12-07-2018 дата публикации
Номер: US20180194682A1
Принадлежит:
The invention relates to the use of carboxylic acid-based polyoxyalkylenes as low-emissions shrinkage reducers in mineral binders, to methods of reducing shrinkage and to corresponding compositions. 2. The shrinkage-reducing agent according to claim 1 , wherein claim 1 , in formula (I) claim 1 , the R radical is independently an aliphatic hydrocarbyl radical having from 3 to 38 carbon atoms claim 1 , where the carbon chain is terminally substituted by 1 or 2 polyoxyalkylene radicals A and a is the number of polyoxyalkylene radicals A and is 1 or 2.3. The shrinkage-reducing agent according to claim 1 , wherein the R radicals derive from a fatty acid or a dimer fatty acid.4. The shrinkage-reducing agent according to claim 1 , wherein the R radicals derive from hexanoic acid claim 1 , heptanoic acid claim 1 , octanoic acid claim 1 , nonanoic acid claim 1 , decanoic acid claim 1 , undecanoic acid claim 1 , dodecanoic acid claim 1 , tridecanoic acid claim 1 , tetradecanoic acid claim 1 , pentadecanoic acid claim 1 , hexadecanoic acid claim 1 , heptadecanoic acid claim 1 , octadecanoic acid claim 1 , nonadecanoic acid claim 1 , eicosanoic acid claim 1 , 2-ethylhexanecarboxylic acid claim 1 , isononanoic acid claim 1 , 3 claim 1 ,5 claim 1 ,5-trimethylhexanecarboxylic acid claim 1 , neodecanoic acid claim 1 , isotridecanecarboxylic acid claim 1 , isostearic acid claim 1 , undecylenoic acid claim 1 , oleic acid claim 1 , linoleic acid claim 1 , ricinoleic acid claim 1 , linolenic acid claim 1 , benzoic acid claim 1 , cinnamic acid claim 1 , phthalic acid claim 1 , isophthalic acid claim 1 , terephthalic acid claim 1 , cyclohexanecarboxylic acid claim 1 , hexahydrophthalic acid claim 1 , tetrahydrophthalic acid claim 1 , methyltetrahydrophthalic acid or the dimer fatty acids that derive from the aforementioned unsaturated carboxylic acids.5. The shrinkage-reducing agent according to claim 1 , wherein claim 1 , in formula (I) claim 1 , a is less than 3.6. The shrinkage- ...
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