15-02-2018 дата публикации
Номер: US20180048029A1
The invention relates to sodium-ion-conducting elements for use in electrochemical cells, more particularly as solid electrolyte/separator in high-temperature batteries. In these elements, a surface of a porous substrate bears a coating which is obtained by sintering at a temperature of not more than 1100° C. and which is formed with the system NaO—SiO—RO—R1O, in which R1=Sc, Y, La and/or B and R2=P, Sb, Bi, Sn, Te, Zn and/or Ge. 1. A sodium-ion-conducting element for use in electrochemical cells , more particularly as solid electrolyte/separator in high-temperature batteries , wherein a surface of a porous substrate bears a coating which is obtained by sintering at a temperature of not more than 1100° C. and which is formed with the system NaO—SiO—RO—R1O , in which R1=Sc , Y , La and/or B and R2=P , Sb , Bi , Sn , Te , Zn and/or Ge.2. The element as claimed in claim 1 , characterized in that the coating has a thickness in the 3 μm to 750 μm range.3. The element as claimed in claim 1 , characterized in that the material of the coating has a coefficient of thermal expansion which is lower claim 1 , preferably lower by not more than 1.5 ppm/K claim 1 , than the coefficient of thermal expansion of the substrate material.4. The element as claimed in claim 1 , characterized in that the substrate is an element in the shape of a plate claim 1 , honeycomb claim 1 , or tube which is open at one side.5. The element as claimed in claim 1 , characterized in that the substrate is formed of AlO claim 1 , mullite claim 1 , spinel claim 1 , fosterite claim 1 , ZrO claim 1 , a silicatic ceramic material claim 1 , an electrically conducting ceramic material claim 1 , or a metal or a metal alloy.6. The element as claimed in claim 1 , characterized in that electrically conducting ceramic substrate material consists of Nb-doped TiO claim 1 , CaLaTiOor SrYTiOor of a mixture of these components with AlO claim 1 , mullite claim 1 , spinel claim 1 , fosterite claim 1 , ZrOor a silicatic ...
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