01-11-1972 дата публикации
Номер: GB1294795A
1294795 Selective hydrogenation INSTITUT FRANCAIS DU PETROLE DES CARBURANTS ET LUBRIFIANTS 19 April 1971 [6 April 1970 23 Dec 1970] 26021/71 Addition to 1233129 Heading G5E [Also in Division B1] A polyolefin or an acetylenically unsaturated compound is selectively hydrogenated to a monoolefin by contact with (a) hydrogen (b) a tertiary or heteroaromatic amine and (c) a catalyst comprising a transition metal compound and an aluminium compound of the formula M(AlH m X 4-m ) p where m is 1, 2 or 3, M is a univalent or bivalent metal of Group Ia or IIa, p is the valency of M and each X is R, OR, NR 2 , NHR or SR group wherein R is a univalent optionally substituted hydrocarbyl radical or two R groups together form a bivalent radical -A-Z-B- where A and B are alkylene radicals and Z is O, S, Al, alkylene, NH, or N-hydrocarbyl group. Suitable amines are trimethyltriethyl- and triisobutylamines, dimethylaniline, quinoline, methyl-2-pyridine, N- methyl piperidine, NN<SP>1</SP>-dimethyl piperazine, pyrazine. or preferably pyridine. The transition metal compound is preferably a Ni compound, e.g. an octoate, stearate or naphthenate. Suitable Al compounds are NaAlH 2 (Ot-Bu) 2 and NaAlH 2 (OCH 2 CH 2 OCH 3 ) 2 . Examples describe the hydrogenation of (1) cyclopentadiene to cyclopentene, (2) hexyne-1 to hexene-1, (3) propyne to propene, and (4) butadiene to butene. Other possible feeds mentioned are 1,3- and 1,5-cyclooctadiene and cyclododecatriene. The hydrogenation may be effected at - 20 to + 200 C., 1-200 atmos. H 2 and in the presence of 0À1-100 p.p.m. CO.
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