09-06-2010 дата публикации
Номер: CN0101723817A
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The invention discloses a method for preparing 2, 3-butanedione, which takes acetaldehyde as raw material, substituted 5-ethoxy thiazole salt as catalyst of acetaldehyde coupling condensation reaction and one or more in MnO2, Bi2O3, CuSO4 or Fe2(SO4)3 as catalyst for preparing the 2, 3-butanedione by acetylmethylcarbinol oxidative dehydrogenation; and the method adopts a 'one pot' method to realize the new technique for preparing the 2, 3-butanedione by carrying out coupling condensation reaction and oxidative dehydrogenation reaction on dimolecular acetaldehyde. The thiazole salt catalyst ofthe method is simple in preparation and low in cost, the dosage of the catalyst in the oxidative dehydrogenation reaction is less, and the technique process flow for preparing the 2, 3-butanedione issimplified by the 'one pot' method. The acetaldehyde has the conversion rate of 80-91%, and the 2, 3-butanedione has the selectively of 80-90%. Therefore, the process route provides a new method for the ...
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