11-05-2017 дата публикации
Номер: US20170133162A1
Принадлежит:
A device for storing electrical energy comprises a photo electrode, having a semiconductor layer with a photo dye thereon, a counter electrode, a reservoir comprising a solvent, a first redox mediator for enabling a redox reaction at the photo electrode, a second redox mediator for enabling a redox reaction at the counter electrode, wherein the photo electrode and the counter electrode are at least partly in the solvent, the first redox mediator is adapted to form an entity that is soluble in the solvent when the first redox mediator is in its reduced state, and an entity that is insoluble in the solvent when the first redox mediator is in its oxidized state. 2. A device according to claim 1 , wherein the second redox mediator is adapted to form: 'an entity that is insoluble in the solvent when the first redox mediator is in its reduced state.', 'an entity that is soluble in the solvent when the second redox mediator is in its oxidized state; and'}3. A device according to claim 1 , wherein the working electrode comprises a non-soluble coating claim 1 , the coating comprising the second redox mediator.4. A device according to claim 2 , the device being operable to perform in a charging cycle the steps of:injecting, upon solar spectrum excitation, electrons by the photo dye into the semiconductor layer that travel via a charging circuit from the photo electrode to the counter electrode;oxidizing the first redox mediator at the photo electrode, thereby depositing the first redox mediator at the photo electrode and releasing electrons to the photo electrode in order to reduce the photo dye;reducing the second redox mediator at the counter electrode by means of the electrons that travelled from the photo electrode to the counter electrode, thereby depositing the second redox mediator at the counter electrode.5. A device according to claim 2 , the device being operable to perform in a discharging cycle the steps of:oxidizing, at the counter electrode, the second redox ...
Подробнее