26-06-1963 дата публикации
Номер: GB929457A
The invention comprises substituted pyridazones of formula <FORM:0929457/IV(a)/1> in which A denotes a hydrogen atom, B denotes a hydroxyl group, or A and B together denote an oxo radical (= o), R denotes a hydrogen atom, a linear or branched alkyl group, a linear or branched halogensubstituted alkyl group, a halogen-substituted phenoxy- or an alkylhalo-phenoxy-alkyl group, an alkenyl group, an aralkyl group, the group <FORM:0929457/IV(a)/2> when A and B together represent an oxo radical, a phenyl group or a halogen-substituted phenyl group, and D denotes a phenyl group or a cycloalkyl group. The compounds can be prepared by reacting aminopyridazones of formula <FORM:0929457/IV(a)/3> with aldehydes, carboxylic acids or carboxylic acid derivatives having the formula RCOX in which R has the meaning given above and X is H, Cl, Br, OH or the group -OCOR. For example, 1-phenyl-4-chloroacetyl-amino-5-chloropyridazone-6 is obtained by treating the corresponding 4-amino compound with chloroacetyl chloride. The 4-amino starting compound may be obtained by reacting the corresponding 4-chloro compound with ammonia in methanol. The compounds of the invention are effective herbicides and can also be used to influence plant growth in other ways (see Groups I and VI). Several compounds are specified, typical examples being:-1-phenyl-4-hydroxy-methylamino-5-chloropyridazone-6, 1-phenyl-4-b ,b , b - trichloroa -hydroxyethylamino- 5-chloropyridazone-6, 1-phenyl- 4-a - chloro-n-butyrylamino-5-chloropyridazone-6, 1-phenyl-4-(21-methyl-41-chlorophenoxy) - acetylamino-5-chloropyridazone-6, N,N1-bis- [1-phenyl-5-chloropyridazone-6-yl-4]-oxalic acid diamide, and 1-cyclooctyl- 4-chloroacetylamino-5-chloropyridazone-6.ALSO:Compositions for influencing plant growth comprise as the active ingredient a substituted pyridazene of formula <FORM:0929457/I/1> in which A denotes a hydrogen atom, B denotes a hydroxyl group, or A and B together denote an oxo radical (= O), R ...
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