29-09-2022 дата публикации
Номер: US20220306463A1
Принадлежит:
A process and apparatus for producing a hydrogen-enriched product and recovering COfrom an effluent stream from a hydrogen production process unit are described. The process utilizes a COrecovery system integrated with a PSA system that produces at least two product streams to recover additional hydrogen and COfrom the tail gas stream of a hydrogen PSA unit in the hydrogen production process. 1. A method of producing a hydrogen-enriched product and recovering COcomprising:processing a feed stream comprising hydrocarbons or a carbonaceous feedstock in a hydrogen production process unit to produce a synthesis gas mixture comprising hydrogen, carbon dioxide, water, and at least one of methane, carbon monoxide, nitrogen, and argon;separating an effluent stream comprising the synthesis gas from the hydrogen production process unit in a hydrogen pressure swing adsorption (PSA) unit into a first high-pressure hydrogen stream enriched in hydrogen and a hydrogen depleted tail gas stream comprising a portion of the hydrogen, the carbon dioxide, the water, and the at least one of the methane, the carbon monoxide, the nitrogen, and the argon;compressing the hydrogen depleted tail gas stream in a compressor to form a compressed tail gas stream;{'sub': 2', '2, 'separating the compressed tail gas stream in a COrecovery system into a CO-enriched product stream and an overhead stream comprising the portion of the hydrogen, a portion of the carbon dioxide, and the at least one of the methane, the carbon monoxide, the nitrogen, and the argon;'}{'sub': 2', '2, 'separating the overhead stream from the COrecovery system in a PSA system that produces at least two product streams into at least a second high-pressure hydrogen stream enriched in hydrogen, and a low-pressure COstream enriched in carbon dioxide;'}recovering the second high-pressure hydrogen stream; and{'sub': '2', 'optionally recycling the low-pressure COstream to the compressor.'}2. The method of wherein the PSA system that ...
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