25-09-2014 дата публикации
Номер: US20140288220A1
Disclosed are heat resistant polyamide compositions including a) one or more polyamide resins, b) one or more reinforcing agents, c) a zinc compound; d) a copper heat stabilizer; and optionally, e) a polyhydric alcohol. 2. The polyamide composition of wherein 0.25 to 5.0 weight percent polyhydric alcohol is present.3. The polyamide composition of wherein the zinc compound is selected from the group of zinc borate claim 1 , zinc oxide and mixtures of these.4. The polyamide composition of wherein 2 mm test bars prepared from said polyamide composition claim 1 , exposed at a test temperature of 230° C. for a test period of 1000 hours claim 1 , in an atmosphere of air claim 1 , and subsequently tested according to ISO 527-2/1A claim 1 , have claim 1 , on average claim 1 , a retention of tensile strength of at least 66 percent claim 1 , as compared with that of an unexposed control of identical composition and shape.5. The polyamide composition of wherein 2 mm test bars prepared from said polyamide composition claim 1 , exposed at a test temperature of 230° C. for a test period of 1000 hours claim 1 , in an atmosphere of air claim 1 , and subsequently tested according to ISO 527-2/1A claim 1 , have claim 1 , on average claim 1 , a tensile strength of at least 100 MPa.6. The polyamide composition of wherein the polyamide resin is selected from the group consisting of Group (III) polyamides.7. The polyamide composition of wherein the polyamide resin comprises about 1 to 20 weight percent of polycaprolactam.8. The polyamide composition of wherein the polyamide resin is selected from the group consisting of poly(hexamethylene hexanediamide) (PA 66) claim 1 , poly(hexamethylene hexanediamide/hexamethylene terephthalamide) (PA 66/6T) claim 1 , poly(ε-caprolactam) (PA 6) claim 1 , and combinations of these.9. The polyamide composition of wherein the reinforcing agent is selected from the group consisting of circular glass fibers claim 1 , noncircular glass fibers claim 1 , ...
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