herein are dual cure coating compositions that include a melamine group-containing polyethylenically unsaturated compound and a polysiloxane. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.

Polythioether polymers, methods for preparation thereof, and compositions comprising them

Dislcosed are poilythioethers that are the reaction product of reactants that include: a) an isocyanurate-containing trithiol; b) a polythiol different from (a); and c) a diene. Also disclosed are compositions, such as sealant compositions, that include such polythioethers.

Coating compositions having a geometrically ordered array of polymeric particles and substrates coated therewith

Coating materials comprising polymeric particles in a geometrically ordered array are disclosed. The particles can be formed from materials having different glass transition temperatures; this allows for phase segregation between areas of different glass transition temperatures within each particle. Typically, at least 50 percent of the particles will form a hexagonal array, capable of exhibiting Bragg diffraction. Because the particles within the array do not coalesce to any appreciable extent, significant surface area is provided by the present coating materials. Thus, the present materials have particularly good sound deadening properties. Substrates coated with the present materials are also disclosed, as are methods for inhibiting sound transmission through a substrate using these coatings.

Azetidinol reaktionsprodukte

Multilayered coating with a powder clear coat, substrates coated therewith and method for making it

Cured thermoset multilayered composite coatings with a powder clear coat and a waterborne base coat have improved chip resistance for the coating. The waterborne base coat composition has one or more cross linkable film-forming polymers, one or more cross linking agents for cross linking the film-forming polymer, and one or more pigments. This basecoat is applied to a bare or previously painted substrate to give a film thickness in the range of about 0.1 to 3 mils (2.54 to 76.2 microns). The basecoat is dehydrated from treatment at a temperature from ambient to an elevated temperature of up to about 90 °C for up to about 15 minutes before it is contacted with powder clear coating composition. The powder clear coating composition has a predominant amount of one or more cross linkable, meltable and mobile film-forming polymer and/or copolymer having a weight average molecular weight of one or more polymers/copolymers in the range of about 2000 to about 6000. The film-forming polymer or copolymer has an amount of functionality for cross linking of at least 40 weight percent of the total resin solids for the polymers. The glass transition temperature for the powder coating composition is at least about 25 °C. The powder coating composition for the clear coat also has one or more cross linking agents and when cured has a film thickness in the range of about 35 to about 100 microns. The basecoat and clear coat are co-cured. Optionally, one or more primer coats may be beneath the basecoat.

Powder coating compositions and coated substrates with multilayered coatings

Curable powder clear coating composition and coated substrate with multilayered coatings have as the predominant film-forming polymer in the coating at least one epoxy acrylic copolymer in an amount from 60 to 99.99 percent by weight and 10 to 40 percent by weight of a polycarboxylic acid crosslinking agent. The percentages by weight are based on solids of the curable coating composition. A single predominant film-forming epoxy acrylic copolymer has a number average molecular weight in the range of about 1000 to 5500; a calculated Tg in the range of 50 to 85 °C; epoxy content in the range of 35 to 85, and a styrene content resulting from an amount of styrene monomer in the range of up to about 25 weight percent based on the weight percent of the monomers to form the copolymer. The blend of epoxy acrylic copolymer has one polymer which is the single epoxy acrylic copolymer or one having a number average molecular weight in the range of about 1000 to about 10,000, a calculated Tg in the range of about 40 °C to 85 °C, and an epoxy content from 40 to 60 weight percent of the total weight of the monomers to prepare the epoxy acrylic copolymer. The other polymer of the blend has a number average molecular weight in the range of about 500 to about 3000, a calculated Tg in the range of about 35 °C to about 125 °C, and an epoxy content from glycidyl functional ethylenically unsaturated monomer that is higher than that of the first epoxy functional acrylic copolymer of the blend and in the range of about 50 to about 100.

Pulverlackbeschichtungen auf basis von (meth)acrylatfunktionellen polyurethanen

(meth)acrylate functional polyurethane and method of making

The present invention relates to a powder coating composition comprising the reaction product of (a) a polyisocyanate with (b) the reaction product of (i) a polyol having at least three hydroxyl groups, one of which is less reactive than the other hydroxyl groups, and (ii) a (meth)acrylic acid or functional equivalent thereof, in which the equivalent ratio of (ii) to (i) is (n−1):n, where n is the hydroxyl functionality of the polyol, and the equivalent ratio of (a) to (b) is about 1:1.

Composiciones de revestimiento en polvo en base a poliuretanos con funcionalidad (met)acrilato

Una composición de revestimiento en polvo curable por UV que comprende un poliuretano con funcionalidad (met) acrilato formado a partir de hacer reaccionar: (a) un poliisocianato; y (b) el producto de reacción de: (i) un poliol que tiene al menos tres grupos hidroxilo, uno de los que es menos reactivo que los otros grupos hidroxilo, y (ii) un ácido (met) acrílico o equivalente funcional del mismo, en el que la relación equivalente de (ii) y (i) es (n-1) :n, en la que n es la funcionalidad hidroxilo del poliol, y la relación equivalente de (a) y (b) es aproximadamente 1:1.

Proszkowe kompozycje powlekające oparte na poliuretanach funkcjonalizowanych (met)akrylanami

Composiciones de revestimiento, sustratos revestidos y procedimiento de inhibicion de la transmision de los sonidos a traves de un sustrato.

Uso de una composición de recubrimiento para inhibir la transmisión de sonido a través de un sustrato revestido con dicha composición de recubrimiento que consiste en: (a) una dispersión acuosa de micropartículas poliméricas preparada a partir de componentes que consisten en: (i) un componente seleccionado del grupo que consiste en un material con función nitrilo, un material con función amida y un material con función carbamato; y (b) un material de carga.

Wässrige Emulsionspolymere, hergestellt mit vernetzbaren nichtionischen Emulgiermitteln

Wässrige Emulsionspolymere, hergestellt mit vernetzbaren nichtionischen Emulgiermitteln

Wässrige emulsionspolymere, hergestellt mit vernetzbaren nichtionischen emulgiermitteln

Beschichtungszusammensetzungen, damit beschichtete Oberfläche und Verfahren zur Hemmung der Schallübertragung durch die Oberfläche

Beschichtungszusammensetzungen, damit beschichtete Oberfläche und Verfahren zur Hemmung der Schallübertragung durch die Oberfläche

Coating compositions, coated substrates and methods for inhibiting sound transmission through a substrate

The present invention provides coating compositions including aqueous dispersions of polymeric microparticles prepared from nitrile, carbamate and amide functional materials, polyoxyalkylene acrylates and/or hydroxy functional materials, which are useful for sound deadening applications.

Composiciones de revestimiento, sustratos revestidos y procedimiento de inhibicion de la transmision de los sonidos a traves de un sustrato.

Uso de una composición de recubrimiento para inhibir la transmisión de sonido a través de un sustrato revestido con dicha composición de recubrimiento que consiste en: (a) una dispersión acuosa de micropartículas poliméricas preparada a partir de componentes que consisten en: (i) un componente seleccionado del grupo que consiste en un material con función nitrilo, un material con función amida y un material con función carbamato; y (b) un material de carga.