23-05-2023 дата публикации
Номер: CN116154275A
Принадлежит:
The invention discloses an in-situ gel preparation method, and belongs to the technical field of lithium metal batteries. According to the method, a trace amount of initiator is introduced, so that 1, 3-dioxolame DOL in the electrolyte is subjected to ring-opening polymerization reaction, and in-situ solidification of the liquid ether-based electrolyte on the surface of a lithium negative electrode is realized by forming DOL crosslinking in advance. And then injecting an electrolyte into the soft package battery with the formed gel phase to construct a gel phase-liquid phase two-phase system. By controlling the ratio of the electrolyte to the poly-DOL, gradient curing of the ether electrolyte in the battery is realized, and the mechanical property of the gel electrolyte is adjusted. The intermolecular interaction exists between polyDOL and lithium salt anions, the ionic conductivity and the lithium ion transference number of the gel electrolyte are remarkably improved, a formed in-situ ...
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